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1.
Major and trace element and isotopic ratios (Sr, Nd and Pb) are presented for mafic lavas (MgO > 4 wt%) from the southwestern Yabello region (southern Ethiopia) in the vicinity of the East African Rift System (EARS). New K/Ar dating results confirm three magmatic periods of activity in the region: (1) Miocene (12.3–10.5 Ma) alkali basalts and hawaiites, (2) Pliocene (4.7–3.6 Ma) tholeiitic basalts, and (3) Recent (1.9–0.3 Ma) basanite-dominant alkaline lavas. Trace element and isotopic characteristics of the Miocene and Quaternary lavas bear a close similarity to ocean island basalts that derived from HIMU-type sublithospheric source. The Pliocene basalts have higher Ba/Nb, La/Nb, Zr/Nb and 87Sr/86Sr (0.70395–0.70417) and less radiogenic Pb isotopic ratios (206Pb/204Pb = 18.12–18.27) relative to the Miocene and Quaternary lavas, indicative of significant contribution from enriched subcontinental lithospheric mantle in their sources. Intermittent upwelling of hot mantle plume in at least two cycles can explain the magmatic evolution in the southern Ethiopian region. Although plumes have been originated from a common and deeper superplume extending from the core–mantle boundary, the diversity of plume components during the Miocene and Quaternary reflects heterogeneity of secondary plumes at shallower levels connected to the African superplume, which have evolved to more homogeneous source.  相似文献   

2.
The Pleistocene Incapillo Caldera and Dome Complex (5,570 m) marks the southernmost siliceous center of the Andean Central Volcanic Zone (~28°S), where the steeply dipping (~30°) segment of the subducting Nazca plate transitions into the Chilean “flatslab” to the south. The eruption of the Incapillo Caldera and Dome Complex began with a 3–1 Ma effusive phase characterized by ~40 rhyodacitic dome eruptions. This effusive phase was terminated by an explosive “caldera-forming” event at 0.51 Ma that produced the 14 km3 Incapillo ignimbrite. Distinctive and virtually identical chemical signatures of the domes and ignimbrites (SiO2 = 67–72 wt%; La/Yb = 37–56; Ba/La = 16–28; La/Ta = 30–50; 87Sr/86Sr = 0.70638–0.70669; ε Nd = −4.2 to −4.6) indicate that all erupted lavas originated from the same magma chamber and that differentiation effects between units were minor. The strong HREE depletion (Sm/Yb = 6–8) that distinguishes Incapillo magmas from most of the large ignimbrites of the Altiplano–Puna plateau can be explained by the extent and degree of partial melting at lower crustal depths (>40 km) in the presence of garnet. At upper crustal depths, this high-pressure residual geochemical signature, also common to adjacent late Miocene/Pliocene Pircas Negras andesites, was partially overprinted by shallow-level assimilation and fractional crystallization processes. Energy-constrained AFC modeling suggests that incorporation of anatectic upper crustal melts into a fractionated “adakite-like” dacitic host best explains the petrogenesis of Incapillo magmas. The diminution of the sub-arc asthenospheric wedge during Nazca plate shallowing left the Incapillo magma chamber unreplenished by both mafic mantle-derived and lower crustal melts and thus stranded at shallow depths within the Andean crust. Based on its small size and distinctive high-pressure chemical signature, the Incapillo Caldera and Dome Complex provides an endmember model for an Andean caldera erupting within a waning magmatic arc over a shallowing subduction zone.  相似文献   

3.
The subaerial portion of Gran Canaria, Canary Islands, was builtby three cycles of volcanism: a Miocene Cycle (8•5–15Ma), a Pliocene Cycle (1•8–6•0 Ma), and a QuaternaryCycle (1•8–0 Ma). Only the Pliocene Cycle is completelyexposed on Gran Canaria; the early stages of the Miocene Cycleare submarine and the Quaternary Cycle is still in its initialstages. During the Miocene, SiO2 saturation of the mafic volcanicsdecreased systematically from tholeiite to nephelinite. Forthe Pliocene Cycle, SiO2 saturation increased and then decreasedwith decreasing age from nephelinite to tholeiite to nephelinite.SiO2 saturation increased from nephelinite to basanite and alkalibasalt during the Quaternary. In each of these cycles, increasingmelt production rates, SiO2 saturation, and concentrations ofcompatible elements, and decreasing concentrations of some incompatibleelements are consistent with increasing degrees of partial meltingin the sequence melilite nephelinite to tholeiite. The maficvolcanics from all three cycles were derived from CO2-rich garnetlherzolite sources. Phlogopite, ilmenite, sulfide, and a phasewith high partition coefficients for the light rare earth elements(LREE), U, Th, Pb, Nb, and Zr, possibly zircon, were residualduring melting to form the Miocene nephelinites through tholeiites;phlogopite, ilmenite, and sulfide were residual in the sourceof the Pliocene–Quaternary nephelinites through alkalibasalts. Highly incompatible element ratios (e.g., Nb/U, Pb/Ce,K/U, Nb/Pb, Ba/Rb, Zr/Hf, La/Nb, Ba/Th, Rb/Nb, K/Nb, Zr/Nb,Th/Nb, Th/La, and Ba/La) exhibit extreme variations (in manycases larger than those reported for all other ocean islandbasalts), but these ratios correlate well with degree of melting.Survival of residual phases at higher degrees of melting duringthe Miocene Cycle and differences between major and trace elementconcentrations and melt production rates between the Mioceneand Pliocene tholeiites suggest that the Miocene source wasmore fertile than the Pliocene–Quaternary source(s). We propose a blob model to explain the multi-cycle evolutionof Canary volcanoes and the temporal variations in chemistryand melt production within cycles. Each cycle of volcanism representsdecompression melting of a discrete blob of plume material.Small-degree nephelinitic and basanitic melts are derived fromthe cooler margins of the blobs, whereas the larger-degree tholeiiticand alkali basaltic melts are derived from the hotter centersof the blobs. The symmetrical sequence of mafic volcanism fora cycle, from highly undersaturated to saturated to highly undersaturatedcompositions, reflects melting of the blob during its ascentbeneath an island in the sequence upper margin-corelower margin.Volcanic hiatuses between cycles and within cycles representperiods when residual blob or cooler entrained shallow mantlematerial fill the melting zone beneath an island.  相似文献   

4.
Pre-collisional Eocene–Oligocene arc diorites, quartzdiorites, granodiorites, and volcanic equivalents in the Kerman arc segment in central Iran lack porphyry Cu mineralization and ore deposits, whereas collisional middle-late Miocene adakite-like porphyritic granodiorites without volcanic equivalents host some of the world’s largest Cu ore deposits. Petrological and structural constraints suggest a direct link between orogenic arc crust evolution and the presence of a fertile metallogenic environment. Ore-hosting Kuh Panj porphyry intrusions exhibit high Sr (>400 ppm), low Y (<12 ppm) contents, significant REE fractionation (La/Yb > 20), no negative Eu anomalies (Eu/Eu* ≥ 1), and relatively non-radiogenic Sr isotope signatures (87Sr/86Sr = 0.7042–0.7047), relative to Eocene–Oligocene granitoids (mainly Sr < 400 ppm; Y > 12; La/Yb < 15; Eu/Eu* < 1; 87Sr/86Sr = 0.7053–0.7068). Trace element modeling indicates peridotite melting for the barren Eocene–Oligocene intrusions and a hydrous garnet-bearing amphibolite source for middle-late Miocene ore-hosting intrusions. The presence of garnet implies collisional arc crustal thickening by shortening and basaltic underplating from about 30–35 to 40–45 km or 12 kbar. The changes in residual mineralogy in the source of Eocene to Miocene rocks in the Kerman arc segment reflect probing of a thickening arc crust by recycling melting of the arc crustal keel. Underplating of Cu and sulfur-rich melts from fertile peridotite generated a fertile metallogenic reservoir at or near the crust–mantle boundary, and dehydration melting under oxidizing conditions produced syn- and post-collisional ore-hosting intrusions, while the lack of post-collisional volcanism prevented the venting of volatiles to the atmosphere from sulfur-rich and oxidized adakitic magmas. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

5.
Miocene Intrusives and Lower Cretaceous siliciclastic sedimentary rocks from the Basal Complex in western-Fuerteventura were analyzed with low-temperature thermochronometric methods such as fission-track, and (U–Th–Sm)/He dating, in order to reveal the evolution of the island’s exhumation history. The obtained thermochronometric data yields a very slow rate of cooling in the order of 1.5–3°C/Myr from ~50 to 20 Ma for the Early Cretaceous siliciclastic rocks. These sedimentary units have never been heated significantly above 240°C after deposition and still record the submarine onset of the island’s formation in the Eocene. Intrusive bodies associated with the early Miocene magmatic activity of the central volcanic complex of the island show rapid initial cooling rates of 50–70°C/Myr from ~20 to 14 Ma. Contemporaneous with the intrusions the cooling rate of the Cretaceous sedimentary units increased to 25–35°C/Myr and it is inferred that this increase is associated with enhanced uplift and erosion of the Central Volcanic Complex. After ~14 Ma rates slowed down to 3–6°C/Myr. Palaeosols overlying the sedimentary units are themselves covered by Pliocene basalt flows and reveal that the sedimentary rocks reached the surface before ~5 Ma. The thermochronometric data obtained in this study for central Fuerteventura is difficult to reconcile with the cooling history derived from previously obtained fission-track and K–Ar data from the north-western part of the island. This inconsistency is likely to indicate that the exhumation history of Fuerteventura is more complex and regionally subdivided than previously believed.  相似文献   

6.
The composite Meghri–Ordubad and Bargushat plutons of the Zangezur–Ordubad region in the southernmost Lesser Caucasus consist of successive Eocene to Pliocene magmatic pulses, and host two stages of porphyry Cu–Mo deposits. New high-precision TIMS U–Pb zircon ages confirm the magmatic sequence recognized by previous Rb–Sr isochron and whole-rock K–Ar dating. A 44.03 ± 0.02 Ma-old granite and a 48.99 ± 0.07 Ma-old granodiorite belong to an initial Eocene magmatic pulse, which is coeval with the first stage of porphyry Cu–Mo formation at Agarak, Hanqasar, Aygedzor and Dastakert. A subsequent Oligocene magmatic pulse was constrained by U–Pb zircon ages at 31.82 ± 0.02 Ma and 33.49 ± 0.02 Ma for a monzonite and a gabbro, and a late Miocene porphyritic granodioritic and granitic pulse yielded ages between 22.46 ± 0.02 Ma and 22.22 ± 0.01 Ma, respectively. The Oligo-Miocene magmatic evolution broadly coincides with the second porphyry-Cu–Mo ore deposit stage, including the major Kadjaran deposit at 26–27 Ma.Primitive mantle-normalized spider diagrams with negative Nb, Ta and Ti anomalies support a subduction-like nature for all Cenozoic magmatic rocks. Eocene magmatic rocks have a normal arc, calc-alkaline to high-K calc-alkaline composition, early Oligocene magmatic rocks a high-K calc-alkaline to shoshonitic composition, and late Oligocene to Mio-Pliocene rocks are adakitic and have a calc-alkaline to high-K calc-alkaline composition. Radiogenic isotopes reveal a mantle-dominated magmatic source, with the mantle component becoming more predominant during the Neogene. Trace element ratio and concentration patterns (Dy/Yb, Sr/Y, La/Yb, Eu/Eu*, Y contents) correlate with the age of the magmatic rocks. They reveal combined amphibole and plagioclase fractionation during the Eocene and the early Oligocene, and amphibole fractionation in the absence of plagioclase during the late Oligocene and the Mio-Pliocene, consistent with Eocene to Pliocene progressive thickening of the crust or increasing pressure of magma differentiation. Characteristic trace element and isotope systematics (Ba vs. Nb/Y, Th/Yb vs. Ba/La, 206Pb/204Pb vs. Th/Nb, Th/Nb vs. δ18O, REE) indicate that Eocene magmatism was dominated by fluid-mobile components, whereas Oligocene and Mio-Pliocene magmatism was dominated by a depleted mantle, compositionally modified by subducted sediments.A two-stage magmatic and metallogenic evolution is proposed for the Zangezur–Ordubad region. Eocene normal arc, calc-alkaline to high-K calc-alkaline magmatism was coeval with extensive Eocene magmatism in Iran attributed to Neotethys subduction. Eocene subduction resulted in the emplacement of small tonnage porphyry Cu–Mo deposits. Subsequent Oligocene and Miocene high-K calc-alkaline and shoshonitic to adakitic magmatism, and the second porphyry Cu–Mo deposit stage coincided with Arabia–Eurasia collision to post-collision tectonics. Magmatism and ore formation are linked to asthenospheric upwelling along translithospheric, transpressional regional faults between the Gondwana-derived South Armenian block and the Eurasian margin, resulting in decompression melting of lithospheric mantle, metasomatised by sediment components added to the mantle during the previous Eocene subduction event.  相似文献   

7.
Neoproterozoic metavolcanic rocks of Kolet Um Kharit (KUKh) in the southern Eastern Desert of Egypt have been traditionally regarded as a bimodal island-arc sequence. However, geological and geochemical arguments presented here make this interpretation doubtful. Geochemically, these rocks are classified into mafic (tholeiitic basalts) and felsic (high-K rhyodacites to rhyolites) groups. Both the KUKh mafic and felsic metavolcanic rocks show similar geochemical characteristics, implying a genetic link. They have comparable trace element ratios, such as Zr/Nb (27–30 vs. 20–36), Y/Nb (5.44–6.25 vs. 5.05–5.9), K/Rb (577–1164 vs. 573–937), Ba/La (4.29–25–9 vs. 11.4–16.2), Nb/Yb (1.82–2.03 vs. 1.76–1.99). Similarly both groups have parallel LREE-enriched patterns (La/YbCN=2.37–2.81 vs. 2.55–3.17); and negative Nb and Ta anomalies (Nb/Lapm=0.51–0.58 vs. 0.45–0.52 and Ta/Lapm=0.51–0.62 vs. 0.49–0.55). The observed negative Nb and Ta anomalies in the KUKh metavolcanic rocks cannot be attributed to crustal contamination or fractional crystallization. These rocks could represent either a remnant of break-up LIP or were derived from an enriched mantle source containing subduction components beneath an intraoceanic back-arc basin. The recognition of the KUKh rocks as derived from an enriched mantle source revives interest in models that involve enrichment from “plume” interaction during the evolution of the Arabian-Nubian Shield.  相似文献   

8.
The Karakaya Complex within the Early Mesozoic Cimmerian Orogeny in northern Turkey represents the remnants of the Palaeotethys. It includes slivers and/or mega-blocks of slightly metamorphic basic volcanic rocks associated with fossiliferous sediments as well as hypabyssal and intrusive rocks with basaltic-andesitic to ultramafic compositions. They display two distinct compositional groups; namely alkaline and variably tholeiitic. The alkaline basalt samples are more akin to oceanic-island basalts (OIB) with relatively enriched trace element characteristics together with strong partitioning in HREE ([La/Yb]= 5.8–16.2), suggesting that garnet is present as a residual phase in the source of those basalts. The variably tholeiitic samples apart from diabases display E-MORB characteristics; being relatively depleted compared to the alkaline counterparts and less fractionated REE patterns ([La/Yb]= 2.1–3.6). The diabases, on the other hand, are distinctively different with a significant negative Nb anomaly (Zr/Nb = 28.9–43.4) and flat REE patterns ([La/Yb]= 0.8–1.4), suggesting their generation above a supra-subduction zone, probably a back-arc basin. These results may suggest that a mantle plume-related magmatism associated with extensional oceanic system should have been installed within Palaeotethys during Middle-Late Triassic time, which was then incorporated into subduction–accretion prism forming the final picture, that is, “the Karakaya Complex”.  相似文献   

9.
The tectonic evolution of the Mt Amiata volcano-geothermal area is under discussion. Some authors state that this region, as well as the hinterland of the Northern Apennines, were affected by compression from the Cretaceous to the Quaternary. In contrast, most authors believe that extension drove the tectonic evolution of the Northern Apennines from the Early Miocene to the Quaternary. Field data, seismic analyses and borehole logs have been integrated in order to better define the structural features of the continental crust in the Mt Amiata geothermal area. In this paper I propose the hypothesis that the structure of the crust in the Mt Amiata volcano-geothermal area derives from two main geological processes: (1) contractional tectonics related to the stacking of the Northern Apennines (Cretaceous–Early Miocene), (2) subsequent extensional collapse of the hinterland of the mountain chain, and related opening of the Northern Tyrrhenian Sea (Early Miocene–Quaternary). Compressional and extensional structures characterise the Mt Amiata region, although extensional structures dominate its geological framework. In particular the extension produced: (a) Middle-Late Miocene boudinage of the previously stacked tectonic units; (b) Pliocene–Quaternary normal faulting which favoured the emplacement of a magmatic body in the middle-upper crust; and (c) the eruption of the Mt Amiata volcano, which gave rise to an acid and intermediate volcanic complex (0.3–0.19 Ma). The extension produced the space necessary to accommodate the Middle-Late Miocene marine and continental sediments. Pliocene and Quaternary normal and transtensional faults dissected the previous structures and influenced the Early Middle Pliocene marine sedimentation within the structural depressions neighbouring the Mt Amiata volcano. The magmatic body was emplaced at depth (about 6–7 km) during the Pliocene extension, and produced the eruption of the Mt Amiata volcano during the Late Pleistocene. This gave rise to local uplift, presently reaching about 3,000 m, as well as a negative Bouguer anomaly (−16 mgal), both centred on the Mt Amiata area. The crustal dome shows a good correspondence with the convex shape of the regional seismic marker known as the K-horizon, which corresponds to the 450°C isotherm, and the areas with greatest heat flow. This is probably a consequence of the above-cited magmatic body presently in the process of solidification. A Late Pleistocene eruption occurred along a crustal fissure striking N50° (Mt Amiata Fault), which crosscuts the crustal dome. Hydrothermal circulation, proven by the occurrence of thermal springs and gas vents (mainly CO2 and H2S), mainly occurs along the Mt Amiata Fault both in the northeastern ans southwestern sides of the volcano.  相似文献   

10.
Zircon and apatite fission track (FT) thermochronology was applied to investigate the history of cooling and denudation of the Southern Andes between 41° and 42°15′S in relation to the late Cenozoic activity of the Liquiñe-Ofqui fault zone (LOFZ) and the northward migration of the Chile Triple Junction (CTJ). Fifty-six zircon and 51 apatite FT ages, plus 37 apatite confined track-length distributions were obtained mainly from plutonic rocks of the North Patagonian Batholith (NPB) in the main Andean Cordillera. Apatite FT ages and track lengths indicate a stage of rapid cooling at ∼5--3 Ma along both sides of the LOFZ, whereas older Miocene ages with monotonous cooling histories were obtained further away from the fault. Zircon FT ages range from Cretaceous to Pliocene, with marked differences observed along and across the LOFZ. Three different types of temperature-time histories characterise the post-magmatic cooling of the NPB in the region: deep intrusions with moderate and steady cooling rates, intrusions in the upper crust with very slow cooling rates following a stage of initial rapid cooling, and rapidly cooled and exhumed shallow intrusions, the latter with younger ages towards the fault zone. The most prominent denudation episode along the LOFZ is late Miocene to Pliocene, coeval with plate tectonic reconstructions for the arrival and subduction of the Chile Rise beneath the Taitao Peninsula.  相似文献   

11.
李壮  郎兴海  章奇志  何亮 《岩石学报》2019,35(3):737-759
浦桑果矿床位于拉萨地块冈底斯成矿带中段,为侵入岩体与钙质围岩接触带内形成的矽卡岩型高品位铜多金属矿床(Cu@1. 42%,Pb+Zn@2. 83%),是冈底斯成矿带目前唯一一个大型富铜铅锌(钴镍)矿床。本文以浦桑果矿床相关中酸性侵入岩体(黑云母花岗闪长岩和闪长玢岩)为主要研究对象,开展LA-ICP-MS锆石U-Pb年代学、全岩主微量元素、全岩SrNd-Pb及锆石Lu-Hf同位素研究,旨在厘定侵入岩体的形成时代、岩石成因及成岩成矿的动力学背景。LA-ICP-MS锆石U-Pb定年结果表明,黑云母花岗闪长岩和闪长玢岩侵位年龄分别为13. 6~14. 4Ma和13. 6~14. 6Ma,岩体形成时代均属中新世。岩石地球化学特征表明,闪长玢岩和黑云母花岗闪长岩均属高钾钙碱性I型花岗质岩石;岩石普遍具高Sr含量(599×10~(-6)~1616×10~(-6))、高Sr/Y(48. 2~132. 3)和高(La/Yb)N(19. 6~25. 4)比值特征,具低Y(10. 38×10~(-6)~12. 70×10~(-6))和Yb含量(0. 79×10~(-6)~1. 17×10~(-6))特征,表现出埃达克质岩的地球化学属性。全岩稀土元素表现为明显富集轻稀土元素(LREEs)和大离子亲石元素(LILEs),而相对亏损重稀土元素(HREEs)和高场强元素Nb、Ta、P、Ti等(HFSE)。全岩Sr-Nd-Pb及锆石Hf同位素分析结果表明,浦桑果矿床相关中酸性岩石与冈底斯成矿带中新世大多斑岩-矽卡岩矿床紧密相关的埃达克质侵入岩体具相似的同位素组成特征,指示岩石具同源岩浆特征且埃达克质岩浆主要起源于拉萨地块加厚新生下地壳。浦桑果矿床中酸性岩体主要形成于后碰撞伸展的构造背景,因碰撞挤压向后碰撞伸展背景的构造转换,引起印度大陆岩石圈发生拆沉(42~25Ma)及拉萨地块中富集岩石圈地幔发生部分熔融,从而形成富含Cu、Co等基性岩浆熔体底侵加厚新生下地壳(25~18Ma),导致拉萨地块加厚新生下地壳中部分石榴子石角闪岩相发生部分熔融,最终形成闪长质熔体于浦桑果矿区有利构造部位形成具埃达克质属性的中酸性侵入岩体(13~14Ma)和矽卡岩型铜多金属矿体。  相似文献   

12.
We report major and trace element composition, Sr–Nd isotopic and seismological data for a picrite–basalt–rhyolite suite from the northern Tarim uplift (NTU), northwest China. The samples were recovered from 13 boreholes at depths between 5,166 and 6,333 m. The picritic samples have high MgO (14.5–16.8 wt%, volatiles included) enriched in incompatible element and have high 87Sr/86Sr and low 143Nd/144Nd isotopic ratios (εNd (t) = −5.3; Sri = 0.707), resembling the Karoo high-Ti picrites. All the basaltic samples are enriched in TiO2 (2.1–3.2 wt%, volatiles free), have high FeOt abundances (11.27–15.75 wt%, volatiles free), are enriched in incompatible elements and have high Sr and low Nd isotopic ratios (Sri = 0.7049–0.7065; εNd (t) = −4.1 to −0.4). High Nb/La ratios (0.91–1.34) of basalts attest that they are mantle-derived magma with negligible crustal contamination. The rhyolite samples can be subdivided into two coeval groups with overlapping U–Pb zircon ages between 291 ± 4 and 272 ± 2 Ma. Group 1 rhyolites are enriched in Nb and Ta, have similar Nb/La, Nb/U, and Sr–Nd isotopic compositions to the associated basalts, implying that they are formed by fractional crystallization of the basalts. Group 2 rhyolites are depleted in Nb and Ta, have low Nb/La ratios, and have very high Sr and low Nd isotopic ratios, implying that crustal materials have been extensively, if not exclusively, involved in their source. The picrite–basalt–rhyolite suite from the NTU, together with Permian volcanic rocks from elsewhere Tarim basin, constitute a Large Igneous Province (LIP) that is characterized by large areal extent, rapid eruption, OIB-type chemical composition, and eruption of high temperature picritic magma. The Early Permian magmatism, which covered an area >300,000 km2, is therefore named the Tarim Flood Basalt.  相似文献   

13.
Adakite-like features are recognized in the Late Miocene (~10 Ma) porphyritic intrusions of the Los Pelambres giant porphyry copper deposit, central Chile (32°S). Located within the southern portion of the flat-slab segment (28–33°S) of the Chilean Andes, the Al- and Na-rich porphyries of Los Pelambres display distinctly higher Sr/Y (~100–300) and LaN/YbN (~25–60) ratios than contemporaneous and barren magmatic units (e.g., La Gloria pluton, Cerro Aconcagua volcanic rocks) of the same Andean magmatic belt. Strong fractionation of heavy rare earth elements (HREE), absence of Eu anomalies, high Sr/Y and Zr/Sm and low Nb/Ta ratios suggest melt extraction from a garnet-amphibolite source. The Late-Miocene adakite-like porphyritic intrusions at Los Pelambres formed closely related in time and space to the subduction of the Juan Fernández Ridge (JFR) hotspot chain along the Chilean margin. Current tectonic reconstructions reveal that, at the time of formation of the Los Pelambres rocks, a W-E segment of the JFR started to subduct beneath them, producing a slow-down of a previously rapid southward migration of a NE-ridge—trench collision. These particular tectonic conditions are favorable for the origin of the Los Pelambres porphyry suite by melting of subducting young hotspot rocks under flat-slab conditions. The incorporation of crustal components into the oceanic lithopheric magma source by subduction erosion is evidenced by the Sr-Nd isotope composition of the Los Pelambres rocks different from the MORB signatures of true adakites. A close relationship apparently exists between the origin of this adakite-like magmatism and the source of the mineralization in the Los Pelambres porphyry copper deposit.Editorial handling: R.J. Goldfarb  相似文献   

14.
The presence or absence of a thermally anomalous mantle plume during the formation of the widespread Carboniferous–Permian magmatism of northern Europe is examined. The geochemistry of representative samples from the extensive Carboniferous–Permian dyke and sill intrusions across northern Europe are reported in order to ascertain whether they have a common ‘plume’ source. Both tholeiitic and alkaline magmas have diverse trace element compositions. Alkaline samples with relatively low Ti and Nb/La < 1 are considered to originate in the lithospheric mantle and those with Nb/La > 1 from the asthenosphere. The tholeiites have a close affinity to E-MORB but have mixed with variable amounts of lithosphere and upper crust. Tectonic reorganisation and decompression melting of a trace element-enriched mantle is considered to have controlled the Carboniferous–Permian magmatism, which contains no coherent geochemical evidence for a single plume-related thermo-chemical anomaly.  相似文献   

15.
Two age groups were determined for the Cenozoic granitoids in the Dinarides of southern Serbia by high-precision single grain U–Pb dating of thermally annealed and chemically abraded zircons: (1) Oligocene ages (Kopaonik, Drenje, Željin) ranging from 31.7 to 30.6 Ma (2) Miocene ages (Golija and Polumir) at 20.58–20.17 and 18.06–17.74 Ma, respectively. Apatite fission-track central ages, modelling combined with zircon central ages and additionally, local structural observations constrain the subsequent exhumation history of the magmatic rocks. They indicate rapid cooling from above 300°C to ca. 80°C between 16 and 10 Ma for both age groups, induced by extensional exhumation of the plutons located in the footwall of core complexes. Hence, Miocene magmatism and core-complex formation not only affected the Pannonian basin but also a part of the mountainous areas of the internal Dinarides. Based on an extensive set of existing age data combined with our own analyses, we propose a geodynamical model for the Balkan Peninsula: The Late Eocene to Oligocene magmatism, which affects the Adria-derived lower plate units of the internal Dinarides, was caused by delamination of the Adriatic mantle from the overlying crust, associated with post-collisional convergence that propagated outward into the external Dinarides. Miocene magmatism, on the other hand, is associated with core-complex formation along the southern margin of the Pannonian basin, probably associated with the W-directed subduction of the European lithosphere beneath the Carpathians and interfering with ongoing Dinaridic–Hellenic back-arc extension.  相似文献   

16.
The Kabanga deposit constitutes one of the most significant Ni sulfide discoveries of the last two decades (indicated mineral resource 23 Mt of ore at 2.64% Ni, inferred resource 28.5 Mt at 2.7% Ni, November 2008). The sulfides are hosted by predominantly harzburgitic and orthopyroxenitic intrusions that crystallized from magnesian basaltic and picritic magmas. However, compared with other sulfide ores that segregated from such magmas (e.g., Jinchuan, Pechenga, Raglan), most Kabanga sulfides have low Ni (<1–3%), Cu (∼0.1–0.4%), and PGE contents (≪1 ppm), high Ni/Cu (5–15), and low Ni/Co (10–15) and Pd/Ir (2–20). Sulfides with higher metal contents (up to ∼5% Ni, 0.8% Cu, 10 ppm PGE) are found in only one unit from Kabanga North. The observed metal contents are consistent with segregation of magmatic sulfides from fertile to strongly metal-depleted magmas, at intermediate to very low mass ratios of silicate to sulfide liquid (R factors) of approximately 10–400. Sulfide saturation was triggered prior to final emplacement, by assimilation of up to 50% of the total sulfur in the intrusions from sulfide-bearing metasedimentary country rocks. Immiscible sulfide liquid was entrained by the magma and ultimately precipitated in dynamic magma conduits that formed tubular and sill-like mafic–ultramafic bodies characterized by abundant magmatic breccias, highly irregular layering, and frequent compositional reversals. The unusually large degree of crustal contamination and the low R factors render Kabanga an end-member in the spectrum of magmatic Ni sulfide ores.  相似文献   

17.
This paper presents a review of hydrothermal alteration and K–Ar age data from the Toyoha‐Muine area (TMA), where the Toyoha polymetallic (Ag–Pb–Zn–Cu–In) deposit is located near the Pliocene andesitic volcano that formed Mt Muine. Systematic prospect‐scale mapping, sampling, X‐ray analysis and microscopic observation show that hydrothermal alteration is divided into two groups: acid‐pH and neutral‐pH alteration types. The former is further divided into mineral assemblages I, II and III, while the latter into mineral assemblages IV and V. Different mineralogical features in five mineral assemblages are summarized as follows: (I) Quartz (silicified rock); (II) Pyrophyllite or dickite; (III) Kaolinite or halloysite ± alunite; (IV) Sericite or K‐feldspar; and (V) Interstratified minerals (illite/smectite and chlorite/smectite) and/or smectite. K–Ar radiometric ages determined on twenty‐eight K‐bearing samples (whole volcanic rocks and separated hydrothermal minerals) mainly fall into one of three periods: Early Miocene (24.6–21.4 Ma), Middle–Late Miocene (12.5–8.4 Ma) and Pliocene–Pleistocene (3.2–0 Ma). These three periods are characterized as follows. Early Miocene: A minor hydrothermal activity, which might be genetically related to the intermediate or felsic magmatic activities, formed mineral assemblage IV at 24.6 Ma in the northern part of the TMA. Middle to Late Miocene: The basaltic intrusion, andesitic eruption, and granodiorite intrusions induced hydrothermal activities between 12.5 and 8.4 Ma, resulting in the formation of a mineral assemblage IV with some base metal mineralization. Pliocene–Pleistocene: An andesitic eruption formed Mt Muine between 3.2 and 2.9 Ma. The andesitic activity was associated with acid‐pH mineral assemblages I, II and III locally around the volcano. Latent magmatic intrusions subsequent to the andesitic eruption generated hydrothermal activities that formed mineral assemblages IV and V between 1.9 and 0 Ma in the southern and southeastern parts of Toyoha deposit at depth, overprinting the Middle to Late Miocene alteration. The hydrothermal activities also formed mineral assemblages I, II and III along the Yunosawa fault (east of the Toyoha deposit) and assemblage III in the south and southeast of the Toyoha deposit near the surface.  相似文献   

18.
The timing of the emplacement of ore-bearing melts in the process of evolution of flood-basalt magmatism in the Noril’sk District is discussed. The current models of ore formation consider the emplacement of ore-bearing intrusions either under the conditions of a closed magmatic system as a product of a self-dependent magmatic event, or under the conditions of an open magmatic system, where intrusions are parts of the conduits feeding lava flows. In both cases, the composition of the initial magma, the content of volatile components therein, and the contribution of country rock assimilation are important for the development of a genetic model. The relationships between lavas and intrusions are exemplified in the South Maslov intrusion, which cuts through the rocks of the Nadezhdinsky Formation. No geological evidence for links of lavas to intrusions has been established. Substantial difference in geochemistry (Ti contents, Gd/Yb and La/Sm ratios, etc.) of the tuff and lava sequence on the northern shore of Lake Lama and the Maslov intrusions are demonstrated. It is concluded that the Noril’sk deposits were formed as products of emplacement of self-dependent portion of magma in the post-lower Nadezhdinsky time. The melt composition determined from melt inclusions in olivine corresponds to high-Mg tholeiitic basalt (up to 7–8 wt % MgO) containing up to 1 wt % H2O and 0.3 wt % Cl and undersaturated with sulfur. The fluid regime of flood-basalt volcanism had no anomalous features—the fluid was aqueous-carbon dioxide. The melts of ore-bearing and barren intrusions had similar concentrations of volatile components. The distribution of major and trace elements in intrusive rocks of the contact zone with the lower part of the Nadezhdinsky Formation characterized by high (La/Sm)N ratio in comparison with gabbroic rocks (2.8–2.3 and 1.3–1.6, respectively), indicates that contamination of the initial melt only took place in a narrow (1 m) contact zone or did not develop at all. New data on isotopic compositions of Sr (87Sr/86Sr)251 = 0.7089 and Pb (206Pb/204Pb = 20.877–24.528 in anhydrite confirm that local assimilation did not play a substantial role in the formation of rock and ores. On the basis of chemical composition of ore-forming intrusions, their isotopic characteristics, and the composition of melt inclusions in olivine, it is suggested that the lower crustal rocks were a major source of ore-bearing magmas.  相似文献   

19.
An isotope-geochronological study has been performed to examine the products of Late Cenozoic collision volcanism on the northern coast of Van Lake, Turkey. We obtained 45 new K-Ar dates, based on which the principal time characteristics of volcanic activity in the region have been determined. The total duration of magmatic activity in the area of the northern coast of Van Lake has lasted ∼15 myr; it has had an expressed discrete nature, when periods of intense volcanic activity alternated with lasting breaks in eruptions. Four stages of Neogene-Quaternary volcanism have been identified: Middle Miocene (15.0–13.5 myr), Late Miocene (10–9 myr), Pliocene (5.8–3.7 myr), and Quaternary (1.0–0.4 Ma). The average duration of the stages has been 1–2 myr; the stages were separated from each other with periods of inactivity of approximately equal lengths (∼3 myr). For each of the Pliocene and Quaternary stages, three additional phases of volcanism have been identified, which were separated from each other with short time intervals (a few hundred thousand years). The last burst of volcanic activity in the area in question took place ∼400 ka; similar to Quaternary volcanism in general, it was not characterized by a high intensity. An important result of the studies performed was to confirm the existence of a separate Middle Miocene stage of collision volcanism for the Caucasian-Anatolian Segment of the Alpine Fold Belt. The data generated allow concluding that Neogene-Quaternary volcanism in this portion of the belt started much earlier (∼15 Ma) than assumed by the majority of the previous researchers.  相似文献   

20.
A combination of four thermochronometers [zircon fission track (ZFT), zircon (U–Th)/He (ZHe), apatite fission track (AFT) and apatite (U–Th–[Sm])/He (AHe) dating methods] applied to a valley to ridge transect is used to resolve the issues of metamorphic, exhumation and topographic evolution of the Nízke Tatry Mts. in the Western Carpathians. The ZFT ages of 132.1 ± 8.3, 155.1 ± 12.9, 146.8 ± 8.6 and 144.9 ± 11.0 Ma show that Variscan crystalline basement of the Nízke Tatry Mts. was heated to temperatures >210°C during the Mesozoic and experienced a low-grade Alpine metamorphic overprint. ZHe and AFT ages, clustering at ~55–40 and ~45–40 Ma, respectively, revealed a rapid Eocene cooling event, documenting erosional and/or tectonic exhumation related to the collapse of the Carpathian orogenic wedge. This is the first evidence that exhumation of crystalline cores in the Western Carpathians took place in the Eocene and not in the Cretaceous as traditionally believed. Bimodal AFT length distributions, Early Miocene AHe ages and thermal modelling results suggest that the samples were heated to temperatures of ~55–90°C during Oligocene–Miocene times. This thermal event may be related either to the Oligocene/Miocene sedimentary burial, or Miocene magmatic activity and increased heat flow. This finding supports the concept of thermal instability of the Carpathian crystalline bodies during the post-Eocene period.  相似文献   

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