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1.
Concentration profiles of Mg, K, La, Fe, Mn, V, Cr, As and Mo were determined in samples from a freeze core taken at the deepest site of Baldeggersee in 1993. The special coring technique allowed an exact dating of the sediment samples and an annual resolution of the profiles. Long term changes in benthic redox conditions produce diagnostic trends in several metal profiles. Fe, As and Mn enrichments trace the onset of anoxia at the deepest site of the lake. High values of Mo concentrations and Cr/V ratios indicate periods of stable anoxic conditions in a meromictic hypolimnion. A comparison of oxygen time series with metal profiles between 1950 and 1990 indicates that Mn reacts sensitively to large seasonal variations of deep-water oxygen concentrations.  相似文献   

2.
Tidal and seasonal behaviour of the redox-sensitive trace metals Mn, Fe, Mo, U, and V have been investigated in the open-water column and shallow pore waters of the backbarrier tidal flats of the island of Spiekeroog (Southern North Sea) in 2002 and 2007. The purpose was to study the response of trace metal cycles on algae blooms, which are assumed to cause significant changes in the redox state of the entire ecosystem. Trace metal data were complemented by measurements of nutrients and enumeration of algae cells in 2007. Generally, Mn and V show a tidal cyclicity in the water column with maximum values during low tide which is most pronounced in summer due to elevated microbial activity in the sediments. Mo and U behave almost conservatively throughout the year with slightly increasing levels towards high tide. Exceptions are observed for both metals after summer algae blooms. Thus, the seasonal behaviour of the trace metals appear to be significantly influenced by productivity in the water column as the occurrence of algae blooms is associated with an intense release of organic matter (e.g. transparent exopolymer particles, TEP) thereby forming larger organic-rich aggregates. Along with elevated temperatures in summer, the deposition of such aggregates favours microbial activity within the surface sediments and release of DOC, nutrients and trace metals (Mn, Mo and V) during the degradation of the aggregates. Additionally, pronounced reducing conditions lead to the reduction of Mn(IV)-oxides and Fe(III)-(oxihydr)oxides, thereby releasing formerly scavenged compounds as V and phosphate. Therefore, pore-water profiles show significant enrichments in trace metals especially from July to September. Finally, the trace metals are released to the open water column via draining pore waters (esp. Mo, Mn, and V) and/or fixed in the sediment as sulphides (Fe, Mo) and bound to organic matter (U). Non-conservative behaviour of Mo in oxygenated seawater, first observed in the investigation area by Dellwig et al. (Geochim Cosmochim Acta 71:2745–2761, 2007a), was shown to be a recurrent phenomenon which is closely coupled to bacterial activity after the breakdown of algae blooms. In addition to the postulated fixation of Mo in oxygen-depleted micro-zones of the aggregates or by freshly formed organic matter, a direct removal of Mo from the water column by reduced sediment surfaces may also play an important role.  相似文献   

3.
李传琼  王鹏  陈波  李燕 《湖泊科学》2018,30(1):139-149
于2015年1月和7月在赣江干流和主要支流37个采样点共采集74个水样,分析赣江水系15种溶解态金属元素(Be、Al、V、Mn、Fe、Co、Ni、Cu、As、Mo、Cd、Sb、Tl、Pb、U)的空间分布特征和污染来源的贡献率.结果表明:多数水样的溶解态金属元素浓度符合水质标准,主要的超标元素是Fe,样品超标率为21.60%,其次为As(8.10%)、Mn(4.05%)、Tl(4.05%)和Al(1.35%).Be、Al、V、Fe、Co、Ni、Cu、U浓度在枯水期显著高于丰水期,其他元素差异不显著.依据溶解态金属元素的空间分布特征,赣江流域可分为3个区域:湘水、章水和赣江赣州市段(C1),桃江、袁水和锦江(C2),其他区域(C3);溶解态金属元素水平大小排序为C1C2C3,其中Be、Al、Cu、Mo、Sb、As浓度在C1最高,V、Mn、Fe、Ni、Cd浓度在C2最高.采矿废水、矿渣和农田土壤降雨淋滤、钢铁冶炼废水是赣江溶解金属元素的主要来源;Be、Al、Cu、Pb、U的污染源超过40%来自采矿废水,Cu、As、Mo、Cd的污染源超过35%来自矿渣和农田土壤降雨淋滤,V、Mn、Co、Ni的污染源超过41%来自钢铁冶炼废水.  相似文献   

4.
Upwelling coastal systems can be used to understand how dissolved oxygen and biological productivity control the accumulation of redox-sensitive metals in marine sediments. The aluminium (Al), cadmium (Cd), iron (Fe), nickel (Ni), molybdenum (Mo), vanadium (V), total organic carbon (TOC), total nitrogen (TN) and total sulfur (TS) contents in surficial sediment collected from different water depths (30, 70, and 120?m) in three northern Chilean bays influenced by coastal upwelling and oxygen minimum zones (OMZs) were measured. Principal component analysis (PCA), cluster analysis, and Spearman?s rank correlation were used to identify the mechanisms responsible for the redox-sensitive metal accumulation. The content of redox-sensitive metals and organic components in sediment increased with increasing water column depth, whereas lithogenic metals decreased. In the Mejillones del Sur and Caldera bays, the enrichment factors of the redox-sensitive metals showed enrichment for all metals with depth. The Cd and V enrichments are mainly the product of biogenic flow to the seabed, and the Mo and Ni enrichments are due to preservation under low subsurface oxygen conditions. Sulfate reduction is not an important mechanism in the accumulation of redox-sensitive metals in the sediment of the three bays. The PCA showed that the behaviors of the redox-sensitive metals and organic components reflect differences in the effects of the OMZ in sediment along the coast of northern Chile, with a more intense OMZ in Mejillones del Sur bay and weaker OMZs in Caldera and Inglesa bays. However, the high degree of enrichment in redox-sensitive metals in Caldera Bay can be attributed to the intense activity of the mining industry near the bay, a situation that produces geochemical behavior similar to that observed in Mejillones del Sur Bay.  相似文献   

5.
This study focuses on the trace and rare earth elements(REE) geochemistry of the Nkporo and Ekenkpon Shales of the Calabar Flank.The main aim is to infer their depositional environment and the degree of their metal enrichment.The shale samples were analyzed using inductively coupled plasma mass spectrometry.The results indicated that the mean concentrations of K,Na,and Fe in Nkporo and Ekenkpon Shales are 1.45,0.4,and 4.17 wt%,and 1.11,0.44,and 5.42 wt%;respectively.The Nkporo Shale is enriched with the following trace elements;PMn Sr Ba Zn Ce Rb Zr VCr Ni and depleted in the following trace elements;Ta GeSb Bi Cd Ag Te In Hg.While the Ekenkpon Shale is enriched with the following trace elements;P Mn Ba Sr VCe Zr Rb Cr Zn Ni and depleted in;Sb Ge Bi Ag Ce Te InHg.The concentration of redox-sensitive elements such as V,Ni,Mo,U,Cu,Cr,Re,Cd,Sb,Ti,Mn,and their ratio V/Mo and U/Mo in the black and grey shale samples show different patterns.The REE obtained from the Nkporo and Ekenkpon Shales were PAAS normalized.The Nkporo Shale showed a slightly flat light rare-earth element(LREE),middle rare-earth element(MREE),and heavy rare earth element(HREE) pattern enrichment.Ce/Ce*ranges from 0.95 to 1.09 in Nkporo Shale and 0.67 to 1.40 in Ekenkpon Shale.The Ekenkpon Shale showed a slight LREE,MREE enrichment,and depleted HREE patterns.The Mn contents and U/Mo ratio in Nkporo and Ekenkpon Shales suggests a poor oxygen transitional environment.The V/Mo and V/(V+Ni) ratios indicated that the Nkporo shales were deposited in an anoxic to suboxic conditions and Ekenkpon shales were also deposited under an anoxic to suboxic conditions.The V/Ni ratio indicated that the organic matter in the Nkporo shale is terrigenous while that of the Ekenkpon shales are both terrigenous and marine in origin.  相似文献   

6.
The presence of metals, including manganese (Mn) and iron (Fe), adversely impacts water quality. In seasonally stratified reservoirs, Mn and Fe can accumulate in the water column due to reducing conditions in sediments and be released to downstream rivers through dam discharge. In addition to reservoir stratification influences, the release of metals downstream is influenced by hydrologic conditions in the river. We examined the seasonal and spatial variability of Mn and Fe concentrations in a eutrophic, hydropower reservoir and the downstream river over a two‐year period. Overall, we found that reservoir stratification was a strong predictor of tailrace Mn and Fe concentrations but that tailrace Fe concentrations were also influenced by dam discharge. Downgradient of the tailrace, river discharge and suspended sediment were the dominant predictors of both Mn and Fe concentrations. Using our data, we develop a conceptual model of seasonal and hydrologic drivers of metal concentrations. The model can be modified for other systems aiding drinking water utilities and other water users in forecasting under what seasonal and hydrologic conditions that Mn and Fe concentrations in river systems are likely to be elevated.  相似文献   

7.
The dispersion and influence of soluble and particulate trace elements(TEs) present in the materials from abandoned mines is an imminent problem on terrestrial and aquatic environments.The goal of this research is to provide a broader view of such transport,assessing particle size distribution and TE interactions(e.g.,scavenging) with mine tailings and locally derived sediments transported by water in arid region.Sand grains from wash sediment were collected from a dry ephemeral wash in Nelson,N...  相似文献   

8.
阿哈湖Fe、Mn沉积后再迁移的生物地球化学机理   总被引：18，自引：1，他引：17  
万曦  万国江  黄荣贵  普勇 《湖泊科学》1997,9(2):129-134
贵州阿哈湖是一底层滞水带季节性缺氧的中型人工湖。由于长期积累。沉积物顶部微粒悬浮层出现了Ｆｅ、Ｍｎ富集。湖底缺氧时,经生物氧化作用形成的Ｆｅ＾２＋、Ｍｎ＾２＋自沉积物向上覆水体扩散,水体Ｆｅ＾２＋浓度增高比Ｍｎ＾２＋滞后出现且超过前结束。  相似文献   

9.
Long-term observational data (1992?C2009) on heavy metal (Cu, Zn, Pb, Cr, Ni, V, Mo, Co, Fe, and Mn) content of different links in the Ivankovo Reservoir ecosystem are used to consider the regularities in the distribution and behavior of heavy metals in the system anthropogenic pollution sources-reservoir and its drainage area, thus enabling the assessment of the pollution level of the Volga Source of water supply to Moscow.  相似文献   

10.
P, Fe, Mn, and S species were analyzed in water samples from the sediment-water interface collected at four seasonally different times during the course of a year at two sampling sites in the southern basin of Lake Lugano (Lago di Lugano). The results reveal the strong influence of the biogeochemical processes in the sediment on the chemical composition of the lake water above. Consumption of oxygen and nitrate under oxic to microoxic conditions in the water column as well as sequential release of reduced manganese and iron under anoxic conditions was observed as a direct or indirect consequence of microbially mediated degradation of organic matter. The seasonal pattern observed for the release and the retainment of dissolved reduced iron and manganese correlates well with the one for dissolved phosphate. Iron, manganese and phosphorus cycling are coupled tightly in these sediments. Both sediment types act as sinks for hydrogen sulfide and sulfate. An inner-sedimentary sulfur cycle is proposed to couple iron, manganese and phosphorus cycling with the degradation of organic matter. Nutrient cycling at the sediment-water interface might thus be driven by a microbially regulated electron pumping mechanism. The results contribute to a better understanding of the role of sediment processes in the lake's internal phosphorus cycle and its seasonal dynamics.  相似文献   

11.
The geochemical baselines and distribution of 31 elements (Al, Fe, K, Na, Mg, Ca, Mn, Ba, Cr, Zr, Ni, Sr, Zn, Y, Li, Cu, Mo, Nb, Th, Co, Ga, W, Ta, Be, Ti, Ge, Se, Bi, Te, Sc and Re) and physico-chemical parameters of the tropical surface sediments of the Terengganu River basin, Malaysia, are reported. Sediments are sandy loam to sand in texture consisting of mostly quartz, low organic matter content (average-2.68%), low CEC (average-2.02 cmol(+)/kg) and mildly acidic pH1:5 (average-5.91). Concentrations of Mn, Fe, Ba, Cr, Ni, Cu, Mo and Se were measured to be above the environmental sediment quality criteria at various locations. Lake sediments registered significantly higher Al, Fe, Ti, Mg, Ca, Mn, Te and Sc concentrations as compared to the river sediments. Most of the elements investigated showed an association with silt size fraction (2-63 μm). Among the investigated metals, Mo and Fe concentrations showed an increasing (5-fold) and decreasing (3-fold) trend, respectively, along the river path from the upstream to the downstream depending on the stream pH-redox conditions. The enrichment factor values (EF 5) of Cr, Ni, Mo and Se indicated enrichment from anthropogenic activities. Alkali and alkali earth metals registered a significant depletion (EF values 0.7) as compared to the Earth's crust. Principal component analysis of the two main components (PC1, 87.4% and PC2, 8.7%) revealed a well-defined group of estuary sediments. Lake and river sediment sampling locations did not form defined groups revealing heterogeneity in the origin of geologic material and the in-stream geochemical processes. However, Cr, Ni, Mo and Se formed a separate group with elevated concentrations (e.g. Cr1,000 mg/kg) indicating contamination of sediments. This work presents the geochemical baselines of the tropical sediments as industrial development and urbanization along the north east coast of Peninsular Malaysia are advancing rapidly.  相似文献   

12.
Ferromanganese nodules from the Bauer Basin of the south equatorial Pacific are unlike virtually all oceanic nodules so far analyzed in showing negative Ce anomalies in their REE abundance patterns. In comparison with similarly Cu-Ni-enriched nodules from the north equatorial Pacific they are depleted in REE by 50–80% and are heavy REE enriched relative to intermediate REE. The REE patterns can be accounted for by the input of hydrothermal iron oxyhydroxides and associated REE to the Bauer Basin and the transfer of the REE to the nodules because of diagenetic reactions in the sediment. The excess iron input also is reflected in lower Cu/Ni ratios in the nodules as compared with nodules from the north equatorial zone, apparently because of the larger proportions of a residual Fe phase in the nodules relative to todorokite. Cerium anomalies of the Bauer Basin nodules range from ?0.17 to ?0.29 as compared with +0.33 to +0.07 in the north equatorial Pacific but show a parallel sensitivity of Ce anomaly to Mn/Fe ratios of the nodules. Nodules with the more positive anomalies within each group have the smallest Mn/Fe ratios and have been subjected to the greatest seawater influence whereas nodules with the more negative anomalies have the largest Mn/Fe ratios and have been subjected to the greatest diagenetic influence.  相似文献   

13.
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14.
The quantitative separation of As(III) from a water sample containing As(III) and As(V) in the presence of Fe and Mn in an ion exchange resin (AG1 X8) column for the speciation of arsenic is described. Individual and combined effects of Fe and Mn on the separation of As(III) from the solution have been studied separately. In absence of Fe and Mn, the ratio between the As(T) concentration in the eluent and the As(III) concentration in the original sample has been found to be 0.9717 under optimum process conditions. The presence of Fe(II) in the water sample increased the As(T) concentration in the eluent whereas Mn(II) decreased it. Combined effects of Fe and Mn on the percentage increment in the eluent arsenic concentration have been expressed by additive and interactive models. The interactive model has been developed by a statistical software with a 95 % confidence level. In most of the cases the error on the determination of the As(III) concentration had a minimum when using the interactive model.  相似文献   

15.
North Sea drill cuttings piles are a distinct anthropogenic legacy resulting from the exploration and production of North Sea oil reserves. The need to understand metal cycling within the piles becomes increasingly important with the imminent decommissioning of many North Sea platforms and the subsequent fate of associated cuttings piles. This paper presents results of the simultaneous analysis of geochemical carrier substances (Mn and Fe oxyhydroxides), along with dissolved (<0.2 microm) and total (>0.2 microm) metal (Ba, Co, Cr, Cu, Mo, Pb, V) concentrations from a North Sea cuttings pile and surrounding sediment. These data are examined in conjunction with in situ measured porewater oxygen and sulfide. Results show a rapid removal of oxygen within the top few millimeters of the cuttings pile along with elevated concentrations of total hydrocarbons and solid phase metal concentrations compared to the surrounding environment.  相似文献   

16.
Water Resources - The average concentrations of elements Fe, Mn, Zn, Pb, Cu, Cr, V, Co, Cd, Ni, As, and Mo in the subcolloidal fraction of bottom sediments were determined in the northern and...  相似文献   

17.
The European Water Framework Directive (WFD) commits European Union member states to achieving good ecological status in all water bodies by 2015. For sediments the definition of good chemical status is based on numerical sediment quality guidelines. The aqua regia fraction is thus used for the evaluation of heavy metal concentrations in sediments. The chemical constituents in sediments responsible for mobility and toxicity are not considered generally. This article presents the combining of the sequential BCR procedure, for determining the chemical species of relevant elements, with the geoaccumulation index principle a numerical classification method for sediment quality guidelines. Using the BCR method it can be demonstrated that changes in element speciation can lead to more highly mobile species of trace elements which may affect the hazardous potential of sediments despite the “good chemical status” classification for aqua regia digestions. The Klinke stream is an urban surface water body located in Magdeburg, the state capital of Saxony‐Anhalt, Germany. Using this stream as an example it is shown that this additional information helps to describe the dynamics and discharge of the trace elements Al, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Rb, Sr, Mo, Pd, Cd, Sb, Ba, Pb, Bi, and U into the Elbe River from urban water bodies.  相似文献   

18.
Estimation of internal nutrient release in large shallow Lake Taihu, China   总被引：17，自引：2，他引：17  
Based on field investigation of wave, sediment suspension and the changes in nutrient concentration of the water column in Lake Taihu, China, we proposed two release models to quantify nutrient release under static and dynamic conditions, respectively. Under static conditions, nutrient release from sediments to the overlying water mainly depends on chemical diffusion induced by concentration gradient, in which the nutrient release is controlled by the temperature, dissolved oxygen concentration in the sediment-water interface, oxidation-reduction potential and the concentration difference between porewater and overlying water. Under dynamic condition (or disturbed condition), both dissolved and particulate nutrients in sediments are released into the water column because of wind-induced sediment suspension. The amount of nutrient release under dynamic conditions is larger than that under the static condition. The release of dissolved nutrients, however, does not increase because the wind induced turbulence made oxidation of metallic elements such as Fe (ferric iron), Mn which are capable of precipitating soluble reactive phosphate (SRP). Under dynamic conditions, therefore, the release of total phosphorus (TP) increases dramatically but the release of SRP is close to those under static conditions. In sediments of Lake Taihu, high Fe content leads to a high ratio of Fe to P contents in sediments (Fe:P ratio). Under dynamic conditions, therefore, nutrient release is controlled by the intensity of disturbance, sediment consolidation and nutrient content in sediments. As for dissolved nutrients, especially SRP, the release is also controlled by the intensity of dynamic re-oxidation, Fe content in sediments and nutrient concentration gradient between porewater and overlying water. Based on these two release modes, the release flux in Lake Taihu has been estimated. In the static condition (i.e. laboratory experimental condition), total release of NH4 -N for whole lake is ca. 10,000 ton/a, and PO43--P is ca. 900 ton/a. In the dynamic condition, nutrient release following sediment suspension was estimated according to three different intensities of wind forcing which were defined as "calm" (wind speed is less than 2 m/s), "gentle" (wind speed is greater than 2 m/s and less than 6 m/s) and "gust" (wind speed is greater than 6 m/s). The release rate in the condition of "calm" was estimated in terms of the nutrient release in the laboratory experimental static condition; whereas the release rate in conditions of "gentle" and "gust" was estimated in terms of measurement during sediment resuspension conducted in flume experiments. With the observation of wind velocity and frequency in 2001, each type of wind forcing took the frequency of 12%, 82% and 6% for "calm", "gentle" and "gust", respectively. The yearly release of nitrogen was 81,000 ton and phos- phorus was 21,000 ton, which is about 2-6 folds of annual external loading, respectively.  相似文献   

19.
The spatial distribution of As (total As, As (III) and As (V)) in estuarine sediments from the main tributaries of Todos os Santos Bay, BA, Brazil, was evaluated under high and low flow conditions. The concentrations of As were determined using a slurry sampling procedure with hydride generation atomic absorption spectrometry (HG-AAS). The highest concentrations were observed at estuary mouths, and exceeded conservative lower threshold value (Threshold Effects Level; TEL). Due to the oxic conditions and abundance of Mn and Fe (oxyhydr)oxides in the sediments, most inorganic arsenic in the Subaé and Paraguaçu estuaries was present as As (V). Nevertheless, the concentration of As (III) at several locations along the Jaguaripe River were also above the TEL value, suggesting that As may be toxic to biota. In the Subaé estuary, antropogenic activities are the main source of As. At the Jaguaripe and at Paraguaçu estuaries, nevertheless, natural sources of As need to be considered to explain the distribution patterns.  相似文献   

20.
A survey on the metal concentrations (As, Ba, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, Sr, V, Zn) in beach water and sediments is reported from the tourist destination of Acapulco city on the Pacific coast of Mexico. The concentration of dissolved trace metals (DTMs) in beach water and acid leachable trace metals (ALTMs) in sediments indicated that they are anthropogenic in nature due to the increased tourist activities in the crowded beach locations. The statistical analysis indicates Fe and Mn play a major role as metal scavengers in both the medium (water and sediment) and the higher value of other metals is site specific in the study area, indicating that they are transported from the local area. Comparison results suggest that the beach water quality has deteriorated more than the sediments and special care needs to be taken to restore the beach quality.  相似文献   

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