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1.
Abstract– None of the well‐established nitrogen‐related IR absorption bands, common in synthetic and terrestrial diamonds, have been identified in the presolar diamond spectra. In the carbonado diamond spectra, only the single nitrogen impurity (C center) is identified and the assignments of the rest of the nitrogen‐related bands are still debated. It is speculated that the unidentified bands in the nitrogen absorption region are not induced by nitrogen, but rather by nitrogen‐hydrides because in the interstellar environment, nitrogen reacts with hydrogen and forms NH+; NH; NH2; NH3. Among these hydrides, the electronic configuration of NH+ is the closest to carbon. Thus, this ionized nitrogen‐mono‐hydride is the best candidate to substitute carbon in the diamond structure. The bands of the substitutional NH+ defect are deduced by redshifting the irradiation‐induced N+ bands due to the mass of the additional hydrogen. The six bands of the NH+ defects are identified in both the presolar and the carbonado diamond spectra. The new assignments identify all of the nitrogen‐related bands in the spectra, indicating that presolar and carbonado diamonds contain only single nitrogen impurities.  相似文献   

2.
Abstract— A series of experiments carried out by Koscheev et al. (1998, 2001, 2004, 2005) showed that the bimodal release of heavy noble gases from meteoritic nanodiamonds can be reproduced by a single implanted component. This paper investigates the implications of this result for interpreting the noble gas compositions of meteoritic nanodiamonds and for their origin and history. If the bimodal release exhibited by meteorite diamonds reflects release of the P3 noble gas component, then the composition inferred for the pure Xe‐HL end member changes slightly, the excesses of heavy krypton isotopes that define Kr‐H become less extreme, evidence appears for a Kr‐L component, and the nucleosynthetic contribution to argon becomes much smaller. After correction for cosmogenic neon inherited from the host meteorites, the neon in presolar diamonds shows evidence for pre‐irradiation, perhaps in interstellar space, and a nucleosynthetic component perhaps consistent with a supernova source. After a similar correction, helium also shows evidence for presolar irradiation and/or a nucleosynthetic component. For the case of presolar irradiation, due to the small size of the diamonds, a large entity must have been irradiated and recoiling product nuclei collected by the nanodiamonds. The high 3He/21Ne ratio (?43) calls for a target with a (C + O)/heavier‐element ratio higher than in chondritic abundances. Bulk gas + dust (cosmic abundances) meet this criteria, as would solids enriched in carbonaceous material. The long recoil range of cosmogenic 3He argues against a specific phase. The excess 3He in presolar diamonds may represent trapped cosmic rays rather than cosmogenic 3He produced in the vicinity of the diamond crystals.  相似文献   

3.
Abstract— We have determined the recoil losses from silicon carbide (SiC) grain‐size fractions of spallation Ne produced by irradiation with 1.6 GeV protons. During the irradiation, the SiC grains were dispersed in paraffin wax in order to avoid reimplantation into neighboring grains. Analysis for spallogenic 21Ne of grain‐size separates in the size range 0.3 to 6 μm and comparison with the 22Na activity of the SiC + paraffin mixture indicates an effective recoil range of 2–3 μm with no apparent effect from acid treatments, which are routinely used in the isolation of meteoritic SiC grains. Our results indicate that the majority of presolar SiC grains in primitive meteorites, which are micrometer‐sized, will have lost essentially all spallogenic Ne produced by cosmic‐ray interaction in the interstellar medium. This argues against the validity of previously published presolar ages of Murchison SiC (～10 to ～130 Ma, increasing with grain size; Lewis et al., 1994), where recoil losses had been based on calculated recoil energies. It is argued that the observed variations in meteoritic SiC grain‐size fractions of 21Ne/22Ne ratios are more likely due to the effects of nucleosynthesis in the He‐burning shell of the parent AGB stars which imposes new boundary conditions on nuclear parameters and stellar models. It is suggested that spallation‐Xe produced on the abundant Ba and REE in presolar SiC, rather than spallogenic Ne, may be a promising approach to the presolar age problem. There is a hint in the currently available Xe data (Lewis et al., 1994) that the large (>1 μm) grains may be younger than the smaller (<1 μm) grains. The retention of spallogenic 21Ne produced by the bombardment of SiC grains of different grain sizes with 1.6 GeV protons, avoiding reimplantation into neighboring grains by dispersing the SiC grains in paraffin wax, has been derived from a comparison of mass spectrometrically determined 21Ne, retained in the grains, with the 22Na activity of the grains‐plus‐paraffin mixture. Compared to estimates of retention used in previous attempts to determine presolar ages for SiC (Tang and Anders, 1988b; Lewis et al., 1990, 1994), the results indicate significantly lower values. They do, however, agree with retention as expected from previous measurements of recoil ranges in similar systems (Nyquist et al., 1973; Steinberg and Winsberg, 1974). The prime reason for the discrepancy must lie in the energy of the recoiling nuclei entering in the calculation of retention by Tang and Anders (1988b), which is based on considerations by Ray and Völk (1983). Based on the results, it appears questionable that spallation contributes significantly to the observed variations of 21Ne/22Ne ratios among various SiC grain‐size separates (Lewis et al., 1994). We rather suggest that the variations, just as it has been observed for Kr and Ba already (Lewis et al., 1994; Prombo et al., 1993), have a nucleosynthetic origin. Confirmation needs input of improved nuclear data and stellar models into new network calculations of the nucleosynthesis in AGB stars of elements in the Ne region. Finally we argue that, to determine presolar system irradiation effects, spallation Xe is more favorable than is Ne, primarily because of smaller recoil losses for Xe. Although preliminary estimates hint at the possibility that the larger (>1 μm) grains are younger than the smaller (<1 μm) ones, the major uncertainty for a quantitative evaluation lies in the exact composition of the Xe‐N component thought to originate from the envelope of the SiC grains' parent stars.  相似文献   

4.
We analyzed noble gases in an oxidized residue prepared from a HF‐HCl residue of the Saratov L4 chondrite. The Ar, Kr, and Xe concentrations in the oxidized residue are two orders of magnitude lower than those in the HF‐HCl residue, and they are close to concentrations in the bulk. The He and Ne concentrations are similar in the three samples. The Ne isotopic ratios are almost purely cosmogenic, indicating absence of presolar diamonds (the carrier of the HL component). Thus, Saratov contains phase Q without presolar diamond. A study of the Raman spectroscopic parameters for the HF‐HCl residue and the oxidized residue shows large changes due to oxidation. The directions of these changes are the same as observed in Allende, except oxidation increased the ID/IG (intensity ratio of the D band to the G band) in Saratov but decreased in Allende. This difference may be attributed to the different crystalline stages of carbon in both meteorites. The shifts in the Raman parameters to a discrete and/or more expanded region suggest that (1) oxidation changes the crystalline condition of graphitic carbon, (2) phase Q is not a dissolved site, and (3) the release of Q‐gas is simply related to the rearrangement of the carbon structure during oxidation.  相似文献   

5.
Abstract— Nineteen diamond aggregate specimens (1–2 mm in size) from impactites of Popigai crater and five diamond samples (5–7 mm in size) from Ebeliakh river placers were studied. Our investigations indicate that samples from Ebeliakh were formed in an impact event with the exception of one specimen (Y7). The carbon isotopic composition of diamonds from Popigai varies within the previously reported limits (δ13C, ?8 to ?22%); whereas, diamonds from Ebeliakh placers show heavier values of δ13C (?7 to ?10%). All the specimens studied contain very low amounts of N, mostly <20 ppm, but a few contained up to 60 ppm. For specimens, where the quantity of N allowed reliable analysis, δ15N values were found to be in the range of ?3.9 to +11.9%. On the basis of combined Ar and N study, it was concluded that impact diamonds studied here can be a mixture of at least two types of gas carriers (e.g., different diamond components). A possible explanation would be involvement of a carbon vapour deposition (CVD) process or diamond growth in the impact melt in addition to the direct graphite-diamond shock transformation. The δ13C distributions and different N/36Ar correlations have indicated a difference between impact diamonds from Ebeliakh and diamonds extracted from Popigai crater. This could be explained by the existence of different diamond populations formed during the Popigai impact event. On the other hand, Ebeliakh diamonds could have resulted from a separate impact event to Popigai and an alternative crater is yet to be found.  相似文献   

6.
Abstract— A new olivine‐pigeonite ureilite containing abundant diamonds and graphite was found in the United Arab Emirates. This is the first report of a meteorite in this country. The sample is heavily altered, of medium shock level, and has a total weight of 155 g. Bulk rock, olivine (Fo79.8–81.8) and pyroxene (En73.9–75.2, Fs15.5–16.9, Wo8.8–9.5) compositions are typical of ureilites. Olivine rims are reduced with Fo increasing up to Fo96.1–96.8. Metal in these rims is completely altered to Fehydroxide during terrestrial weathering. We studied diamond and graphite using micro‐Raman and in situ synchrotron X‐ray diffraction. The main diamond Raman band (LO = TO mode at ?1332 cm?1) is broadened when compared to well‐ordered diamond single crystals. Full widths at half maximum (FWHM) values scatter around 7 cm?1. These values resemble FWHM values obtained from chemical vapor deposition (CVD) diamond. In situ XRD measurements show that diamonds have large grain sizes, up to >5 μm. Some of the graphite measured is compressed graphite. We explore the possibilities of CVD versus impact shock origin of diamonds and conclude that a shock origin is much more plausible. The broadening of the Raman bands might be explained by prolonged shock pressure resulting in a transitional Raman signal between experimentally shock‐produced and natural diamonds.  相似文献   

7.
Abstract— Chondrules are generally believed to have lost most or all of their trapped noble gases during their formation. We tested this assumption by measuring He, Ne, and Ar in chondrules of the carbonaceous chondrites Allende (CV3), Leoville (CV3), Renazzo (CR2), and the ordinary chondrites Semarkona (LL3.0), Bishunpur (LL3.1), and Krymka (LL3.1). Additionally, metalsulfide‐rich chondrule coatings were measured that probably formed from chondrule metal. Low primordial 20Ne concentrations are present in some chondrules, while even most of them contain small amounts of primordial 36Ar. Our preferred interpretation is that‐in contrast to CAIs‐the heating of the chondrule precursor during chondrule formation was not intense enough to expel primordial noble gases quantitatively. Those chondrules containing both primordial 20Ne and 36Ar show low presolar‐diamond‐like 36Ar/20Ne ratios. In contrast, the metal‐sulfide‐rich coatings generally show higher gas concentrations and Q‐like 36Ar/20Ne ratios. We propose that during metalsilicate fractionation in the course of chondrule formation, the Ar‐carrying phase Q became enriched in the metal‐sulfide‐rich chondrule coatings. In the silicate chondrule interior, only the most stable Ne‐carrying presolar diamonds survived the melting event leading to the low observed 36Ar/20Ne ratios. The chondrules studied here do not show evidence for substantial amounts of fractionated solar‐type noble gases from a strong solar wind irradiation of the chondrule precursor material as postulated by others for the chondrules of an enstatite chondrite.  相似文献   

8.
Abstract— Carbon isotopic compositions were measured for shock‐produced diamond and shocked graphite formed at peak pressures ranging from 37 to 52 GPa. The δ13C values of diamonds produced in a sealed container were generally lower than that of the initial graphite. The differences in the carbon isotopic composition between initial graphite and shocked graphite/diamond may reflect kinetic isotopic fractionation during the oxidation of the graphite/diamond and/or analytical artifacts possibly induced by impurities in the samples. The pressure effect on the isotopic fractionations between graphite and diamond can be estimated from the δ13C values of impurity‐free diamonds produced using a vented container from which gases, including oxygen, in pore spaces escaped during or after the diamond formation (e.g., 0.039 ± 0.085‰ at a peak pressure of 52 GPa). Any isotopic fractionation induced by shock conversion of graphite to diamond is too small to be detected in natural shock‐induced diamond‐graphite systems related to terrestrial impact cratering processes.  相似文献   

9.
Abstract— ‐The elemental and isotopic abundances of Te and Pd have been measured by thermal ionization mass spectrometry in a purified sample of interstellar nanodiamonds from the Allende meteorite, after combustion of the diamonds in an oxygen plasma. Small positive anomalies were found in 128Te (4.0 ± 1.5 %0) and 130Te (9.3 ± 2.8 %0) from three analyses of the Allende nanodiamond sample EB, and in 110Pd (9.4 ± 5.7 %0) from two analyses of the same sample. No other anomalies of a significant nature were found in either Te or Pd. These results are consistent with the neutron burst model (Meyer et al., 2000), and the r‐process based rapid separation model of Ott (1996) in that 128, 130Te and 110Pd are enhanced relative to their solar abundances. However, in the framework of the neutron burst model, some separation between stable products and radioactive precursors may be required in order to be consistent with the full data set of Te isotopes. In the framework of the rapid separation scenario, our data suggests a separation time of approximately 4000 s, based on the magnitudes of the precursor life‐times for 128Te and 130Te. The elemental abundance ratio Te‐H/Xe‐H agrees with the prediction of the rapid separation model, provided little fractionation occurred during trapping of the exotic components by the diamonds, but differs significantly from expectations based on the neutron burst model. Differences in the inferred 128Te/130Te ratio between our work and that of Richter et al. (1998) point to the need for further investigations.  相似文献   

10.
Four ureilites subjected to impact metamorphism in a pressure range of ~15–100 GPa were investigated for mineralogical and petrological features and optical luminescence of their diamonds with the aim to understand how properties of ureilitic diamonds are correlated with shock and thermal histories of the host meteorite. Petrological data show that all the investigated ureilites experienced multistage metamorphic histories. Some of them were shocked at least twice or/and underwent high‐temperature thermal metamorphism and fluid metasomatism in the parent body interior. Photoluminescence spectra of individual diamond grains reveal the presence of neutral and negatively charged nitrogen‐vacancy (NV0 and NV?, respectively) and H3 (two nitrogens and a vacancy) defects, indicating relatively high nitrogen contents of the diamonds and some degree of thermal annealing of the grains. The diamond grain size and morphology, a texture of graphite‐diamond aggregates, and spectroscopic properties of the diamond phase vary widely both within an individual meteorite and between the ureilites. Shock‐driven transformation of sp2‐C into diamond provides the most natural explanation of the observed spectroscopic diversity of the diamond grains if one takes into account strong dependence of the PT parameters and efficiency of the transformation on structure of the carbonaceous precursor.  相似文献   

11.
Abstract— A wide range of stellar nucleosynthetic sources has been analyzed to derive their contributions of short‐lived and stable nuclei to the presolar cloud. This detailed study is required to infer the most plausible source(s) of short‐lived nuclei through a critical comparison among the various stellar sources that include AGB stars, novae, supernovae II, Ia, and Wolf‐Rayet stars that evolved to supernovae Ib/c. In order to produce the canonical value of 26Al/27Al in the early solar system, almost all stellar sources except low‐mass AGB stars imply large isotopic anomalies in Ca‐Al‐rich inclusions (CAIs). This is contrary to the observed isotopic compositions of CAIs. The discrepancy could impose stringent constraints on the formation and thermal evolution of CAIs from different chondrites. Among the various stellar scenarios, the injection of short‐lived nuclei into the previously formed solar protoplanetary disc by a massive star of an ad hoc chosen high‐injection mass cut is a possible scenario. There is a possibility of the contribution of short‐lived nuclides by a 1.5–3 M⊙ AGB star as it implies the smallest shift in stable isotopes. A low‐mass AGB star of relatively low metallicity would be even a better source of short‐lived nuclei. However, this scenario would require independent gravitational collapse of the presolar cloud coupled with ambipolar diffusion of magnetic flux. Alternatively, numerous scenarios can be postulated that involve distant (≥10 pc) massive stars can contribute 60Fe to the presolar cloud and can trigger its gravitational collapse. These scenarios would require production of 26Al and 41Ca by irradiation in the early solar system. Significant production of 26Al and 60Fe can be explained if massive, rotating Wolf‐Rayet stars that evolved to supernovae Ib/c were involved.  相似文献   

12.
Abstract— High-purity separates of presolar diamond were prepared from 14 primitive chondrites from 7 compositional groups. Their noble gases were measured using stepped pyrolysis. Three distinct noble gas components are present in diamonds, HL, P3, and P6, each of which is found to consist of five noble gases. P3 , released between 200 °C and 900 °C, has a “planetary” elemental abundance pattern and roughly “normal” isotopic ratios. HL , consisting of isotopically anomalous Xe-HL and Kr-H, Ar with high 38Ar/36Ar, and most of the gas making up Ne-A2 and He-A, is released between 1100 °C and 1600 °C. HL has “planetary” elemental ratios, except that it has much more He and Ne than other known “planetary” components. HL gases are carried in the bulk diamonds, not in some trace phase. P6 has a slightly higher median release temperature than HL and is not cleanly separated from HL by stepped pyrolysis. Our data suggest that P6 has roughly “normal” isotopic compositions and “planetary” elemental ratios. Both P3 and P6 seem to be isotopically distinct from P1, the dominant “planetary” noble-gas component in primitive chondrites. Release characteristics suggest that HL and P6 are sited in different carriers within the diamond fractions, while P3 may be sited near the surfaces of the diamonds. We find no evidence of separability of Xe-H and Xe-L or other isotopic variations in the HL component. However, because ～1010 diamonds are required to measure a Xe composition, a lack of isotopic variability does not constrain diamonds to come from a single source. In fact, the high abundance of diamonds in primitive chondrites and the presence of at least three distinct noble-gas components strongly suggest that diamonds originated in many sources. Relative abundances of noble-gas components in diamonds correlate with degree of thermal processing (see companion paper), indicating that all meteorites sampled essentially the same mixture of diamonds. That mixture was probably inherited from the Sun's parent molecular cloud.  相似文献   

13.
Abstract— Bottke et al. (2007) suggested that the breakup of the Baptistina asteroid family (BAF) 160+30/‐20 Myr ago produced an “asteroid shower” that increased by a factor of 2–3 the impact flux of kilometer‐sized and larger asteroids striking the Earth over the last ?120 Myr. This result led them to propose that the impactor that produced the Cretaceous/Tertiary (K/T) mass extinction event 65 Myr ago also may have come from the BAF. This putative link was based both on collisional/dynamical modeling work and on physical evidence. For the latter, the available broadband color and spectroscopic data on BAF members indicate many are likely to be dark, low albedo asteroids. This is consistent with the carbonaceous chondrite‐like nature of a 65 Myr old fossil meteorite (Kyte 1998) and with chromium from K/T boundary sediments with an isotopic signature similar to that from CM2 carbonaceous chondrites. To test elements of this scenario, we obtained near‐IR and thermal IR spectroscopic data of asteroid 298 Baptistina using the NASA IRTF in order to determine surface mineralogy and estimate its albedo. We found that the asteroid has moderately strong absorption features due to the presence of olivine and pyroxene, and a moderately high albedo (?20%). These combined properties strongly suggest that the asteroid is more like an S‐type rather than Xc‐type (Mothé‐Diniz et al. 2005). This weakens the case for 298 Baptistina being a CM2 carbonaceous chondrite and its link to the K/T impactor. We also observed several bright (V Mag. ≤16.8) BAF members to determine their composition.  相似文献   

14.
We measured the contents and isotopic compositions for C, N, and noble gases in the diamond fractions separated in a heavy liquid ( = 2.9 g/cm3) from a sample enriched with diamond from the Novo Urei ureilite. The results show that the concentrations of nitrogen and noble gases in the diamond fraction isolated from the supernatant (the fraction is named DNU-1) are more than a factor of 1.5 higher than those in the diamond fraction from the residue (DNU-2). This difference is probably caused by smaller sizes of grains and (or) clusters of smaller grains as well as by larger defectiveness of the crystal lattice of the diamond in the DNU-1 fraction as compared to DNU-2. Both fractions are similar in the isotopic composition of C and N and in the ratios of trapped chemical elements. The results obtained and the published data concerning C, N, and noble gases in different fractions of other ureilites allow us to conclude the following. (1) The ureilite diamond was most likely formed from graphite and the fine-grained crystalline (or semiamorphous) carbonaceous phase as a result of shock transformation in the parent bodies. (2) The negative result in the search for the isotopically light component of nitrogen (15N is about –100) in the Antarctic unshocked ureilite ALH 78019 (Rai et al., 2002), which introduced serious difficulties for explaining the origin of the ureilite diamond in the parent bodies during the impact, is most likely caused by the absorption of atmospheric nitrogen by the carbonaceous material in the processes of terrestrial weathering. (3) The source of light nitrogen (15N –100) in the ureilite diamond was probably the presolar diamond in the initial carbonaceous material of the ureilite parent bodies, because the impurity elements, including nitrogen (15N < –350), in this diamond could be trapped in the magmatic processes by the carbonaceous material, which became a precursor of the ureilite diamond in the shock event.  相似文献   

15.
Abstract— We have spectrophotometrically observed 433 Eros, the target of the NEAR‐Shoemaker spacecraft, on 1995 December 4 from 1.25 to 3.35 μm. As expected, Eros shows no evidence of an absorption feature >5% in the 3 μm region, and is interpreted to have an anhydrous surface within observational uncertainties. Our observations in the JHK region agree with previous work by Chapman and Morrison (1976) and Murchie and Pieters (1996), but differ from the near‐infrared spectrometer spectra reported by Clark et al. (2001). Our calculations indicate that thermal flux from Eros is not responsible for this mismatch.  相似文献   

16.
The results of ground-based spectrophotometry of the icy Galilean satellites of Jupiter—Europa, Ganymede, and Callisto—are discussed. The observations were carried out in the 0.39–0.92 μm range with the use of the CCD spectrometer mounted on the 1.25-m telescope of the Crimean laboratory of the Sternberg Astronomical Institute in March 2004. It is noted that the calculated reflectance spectra of the satellites mainly agree with the analogous data of the earlier ground-based observations and investigations in the Voyager and Galileo space missions. The present study was aimed at identifying new weak absorption bands (with the relative intensity of ～3–5%) in the reflectance spectra of these bodies with laboratory measurements (Landau et al., 1962; Ramaprasad et al., 1978; Burns, 1993; Busarev et al., 2008). It has been ascertained that the spectra of all of the considered objects contain weak absorption bands of molecular oxygen adsorbed into water ice, which is apparently caused by the radiative implantation of O+ ions into the surface material of the satellites in the magnetosphere of Jupiter. At the same time, spectral features of iron of different valence (Fe2+ and Fe3+) values typical of hydrated silicates were detected on Ganymede and Callisto, while probable indications of methane of presumably endogenous origin, adsorbed into water ice, were found on Europa. The reflectance spectra of the icy Galilean satellites were compared to the reflectance spectra of the asteroids 51 Nemausa (C-class) and 92 Undina (X-class).  相似文献   

17.
Abstract— We examine quantitatively the suggestion that the heavy anomalous isotopes of Xe-HL found in meteoritic diamonds were produced by a short intense neutron burst and then implanted into the diamonds. Using a large nuclear reaction network we establish one (out of many) neutron irradiation histories that successfully reproduces the heavy isotopes of Xe-HL, and then evaluate what that same history would produce in every heavy element. This has become more relevant following recent measurement of anomalous Ba and Sr in those same diamond samples. Therefore we offer these calculations as a guide to the anomalies to be expected in all elements if this scenario is correct. We also discuss several other aspects of the problem, especially the established contradictions for Ba, the observed Kr pattern, the near normalcy of 129Xe, and some related astrophysical ideas. In particular we argue from p-process theory that the observed deficit of 78Kr in correlation with 124–126Xe excess implicates Type II supernovae as the diamond sources. However, our more complete astrophysical conclusions will be published elsewhere. This present work is offered as computational expectation for this class of models and as a guide to considerations that may accelerate the digestion of new experimental results in the diamonds.  相似文献   

18.
Abstract— The CV (Vigarano‐type) chondrites are a petrologically diverse group of meteorites that are divided into the reduced and the Bali‐like and Allende‐like oxidized subgroups largely based on secondary mineralogy (Weisberg et al., 1997; Krot et al., 1998b). Some chondrules and calcium‐aluminum‐rich inclusions (CAIs) in the reduced CV chondrite Vigarano show alteration features similar to those in Allende: metal is oxidized to magnetite; low‐Ca pyroxene, forsterite, and magnetite are rimmed and veined by ferrous olivine (Fs40–50); and plagioclase mesostases and melilite are replaced by nepheline and sodalite (Sylvester et al., 1993; Kimura and Ikeda, 1996, 1997, 1998). Our petrographic observations indicate that Vigarano also contains individual chondrules, chondrule fragments, and lithic clasts of the Bali‐like oxidized CV materials. The largest lithic clast (about 1 times 2 cm in size) is composed of opaque matrix, type‐I chondrules (400–2000 μm in apparent diameter) surrounded by coarse‐grained and fine‐grained rims, and rare CAIs. The matrix‐chondrule ratio is about 1.1. Opaque nodules in chondrules in the clast consist of Cr‐poor and Cr‐rich magnetite, Ni‐ and Co‐rich metal, Ni‐poor and Ni‐rich sulfide; low‐Ni metal nodules occur only inside chondrule phenocrysts. Chromium‐poor magnetite is preferentially replaced by fayalite. Chondrule mesostases are replaced by phyllosilicates; low‐Ca pyroxene and olivine phenocrysts appear to be unaltered. Matrix in the clast consists of very fine‐grained (<1 μm) ferrous olivine, anhedral fayalite grains (Fa80–100), rounded objects of porous Ca‐Fe‐rich pyroxenes (Fs10–50Wo50), Ni‐poor sulfide, Ni‐ and Co‐rich metal, and phyllosilicates; magnetite is rare. On the basis of the presence of the Bali‐like lithified chondritic clast—in addition to individual chondrules and CAIs of both Bali‐like and Allende‐like materials—in the reduced CV chondrite Vigarano, we infer that (1) all three types of materials were mixed during regolith gardening on the CV asteroidal body, and (2) the reduced and oxidized CV materials may have originated from a single, heterogeneously altered asteroid.  相似文献   

19.
Abstract— Using the isotopic compositions derived in Huss and Lewis, 1994a (Paper I), abundances of the P3, HL, and P6 noble-gas components were determined for 15 diamond separates from primitive chondrites of 8 chondrite classes. Within a meteorite class, the relative abundances of these components correlate with the petrologic subtype of the host meteorite, indicating that metamorphism is primarily responsible for the variations. Relative abundances of P3, HL, and P6 among diamond samples can be understood in terms of thermal processing of a single mixture of diamonds like those now found in CI and CM2 chondrites. With relatively gentle heating, primitive diamonds first lose their low-temperature P3 gases and a “labile” fraction of the HL component. Mass loss associated with release of these components produces an increase in the HL and P6 content of the remaining diamond relative to unprocessed diamond. Higher temperatures initiate destruction of the main HL carrier, while the HL content of the surviving diamonds remains essentially constant. At the same time, the P6 carrier begins to preferentially lose light noble gases. Meteorites that have experienced metamorphic temperatures ?650 °C have lost essentially all of their presolar diamond through chemical reactions with surrounding minerals. The P3 abundance seems to be a function only of the maximum temperature experienced by the diamonds and thus is independent of the nature of the surrounding environment. If all classes inherited the same mixture of primitive diamonds, then P3 abundances would tie together the metamorphic scales in different meteorite classes. However, if the P3 abundance indicates a higher temperature than do other thermometers applicable to the host meteorite, then the P3 abundance may contain information about heating prior to accretion. Diamonds in the least metamorphosed EH, CV, and CO chondrites seem to carry a record of pre-accretionary thermal processing.  相似文献   

20.
It has been found that certain optical properties of interstellar grains obtained by Hayakawaet al. (1969) from their study of the diffuse radiation of the Galaxy in far UV are not in reality consistent with the more accurate theoretical calculations of diffuse radiation for the model of the Galaxy used by Hayakawaet al. in their work. A more complex model of the Galaxy may be required for interpretation of observations in far UV.Receipt delayed by postal strike in Great Britain.  相似文献   

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