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1.
Vertical profiles of 210Po in soils near the Midwest uranium deposit and an associated surficial radioactive sandstone boulder train in northern Saskatchewan show a high 210Po background in air-dried forest litter (24 pCi/g) and Ah horizon soil (11 pCi/g) relative to lower soil horizons (<1 pCi/g). These high levels mask the 210Po signal from the radioactive boulders in the near-surface soil horizons. Only in the Bf and C horizons can the existence of the radioactive boulders be inferred from 210Po determinations. For comparative purposes profiles for 226Ra, U, Ni, and other trace elements are also presented.Escape of most of the Rn from near surface soils into the atmosphere, homogenization and decay of Rn, and precipitation of decay products back onto surface soils satisfactorily explain the field observations discussed here.Compared to the highly anomalous 222Rn signal in soil gases over this boulder train the 210Po contrast is very weak and is of little use for prospecting for this type of boulder train. The relatively high 210Po background in surficial materials relative to lower soil horizons dictates that great care be taken with the 210Po method; the deepest possible horizons should be sampled.  相似文献   

2.
《Applied Geochemistry》1993,8(5):447-471
Ground water is the main source of domestic and public supply in the Carson River Basin. Ground water originates as precipitation primarily in the Sierra Nevada in the western part of Carson and Eagle Valleys, and flows down gradient in the direction of the Carson River through Dayton and Churchill Valleys to a terminal sink in the Carson Desert. Because radionuclides dissolved in ground water can pose a threat to human health, the distribution and sources of several naturally occurring radionuclides that contribute to gross-alpha and gross-beta activities in the study area were investigated. Generally, alpha and beta activities and U concentration increase from the up-gradient to down-gradient hydrographic areas of the Carson River Basin, whereas222Rn concentration decreases. Both226Ra and228Ra concentrations are similar throughout the study area. Alpha and beta activities and U concentration commonly exceed 100 pCi/l in the Carson Desert at the distal end of the flow system. Radon-222 commonly exceeds 2,000 pCi/l in the western part of Carson and Eagle Valleys adjacent to the Sierra Nevada. Radium-226 and228Ra concentrations are <5pCi/l. Four ground water samples were analyzed for210Po and one sample contained a high concentration of 21 pCi/l. Seven samples were analyzed for210Pb; six contained <3pCi/l and one contained 12 pCi/l. Thorium-230 was detected at concentrations of 0.15 and 0.20 pCi/l in two of four samples.Alpha-emitting radionuclides in the ground water originated from the dissolution of U-rich granitic rocks in the Sierra Nevada by CO2, oxygenated water. Dissolution of primary minerals, mainly titanite (sphene) in the granitic rocks, releases U to the water. Dissolved U is probably removed from the water by adsorption on Fe- and Mn-oxide coatings on fracture surfaces and fine-grained sediment, by adsorption on organic matter, and by coprecipitation with Fe and Mn oxides. These coated sediments are transported throughout the basin by fluvial processes. Thus, U is transported as dissolved and adsorbed species. A rise in the water table in the Carson Desert because of irrigation has resulted in the oxidation of U-rich organic matter and dissolution of U-bearing coatings on sediments, producing unusually high U concentration in the ground water.Alpha activity in the ground water is almost entirely from the decay of U dissolved in the water. Beta activity in ground water samples is primarily from the decay of40K dissolved in the water and ingrowth of238U progeny in the sample before analysis. Approximately one-half of the measured beta activity may not be present in ground water in the aquifer, but instead is produced in the sample after collection and before analysis. Potassium-40 is primarily from the dissolution of K-containing minerals, probably K-feldspar and biotite. Radon-222 is primarily from the decay of226Ra in the aquifer materials. Radium in the ground water is thought to be mainly from alpha recoil associated with the decay of Th in the aquifer material. Some Ra may be from dissolution (or desorption) or Ra-rich coatings on sediments.  相似文献   

3.
 Two test cases from Israel are presented herein employing the decay rate of radon along the flow path to assess groundwater flow velocities. Groundwater flow reaching the fault zone emerges in several places along the rift fault zone as thermal springs because of deep water confinement. The high water temperature of the surface is indicative of high vertical flow velocities, which maintains the original high temperatures. Knowing the Rn content at a source point and at a given down-gradient, and assuming no Rn addition from the water itself or along the flow path, one can calculate the flow velocity based on the Rn half-life time. The decay of Rn in western Galilee was found to be ∼570–150 pCi/l, and in the Dead Sea area from 5000–2000 pCi/l along a respective flow path of 1000 and 200 m, Based on the above, the calculated flow velocities were compared with those obtained from pumping tests in the study area. The method is applicable, because of the short Rn half-life, to cases of high Rn contents, short distances and high flow velocities. Received: 18 January 2000 · Accepted: 21 March 2000  相似文献   

4.
Analysis of 153 residential air radon (Rn-222) screening measurements from southeast Michigan indicates that basements host Rn levels two to three times higher than upper-level rooms. Compared to unfinished basements, finished (e.g., paneled walls, tiled floors) basements apparently reduce indoor air Rn levels while partially finished basements may not. Factor analysis of residence questionnaire data explains 59 percent of the Rn data variance. The volume of pathways (e.g., foundation cracks/holes, uncapped sumps) allowing Rn seepage into the dwelling controls the largest portion, 23 percent, of the explained data variance. The residence water source explains 11 percent of the Rn data variance. Groundwater Rn levels contribute to the air Rn data variability, but the study data cannot quantitatively assess this contribution. Seven percent of the Rn data variance is likely controlled by house depressurization facilitated by residence structural properties. Residences with foundation cracks or poorly sealed joints and low-volume indoor-outdoor air exchange are more prone to this effect. Eighteen percent of the explained Rn data variance correlates with the residence's primary heat source. Evidently, operating combustion sources also induce house depressurization and allow Rn to be drawn into the house through entry paths. Twenty-four percent of the analyses equal or exceed 4 pCi/1 Rn. In residences occupied 5 years by the same individuals, 17 percent of the Rn data are 4 pCi/l; here the arithmetic mean air Rn level is 8.3 pCi/l and the average occupancy period 17.4 years.  相似文献   

5.
The abundance and distribution of radioelements on bulk and microscopic scales were investigated in residual granitic-derived soil at a facility for investigating the movement of radon into structures. In bulk soil samples, Ra concentrations range from 0.6 to 1.3 pCi/g, and variations in Ra, Th, and K appear to be controlled mainly by heterogeneities inherited from the parent granitic rock, which contains abundant dikes and inclusions. U in soil and parent rock is concentrated in primary minerals (mainly zircon and sphene), and in secondary sites that are of greater importance for Rn emanation. The main U-bearing secondary sites are weathered sphene, grain boundary coatings, weathered biotite and plagioclase, as well as dense Fe-rich coatings and a REE-phosphate mineral present in near-vertical fracture zones in saprolite underlying shallow loam. Elevated U in these sites generally correlates with high Ti, Al, Fe, and/or P. Preferential distribution of U and Ra on grain boundaries and porous weathered minerals is reflected in relatively high Rn emanation rates in the soil. Highest emanation occurs between 1.3 and 2.3 m depth, where fine pedogenic phasesgibbsite and amorphous silica and Fe-OOH—are most abundant; it is related to fixation of Ra by these phases, which precipitate close to the surface and accumulate at these depths by illuviation. Separation of Ra from U may occur locally, given remobilization of U-series elements from secondary sites, and large differences between Ra and U sorption capabilities of several phases present in the soil. Concentration of U along permeable fracture zones in saprolite suggests that contribution of soil-gas Rn from depth (> 2 m) could be significant to Rn availability near the surface.  相似文献   

6.
《Applied Geochemistry》1997,12(2):213-224
In March 1994, soil gases were sampled in the area of Vulcano Porto, on the island of Vulcano, using a grid of about 200 points/km2. Analysed gases were CO2, He and222Rn and, over a smaller area, H2S. Some of the samples were also analysed for the isotope composition of CO2C. Three anomalous CO2 degassing areas were identified: Grotta dei Palizzi, the area near the Telephone Exchange, and the area near the beach fumaroles. The behaviour of He and222Rn is different in these 3 areas. The concentration of He is much lower than that of atmospheric He (down to −3950 ppb) in the isthmus, and only in the area near Grotta dei Palizzi does it have values significantly higher than atmospheric ones (up to 1900 ppb). The activity of222Rn, always significantly positively related to CO2 concentrations, peaked in the 2 fumarole areas (isthmus, Telephone Exchange).  相似文献   

7.
High indoor radon in approximately 30 percent of private dwellings in the Albuquerque, New Mexico area has been reported previously. The present study explains the areas of high indoor radon as a function of different soil and/or bedrock in the area. Soils were sampled during summer and winter periods using alpha track radon detectors. The values range from 40 to 890 pCi/I air at a depth of 38 cm. The gross mean average is 360 pCi/I for the area for summer readings and 200 pCi/I for winter readings; both values are well over the average U.S. soil radon values of approximately 100 pCi/I. Analyses of soil uranium show a range in values of 1–6 ppm, with a mean of 3.1 ppm. Thorium values range from 3.3 to 28.8 ppm, and Th/U ratios range from 2.9 to 4.6.These values for U, Th, and Th/U suggest that soil U and Th are close to the values reported for the Sandia granite, the source of most of the pediment on which Albuquerque is built. Soil infiltration rates range from ~6 × 10–4 to 4.5 × 10–3 cm/sec for the samples, and soil moisture content ranges from 1.4 to 7.2 percent. A fair correlation of summer soil radon with infiltration rate is noted. Correlation of soil radon with moisture content and/or with percent silt, silt + clay, clay size fraction material is not established by this study. Soil radon values do correlate with regions in the Albuquerque area where high indoor radon is common. A better correlation of high indoor radon values with soils developed immediately over bedrock is observed. Furthermore, all values of average soil and indoor radon increase significantly with proximity of the stations to the Sandia Mountains. Soil uranium also shows this trend. The data argue that regions of potentially high radon can thus be identified.  相似文献   

8.
The concentrations of uranium. 226Ra and 222Rn were determined in 308 drilled and 58 dug wells in the Helsinki region. The study area was about 400 km2 and geologically highly variable, with granites, amphibolites and migmatites the dominant rocks. The radioactivity of water in the dug wells was on a “normal” level, but in numerous drilled wells it was anomalously high. In 14 drilled wells the concentration of uranium exceeded 1000 μg/l, the highest concentration being 14,870 μg/l. For 222Rn the maximum concentration was 880,000 pCi/l. The 226Ra228Ra and 230Th232Th activity ratios showed the isotopes of the uranium series to be dominant in the study area. A state of disequilibrium between 238U and 234U was very common in the samples. The 234U238U activity ratios varied in the range 1.0–4.0 regardless of the amount of uranium in the water. The conclusion can be drawn from the isotopic data that the high radioactivity of water is in some cases caused by primary uranium mineralizations, but mostly by uranium deposited in fissures of the bedrock. The paper includes a summary of the results of two studies carried out between 1967 and 1977.  相似文献   

9.
Published reports show that 222Rn contents of soil gas can increase under snow-covered or frozen soils. By utilizing these observations and results of field tests described here, it can be stated that U prospecting with 222Rn in frozen terrain is practicable.Rn profiles in frozen and snow-covered soils over U mineralization in the Bancroft area of Ontario outlined known radioactive zones more clearly than did scintillometer profiles.Tests in Gatineau Park, Quebec, in the proximity of a radioactive pegmatite dike showed that lake ice acts as a restrictive barrier to Rn movement from lake waters beneath. Water samples, collected and allowed to freeze in plastic bottles, retained dissolved Rn quite effectively thus permitting sample collection and storage under the most severe winter conditions. Rn sampling of through-ice lake waters is therefore a feasible prospecting tool.Samples of spring run-off (snow-melt) waters and slushy snow collected from within a known weakly radioactive zone near South March, Ontario, were shown to contain less Rn than found in the same stream waters in the summer. No pronounced Rn degassing event of frozen soils was apparent early in the spring thaw in percolating run-off waters draining from the zone. The usefulness of spring thaw hydrogeochemistry using Rn is discussed.  相似文献   

10.
Granulometric analysis of nineteen sediment samples has been carried out for their statistical and textural parameters. The samples are collected from the northern and southern margins of Schirmacher Oasis extending below the polar ice sheet and grading to coastal area respectively and main rocky land of Schirmacher including lakes. The analysis shows that most of the sediments are of medium grain size and fall in poor to very poor sorted category. An attempt has been made to interpret the depositional set-up by plotting the scatter patterns between various textural parameters, including C-M plot and arithmetic log-probability curves. The influence of physical parameters viz. low to high velocity winds, ice and meltwater on sediment characteristics has been discussed.  相似文献   

11.
Land‐terminating parts of the west Greenland ice sheet have exhibited highly dynamic meltwater regimes over the last few decades including episodes of extremely intense runoff driven by ice surface ablation, ponding of meltwater in an increasing number and size of lakes, and sudden outburst floods, or ‘jökulhlaups’, from these lakes. However, whether this meltwater runoff regime is unusual in a Holocene context has not been questioned. This study assembled high‐resolution topographical data, geological and landcover data, and produced a glacial geomorphological map covering ~1200 km2. Digital analysis of the landforms reveals a mid‐Holocene land‐terminating ice margin that was predominantly cold‐based. This ice margin underwent sustained active retreat but with multiple minor advances. Over c. 1000 years meltwater runoff became impounded within numerous and extensive proglacial lakes and there were temporary connections between some of these lakes via spillways. The ice‐dams of some of these lakes had several quasi‐stable thicknesses. Meltwater was apparently predominantly from supraglacial sources although some distributary palaeochannel networks and some larger bedrock palaeochannels most likely relate to mid‐Holocene subglacial hydrology. In comparison to the geomorphological record at other Northern Hemisphere ice‐sheet margins the depositional landforms in this study area are few in number and variety and small in scale, most likely due to a restricted sediment supply. They include perched fans and deltas and perched braidplain terraces. Overall, meltwater sourcing, routing and the proglacial runoff regime during the mid‐Holocene in this land‐terminating part of the ice sheet was spatiotemporally variable, but in a manner very similar to that of the present day.  相似文献   

12.
Ice sheets that advance upvalley, against the regional gradient, commonly block drainage and result in ice‐dammed proglacial lakes along their margins during advance and retreat phases. Ice‐dammed glacial lakes described in regional depositional models, in which ice blocks a major lake outlet, are often confined to basins in which the glacial lake palaeogeographical position generally remains semi‐stable (e.g. Great Lakes basins). However, in places where ice retreats downvalley, blocking regional drainage, the palaeogeographical position and lake level of glacial lakes evolve temporally in response to the position of the ice margin (referred to here as ‘multi‐stage’ lakes). In order to understand the sedimentary record of multi‐stage lakes, sediments were examined in 14 cored boreholes in the Peace and Wabasca valleys in north‐central Alberta, Canada. Three facies associations (FAI–III) were identified from core, and record Middle Wisconsinan ice‐distal to ice‐proximal glaciolacustrine (FAI) sediments deposited during ice advance, Late Wisconsinan subglacial and ice‐marginal sediments (FAII) deposited during ice‐occupation, and glaciolacustrine sediments (FAIII) that record ice retreat from the study area. Modelling of the lateral extent of FAs using water wells and gamma‐ray logs, combined with interpreted outlets and mapped moraines based on LiDAR imagery, facilitated palaeogeographical reconstruction of lakes and the identification of four major retreat‐phase lake stages. These lake reconstructions, together with the vertical succession of FAs, are used to develop a depositional model for ice‐dammed lakes during a cycle of glacial advance and retreat. This depositional model may be applied in other areas where meltwater was impounded by glacial ice advancing up the regional gradient, in order to understand the complex interaction between depositional processes, ice‐marginal position, and supply of meltwater and sediment in the lake basin. In particular, this model could be applied to decipher the genetic origin of diamicts previously interpreted to record strictly subglacial deposition or multiple re‐advances.  相似文献   

13.
冰川表面水文过程研究进展   总被引：1，自引：1，他引：0  
杨康  刘巧 《冰川冻土》2016,38(6):1666-1678
冰面水文过程是冰川径流过程的重要组成部分,对于冰川运动与物质平衡具有重要影响。冰川表面在太阳辐射、冰川物理性质、冰面地形和成冰带空间分布等多种因素影响下消融,形成以冰面水系为主线,锅穴、冰裂隙、冰面湖等为端点的冰面融水输送与分配体系。深入理解冰面水文过程,掌握冰川表面融水的输送、存储与释放,对于研究短时间尺度的冰川融水径流过程、探索冰川动态响应机理具有重要意义。总结回顾了目前国内外冰面水文过程的研究现状,提出了该领域有待解决的主要科学问题。  相似文献   

14.
Generally, sandstone-type uranium deposits can be divided into three zones according to their redox conditions: oxidized zone, ore zone and reduced zone. The Dongsheng uranium deposit belongs to this type. In order to study its geochemical characteristics, 11 samples were taken from the three zones of the Dongsheng uranium deposit. Five samples of them were collected from the oxidized zone, four samples from the ore zone and two samples from the reduced zone. These samples were analyzed using organic and inorganic geochemical methods. The results of GC traces and ICP-MASS indicate that the three zones show different organic and inorganic geochemical characteristics.  相似文献   

15.
The isotopic (U-Pb, 238U-235U, 234U-238U) and chemical study of whole-rock samples and finegrained fractions of rocks in a vertical section of the terrigenous sequence at the Dybryn uranium deposit in the Khiagda ore field shows that a wide U-Pb isotopic age range (26.9-6.5 Ma) is caused by oxidation and disturbance of the U-Pb isotopic system in combination with protracted uranium ore deposition. The oxidation of rocks resulted in the loss of uranium relative to lead and eventually to an overestimated 206Pb/238U age at sites with a low U content. The 238U/235U ratios in the studied samples are within the range of 137.74–137.88. Samples with a high uranium content are characterized by a decreasing 238U/235U ratio with a decrease in 207Pb/235U and 206Pb/238U ages. A nonequilibrium 234U/238U ratio in most studied samples furnishes evidence for young (<1.5 Ma) transformation of the Miocene uranium ore, which is responsible for uranium migration and its redeposition.  相似文献   

16.
Radon levels were surveyed in 517 monitoring wells constructed in five major groundwater areas of Taiwan. The radon concentration in groundwater samples varied in a wide range from below the detection limit of 18 pCi/L up to 1,100 pCi/L. A worldwide comparison of reported groundwater radon levels was conducted. Overall radon levels in Taiwan groundwater are relatively low compared to other countries because the geology of Taiwan is mainly comprised of sedimentary rocks. Among the 517 wells monitored, only five wells were found with radon concentrations higher than 500 pCi/L. These five wells are all located near the Chaochou Fault in the Pingtung Plain. This study suggests that well sites near the Chaochou Fault could be good locations to monitor radon anomalies for earthquake prediction and should be avoided for developing domestic water supply. In the recharge area near the Chaochou Fault, the radon concentration in groundwater from shallow wells was approximately 1/2 to 1/4 of that from deep wells in the same cluster.
Resumen Se investigaron los niveles de radón en 517 pozos de monitoreo, construidos en las cinco mayores áreas de agua subterránea de Taiwan. La concentración de radón en las muestras de agua subterránea varía en un rango amplio, desde inferior al límite de detección que es 18 pCi/L hasta 1,100 pCi/L. Se realizó una comparación a escala mundial de los niveles de radón reportados en agua subterránea. En general los niveles de radón presente en el agua subterránea de Taiwan, son relativamente bajos comparados con otros países, puesto que la geología de Taiwan está compuesta de rocas sedimentarias. Entre los 517 pozos monitoreados, solamente en cinco se encontraron concentraciones de radón mayores a 500 pCi/L. Estos cinco pozos están todos localizados cerca de la falla ChaoChou en la Planicie de PingTung. El presente estudio sugiere que los pozos cercanos a la falla Chaochou, podrían ser buenos sitios para monitorear anomalías de radón para la predicción de terremotos y deberían evitarse para los desarrollos de abastecimiento de agua potable. En la zona de recarga cerca de la falla Chaochou, la concentración de radón en agua subterránea obtenida en pozos someros, fue aproximadamente de &frac; a &frac; de aquella en pozos profundos ubicados en el mismo sector.
Résumé On a mesuré les taux de Rn dans 517 forages ouverts dans cinq aquifères majeures de Taiwan. Les concentrations en Rn couvrent un domaine très large, à partir de valeurs très basses, au dessous de la limite de détection de 18pCi/l jusquaux valeurs assez grandes de 1100pCi/l. On a mené une analyse comparative avec des valeurs mentionnées en littérature. Par report aux valeurs mesurées en autres pays, les concentrations en Rn en Taiwan sont asses basses, compte que la structure géologique de Taiwan est constituée surtout par des roches sedimentaires. On a trouvé des concentrations au desuss de 500pCi/l seulement en cinq de 517 forages investigués. Tous ces cinq forages se trouvent au voisinage de la faille de Chaochou dans la plaine de Pingtung. Cet étude suggere que les forages situés près de la faille de Chaochou peuvent bien monitoriser les anomalie de Rn pour la prédiction des séismes mais doivent être évités lorsqil sagit de lalimentation en eau potable. Dans la zone de recharge près de la faille de Chaochou les concentrations en Rn mesurées dans les puits peu profondes representent 1/2-1/4 de ceux mesurées dans les forages de profondeur.
  相似文献   

17.
During the Vashon Stade of the Fraser Glaciation, about 15,000–13,000 yr B.P., a lobe of the Cordilleran Ice Sheet occupied the Puget lowland of western Washington. At its maximum extent about 14,000 yr ago, the ice sheet extended across the Puget lowland between the Cascade Range and Olympic Mountains and terminated about 80 km south of Seattle. Meltwater streams drained southwest to the Pacific Ocean and built broad outwash trains south of the ice margin. Reconstructed longitudinal profiles for the Puget lobe at its maximum extent are similar to the modern profile of Malaspina Glacier, Alaska, suggesting that the ice sheet may have been in a near-equilibrium state at the glacial maximum. Progressive northward retreat from the terminal zone was accompanied by the development of ice-marginal streams and proglacial lakes that drained southward during initial retreat, but northward during late Vashon time. Relatively rapid retreat of the Juan de Fuca lobe may have contributed to partial stagnation of the northwestern part of the Puget lobe. Final destruction of the Puget lobe occurred when the ice retreated north of Admiralty Inlet. The sea entered the Puget lowland at this time, allowing the deposition of glacial-marine sediments which now occur as high as 50 m altitude. These deposits, together with ice-marginal meltwater channels presumed to have formed above sea level during deglaciation, suggest that a significant amount of postglacial isostatic and(or) tectonic deformation has occurred in the Puget lowland since deglaciation.  相似文献   

18.
Sediments deposited in two small ice-contact lakes with low rates of sediment input have been studied in subaerial exposures. Sediment characteristics are a function of the water source (glacial meltwater versus non-meltwater), proximity to the glacier margin and lake shore, amount of supraglacial debris, and lake duration. Calving Lake expanded (and later partially drained) as a calving ice margin retreated. Nearshore deltas contain 1 × 105 m3 stratified sand and gravel deposited at rates up to 1 m/yr during a 9-yr interval. Deltaic sediment contains types A and B ripple-drift cross-lamination, draped lamination, and scour surfaces caused by variations in water-flow velocity and the amount of sediment settling from suspension. Most water inflow came from non-subglacial meltwater sources and was sediment-poor, so overflow and interflow sedimentation processes dominated the offshore environment. Offshore sediment generally contains massive silt or silt interbedded with fine-grained sand deposited at rates of 1.3-1.5 cm/yr. Iceberg gravity craters observed on the lake plain were formed when icebergs impacted the lake floor during calving events. In Bruce Hills Lake, proximity to glacier ice and the presence of supraglacial sediment formed coarsening-upward successions when debris fell directly from an ice ledge onto silty lacustrine sediment.  相似文献   

19.
The mineralogy and geochemistry of soils developed over the unmined Coles Hill uranium deposit (Virginia) were studied to determine how phosphorous influences the speciation of uranium in oxidizing soil/saprolite systems typical of the eastern US. Results from this study have implications for both uranium remediation (e.g. in situ stabilization) and uranium resource exploration (e.g. near-surface geochemical sampling). The primary uranium ore (coffinite and uraninite hosted in quartzo-feldspathic gneiss) weathers to saprolites containing the same uranium concentration as the underlying ore (approximately 1000 mg U/kg saprolites). In these water saturated (below water table) saprolites the uranium is retained as uranyl phosphates of the meta-autunite group (mainly meta-uranocircite). Above the water table the soils overlying the deposit contain approximately 200 mg uranium per kg soil (20 times higher than uranium concentrations in similar soils formed from unmineralized rocks adjacent to the deposit). In these unsaturated zone soils uranium is retained by two processes: (1) incorporation into barium–strontium–calcium aluminum phosphate minerals of the crandallite group (mainly gorceixite), and (2) sorption of uranium with phosphorous onto iron oxides that coat the surfaces of other soil minerals.Thermodynamic calculations suggest that the meta-autunite group minerals present in the saprolites below the water table are not stable in the unsaturated zone soils overlying the deposit due to the drop in soil pH from  6.0 down to  4.5. Mineralogical observations suggest that, once exposed to the unsaturated environment, the meta-autunite group minerals react to form U(VI)-bearing aluminum phosphates and U(VI) surface complexes or nano-precipitates associated with ferric oxides. These results therefore indicate that models predicting U(VI) speciation in phosphate amended soils must simultaneously account for variations in pH, ion activities (aluminum appears to be particularly important) and surface complexation with iron oxide mineral surfaces.  相似文献   

20.
格陵兰冰盖表面消融研究进展   总被引：3，自引：1，他引：2  
杨康 《冰川冻土》2013,35(1):101-109
冰盖表面消融是格陵兰冰盖物质平衡的重要组成部分, 已成为近年来格陵兰冰盖研究的热点. 格陵兰冰盖表面消融研究的关键在于理解冰盖融水的产生、 运移和释放等水文过程, 需要解决如下关键科学问题: 1) 冰盖表面产生了多少融水;2)冰盖表面水文系统具有什么特征; 3)冰盖表面融水如何影响冰盖运动; 围绕这些科学问题, 总结了格陵兰冰盖表面消融的研究进展. 冰盖表面消融建模、 冰盖表面湖的信息提取与面积特征变化、 深度反演与体积量算等是目前研究冰盖表面融水量的主要途径, 冰盖表面湖、 冰盖表面径流、 锅穴与冰裂隙等表面水文要素的空间分布规律研究则可用于揭示冰盖表面水文系统特征, 冰盖表面融水与冰盖运动速率的关系、 表面融水进入冰盖内部与底部的水文过程是目前揭示表面融水如何影响冰盖运动的主要手段.  相似文献   

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