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1.
The groundwater discharge zone of central Australia is marked by a chain of playas extending 500 km from Lake Hopkins in Western Australia through Lake Neale, Lake Amadeus and numerous smaller playas to the Finke River in the Northern Territory. This great valley is devoid of surface drainage, and the playas and their associated landforms and chemical sediments are a result of groundwater transmission, and discharge from a large regional flow system. The valley contains extensive groundwater calcrete deposits, which are commonly silicified. The playas contain gypsum and glauberite deposits resulting from the evaporative concentration of discharging groundwater to 250 g/1total dissolved solids. Thin gypcrete crusts have developed on the playa margins and islands as a result of induration of bordering gypsum dunes. Diagenetic changes in the calcrete and gypcrete are caused by dissolution and reprecipitation through groundwater movement.

Calcrete and gypcrete samples from playas near Curtin Springs, NT, dated by electron spin resonance (ESR) — calibrated by 14C dates on calcrete and the uranium content of gypcrete — are mostly in the range 8000–16 000 years BP, and are evidence of groundwater discharge conditions similar to those of the present day. Calcrete in the vadose zone, above the present water‐table, gives ESR dates in the range 22 000–27 000 years BP suggesting episodes of high intensity rainfall at that time. Phreatic calcrete, below the water‐table, with ages in the range 34 000–75 000 years BP, provides evidence of older episodes of calcretization.

The ESR and 14C dates for the chemical sediments suggest that this groundwater flow system has been an important feature in the region for much of the Late Quaternary. Although there are problems with the interpretation of ESR dating for chemical sediments with diagenetic alteration, the technique shows promise as a dating tool.  相似文献   

2.
Calcite-rich soils (calcrete) in alluvium and colluvium at Solitario Wash, Crater Flat, Nevada, USA, contain pedogenic calcite and opaline silica similar to soils present elsewhere in the semi-arid southwestern United States. Nevertheless, a ground-water discharge origin for the Solitario Wash soil deposits was proposed in a series of publications proposing elevation-dependent variations of carbon and oxygen isotopes in calcrete samples. Discharge of ground water in the past would raise the possibility of future flooding in the unsaturated zone at Yucca Mountain, Nevada, site of a proposed high-level nuclear waste repository. New geochemical and carbon, oxygen, strontium, and uranium-series isotopic data disprove the presence of systematic elevation-isotopic composition relations, which are the main justification given for a proposed ground-water discharge origin of the calcrete deposits at Solitario Wash. Values of δ13C (−4.1 to −7.8 per mil [‰]), δ18O (23.8–17.2‰), 87Sr/86Sr (0.71270–0.71146), and initial 234U/238U activity ratios of about 1.6 in the new calcrete samples are within ranges previously observed in pedogenic carbonate deposits at Yucca Mountain and are incompatible with a ground-water origin for the calcrete. Variations in carbon and oxygen isotopes in Solitario Wash calcrete likely are caused by pedogenic deposition from meteoric water under varying Quaternary climatic conditions over hundreds of thousands of years.  相似文献   

3.
从已获资料分析出我国西北地区含铀钙结岩(膏结岩)主要发育在古盐湖中。它是由膏结泥岩、膏结砾岩、膏结砂岩等组成。含铀层数多,工业矿化只在近地表一层或两层,含铀矿物主要是硅钙铀矿、钒钙铀矿、钒钾铀矿等。以西北区域地质特征及古气候条件为依据,结合区调、普查,勘探成果进行综合对比,编出了钙(膏)结岩分布略图,并认为钙(膏)结岩型铀矿化是西北地区值得探索的一种新类型。  相似文献   

4.
Diagenetic alunite occurs with calcrete, gypcrete and silcrete deposits in a Mio-Pleistocene clastic sequence at several locations in southern Kuwait, Arabian Gulf. Based on their physical properties and textural characteristics the alunite deposits were divided into (1) chalky quartzitic alunite, (2) chalky quartz-free alunite, (3) hard pink alunitic sandstone. The chalky alunite is composed mainly of hydronium-alunite (H3O)Al3(SO4)2(OH)6, while the hard pink alunite is composed solely of well developed potassium alunite KAl3(SO4)2(OH)6. These minerals resulted from the action of sulphuric acid on clays and K-feldspars in the muddy sandstone and mudstone host sediments. The sulphuric acid is most probably produced by the oxidation of hydrogen sulphide that might have seeped in from the oil fields of this area. Four diagenetic stages are suggested for the genesis of the studied alunites: gypsification, sulphuratization, silicification and alunitization. In oil field areas, the occurrences of alunite would serve as an indicator for the presence at depth of hydrocarbons.  相似文献   

5.
Radiocarbon and thermoluminescence (TL) age-determinations have been obtained for a large Pleistocene alluvial terrace on the Nepean River near Sydney, New South Wales, Australia. The deposit was laid down by a braided river system prior to the last glacial maximum. Six thoroughly pretreated samples of charcoal and degraded wood buried within gravels at the base of the terrace yielded apparent 14C ages of 37,000–42,000 yr B.P. These compare favorably with four TL determinations that gave apparent ages of 41,000–47,000 yr B.P. for the same deposit. Adjustment of the 14C ages to take geomagnetic effects into account further improves the correlation between these two independent dating techniques. In addition, 14C and TL correctly identified a reworked portion of the fine-grained alluvial overburden as being substantially younger than the main body of the terrace. These results augur well for the usefulness of TL age determinations of certain alluvial deposits.  相似文献   

6.
The chronostratigraphy of mostly Holocene sediments in the Northern Negev desert of Israel was studied through amino acid epimerization analysis (alloisoleucine/isoleucine ratio, A/I) of individual land snail shells and 14C analysis of bulk samples of land snail shells contained within the sediments. Analysis of 31 deposits shows a very strong correlation between A/I and 14C age. A/I analyses indicate that age mixtures occur within all colluvial and in some fluvial deposits. Consequently, radiocarbon dates of bulk samples, which give an average age, overestimate the time of deposition. Sedimentation rates were generally rapid in both fluvial and colluvial deposits. Colluviation shows a maximum in the early Holocene and decreases progressively thereafter, in accordance with the change in average rainfall. Accumulation of fluvial sediments shows a distinct mid-Holocene maximum and apparently relates to the interaction between variation in rainfall, extent of bedrock exposure, and vegetation density. Late Holocene fluvial deposition may relate to agricultural activity. The understanding of the chronology of sedimentation is dependent on an integrated approach employing amino acid epimerization analysis to study age variation within a layer and 14C analyses for establishment of an absolute chronology.  相似文献   

7.
Anomalously high Au concentrations (2.5 to 50 ppb) in regolith carbonate accumulations, such as calcrete and calcareous sands in aeolian sand dunes overlying Au mineralisation of the Gawler Craton, South Australia, show a marked covariance of Au with K, Mg and most notably Ca. This relationship appears to be linked to the authigenic formation of smectites and carbonates within the aeolian dunes in the region. However, little is known about the processes involved in the formation of carbonates under semi-arid and arid conditions. In this study the geochemical properties of aeolian dunes along several depth profiles of 2 to 4 m are investigated in order to assess the relationship between Au mobility and calcrete formation. In the profiles a strongly systematic relationship between Au and the increasing Ca–Mg contents at depth highlights the close association between the enrichment of Au in the calcrete and the underlying hydrothermal mineralisation. Intense calcrete formation and concurrent Au enrichment also occurs in the vicinity of roots penetrating the dune. Thin section petrography and cathodoluminescence show that most of the calcrete in the regolith profiles is micritic; some sparic crystallites have also been identified. To demonstrate the presence of microbial processes that may mediate the formation of calcrete, samples from a depth profile in the dune were taken under sterile conditions. After amendment with urea and incubation of up to 24 h, up to 18 mg/l of NH4+ were detected in near surface samples. At depth of 2.3 m 1 mg/l NH4+ were detected compared to a control that contained below 0.05 mg/l NH4+. These results suggest that the genesis of calcrete and pedogenic carbonate in the area may be partly biologically mediated via processes such as the metabolic breakdown of urea by resident microbiota which generates a pH and pCO2 environment conducive to the precipitation of carbonate. In the process of urea breakdown organic Au complexes such as Au-amino acid complexes may become destabilised in solution and Au may be co-precipitated, resulting in the fine, non-particulate distribution of Au throughout the micritic calcrete carbonate. In conclusion, this study suggests a coupled mechanism of biologically mediated and inorganic mechanisms that lead to the formation of Au-in-calcrete anomalies.  相似文献   

8.
Both aquatic and land snails are common in the geologic record, but their utility in dating is greatly restricted by their well-documented tendency to yield14C dates inconsistent with true14C ages. In this study, we examine the use of14C ages from (1) small, previously unstudied, terrestrial snails to date hosting spring deposits and from (2) cooccuring aquatic snails to constrain groundwater travel times during the last glacial period. Our study area in the southern Great Basin encompasses Yucca Mountain, site of the proposed high-level nuclear waste repository, where information on the age and extent of past high water tables and on groundwater flow times is crucial to several licensing issues. Our results show that shells of small terrestrial snails belonging toValloniasp. yield14C dates consistent with14C ages of associated carbonized wood. These results imply that these taxa can provide reliable14C age control on the broadly distributed deposits in which they have been described. In contrast, cooccurring aquatic snails from fossil spring deposits yield14C ages generally greater than the control age. This is because the aquatic shells often formed in spring waters that had an initial14C deficiency. However, the magnitude of the deficiency is much less than that observed in nearby modern springs, arguing for much higher average14C contents in late Pleistocene groundwaters in these basins. If representative, this implies shorter groundwater travel times through aquifers in southern Nevada during late-glacial time.  相似文献   

9.
Trace elements together with some O and C isotope analysis were undertaken on duricrust strandline deposits in the palaeo-Makgadikgadi sub-basin (PMSB) to provide insight into palaeo-climatic conditions through the interpretation of calcrete, silcrete–calcrete intergrade and silcrete deposits. Trace element content and relative abundance suggest that the duricrust origins are associated with the long-term weathering of the Karoo Large Igneous Province which underlies the PMSB. This work shows that duricrust origins are related to Ca2+ and Si (and associated trace elements) being transported mainly through the groundwater and then subsequently precipitated at different strandline elevations over time. Local groundwater feeding in towards the pan margin and accumulating in near-neutral pan-marginal pools, appears to facilitate Si concentration and permeation of pre-existing calcretes. The silica precipitates as the pH drops when renewed freshwater enters the pools. Hence the inferred palaeo-climatic regime for silcretisation may be similar to that occurring in Botswana at present being dry semi-arid with low seasonal rainfall. In contrast the extensive calcrete precipitation in the strandlines results from abundant Ca2+ in adjacent waters which appear to be derived from both local and regional sources. The arrival of Ca2+ from regional sources (shown by trace element evidence) infers heavy rainfall in the upper catchment suggesting a major humid event followed by regional drying. Palaeo-climatic inferences suggest the juxtaposition of major humid events interspersed with more normal semi-arid palaeo-climates with an exception obtained from isotope data, of drier and cooler conditions than usual for the region around 80–90 000 years ago. Whereas trace element data can greatly assist in the interpretation of complex deposits such as duricrusts, care should be taken over the use of particular ratios (such as Yb/Gd ratio) which may produce spurious results.  相似文献   

10.
Marine reservoir age is reported for Foxe Basin, Canada, during deglaciation of the Laurentide Ice Sheet. Radiocarbon (14C) measurements were made on pairs of contemporaneous molluscs and Salix (willow) macrofossils, yielding a mean marine reservoir age of 985 ± 10 14C a. Mean regional ΔR is calculated to be 615 ± 20 14C a relative to a mean global reservoir age of ca. 400 14C a. Previous studies in the Canadian Arctic that have been conducted on modern pre‐bomb molluscs give ΔR values of ca. 100–300 14C a. The difference between modern and deglacial reservoir ages indicates that ΔR in Foxe Basin has changed over time, which has implications for the reconstruction of past events based on marine 14C dates. We recalculate the timing of deglaciation of Hudson Strait with this new reservoir age and relate this to the 8.2 cal. ka event. We recommend that local ΔR be determined for the time period being examined whenever possible, and that in cases where this is impossible a ΔR value of 615 14C a be applied when calibrating marine samples from Foxe Basin and vicinity during deglaciation. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

11.
Detailed information on semi‐arid, palustrine carbonate–calcrete lithofacies associations in a sheetwash‐dominated regolith setting is sparse. This is addressed by studying the Lower Limestone of the Lameta Beds, a well‐exposed Maastrichtian regolith in central India. The general vertical lithofacies assemblage for this unit comprises: (a) basal calcareous siltstones and marls with charophytes, ostracods and gastropods; (b) buff micritic limestones associated in their upper parts with calcretized fissure‐fill sandstones; (c) sheetwash as fissure‐fill diamictites and thin pebbly sheets, locally developed over a few metres; and (d) sandy, nodular, brecciated and pisolitic calcretes at the top. The sequence is ‘regressive’, with upsection filling of topographic lows by increased sheetwash. Lateral lithofacies change is marked, but there are no permanent open‐water lake deposits. In topographic lows close to the water table, marshy palustrine or groundwater calcretes formed, whereas on better drained highs, brecciation and calcretization occurred. Prolonged exposure is implied, suggesting that shrinkage was the main cause of brecciation. Evidence for rhizobrecciation and other biological calcrete fabrics is sparse, contrasting with the emphasis on root‐related brecciation in many studies of palustrine lithofacies. Stable isotope (δ18O and δ13C) values are consistent with the palustrine limestones being fed from meteoric‐derived groundwater with a strong input of soil‐zone carbon. There is overlap of both δ18O and δ13C values from the various palustrine and calcrete fabrics co‐occurring at outcrop. This suggests that, in groundwater‐supported wetlands, conversion from palustrine carbonate to calcrete need not show isotopic expression, as the groundwater source and input of soil‐zone carbon are essentially unchanged. Cretaceous–Tertiary δ18O and δ13C values from palustrine lithofacies and associated calcretes appear to be strongly influenced by the inherited values from lakes and wetlands. Hydrologically closed lakes and marine‐influenced water bodies tend to result in low negative palustrine δ18O and δ13C values. During brecciation and calcretization, the degree of isotopic inheritance depends on whether or not alteration occurs in waters that are different from those of the original water body or wetland. Marked biological activity (e.g. rhizobrecciation or root mat development) during calcretization may lower δ13C values where C3 plants are abundant but, in shrinkage‐dominated systems, δ13C values will be largely inherited from the palustrine limestones.  相似文献   

12.
《Quaternary Science Reviews》2003,22(10-13):953-959
The Nußloch loess section in South West Germany is famous in Central Europe for its thick deposits from the Last Glacial Maximum. It has therefore been intensively studied during the past few years and offers an excellent opportunity to compare the performance of different dating techniques covering the period 15–45 ka.Here we present results from optical and AMS 14C dating. The silt-sized polymineral fraction of the clastic sediments and a multiple-aliquot approach was used for IR-OSL dating. 14C dating was carried out on organic macro-remnants and humin fractions extracted from the sediments.With the exception of samples taken from the uppermost 1.5 m of the section, IR-OSL and calibrated 14C-AMS ages are consistent over the entire period. The inconsistencies in the upper meters are thought to be due to disturbances during soil formation in the Holocene. The good agreement obtained on the remaining sequence demonstrates the high accuracy of both methods when studying loess sections: for the IR-OSL ages no significant age underestimations are obvious.The results clearly document that accurate chronologies can be developed for such continental sedimentary sequences. This gives access to archives that can now be studied with a high temporal resolution and allows the establishment of new paleoclimatic proxies for the study of terrestrial responses to past climatic changes.  相似文献   

13.
Nine faunal teeth from layer 20 of El Castillo cave in Cantabrian Spain were dated using electron spin resonance (ESR). Two teeth were rejected due to inconsistent subsample ages, while the remaining teeth yielded a mean age that is consistent with the stratigraphic expectations: 42.7±3.5. Uncertainty in the external γ dose rate results in a potential systematic uncertainty of±6.4ka that should affect all samples equally. The results provide independent confirmation of previously reported 14C ages for layer 20. © 2010 Wiley Periodicals, Inc.  相似文献   

14.
This paper reports the preliminary application of ESR dating to loess strata. The samples were collected from the 7th palaeosol layer (S7) of the Luochuan section, Shaanxi province in China. The ESR age of S7 is 736 ka (total dose 2945 Gy, annual dose 4 mGy/year). This age represents the original eolian accumulation age. The result is consistent with the palaeomagnetic data (730 ka). We have also carried out thermal annealing experiments on quartz grains from the S7 sample. ESR intensities (g = 2.0005) increase from 25°C to 320°C. It may be that trapped electrons transfer into the E′ centre site. ESR intensities decrease from 340°C to 460°C due to thermal annealing. We obtained a mean-life of E′ centre electrons at 20°C of 6.66 × 108 years. The activation energy is 1.35 eV and frequency factor is 3.7 × 108 min−1.  相似文献   

15.
Holocene shore-face and beach-face deposits form plains <5 m above present sea level along Taiwan Strait. We measured the14C ages of detrital mollusk shells and coral in such deposits at the Penghu Islands. Twelve carbonate samples—mainly from the largest island, Makung—were dated. Age measurements for two coral samples and one mollusk sample from the same outcrop imply that the14C ages of mollusk shells give the best approximation of depositional age. The highest Holocene relative sea level in the Penghu Islands occurred about 4700 years ago with a height about 2.4 m above the present sea level. Thereafter, relative sea level appreciably fell without detectable fluctuations to its recent position. Our sea level data are consistent with other studies from the central and western Pacific, except for the timing of peak sea level position. This variation may reflect local crustal response to hydroisostatic effects on the continental shelf.  相似文献   

16.
From the viewpoint of precision and reliability of radioisotopic dating, deposits whose quantitative age can be determined through several methods of geochronometry are of special interest. The mutually conforming finite 14C and 230Th/U dates of buried Neopleistocene organic deposits, taken from the Tolokonka section by the North Dvina River (100 km downstream from the city of Kotlas), have been obtained for the first time in Russia. The stratigraphical reference of these results to those obtained via the optically induced luminescence for upper and lower bedding layers has been established. The presented geochronometric data have allowed us to consider the age of oxbow lake organic deposits completely reliable and refer the time of their formation to the Tyrbei warming within the MIS-3. The applicability of the new version of the 230Th/U method for dating of interglacial and interstadial deposits, for the purpose of solving the Middle and Late Neopleistocene chronostratigraphy issues, is confirmed.  相似文献   

17.
Orissa is an important area for gem variety of corundum deposits in India. Spectroscopic studies, such as ESR, OAS on samples from Sardapur, Orissa, were carried out to ascertain the colour cause of corundum. Electron spin resonance (ESR) spectroscopic study was carried out on the samples to detect the presence of paramagnetic ions i.e. Fe2+, Fe3+, Ti4+, Cr3+ and V3+ etc. The variable temperature experiment carried out to observe the effect of heating on peak valence state change in paramagnetic ions. Samples were cut and polished to obtain the optical absorption spectrum (OAS) to detect the colour causing transition ions/defect centres. The samples of gem variety were step heated up to 300°C for colour enhancement studies. EPMA analysis has revealed the low chromium concentration in the rubies. The varying hues of red in the corundum are due to the presence of bivalent and trivalent iron and charge transfer process along with Cr3+ absorption in the 550 nm region.  相似文献   

18.
The southwestern region of Australia contains the Yilgarn Craton that has been exposed to subaerial weathering since mid-Proterozoic. The gently undulating landscape experienced lateritic weathering so that today variably dissected, deep in situ isovolumetrically weathered regolith is widespread. Imposition of a more arid climate since the Miocene with the cessation of effective external drainage has resulted in substantial geochemical modification of the highly porous regolith. This vast pore volume acts as a reservoir for complex solutions that may be highly saline, extremely acid to alkaline and reducing. Diverse precipitates have formed in the regolith including widespread occurrence of silcrete, calcrete, dolocrete, ferricrete and gypcrete together with localised occurrences of pyrite, alunite, jarosite, barite, halite and other salts. Clearing of bush land for agriculture in the 20th century increased recharge so that rising chemically active groundwaters are damaging farmland and infrastructure throughout the region. To cite this article: B. Gilkes et al., C. R. Geoscience 335 (2003).  相似文献   

19.
Glaciations of the West Coast Range,Tasmania   总被引：1，自引：0，他引：1  
Geomorphic, stratigraphic, palynologic and 14C evidence indicates that the West Coast Range, Tasmania, was glaciated at least three times during the late Cenozoic. The last or Margaret Glaciation commenced after 30,000 yr B.P., culminated about 19,000 yr B.P., and ended by 10,000 yr B.P. During this period a small ice cap, ca. 250 m thick, and cirque and valley glaciers covered 108 km2. The glacial deposits show little chemical weathering or erosional dissection. The snow line ranged from 690 to 1000 m with an average of 830 m for the ice cap. Mean temperature was 6.5°C below the present temperature. During the preceding Henty Glaciation a 300- to 400-m-thick ice cap and outlet glaciers exceeded 1000 km2. The glacial deposits are beyond 14C assay. They are more weathered chemically and more dissected than Margaret age deposits, and the degree suggests a pre-last interglaciation age (> 130,000 yr B.P.). The snow line of the ice cap lay at 740 m, and annual temperature was reduced by 7°C. Ice of the earliest Linda Glaciation slightly exceeded that of the Henty Glaciation but had a similar distribution. The glacial deposits are intensely weathered, have reversed magnetization, and overlie a paleosol containing pollen of Tertiary type. An early Pleistocene or Tertiary age is indicated.  相似文献   

20.
Bark samples isolated from brown coal deposits in Victoria, Australia, and buried wood from Rhizophora mangle have been studies by high-resolution solid-state nuclear magnetic resonance (NMR) techniques. Dipolar dephasing 13C NMR appears to be a useful method of detecting the presence of tannins in geochemical samples including barks, buried woods, peats and leaf litter. It is shown that tannins are selectively preserved in bark during coalification to the brown coal stage.  相似文献   

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