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1.
The Apollo 16 soils have the largest low energy neutron fluences (up to 1017 n/cm2, E < 0.18eV) yet observed in lunar samples. Variations in the isotopic ratios 158Gd/157Gd and 150Sm/149Sm (up to 1.9% and 2.0% respectively) indicate that the low energy neutron fluence in the Apollo 16 drill stem increases with depth throughout the section sampled. Such a variation implies that accretion has been the dominant regolith “gardening” process at this location. The data may be fit by a model of continuous accretion of pre-irradiated material at a rate of ～70 g/(cm2 · 108yr) or by models involving as few as two slabs of material in which the first slab could have been deposited as long as 109 yr ago.The ratio of the number of neutrons captured per atom by Sm to the number captured per atom by Gd is lower than in previously measured lunar samples, which implies a lower energy neutron spectrum at this site. The variation of this ratio with chemical composition is qualitatively similar to that predicted by Lingenfelter, Canfield and Hampel.Variations are observed in the ratio 152Gd/160Gd which are fluence correlated and probably result from neutron capture by151Eu.  相似文献   

2.
The Gd and Sm isotopic compositions have been measured in the Luna 16, G-2 soil. This sample has the largest low energy neutron fluence ψ = 5.9 × 1016n/cm2 (E < 0.18eV) yet observed in a lunar sample. The ratio of the number of neutrons captured per atom by149Sm to157Gd is 0.76 which is distinct from the value of 0.86 observed at the Apollo 11, 12 and 14 sites. This indicates a softer neutron energy spectrum at the Sea of Plenty.  相似文献   

3.
Mariana Trough basalt (MTB) glasses from zones of of active seafloor volcanism have incompatible trace element compositions which are intermediate between normal MORB and basaltic rocks from the active northern Mariana Island Arc (MIAB). The chemical variation is observed in trace elemental abundances and ratios such as LIL/LIL and LIL/HFS. MTB glasses with high LIL/HFS and Ba/Sm ratios, and low K/Rb, K/Ba, and Sm/Nd ratios have more enriched Sr and Nd isotopic compositions.Comparison of the SrNd isotopic compositions of MTB and MIAB suggests that the source region within the mantle wedge is heterogeneous. The diverse trace element and isotopic compositions of MTB glasses both within and between dredge sites near 18°N imply small-scale source heterogeneity. Correlation between Sm/Nd and143Nd/144Nd of the MTB glasses is interpreted as due to recent binary mixing, rather than closed system evolution of a common homogeneous source. Mixing of melts at or near the source region between a mantle component with long-term LREE and LIL element depletion (MORB-like) and a relatively enriched component with lower integrated143Nd/144Nd (Arc-like) is suggested by trends of the MTB data on ratio-ratio, ratio-element and element-element plots.  相似文献   

4.
Sm-Nd isotopic evolution of chondrites   总被引：8，自引：0，他引：8  
The143Nd/144Nd and147Sm/144Nd ratios have been measured in five chondrites and the Juvinas achondrite. The range in143Nd/144Nd for the analyzed meteorite samples is 5.3 ε-units (0.511673–0.511944) normalized to150Nd/142Nd= 0.2096. This is correlated with the variation of 4.2% in147Sm/144Nd (0.1920–0.2000). Much of this spread is due to small-scale heterogeneities in the chondrites and does not appear to reflect the large-scale volumetric averages. It is shown that none of the samples deviate more than 0.5 ε-units from a 4.6-AE reference isochron and define an initial143Nd/144Nd ratio at 4.6 AE of0.505828 ± 9. Insofar as there is a range of values of147Sm/144Nd there is no unique way of picking solar or average chondritic values. From these data we have selected a new set of self-consistent present-day reference values for CHUR (“chondritic uniform reservoir”) of (143Nd/144Nd)CHUR0 = 0.511836and(147Sm/144Nd)CHUR0 = 0.1967. The new147Sm/144Nd value is 1.6% higher than the previous value assigned to CHUR using the Juvinas data of Lugmair. This will cause a small but significant change in the CHUR evolution curve. Some terrestrial samples of Archean age show clear deviations from the new CHUR curve. If the CHUR curve is representative of undifferentiated mantle then it demonstrates that depleted sources were also tapped early in the Archean. Such a depleted layer may represent the early evolution of the source of present-day mid-ocean ridge basalts. There exists a variety of discrepancies with most earlier meteorite data which includes determination of all Nd isotopes and Sm/Nd ratios. These discrepancies require clarification in order to permit reliable interlaboratory comparisons. The new CHUR curve implies substantial changes in model ages for lunar rocks and thus also in the interpretation of early lunar chronology.  相似文献   

5.
High-precision Nb, Ta, Zr, Hf, Sm, Nd and Lu concentration data of depleted mantle rocks from the Balmuccia peridotite complex (Ivrea Zone, Italian Alps) were determined by isotope dilution using multiple collector inductively coupled plasma mass spectrometry (MC-ICPMS) and thermal ionisation mass spectrometry (TIMS). The Zr/Hf ratios of all investigated samples from the Balmuccia peridotite complex are significantly lower than the chondritic value of 34.2, and the most depleted samples have Zr/Hf ratios as low as 10. Correlated Zr/Hf ratios and Zr abundances of the lherzolites preserve the trend of a mantle residue that has been depleted by fractional melting. This trend confirms experimental studies that predict Hf to behave more compatibly than Zr during mantle melting. Experimentally determined partition coefficients imply that the major Zr and Hf depletion most likely occurred in the spinel stability field, with (DZr/DHf)cpx≈0.5, and not in the garnet stability field, where (DZr/DHf)grt is probably close to one. However, minor amounts of melting must have also occurred in a garnet facies mantle, as indicated by low Sm/Lu ratios in the Balmuccia peridotites. The Nb/Ta ratios of most lherzolites are subchondritic and vary only from 7 to 10, with the exception of three samples that have higher Nb/Ta ratios (18–24). The overall low Nb/Ta ratios of most depleted mantle rocks confirm a higher compatibility of Ta in the mantle. The uniform Nb/Ta ratios in most samples imply that even in ‘depleted’ mantle domains the budget of the highly incompatible Nb and Ta is controlled by enrichment processes. Such a model is supported by the positive correlation of Zr/Nb with the Zr concentration. However, the overall enrichment was weak and did barely affect the moderately incompatible elements Zr and Hf. The new constraints from the partitioning behaviour of Zr–Hf and Nb–Ta provide important insights into processes that formed the Earth’s major silicate reservoirs. The correlation of Zr/Hf and Sm/Nd in depleted MORB can be assigned to previous melting events in the MORB source. However, such trends were unlikely produced during continental crust formation processes, where Sm/Nd and Zr/Hf are decoupled. The different fractionation behaviour of Zr/Hf and Sm/Nd in the depleted mantle (correlated) and the crust (decoupled) indicates that crustal growth by a simple partial melting process in the mantle has little effect on the mass budget of LREE and HFSE between crust and mantle. A more complex source composition, similar to that of modern subduction rocks, is needed to fractionate the LREE, but not Zr/Hf and the HREE.  相似文献   

6.
Lower Proterozoic sapphirine-bearing and associated granulites from Central Australia exhibit the greatest range of present-day143Nd/144Nd ratios (∈Nd(O)= ?26.5 to +112.3) yet reported for rocks believed to be cogenetic. The Nd isotopic data and REE abundances of these rocks demonstrate extreme fractionation of the rare earths during the formation of stratiform CuPbZn sulfide deposits with which they are closely associated. Field relationships, petrography and chemistry of the sapphirine granulites suggest that their protoliths comprised chlorite-rich rocks which were generated by hydrothermal alteration of a range of rock types prior to metamorphism; calculations employing REE abundances of the sapphirine granulites and associated rocks, combined with bulk solid-fluid distribution coefficient data yield high fluid/rock ratios, consistent with a pre-metamorphic hydrothermal origin for the unusual REE patterns. The SmNd data for these rocks define an age of 1760±75Ma, which is significantly younger than the crust formation age of the terrain ( 2070±125Ma) but indistinguishable from the RbSr whole rock age for granulite facies metamorphism (1790±35Ma). These data are interpreted in terms of major hydrothermal fractionation of the rare earths shortly (perhaps tens of millions of years) before granulite facies metamorphism, followed by redistribution of Nd isotopes or small fractionations of the Sm/Nd ratio during the granulite facies event, and possibly also during intense retrogression which reset RbSr whole rock and UPb zircon and monazite systematics at about 1700 Ma.  相似文献   

7.
Post-glacial tholeiitic basalts from the western Reykjanes Peninsula range from picrite basalts (oldest) to olivine tholeiites to tholeiites (youngest). In this sequence there are large systematic variations in rare earth element (REE) abundances (La/Sm normalized to chondrites ranges from 0.33 in the picrite basalts to 1.25 in the fissure tholeiites) and corresponding variations in 143Nd/144Nd (0.51317 in the picrite basalts to 0.51299 in the fissure tholeiites). The large viaration in 143Nd/144Nd, more than one-third the total range observed in most ocean islands and mid-ocean ridge basalts (MORB), is accompanied by only a small variation in 87Sr/86Sr (0.7031–0.7032). These 87Sr/86Sr ratios are within the range of other Icelandic tholeiites, and distinct from those of MORB.We conclude that the mantle beneath the Reykjanes Peninsula is heterogeneous with respect to relative REE abundances and 143Nd/144Nd ratios. On a time-averaged basis all parts of this mantle show evidence of relative depletion in light REE. Though parts of this mantle have REE abundances and Nd isotope ratios similar to the mantle source of “normal” MORB, 87Sr/86Sr is distinctly higher. Unlike previous studies we find no evidence for chondritic relative REE abundances in the mantle beneath the Reykjanes Peninsula; in fact, the data require significant chemical heterogeneity in the hypothesized mantle plume beneath Iceland, as well as lateral mantle heterogeneity from the Reykjanes Ridge to the Reykjanes Peninsula. The compositional range of the Reykjanes Peninsula basalts is consistent with mixing of magmas produced by different degrees of melting in different parts of the heterogeneous mantle source beneath the Reykjanes Peninsula.  相似文献   

8.
143Nd/144Nd ratios, and Sm and Nd abundances, are reported for particulates from major and minor rivers of the Earth, continental sediments, and aeolian dusts collected over the Atlantic, Pacific, and Indian Oceans. Overall, Sm/Nd ratios and Nd isotopic compositions in contemporary continental erosion products vary within the small ranges of 147Sm/144Nd= 0.115 ± 0.01 and143Nd/144Nd= 0.51204 ± 0.0002 (εNd = −11.4 ± 4). The average period of residence in the continental crust is estimated to be1.70 ± 0.35Ga.

These results combined with data from the literature have implications for the age, history, and composition of the sedimentary mass and the continental crust: (1) The average “crustal residence age” of the whole sedimentary mass is about 1.9 Ga. (2) The range of Nd isotope compositions in the continent derived particulate input to the oceans is the same as Atlantic sediments and seawater, but lower than those of the Pacific, demonstrating the importance of Pacific volcanism to Pacific Nd chemistry. (3) The average ratio of Sm/Nd is about 0.19 in the upper continental crust, and has remained so since the early Archean. This precludes the likelihood of major mafic to felsic or felsic to mafic trends in the overall composition of the upper continental crust through Earth history. (4) Sediments appear to be formed primarily by erosion of continental crust having similar Sm/Nd ratios, rather than by mixing of mafic and felsic compositions. (5) The average ratio of 143Nd/144Nd≈ 0.5117 (εNd ≈ −17) in the upper continental crust, assuming its mean age is about 2 Ga. (6) The uniformity of the SmNd isotopic systematics in river and aeolian particulates primarily reflects efficient recycling of old sediment by sedimentary processes on a short time scale compared to the amount of time the material has resided in the crust.  相似文献   


9.
New Hf isotope and trace element data on mid-ocean ridge basalts (MORB) from the Pacific Ocean basin are remarkably uniform (176Hf/177Hf≈0.28313–0.28326) and comparable to previously published data [Salters, Earth Planet. Sci. Lett. 141 (1996) 109–123; Patchett, Lithos 16 (1983) 47–51]. Atlantic MORB have 176Hf/177Hf ranging from 0.28302 to 0.28335 confirming the wide range originally identified by Patchett and Tatsumoto [Geophys. Res. Lett. 7 (1980) 1077–1080]. Indian MORB define an even wider range, from 0.28277 to 0.28337, but three exotic samples have very unradiogenic Hf isotope compositions. Their very low 176Hf/177Hf ratios, together with their trace element characteristics, require the presence of unusual plume-type material beneath the Indian ridge. All other Indian MORB have uniform Hf isotope compositions at about 0.2832, and define a small field displaced to the right of other MORB in Hf–Nd isotope space. The distinct nature of Indian MORB is best explained by the presence in Indian depleted mantle of old recycled oceanic crust and pelagic sediments. Sm/Hf ratios calculated from new high-precision rare earth element and Hf trace element data do not vary in MORB in the same way as in ocean island basalts (OIB): ratios are constant in OIB, but decrease with increasing Sm contents in MORB. The constancy of Sm/Hf in OIB is probably due to an overwhelming influence of residual garnet during melting. By contrast, the decrease of Sm/Hf in MORB is due to the effect of clinopyroxene in the residue of melting beneath ridges, an interpretation confirmed by quantitative modeling of melting. The relationship between Sm/Nd and Lu/Hf ratios in MORB does not require the presence of garnet in the residual mineralogy. The decoupling of Lu/Hf ratios and Hf isotope compositions – the so-called Hf paradox [Salters and Hart, EOS Trans. Am. Geophys. Union 70 (1989) 510] – can be explained by melting dominantly in the spinel field at shallow depths beneath mid-ocean ridges.  相似文献   

10.
This paper reports Re-Os and Nd isotopes of black shales at the bottom of Lower Cambrian from the northern Tarim Basin and traces source materials of the black shales through isotopes. The average Re/Os, 187Re/188Os, and 187Os/188Os ratios of the black shales at the bottom of Lower Cambrian from the Tarim Basin are 7.18, 5.6438, and 1.9616, respectively. These isotopic ratios suggest the crustal sources of the black shales. The εNd(0) value is -13.17, the εNd(540 Ma) value is -7.32 and the Nd model ages are 1.535 Ga. These parameters in the black shales are quite consistent with those from the basement rocks. Based on the Re-Os and Nd isotopic characteristics of the black shales, we conclude that the continental crust mainly composed of basement rocks is the source material of the black shales. Through comparison of these isotopic parameters with those from the Yangtze Platform, it is clear that the Re-Os isotopic characteristics in the black shales from the Tarim and Yangtze platforms are quite different, which maybe indicates the differences in depositional settings between two platforms. These Re-Os isotopic data provide us with constraints to analyze the genetic relation between the two platforms.  相似文献   

11.
There exists extensive basic-acidic volcanic rock series in the middle section of the Okinawa Trough. Different types of these volcanic rocks have their own average strontium ratios of 0.704 749, 0.705 062, 0.708 771, 0.704 840 and 0.720 301 with average143Nd/144Nd ratios of 0.512 820, 0.512 673, 0.512 413, 0.512 729 and 0.512 034. These ratios of Sr and Nd isotopes all fall on a theoretic hyperbolic curve of mixing between two end-members of MORB and rhyolitic magma. So we infer that these different kinds of volcanic rocks in the middle Okinawa Trough are the erupted product in different stages of formation and evolution of the trough crust. MORB magma, which had suffered assimilation, mixed with the early-formed crust-derived rhyolitic partial melt mass at different ratios; then, these mixed magma erupted and formed volcanic rock types of the trough. This study indicates that the Okinawa Trough is coming into a stage of submarine spreading from the stage of continental rift.  相似文献   

12.
We have studied SmNd systematics in pyroxene and phosphate mineral separates of Angra dos Reis. A pyroxene-phosphate internal isochron age ofT2 = 4.55 ± 0.04AE is obtained, in excellent agreement with reported Pb-Pb ages.142Nd/144Nd ratios in pyroxene samples are systematically larger than those in phosphates by 6 parts in 105. This variation is tentatively assigned to a radiogenic contribution from extinct146Sm. Fission xenon components in pyroxene and phosphate separates are characterized by discrete ratios of fission/spallation and evidence is presented for a third ratio in celsian. It is shown that this characteristic is due to a close association of244Pu with the light REE. Computed ratios244Pu/Nd are the same in pyroxene and phosphate separates, but244Pu/238U and244Pu/232Th ratios are not. Taking the fission xenon retention age to be 4.55 AE, we obtain an abundance ratio244Pu/Nd= 1.5 × 10?4 (or an atomic ratio244Pu/150Nd= 1.6 × 10?3) at this time and in the region of the solar system where the Angra dos Reis parent body formed. The exposure age of Angra dos Reis, as obtained by the81Kr-83Kr method is55.5 ± 1.2m.y. Neutron capture during the 55.5-m.y. exposure to cosmic rays increased the ratio150Sm/149Sm in Angra dos Reis by 6 parts in 104.  相似文献   

13.
Measurements of143Nd/144Nd and147Sm/144Nd are reported for whole rocks and mineral separates from granulites of the Napier Complex at Fyfe Hills. Charnockites, leuconorites and gabbros yield a whole rock SmNd isochron age of3060 ± 160m.y. and an initial143Nd/144Nd ratio of0.50776 ± 10 (?Nd(3060m.y.) = ?2.0 ± 1.8). The negative ?Nd value and the presence of geologically induced dispersion in the data suggest that the isochron age does not represent the time of primary crystallization of the complex but instead indicates a time of later redistribution of Sm and Nd and partial re-equilibration of143Nd/144Nd ratios. This probably occurred during the upper granulite facies metamorphism which has also been dated at～ 3100m.y. by RbSr and UPb zircon studies [1]. Coexisting clinopyroxene, apatite and total rock fractions in two adjacent samples define an approximately linear array corresponding to an age of 2300 ± 300 m.y. This array indicates that redistribution of Sm and Nd and re-equilibration of143Nd/144Nd ratios occurred on an intermineral scale during the upper amphibolite to lower granulite facies metamorphism at～ 2450m.y.Due to the resetting of the SmNd system on both whole rock and mineral scales, the primary crystallization age of the igneous protolith is not well constrained by the present data, although it is clearly3100m.y. If it is assumed that the complex was derived initially from a depleted mantle reservoir(?Nd(T) ? 2), evolution of the negative ?Nd value of ?2.0 with the observed Sm/Nd ratios requires a prehistory of～ 380m.y. This implies a primary age of～ 3480m.y. However, substantially older primary ages can be inferred if the source reservoirs had?Nd(T) > 2 and/or substantial reductions in the Sm/Nd ratio occurred in whole rocks during the granulite facies metamorphism at 3100 m.y. Such an inferred reduction in the Sm/Nd ratio may have been the result of preferential loss of Sm relative to Nd, or introduction of a low Sm/Nd fluid with?Nd ≥ 0 during granulite facies metamorphism.  相似文献   

14.
Sm-Nd data for ten greenstone belt volcanics from Rhodesia define an age of2.64 ± 0.14AE, which is in agreement with other geochronological data and with observed field relationships. This age and the initial143Nd/144Nd ratio of0.50919 ± 0.00018 yield a time-integrated Sm/Nd ratio of0.302 ± 0.009 in the mantle source region, similar to that in chondrites. Sm/Nd ratios of some lavas are0.31 and imply that a small fraction of their source was removed prior to or as part of the main melting event.The utility of the Sm-Nd system for dating altered Archaean volcanic rocks is amply demonstrated by these data.  相似文献   

15.
Pb, Nd and Sr isotope compositions of oceanic basalts have been used to identify recycled components of continent derivation in the mantle. The isotopic compositions of Sr, Nd and Pb, together with U, Pb, Sm, Nd, Rb, and Sr abundances have been determined for back-arc basalt glasses from the Scotia Sea and Parece Vela and West Philippine Basins, in addition to basalts from South Sandwich Islands, Ascension, St. Helena and Tristan da Cunha. Comparisons made between the isotopic compositions of South Sandwich Islands basalts and Atlantic MORB glasses permit the identification of recycled components of continent derivation in the source of the island arc basalts. Recycled Sr of continent derivation is also recognisable in back-arc basalt glasses from the Scotia Sea and Parece Vela and West Philippine Basins. However, contemporary reinjection of material with the isotopic structures similar to those identified as a component of island arc and back-arc regions cannot be the sole or dominant influence on the fine structure observed in MORB glasses from the Atlantic Ocean, nor the isotopic compositions of Tristan da Cunha, St. Helena and Ascension basalts. Recycled materials are likely to have been responsible for the generation of these heterogeneities only if they have been stored in the mantle for periods of time exceeding 109 years.  相似文献   

16.
Alkaline magmatism in the Southern Highlands Province, New South Wales, Australia is associated with continental rifting. Near-primary liquids have a wide range in Nd and Sr isotope composition that indicates gross isotopic and chemical heterogeneities in a mantle source region depleted in light rare earth elements (LREE) for much of Earth's history. The large-ion lithophile element and LREE-enriched nature of the primary lavas ((Ce)N = 95–182 and (Yb)N = 8.5–13.3) is consistent with an enriched mantle source region. This elemental enrichment may be accomplished by veining of the subcontinental mantle with volatile-rich phases like amphibole, apatite and carbonate which provide the volatile flux necessary to trigger anatexis.Degassing of mantle CO2 has led to migration of LREE-enriched fluids and local transformation of the lherzolitic mantle to pyroxenite veined by apatite ± kaersutite ± mica ± diopside. The mantle veining event may be related to upwelling of silica-undersaturated incompatible element-enriched magmas similar to the host magma of the Kiama xenoliths. In a relatively short period of time (100 m.y.), the Sr and Nd isotopes in essentially LREE-depleted mantle have evolved in response to low Sm/Nd and low Rb/Sr ratios, and now define a near-vertical vector on a isotope-isotope plot. From this rather unique signature we can infer that CO2- and LREE-rich, Rb-poor mantle is a potentially suitable mantle source region for the genesis of alkali-potassic volcanic rocks characterized by a narrow range in87Sr/86Sr ratio and a wide range in143Nd/144Nd ratio (e.g. Leucite Hills).  相似文献   

17.
Isotopic dilution technique and mass spectrometry are used in order to measure isotopic compositions and concentrations of some particular elements on the Oklo sample KN50-3548, which are interesting for describing the nuclear reaction. These analyses give coherent results leading to the determination of the following parameters: neutron fluence, spectrum index, total number of fissions relative to uranium, and percentage of238U and239Pu fissions. From the percentage of plutonium fissions, the duration of the nuclear reaction is estimated to be 800,000 years. The age of the nuclear reaction is measured from the lead analysis and from the number of uranium fissions; these two determinations give respectivelyd = 1730 ± 10m.y. andd = 2000 ± 100m.y. The second method, based on the assumption that uranium and rare earths have not migrated, could mean that the nuclear reaction might be older than the Francevillian. It is also shown that no contamination by natural elements has occurred for lead, rare earths, palladium and rare gases, after the reaction.  相似文献   

18.
Osmium, strontium, neodymium, and lead isotopic data have been obtained for 30 hand picked samples of basaltic glass from the Pacific, Atlantic and Indian mid-oceanic ridges. Large variations in Os isotopic ratios exist in the glasses, from abyssal peridotite-like values to radiogenic compositions similar to oceanic island basalts (187Os/186Os and 187Os/188Os ratios range from 1.06 to 1.36 and from 0.128 to 0.163, respectively). Os isotopic and elemental data suggest the existence of mixing correlations. This relationship might be ascribed to secondary contamination processes; however, such a hypothesis cannot account for the negative correlation observed between Os and Nd isotopes and the existence of complementary covariations between Os and SrPb isotopes. In this case, OsSrNdPb isotopic variations are unrelated to late post-eruption or shallow level contamination. These relationships provide strong evidence that the Os isotopic composition of the samples are derived from the mantle and thus implies a global chemical heterogeneity of the oceanic upper mantle. The results are consistent with the presence of recycled oceanic crust in the mantle sources of mid-ocean ridge basalts, and indicate that the unique composition of the upper mantle below the Indian ocean results from its contamination by a mantle component characterized by radiogenic Os and particularly unradiogenic Nd and Pb isotopic compositions.  相似文献   

19.
87Sr/86Sr and143Nd/144Nd ratios, REE and selected minor and trace elements are presented and compared for present-day volcanic rocks in the Scotia Sea.Tholeiitic basalts from the South Sandwich Islands show widely ranging contents of some lithophile elements, e.g. K2O (0.09–0.55%) and Rb (1.55–14.2 ppm), but fairly constant Na2O and Sr. Total REE contents range from about 4–20 times chondritic abundances with significant light-REE depletion and both positive and negative Eu anomalies. The variations in minor and trace element abundances are consistent with low-pressure fractional crystallization of plagioclase and clinopyroxene but only minor amounts of olivine. The87Sr/86Sr and143Nd/144Nd ratios of the parental magmas are thought be 0.7038–0.7039 and 0.51301–0.51314 respectively, and indicate derivation of at least some87Sr from subducted ocean crust.The back-arc tholeiites in the Scotia Sea have lower87Sr/86Sr ratios (0.7028–0.7033), similar143Nd/144Nd ratios (0.51305) and are variably light-REE-enriched(CeN/YbN= 1.0–1.6). Total REE contents are comparable to those of the South Sandwich Islands tholeiites.  相似文献   

20.
We determined the Nd isotopic composition and the Sm/Nd ratios in a series of Australian shales ranging from 0.2 Gy to 3.3 Gy. The first result of this study is the constancy of the Sm/Nd ratio in these shales, as in granitoids. Secondly, the initial (143Nd/144Nd) ratio gives a regular curve decreasing through geological time. Both results confirm that shales are representative samples of the continental crust, when insoluble elements, like REE, are studied.We calculated their Nd model ages of crustal differentiation. The model ages regularly decrease with the stratigraphic ages and after 2 Gy, the curve flattens and tends to an asymptotic value at around 1.8 Gy. The significance of the shales is that they represent a mixture of continental materials and we consider the model age of such a mixture directly linked with the mean age of the continental portion feeding the sedimentary basin.From these results, we deduce a quantitative model of the growth curve of the continental source of the shales taking into account the effects of erosion which selectively sample recent mountains relative to shield areas. We propose that the results obtained here are representative of the whole Gondwana continent.Having studied the case of the Australian shales, we try to extend our study. First we applied our quantitative approach to the recent results obtained by O'Nions et al. on North Atlantic provinces. The continental growth curves obtained by our inversion procedure are quite distinct from the Australian shales showing the regional character of shales.With these two cases studied we try to compare our results with the already developed model for continental growth. The consideration of the surface conservative versus surface non-conservative models clearly show the non-uniqueness of the geological interpretation of the growth curve. On the other hand, we have calculated for each case the recycling rate versus geological time by comparing the growth curve with the Hurley-Rand province age curve. Such recycling increases with time in agreement with the data obtained on Nd and Sr initial ratios on granitoids.  相似文献   

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