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1.
The rainfall series for Fortaleza (Ceará) is compared with similar series for several other locations in Northeast Brazil. It is shown that the correlations are high for distances up to about 600 km from Fortaleza. The Fortaleza series shows prominent periodicities at T = 2.1, 10.1, 12.9, 25.1, and 61.0 years, all significant at a 3 a priori level. Amongst these, T = 12.9 and 25.1 years are significant at a 4 a priori level. A master Curve (for 1912–1978 only), obtained by averaging rainfall data for 93 stations having good correlations with Fortaleza, shows very prominent periodicities at T = 5.6, 12.3 and 47.3 years, significant at a 3 a priori level. T = 12.3 is significant at a 4 a priori level. Predictions from both the Fortaleza series (1849–1976) and the Master Curve (1912–1978) indicated droughts during 1979–1983. This prediction seems to have come true. In the future, droughts during 1992–1994 and 2002–2006 are indicated.  相似文献   

2.
The annual mean sea-level time series for Stockholm (Sweden) for 1825–1984 (160 data points) had a large long-term negative (almost linear, only slightly quadratic) trend. After correcting for the same, the detrended series was subjected to maximum entropy spectral analysis (MESA). Choosing selected periodicities for further multiple regression analysis, series for the first 80 yr (1825–1904) showed periodicities at T = 2.40, 5.0, 6.1, 13.5, 14.8 and 32 yr, significant at a 2 level. The three largest peaks (italicized) had amplitudes of approximately (2.5–3.0) ± 0.8 cm. The latter 80 yr (1905–1984) showed significant periodicities at T= 2.05, 2.7, 3.0, 3.6, 4.4, 5.5, 6.3, 7.7, 9.8, 20.5 and 33 yr. The three largest peaks (italicized) had amplitudes of approximately (2.0–2.5) ± 0.7 cm. The whole period of 160 yr (1825–1984) showed significant periodicities at T = 2.05, 2.9, 3.2, 4.5, 4.9, 5.6, 6.4, 7.8, 11.0, 13.7, 14.8, 29 and 43 yr. The three largest peaks (italicized) had amplitudes of approximately (1.6–1.9) ± 0.6 cm. All these significant peaks explained a variance of only about 30% or less, indicating a large random component of approximately 70%. Peaks at T = 11 yr (sunspot cycle) or T = 18.6 yr (lunar nodal term) were either absent or very weak. Most of the other peaks were transient (present in the first 80 yr or the latter 80 yr) except an uncertain quasibiennial oscillation (QBO) (T = 2–3 yr) and T = 5–6 yr and T 30 yr, which seemed to be persistent throughout the whole period. Some periodicities seem to resemble those seen in the Southern Oscillation (SO) index.  相似文献   

3.
A 1053-year reconstruction of spring rainfall (March-June) was developed for the southeastern United States, based on three tree-ring reconstructions of statewide rainfall from North Carolina, South Carolina, and Georgia. This regional reconstruction is highly correlated with the instrumental record of spring rainfall (r = +0.80; 1887–1982), and accurately reproduces the decade-scale departures in spring rainfall amount and variance witnessed over the Southeast during the past century. No large-magnitude centuries-long trends in spring rainfall amounts were reconstructed over the past 1053 years, but large changes in the interannual variability of spring rainfall were reconstructed during portions of the Medieval Warm Period (MWP), Little Ice Age (LIA), and the 20th century. Dry conditions persisted at the end of the 12th century, but appear to have been exceeded by a reconstructed drought in the mid-18th century. High interannual variability, including five extremely wet years were reconstructed for a 20-yr period during the late 16th and early 17th centuries, and may reflect amplified atmospheric circulation over eastern North America during what appears to have been one of the most widespread cold episodes of the Little Ice Age.  相似文献   

4.
Summary The relationships between the El-Niño phenomenon and the planetary-scale waves, and the interannual variations in the Indian monsoon (June–September) rainfall have been analysed in order to investigate how the sea surface temperature (SST) in the equatorial eastern Pacific associated with the El-Niño can produce reduced monsoon rainfall over India by teleconnections.The longitude of ridge location over the Indian region of the integrated planetary waves (numbers 1–3) along 15° N latitude circle in the height field of 200 mb pressure level in May is significantly (r=0.93, significant at 98% CL) related to the May SST anomaly at Puerto Chicama. This implies that warmer (colder) SST anomalies are associated with eastward (westward) longitude of the ridge location. The variations of the ridge location in May appear to be significantly inversely (r=–0.95, significant at 99% CL) related to the Indian monsoon rainfall, with rainfall tending to be less (more) than normal during eastward (westward) longitude of the ridge location suggesting some predictive value for the Indian monsoon rainfall. The Indian monsoon rainfall and May SST anomaly at Puerto Chicama are inversely related (r=–0.90, significant at 96% CL).In terms of the observed relationships, a plausible mechanism for linking El-Niño with the reduced Indian monsoon rainfall is discussed. The relationships noted suggest that excessive warm SST anomalies associated with El-Niño induce an eastward shift in the planetary waves which in turn reduce the Indian monsoon rainfall.With 8 Figures  相似文献   

5.
In the present study the Principal Component Analysis (PCA) is used to determine the dominant rainfall patterns from rainfall records over India. Pattern characteristics of seasonal monsoon rainfall (June–September) over India for the period 1940 to 1990 are studied for 68 stations. The stations have been chosen on the basis of their correlation with all India seasonal rainfall after taking the ‘t’ Student distribution test (5% level). The PCA is carried out on the rainfall data to find out the nature of rainfall distribution and percentage of variance is estimated. The first principal component explains 55.50% of the variance and exhibits factor of one positive value throughout the Indian subcontinent. It is characterized by an area of large positive variation between 10°N and 20°N extending through west coast of India. These types of patterns mostly occur due to the monsoon depression in the head Bay of Bengal and mid-tropospheric low over west coast of India. The analysis identifies the spatial and temporal characteristics of possible physical significance. The first eight principal component patterns explain for 96.70% of the total variance.  相似文献   

6.
Are droughts predictable?   总被引：2，自引：0，他引：2  
From a study of rainfall series at several locations, it is shown that approximate but meaningful predictions of drought-prone intervals are possible only for regions where the rainfall series have prominent periodicities (of large amplitudes) in the long periodicity region (about 10 yr or more), provided the patterns do not change abruptly and drastically. Also, rainfall for individual years cannot be predicted accurately.  相似文献   

7.
Rate constants have been measured for the gas-phase reactions of hydroxyl radical with partly halogenated alkanes using the discharge-flow-EPR technique over the temperature range 298–460 K. The following Arrhenius expressions have been derived (units 10–13 cm3 molecule–1 s–1): (8.1 –1.2 +1.5 ) exp{–(1516±53)/T} for CHF2Cl (HCFC-22); (10.3 –1.5 +1.8 ) exp{–(1588±52)/T} for CH2FCF3 (HFC-134a); (11.3 –1.6 +2.1 ) exp{–(918±52)/T} for CHCl2CF2Cl (HCFC-122); (9.2 –2.0 +2.5 ) exp{–(1281±85)/T} for CHFClCF2Cl (HCFC-123a).The atmospheric lifetimes for the substances have been estimated to be 12.6, 12.9, 1.05, and 4.8 years, respectively, and the accuracy of the estimates is discussed.  相似文献   

8.
Vapor phase concentrations of acetone, acetaldehyde and acetonitrile over their aqueous solutions were measured to determine Henry's law partition coefficients for these compounds in the temperature range 5–40 °C. The results are for acetone: ln(H 1/atm)=–(5286±100)T+(18.4±0.3); acetaldehyde: ln(H 1/atm)=–(5671±22)/T+(20.4±0.1); and acetonitrile: ln(H 1/atm)=–(4106±101)/T+(13.8±0.3). Artificial seawater of 3.5% salinity in place of deiionized water raisesH 1 by about 15%. A similar technique has been used to measure the equilibrium constants for the addition compounds of acetone and acetaldehyde with bisulfite in aqueous solution. The results are ln(K 1/M –1)=(4972±318)/T–(11.2±1.1) and ln(K 1/M –1)=(6240±427)/T–(8.1±1.3), respectively. The results are compared and partly combined with other data in the literature to provide an average representation.  相似文献   

9.
Summary Mean monthly rainfall data of 28 meteorological stations in Nigeria for the period 1911–1980 are analysed to examine trends in precipitation patterns in the country. Specifically, four 40-year periods (1911–50, 1921–60, 1931–70 and 1941–80) have been studied in detail.Results show three prominent features. First, both the amount and area of the secondary rainfall maximum at 9°–10°N latitude in Nigeria has depreciated with time. Second, the belt of relative minimum rainfall, with its east-west axis almost coincident with the channels of the rivers Niger and Benue, appears to be expanding with time. Last, while places north of 8°N latitude (the mean axis of the belt of relative minimum rainfall) receive 90–100% of the annual total rainfall from April to October, fluctuations of the wet or rainy season contribution to total annual rainfall further south is about 84–88%.These aberrations, which imply a decrease in the dry season contribution to the annual rainfall, suggest a drier environment in the long-term, especially if drought spells of the type 1969–73 and 1979–84 become a regular feature in West Africa. The planning implications are discussed in relation to water-use problems.
Zusammenfassung Mittlere Monatssummen des Niederschlags von 28 meteorologischen Stationen in Nigeria von 1911–1980 wurden analysiert, um Trends in den Niederschlagsverteilungen des Landes zu untersuchen. Insbesondere wurden die 40-Jahresperioden 1911–50, 1921–60, 1931–70 und 1941–80 bearbeitet.Die Ergebnisse zeigen drei bedeutende Merkmale. Erstens, Menge und Niederschlagsgebiet des sekundären Maximums in 9–10° nördlicher Breite wurden kleiner. Zweitens, der Gürtel eines relativen Niederschlagsminimums, dessen Ost-West-Achse fast mit den Flußläufen von Niger und Benue zusammenfällt, scheint sich auszudehnen. Und schließlich, während Orte nördlich von 8° nördl. Breite (der Hauptachse des Niederschlagsminimums) 90–100% der Jahressumme von April bis Oktober empfangen, beträgt die Schwankung des Anteils von Regen- und Trockenzeit weiter im Süden 84–88%. Diese Abweichungen, die eine Abnahme des Anteils der Trockenzeit zum Gesamtniederschlag bedeuten, lassen in Zukunft eine trockene Umwelt erwarten, besonders wenn die Trockenperioden von 1969–73 und 1979–84 sich wiederholen sollten. Es werden die Folgen für die Planung des Wasserverbrauches diskutiert.

With 8 Figures  相似文献   

10.
The kinetics of the aqueous phase reactions of NO3 radicals with HCOOH/HCOO– and CH3COOH/CH3COO– have been investigated using a laser photolysis/long-path laser absorption technique. NO3 was produced via excimer laser photolysis of peroxodisulfate anions (S2O 8 2– ) at 351 nm followed by the reactions of sulfate radicals (SO 4 – ) with excess nitrate. The time-resolved detection of NO3 was achieved by long-path laser absorption at 632.8 nm. For the reactions of NO3 with formic acid (1) and formate (2) rate coefficients ofk 1=(3.3±1.0)×105 l mol–1 s–1 andk 2=(5.0±0.4)×107 l mol–1 s–1 were found atT=298 K andI=0.19 mol/l. The following Arrhenius expressions were derived:k 1(T)=(3.4±0.3)×1010 exp[–(3400±600)/T] l mol–1 s–1 andk 2(T)=(8.2±0.8)×1010 exp[–(2200±700)/T] l mol–1 s–1. The rate coefficients for the reactions of NO3 with acetic acid (3) and acetate (4) atT=298 K andI=0.19 mol/l were determined as:k 3=(1.3±0.3)×104 l mol–1 s–1 andk 4=(2.3±0.4)×106 l mol–1 s–1. The temperature dependences for these reactions are described by:k 3(T)=(4.9±0.5)×109 exp[–(3800±700)/T] l mol–1 s–1 andk 4(T)=(1.0±0.2)×1012 exp[–(3800±1200)/T] l mol–1 s–1. The differences in reactivity of the anions HCOO– and CH3COO– compared to their corresponding acids HCOOH and CH3COOH are explained by the higher reactivity of NO3 in charge transfer processes compared to H atom abstraction. From a comparison of NO3 reactions with various droplets constituents it is concluded that the reaction of NO3 with HCOO– may present a dominant loss reaction of NO3 in atmospheric droplets.  相似文献   

11.
Continuous periodogram analyses of 115 years (1871-1985) summer monsoon rainfall over the Indian region show that the power spectra follow the universal and unique inverse power law form of the statistical normal distribution with the percentage contribution to total variance representing the eddy probability corresponding to the normalized standard deviation equal to [(log L/log T50) – 1] where L is the period length in years and T50 the period up to which the cumulative percentage contribution to total variance is equal to 50. The above results are con-sistent with a recently developed non-deterministic cell dynamical model for atmospheric flows. The implications of the above result for prediction of interannual variability of rainfall is discussed.  相似文献   

12.
Summary The relationship between the all-India summer monsoon rainfall and surface/upper air (850, 700, 500 and 200 mb levels) temperatures over the Indian region and its spatial and temporal characteristics have been examined to obtain a useful predictor for the monsoon rainfall. The data series of all-India and subdivisional summer monsoon rainfall and various seasonal air temperatures at 73 surface observatories and 9 radiosonde stations (1951–1980) have been used in the analysis. The Correlation Coefficients (CCs) between all-India monsoon rainfall and seasonal surface air temperatures with different lags relative to the monsoon season indicate a systematic relationship.The CCs between the monsoon rainfall and surface-air temperature of the preceding MAM (pre-monsoon spring) season are positive over many parts of India and highly significant over central and northwestern regions. The average surface air temperature of six stations i.e., Jodhpur, Ahmedabad, Bombay, Indore, Sagar and Akola in this region (Western Central India, WCI) showed a highly significant CC of 0.60 during the period 1951–1980. This relationship is also found to be consistently significant for the period from 1950 to present, though decreasing in magnitude after 1975. WCI MAM surface air temperature has shown significant CCs with the monsoon rainfall over eleven sub-divisions mainly in northwestern India, i.e., north of 15 °N and west of 80 °E.Upper air temperatures of the MAM season at almost all the stations and all levels considered show positive CCs with the subsequent monsoon rainfall. These correlations are significant at some central and north Indian stations for the lower and middle tropospheric temperatures.The simple regression equation developed for the period 1951–1980 isy = – 183.20 + 8.83x, wherey is the all-India monsoon rainfall in cm andx is the WCI average surface air temperature of MAM season in °C. This equation is significant at 0.1% level. The suitability of this parameter for inclusion in a predictive regression model along with five other global and regional parameters has been discussed. Multiple regression analysis for the long-range prediction of monsoon rainfall, using several combinations of these parameters indicates that the improvement of predictive skill considerably depends upon the selection of the predictors.With 9 Figures  相似文献   

13.
Rainfall during the warm season (June 15–October 15) is the most important of the year in terms of flood generation and erosion in rivers of the southern Colorado Plateau. Fluvial erosion of the plateau decreased substantially in the 1930s to early 1940s, although the cause of this change has not been linked to variation of warm-season rainfall. This study shows that a decrease of warmseason rainfall frequency was coincident with and probably caused the decreased erosion by reducing the probability of large floods. Warm-season rainfall results from isolated thunderstorms associated with the Southwestern monsoon and from dissipating tropical cyclones and (or) cutoff low-pressure systems that produce widespread, general rainfall. Warm-season rainfall is typically normal to above normal during warm El Niño-Southern Oscillation (ENSO) conditions. A network of 24 long-term precipitation gages was used to develop an index of standardized rainfall anomalies for the southern Colorado Plateau for the period 1900–85. The index shows that the occurrence of anomalously dry years increased and the occurrence of anomalously wet years decreased after the early 1930s, although 1939–41, 1972, and 1980–84 were anomalously wet. The decrease in warm-season rainfall after the early 1930s is related to a decrease in rainfall from dissipating tropical cyclones, shifts in the incidence of meridional circulation in the upper atmosphere, and variability of ENSO conditions.  相似文献   

14.
A laboratory study of scalar diffusion in the convective boundary layer has found results that are consistent with a 1999 large-eddy simulation (LES) study by Jonker, Duynkerke and Cuijpers. For bottom-up and top-down scalars (introduced as ‘infinite’ area sources of passive tracer at the surface and inversion, respectively) the dominant length scale was found to be much larger than the length scale for density fluctuations, the latter being equal to the boundary-layer depth h. The variance of the normalized passive scalar grew continuously with time and its magnitude was about 3–5 times larger for the top-down case than for the bottom-up case. The vertical profiles of the normalized passive scalar variance were found to be approximately constant through the convective boundary layer (CBL) with a value of about 3–8c*2 for bottom-up and 10–50c*2 for top-down diffusion. Finally, there was some evidence of a minimum in the variance and dominant length scale for scalar flux ratios (top-down to bottom-up flux) close to −0.5. All these convection tank results confirm the LES results and support the hypothesis that there is a distinct difference in behaviour between the dynamic and passive variables in the CBL.  相似文献   

15.
Summary Mean temperature (T) values at the 1000/500 hPa atmospheric layer over Europe have been calculated on the basis of grid point data, for the period between 1945–88. An analysis of trend inT values over the whole period found that most of the area is characterized by positive trends. During the summer of the last sub-period, 1970–88, there was a positive trend predominant over most of the region, with a maximum rate of 0.5°C/10 years. It is therefore evident that the warmth of the 1980s is not just a surface phenomenon over the region. Regarding significant periodicities, the well known Quasi Biennial Oscillation (QBO) was identified only for some grid points of the NW and NE regions, while the Southern Hemisphere Oscillation (SO) was only identified for the Mediterranean area.With 8 Figures  相似文献   

16.
Paralleling the Southern Himalayan Province, the Indo-GangeticPlains region (IGPR) of India (geographical area 6,00,000 km2) is veryimportant for the food security of South Asia. Due to numerous factors inoperation there is widespread apprehension regarding sustainability offragile ecosystems of the region. Literature provides detailed documentation of environmental changes due to different factors except climatic. The present study is intended to document the instrumental-period fluctuations of important climatic parameters like rainfall amounts (1829–1999), severe rainstorms (1880–1996) and temperature (1876–1997) exclusively for the IGPR. The summer monsoon rainfall over western IGPR shows increasing trend(170 mm/100-yr, significant at 1% level) from 1900 while over central IGPR it shows decreasing trend (5 mm/100-yr, not significant) from 1939 and over eastern IGPR decreasing trend (50 mm/100-yr, not significant) during 1900–1984 and insignificant increasing trend (480 mm/100-yr, not significant) during 1984–1999. Broadly it is inferred that there has been a westward shift in rainfall activities over the IGPR. Analysis suggests westward shift in the occurrence of severe rainstorms also. These spatial changes in rainfall activities are attributed to global warming and associated changes in the Indian summer monsoon circulation and the general atmosphericcirculation. The annual surface air temperature of the IGPR showed rising trend (0.53 ° C/100-yr, significant at 1% level) during 1875–1958 and decreasing trend (–0.93 ° C/100-yr, significant at 5% level) during 1958–1997. The post-1958 period cooling of the IGPR seems to be due to expansion and intensification of agricultural activities and spreading of irrigation network in the region. Lateral shift in the river courses is an environmental hazard of serious concern in the IGPR. In the present study it is suggested that meteorologic factors like strength and direction of low level winds and spatial shift in rainfall/climatic belt also play a significant role along with tectonic disturbances and local sedimentological adjustments in the vagrancy of the river courses over the IGPR.  相似文献   

17.
Microphysical theory has proven essential for explaining sea spray's role in transferring heat and moisture across the air–sea interface. But large-scale models of air–sea interaction, among other applications, cannot afford full microphysical modules for computing spray droplet evolution and, thus, how rapidly these droplets exchange heat and moisture with their environment. Fortunately, because the temperature and radius of saline droplets evolve almost exponentially when properly scaled, it is possible to approximate a droplet's evolution with just four microphysical endpoints: its equilibrium temperature, Teq; the e-folding time to reach that temperature, τT; its equilibrium radius, req; and the e-folding time to reach that radius, τr.Starting with microphysical theory, this paper derives quick approximation formulas for these microphysical quantities. These approximations are capable of treating saline droplets with initial radii between 0.5 and 500 μm that evolve under the following ambient conditions: initial droplet temperatures and air temperatures between 0 and 40 °C, ambient relative humidities between 75% and 99.5%, and initial droplet salinities between 1 and 40 psu.Estimating Teq, τT, and τr requires only one-step calculations; finding req is done recursively using Newton's method. The approximations for Teq and τT are quite good when compared to similar quantities derived from a full microphysical model; Teq is accurate to within 0.02 °C, and τT is typically accurate to within 5%. The estimate for equilibrium radius req is also usually within 5% of the radius simulated with the full microphysical model. Finally, the estimate of radius e-folding time τr is accurate to within about 10% for typical oceanic conditions.  相似文献   

18.
In this study, two universal turbidity parameters, the Angstrom turbidity coefficient and Linke turbidity factor, are applied to study the atmospheric turbidity characteristics of Taichung Harbor. Meteorological parameter values were measured during 2004 and 2005 at the Wuchi weather station of the Taiwan Central Weather Bureau, near the Taiwan Strait. Results based on the Angstrom turbidity models (βLou, βPin, and βVis) indicated that annual mean values of the Angstrom turbidity coefficients were 0.174, 0.21 and 0.201, respectively. Four sets of Linke turbidity factors (TLin, TLou, TPin and TVis) were calculated using the original Linke method and the Dogniaux method, incorporating the computed Angstrom turbidity coefficients (βLou, βPin and βVis); the resultant values were 4.30, 6.40, 7.10 and 6.95, respectively. The monthly average values, frequency of occurrence, and cumulative frequency distributions were calculated using different models to describe the clear-sky atmospheric conditions at Taichung Harbor. The frequency results show that for over 50% of the dataset, three sets of Angstrom turbidity coefficients fell between 0.15 and 0.18, and four sets of Linke turbidity factors (TLin, TLou, TPin and TVis) fell between 4.0 and 6.5. Thus, for 50% of cloudless days, the sky can be between turbid and clear over Taichung Harbor. Furthermore, the results reveal that for 30% of the dataset, three Angstrom sets of turbidity coefficients (βLou, βPin, and βVis) exceed 0.2 and four sets of Linke turbidity factors (TLin, TLou, TPin and TVis) exceed 5.0. This indicates that 30% of cloudless sky conditions can be considered turbid to very turbid.  相似文献   

19.
Summary The behavior of the Indian summer monsoon during the period 1979–1985 is examined with surface rainfall and infrared satellite data in order to determine how well the satellite measurements mimic the episodic rainfall processes. It is shown that equivalent-black-body-temperatures derived from satellite measured outgoing longwave radiation (OLR) estimates are reliable indicators for reproducing the timevariant zonal structure of monsoon rainfall over the Indian sub-continent—but only at preferred frequencies. The Indian summer monsoon is found to exhibit a distinct three episode cycle of active-break periods along two north-south aligned cross-sections; the first along the west Indian coast, the second through central India up to the plains of west Uttar Pradesh.We use the triplex behavior of the monsoon as a framework to describe individual monsoons from 1979 to 1985. This is done in terms of the initiation or phase, amplitude, duration, and propagation of the individual episodes. Cospectrum calculations between the rainfall and satellite temperature show that significant coherence is only associate with the frequencies corresponding to specific sub-seasonal fluctuating modes of the monsoon, i.e. 30–50 day and 10–20 day modes. The 30–50 day mode exhibits particularly strong coherence. It is shown how the behavior of the rainfall normals can be used to aid the calculation of a synthetic satellite temperature normal. Coherance at the 30–50 day mode in the co-spectrum of the departure time series is also strong; coherence at the 10–20 day mode is weaker but significant. This suggests that although satellite derived temperature is not a universal for rainfall, it could be used as a variable for monitoring the inra-annual behavior of the fluctuating rainfall modes of the monsoon.With 12 Figures  相似文献   

20.
Henry's law constantsK H (mol kg–1 atm–1) have been determined at 298.15 K for the following organic acids: formic acid (5.53±0.27×103); acetic acid (5.50±0.29×103); propionic acid (5.71±0.34×103);n-butyric acid (4.73±0.18×103); isobutyric acid (1.13±0.12×103); isovaleric acid (1.20±0.11×103) and neovaleric acid (0.353±0.04×103). They have also been determined fromT=278.15 K toT=308.15 K forn-valeric acid (ln(K H)=–14.3371+6582.96/T);n-caproic acid (ln(K H)=–13.9424+6303.73/T) and pyruvic acid (ln(K H)=–4.41706+5087.92/T). The influence of 9 salts on the solubility of pyruvic acid at 298.15 K has been measured. Pyruvic acid is soluble enough to partition strongly into aqueous atmospheric aerosols. Other acids require around 1 g of liquid water m–3 (typical of clouds) to partition significantly into the aqueous phase. The degree of partitioning is sensitive to temperature. Considering solubility and dissociation (to formate) alone, the ratio of formic acid to acetic acid in liquid water in the atmosphere (at equilibrium with the gas phase acids) is expected to increase with rising pH, but show little variation with temperature.  相似文献   

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