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1.
Peter Nielsen 《Coastal Engineering》1985,9(3):261-276
An empirical analysis is performed on the most detailed, recent measurements of turbulent oscillatory boundary layer flow. The measurements show that throughout elevations where the flow can be considered horizontally uniform, one deficit model is sufficient for describing the fundamental mode. Some general properties of the non dimensional velocity deficit D1(z) appear with striking consistency. First of all the identity , which is a theoretical result for smooth laminar flow, seems to hold with great accuracy for a large range of turbulent flow conditions as well. This is of principal theoretical interest because all previous analytical eddy viscosity models as well as numerical mixing length models predict a consistent and fairly large difference between Arg D1 and . If the identity between and Arg D1 extends all the way to the bed, it means that the bed shear stress leads the free stream velocity by 45 degrees. It is also found that the structure of smooth turbulent oscillatory flows as measured by Kalkanis (1964) corresponds to a sharp maximum in the normalized energy dissipation rate. 相似文献
2.
Trevor J. McDougall 《Progress in Oceanography》1981,10(2):91-121
The term cabbeling describes the convection that can occur when a mixture of two oceanic water masses is more dense than both of the parent water masses. When the two water masses are situated one above the other, the temperature and salinity distributions are in the correct senses for double-diffusive convection to occur and it is found that the prime effects of the nonlinearity of the equation of state are firstly to drive a greater level of double-diffusive convective activity in the lower layer than in the upper layer, and secondly, to make the lower edge of the interfacial region less gravitationally stable. Both of these effects cause the interface to migrate upwards as the lower layer grows at the expense of the upper layer. We introduce a nondimensional parameter (called the cabbeling parameter) which represents the importance of the nonlinearity of the equation of state:— is zero when the equation of state is linear and when cabbeling is normally thought to be possible, is greater than unity. Experiments set up in both the finger and diffuse sense show how the nondimensional measure of the upward interface migration (called the “entrainment” parameter ) varies with the density anomaly ration R? for various values of between zero and 2.0 and that no abrupt change in this behaviour occurs at . It is impossible to explain these observation by neglecting double-diffusive convection and considering only the convection driven by the conventional cabbeling instability. The successful interpretation of the laboratory results relies on considering the effects of a non-linear equation of state on the double-diffusive convection process. 相似文献
3.
Spectrophotometric measurements are reported for the first apparent dissociation constant of hydrogen sulfide in seawater over the temperature range 7.5–25°C and 2–35.8‰ salinity. These data are described by the expression . The second apparent dissociation constant in potassium chloride solution was estimated potentiometrically using a sulfide specific ion electrode. A value of ～13.6 was found for pK2′ at a KCl concentration of 0.67 M. It is suggested that explicit reference to the sulfide ion, S2?, in describing equilibria in marine waters be dropped in favor of a formulation involving the bisulfide ion, HS?. 相似文献
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The apparent solubility product of calcite was measured by saturometry as a function of temperature and salinity. Simplified equations for the carbonic-acid dissociation constants of Mehrbach et al., 1973 (Limnol. Oceanogr., 18: 897–907) have been derived from their experimental data and used to calculate apparent solubility product, K′sp, K′sp at 25°C and 35‰ salinity, was found to be K′sp = 4.70 × 10?7(mol2kgseawater?2) An equation was fitted to the experimental data, resulting in pK′sp = 6.5795 ? 3.7159 × 105(TS) + 0.91056(T/S) ? 22.110(1.0/S)The mean activity coefficients, , were calculated at various temperatures and salinities, using the thermodynamic solubility product of Jacobson and Langmuir, 1974 (Geochim. Cosmochim. Acta, 38: 301–318) and the apparent solubility products quoted in their paper. The change in K′sp at each salinity, as a function of temperature, was used to calculate the apparent enthalpy of dissociation for calcite, ΔH′, and the extrapolated value of ΔH0 was in good agreement with that of Jacobson and Langmuir. Finally, this work was used to calculate saturation profiles for oceanic stations and as a basis for comment of the accuracy of in-situ saturometry, as well as the applicability of in-situ K′sp pressure corrections. 相似文献
6.
Examination of the consequences of the stoichiometric association constant for MgSO4 in seawater as advocated by Johnson and Pytkowicz (1979) leads to a thermodynamic association constant Ka = 212.6, a value 32% greater than KA = 160 derived from conductance data. Use of Ka = 160 leads to a in essential agreement with the value of 10.2 reported by Kester and Pytkowicz (1969). 相似文献
7.
A field investigation was carried out to collect data of inner bar migration. Profiles were measured once or twice a week for a two-year period at Naka Beach, Ibaraki Prefecture, Japan. It was found that the onshore migration of inner bars could be described by two dimensionless quantities as: where (Hb)max is the maximum value of daily average breaker height during one interval between surveys, Tmax is the average wave period of the day giving (Hb)max, D is the mean size of the beach sediment, and g is the acceleration due to gravity. Analyses based on surfzone sediment dynamics yields , where is the average speed of onshore bar-migration, b is the bar height, is the average breaker height, and w is the fall velocity of the beach sediment. Nomographs for the speed of landward migrating bars are also presented. 相似文献
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The various assumptions implicit in the calculation of acid dissociation constants (based on ionic medium standard states) from potentiometric titrations using a cell with liquid junction (i.e. a pH measuring cell) have been examined. It was concluded that results can be obtained having an accuracy commensurate with the experimental precision. It has been shown that although the precise composition of the medium is a function of the hydrogen ion concentration (because of the protolytic nature of some of the ions in the media, e.g., sulphate and fluoride), the effect of such variations in the medium composition can be compensated for when defining the activity of hydrogen ion on an ionic medium standard state by defining the concentration of hydrogen ion as: where βHSO4 and βHF are the relevant association constants and ST and FT are the total concentrations of sulphate and fluoride, respectively.This approach was used to obtain values for the ionic product of water (KW) in artificial seawater media at various temperatures and ionic strengths. These were fitted to give the equation (molal concentration units): where I is the formal ionic strength of the artificial seawater medium and T is the absolute temperature. The values obtained are in reasonable agreement with those found by previous workers. 相似文献
10.
小尺度湍流过程对河口物质输运与能量交换至关重要。受传统观测方法的限制, 河口浅水区域的剖面观测资料至今较为匮乏, 进而限制了湍流过程的研究。为此, 采用新型5波束声学多普勒流速剖面仪(Nortek Signature 1 000 kHz AD2CP)在长江口开展湍流剖面观测, 获取高频、低噪的高质量湍流剖面数据, 并与声学多普勒点式流速仪(acoustic doppler velocimeters, ADV)同步观测的数据进行对比。结果表明, 通过AD2CP与ADV获得的近底部边界层摩阻流速u*、拖曳系数Cd、雷诺应力SR等特征参数基本一致, 底摩擦与波浪能量为河口区域湍动能的主要输入源。湍流垂向结构存在显著的非局地平衡, 即温盐等斜压作用引起的浮力通量、对流项以及强波浪作用影响的脉动压力做功、黏性输运等因素可能为长江口湍流非局地平衡的主因。 相似文献
11.
The apparent ionization constants for silicic acid, k1 and k2, and the ionic product of water, kw, have been determined in 0.05, 0.1, 0.2, 0.4 and 2.0 M Na(CI) media at 25°C. The medium dependence of these constants was found to fit equations of the form where K1 is the ionization constant in pure water, αi and bi are parameters of which bi has been adjusted to present data. The following results were obtained (αi, bi): pK1 = 9.84, (1.022, ?0.11); pK2 = 13.43, (2.044, ?0.20); and pKw = 14.01 (1.022, ?0.22). ki values are collected in Tables I and II. Attempts have been made to explain the medium dependence of k1 and k2 with weak sodium silicate complexing according to the equilibria giving k11 = 0.37M?1 and k21= 3.0M?1. However, these weak interactions cannot be interpreted unambiguously from potentiometric data at different 1-levels. Probably the medium dependence could equally well be expressed by variations in the activity coefficients.The measurements were performed as potentiometric titrations using a hydrogen electrode. The average number of OH- reacted per Si(OH)4, Z, has been varied within the limits 0 ? Z ? 1.1 and B1, the total concentration of Si(OH)4, between 0.001 M and 0.008 M. k1 was evaluated from experimental data with B ? 0.003 M, and k2 with B ? 0.008 M and Z ? 0.95. 相似文献
12.
A number of parameterisations for the simulation of mixing processes in the thermocline are compared and tested against the microstructure data of the PROVESS campaigns, conducted in the northern part of the North Sea during the autumn of 1998. The transport term in the turbulent kinetic energy equation is parameterised via the introduction of a third stability function Sk for turbulent energy diffusion. The formulations are compared with a simpler scheme based upon limiting conditions for turbulence variables. Improved results are obtained with a new form of Sk. The best agreement is, however, found with the simpler limiting scheme. This is explained in terms of a turbulence length scale theory for stably stratified turbulence. In agreement with previous laboratory and ocean data it is found that the ratios of the Thorpe and Kolmogorov scales to the Ozmidov length scale approach critical limiting values in the thermocline. The first of these conditions is satisfied when limiting conditions are implemented into the scheme, providing the necessary minimum value for the dissipation rate, whereas the schemes without limiting conditions fail to produce this critical ratio. The basic reason for this failure is that the Thorpe scale is overestimated, which is shown to be connected to an even larger overprediction of the dissipation rate of temperature variance. To investigate the impact of non-resolved advective processes and salinity stratification on the turbulence predictions, additional numerical experiments were conducted using a simple scheme for data assimilation. The best agreement is found again with the limiting scheme, which is able to make reasonable predictions for the dissipation rate without knowing the detailed shape of the mean stratification profile. It is shown that advective transport due to tidally and wind-driven motions has a non-negligible impact on vertical mixing. This is seen in the data and the models by periodic enhancements of turbulent mixing inside the thermocline. 相似文献
13.
C.Ernest Knowles 《Estuarine, Coastal and Shelf Science》1983,17(4):395-404
According to small-amplitude theory, the surface gravity-wave spectrum can be estimated from a subsurface pressure-fluctuation spectrum by applying a factor (K) that compensates for the attenuation of surface-wave amplitude as the depth below the water surface and the wave frequency increase.There are a number of factors, however, that cause K to be inaccurate over a large portion of the spectrum's frequency range. Numerous attempts have been made to derive an empirical correction factor (n) that could be applied to K to provide a better estimate of the surface-wave spectrum. This paper evaluates some of these empirical factors, specifically for use in an estuarine environment, and recommends Graces' (1978) equation for n as a function of the non-dimensional frequency parameter kh (where is the local wavenumber, h the local depth and L the wavelength).The paper also evaluates the maximum limit (Kmax) on the magnitude of K suggested by Esteva & Harris (1970), where relative depth (d is the pressure transducer height above the bottom) and koh (a parameter directly related for large values of kh to wave frequency by the dispersion relation) are the independent variables. The choice of Kmax may be made unimportant if d is selected beforehand using an equation (Knowles, 1981a) for the minimum limit affected by the choice of Kmax. 相似文献
14.
Laboratory investigations were conducted on the formation of NaF° ion-pairs at the ionic strength of seawater using specific ion electrodes. Sodium and fluoride ion electrodes produced results which are consistent with the ion-pairing model for these ionic interactions. The stoichiometric association constant for NaF°, , was determined at 15, 25, and 35°C. It was assumed that was a function of temperature, pressure, and ionic strength but not of solution composition. The value for at 25°C and I = 0.7 m is 0.045 ± 0.006. increased with decreasing temperature. This result was used to recompute values of and accounting for the presence of NaF° ion-pairs. The value for indicates that 1.1% of the fluoride in seawater is ion-paired with sodium at 25°C and 35‰ salinity. This fraction increases to approximately 2% at the lower temperatures found in the deep ocean. The percentage of free fluoride in natural seawater was measured at 15, 25, and 35°C to verify the speciation calculated from equilibrium constants. 相似文献
15.
Paolo Boccotti 《Applied Ocean Research》1983,5(3):134-140
For wind waves modelled by a stationary Gaussian process ζ(t) (ζ = height above m.w.l. of one point of the free surface) it is shown that, in a time interval including an instant tm where a maximum ζm occurs, the ratio between ζ(t) and ζm tends with probability approaching one, to the ratio Ψ(t ? tm)/Ψ(O), as tends to infinity, Ψ(t) being the autocovariance of the process.Starting from this result, it is possible to find analytically the characteristic periods of the highest waves in a sea with a given energy spectrum. These periods, calculated according to period definitions of three methods of wave record analysis, are found to be in remarkably good agreement with data from Bretschneider1 and Svasek.2 相似文献
16.
Observations of turbulence, stratification, and mean current were made using a microstructure profiler and an acoustic Doppler current profiler (ADCP) during four cruises at a central location in the Ariake Sea, under weakly and strongly stratified conditions. Continuous measurements of the dissipation rate of turbulent kinetic energy (TKE), ε, were made. These revealed that frictional bed turbulence with quarterdiurnal variation in the bottom boundary layer (BBL) was one of the most energetic sources of vertical mixing in the sea. Thickness of the BBL was strongly confined by the stable stratification. We investigate a relationship between the BBL height h and the Ozmidov scale. We present a systematic argument that describes the vertical structure and characteristic scales of velocity and turbulence inside the frictional BBL, where the stratification persisted. Considerable deviation of observed vertical shear from the law of the wall indicated a modification of turbulent scales by the stratification. Shear stress calculated from the velocity data using vertical integration of the equation of motion was found to decrease approximately linearly with height. The TKE production rate P, estimated using the shear stress, was highly correlated with the dissipation rate. The buoyancy contribution to TKE balance in the BBL was quantified in terms of the flux Richardson number R f as R f?=?0.12. 相似文献
17.
For a concave-up power Bruun beach profile, the following two energetics-based sediment transport models are developed: (1) a Bagnold-type model and (2) a combined wave-current stress model. The stress model is calibrated with the Bagnold model using observed transport rates on planar beaches. The sediment transport profiles for the two models are in agreement within the surf zone for the planar beach case; but the stress model is also applied seaward of the breaker line where the Bagnold model is not. A mean swash transport of sand is predicted by the Bagnold model for a power least-squares approximation to total depth including setup/setdown on a Bruun beach profile. The total longshore transport of sand is determined for each transport model as a function of the turbulent lateral mixing strength. The total sand transport is found to be less on a concave-up beach profile than for the corresponding planar beach case. 相似文献
18.
An investigation of ferric ion complexing has been conducted in synthetic media and seawater at 25°C. Formation constants were potentiometrically determined for the species FeCl2+, FeCl2+, FeOH2+, and Fe(OH)2+ at an ionic strength of 0.68 m. Formation constants for the ferric chloride complexes were determined as Clβ1 = 2.76 and Clβ2 = 0.44. In a study of the reaction Fe3+ + nH2O ? Fe(OH)n(3?n)+ + nH+ in NaClO4, NaNO3 and NaCl the formation constants were shown to be relatively independent of medium when the effects of nitrate and chloride complexing were taken into account. The average values obtained for these constants are . Reasonable agreement with these values was obtained when these constants were determined in seawater by accounting for the effects of chloride, fluoride and sulfate complexing. 相似文献
19.
The choice of convenient basic constituents for evaluating pH stability of aqueous systems is discussed, and two useful interaction parameters are defined and related to the buffer capacity: the interaction capacity, , and the interaction intensity, ; for pH and TOTH, δ′H, H = ?βH?1, where βH is the pH buffer capacity. A method is presented for the computation of exact values of all interaction capacities and intensities through inversion of the Jacobian matrix of the system of non-linear equations describing the aqueous system. The major species of an aqueous system (H2O, H+, solid phases, gases, and the most abundant solute species) are shown to constitute a useful set of basic constituents for evaluation of approximate pH buffer capacities according to a simple rule: the major-minor species rule for zeroth order pH-TOTH interaction. The concepts of buffering and pH-statting are examined and contrasted; it is demonstrated that the buffer capacity of an aqueous system cannot be infinite: it is limited by the concentration of solutes in solution. The effect upon pH of variations in constituents other than H+ is described in terms of first order interactions via complex formation and solid formation; approximate formulas for calculation are derived. Higher order interactions are derived from combinations of first order ones. The pH stability of the ocean system is examined in terms of an aqueous phase model including ion-association reactions and a heterogeneous model incorporating CO2 in the gas phase, quartz, kaolinite, calcite, chlorite, and illite, in addition to the aqueous phase. There is an approximately three-fold enhancement of buffer capacity in the aqueous model as a consequence of ion-association. Only a few interaction pathways are of quantitative significance in establishing the buffer capacity. Results for the heterogeneous ocean model lend quantitative support to Sillén's notion of pH stability: the buffer capacity is about four hundred times greater than that of the aqueous phase model. 相似文献