The Elzevir batholith belongs to a suite of trondhjemitic intrusions emplaced at ca. 1,240 Ma in the Grenville Province of eastern Ontario. New major and trace element data, including REE, combined with isotopic and petrographic data indicate that:
the batholith has calc-alkalic affinities;
the Elzevir parental magma is very similar to that of dacites in the nearby, coeval metavolcanic rocks; the magma formed by partial melting of crustal material at granulite grade;
chemical differences between the plutonic and volcanic rocks can be best explained by accumulation of plagioclase in the plutonic environment;
fractionation was dominated by plagioclase and quartz, with lesser biotite and epidote, and minor zircon and apatite.
It is suggested that melting of sialic crust took place during the ‘docking’ of a partly-evolved, originally ensimatic arc system against the main cratonic mass to the northwest. 相似文献
Six lithologic units in tectonic contact with each other have been defined during mapping of the Devonian in the Beaujolais area of the northeastern Massif Central. Five main igneous suites have been recognized:
A transitional basaltic suite restricted to a single unit.
An acid volcanic-plutonic suite the members of which are related by fractional crystallization and magma mixing.
Low-TiO2 volcanic rocks with calc-alkaline affinities.
A TiO2-rich tholeiitic suite related to an ophiolitic complex.
A plutonic suite with close resemblances to Alaskantype intrusions.
The transitional metabasalts (1) form the oldest igneous suite and could represent either an intraplate magmatic forerunner of rifting or tectonic slices of weakly metamorphosed rocks representing a pre-Acadian event. The next three suites may be related to a short-lived ensialic marginal basin that developed between the Acadian and Bretonian orogenies. The basin is asymmetric, with the ophiolite of the central part flanked by an acid ridge on one side and a passive continental margin on the other. Quartz-keratophyres (2) and calc-alkalic basic volcanic rocks (3) were intercalated in varying proportions to form a bimodal volcanic pile before the rifting event that led to the formation of the ophiolites (4). The acid ridge (2) may be due to the reactivation of a continental basement. Cumulate rocks with Alaskan-type affinities occur as olistoliths, emplaced before the formation of the rift basin, supporting a comparison of the Hercynian belt with accreted magmatic arc terranes. 相似文献
The Naqadeh mafic plutonic rocks are located on a plutonic assemblage and include different granitoid rocks related to ～40 Ma. U-Pb SHRIMP data shows different ages of 96?±?2.3 Ma for mafic rocks. Naqadeh mafic plutonic rocks consist of diorite to diorite-gabbros with relatively high contents of incompatible elements, low Na2O, and $ {\hbox{Mg\# }} = \left[ {{\hbox{molar}}\;{100} \times {\hbox{MgO/}}\left( {{\hbox{MgO}} + {\hbox{FeO}}} \right)} \right] > 44.0 $. These features suggest that the Naqadeh mafic rocks originate from enriched lithospheric mantle above subducted slab during Neotethys subduction under Iranian plate. 相似文献
The key to mantled feldspar genesis is epitaxial nucleation of plagioclase on K-feldspar or K-feldspar on plagioclase. Once this nucleation takes place there is a relatively straightforward process of crystal growth yielding rapakivi and antirapikivi textures. The most common mantling is plagioclase on K-feldspar which occurs in both volcanic and plutonic environments. In the volcanic environment the morphology of the plagioclase overgrowth typically is dendritic, though in subvolcanic and shallow plutonic environments dendritic growth is followed by a more or less continuous non-cellular shell of plagioclase. In the plutonic environment, early stages of plagioclase overgrowth also tend to be dendritic, although with coarser-grained characteristics. Dendritic morphology is thus a common denominator in rapakivi genesis. Since growth of dendritic plagioclase is clearly related to marked undercooling in silicate melt systems its occurrence in many volcanic rocks is to be expected. Equivalent quenching in the plutonic environment requires a cooling mechanism independent of conductive heat transfer to wallrock and also independent of effective cooling related to sudden loss of volatile phases that could only occur late in the crystallization of most magmas and therefore after much dendritic plagioclase had already formed. Internal quenching of portions of magma systems must occur if mafic magma is abruptly mixed with felsic magma. Such magma mixing yields a heterogeneous system at first, one that is in a drastic state of disequilibrium and tending to force nucleation of one feldspar type on the surface of another resulting in epitaxial crystallization of dendritic plagioclase on K-feldspar. Mantling of one feldspar type by another during magma mixing is paralleled by dendritic growth zones in coexisting plagioclase crystals.Mantling textures occur in hybrid rocks of magma mixing origin. Some of the hybrid rocks are fine-grained, mafic-rich, and may contain phenocrysts of quartz, plagioclase, and K-feldspar. They occur as rounded inclusions in calc-alkaline granites and granodiorites. The host plutons themselves commonly have mantled feldspars or at least plagioclase with the unusual zoning characteristics commonly accompanying rapakivi texture. Magma-mixing tends to occur in batches so that hybrid crystal-melt systems, the calc-alkaline granitic plutons, become intrusive into earlier hybrid crystal-melt systems, represented by the mafic-rich inclusions. 相似文献
Eighteen silicic volcanic rocks of the Warrawoona Group and ten associated plutonic rocks from the Pilbara Block, Western Australia, have been chosen for geochemical and isotopic studies. Silicic volcanics of the UNSB (Upper member of North Star Basalt) are dated at 3.56—3.57 , by both the Rb-Sr and the Sm-Nd methods. The respective 1 (initial isotopic composition) values are 0.7005 ± 5 (Sr) and 0.50810 ± 39 (Nd). This age is consistent with the stratigraphic interpretation that the TalgaTalga Subgroup, in which the North Star Basalt occupies the lowermost position, is overlain by the Duffer Formation, whose age was earlier established at 3.45 by the zircon U-Pb method. The new Rb-Sr data on six silicic lava samples from the Duffer Formation yield an isochron of 3.23 ± 0.28 (2v). Though imprecise, this age agrees with the zircon age within error limits. Rb-Sr ages of 2.3–2.4. obtained for the ‘Panorama’ rocks and the Wyman Formation do not correspond to their initial eruption ages. Chemical arguments suggest that these ages represent the time of metasomatism associated with the widespread thermal event in this region about 2.3–2.4 ago.Geochemically, most of these analyzed rocks (volcanic and plutonic) are of tonalite-trondhjemitegranodiorite (TTG) composition, a typical feature found in many other Archean terrains. They generally show fractionated REE patterns, except the Panorama Formation rocks. Furthermore, the Wyman Formation rhyolites and the post-tectonic adamellites show significant negative Eu anomalies, suggesting a similar mode of magma generation and a probable genetic link. Theoretical considerations suggest that most of these TTG rocks could have been generated by partial melting of amphibolitic or basaltic sources, followed by fractional crystallization.Although the Archean granitic gneisses often possess mantle-like Isr values, the trace element data indicate that they could not have been derived by direct melting of upper mantle materials. The immediate tectonic implication is that in any Archean terrain, the formation of Na-rich continental crust of TTG suite must be preceded by the presence of basaltic crust. The occurrence of this basaltic crust is a matter of controversy. Such crust might have been totally destroyed by repeated melting processes, or its remnants are now represented by some of the mafic-ultramafic enclaves within the tonalite-trondhjemite batholiths. 相似文献
Trace elements, including rare earth elements (REE), exhibit systematic variations in plutonic rocks from the Captains Bay pluton which is zoned from a narrow gabbroic rim to a core of quartz monzodiorite and granodiorite. The chemical variations parallel those in the associated Aleutian calcalkaline volcanic suite. Concentrations of Rb, Y, Zr and Ba increase as Sr and Ti decrease with progressive differentiation. Intermediate plutonic rocks are slightly enriched in light REE (La/Yb=3.45–9.22), and show increasing light REE fractionation and negative Eu anomalies (Eu/Eu*=1.03–0.584). Two border-zone gabbros have similar REE patterns but are relatively depleted in total REE and have positive Eu anomalies; indicative of their cumulate nature. Initial 87Sr/86Sr ratios in 8 samples (0.70299 to 0.70377) are comparable to those of volcanic rocks throughout the arc and suggest a mantle source for the magmas. Oxygen isotopic ratios indicate that many of the intermediate plutonic rocks have undergone oxygen isotopic exchange with large volumes of meteoric water during the late stages of crystallization; however no trace element or Sr isotopic alteration is evident.Major and trace element variations are consistent with a model of inward fractional crystallization of a parental high-alumina basaltic magma at low pressures (6 kb). Least-squares approximations and trace element fractionation calculations suggest that differentiation in the plutonic suite was initially controlled by the removal of calcic plagioclase, lesser pyroxene, olivine and Fe-Ti oxides but that with increasing differentiation and water fugacity the removal of sub-equal amounts of sodic plagioclase and hornblende with lesser Fe-Ti oxides effectively drove residual liquids toward dacitic compositions. Major and trace element compositions of aplites which intrude the pluton are not adequately explained by fractional crystallization. They may represent partial melts derived from the island arc crust. Similarities in Sr isotopes, chemical compositions and differentiation trends between the plutonic series and some Aleutian volcanic suites indicates that shallow-level fractional crystallization is a viable mechanism for generating the Aleutian calcalkaline rock series.LDGO Contribution no. 2964 相似文献
Variably foliated, predominantly granodioritic plutonic rocks from the northern part of the Shaw Batholith in the east Pilbara Archaean craton are dated at 3,499±22 Ma (2σ errors) by a whole-rock Pb-Pb isochron. These rocks intrude the surrounding greenstone sequence, and their age is indistinguishable from that sequence. High strain grey gneisses which occupy much of the western and southern Shaw Batholith are chemically and isotopically similar to the North Shaw suite and are inferred to have been derived from this suite by tectonic processes. Felsic volcanics within the greenstones together with a major portion of the granitic batholiths apparently formed in a calc-alkaline volcanic and plutonic province at ～3,500 Ma. This volcanic and plutonic suite is similar to modern calc-alkaline suites on the basis of major element, rare earh element and most other trace element contents. The Archaean suite contrasts with modern equivalents only in having lower concentrations of HREE and higher concentrations of Ni and Cr. The average composition of the North Shaw suite is similar to that of Archaean gneiss belts for most elements and is consistent with the previously formulated hypothesis that the Shaw Batholith is transitional to the upper crustal level of a high-grade gneiss belt. Enrichment of the gneissic crust in the Shaw Batholith in alkali and heat-producing elements is inferred to have taken place by both igneous and hydrothermal processes over a protracted time interval. Late- and post-tectonic adamellite and granite melts intrude the gneissic rocks and there is isotopic evidence consistent with the gneisses being substantially enriched in Rb by pegmatite injection at ～3,000 Ma. 相似文献
The Early to Middle Jurassic Talkeetna Arc section exposed inthe Chugach Mountains of south–central Alaska is 5–18km wide and extends for over 150 km. This accreted island arcincludes exposures of upper mantle to volcanic upper crust.The section comprises six lithological units, in order of decreasingdepth: (1) residual upper mantle harzburgite (with lesser proportionsof dunite); (2) pyroxenite; (3) basal gabbronorite; (4) lowercrustal gabbronorite; (5) mid-crustal plutonic rocks; (6) volcanicrocks. The pyroxenites overlie residual mantle peridotite, withsome interfingering of the two along the contact. The basalgabbronorite overlies pyroxenite, again with some interfingeringof the two units along their contact. Lower crustal gabbronorite(10 km thick) includes abundant rocks with well-developed modallayering. The mid-crustal plutonic rocks include a heterogeneousassemblage of gabbroic rocks, dioritic to tonalitic rocks (30–40%area), and concentrations of mafic dikes and chilled mafic inclusions.The volcanic rocks (7 km thick) range from basalt to rhyolite.Many of the evolved volcanic compositions are a result of fractionalcrystallization processes whose cumulate products are directlyobservable in the lower crustal gabbronorites. For example,Ti and Eu enrichments in lower crustal gabbronorites are mirroredby Ti and Eu depletions in evolved volcanic rocks. In addition,calculated parental liquids from ion microprobe analyses ofclinopyroxene in lower crustal gabbronorites indicate that theclinopyroxenes crystallized in equilibrium with liquids whosecompositions were the same as those of the volcanic rocks. Thecompositional variation of the main series of volcanic and chilledmafic rocks can be modeled through fractionation of observedphase compositions and phase proportions in lower crustal gabbronorite(i.e. cumulates). Primary, mantle-derived melts in the TalkeetnaArc underwent fractionation of pyroxenite at the base of thecrust. Our calculations suggest that more than 25 wt % of theprimary melts crystallized as pyroxenites at the base of thecrust. The discrepancy between the observed proportion of pyroxenites(less than 5% of the arc section) and the proportion requiredby crystal fractionation modeling (more than 25%) may be bestunderstood as the result of gravitational instability, withdense ultramafic cumulates, probably together with dense garnetgranulites, foundering into the underlying mantle during thetime when the Talkeetna Arc was magmatically active, or in theinitial phases of slow cooling (and sub-solidus garnet growth)immediately after the cessation of arc activity. KEY WORDS: island arc crust; layered gabbro; Alaska geology; island arc magmatism; lower crust相似文献
Geologic, petrological and geochemical investigations have been carried out in the western part of the “Zillertaler Alpen”. Important results are:
The premetamorphic material of the Greiner series consists of conglomerates, breccias, arcosic-sandstones or greywackes, bituminous shales, volcanic lavas and tuffs.
The southern part of the “Zentralgneis” shows a differentiation trend from alkaline granite to quarzdiorite with predomination of granodiorite.
Chemical relationships of granodiorite to its restitic inclusions allow the supposition of a palingenetic origin of the granitic rocks.
At least two stages of metamorphism can be differentiated.
Parts of the Greiner series, covered by triassic metasediments, are supposed to be of Permian age. A lower age boundary can not yet be given.
Some vertical, northeast striking faults with throws of more than 1 or 2 kilometers produced southward verging drag folds.
Geodynamic aspects, revealed from regional metamorphism and tectonics, are discussed.
Principe is one of the volcanic centres comprising the Cameroun line in West Africa. The volcanic rocks can be divided into two stratigraphic units:
Younger lava series — basanite and nephelinite overlying.
Older lava series — transitional to mildly alkaline basalt and hawaiite.
These units lie on a basement of palagonite breccias of tholeiitic affinities. The basic lavas are intruded by plugs ranging in composition from tristanite to phonolite and are overlain by phonolite lavas. These rocks form two chemically and mineralogically distinct suites:
Phonolites which evolved by low pressure crystal fractionation of the younger lava series basanitic magma, and
Tristanite — trachyte — trachyphonolite suite which may have evolved by high pressure crystal fractionation of the older lava series magma.
Xenoliths of ultrabasic, ultramafic, gabbroic or syenitic type occur in Teneriffe: dunites and clino-pyroxenites in the old alkalic basalt formations of Teno and Anaga peninsulas; gabbroic xenoliths in the Pedro Gil region; nepheline-syenite xenoliths in the Las Canadas and Vilaflor regions where intermediate and phonolitic lavas are abundant; ultramafic, clino-pyroxenite and syenitic xenoliths in the Anaga peninsula where there are many intrusions of nepheline-syenite and phonolitic syenite. Several xenoliths show signs of cataclasis, recrystallisation or reaction of their minerals with the host liquids.
The ultrabasic, ultramafic and anorthoclase-rich xenoliths appear to be of cumulus origin, subtracted from basic to intermediate alkalic liquids. Major cumulus phases are: magnesium-rich olivine, sub-silicic, aluminous pyroxene, titanomagnetite, sub-silicic potassic kaersutite, and anorthoclase. It is suggested that the xenoliths formed at depths between 11 km and 30 km, largely under wet conditions that helped suppress formation of cumulus plagioclase.
The subtraction of kaersutite from liquids of intermediate composition is thought to be a means of producing the gap in silica content between the Teneriffe trachybasalts and the more siliceous trachyphonolites and phonolites. It is also suggested that the subtraction of kaersutite and anorthoclase would considerably deplete residual liquids in alumina whilst enriching then in soda and this might be the means of producing peralkaline liquids.
The presence of the xenoliths supports the geophysical data that indicated that Teneriffe has a sub-crustal structure of plutonic rocks. Correlation of the Teneriffe plutonic xenoliths with exposed plutonic basement rocks from other Canary Islands, which are believed to have similar sub-crustal structures, is considered necessary.
Plutonic rocks associated with the Latir volcanic field comprise three groups: 1) 25 Ma high-level resurgent plutons composed of monzogranite and silicic metaluminous and peralkaline granite, 2) 23–25 Ma syenogranite, and alkali-feldspar granite intrusions emplaced along the southern caldera margin, and 3) 19–23 Ma granodiorite and granite plutons emplaced south of the caldera. Major-element compositions of both extrusive and intrusive suites in the Latir field are broadly similar; both suites include high-SiO2 rocks with low Ba and Sr, and high Rb, Nb, Th, and U contents. Moreover, both intermediateto siliciccomposition volcanic and plutonic rocks contain abundant accessory sphene and apatite, rich in rare-earth elements (REE), as well as phases in which REE's are essential components. Strong depletion in Y and REE contents, with increasing SiO2 content, in the plutonic rocks indicate a major role for accessory mineral fractionation that is not observed in volcanic rocks of equivalent composition. Considerations of the rheology of granitic magma suggest that accessory-mineral fractionation may occur primarily by filter-pressing evolved magmas from crystal-rich melts. More limited accessory-mineral crystallization and fractionation during evolution of the volcanic magmas may have resulted from markedly lower diffusivities of essential trace elements than major elements. Accessory-mineral fractionation probably becomes most significant at high crystallinities. The contrast in crystallization environments postulated for the extrusive and intrusive rocks may be common to other magmatic systems; the effects are particularly pronounced in highly evolved rocks of the Latir field. High-SiO2 peralkaline porphyry emplaced during resurgence of the Questa caldera represents non-erupted portions of the magma that produced the Amalia Tuff during caldera-forming eruption. The peralkaline porphyry continues compositional and mineralogical trends found in the tuff. Amphibole, mica, and sphene compositions suggest that the peralkaline magma evolved from metaluminous magma. Extensive feldspar fractionation occurred during evolution of the peralkaline magmas, but additional alkali and iron enrichment was likely a result of high halogen fluxes from crystallizing plutons and basaltic magmas at depth. 相似文献
Between the upper tertiary volcanic areas of Westerwald and Vogelsberg (central Western Germany) occur more than 40 isolated tertiary volcanic dikes, eroded necks, plugs and domes. Twelve of these volcanic rocks have been investigated petrographically and chemically and classified by means of their modal and chemical composition. Additional modal analyses have been performed on seven other volcanics. On seventeen volcanic occurences K-Ar-whole rock age determinations have been made. The K-Ar age determinations yield- with the exception of an olivine-nephelinite — values between 27 and 15 Ma. Regarding the known intervals of volcanic activities of the Westerwald- and Voge1sberg-areas, most of the examined volcanics can be related genetically with one of the adjacent volcanic areas. There seems to be no geographical overlapping of volcanics showing Westerwaldages and Vogelsberg-ages. A possible influence of excess-Ar-bearing phases (e. g. mantle xenoliths) and an Ar-loss of constituent matter of the groundmass have been estimated by additional age determinations of enriched samples. These influences — partially compensating each other — may shift the K-Ar whole rock age to a maximum of 5 % and thus do not exceed the dimension of the standard deviations. A distinct NNE-SSW-striking fault in the region between Marburg and Gießen is situated parallel with the eastern border of the “Rheinisches Schiefergebirge”. Volcanics showing Westerwald-age and Vogelsberg-age respectively reach this fault, but obviously do not overlap it. Relations between rock-type an rock age, as it has been observed for the volcanics of the northern Hessian Depression (Kreuzer et al. 1973;Wedepohl 1982) cannot be proved certainly. On the other hand, similar to the basaltic rocks of the northern Hessian Depression, the youngest volcanic product is an olivine-nephelinite (9 Ma). 相似文献
The Uimen-Lebed’ volcanoplutonic terrane is located at the junction of the Gorny Altai, Gornaya Shoriya, and western Sayan structures and is part of the Devonian-Early Carbonaceous Salair-Altai volcanoplutonic belt. The volcanic facies of the terrane composes the contrasting Nyrnin-Sagan Group, which includes basalt-basaltic andesite and basalt-rhyolite associations. The plutonic facies makes up the multiplet Elekmonar Group, which includes two independent complexes: monzogabbro-monzodiorite-granodiorite-granite and granodiorite-granite-leucogranite. The volcanic and plutonic rocks are asymmetrically distributed: volcanic sequences fill inherited depressions in the eastern part of the terrane, whereas plutonic complexes are located in its western part at the fault system branching from the transregional Kuznetsk-Teletsk-Kurai fault zone. The basalts of the Nyrnin-Sagan Group show geochemical signatures of both suprasubduction and rift-related rocks. The evolution of basaltoid magmatism reflects the formation and development of a suprasubduction mantle wedge in the inner part of an active continental margin accompanied by the influence of an intraplate mantle source. The silicic volcanism was generated under lower crustal conditions (P > 10 kbar) at the expense of metabasic materials and was accompanied by the influx of potassium into the anatectic zones. The gabbroids of the Elekmonar Group show suprasubduction geochemical features and no signatures of rift-related structures. The composition of the Elekmonar granitoids indicates significantly shallower (compared with the silicic volcanics) depths of their generation. The Uimen-Lebed’ volcanoplutonic terrane in the northeastern part of Gorny Altai was formed in the inner part of an active continental margin of the Andean type. Its magmatic complexes were formed over a considerable time range, from the early Emsian, when the formation of the active continental margin began, to the end of the Eifelian or, more likely, the beginning of the Givetian stage. 相似文献
Oxygen isotope analyses have been obtained for 443 igneous rock and mineral samples from various localities throughout the world. Detailed studies were made on the Medicine Lake, Newberry, Lassen, Clear Lake, S. E. Guatemala, Hawaii and Easter I. volcanic complexes and on the Bushveld, Muskox, Kiglapait, Guadalupe, Duluth, Nain, Egersund, Lac St. Jean, Laramie, Skaergaard, Mull, Skye, Ardnamurchan and Alta, Utah plutonic complexes, as well as upon several of the zoned ultramafic intrusions of S. E. Alaska. Basalts, gabbros, syenites and andesites are very uniform in O18/O16, commonly with δ-values of 5.5 to 7.0 per mil. Many rhyolite obsidians, particularly those from oceanic areas and the Pacific Coast of the United States, also lie in this range; this indicates that such obsidians are differentiates of basaltic or andesitic magma at high temperatures (about 1,000° C). They cannot represent melted sialic crust. The only plutonic granites with such low δ-values are some of the hypersolvus variety, suggesting that these also might form by fractional crystallization. Obsidians from the continental interior, east of the quartz-diorite line, have higher δ-values. This is compatible with their having assimilated O18-rich sialic crust. A correlation generally exists between the O18/O16 ratios of SiO2-rich differentiates and the chemical trends in volcanic complexes. High O18/O16 ratios accompany those trends having the lower Fe/Mg ratios, while ferrogabbro trends are associated with depletion in O18. Variations in oxygen fugacity may be responsible for these effects, as abundant early precipitation of magnetite should lead to both O18-enrichment and Fe-depletion in later differentiates. Plutonic granites have higher O18/O16 ratios than their volcanic equivalents, because (a) their differentiation occurred at much lower temperatures, or (b) they are in large part derived from O18-rich sialic crust by partial melting or assimilation. Also, the oxygen isotope fractionations among coexisting minerals are distinctly larger in plutonic rocks than in volcanic rocks. This is in keeping with their lower crystallization temperatures and their longer cooling history, which promotes post-crystallization oxygen isotope exchange. Hydrated obsidians and perlites have δO18-values that are much different from their primary, magmatic values. A correlation exists between D/H and O18/O16 ratios in hydrated volcanic glass from the western U.S.A., proving that the isotopic compositions are a result of exchange with meteoric waters. The O18 contents of the glasses appear to be about 25 per mil higher than their associated waters; hence, these hydrated glasses have not simply absorbed H2O, but they have exchanged with large quantities of it. The igneous rocks from Mull, Skye, Ardnamurchan and the Skaergaard intrusion are all abnormally depleted in O18 relative to “normal” igneous rocks. This is a result of their having exchanged at high temperatures with meteoric water that was apparently abundant in the highly jointed plateau lavas into which these igneous rocks were intruded. In part, this exchange occurred with liquid magma and in part with the crystalline rock; in the latter case the feldspar was more easily exchanged and has become much more depleted in O18 than has coexisting quartz or pyroxene. The later differentiates of the Muskox intrusion are markedly O18-rich, but this is not a result of fractional crystallization. It is in large part a result of deuteric exchange between feldspars and an oxygen-bearing fluid (H2O ?) that was either O18-rich or had a relatively low temperature. This phenomenon was also observed in a number of granophyres from other localities, particularly those containing brick-red alkali feldspar. The exchanged feldspars in all these examples are turbid or cloudy, and may be filled with hematite dust. It is concluded that most such feldspar in nature is the result of deuteric exchange and is probably drastically out of oxygen isotopic equilibrium with its coexisting quartz. 相似文献
In the present phase of the volcanic activity on Nea Kameni / Santorini / Greece the calc-alkalic volcanic rocks are decomposed by H2O, CO2 and SO2 gases of about 100 °C. Using a method ofGresens (1967) for the determination of gains and losses of compounds five different processes could be distinguished:
leaching of compounds
enrichment of Ca as gypsum
increase of Fe2O3 (6%–11%), TiO2 (0,8%–3%) and Zr
enrichment of Al2O3 (15%–29%), TiO2 (0,8%–1,5%) and K
increase of Al2O3 (15%–26%), Fe2O3 (6%–9%), TiO2 (0,8%–1,3%), Sr, Ba, Pb and Zr
Finally a model for the process of decomposition of calc-alkalic volcanic rocks by sulfuric acid was developed. 相似文献
There are a variety of approaches to the restoration of the primary rocks,but various discrimina-tion diagrams or functional formulae have a limit on their application and discrimination accuracy.On the basis of statistical analyses in conjunction with the advantages of various discrimination dia-grams,this paper presents a new functional discriminant:Dy=-2lgA 1gE-0.5lgF-2lgM 3lgC 5.5lgN 1.5lgK-Z.The above discriminant can be rewritten as :Dy=lg EC^3N^5.5K^1.5/A^2F^0.5M^2-Z This discriminant is not applicable to sedimentary rocks,particularly those enriched in Ca, and Mg rich ultrabasic rocks.In this study 1640 typical rock samples and 126 sedimentary (metasedimentary )rock samples and 126 volcanogenic iron ore samples were tested with the above described discriminant .The results obtained are satisfactory with the exception of feldspar sandstone.The discrimination rates for various types of rocks are in the range of 85-95% or more with a total discrimination rate of 91.7%.This paper analyzes the factors leading to wrong discrimination and also points out that coarse detrital rocks,weathered volcanic rocks,volcanic fine detrital rocks of two different material sources and Ca-rich sedimentary rocks are easy to suffer wrong discrimination. 相似文献
Sr- and Pb-isotope data from the Calabozos center (87Sr/86Sr= 0.7043, 206Pb/204Pb=18.64–18.66, 207Pb/204Pb=15.59–15.60, 208Pb/204Pb=38.52–38.55) fall within the range of values reported for the southern volcanic zone (33–42° S) of the Andean arc. The range of
18O (5.0–6.3), however, includes unusually low values compared to volcanic rocks of similar bulk composition in the region. The Calabozos caldera complex lies at 35 °30 S, where the continental crust under the Andes thins southward from >45 to 30 km. Three voluminous late Pleistocene ashflow tuffs, collectively called the Loma Seca Tuff, constitute the bulk of >1,000 km3 of eruptive products at the Calabozos caldera complex and are evidence for a major, longlived andesitic-to-rhyodacitic magma reservoir at shallow crustal levels. The
18O values of the most evolved volcanic rocks from the Calabozos center are lower than predicted for rhyodacite produced by crystal fractionation from basalt typical of the region. Variation of
18O independent of bulk composition and inferred magmatic water contents indicates that the 18O depletion is a late-stage, upper-crustal phenomenon that cannot simply be attributed to magmatic interaction with meteoric water. The data are interpreted to be the result of assimilation of 5–30% of roof and wall rocks previously depleted in 18O by isotopic exchange in a meteoric hydrothermal system overlying the magma reservoir. Combined assimilation and fractional crystallization calculations applied to Sr isotope data show that the isotopic contrast between the Calabozos magmas and the assimilated rocks is very small. Hydrothermally-altered volcanic and plutonic rocks from the Tertiary Andean arc complex and Mesozoic-to-Cenozoic volcaniclastic sediments typical of the local basement provide a geologically reasonable contaminant compatible with the Sr- and O-isotope data. Pb-isotope data from the Calabozos system lend no significant insight into upper crustal contamination. 相似文献
