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1.
The colour of aquatic humus increases with pH. The ‘molecular weight distribution’ of a concentrated humus sample has been studied at diffrent pH-levels and ionic strength by use of a molecular sieve (Sephadex G-25) and membrane dialysis. The fraction excluded from G-25 became greater, proportionally with increasing pH, and this was apparently not affected to any great extent by the ionic strength. Membrane dialysis of acidic, alkaline and ‘natural’ samples confirmed this change of the molecular size by pH. The colour increase of aquatic humus, caused by raising pH, is associated with an increase in the size of the humus molecules. ‘Aggregation’ and condensation are proposed as possible mechanisms.  相似文献   

2.
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3.
Decomposition incorporates organic material delivered by Pacific salmon (Oncorhynchus spp.) into aquatic and terrestrial ecosystems of streams where salmon spawn. We hypothesized that salmon tissue decomposition would be faster, and macroinvertebrate abundance and biomass higher, in terrestrial compared to aquatic habitats, and this would be reflected in the nutritional quality of the tissue. Salmon tissue in coarse-mesh bags was placed in four habitats [terrestrial: riparian (RIP), gravel bars (GRA); aquatic: stream sediment surface (STR), buried in sediments (BUR)] in four southeast Alaska watersheds. After 2 (RIP, GRA) or 4 (STR, BUR) weeks of decomposition, tissue dry mass, macronutrient content, and macroinvertebrate colonizer abundance and biomass were determined. Overall, tissue decomposition was rapid (mean k = 0.088 day?1), while nutritional quality remained high based on elemental ratios (mean C:N = 4.9; C:P = 140; N:P = 30), and differed among habitats (Linear-mixed effects model p < 0.05). Macroinvertebrate assemblages colonizing carcasses were unique to each habitat, although Diptera generally dominated. In terrestrial habitats, the dominant macroinvertebrates were Sphaeroceridae (96 % of invertebrate abundance in RIP habitat) and Calliphoridae larvae (98 % in GRA habitat). In aquatic habitats, the dominant macroinvertebrates were Chironomidae (48 % in STR habitat) and Chloroperlidae (72 % in BUR habitat). Macroinvertebrate colonizer abundance and biomass were higher in RIP (mean 286 individuals and 22 mg g?1) than in other habitats (mean 4 individuals and 3 mg g?1) (Friedman p < 0.05). Rapid decomposition rates and high invertebrate biomass, combined with the high nutritional quality of tissue, suggest rapid incorporation of critical salmon nutrients and energy into both aquatic and terrestrial ecosystems.  相似文献   

4.
Variogram-based methods are not capable of capturing high (>2) order statistics since the variogram measures the relationship between two points at a time only. Multiple-point geostatistics (MPS) has brought new insights into many geological modeling problems. The application of MPS methods has been well documented in realizing complex geological patterns. These methods have often been used in reservoir characterization since their advent in recent decades. The frequent non-linear behaviors of geologic continuity are not limited to reservoirs, but mineral deposits bear complicated formations in many cases. Relying on the power of MPS methods and considering the complexity of geological scenarios in mineral deposits, we have applied MPS in the modeling of mineral deposits. A training image (TI) is produced using geological data from upper horizons of a porphyry copper ore deposit which have been mined out during the previous mining operations. In this study, the SNESIM algorithm has been used. A number of realizations are produced using this multiple-point geostatistical method. Extensive validation steps are performed considering the TI as the reference model. These validations first show that the TI is representative for the domain under study and also illustrates some degrees of similarity between the TI and the realizations. Despite simplifications made to the problem, the application of MPS in mineral deposit modeling still faces many challenges.  相似文献   

5.
This paper deals with the mineralogical, textural and chemical features of the dunite, peridotite, pyroxenite and gabbroic inclusions present in the Quaternary basalts of the Canary Islands. The mineralogical composition, structure and texture of the inclusions show that most of them have been formed as crystal cumulates from a nonalkaline basaltic magma in the earlier stages of its fractional crystallization. There are no co-genetic relationships between the inclusions and the host basalts, since the latter have a very strong alkaline-olivine character, although there are also some types with tholciitic aflinities. The study of the data leads to the conclusion that these inclusions can be considered as xenoliths from the basic and ultrabasic complexes that form the substratum and which outcrop in some of the Canary Islands. Attention is called to the fact that in many other volcanic zones of the world there has been a previous emplacement of basic and ultramafic layered complexes and is the question opened whether the association between stratiform-complexes and active basaltic volcanism is more frequent than has been assumed up to now.  相似文献   

6.
Spatio-temporal disease mapping can be viewed as a multivariate disease mapping problem with a given order of the geographic patterns to be studied. As a consequence, some of the techniques in multivariate literature could also be used to build spatio-temporal models. In this paper we propose using the smoothed ANOVA multivariate model for spatio-temporal problems. Under our approach the time trend for each geographic unit is modeled parametrically, projecting it on a preset orthogonal basis of functions (the contrasts in the smoothed ANOVA nomenclature), while the coefficients of these projections are considered to be spatially dependent random effects. Despite the parametric temporal nature of our proposal, we show with both simulated and real datasets that it may be as flexible as other spatio-temporal smoothing models proposed in the literature and may model spatio-temporal data with several sources of variability.  相似文献   

7.
The Method of Splitting Tsunamis (MOST) model adapted by National Oceanic and Atmospheric Administration (NOAA) for tsunami forecasting operations is praised for its computational efficiency, associated with the use of splitting technique. It will be shown, however, that splitting the computations between \(x\) and \(y\) directions results in specific sensitivity to the treatment of land–water boundary. Slight modification to the reflective boundary condition in MOST caused an appreciable difference in the results. This is demonstrated with simulations of the Tohoku-2011 tsunami from the source earthquake to Monterey Bay, California, and in southeast Alaska, followed by comparison with tide gage records. In the first case, the better representation of later waves (reflected from the coasts) by the modified model in a Pacific-wide simulation resulted in twice as long match between simulated and observed tsunami time histories at Monterey gage. In the second case, the modified model was able to propagate the tsunami wave and approach gage records at locations within narrow channels (Juneau, Ketchikan), to where MOST had difficulty propagating the wave. The modification was extended to include inundation computation. The resulting inundation algorithm (Cliffs) has been tested with the complete set of NOAA-recommended benchmark problems focused on inundation. The solutions are compared to the MOST solutions obtained with the version of the MOST model benchmarked for the National Tsunami Hazard Mitigation Program in 2011. In two tests, Cliffs and MOST results are very close, and in another two tests, the results are somewhat different. Very different regimes of generation/disposal of water by Cliffs and MOST inundation algorithms, which supposedly affected the benchmarking results, have been discussed.  相似文献   

8.
Located at the North-Eastern part of Algeria (Tellian Atlas), Constantine has crucial administrative, economic, scientific and cultural importance. It has continuously experienced significant urban evolutions during the different periods of its history. The city is located in an active seismic region within Algeria and has been struck in the past by several moderate and strong earthquakes. The strongest earthquake recorded since the beginning of instrumental seismology took place on October 27, 1985 with a magnitude M \(_\mathrm{S}=\) 5.9. Constantine presents a high seismic risk, because of its dense housing and high population density (2,374 inhabitants/km \(^{2})\) . This requires a risk assessment in order to take preventive measures and reduce the losses in case of potential major earthquake. For this purpose, a scenario based approach is considered. The building damage assessment methodology adopted for the Algerian context is adapted from HAZUS approach. In the present case, the effective Algerian seismic code response spectrum (RPA 99/2003) is considered as a seismic hazard model. The prediction of the expected damages is performed for a set of almost 29,000 buildings.  相似文献   

9.
The search for the Figure of the Earth is rooted in the age-old wonder about the world we live in. The ancient mythical notions have developed, under the tutelage of Greek systematic thought, into specific questions of the shape and size of the Earth. The history of these questions, now spanning more than two millenia, shows a continuous refinement in formulation, as each bona fide answer prompted refined measurements which, in turn, started a new round of problems. The change in concept of what one was looking for was, and still is, closely connected with the technical capability and its potential for further development. This change in concept is traced here from ancient times to the present throungh some of its milestones: Anaximander's partly invisible celestial sphere and Pythagoras' spherical Earth; Eratosthenes' exemplary combination of astronomy and land surveying for the dual purpose of determining the size of the spherical Earth and making a map of the habitable world; the identical dual purpose followed by the Académie Royale des Sciences in the 17th century, but on a more sophisticated technical level; the challenge to the spherical concept by Newton's gravitational theory and the absorption of that theory into a wider concept of the Figure of the Earth; the acknowledgment of the irregular geoid by Gauss, Bessel, and Helmert, and the changed significance of the ellipsoid; Heiskanen's and Vening Meinesz' ‘Basic Hypothesis of Geodesy’ concerning the hydrostatic equilibrium of the Earth, and O'Keefe's contradiction on the basis of satelite data; the dream of global surveys come true through satellite geodesy and the accompanying inclusion of the outer gravity field of the Earth into the concept of its Figure; and lastly, the present and projected capability of high precision measurement and the widening of the concept of the Figure of the Earth from 3-dimensional rigidity to 4-dimensional time-dependence.  相似文献   

10.
A theoretical thermal model has been worked out for the magma reservoir that would have fed the two last Plinian eruptions of Mt. Vesuvius (Barberi et al., 1981). The effect of convective motions is discussed, and it is shown that the size of convective cells and the efficiency of the process in smoothing out temperature gradients evolves in time due to the progressive viscosity increase produced by the heat lost by conductive heat transfer through the host rock. Although convection will be important throughout the history of the reservoir, until very high viscosities are reached, the pure conductive model seems to account satisfactorily for the cumulative heat loss by the reservoir. Gravitative crystal settling can occur, even in presence of convective motions, mostly during several hundred years after the magma emplacement when viscosity is not yet increased to high values.  相似文献   

11.
It has been observed that post-critically reflected S-waves and multiples from the Moho discontinuity could play a relevant role on the ground motion due to medium to strong size earthquakes away from the source. Although some studies investigated the correlation between the Moho reflections amplitudes and the damage in the far field, little attention was given to the frequency content of these specific phases and their scaling with magnitude. The 2012 Emilia seismic sequence in northern Italy, recorded by velocimetric and accelerometric networks, is here exploited to investigate Moho reflections and multiples (SmSM). A single station method for group velocity-period estimation, based on the multiple filter technique, is applied to strong motion data to detect SmSM. Amplitude and frequency scaling with magnitude is defined for earthquakes from \(\hbox {Mw}=3.9\) to \(\hbox {Mw}=5.9\) . Finally, the ability of SmSM to affect the ground motion for a maximum credible earthquake within the Po plain is investigated by extrapolating observed engineering parameters. Data analysis shows that high amplitude SmSM can be recognized within the Po plain, and at the boundaries between the Po plain and the Alpine chain, at epicentral distances larger than 80 km, in the period range from 0.25 to 3 s and in the group velocity window from about 2.6 to 3.2 km/s. 5 % damped pseudo-spectral accelerations at different periods (0.3, 1.0 and 2.0 s), and Housner intensities, are obtained from data characterized by large amplitude SmSM. A scaling relationship for both pseudo-spectral accelerations and Housner intensities is found for the earthquakes of the 2012 Emilia seismic sequence. \(\hbox {I}_{\mathrm{MCS}}\) from VII to VIII is estimated, as a result of SmSM amplitude enhancement, at about 100 km for a maximum credible earthquake ( \(\hbox {Mw}=6.7\) ) in the Po plain, showing that moderate to high damage cloud be caused by these specific phases.  相似文献   

12.
Tanna, one of the southernmost islands of the New Hebrides volcanic arc, is made of Late Pliocene to Recent island arc tholeiitic basalts and andesites, with SiO2 contents ranging from 45 to 57%. These lavas are highly porphyritic (30–50% in volume): phenocrysts of plagioclase are the most abundant, together with olivine and clinopyroxene. The groundmass contain plagioclase, augite, olivine, magnetite and glass; pigeonite, tridymite, sanidine and, rarely, biotite may also occur. The olivines and clinopyroxenes show an iron enrichment from the cores of phenocrysts to their rims and the groundmass crystals, but their compositional variations are not correlated with the Mg/Fe ratio of bulk host rocks, the most Fe-rich compositions being found in Mg-rich lavas. Plagioclase compositions range from An95 to An60 in the basalts and An60 to An50 in the andesites, but, within each group, they are not correlated with SiO2 or Na2O contents of host lavas. Consequently, the bulk major element compositions of Tanna volcanic rocks cannot be considered as primarily controlled by crystal separation from successive liquids. The oxyde-SiO2 variations diagrams, and the modal compositions and mineral chemistry show that crystal accumulation is the predominant mechanism accounting for bulk rock compositions. However, this does not exclude fractional crystallization: the variation of the calculated groundmass mineralogy strongly suggest the occurrence of crystal removal mainly clinopyroxene and magnetite.  相似文献   

13.
The Tertiary and Recent volcanics of Mexico occur in two provinces. The Cordillera Province is made up of about 1700 m of ignimbrite sheets overlain and intercalated in the upper part by olivine basalt and basaltic andesite. The Rio Lerma Province extends transversely across Mexico and in the Valley of Mexico the lavas consist mainly of andesite and dacite, 68 % of those analysed having 62 | 4.7 % SiO2. A total of 108 chemical analyses were made for the major elements, 90 of these including determinations of Cr, Ni, Cu, Zn, Rb, Sr, Ba, Th and Pb for two areas, the Valley of Mexico in the Rio Lerma Province and the Guadalajara region which lies at the intersection of the two provinces. Computer constructions of normative components in the basalt tetrahedron and other projections support an origin of partial melting of tholeiitic to pyrolitic material for the production of andesite. The Guadalajara lavas have consistently higher K/SiO2 and K/Rb ratios and lower Mg/SiO2 ratio than the Valley of Mexico rocks suggesting generation at greater depth.  相似文献   

14.
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15.
In the process of coal gasification, the phase transition from water to water vapour takes place as a result of high temperature. Thus, the parameters of the fluid flowing through the pores of the elastic skeleton change in a significant way. The goal of this work is to calculate the fluid flow process at a variable temperature using Finite Element Method and to determine the soil consolidation process taking place under its own weight and temperature changes. The mathematical model of thermal consolidation for a Biot body accounts for the phase transition of a liquid. Numerical calculations for a homogeneous and isotropic porous medium, consisting of two conventionally accepted layers, were carried out using the FlexPDE v. 6 software. The obtained results are a first approximation of the actual processes taking place under complex geological conditions. They make it possible to determine, in approximation, the range of the phase transition and the influence of water vapour filtration on soil consolidation.  相似文献   

16.
The rhyodactic O’Leary Porphyry which forms the Pleistocene (0.233±0.37 m.y.) volcanic domes of O’Leary Peak and Darton Dome in the San Francisco Volcanic Field (northern Arizona, U.S.A.) contains sanidine phenocrysts with oligoclase mantles (rapakivi texture). Rapakivi texture occurs worldwide in silicic rocks of many ages and has been attributed to various igneous and metamorphic processes. The O’Leary Porphyry contains both mantled and unmantled sanidine (both are Or63–69 Ab30–36An1), oligoclase and quartz phenocrysts, labradorite (An53Ab45Or2) and kaersutite xenocrysts and andesite xenoliths. The compositional range of oligoclase is the same (An11–26Ab70–80Orr–10) for the rapakivi mantles, the oligoclase phenocrysts, and the oligoclase crystals poikilitic within sanidines. Most mantles are discontinuous. The sanidine appears to have been resorbed prior to mantling. Experimental melting studies on the O’Leary Prophyry show that, for a 15 wgt.% water system, plagioclase crystallized prior to sanidine and quartz crystallized last. The O’Leary Porphyry, although inhomogeneous, plots on a Q-Or-Ab-An diagram well within the plagioclase stability field. Poikilitic plagioclases within sanidines further support crystallization of plagioclase prior to sanidine in the O’Leary Porphyry. Exsolution of a ternary feldspar to form a plagioclase mantle is the most commonly accepted igneous theory of rapakivi texture formation but has been eliminated as the origin of the O’Leary Porphyry rapakivi. Petrologic models by Tuttle and Bowen and by Stewart are rejected for the O’Leary rapakivi because of inconsistencies with the O’Leary occurrences. Two theories are viable for the O’Leary rapakivi texture. First, is a decrease in water vapor pressure which would enlarge the plagioclase stability field possibility causing mantling of metastable sanidines. The second and preferred theory is that of an addition of sodium and calcium by basification (chemical assimilation without melting) of the xenoliths within the O’Leary Porphyry. This would move the bulk composition of the melt into the plagioclase field possibly resulting in crystallization of plagioclase on sanidine crystals. Diffusion of sodium and calcium from the xenoliths to sanidine would result in mantling only those crystals near to the xenoliths. Later, convection would result in distribution throughout the melt of rapakivi, unmantled sanidines, and xenolithic kaersutite as is seen in the porphyry. Basic xenoliths are extremely common in rapakivi-bearing rocks. Those within the O’Leary Porphyry are andesitic and show resorption, and in some areas of O’Leary Peak itself, have been drawn out into schlieren.  相似文献   

17.
Forecasts of the dynamics of meteorological characteristics in the basins of the Olenek and Indigirka rivers (the Republic of Sakha) in the XXI century have been obtained for four IPCC global climate scenarios of SRES family, corresponding to specified scenarios of economic, technological, political, and demographic development of human civilization. The forecasts have been used to calculate scenarios of possible changes in water balance components for the basins under consideration up to the year of 2063. The calculation procedure involves a physically-based model of heat and mass exchange between the land surface and the atmosphere SWAP and climate scenario generator MAGICC/SCENGEN.  相似文献   

18.
An overview of the geomagnetic observations made in the northern part of Russia is presented from a historical perspective. Several stations were deployed on the territory of the former Soviet Union during the International Geophysical Year, 1957–1958, with the active participation and guidance of the Interagency Geophysical Committee which is inherited by the Geophysical Center of the Russian Academy of Sciences (GC RAS). In the 1990s, the majority of these stations, especially those in the remoter regions, were closed. Nowadays, the geomagnetic network, including the observatories of the INTERMAGNET program, has been restored. Examples of high-latitude geomagnetic variations in the Russian longitudinal sector are shown, and maps and trends of the secular variation over the territory of Russia presented. Particular attention is paid to the automated processing of data and to the analysis methods used. To process the growing amount of high-resolution geomagnetic data, sophisticated mathematical methods based on the fuzzy logic approach and new discrete mathematical analysis algorithms have been developed. The formal methods and algorithms for recognizing both artificial and natural disturbances in the magnetograms are described.  相似文献   

19.
More than two hundred new analyses of basaltic rocks from the Canary Islands are presented. The available data show that the earlier successions have similar variation trends throughout the archipelago; these trends represent all the intermediate types between basic differentiates (oceanites, ankaramites) and more salic differentiates (trachy-basalts, hawaiites). In the more recent volcanic series, the study shows that there is a magmatic diversification with different variation trends in the Eastern than in the Central Canary Islands. In the latter the alkaline character becomes stronger in the successive periods of volcanic activity which have been established in each island. In the Eastern islands the basaltic evolution is, on the contrary, towards basaltic rocks with tholeiitic affinities.  相似文献   

20.
Pumiceous pyroclastic products are present as flows and falls at several stages of the evolution of the southern Guadeloupe volcanic island. An understanding of this volcanism had to rely on detailed petrochemical data of these products to complement similar data for effusive rocks so as to yield complete stratigraphical coverage. On the other hand most pumiceous rocks are more or less conspicuousily banded suggesting that mixing phenomena occurred to different degrees in their genesis. Three major classes of pumiceous products are found: (1) the Axial Chain deposits (2.0–0.5 My) are characterized by An90, 75-55 + En55 + Wo42En37 + Usp35-37 ± Fo68 ± Hble, SiO2 60%, SiO2/Th 35.6, and La/Th 3.9. Banded samples have components that differ in evolution indices by about 50%; (2) the Bouillante Chaine pyroclastics (0.3–0.1 My) consist of scattered deposits with variable mineralogical and geochemical compositions that seem to have erupted from a number of small eruptive centers. Qz-dacitic pumice is common with An90, 70-45 + En66-56 + Usp32-38 + Ilm94 + Hble ± Wo40-42En40-42, SiO2 62%, SiO2/Th 22.9, and La/Th >4. Mixed pumice samples have highly contrasted evolution indices differing by up to 120%; (3) the Pintade pumice flows and falls correspond to the major pyroclastic event (approx. 10 km3) in the southern Basse Terre area. They are characterized by An85-70 + En66-56 + Usp32-37 ± Wo42En42, SiO2/Th 18.7-22?6, and La/Th 3.0-4.0. Banded pumice lumps are scarce and show slight compositional contrasts; differences in evolution indices do not exceed 38%. Axial and Bouillante chain pyroclastics and Grande Découverte volcano pumice respectively, form two different families in trace element plots. Minor elements in pyroxenes also are distinctive. These trends are similar to those obtained for effusive rocks and define comagmatic series. Major and trace element data for the separated components of inhomogeneous pumice in each formation always plot in the corresponding series. These chemical discriminants can be used to attribute samples of unknown provenance to a given volcanic ensemble. An inverse relationship between differences in evolution indices in inhomegeneous pumice and the volume of any single eruptive sequence is noted. This is an indication that pumiceous pyroclastic rocks were erupted from a zoned magma chamber. We favor an interpretation where zonation is produced by influx of less envolved magma in superficial differentiated chambers which is a direct cause for eruption.  相似文献   

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