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1.
In the Segura area, Variscan S-type granites, aplite veins and lepidolite-subtype granitic aplite-pegmatite veins intruded the Cambrian schist-metagraywacke complex. The granites are syn D3. Aplite veins also intruded the granites. Two-mica granite and muscovite granite have similar ages of 311.0 ± 0.5 Ma and 312.9 ± 2.0 Ma but are not genetically related, as indicated by their geochemical characteristics and (87Sr/86Sr)311 values. They correspond to distinct pulses of magma derived by partial melting of heterogeneous metapelitic rocks. Major and trace elements suggest fractionation trends for: (a) muscovite granite and aplite veins; (b) two-mica granite and lepidolite-subtype aplite-pegmatite veins, but with a gap in most of these trends. Least square analysis for major elements, and modeling of trace elements, indicate that the aplite veins were derived from the muscovite granite magma by fractional crystallization of quartz, plagioclase, K-feldspar and ilmenite. This is supported by the similar (87Sr/86Sr)311 and δ18O values and the behavior of P2O5 in K-feldspar and albite. The decrease in (87Sr/86Sr)311 and strong increase (1.6‰) in δ18O from two-mica granite to lepidolite-subtype aplite-pegmatite veins, and the behaviors of Ca, Mn and F of hydroxylapatite indicate that these veins are not related to the two-mica granite.  相似文献   

2.
The Sanandaj-Sirjan Zone (SSZ) trends northwestward in western Iran on the Precambrian to Paleozoic basement and exposes abundant I-type granitoids and calc-alkaline volcanic rocks that were most active during the Late Jurassic to Upper Cretaceous. The petrogenesis of the granitoids and associated volcanic rocks has been widely related to Neotethyan subduction beneath the Iranian plate. We report a geochronological and geochemical study of the Suffi abad granite (SLG) body that crops outs southeast of Sanandaj within the SSZ and is mainly composed of K-feldspar + quartz + plagioclase ± hornblende. The SLG, which shows a high-K calc-alkaline affinity, has LA-ICPMS zircon U–Pb ages ranging between 149 ± 2 and 144 ± 3 Ma and initial 87Sr/86Sr of ∼0.7024–0.7069 and 143Nd/144Nd of ∼0.5125–0.5127. These value correspond to an ?Nd (145 Ma) of +1.5 and +4.9, suggesting that the SLG originated from the juvenile crust or depleted mantle with a young TDM (650–900 Ma) over the subduction zone beneath the SSZ. Zircon saturation temperatures suggest that crystallization of the zircons, or emplacement of the host magmas, occurred at 560–750 °C, consistent with an intergrowth texture of K-feldspar and quartz that implies crystallization around the K-feldspar-quartz eutectic at lower temperatures. Overall, geochemical data suggest that crystallization of the hornblende and plagioclase played a role in magma differentiation. These data allow us to conclude that the high-K SLG did not originate directly from the juvenile mantle source as do most I-type, calc-alkaline granitoids, but more likely was produced from the partial melting of pre-existing I-type granitoids in the upper continental crust under low pressure conditions.  相似文献   

3.
Incipient charnockite formation at Kurunegala in Sri Lanka is characterized by the growth of orthopyroxene at the expense of amphibole and biotite in an originally homogeneous gneiss. Mineral equilibria in the charnockite assemblage record pressure-temperature (P-T) conditions of 738±60° C and 6.9±1.2 kbar at-17.0±1.2 log fO2 and aH2O=0.18±0.16. Wholerock trace-element and isotopic measurements show that charnockite formation was accompanied by a systematic depletion of Sm>Rb>Pb>U>Sr>Nd, with a fractionation of Rb/Sr, Sm/Nd and Th/U ratios, and crystallization of the charnockite assemblage at 535±5 Ma. Major element (Fe–Mg–Ca) and Sm–Nd equilibration between minerals occurred at 524±9 Ma, whereas, Pb and Rb–Sr underwent continued exchange to 501±5 Ma and 486±1 Ma, respectively. Trace-element data for both amphibolite and charnockite minerals show that depletion on a whole-rock scale can be accounted for either by changes in mineral modes or trace-element abundances, within the immediate area of dehydration. The fractionation of Sm/Nd on a whole-rock scale is controlled by the breakdown of amphibole, without the growth of a major new host-phase for Sm in the charnockite. Rubidium and Sr are dependent on the relative behaviour of biotite, plagioclase and alkali-feldspar. Modelling of dehydration-melting involving the breakdown of amphibole, biotite, and alkali-feldspar reproduces the observed Sm/Nd and Rb/Sr fractionation, and indicates the loss of small melt fractions, on a cm scale, from the charnockite. These observations suggest that partial melting is the most plausible means of effecting both the dehydration and depletion that accompanies charnockite formation.  相似文献   

4.
The late Paleozoic to early Mesozoic granites exposed in northwestern Lao PDR provide important constraints on the tectonic evolution of the Eastern Paleotethyan Ocean and regional correlation with the giant granitic belt in Southeast Asia. New geochronological data show that the granites have Late Triassic zircon U–Pb ages of 231–220 Ma. They are dominated by monzogranite and biotite granite with an I-type geochemical affinity. These granites are enriched in LREEs and LILEs and depleted in HFSEs. The geochemical variations for these granites indicate the fractional crystallization of plagioclase, K-feldspar, biotite, apatite, and Fe–Ti oxides. Their initial 87Sr/86Sr ratios range from 0.7021 to 0.7105 and εNd (t) values from −1.6 to −7.3. Zircon in-situ εHf (t) values are in range of −6.0–+5.3 (peaks at −2.8 and +2.5, respectively), Hf model ages of 0.67–1.64 Ga (peaks at 0.83 Ga and 1.45 Ga, respectively), and δ18O values of 6.6‰–8.0‰, similar to the Late Triassic granitoids from the Eastern Province in Southeast Asia. These granites originated from a mixed source of ancient metamorphic rocks with juvenile mafic crust. The Late Triassic granites in northwestern Lao PDR formed in a post-collisional setting in response to the thickened crustal collapse during the assembly of the Sibumasu with Indochina blocks. These granites can southerly link with the Eastern granite province of the Eastern Paleotethyan Domain in Southeast Asia.  相似文献   

5.
The zoned pluton from Castelo Branco consists of Variscan peraluminous S-type granitic rocks. A muscovite>biotite granite in the pluton's core is surrounded successively by biotite>muscovite granodiorite, porphyritic biotite>muscovite granodiorite grading to biotite=muscovite granite, and finally by muscovite>biotite granite. ID-TIMS U–Pb ages for zircon and monazite indicate that all phases of the pluton formed at 310 ± 1 Ma. Whole-rock analyses show slight variation in 87Sr/86Sr310 Ma between 0.708 and 0.712, Nd310 Ma values between − 1 and − 4 and δ18O values between 12.2 and 13.6. These geological, mineralogical, geochemical and isotopic data indicate a crustal origin of the suite, probably from partial melting of heterogeneous Early Paleozoic pelitic country rock. In detail there is evidence for derivation from different sources, but also fractional crystallization linking some of internal plutonic phases. Least-squares analysis of major elements and modelling of trace elements indicate that the porphyritic granodiorite and biotite=muscovite granite were derived from the granodiorite magma by fractional crystallization of plagioclase, quartz, biotite and ilmenite. By contrast variation diagrams of major and trace elements in biotite and muscovite, the behaviours of Ba in microcline and whole-rock δ18O, the REE patterns of rocks and isotopic data indicate that both muscovite-dominant granites were probably originated by two distinct pulses of granite magma.  相似文献   

6.
Mesozoic granitic intrusions are widely distributed in the Nanling region,South China.Yanshanian granites are closely connected with the formation of tungsten deposits.The Xihuashan granite is a typica...  相似文献   

7.
Petrological and geochemical characteristics of the granites from the Khanak and Devsar areas have been discussed in this paper. Based on field, petrographical and geochemical observations, three types of granites (grey, green and pink granite) have been identified in these areas. Grey granites consist of quartz, plagioclase, biotite, hornblende as essential minerals and hematite, zircon, annite, monazite & rutile as accessory minerals. Petrographically, green granites are same as grey granites including perthite and zircon as accessory minerals. Pink granites consist of quartz, k-feldspar and biotite in Khanak whereas in Devsar granites alike as Khanak granites, but plagioclase is replaced by perthite and occurs as dominantly. Microscopically, granites of both areas show porphyritic, hypidiomorphic, granophyric, perthitic and micro granophyric textures. Geochemically, major oxide elements (except alkalies) and trace elements (Ba, Sr, Cr, Ni, V, Cu, Zn, Ga, Pb, Th and Zr) are more in green and grey granites of Khanak and Devsar areas than pink granites. Generally, they show enrichments in SiO2, Na2O+K2O, Fe/Mg, Rb, Zr, Y and and AI (Agpaitic Index) (ranges from 0.10 to 1.18) and depletion in MgO, CaO, P, Ti, Ni, Cr and V indicate their A-type affinity which is very similar to the A-type granites of MIS (Malani igneous suite) in northwestern peninsular India. Green and grey granites of Devsar area show high concentrations of Heat production (HP) 9.68 & 11.70 μWm-3 and total Heat Generation Unit (HGU) i.e 23.04 & 27.86 respectively. On the other hand, pink granites of Khanak area display a higher enrichment of HP (16.53 μWm-3) and HGU (39.37) than those granites of Devsar area. Overall, they have much a higher values of HP and HGU than the average value of continental crust (3.8 HGU), which imply a possible linear relationship with the surface heat flow and crustal heat generation in the rocks of MIS. From the petrography as well as the chemistry of Khanak and Devsar granites, it is suggested that they might have derived from the different degree of partial melting from the similar source of magma.  相似文献   

8.
The Dahongliutan granitic pluton consists of two-mica granites and is located in the eastern part of the Western Kunlun Orogen, northwestern Tibetan Plateau. Zircon separates from the pluton yield a SIMS U–Pb age of 217.5 ± 2.8 Ma. Rocks from the pluton contain relatively high and uniform SiO2 (72.32–73.48 wt%) and total alkalis (Na2O + K2O = 8.07–8.67 wt%) and are peraluminous and high-K calc-alkaline to shoshonitic in composition. The Dahongliutan granites are relatively depleted in the high-field-strength elements and the heavy rare earth elements (HREEs) and have relatively high Rb, and low Ba and Sr concentrations. They contain low total rare earth element (REE) concentrations. The light REEs are strongly enriched relative to the HREEs, with (La/Yb)N values of 28.56–37.01. The εNd(t) values range from ?10.6 to ?8.8, and (87Sr/86Sr)i = 0.7142–0.7210. Zircons from the pluton yield εHf(t) values of ?13.8 to ?1.6, and δ18O = 10.5–11.6‰. Petrographic and geochemical features of the pluton indicate that the granites are S-type and were derived from parting melting of a mixture of metasedimentary and minor metaigneous sources in the middle–lower crust. Magmatic differentiation was dominated by the fractional crystallization of plagioclase, K-feldspar, muscovite, biotite, and accessory monazite, allanite, and Fe–Ti oxides. Regional granitoids were emplaced in the Early-to-Middle Triassic. Other younger granitoids, with ages of 240–200 Ma, are mostly I-type in character and were likely derived from multiple types of source rock, suggesting the source was heterogeneous Triassic crust. Such a scenario is consistent with their formation in a post-collisional setting. Our new data, combined with other geological evidence, suggest that the collision between the Tianshuihai and southern Kunlun terranes occurred between ca. 250 and 240 Ma, resulting in the closure of the Palaeo-Tethys. Post-collisional tectono-magmatic events may have occurred between 240 and 200 Ma.  相似文献   

9.
Whole rock elemental and Sr–Nd isotope geochemistry and in situ K-feldspar Pb isotope geochemistry were used to identify the sources involved in the genesis of Neoproterozoic granites from the Embu Terrane, Ribeira Belt, SE Brazil. Granite magmatism spanned over 200 Ma (810–580 Ma), and is dominated by crust-derived relatively low-T (850–750 °C, zircon saturation) biotite granites to biotite-muscovite granites. Two Cryogenian plutons show the least negative εNdt (−8 to −10) and highest mg# (30–40) of the whole set. Their compositions are strongly contrasted, implying distinct sources for the peraluminous (ASI ∼ 1.2) ∼660 Ma Serra do Quebra-Cangalha batholith (metasedimentary rocks from relatively young upper crust with high Rb/Sr and low Th/U) and the metaluminous (ASI = 0.96–1.00) ∼ 630 Ma Santa Catarina Granite. Although not typical, the geochemical signature of these granites may reflect a continental margin arc environment, and they could be products of a prolonged period of oceanic plate consumption started at ∼810 Ma. The predominant Ediacaran (595–580 Ma) plutons have a spread of compositions from biotite granites with SiO2 as low as ∼65% (e.g., Itapeti, Mauá, Sabaúna and Lagoinha granites) to fractionated muscovite granites (Mogi das Cruzes, Santa Branca and Guacuri granites; up to ∼75% SiO2). εNdT are characteristically negative (−12 to −18), with corresponding Nd TDM indicating sources with Paleoproterozoic mean crustal ages (2.0–2.5 Ga). The Guacuri and Santa Branca muscovite granites have the more negative εNdt, highest 87Sr/86Srt (0.714–0.717) and lowest 208Pb/206Pb and 207Pb/206Pb, consistent with an old metasedimentary source with low time-integrated Rb/Sr. However, a positive Nd–Sr isotope correlation is suggested by data from the other granites, and would be consistent with mixing between an older source predominant in the Mauá granite and a younger, high Rb/Sr source that is more abundant in the Lagoinha granite sample. The Ediacaran granites are coeval with profuse granite magmatism attributed to continental arc magmatism in northern Ribeira and Araçuaí belts. However, their evolved compositions with low mg# and dominantly peraluminous character are unlike those of magmatic arc granites, and they are more likely products of post-collisional magmatism or correspond to an inner belt of crust-derived granites.  相似文献   

10.
The Shexian gneissic granodiorite in southern Anhui trends NE 55° from Shexian in the west to Guitoujian in the east with a length of 22 km and an outcrop area of 32 km. It was considered formerly to be Caledonian on the basis of a biotite K-Ar age of 474 Ma (1982). However, new evidence indicates that it may be Early Jinning in age as shown by: (1) it is found intruding into the Mid-Proterozoic Shangxi Group and is unconformably overlain by the Sinian Xiuning Formation, and (2) a zircon U-Th-Pb age of 928 Ma is obtained for the pluton. The pluton is composed of plagioclase (An=27.37%), K-feldspar(14%), biotite(16%) and quartz(32%). Accessory minerals are ilmenite (150g/T), xenotime (15g/T). garnet(25g/T), monazite(10g/T), zircon (20g/T) and apatite (104g/T). Petrochemical characteristics of the intrusion are:(l) Al-enrichment (A/NKC=1.30); (2) H2O enrichment (H2O= 1.74%); and (3) low oxidation index (f ’=0.10). It belongs to the continental crust transformation type as evidenced by: (1) MF and Mg/Y values of biotite are 0.41 and 0.31 respectively; (2) (87Sr/86Sr)=0.71119; (3) δ Eu=0.52; and (4) A/NKC=130. The Shexian pluton is therefore considered as a product of melting of phyllite at depth in the light of similarities in trace element and REE contents with the phyllite of the Banxi Group. Calculations of REE batch partial melting indicate that it may have resulted from 75% melting of the Banxi phyllite.  相似文献   

11.
Whole-rock major and trace element and Sr-Nd isotopic data, together with zircon LA ICPMS in-situ U-Pb and Hf isotopic data of the syenites and granites in the Tengchong Block are reported in order to understand their petrogenesis and tectonic implications. Zircon U-Pb data gives the emplacement ages of ca. 115.3±0.9 Ma for syenites and 115.7±0.8 Ma for granites, respectively. The syenites are characterized by low SiO_2 content(62.01–63.03 wt%) and notably high Na_2O content(7.04–7.24 wt%) and Na_2O/K_2O ratios(2.02–2.10), low MgO, Fe_2O_3 T and TiO_2, enrichment of LILEs(large-ion lithophile element) such as Rb, Th, U, K, and Pb) and obvious depletion HFSE(high field strength element; e.g. Nb, Ta, P, and Ti) with clearly negative Eu anomalies(d Eu=0.53–0.56). They also display significant negative whole-rock εNd(t) values of-6.8 and zircon εHf(t) values(-9.11 to-0.27, but one is +5.30) and high initial ~(87) Sr/~(86) Sr=0.713013. Based on the data obtained in this study, we suggest that the ca. 115.3 Ma syenites were possibly derived from a sodium-rich continental crustal source, and the fractionation of some ferro-magnesian mineral and plagioclase might occur during the evolution of magma. The granites have high SiO_2 content(71.35–74.47 wt%), metaluminous to peraluminous, low Rb/Ba, Rb/Sr, and Al_2O_3/(MgO+FeOT+TiO_2) ratios and moderate(Al_2O_3+MgO+FeOT+TiO_2) content. They show low initial ~(87) Sr/~(86) Sr(0.703408 to 0.704241) and εNd(t) values(-3.8 to-3.5), plotted into the evolutionary trend between basalts and lower crust. Hence, we suggest that the granites were derived from the melting of mixing sources in the ancient continental crust involving some metabasaltic materials and predominated metasedimentary greywackes. Together with data in the literatures, we infer that the Early Cretaceous magmatism in the Tengchong block was dominated by magmas generated by the partial melting of ancient crustal material, which represent the products that associated to the closure of Bangong-Nujiang Meso-Tethys.  相似文献   

12.
The Leuchtenberg granite (Oberpfalz, NE Bavaria) displays a continuous differentiation trend ranging from mildy peraluminous, coarse-grained, porphyritic biotite granites (BG) to strongly peraluminous, medium- to fine-grained, garnet-bearing muscovite granites (GMG). The Rb–Sr and K–Ar age determinations of whole-rock and mineral samples from the granite and associated intermediate rocks (redwitzites) have revealed two divergent age gradients: Rb–Sr wholerock dates decrease and initial 87Sr/86Sr ratios increase for successively more evolved subsets of the granite. All BG samples (87Rb/86Sr=2–16) yield a date of 326±2 Ma with a low initial 87Sr/86Sr ratio of 0.70778±0.00013 (1), while all GMG samples (87Rb/86Sr=70 to 1000) yield a younger date of 317±2 Ma with an enhanced initial 87Sr/86Sr ratio of 0.7146±0.0039. The K–Ar measurements on biotites and muscovites give closely concordant dates for the GMG (326–323 Ma) and the southern lobe of the BG (324–320 Ma). The northern lobe of the BG, including the redwitzites, shows a well-defined trend of decreasing K–Ar dates from 320 Ma to 300 Ma towards the northwest. Critical consideration of both isotope systems leads to the conclusion that the Rb–Sr system of the GMG was disturbed by a later hydrothermal event. The ca. 326 Ma whole-rock Rb–Sr date for the BG is not in conflict with any of the K–Ar mineral dates and is taken as approaching the crystallization age of the Leuchtenberg granite. The K–Ar age progression within the northern lobe of the BG indicates that this part either cooled down over a protracted period of some 20 Ma or experienced reheating at ca. 300 Ma. The study highlights the potential of combined Rb–Sr and K–Ar dating in deciphering detailed chronology on the scale of a single igneous intrusion.  相似文献   

13.
Whole rock major and trace element and Sr-, Nd- and Hf-isotope data, together with zircon U-Pb, Hf- and O-isotope data, are reported for the Nb-Ta ore bearing granites from the Lingshan pluton in the Southeastern China, in order to trace their petrogenesis and related Nb-Ta mineralization. The Lingshan pluton contains hornblende-bearing biotite granite in the core and biotite granite, albite granite and pegmatite at the rim. In addition, numerous mafic microgranular enclaves occur in the Lingshan granites. Zircon SIMS U-Pb dating gives consistent crystallization ages of ca. 132 Ma for the Lingshan granitoids and enclaves, consistent with the Nb-Ta mineralization age of ∼132 Ma, indicating that mafic and felsic magmatism and Nb-Ta mineralization are coeval. The biotite granites contain hornblende, and are metaluminous to weakly peraluminous, with high initial 87Sr/86Sr ratios of 0.7071–0.7219, negative εNd(t) value of −5.9 to −0.3, εHf(t) values of −3.63 to −0.32 for whole rocks, high δ18O values and negative εHf(t) values for zircons, and ancient Hf and Nd model ages of 1.41–0.95 Ga and 1.23–1.04 Ga, indicating that they are I-type granites and were derived from partial melting of ancient lower crustal materials. They have variable mineral components and geochemical features, corresponding extensive fractionation of hornblende, biotite and feldspar, with minor fractionation of apatite. Existence of mafic microgranular enclaves in the biotite granites suggests a magma mixing/mingling process for the origin of the Lingshan granitoids, and mantle-derived mafic magmas provided the heat for felsic magma generation. In contrast, the Nb-Ta mineralized albite granites and pegmatites have distinct mineral components and geochemical features, which show that they are highly-fractionated granites with extensive melt and F-rich fluid interaction in the generation of these rocks. The fluoride-rich fluids induce the enrichment in Nb and Ta in the highly evolved melts. Therefore, we conclude that the Nb-Ta mineralization is the result of hydrothermal process rather than crystal fractionation in the Lingshan pluton, which provides a case to identify magmatic and hydrothermal processes and evaluate their relative importance as ore-forming processes.  相似文献   

14.
Penang Island represents the northwestern extension of the western magmatic belt of Peninsular Malaysia. Thirty-one samples of highly evolved biotite-and biotite-muscovite granites were used in an integrated study to unravel the complex magmatic, tectonic and cooling histories of these rocks. Highly distorted Rb–Sr whole-rock age patterns are evident. These are attributed to the partial post-magmatic Sr homogenization within the granite batholith which led to the rotation of isochrons towards younger ages and higher (87/86)Sr intercepts. The recognition of this mechanism allowed the establishment of a new Rb–Sr interpretation model. The intrusion ages of the granites can be extrapolated based on the evolutionary trend of the initial (87/86)Sr. Including the data of Bignell and Snelling, three episodes of granite emplacement at 307±8 Ma, 251±7 Ma and 211±2 Ma are suggested for Penang and the NW Main Range. The late-Triassic intrusive induced a hydrothermal conductive convection system which affected all the granites. It is considered to be responsible for the Rb–Sr whole-rock age distortion, the Rb–Sr and K–Ar biotite age resetting and the textural and mineralogical changes in the granites. The duration of the hydrothermal convections, deduced from the Rb–Sr whole rock ages, is about 6 Ma and 20 Ma in the northern and southern parts of Penang respectively. Fast regional cooling to 350±50°C within a time span of 1–3 Ma is recognized for the late-Triassic Feringgi intrusive from the mica ages, followed by a generally slow cooling rate of about 1°C/Ma. Fission track ages, in addition, indicate blockwise uplift along the N-S and NW-SE tending faults, thus resulting in the exposure of deeper crustal levels in southern and eastern Penang. A change in the tensional regime since Oligocene/Miocene, accompanied by a southwest tilting of the island, is indicated by the fission track apatite ages. Variable sometimes younger K–Ar, respectively Rb–Sr biotite ages mainly depend on the degree of hydrothermal overprint at different crustal levels. An increase of the reaction surface by grain size reduction influences Rb–Sr and K–Ar mica ages in similar ways, as has been demonstrated by experimental data.  相似文献   

15.
张超  吴新伟  张渝金  郭威  权京玉 《地质通报》2017,36(9):1531-1541
对大兴安岭北段龙江盆地光华组碱流岩进行了岩石地球化学及锆石U-Pb年龄研究,并对其岩石成因及构造意义进行了讨论。结果表明,龙江盆地碱流岩的锆石具有典型的岩浆振荡生长环带和较高的Th/U值(0.71~2.12),反映了岩浆成因特征,LAICP-MS锆石U-Pb年龄为122.4±1.7Ma(n=19,MSWD=0.77)。岩石富硅、富碱,贫Mg、Ca;稀土元素配分曲线呈现右倾"V"字形特征,显示强烈的负Eu异常;微量元素显示具有较低的Sr和Ba丰度,以及较高的Rb、Th、U、Zr等特点。以上特征表明,龙江盆地碱流岩类似于铝质A1型花岗岩,为长英质地壳部分熔融及其后斜长石和Ti、Fe氧化物分离结晶作用的产物,代表了伸展的构造环境。  相似文献   

16.
The Zhuguangshan complex carries some of the most important granite-hosted uranium deposits in South China. Here we investigate the Changjiang and Jiufeng granites which represent typical U-bearing and barren granites in the complex, using zircon U-Pb ages, whole-rock geochemistry, Sr-Nd isotopic and zircon Hf isotopic data, and mineral chemistry, to constrain the petrogenesis and uranium mineralization. LA-ICP-MS zircon U-Pb dating shows that both the Changjiang and Jiufeng granites were emplaced ca. 160 Ma. These rocks show high silica, weakly to strongly peraluminous compositions, enrichment in Rb, Th, and U, and depletion in Ba, Nb, Sr, P, and Ti. These features coupled with the high initial 87Sr/86Sr ratios, negative εNd(t) values and εHf(t) values, and the Paleoproterozoic two stage model ages of these two granites suggest that the two granites belong to S-type granites, and the parental magmas of the two granites were derived from the Paleoproterozoic metasedimentary rocks. However, the granitoids show different mineralogical characteristics. The biotite in the Changjiang granite belongs to siderophyllite, marking higher degree of chloritization, whereas the biotite in the Jiufeng granite is ferribiotite, characterized by only slight chloritization. Compared with the Jiufeng granite, the biotite in the Changjiang granite has lower crystallization temperature and oxygen fugacity, but higher F content, and the uraninite has higher UO2 content but lower ThO2 content, and stronger corrosion. The chemical ages of uraninites from both granites are (within error) consistent with the zircon U-Pb ages and are considered to represent the emplacement ages of granites. Chemical ages of pitchblende in the Changjiang granite yield 118 ± 8 Ma, 87 ± 4 Ma, and 68 ± 6 Ma, representing multiple episodes of hydrothermal events that are responsible for the precipitation of U ores in the Changjiang uranium ore field. Our study suggests that the degree of magma differentiation and physicochemical conditions of the magmatic-hydrothermal system are the key factors that control the different U contents of these two granites. The mineralogical characteristics of uraninite and biotite can be used to distinguish between U-bearing and barren granites, and serve as a potential tool for prospecting granite-hosted uranium deposits.  相似文献   

17.
《Gondwana Research》2014,26(4):1570-1598
Granitic rocks are commonly used as means to study chemical evolution of continental crust, particularly, their isotopic compositions, which reflect the relative contributions of mantle and crustal components in their genesis. New SIMS and K–Ar geochronology, isotope, geochemical, and mineral chemistry data are presented for the granitoid rocks located in and around Gabal Dara in the Northern Eastern Desert of Egypt. The granitoid suite comprises quartz diorites, Muscovite (Mus) trondhjemites, and granodiorites intruded by biotite-hornblende (BH) granites and alkali feldspar (AF) granites. Mus trondhjemite, granodiorite and BH granite exhibit I-type calc alkaline affinities. Mus trondhjemite and granodiorite show medium-K calc-alkaline and metaluminous/mildy peraluminous affinities, whereas BH granites have high-K calc-alkaline and metaluminous character. Concordant 206Pb/238U weighted mean ages together with geochemical peculiarities suggest that Mus trondhjemites (741 Ma) followed by granodiorites (720 Ma) are genetically unrelated, and formed in subduction-related regime by partial melting of lower oceanic crust together with a significant proportion of mantle melt. The genesis of Mus trondhjemites is correlated with the main event in the evolution of the Eastern Desert, called “~750 Ma crust forming event”.The field and geochemical criteria together with age data assign the high-K calc-alkaline BH granites (608–590 Ma) and alkaline AF granites (600–592 Ma) as post-collisional granites. The differences in geochemical traits, e.g. high-K calc-alkaline versus alkaline/peralkaline affinities respectively, suggest that BH granites and AF granites are genetically unrelated. The age overlap indicating coeval generation of calc-alkaline and alkaline melts, which in turn suggests that magma genesis was controlled by local composition of the source. The high-K calc-alkaline BH granites are most likely generated from lithospheric mantle melt which have been hybridized by crustal melts produced by underplating process. AF granites exhibit enrichment in K2O, Rb, Nb, Y, and Th, and depletion in Al2O3, TiO2, MgO, CaO, FeO, P2O5, Sr, and Ba as well as alkaline/peralkaline affinity. These geochemical criteria combined with the moderately fractionated rare earth elements pattern (LaN/YbN = 9–14) suggest that AF granite magma might have been generated by partial melting of Arabian–Nubian Shield (ANS) arc crust in response of upwelling of hot asthenospheric mantle melts, which became in direct contact with lower ANS continental crust material due to delamination. Furthermore, a minor role of crystal fractionation of plagioclase, amphibole, biotite, zircon, and titanomagnetite in the evolution of AF granites is also suggested. The low initial 87Sr/86Sr ratios (0.7033–0.7037) and positive εNd(T) values (+ 2.32 to + 4.71) clearly reflect a significant involvement of depleted mantle source in the generation of the post-collision granites and a juvenile nature for the ANS.  相似文献   

18.
Intrusion-related migmatites comprise a substantial part of the high-grade part of the southern Damara orogen, Namibia which is dominated by Al-rich metasedimentary rocks and various granites. Migmatites consist of melanosomes with biotite+sillimanite+garnet+cordierite+hercynite and leucosomes are garnet- and cordierite-bearing. Metamorphic grade throughout the area is in the upper amphibolite to lower granulite facies (5–6 kbar at 730–750 °C). Field evidence, petrographic observations, chemical data and mass balance calculations suggest that intrusion of granitic magmas and concomitant partial melting of metasedimentary units were the main processes for the generation of the migmatites. The intruding melts were significantly modified by magma mixing with in situ partial melts, accumulation of mainly feldspar and contamination with garnet from the wall rocks. However, it is suggested that these melts originally represented disequilibrium melts from a metasedimentary protolith. The occurrence of LILE-, HFSE- and LREE-enriched and -depleted residues within the leucosomes implies that both quartzo-feldspathic and pelitic rocks were subjected to partial melting. Isotope ratios of the leucosomes are rather constant (143Nd/144Nd (500 Ma): 0.511718–0.511754, ε Nd (500 Ma): ?3.54 to ?5.11) and Sr (87Sr/86Sr (500 Ma): 0.714119–0.714686), the metasedimentary units have rather constant Nd isotope ratios (143Nd/144Nd (500 Ma): 0.511622–0.511789, ε Nd (500 Ma): ?3.70 to ?6.93) but variable Sr isotope ratios Sr (87Sr/86Sr (500 Ma): 0.713527–0.722268). The most restitic melanosome MEL 4 has a Sr isotopic composition of 87Sr/86Sr (500 Ma): 0.729380. Oxygen isotopes do not mirror the proposed contamination process, due to the equally high δ18O contents of metasediments and crustal melts. However, the most LILE-depleted residue MEL 4 shows the lowest δ18O value (<10). Mass balance calculations suggest high degrees of partial melting (20–40%). It is concluded that partial melting was promoted by heat transfer and release of a fluid phase from the intruding granites. High degrees of partial melting can be reached as long as the available H2O, derived from the crystallization of the intruding granites, is efficiently recycled within the rock volume. Due to the limited amounts of in situ melting, it seems likely that such regional migmatite terranes are not the sources for large intrusive granite bodies. The high geothermal gradient inferred from the metamorphic conditions was probably caused by exhumation of deep crustal rocks and contemporaneous intrusion of huge masses of granitoid magmas. The Davetsaub area represents an example of migmatites formed at moderate pressures and high temperatures, and illustrates some of the reactions that may modify leucosome compositions. The area provides constraints on melting processes operating in high-grade metasedimentary rocks.  相似文献   

19.
Magnesium isotopic compositions, along with new Sr–Nd–Pb isotopic data and elemental analyses, are reported for 12 Miocene tourmaline-bearing leucogranites, 15 Eocene two-mica granites and 40 metamorphic rocks to investigate magnesium isotopic behaviors during metamorphic processes and associated magmatism and constrain the tectonic-magmatic-metamorphic evolution of the Himalayan orogeny. The gneisses, granulites and amphibolites represent samples of the Indian lower crust and display large range in δ26Mg from −0.44‰ to −0.09‰ in mafic granulites, −0.44‰ to −0.10‰ in amphibolites, and −0.70‰ to −0.03‰ in granitic gneisses. The average Mg isotopic compositions of the granitic gneisses (−0.19 ± 0.34‰), mafic granulites (−0.22 ± 0.17‰) and amphibolites (−0.25 ± 0.24‰) are similar, indicating the limited Mg isotope fractionation during prograde metamorphism from granitic gneisses to mafic granulites and retrograde metamorphism from mafic granulites to amphibolites. The Eocene two-mica granites and Miocene leucogranites are characterized by large variations in elemental and Sr–Nd–Pb isotopic compositions. The leucogranites and two-mica granites have their corresponding (87Sr/86Sr)i varying from 0.7282 to 0.7860 and 0.7163 to 0.7191, (143Nd/144Nd)i from 0.511888 to 0.512040 and 0.511953 to 0.512076, 207Pb/204Pb from 15.7215 to 15.7891 and 15.7031 to 15.7317, 208Pb/204Pb from 38.8521 to 39.5286 and 39.2710 to 39.4035, and 206Pb/204Pb from 18.4748 to 19.0139 and 18.7834 to 18.9339. However, they have similar Mg isotopic compositions (−0.21‰ to +0.06‰ versus −0.24‰ to +0.09‰), which did not originate from fractional crystallization nor source heterogeneity. Based on hornblende/biotite/muscovite dehydration melting reaction and Mg isotopic variations in two-mica granites and leucogranites with the proceeding metamorphism, along with elemental discrimination diagrams, Eocene two-mica granites and Miocene leucogranites could be related to hornblende dehydration melting and muscovite dehydration melting, respectively. Mg isotopic compositions of Eocene two-mica granites become heavier compared to the source because of residues of isotopically light garnet in the source; while those of Miocene leucogranites become lighter because of entrainment of isotopically light garnet from the source region. Thus, a new model for crustal anatexis and Himalayan orogenesis was proposed based on the Mg isotope fractionation in the leucogranites and metamorphic rocks. This model emphasizes a successive process from Indian continental subduction to rapid exhumation of the Higher Himalayan Crystalline Series (HHCS). The former underwent high-temperature (HT) and high-pressure (HP) granulite-facies prograde metamorphism, which resulted in the hornblende dehydration melting and the formation of Eocene two-mica granites; while the latter experienced amphibolite-facies retrogression and decompression, which resulted in the muscovite dehydration melting and the formation of Miocene leucogranites.  相似文献   

20.
We report in the paper integrated analyses of in situ zircon U–Pb ages, Hf–O isotopes, whole-rock geochemistry and Sr–Nd isotopes for the Longlou granite in northern Hainan Island, southeast China. SIMS zircon U–Pb dating results yield a crystallization age of ∼73 Ma for the Longlou granite, which is the youngest granite recognized in southeast China. The granite rocks are characterized by high SiO2 and K2O, weakly peraluminous (A/CNK = 1.04–1.10), depletion in Sr, Ba and high field strength elements (HFSE) and enrichment in LREE and large ion lithophile elements (LILE). Chemical variations of the granite are dominated by fractional crystallization of feldspar, biotite, Ti–Fe oxides and apatite. Their whole-rock initial 87Sr/86Sr ratios (0.7073–0.7107) and εNd(t) (−4.6 to −6.6) and zircon εHf(t) (−5.0 to 0.8) values are broadly consistent with those of the Late Mesozoic granites in southeast China coast. Zircon δ18O values of 6.9–8.3‰ suggest insignificant involvement of supracrustal materials in the granites. These granites are likely generated by partial melting of medium- to high-K basaltic rocks in an active continental margin related to subduction of the Pacific plate. The ca. 73 Ma Longlou granite is broadly coeval with the Campanian (ca. 80–70 Ma) granitoid rocks in southwest Japan and South Korea, indicating that they might be formed along a common Andean-type active continental margin of east–southeast Asia. Tectonic transition from the Andean-type to the West Pacific-type continental margin of southeast China likely took place at ca.70 Ma, rather than ca. 90–85 Ma as previously thought.  相似文献   

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