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1.
The consequences on the chemistry in diffuse clouds of the injection of small hydrocarbon molecules is explored. It is assumed that the injection arises from the erosion of carbonaceous grains at cloud boundaries, and that the injected species take part in conventional interstellar chemistry. The models indicate that for plausible injection rates the daughter species of the injected parent molecules should appear in significant amounts, at least during the injection period, and that daughter species can appear in gas that is otherwise almost entirely atomic. Therefore, injection of hydrocarbons is a mechanism that is capable of providing polyatomic molecules in detectable amounts in diffuse atomic regions of the interstellar medium. The implications of this result for the carriers of the unidentified diffuse interstellar bands are briefly described. 相似文献
2.
A model of the formation of molecules by surface reactions on interstellar grains is described and assessed numerically. The model predicts that for the molecules—other than H2-likely to be important in the interstellar medium, the formation rates by surface reactions are insensitive to the nature of the surface. The formation rates have magnitudes which are significant when compared with other routes. The model also describes H2 formation in high density clouds and shows it to be parameter dependent. 相似文献
3.
M. Y. Amin 《Earth, Moon, and Planets》1996,73(2):133-145
A new time-dependent model of chlorine chemistry in cold and warm TMC-1 and Orion clouds was constructed using results of recent laboratory and theoretical studies on the reaction of chlorine molecules. The chemistry of chlorine was found to be fairly simple in dense interstellar clouds. Only the species Cl and HCl have a significant fractional abundance. Our results for the HCl molecule are in agreement with those obtained from the observation and from theoretical values of Orion cloud. 相似文献
4.
We show how, given observed equivalent widths of Mgii and Mgi absorptions due to an interstellar cloud in which a late-B star is embedded, the basic physical parameters: kinetic temperature, mean density, electron density, and radius can be constrained. Hydrogen ionization by means of cosmic rays and the effect of the stellar radiation field on the magnesium ionization equilibrium are taken into account.The method is applied to the reflection nebula surrounding the star HD 26676. The resulting solutions for the radius and temperature of the nebulosity are comparable to the typical values derived for diffuse interstellar clouds from optical and 21-cm measurements, if a cosmic-ray ionization rate 10–16s–1 — in agreement with recent determinations — is assumed. The results are not strongly dependent on the gas pressureP forP varying in a range of values typical of interstellar clouds. 相似文献
5.
The abundance ratio of neutral hydrogen to helium, as deduced from interplanetary observations of Lyman-alpha and He 584 Å radiation by Mariner 10, is significantly lower than the cosmic abundance ratio of these elements, thus showing that the local interstellar medium (LISM) is partly ionized. The effect of various sources of ionization — especially electron impact and EUV photon flux — on hydrogen and helium is discussed. It is shown that the observational data on the temperature of the LISM, on the diffuse EUV flux and on the neutral and electron densities in the nearby interstellar medium (NISM) are not all compatible. However, if the diffuse EUV flux below 912 Å as deduced from the preliminary analysis of Voyager observations is not representative, then it is easy to reconcile all observations. In this case an important source of ionization of the LISM would be electron impact, yielding an ionization degree of about 50% for the hydrogen component. 相似文献
6.
In this review, the nature of carbon-containing molecules and carbonaceous solids present in meteorites, comets, and the interstellar
medium is discussed. Carbon plays an active role in the lifecycle of stars and the interstellar medium. It is the basis of
a rich interstellar chemistry and the main component of pre-biotic organic material in space. The aim of the review is to
build a bridge between astronomical spectroscopy and laboratory studies relevant to the investigation of cosmic carbon. Special
emphasis is given to the structural variety of carbon-containing species and their characterization by experimental techniques.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
7.
Several organic molecules have now been detected in the coma of Hale–Bopp. These species may either emanate from the nucleus, or, as has been suggested by Bockelée–Morvan et al., could be synthesized in the coma. We have modelled the gas phase chemistry which occurred in the coma of Hale–Bopp, concentrating on the observed organic molecules HCOOH, HCOOCH3 , HC3 N and CH3 CN. We find that gas phase chemical reactions are unable to synthesize the observed abundances of these molecules, so all these species are most probably present in the nuclear ice. We briefly discuss the implications of this result for the connection between cometary and interstellar ices. 相似文献
8.
Taking advantage of the fact that Be stars produce a characteristic infra-red excess, the DENIS data — in combination with UBV and IRAS photometric data — can provide us with a quite complete sample of Be stars within about 4 kpc around the sun. This will give us the possibility to carry out further studies to see if there presence is correlated with particular physical characteristics of the interstellar medium surrounding them. 相似文献
9.
Laboratory and theoretical studies have been made of the effects of ultraviolet photolysis of interstellar grain mantles which consist of combinations of hydrogen, oxygen, carbon and nitrogen — dirty ice. It is shown that processes involving photolysis (photoprocessing) of interstellar grains are important during most of their lifetime even including the time they spend in dense clouds. A laboratory designed to simulate the interstellar conditions is described. This is the first time such a laboratory has been able to provide results which may be directly scaled to the astrophysical situations involving interstellar grains and their environment. The evolution of grain analogs is followed by observing the infrared absorption spectra of photolyzed samples of ices deposited at 10 K. The creation and storage of radicals and the production of molecules occur as a result of reactions within the solid. A large number of molecules and radicals observed in the interstellar gas appear in the irradiated ices. Energy released during warm-up is seen from visible luminescence and inferred from vapor pressure enhancement which occurs during warming of photolyzed samples relative to unphotolyzed samples. The evolution of a grain and its role as a source as well as a sink of molecules is pictured as a statistical process within dense clouds. The gradual accretion on and photolysis of an individual grain provides the stored chemical energy the release of which is sporadically triggered by relatively mild events (such as low velocity grain-grain collisions) to produce the impulsive heating needed to eject or evaporate a portion of the grain mantle. An extremely complex and rather refractory substance possessing the infrared signatures of amino groups and carboxylic acid groups and having a maximum mass of 514 amu has been produced at a rate corresponding to a mass conversion rate of interstellar grains of between 2% and 20% in 107 yr. The shape and position of the astronomically observed 3.1 m band is duplicated in the laboratory and is shown to be a natural consequence of the processing of grain mantles.Invited contribution to the Proceedings of a Workshop onThermodynamics and Kinetics of Dust Formation in the Space Medium held at the Lunar and Planetary Institute, Houston, 6–8 September, 1978. 相似文献
10.
We have derived the real and imaginary indices of refraction for 10 phyllosilicate minerals—montmorillonite, beidellite, nontronite, hectorite, saponite, illite, illite–smectite (60/40 interlayered) kaolinite, halloysite, and serpentine—from 100–2000 cm−1 (5–100 μm) at 2 cm−1 spectral sampling using classical Lorentz–Lorenz dispersion theory. We present the real and imaginary indices and the oscillator parameters with which they were modeled. Use of these optical constants will aid in the modeling of thermal infrared spectra of planets, asteroids, interplanetary and interstellar dust, and protoplanetary disks around nearby stars. 相似文献
11.
A fairly complete but limited set of gas phase reactions involving nitrogen-bearing molecules is linked to a simple model of grain surface reactions. Calculations are performed attempting to simulate the nitrogen chemistry in interstellar clouds of low and high density. While it appears probable that grain surface reactions contribute to the chemistry in both régimes, conclusive evidence awaits observational and theoretical developments. 相似文献
12.
A survey of the distribution of long carbon chain molecules in interstellar clouds shows that their abundance is correlated. The various formation schemes for these molecules are discussed. We conclude that the ion-molecule type formation mechanisms are more promising than their competitors. They have also the advantage of allowing predictions which can be tested by observations. Acetylene C2H2 and diacetylene HCCCCH, may be very abundant in interstellar clouds.Invited contribution to the Proceedings of a Workshop onThermodynamics and Kinetics of Dust Formation in the Space Medium held at the Lunar and Planetary Institute, Houston, 6–8 September, 1978. 相似文献
13.
D. A. Mendis 《Astrophysics and Space Science》1979,65(1):5-12
Cosmic dust is invariably immersed in a plasma and a radiative environment. Consequently, it is charged to some electrostatic potential which depends on the properties of the environment as well as the nature of the dust. This charging affects the physical and dynamical properties of the dust. In this paper the basic aspects of this dust-plasma interaction in several cosmic environments — including planetary magnetospheres, the heliosphere and the interstellar medium — are discussed. The physical and dynamical consequences of the interaction, as well as the pertinent observational evidence, are reviewed. Finally, the importance of the surface charge during the condensation process in plasma environments is stressed.Invited contribution to the Proceedings of a Workshop onThermodynamics and Kinetics of Dust Formation in the Space Medium held at the Lunar and Planetary Institute, Houston, 6–8 September, 1978. 相似文献
14.
T. J. Millar 《Astrophysics and Space Science》1980,72(2):509-517
The equilibrium chemistry of silicon in dense interstellar clouds is discussed in terms of both gas phase and grain surface reactions. Unless the metal depletion is very large, the gas phase scheme tends to over-produce SiO and/or SiS when compared to the observations of Sgr B2. The scheme also predicts SiC to be an abundant form of silicon. There is a great need for relevant laboratory data on the reactions used here—of the 35 rate coefficients adopted in the scheme, only three have been measured in the laboratory. Reactions between positively charged gas phase ions and small grains can lead to the formation of SiO and SiS. This type of reaction seems to offer a simple explanation for the observed differences between sulphur and silicon chemistry in dense clouds. 相似文献
15.
It is not a trivial problem to imagine how a spherical high-pressure balloon with supersonic gas jets leaving from pores densely distributed on its surface can be influenced by an ambient gas flow. The relative motion of such a balloon can be controlled by a corresponding rearrangement of the gas outflow into an aspherical configuration. A similar problem is connected with stars driving a supersonic stellar wind and moving relative to the interstellar medium. As we shall show, the adapted circumstellar flow leads to an upwind-downwind pressure asymmetry balancing the momentum loss that is braking such stars. The opposite process — i.e., acceleration — may occur if luminous stars are closely associated and their wind systems interfere with each other. This should lead to a mutual repulsion. 相似文献
16.
The evolution of the different chemical species are followed in a model of contracting interstellar cloud. The central density increases from n = 10 cm–3 diffuse initial cloud model to a dense cloud with central density number of n >- 105 cm–3 after a time of 1.2 × 107 yr. A network of 622 reactions has been involved. The chemistry of the cloud is integrated simultaneously with the hydrodynamic equations of contraction.The results predict that the different molecular species increase in abundance as the contraction proceeds. The species which enhance significantly are CO, HCO, CS and NO. The fractional abundances of many of the other molecular species increase distinctly with contraction, e.g. CH, C2H, CN, SO2, CO2, H2O, C2, NH3, HCN, SO, OCS and SN. The transformation of the initial diffuse cloud model with small abundances of molecular species to a dense molecular cloud with enhancement of the different molecular species is confirmed. The results predict good agreements of our results with both the observations and other theoretical studies. 相似文献
17.
Theodore P. Snow Jr. 《Astrophysics and Space Science》1979,66(2):453-466
Observational results obtained to date on interstellar grains and molecules are briefly reviewed, and several promising areas for further research withSpacelab are suggested. Regarding grains, useful data can be expected on the shape of the ultraviolet extinction curve for new interstellar regions; the nature of UV extinction at short wavelengths, down to the Lyman limit; the presence or absence of structure in the UV extinction curve comparable to the visible-wavelength diffuse bands; the scattering properties of grains in new kinds of clouds and nebulae; and the polarization properties of grains in UV wavelengths. The principal advances which may be expected in observations of molecules will include the ability to probe more heavily-obscured regions, where molecular species are more abundant than in the diffuse clouds observed to date; coverage of wavelength regions (such as 1400–3200) not well-studied with previous instruments such asCopernicus; and the capability of observing in optical absorption species detected in the same line of sight in radio emission, which provides unique information on cloud geometry and physical conditions. 相似文献
18.
Charnley S. B. Rodgers S. D. Butner H. M. Ehrenfreund P. 《Earth, Moon, and Planets》2002,90(1-4):349-360
Recent developments in the chemical modelling of cometary comae aredescribed. We discuss the cyanide chemistry and present
new HCNobservations of the recent comet C/2002 C1 (Ikeya–Zhang). Theconnection between interstellar and cometary organic molecules
isdiscussed from the perspective of recent theories of interstellargas-grain chemistry. 相似文献
19.
Helen J. Fraser Suzanne E. Bisschop Klaus M. Pontoppidan Alexander G. G. M. Tielens Ewine F. van Dishoeck 《Monthly notices of the Royal Astronomical Society》2005,356(4):1283-1292
A solid-state feature was detected at around 2175 cm−1 towards 30 embedded young stellar objects in spectra obtained using the Infrared Spectrometer and Array Camera at the European Southern Observatory Very Large Telescope. We present results from laboratory studies of CO adsorbed at the surface of zeolite wafers, where absorption bands were detected at 2177 and 2168 cm−1 (corresponding to CO chemisorbed at the zeolite surface) and 2130 cm−1 (corresponding to CO physisorbed at the zeolite surface), providing an excellent match to the observational data. We propose that the main carrier of the 2175-band is CO chemisorbed at bare surfaces of dust grains in the interstellar medium. This result provides the first direct evidence that gas–surface interactions do not have to result in the formation of ice mantles on interstellar dust. The strength of the 2175-band is estimated to be ∼4 × 10−19 cm molecule−1 . The abundance of CO adsorbed at bare grain surfaces ranges from 0.06 to 0.16 relative to H2 O ice, which is, at most, half of the abundance (relative to H2 O ice) of CO residing in H2 O-dominated ice environments. These findings imply that interstellar grains have a large (catalytically active) surface area, providing a refuge for interstellar species. Consequently, the potential exists for heterogeneous chemistry to occur involving CO molecules in unique surface chemistry pathways not currently considered in gas grain models of the interstellar medium. 相似文献
20.
An analysis of the experimental data on nuclear gamma-ray lines from Cen A reveals essential energetic difficulties, associated with the usual interpretation of these lines as a result of interactions of subcosmic rays with interstellar gas; since the necessary instantaneous energy loss rate of the cosmic rays should reach tremendous values of about 1048–1049 ergs s–1. These difficulties are eliminated if the gamma rays are produced in the relativistic non-isothermal plasma near a compact source of activity — such as a massive black hole or a magnetoid (spinar). 相似文献