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1.
We analyzed pollen, non-pollen palynomorphs (NPPs), calcareous microfossils, plant macrofossils, diatoms, chrysophyte cysts, opal phytoliths and organic matter content in a 123-cm sediment sequence from Nahuel Rucá Lake, a shallow, freshwater system in the southeastern Pampa grasslands, Argentina. Three stages in the lake evolution were identified. Before 3,680 cal year BP, only pollen, NPPs (dinoflagellate cysts and acritarchs) and ostracods were recovered, suggesting brackish/saline conditions in the lake and nearby areas. Freshwater conditions are, however, indicated by Myriophyllum, Pediastrum and Zygnemataceae. The brackish/saline conditions could have been caused by marine influence during a Holocene sea level high stand that affected the area ca. 6,000 year BP. Between 3,680 and 390 cal year BP, macrophyte pollen and plant macrofossils indicate increasingly freshwater conditions in the lake and the adjacent area. Diatom and ostracod assemblages, however, suggest brackish and oligotrophic conditions, giving way to freshwater and meso-eutrophic conditions toward the end of this period. The relationship between submersed macrophytes (Myriophyllum, Potamogeton, Ceratophyllum, Chara) and planktonic algae (Chlorophyta and diatoms), suggests a shift in the lake from a clear to a turbid state. This turbid state is more evident after 390 cal year BP. High values of Pediastrum, Scenedesmus and diatoms (Cyclotella meneghiniana, Aulacoseira granulata, A. muzzanensis) observed during this stage could have reduced light penetration, with consequent loss of submersed plants. Pollen and plant macrofossils in the uppermost 20 cm indicate a shallow, freshwater lake similar to present, though an increase in brackish/freshwater diatoms suggests an increase in salinity, perhaps related to periodic droughts. Opal phytoliths yield a regional paleoclimatic reconstruction that agrees closely with inferences made using pollen, mammals and sediment characteristics.  相似文献   

2.
Data derived from monthly sediment traps in Sihailongwan, a maar lake in northeastern China, yielded a detailed record of seasonal sediment fluxes. Sediment fluxes correspond to seasonal climatic variations. The diatom flux shows two distinct peaks in September and November, whereas the flux of chrysophyte stomatocysts shows a maximum in May. The blooms of diatoms may be related to the subsequent deepening of the thermocline in September and lake overturn in spring and November, and influx of nutrient-rich groundwater sometime after the onset of the summer monsoon. The fluxes of organic matter and siliciclastics show a distinct seasonal pattern. They are varying between 0.03 and 0.56 g m−2 d−1 and reach a maximum in May. Quartz in the trap samples indicates that the siliciclastic matter may originate from distant aeolian sources. Sediment trap data and thin section investigations confirm the seasonality of Lake Sihailongwan sediments. Dark-colored layer, which mainly consists of valves of Cyclotella comta, might be deposited during autumn, and then is followed by a light-colored mixed layer starting with siliciclastics deposited after ice-out. The varved sediments in the U-shaped Lake Sihailongwan represent a sensitive siliciclastic and geochemical archive of paleoenvironmental variability in this data-sparse area. Detailed investigations of varved sediments should provide decadal to annual records of seasonal sediment flux and its relation to climatic parameters. Especially the diatomaceous layer is regarded to indicate summer climatic fluctuations, while the thick siliciclastic layer could be an indictor of dust events.  相似文献   

3.
A combination of biotic, sedimentary and biogeochemical proxies was used to investigate the timing and causes of post-18th century changes in the stratigraphic record of a large, deep lake on the Boothia Peninsula, Nunavut, Canada (70°15′ N, 94°30′ W). A varve chronology verified with radioisotopic dating (210Pb and 137Cs) revealed a complex pattern of environmental dynamics since c. AD 1830. An increase in the diatoms Asterionella formosa, Stephanodiscus minutulus and Cyclotella atomus and a decrease in Aulacoseira taxa in the uppermost centimetre of sediment suggested that environmental conditions have favoured the growth of smaller and/or lighter planktonic species since the 1980s. Longer term changes in some benthic species, the chrysophyte cysts to diatom valve ratio, %C, and C/N ratios suggest declined river inflow and a relative reduction in allochthonous inputs during the last century. Higher than average δ15N values in the late 19th to early 20th centuries coincide with changes in bulk carbon and nitrogen profiles, and below average values since approximately 1950 may be associated with increased atmospheric N loading or reduced productivity. Biogenic silica and organic carbon accumulation in the sediments suggest a possible decline in lake production during the 20th century that may be associated with changes in the river discharge regime. The short and long-term ecological and biogeochemical trends were also reflected in the sedimentary structure through declining varve thickness for the duration of the record and an abrupt change in sedimentology in the uppermost 1 cm, coinciding with deposition since ca. AD 1987. Together, these biological and physical changes suggest changes in hydroclimatic conditions in the 20th century, and an increase in planktonic diatom taxa since the 1980s that coincides with a distinct period of climate warming.  相似文献   

4.
Frozen sediment cores from Lake Pupuke in Auckland City, New Zealand, contain a high resolution decadal to annual scale record of changing lake paleoenvironments and geochemistry that reflects changing landuse and hydrology in the catchment over the past c. 190 years. A reliable chronology is available from AMS 14C and 210Pb dating of the sediments, with the timing of the older part of the record supported by the first appearance of pollen of introduced Pinus and Plantago lanceolata associated with European settlement of Auckland in the early 1840s. Diatom stratigraphy, sediment elemental and carbon isotope geochemistry reflect changes in sediment sources and lake conditions commensurate with European development of the Lake Pupuke catchment, in particular enhanced algal productivity controlled by the influx of nutrients after c. 1920 AD. Attempts to prevent nuisance algal blooms in 1933, 1934 and 1939 using CuSO4 addition produced Cu spikes in the sediment that allowed confirmation of the accuracy of the 210Pb chronology. Hence, the elemental and isotopic composition of the Lake Pupuke sediments reflect the timing of significant anthropogenic activities, rather than climatic variations, that have occurred within the watershed over the past c. 190 years. The comparison of records of land use change in the catchment with the multi-proxy record of changes in the sediments usually allowed unambiguous identification of the signatures of change and their causes.  相似文献   

5.
A multiple core study was conducted on laminated minerogenic sediments from Lake C2, Northern Ellesmere Island, Canadian High Arctic. Lateral persistence, distal thinning, variation in grain size of these laminations as well as present-day processes of highly seasonal sediment transfer into the lake basin suggest that clastic varves have been formed. Sedimentation rates based on 210Pb dating agree well with sedimentation rates based on lamination counts giving further evidence that laminations are annual. Errors in varve counting were reduced from 12% to < 2% using the multi-core approach of cross-correlating all records. Varved sediments are occasionally interrupted by thick coarse-grained layers, which are interpreted as deposits of turbidity currents and may be related to extremely high discharge events and slope failures of the delta front. Micro-laminated sediments spanning the last two centuries were studied in detail. Suspension settling is the dominant process of deposition depending upon stream discharge which is controlled by nival melt and summer temperatures. Application of varve chronology thus allows to use lamination thickness measurements as source of high resolution proxy data for palaeoclimatic reconstruction.This is the fifth in a series of papers published in this issue on the Taconite Inlet Lakes Project. These papers were collected by Dr R. S. Bradley.  相似文献   

6.
Chrysophycean stomatocysts were identified and enumerated from the surface sediments of 60 lakes located on the Interior Plateau of British Columbia. The lakes span a salinity gradient from freshwater to hypersaline (0.0–92.4 g L–1), with the majority being fresh to hyposaline. One hundred and ten stomatocyst morphotypes, almost all of which were previously described, were identified from the lake sediments. The first axis of direct gradient analysis, which was highly significant, was essentially a salinity axis (i.e. [Ca], [Mg], [K], [Na], [SO4], [DIC], and [Cl]). Most cysts were found to have fairly broad tolerances, with the narrowest tolerances occurring among morphotypes with the lowest salinity optima. Weighted-averaging regression and calibration techniques were used to develop an inference model to measure the relationship between measured average lakewater salinity and stomatocyst inferred salinity (apparent r2=0.80). Simple weighted-averaging produced a model with a lower bootstrapped RMSE of prediction than weighted-averaging with tolerance downweighting. These data indicate that chrysophyte stomatocysts are useful quantitative indicators of past lakewater salinity (in the freshwater to hyposaline range) in B.C. lakes, and can be used to strengthen the interpretations from diatom-inference models already developed from the same region.  相似文献   

7.
Biomonitoring past salinity changes in an athalassic subarctic lake   总被引：1，自引：0，他引：1  
A short sediment core was taken from a small saline lake located on an intermontane plateau in the central Yukon Territory, Canada. In July 1990, chemical analyses indicated that, although the lake was shallow (Zmax=1.1 m), it was also chemically stratified, with hyposaline (9.9 to 10.0 g L−1) surface waters and slightly mesosaline (22.0 g L−1) deeper waters. The surface water was dominated by Na+ and HCO 3 − . To our knowledge, this is the northernmost athalassic saline lake yet recorded. Quantification of algal (diatom, chrysophyte, and pigment) and invertebrate (chironomid, ceratopogonid, andChaoborus) fossils at four stratigraphic levels indicated that the lake sediments preserved numerous biological indicators that could be used to infer recent lake development. Many of the taxa are found in other athalassic salt lakes. The most striking stratigraphic change was a remarkable drop in the species richness of diatoms and invertebrates in the recent sediments, which parallels the elimination of species characteristic of less saline conditions. Halophilous taxa dominate the most recent sediments, indicating the development of more saline conditions. At the same time, a significant shift in chrysophyte cyst composition was observed. Fossil carotenoids and chlorophylls indicated a decrease in total algal abundance in recent sediments, as green and blue-green algae replaced diatoms and chrysophytes. Together, these paleolimnological data suggest a recent shift to drier conditions or increased evaporation in the central Yukon Territory.  相似文献   

8.
Chrysophyte cysts and scales and sponge spicules were enumerated, along with diatoms, from the surface sediments of 102 western Canadian lakes. The salinities of these lakes ranged from 0.042 to 369 g L−1 in late summer. Sponge spicules and chrysophyte cysts and scales were more common in fresher waters, although chrysophyte cysts were also present in subsaline and hyposaline waters at lower relative percentages. These siliceous microfossils can easily be distinguished and counted along with diatom valves, with little extra effort. It is likely that using these additional indicators will strengthen paleolimnological inferences of past lakewater salinity.  相似文献   

9.
Sedimentological climate proxies and a 200-year long climate record, reconstructed using a data-set of European-wide meteorological data, have been compared at the high mountain lake Niné Terianske pleso in the High Tatras, Slovakia. Diatoms, chrysophyte stomatocysts, chironomids, plant pigments and spheroidal carbonaceous particles (SCPs) were analysed as well as sediment lithostratigraphic parameters. Using a radiometric approach the sediment core was dated and a depth of 4.6 cm was found to correspond to 1852 AD. The sediment accumulation rate (0.0034 g·cm–2·yr–1) was one of the lowest identified in the European mountain lake project, MOLAR. Despite this slow accumulation rate a remarkably coherent lithological and stratigraphic record has been recovered. The sediments of this remote mountain site, largely free from the effects of direct human impact, have been found to display a wealth of variability over the last 200 years.The record of spheroidal carbonaceous particles, indicators of anthropogenic pollution deposition, begins around 4.5–5.0 cm in depth (1833–1857). Temporal patterns are typical of European lake sites with the concentration peaking in the late 1970's. The SCP/210Pb inventory ratio for the site is also in good agreement with the European latitudinal pattern. A strong influence of sample age on the chrysophyte assemblage composition in the upper-most 4–6 cm indicates that the main changes in the cysts have been related to long term environmental changes, probably pH. Analysis of chironomid remains revealed a stable profundal community. Chironomids as a whole showed no correlations to temperature fluctuations in the last 200 years. Relatively abundant remains of Diamesa sp. head capsules and other taxa closely associated with stream conditions in the older layers contrast with the absence of Diamesa sp. in the recent sediments. This change is considered to be evidence for the existence of a stronger, more stable inlet supplied from permanent granular snow fields in the lake basin. The most important changes in diatom assemblages were observed at 3cm. Many species of the genus Achnanthes spp. together with Navicula schmassmannii and Orthoseira roeseana made up the greatest part of the diatom community above 3 cm, being absent or rare lower in the record. A positive correlation between diatoms and mean summer temperature was found.  相似文献   

10.
We measured variability in the composition of diatom and chrysophyte assemblages, and the pH inferred from these assemblages, in sediment samples from Big Moose Lake, in the Adirondack Mountains of New York. Replicate samples were analyzed from (1) a single sediment core interval, (2) 12 different intervals from each of 3 separate cores, and (3) 10 widely spaced surface sediment samples (0–1 cm). The variability associated with sample preparation (subsampling, processing, and counting) was relatively small compared to between-core and within-lake variability. The relative abundances of the dominant diatom taxa varied to a greater extent than those of the chrysophyte scale assemblages. Standard deviations of pH inferences for multiple counts from the same sediment interval from diatom, chrysophyte, and diatom plus chrysophyte inference equations were 0.04 (n=8), 0.06 (n=32), and 0.06 (n=8) of a pH unit, respectively. Stratigraphic analysis of diatoms and chrysophytes from three widely spaced pelagic sediment cores provided a similar record of lake acidification trends, although with slight differences in temporal rates of change. Average standard deviations of pH inferences from diatom, chrysophyte and diatom plus chrysophyte inference equations for eight sediment intervals representing similar time periods but in different cores were 0.10, 0.20, and 0.09 pH unit, respectively. Our data support the assumption that a single sediment core can provide an accurate representation of historical change in a lake. The major sources of diatom variability in the surface sediments (i.e., top 1.0 cm) were (1) differences in diatom assemblage contributions from benthic and littoral sources, and (2) the rapid change in assemblage composition with sediment depth, which is characteristic of recently acidified lakes. Because scaled chrysophytes are exclusively planktonic, their spatial distribution in lake sediments is less variable than the diatom assemblages. Standard deviations of pH inferences for 10 widely spaced surface sediment samples from diatom, chrysophyte and diatom plus chrysophyte inference equations were 0.21, 0.09, and 0.16 of a pH unit, respectively.  相似文献   

11.
The sedimentary record from Lake Baikal (Siberia, Russia) has been an important source of information about paleoclimatic variability in the northern hemisphere and dynamics of continental rift development. A lack of reliable chronology has, however, been a major obstacle to fully utilizing the Baikal archive for time scales beyond about 4-5 Myr. In this paper we use the distribution of 10Be to establish a new chronology for the longest core drilled in Lake Baikal so far. The 10Be-based chronology spans the last 8 Myr and provides better constraints on sedimentation rates and consequently on an east-west tectonic extension in the lake, which has been apparently coeval with other rifts in Asia that are related to the Tibetan plateau uplift. Our data also show higher 10Be flux in the sediment section older then 5 Myr compared with the younger period. This can be explained partly by warm and humid climatic conditions of the Miocene and partly by a high cosmic ray flux to the Earth resulting from possible low geomagnetic field intensity during that time.  相似文献   

12.
Lake Naivasha, Kenya, is one of a number of freshwater lakes in the East African Rift System. Since the beginning of the twentieth century, it has experienced greater anthropogenic influence as a result of increasingly intensive farming of coffee, tea, flowers, and other horticultural crops within its catchment. The water-level history of Lake Naivasha over the past 200 years was derived from a combination of instrumental records and sediment data. In this study, we analysed diatoms in a lake sediment core to infer past lacustrine conductivity and total phosphorus concentrations. We also measured total nitrogen and carbon concentrations in the sediments. Core chronology was established by 210Pb dating and covered a ~186-year history of natural (climatic) and human-induced environmental changes. Three stratigraphic zones in the core were identified using diatom assemblages. There was a change from littoral/epiphytic diatoms such as Gomphonema gracile and Cymbella muelleri, which occurred during a prolonged dry period from ca. 1820 to 1896 AD, through a transition period, to the present planktonic Aulacoseira sp. that favors nutrient-rich waters. This marked change in the diatom assemblage was caused by climate change, and later a strong anthropogenic overprint on the lake system. Increases in sediment accumulation rates since 1928, from 0.01 to 0.08 g cm−2 year−1 correlate with an increase in diatom-inferred total phosphorus concentrations since the beginning of the twentieth century. The increase in phosphorus accumulation suggests increasing eutrophication of freshwater Lake Naivasha. This study identified two major periods in the lake’s history: (1) the period from 1820 to 1950 AD, during which the lake was affected mainly by natural climate variations, and (2) the period since 1950, during which the effects of anthropogenic activity overprinted those of natural climate variation.  相似文献   

13.
In order to assess the recent anthropogenic environmental changes in Lake Kitaura, central Japan, changes during the past few centuries were reconstructed from results of radiometric and tephrochlonological age determination, magnetic susceptibility measurements, total organic carbon analyses, total nitrogen analyses and fossil diatom analyses on a sediment core from the lake. A total of six major and sub-zones are recognized according to the diatom fossil assemblages, and we discuss aquatic environmental change in Lake Kitaura mainly based on these diatom assemblage change. Zone Ia and Zone Ib (older than AD 1707) are marine to brackish. In Zone IIa (AD␣1707–AD 1836), most of the brackish diatoms disappeared, and were replaced by freshwater species indicating a decrease in salinity. We interpret the salinity decrease in Zone I–IIa as a sea-level fall during the Little Ice Age. The salinity of the lake decreased to near freshwater conditions in Zone IIb (AD 1836–AD 1970), which could arise from alteration in River Tone or development of a sandspit in the mouth of River Tone in addition to sea-level change. In Zone IIIa (AD 1970–AD 1987), the diatom assemblage indicates a freshwater environment, and sedimentation rates increase rapidly. These changes reflect sedimentary environment change and an ecosystem transition due to the construction of the tide gate. In Zone IIIb (AD 1987–AD 2002), the diatom flux (valves cm−2 y−1) increased and species composition changed. The changes in Zone IIIb show a good agreement with limnological monitoring data gathered from the lake. These paleolimnological data suggest that the recent human-induced changes of the aquatic environment of the lake after the 1970s exceed rates during the period concerned in this study.  相似文献   

14.
This paper documents the discovery of peridinioid organic walled dinoflagellate cysts in Holocene sediments of the freshwater, low-alkalinity, high mountain Lake Nero di Cornisello (Adamello mountain range, Trentino, Italy). Among the three main cyst morphotypes found in the samples, the dominant one is acavate, with a smooth and light brown colored wall, with a clear conical shape, elongated with a pointy to rounded end in the antapical-ventral part, with the epicyst broader than the hypocyst and displays a typical peridinioid archeopyle. Comparison with data available in literature, besides pointing out the general scarcity of observations on dinocysts in lakes sediments, suggested a strong morphological similarity with the marine genus Brigantedinium. This finding pinpoints the need for more detailed studies on cysts in freshwater environments offering a new tool for paleoenvironmental interpretations.  相似文献   

15.
Glacial landscapes of the Land of Great Masurian Lakes and Suwa?ki Lakelands in northeast Poland are characterized by very high abundance of lakes. These two areas were surveyed for lakes containing laminated sediments. Using bathymetry as a criterion, 60 small, deep lakes, representing preferred conditions for formation and preservation of lacustrine non-glacial varves, were selected for gravity coring. We found laminated sediments in 24 of the lakes, 15 in the Land of Great Masurian Lakes and 9 in the Suwa?ki Lakeland. Seven of these 24 sediment records were laminated in the topmost part only. Analysis of lake morphometric variables showed that the relation between surface area and maximum water depth can be used to identify lakes with laminated sediments. Most of the newly discovered lakes with laminated deposits have surface areas ≤0.3 km2 and maximum depths of 15–35 m. Multivariate statistical analysis (Linear Discriminant Analysis) of the lake dataset identified the morphological features of lake basins and their catchments that largely control preservation of laminated sediments. Microscopic and geochemical analyses revealed a biogenic (carbonaceous) type of lamination typical for lakes in northeast Poland. Such lakes are characterized by a spring-summer lamina that is rich in calcium carbonate and an autumn-winter lamina composed of organic and minerogenic detritus. This pattern may be modified by multiple periods of calcite deposition during a single year or substantial contribution of clastic material. Laminations and high sedimentation rates offer the possibility of high-resolution investigation of past climate and environmental changes through application of myriad biological, isotopic and geochemical proxies.  相似文献   

16.
Chrysophyte scales were identified and enumerated from the recent sediments of Fonda Lake, Michigan. This lake has undergone marked salinification due to chloride intrusion from an adjacent salt-storage facility established in 1953. From 1950 to 1980, Mallomonas caudata dominated at all levels; this taxon appears to be chloride-indifferent. M. elongata and M. pseudocoronata appeared to be chloride-intolerant as they declined drastically in abundance when chloride levels attained a maximum (ca. 1968–1972). M. tonsurata, on the other hand, was more competitive during this period of maximum [Cl\s-]. This preliminary study suggests that chrysophyte scales may be useful paleoindicators of salinity.  相似文献   

17.
Zeekoevlei is the largest freshwater lake in South Africa and has a century-long history of anthropogenic impact that caused hyper-eutrophic conditions. We used biomarkers (alkanes and pigments), stable isotopes (δ13C and δ15N), rates of primary palaeoproduction and total inorganic carbon (TIC) accumulation rates in the lake sediments to investigate changes in plankton and macrophyte communities in response to anthropogenic activities in this shallow lake. Specific alkanes (ΣC15,17,19, pristane, phytane and n-C29/n-C17 ratio) and pigment (chlorophyll a, β,β-carotene, echinenone, fucoxanthin and zeaxanthin) concentrations in lake waters indicated the present-day hyper-eutrophic condition and seasonal fluctuations of cyanobacteria, zooplankton and diatom populations. Eutrophic conditions were initiated in the lake with the start of recreational activities and construction of a sewage treatment plant in the early 1920s. The lake transformed from a eutrophic to a hyper-eutrophic waterbody following damming, pondweed eradication and accelerated catchment-derived nutrient input. The change in lake trophic state was recorded by a sharp decline in the terrestrial to aquatic ratio (TAR) of specific n-alkanes, low carbon preference index (CPI) and increased δ13C values in the sediment core. In addition, the aquatic macrophyte n-alkane proxy (Paq) values (~1) indicated a slow takeover by floating macrophytes after the eradication of submerged pondweeds in 1951. Elevated n-alkane (ΣC15,17,19), total alkane and pigment (chlorophyll a, β,β-carotene, zeaxanthin and zeaxanthin to β,β-carotene ratio) concentrations, low δ15N values and low TIC accumulation rates in the upper middle section of the core indicated the beginning of intense cyanobacterial blooms after the dredging in 1983. Although the cyanobacterial population has decreased in recent years, hyper-eutrophic conditions are reflected by low CPI <0.04 and TAR <1 values at the top of the sediment core.  相似文献   

18.
Chrysophycean stomatocyst assemblages were analysed from the sediments of 17 lakes and ponds from Svalbard as one component of a multi-proxy investigation of recent environmental change in the high Arctic. Sediment cores and water chemistry were collected from each of the study lakes, and chrysophyte stomatocysts were investigated from the top 0.25 cm of sediment (present-day) and bottom (i.e., bottom of short sediment core, pre-industrial) sediment samples. This study represents the first undertaking of chrysophyte cyst morphology and distribution on Svalbard. A total of 153 cyst morphotypes were described with light microscopy and/or scanning electron microscopy, of which 21 are new forms. Canonical correspondence analysis indicates that the present-day distribution of cysts is significantly related to pH (p= 0.02), altitude (p= 0.02), and Na+ (p= 0.04). Marked shifts in chrysophyte cyst assemblages were recorded between the top and bottom sediment samples of most lakes. A recent study has demonstrated that Svalbard lakes receive atmospheric contaminants from both local and remote sources. The observed assemblage shifts may be the result of the combined effects of these point sources and long-range pollutants, or the effects of recent climate change, or both.  相似文献   

19.
Most 210Pb dating models assume that atmospheric flux of excess 210Pb (210Pbexc) to the sediment–water interface remains constant over time. We revisited this assumption using statistical analysis of a database of laminated sediments and evaluated the implications for radiometric dating of recent deposits. A bibliographic survey enabled us to create a database with 10 annually laminated sediment cores from a variety of aquatic systems. The database has records of 210Pbexc flux, initial 210Pbexc activity, and sediment accumulation rate (SAR). 210Pbexc flux to sediments varied with time, and 1/3 of the data had relative deviations from the mean value >25 %. There was no statistically significant correlation between activities at the core top and SAR, whereas a statistically significant (p < 0.01) linear regression between 210Pbexc flux and SAR was found for nine of the ten cores. Thus, in most of the studied aquatic systems, 210Pbexc flux to the sediment was governed primarily by flux of matter, rather than by direct atmospheric 210Pbexc deposition. Errors in chronology and SAR, attributable to varying 210Pbexc flux and estimated by the constant rate of supply (CRS) model, were evaluated from its analytical solutions, and tested against SAR values from this database that were derived independently from varves. We identified several constraints for general application of the CRS model, which must be taken into account to avoid its misuse.  相似文献   

20.
An 11.6 m long continuous succession of annually laminated sediments from Lake Korttajärvi in central Finland was investigated for the isotopic composition of carbon and hydrogen in organic matter. The sequence covers a time period of 9590 years, and the varve chronology has been thoroughly described in earlier studies. From 7100 to 4400 BC the lake was part of the Ancient Lake Päijänne, but in 4400 BC it became separated and formed the present independent lake system. Two organic fractions were investigated. One fraction obtained by HCl-treatment was analyzed for δ13C and another HCl-HF-digested organic fraction was analyzed for both δ13C and δD. The isotopic data were compared to atomic C/N ratios, carbon contents, diatom-inferred pH values and other environmental parameters. The diatom-inferred pH values and organic carbon contents provide evidence for a long-term change towards more acidic conditions and lower productivity in Lake Korttajärvi. The inferred pH values decrease from 7.0 to 6.1, followed by a slight increase during the last millennia. Variations in pH are accompanied by an increase in the δ13CHCl-HF values of organic matter from ?31.6 to $-29.2\permilleAn 11.6 m long continuous succession of annually laminated sediments from Lake Korttaj?rvi in central Finland was investigated for the isotopic composition of carbon and hydrogen in organic matter. The sequence covers a time period of 9590 years, and the varve chronology has been thoroughly described in earlier studies. From 7100 to 4400 BC the lake was part of the Ancient Lake P?ij?nne, but in 4400 BC it became separated and formed the present independent lake system. Two organic fractions were investigated. One fraction obtained by HCl-treatment was analyzed for δ13C and another HCl-HF-digested organic fraction was analyzed for both δ13C and δD. The isotopic data were compared to atomic C/N ratios, carbon contents, diatom-inferred pH values and other environmental parameters. The diatom-inferred pH values and organic carbon contents provide evidence for a long-term change towards more acidic conditions and lower productivity in Lake Korttaj?rvi. The inferred pH values decrease from 7.0 to 6.1, followed by a slight increase during the last millennia. Variations in pH are accompanied by an increase in the δ13CHCl-HF values of organic matter from −31.6 to , followed by a subtle decrease to . The changes in pH and δ13CHCl-HF are closely related (r = − 0.91, P < 0.01), and apparently reflect changing environmental conditions in the lake and in its catchment area. δD values show a marked shift to higher values during the early Holocene, which may be partly related to a climatic amelioration leading to the Holocene Climatic Optimum in 6000–2500 BC. The Medieval Warm Period in AD 980–1250 is associated with a local maximum in δD, lending support for a significant warming during that time.  相似文献   

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