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1.
It is shown that peat bogs, which accumulate coal- and siderite-bearing sediments, serve as a generator of ferruginous solutions with the significant part of Fe migrating from them in the form of metalloorganic compounds. The stability of organic Fe-bearing complexes provides favorable conditions for the late diagenetic–catagenetic siderite formation in adjacent sea basins. It has been established that the formation of Phanerozoic coals, oil shales, and black shales was nearly coeval with the formation of goethite–chlorite–siderite ores. The paper discusses the influence of volcanic activity on the formation of Precambrian–Phanerozoic iron ore deposits and emphasizes the significance of siderite formation in the general evolution of the sedimentary iron ore formation.  相似文献   

2.
Summary Recent exploration in northern Australia has discovered three shallow water oolitic iron formations, one of Permian age, and two of Upper Proterozoic age. The Permian formation resembles the oxidized oolitic chamositic formations of south-eastern England, but contains more detrital quartz and felspar.The two Precambrian iron formations, consist, below the zone of weathering, of oolites of hematite and of a chamosite-like substance, in a siderite cement, together with well-rounded quartz grains, and are interlayered with sandstones with a chamosite-like cement. Within the zone of weathering the siderite and chamosite are more or less completely replaced by quartz, but with preservation in detail of original textures.Published by permission of the Commonwealth Scientific and Industrial Research Organization (CSIRO).  相似文献   

3.
The role of siderite in Phanerozoic and Precambrian iron formations is discussed. Various types of iron formations are characterized, and their place in the evolution of sedimentary iron ore deposition is outlined. In Precambrian iron ore deposition, siderite is a primary mineral, whereas in Phanerozoic iron formations it becomes a secondary mineral and is commonly related to diagenetic and catagenetic processes.  相似文献   

4.
山西省吕梁山地区早元古宙袁家村铁矿以变质程度浅、地层剖面完整和地质构造简单为特征。厚约1200m 的袁家村组含铁岩系可以分成三个段,它们分别代表了三个沉积-成矿旋回。其中每一个旋回都是以粗碎屑岩开始,经过粉砂岩和泥质岩逐渐过渡为较纯的胶体化学沉积物即硅质岩。矿区出现的铁矿物相沿剖面自下而上依次为黄铁矿、菱铁矿、铁硅酸盐(包括铁绿泥石、铁滑石和黑硬绿泥石)、磁铁矿和赤铁矿。这些铁矿物相是沉积阶段、成岩阶段至初级变质阶段的产物。它们在地层剖面上的空间分布,反映各旋回铁矿物相的形成环境,在时间上自早至晚,空间上自下而上,其氧逸度逐渐增高。控制铁矿物相类型和其中铁价态形式的主要因素,是沉积时泥砂质碎屑组分和铁硅质胶体化学组分的性质和相对比例,以及其中有机质的存在与否及其多寡。  相似文献   

5.
The major, trace and rare earth element (REE) composition of Late Archean manganese, ferromanganese and iron ores from the Iron Ore Group (IOG) in Orissa, east India, was examined. Manganese deposits, occurring above the iron formations of the IOG, display massive, rhythmically laminated or botryoidal textures. The ores are composed primarily of iron and manganese, and are low in other major and trace elements such as SiO2, Al2O3, P2O5 and Zr. The total REE concentration is as high as 975 ppm in manganese ores, whereas concentrations as high as 345 ppm and 211 ppm are found in ferromanganese and iron ores, respectively. Heavy REE (HREE) enrichments, negative Ce anomalies and positive Eu anomalies were observed in post‐Archean average shale (PAAS)‐normalized REE patterns of the IOG manganese and ferromanganese ores. The stratiform or stratabound shapes of ore bodies within the shale horizon, and REE geochemistry, suggest that the manganese and ferromanganese ores of the IOG were formed by iron and/or manganese precipitation from a submarine, hydrothermal solution under oxic conditions that occurred as a result of mixing with oxic seawater. While HREE concentrations in the Late Archean manganese and ferromanganese ores in the IOG are slightly less than those of the Phanerozoic ferromanganese ores in Japan, HREE resources in the IOG manganese deposits appear to be two orders of magnitude higher because of the large size of the deposits. Although a reliable, economic concentration technique for HREE from manganese and ferromanganese ores has not yet been developed, those ores could be an important future source of HREE.  相似文献   

6.
Iron and phosphorite ores are very common in the geological record of Egypt and exploitable for economic purposes. In some cases these deposits belong together to the same geographic and geologic setting. The most common deposits include phosphorites, glauconites, and iron ores. Phosphorites are widely distributed as a belt in the central and southern part of Egypt. Sedimentary iron ores include oolitic ironstone of Aswan area and karstified iron ore of Bahria Oasis. Glauconites occur in the Western Desert associated with phosphorites and iron ores. As these ores are exploitable and phosphorus in iron ores and iron in phosphorites are considered as gangue elements, the iron–phosphorus relationship is examined in these deposits to clarify their modes of occurrences and genetic relationship based on previously published results.Phosphorus occurs mainly as carbonate fluorapatite (francolite). Iron, on the other hand, occurs in different mineralogical forms such as glauconites, hematite, limonite and goethite.In P-rich rocks (phosphorites) no relationship is observed between iron and phosphorus, which in turn indicates that the FeP model is unlikely to interpret the origin of the late Cretaceous phosphorites and the association of phosphorites and glauconites in Egypt. In Fe-rich rocks (iron ores and glauconites) also no relationship between iron and phosphorus is observed. The present work, therefore, does not support the hypothesis that there is a genetic relationship between phosphorus and iron in sedimentary rocks.  相似文献   

7.
The Attepe district consists of Precambrian, Lower–Middle Cambrian, Upper Cambrian–Lower Ordovician and Mesozoic formations. It contains several iron deposits and occurrences. Three types of iron-mineralizations can be distinguished in the area; (i) Sedimentary Fe-sulfide in Precambrian bituminous metapelitic rocks, and Fe-oxides in Precambrian metasandstones (SISO), (ii) vein-type Fe-carbonate and oxides composed of mainly siderite, ankerite and hematite including barite in Lower–Middle Cambrian metacarbonates of the Çaltepe Formation (HICO), (iii) karstic Fe-oxides and hydroxides essentially in the Lower–Middle Cambrian metacarbonates and the unweathered Fe-carbonates (KIO). The latter type is more widespread and located at the upper parts of the most important mineable iron deposits like Attepe deposit.

Oxygen-, carbon-, sulfur- and strontium-isotope studies have been performed on siderites and barites in the vein-type ores, and on calcites in the recrystallized Çaltepe Limestones to investigate the sources and formation mechanism of primary ore-forming constituents. The δ13C values of siderites and calcites in limestones of the Çaltepe Formation range from −10.10‰ to −8.20‰, and from −0.8‰ to 2.30‰. Both carbonate minerals show δ18O values between 17.50–18.30‰ and 16.20–23.00‰, respectively. The δ13C and δ18O isotopic variations do not indicate any direct or linear relations between siderites and limestones. However, it is possible that the carbon and oxygen isotopic compositions of carbonate minerals could be changed to some extent, when limestones were subjected to hydrothermal processes or thermal alterations during metamorphism.

The isotopic values of barites display 32.40–38.30‰ for δ34S and 12.20–14.70‰ for δ18O. The strontium isotope ratios (0.717169–0.718601) of barites and the sulfur isotope compositions of barites and pyrites suggest that there are no direct linkages of ore-forming compounds neither with a magmatic source nor with sedimentary pyrite formations in the Precambrian bituminous shales of the Attepe formation.

According to the field observations and the stable isotope data, siderites and ankerites should be formed by interaction between iron-rich hydrothermal fluids and Çaltepe limestones, whereas isotope ratios of barites indicate that they were formed by mixing of sulfur-rich meteoric waters and deeply circulated hydrothermal solutions.  相似文献   


8.
Detrital iron deposits (DID) are located adjacent to the Precambrian bedded iron deposit (BID) of Joda near the eastern limb of the horseshoe-shaped synclinorium, in the Bonai–Keonjhar belt of Orissa. The detrital ores overlie the Dhanjori Group sandstone as two isolated orebodies (Chamakpur and Inganjharan) near the eastern and western banks of the Baitarani River, respectively. The DID occur as pebble/cobble conglomerates containing iron-rich clasts cemented by goethite. Mineralogy, chemistry and lamination of these clasts are similar to that found in the nearby BID ores. Enrichment of trace and rare-earth elements in the DID relative to the BID is attributed to their concentration during the precipitation of cementing material. The detrital iron orebodies formed when Proterozoic weathering processes eroded pre-existing BID outcrops located on the Joda Ranges, and the resulting detritus accumulated in the paleochannels. In situ dissolution in association with abundant organic material produced Fe-saturated groundwater, which re-precipitated as goethite within the aggraded channel to cement the detritals. Growth of microplaty hematite in the goethite matrix suggests some level of subsequent burial metamorphism.  相似文献   

9.
Blackband iron formations are essentially thin (approximately 0·75 m thick) siderite-rich (total iron up to 40%), carbonaceous, laminated mudrocks which commonly occur in grey coal bearing sequences in close proximity to coal seams. They exhibit a conspicuous laminated macrotexture made up of carbonaceous and siderite-rich laminae together with primary textures such as root-disturbed laminae, sideritized unflattened spores and preservation of plant cell detail. These all point to formation of siderite soon after deposition, in some cases before significant compaction. Their enclosing sediments clearly show that they were deposited in environments intermediate between delta top alluvial floodplains and coastal plain swamps in which small areas were subjected to periods of lacustrine deposition. The presence of varved mudrocks and oil shales in the beds directly above many of the blackband iron formations and the distinctive fine lamination of the blackbands are evidence of such depositional environments. The blackband iron formations are considered to have been formed in a similar way to Recent bog iron ores and are therefore interpreted as fossil bog iron ores. A model for their mode of formation is presented.  相似文献   

10.
Abstract: The metamorphosed sedimentary type of iron deposits (BIF) is the most important type of iron deposits in the world, and super-large iron ore clusters of this type include the Quadrilatero Ferrifero district and Carajas in Brazil, Hamersley in Australia, Kursk in Russia, Central Province of India and Anshan-Benxi in China. Subordinated types of iron deposits are magmatic, volcanic-hosted and sedimentary ones. This paper briefly introduces the geological characteristics of major super-large iron ore clusters in the world. The proven reserves of iron ores in China are relatively abundant, but they are mainly low-grade ores. Moreover, a considerate part of iron ores are difficult to utilize for their difficult ore dressing, deep burial or other reasons. Iron ore deposits are relatively concentrated in 11 metallogenic provinces (belts), such as the Anshan-Benxi, eastern Hebei, Xichang-Central Yunnan Province and middle-lower reaches of Yangtze River. The main minerogenetic epoches vary widely from the Archean to Quaternary, and are mainly the Late Archean to Middle Proterozoic, Variscan, and Yanshanian periods. The main 7 genetic types of iron deposits in China are metamorphosed sedimentary type (BIF), magmatic type, volcanic-hosted type, skarn type, hydrothermal type, sedimentary type and weathered leaching type. The iron-rich ores occur predominantly in the skarn and marine volcanic-hosted iron deposits, locally in the metamorphosed sedimentary type (BIF) as hydrothermal reformation products. The theory of minerogenetic series of mineral deposits and minerogenic models has applied in investigation and prospecting of iron ore deposits. A combination of deep analyses of aeromagnetic anomalies and geomagnetic anomalies, with gravity anomalies are an effective method to seeking large and deep-buried iron deposits. China has a relatively great ore-searching potential of iron ores, especially for metamorphosed sedimentary, skarn, and marine volcanic-hosted iron deposits. For the lower guarantee degree of iron and steel industry, China should give a trading and open the foreign mining markets.  相似文献   

11.
李石 《矿床地质》1984,3(2):94-98
神农架铁矿位于华中第一高峰——鄂西神农架原始林区。目前发现具有工业价值的矿区主要有两个:一个在铁厂河,另一个在大神农架主峰附近(图1)。铁矿露头一般在标高2000—2500米以上。虽然该铁矿沉积形成于元古代,但由于它至今几乎未受变质,使它具有独特的矿石类型,以区别于一般前寒武纪沉积变质铁矿,因此人们专称它为神农架式。现将该铁矿特征简要报道如下。  相似文献   

12.
Based on research on the “Xinyu-type” Sinian iron deposits in Jiangxi Province and metamorphosed iron deposits in Jiangkou and Qidong of Hunan, Sanjiang and Yingyangguan of Guangxi, Longchuan of Guangdong and some other areas in Fujian, the authors have come to the following conclusions:
  1. The metamorphosed late Precambrian iron ores widespread in south China may be roughly assigned to two ore belts, namely the Yiyang-Xinyu (Jiangxi)-Jiangkou(Hunan)-Sanjiang (Guangxi) ore belt or simply the north ore belt, and the Songzheng(Fujian)-Shicheng (Jiangxi)-Bailing (Longchuan of Guangdong)-Yingyangguan (Guangxi) ore belt or the south ore belt. Tectonically, the former lies along the southern margin of the “Jangnan Old Land”, while the latter along the northwestern border of the “Cathaysian Old Land”.
  2. Iron deposits of this type occur exclusively in the same interglacial horizon of the Sinian Glaciation in south China. Above and below the ore bed there lie the glacial till-bearing volcanic-sedimentary layers.
  3. Based on sedimentary features, the iron formations can be divided into four types: silica-iron-basalt formation, silica-iron-clastic rock formation, silica-iron-tuff formation and silica-iron-carbonate rock formation, which progressively grade into each other.
  4. Iron ores were formed at the late stage of late Proterozoic rifting in neritic environments, with their distribution governed by the rift valleys on the margins of the “Jiangnan Old Land” and “Cathaysian Old Land”. Consequently, intense mafic volcanism as well as weathering and denudation of palaeocontinent during rifting provided material sources for the formation of iron deposits. Meanwhile, warm and humid stationary neritic environment during the south China great glacial period constitutes favorable palaeoclimatologic and palaeogeographic conditions for the deposition of iron ores.
  5. The iron formations have undergone regional metamorphism of greenschist-amphibolite facies.
To sum up, the late Precambrian banded iron ores should be of metamorphosed volcano-sedimentary type.  相似文献   

13.
Pioneer results of the comprehensive analysis of nodules from the Upper Paleozoic coaliferous association and the underlying Middle Paleozoic sequence in the southern Tunguska Basin (Siberian Craton) suggest the following: (1) sediments underlying the coaliferous association contain two (siliceous and carbonate) types of normal nodules and one type of allogenic nodules (redeposited chalcedony nodules in the kaolin-itechalcedony unit of the Beloyarsk Formation); (2) the coaliferous association includes four (calcite, siderite, pyrite, and goethite) types of nodules; (3) each nodule type is confined to a specific genetic type of sediment; e.g., siliceous nodules are confined to lagoonal sediments; calcite nodules, to lacustrine and lacustrine-boggy sediments; siderite nodules, to lacustrine-boggy and boggy sediments; pyrite nodules, to boggy sediments; and goethite nodules, to alluvial sediments; (4) the formation of goethite nodules is mainly related to the erosion and redeposition of siderite nodules; (5) the coefficient of carbon concentration shows a distinct positive correction with the coefficient of nodule content; (6) nodules appeared in the coaliferous association during diagenesis and epigenesis; the calcite and pyrite nodules are enriched in sandy material, as suggested by the high content of insoluble residue; (7) combustion of coal seams promoted the melting of the adjacent siderite nodules and the formation of magnetite ores; consequently, the thermally altered mudstones, siltstones, and sandstones were transformed into a high-quality building material that is used as road fill.  相似文献   

14.
Iron isotopes fractionate during hydrothermal processes. Therefore, the Fe isotope composition of ore-forming minerals characterizes either iron sources or fluid histories. The former potentially serves to distinguish between sedimentary, magmatic or metamorphic iron sources, and the latter allows the reconstruction of precipitation and redox processes. These processes take place during ore formation or alteration. The aim of this contribution is to investigate the suitability of this new isotope method as a probe of ore-related processes. For this purpose 51 samples of iron ores and iron mineral separates from the Schwarzwald region, southwest Germany, were analyzed for their iron isotope composition using multicollector ICP-MS. Further, the ore-forming and ore-altering processes were quantitatively modeled using reaction path calculations. The Schwarzwald mining district hosts mineralizations that formed discontinuously over almost 300 Ma of hydrothermal activity. Primary hematite, siderite and sulfides formed from mixing of meteoric fluids with deeper crustal brines. Later, these minerals were partly dissolved and oxidized, and secondary hematite, goethite and iron arsenates were precipitated. Two types of alteration products formed: (1) primary and high-temperature secondary Fe minerals formed between 120 and 300 °C, and (2) low-temperature secondary Fe minerals formed under supergene conditions (<100 °C). Measured iron isotope compositions are variable and cover a range in δ56Fe between −2.3‰ and +1.3‰. Primary hematite (δ56Fe: −0.5‰ to +0.5‰) precipitated by mixing oxidizing surface waters with a hydrothermal fluid that contained moderately light Fe (δ56Fe: −0.5‰) leached from the crystalline basement. Occasional input of CO2-rich waters resulted in precipitation of isotopically light siderite (δ56Fe: −1.4 to −0.7‰). The difference between hematite and siderite is compatible with published Fe isotope fractionation factors. The observed range in isotopic compositions can be accounted for by variable fractions of Fe precipitating from the fluid. Therefore, both fluid processes and mass balance can be inferred from Fe isotopes. Supergene weathering of siderite by oxidizing surface waters led to replacement of isotopically light primary siderite by similarly light secondary hematite and goethite, respectively. Because this replacement entails quantitative transfer of iron from precursor mineral to product, no significant isotope fractionation is produced. Hence, Fe isotopes potentially serve to identify precursors in ore alteration products. Goethites from oolitic sedimentary iron ores were also analyzed. Their compositional range appears to indicate oxidative precipitation from relatively uniform Fe dissolved in coastal water. This comprehensive iron isotope study illustrates the potential of the new technique in deciphering ore formation and alteration processes. Isotope ratios are strongly dependent on and highly characteristic of fluid and precipitation histories. Therefore, they are less suitable to provide information on Fe sources. However, it will be possible to unravel the physico-chemical processes leading to the formation, dissolution and redeposition of ores in great detail.  相似文献   

15.
Ferriferous ooids and microoncoids occur in many sedimentary iron formations. These ferriferous-coated grains are found in fine-grained carbonate-rich groundmasses. Iron mineral-encrusted microbiota are observed in both the coated grains and the groundmass. The branching nature and other morphological features of the microorganisms suggest fungal origins for the oolitic iron ores particularly of the Lower Jurassic (Lorraine Minette). The similarity of the microbial structures in coated grains and their groundmasses suggests that both had developed within microbial mats growing under calm environmental conditions. The contribution of stromatolitic marine fungal mats to the fast extraction and immobilization of iron and thus to the genesis of iron ores is demonstrated. Observations on well-preserved freshwater-derived fungal stromatolites of the Tertiary and laboratory experiments with organotrophic fungal mats confirm the findings on the Jurassic and imply a general role of microorganisms in the formation of such deposits.  相似文献   

16.
The REE distribution in alluvial, deltaic, liman, and lacustrine oolitic iron ores in the northern Aral region is analyzed. In general, the iron ores are relatively enriched in LREE. The REE distribution patterns are sufficiently similar in different facies, although the contents may slightly vary owing to specific features of the mineral and chemical compositions.Translated from Litologiya i Poleznye Iskopaemye, No. 2, 2005, pp. 215–219.Original Russian Text Copyright © 2005 by Golubovskaya.  相似文献   

17.
Ironstone is any chemical sedimentary rock with > 15% Fe. An iron formation is a stratigraphic unit which is composed largely of ironstone. The solutes which have precipitated to become ironstone have dissolved from the Earth's surface, from the upper crust, e.g. the basaltic layer of oceanic crust, or from deeper within the Earth. Genetic modellers generally choose between surficial weathering, e.g. soil formation, and hydrothermal fluids which have convected through the upper kilometre of oceanic crust. Most genetic modellers attribute cherty laminated iron formations to hydrothermal convection and noncherty oolitic iron formations to surficial weathering. However, both types of iron formations are attributable to the exhalation of fluids from a source region too deep for convection of seawater. Evidence for a deep source of ferriferous fluids comes from a comparison of ancient ironstone with modern ferriferous sediment in coastal Venezuela. A deep-source origin for ironstone has wide-ranging implications for the origins of other chemical sedimentary ores, e.g. phosphorite, manganostone, bedded magnesite, sedimentary uranium ore, various karst-filling ores, and even petroleum. Preliminary study of a modern oolitic iron deposit described herein suggests that the source of iron and silica to iron formations may have been even deeper than envisioned within most hydrothermal convection models.  相似文献   

18.
As part of our ongoing research on the application of elemental geochemistry methods to Early Precambrian ferrous quartzite formations and in order to elucidate the nature of their ore material, we investigated the distribution of As, Sb, and Bi in exogenic oxide-hydroxide iron ores, sedimentary carbonate rocks and iron ores, and ferro-siliceous formations of the Krivoi Rog (Ukrainian shield), Kursk-Belgorod (Voronezh crystalline massif), Kostomuksha, and Imandra iron ore provinces (Baltic shield) of the Late Archean and Early Proterozoic. The results of the elemental geochemical investigations were used to evaluate the plausibility of some geological and geochemical models of Early Precambrian ferro-siliceous ore formation.  相似文献   

19.
Mineralogical-geochemical features of different facies types of sedimentary iron ore deposits are described. Particular attention is paid to deposits associated with the weathering crusts of ultramafic igneous rocks and to marine oolitic iron ores. The multistage formation of their geochemical properties is proved available geochemical models are considered.  相似文献   

20.
The Coniacian-Santonian high-phosphorus oolitic iron ore at Aswan area is one of the major iron ore deposits in Egypt. However, there are no reports on its geochemistry, which includes trace and rare earth elements evaluation. Texture, mineralogy and origin of phosphorus that represents the main impurity in these ore deposits have not been discussed in previous studies. In this investigation, iron ores from three localities were subjected to petrographic, mineralogical and geochemical analyses. The Aswan oolitic iron ores consist of uniform size ooids with snowball-like texture and tangentially arranged laminae of hematite and chamosite. The ores also possess detrital quartz, apatite and fine-grained ferruginous chamosite groundmass. In addition to Fe2O3, the studied iron ores show relatively high contents of SiO2 and Al2O3 due to the abundance of quartz and chamosite. P2O5 ranges from 0.3 to 3.4 wt.% showing strong positive correlation with CaO and suggesting the occurrence of P mainly as apatite. X-ray diffraction analysis confirmed the occurrence of this apatite as hydroxyapatite. Under the optical microscope and scanning electron microscope, hydroxyapatite occurred as massive and structureless grains of undefined outlines and variable size (5–150 μm) inside the ooids and/or in the ferruginous groundmass. Among trace elements, V, Ba, Sr, Co, Zr, Y, Ni, Zn, and Cu occurred in relatively high concentrations (62–240 ppm) in comparison to other trace elements. Most of these trace elements exhibit positive correlations with SiO2, Al2O3, and TiO2 suggesting their occurrence in the detrital fraction which includes the clay minerals. ΣREE ranges between 129.5 and 617 ppm with strong positive correlations with P2O5 indicating the occurrence of REE in the apatite. Chondrite-normalized REE patterns showed LREE enrichment over HREE ((La/Yb)N = 2.3–5.4) and negative Eu anomalies (Eu/Eu* = 0.75–0.89). The oolitic texture of the studied ores forms as direct precipitation of iron-rich minerals from sea water in open space near the sediment-water interface by accretion of FeO, SiO2, and Al2O3 around suspended solid particles such as quartz and parts of broken ooliths. The fairly uniform size of the ooids reflects sorting due to the current action. The geochemistry of major and trace elements in the ores reflects their hydrogenous origin. The oolitic iron ores of the Timsha Formation represent a transgressive phase of the Tethys into southern Egypt during the Coniacian-Santonian between the non-marine Turonian Abu Agag and Santonian-Campanian Um Barmil formations. The abundance of detrital quartz, positive correlations between trace elements and TiO2 and Al2O3, and the abundance mudstone intervals within the iron ores supports the detrital source of Fe. This prediction is due to the weathering of adjacent land masses from Cambrian to late Cretaceous. The texture of the apatite and the REE patterns, which occurs entirely in the apatite, exhibits a pattern similar to those in the granite, thus suggesting a detrital origin of the hydroxyapatite that was probably derived from the Precambrian igneous rocks. Determining the mode of occurrence and grain size of hydroxyapatite assists in the maximum utilization of both physical and biological separation of apatite from the Aswan iron ores, and hence encourages the use of these ores as raw materials in the iron making industry.  相似文献   

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