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1.
Levels of estrogenic compounds in Xiamen Bay sediment, China   总被引：5，自引：0，他引：5  
Concentrations of seven estrogenic compounds, i.e., estrone (E1), 17β-estradiol (E2), 17α-ethynylestradiol(EE2), diethylstilbestrol (DES), nonylphenol (NP), octylphenol (OP) and bisphenol A (BPA), were determined in sediments and pore water from Xiamen Bay in China, and their distributions and potential risks in the Bay were assessed. Total estrogenic compounds concentrations varied from 49.20 to 1230.69 ng/g dw in sediments and from 102.33 to 4376.60 ng/L in pore water. The highest levels of these compounds were found at Yundang Lagoon. The results showed that estrogenic compounds in Xiamen Bay originated mainly from municipal wastewaters. Compared with other areas, Xiamen Bay was contaminated with high levels of estrogen hormones. This contamination poses a potential threat to benthic organisms. Although a good relationship (r = 0.94) was observed between the estrogenic compounds concentrations and total organic carbon (TOC) contents in sediments, which did not indicate that the sediment organic matter favors the accumulation of the detected estrogenic compounds.  相似文献   

2.
Concentrations of polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) were determined in nearshore marine surficial sediments from three locations in Trinidad. Sediments were sampled at Sea Lots on the west coast, in south Port-of-Spain Harbor, south of Sea Lots at Caroni Lagoon National Park, and on Trinidad’s east coast at Manzanilla. Total PCB concentrations in Sea Lots sediments ranged from 62 to 601 ng/g (dry weight {dw}), which was higher than at Caroni and Manzanilla, 13 and 8 ng/g dw, respectively. Total OCP concentrations at Sea Lots were ranged from 44.5 to 145 ng/g dw, compared with 13.1 and 23.8 n/g (dw), for Caroni and Manzanilla respectively. The concentrations of PCBs and of some OCPs in sediments from Sea Lots were above the Canadian interim sediment quality guidelines. To date, this data is the first report on the levels of PCBs and other organochlorine compounds from Trinidad and Tobago.  相似文献   

3.
Sixty-eight sediment samples collected from Dongjiang River, Xijiang River, Beijiang River and Zhujiang River in the Pearl River Delta (PRD) region, Southern China, were analyzed for 16 phthalate esters (PAEs). PAEs were detected in all riverine sediments analyzed, which indicate that PAEs are ubiquitous environmental contaminants. The Σ16PAEs concentrations in riverine sediments in the PRD region ranged from 0.567 to 47.3 μg g−1 dry weight (dw), with the mean and median concentrations of 5.34 μg g−1 dw and 2.15 μg g−1 dw, respectively. Elevated PAEs concentrations in riverine sediments in the PRD region were found in the highly urbanized and industrialized areas. Of the 16 PAEs, diisobutyl phthalate (DiBP), di-n-butyl phthalate (DnBP) and di(2-ethylhexyl) phthalate (DEHP) dominated the PAEs, with the mean and median concentrations of 1.12 μg g−1 dw, 0.420 μg g−1 dw and 3.72 μg g−1 dw, and 0.429 μg g−1 dw, 0.152 μg g−1 dw and 1.55 μg g−1 dw, respectively, and accounted for 94.2–99.7% of the Σ16PAEs concentrations. Influenced by local sources and the properties of PAEs, a gradient trend of concentrations and a fractionation of composition from more to less industrialized and urbanized areas were discovered. As compared to the results from other studies, the riverine sediments in the PRD region were severely contaminated with PAEs. Information about PAEs contamination status and its effect on the aquatic organisms in the PRD region may deserve further attention.  相似文献   

4.
Zhong G  Tang J  Zhao Z  Pan X  Chen Y  Li J  Zhang G 《Marine pollution bulletin》2011,62(11):2543-2547
Organochlorine pesticides (HCHs, DDTs and HCB) have been investigated in sediments of Laizhou Bay and its adjacent rivers. The average concentrations of HCHs, DDTs and HCBs are 0.09 ng/g dw, 0.59 and 0.05 for marine sediments and 0.55, 8.6 and 1.1 for riverine sediments, respectively. Laizhou Bay is less contaminated by HCHs and DDTs in comparison with other coastal regions around the world, including the other two biggest bays in Bohai Sea. Fresh input of lindane and dicofol-type DDT were found in several riverine sites. Relatively strong TOC-dependence of HCB distribution in the entire studied area suggested no point source existed and/or water-sediment equilibrium achieved. No significant difference of α/γ-HCH ratios have been observed between marine and riverine sediments. However, o,p′-DDT/p,p′-DDT ratios varied largely between the two regions.  相似文献   

5.
Cadmium (Cd) concentrations in the coastal United States were assessed using the National Status and Trends (NS&T) Mussel Watch dataset, which is based on the analysis of sediments and bivalves collected from 280 sites since 1986. Using the 1997 sediment data, Pearson correlation (r = 0.44, p < 0.0001) suggested that Cd distributions in sediment can, be to some extent, explained by the proximity of sites to population centers. The 2003 tissue data indicated that “high” Cd concentrations (greater than 5.6 μg/g dry weights [dw] for mussel and 5.4 μg/g dw for oysters) were related to salinity along the East and Gulf coasts. Along the West coast, however, these “high” sites appeared to be related to upwelling phenomenon. Additionally, sedimentary diagenesis was found to be the most likely explanation of why sediment and mollusk Cd content were not well correlated.  相似文献   

6.
This study investigated the concentrations and distribution of Perfluoroalkyl and polyfluoroalkyl substances (PFAS) in sediments of 12 rivers from South Bohai coastal watersheds. The highest concentrations of ΣPFAS (31.920 ng g−1 dw) and PFOA (29.021 ng g−1 dw) were found in sediments from the Xiaoqing River, which was indicative of local point sources in this region. As for other rivers, concentrations of ΣPFAS ranged from 0.218 to 1.583 ng g−1 dw were found in the coastal sediments and from 0.167 to 1.953 ng g−1 dw in the riverine sediments. Predominant PFAS from coastal and riverine areas were PFOA and PFBS, with percentages of 30% and 35%, respectively. Partitioning analysis showed the concentrations of PFNA, PFDA and PFHxS were significantly correlated with organic carbon. The results of a preliminary environmental hazard assessment showed that PFOS posed the highest hazard in the Mi River, while PFOA posed a relative higher hazard in the Xiaoqing River.  相似文献   

7.
Elutriate embryo-larval bioassays with sea-urchins (Paracentrotus lividus) were conducted concurrently with chemical analyses of sediments and biota as part of an integrative assessment of pollution in highly productive coastal regions. High metal contents and organic compounds in sediments and mussels were found in localised areas from the inner part of the estuaries indicating a clear anthropogenic influence. In particular, average maximum concentrations of 2803 mg Cu/kg dw, 776 mg Pb/kg dw, 2.5 mg Hg/kg dw and 5803 μg ∑7PAHs/kg dw were measured in sediments from the most polluted sites. Significant correlations were observed between sediment chemistry and toxicity bioassays. Moreover, the Mantel test revealed a significant correlation (rM=0.80; p<0.01) between sediment pollutant concentrations and toxicity data profiles. In addition, sediment quality criteria were used to help in the ecological interpretation of sediment chemistry data and to identify pollutants of concern. The toxicity bioassays identified polluted sites and quantified the level of toxicity, providing a cost-effective tool to complement the routine chemical monitoring currently conducted in European coastal waters with ecologically relevant information. This is in line with the recent European legislation that advocates the use of biological tools with the ultimate aim of protecting marine resources from anthropogenic substances that will affect their sensitive early life stages.  相似文献   

8.
This study evaluated the contamination status and distribution of organochlorine pesticides (OCPs) between Xinghua Bay and adjacent watersheds in Putian region, southeast China. Twenty-five surface soil samples and two sediment cores were collected from two watersheds and the Xinghua Bay, respectively. Results showed that the concentrations of OCPs in samples of the Mulan River Watershed (MRW), the Qiulu River Watershed (QRW), the inner bay core (IBC) and the open bay core (OBC) were in the range of 4.96-38.20 ng/g, 4.62-22.80 ng/g, 1.84-80.46 ng/g and 1.87-23.43 ng/g, respectively. The mean concentration of OCPs was in an order: IBC > MRW > QRW > OBC. The higher concentration of OCPs in recent periods may suggest that a certain amount of OCPs were still input to this area.  相似文献   

9.
There is a recognized dearth of standard environmental quality data in the wider Caribbean area, especially on coral atolls/small island states. Extensive surveys of sediment contamination (n = 109 samples) in Bermuda revealed a wide spectrum of environmental quality. Zinc and especially copper levels were elevated at some locations, associated with boating (antifouling paints and boatyard discharges). Mercury contamination was surprisingly prevalent, with total levels as high as 12 mg kg−1 DW, although methyl mercury levels were quite low. PAH, PCB and PCDD/PCDF contamination was detected a several hotspots associated with road run-off, a marine landfill, and a former US Naval annexe. NOAA sediment quality guidelines were exceeded at several locations, indicating biological effects are possible, or at some locations probable. Overall, and despite lack of industrialization, anthropogenic chemicals in sediments of the atoll presented a risk to benthic biodiversity at a number of hotspots suggesting a need for sediment management strategies.  相似文献   

10.
The study aimed to determine the spatial distribution of n-alkanes and polycyclic aromatic hydrocarbons (PAHs) in surface sediments of the Segara Anakan nature reserve and their potential origins using gas chromatography–mass spectrometry. Total alkane concentrations ranged from 3755 to 129,027 μg kg−1, and the concentrations of 16 PAHs ranged from 375 to 29,517 μg kg−1. The ratios of specific n-alkanes (e.g., CPI24–34, WaxCn, and Paq), including a new proposed index, terrestrial–marine discriminant (TMD), as well as the ratios of selected PAHs (e.g., Ant/∑178, Fl/∑202, BaAnt/∑228, and IPyr/∑276), showed that the sources of hydrocarbons in the sediments were generally biogenic, including both terrigenous and marine, with an anthropogenic pyrolytic contribution (petrogenic and biogenic combustion). For the environmental risk assessment, a sediment quality guideline (SQGs) comparison indicated that the station risk levels ranged from low to medium-low, except for R6, which has a greater impact on the ecological risk for marine organisms.  相似文献   

11.
Matrix-bound phosphine (MBP) has been measured in sediment from two cores in Lake Illawarra on the south east coast of Australia. The sediments were also dated in the upper layers. MBP concentrations found range from 142 to 1813 ng kg−1, dw (dry weight of sediment) with some values being amongst the highest ever measured. Values of MBP in deeper sediments were higher than for near surface samples, but the patterns with depth were not consistent. Strong correlations were noted between MBP and organic phosphorus (OP, r > 0.8) and with total phosphorus (TP, r > 0.7), but only moderate correlations were found with organic carbon (OC, r > 0.5). No correlations were found between MBP concentrations and the age of the sediments. It was confirmed that high MBP concentrations are indicative of a phosphorus rich environment. The results tend to support the premise that MBP is generated by microbial attack on OP under anaerobic conditions.  相似文献   

12.
Sediments quality assessment is of priority concern to provide a comprehensible overview of ecological and chemical state of an ecosystem. The Marennes-Oléron Bay, hosting the largest oyster production in France, is influenced by the historic polymetallic pollution of the Gironde Estuary. Despite, management efforts and decreasing emissions in the Gironde watershed, Cd levels in oysters from the bay are close to consumption limit (5 μg g−1 dw, EC no. 466/2001). In this context, the aim of the study was to assess the priority metal (Ni, Cu, Zn, As, Ag, Cd, Hg, Pb and Th) concentrations in sediment within the Bay, by investigating spatial and temporal distribution variations and the role of hydrodynamic forcing. For that we selected three sites (east, west and south) characterizing different environments of the Bay and we observed metal concentrations, grain size distribution, bed elevation and wave activities during a year survey. The sampling strategy pointed out both spatial and temporal metal concentrations variability in sediment. In general, metal enrichments were close to geochemical background. The eastern part of the Bay, largely influenced by the Charente river particulate deposition, presented constant concentrations over the survey. In contrast, in the western part, bed elevation was strongly influenced by hydrodynamic forcing especially wave activities, and metal distribution showed constant metal concentrations except very located Cd minor enrichment related to the Gironde influence via the Antioche Strait (north). The southern part was disconnected from the rest of the Bay and showed minor to very located moderately severe Cd enrichment, related to the Gironde water discharges via the Maumusson Strait (south). Thus, the multi-disciplinary approach was relevant to characterize the interactions between hydrodynamic forcing on the environment and sediments and their metal quality state which (i) were close to geochemical background over a year for Ni, Cu, Zn, As, Ag, Hg and Pb (i) which presented enrichment of Cd in the western and southern part.  相似文献   

13.
Congener specific determination of polybrominated diphenyl ethers (PBDEs) and polychlorinated biphenyls (PCBs) was carried out in 21 surface sediment samples and a sediment core from Masan Bay, Korea. Among the 40 PBDE congeners targeted only 29 were detectable. PBDE congener profile within sediments was dominated by BDE-209 followed by BDEs-99, -47, -153 and -183, sequentially. In surface sediments, the average ΣPBDEs levels approached that of average ΣPCBs values. However, trends observed in the sediment core suggest that this pattern will alter over time and result in higher surface sediment PBDE concentrations than PCBs in future. Various diffuse and point sources for PBDEs and PCBs were identified in this location. Shipping and other industrial activities were associated with PCB contamination while domestic and industrial waste discharges corresponded with PBDE contamination. The average concentration for PBDEs and PCBs in surface sediments were 5.7, 7.2 ng/g dry weight, respectively.  相似文献   

14.
The concentrations, compositional profiles, and potential ecological risk of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), polychlorinated biphenyls (PCBs) and polychlorinated naphthalenes (PCNs) in sediments of the Daliao River Estuary were investigated. Total concentrations of PCDD/Fs, PCBs, and PCNs were in the range of 11.3-133.2 ng/kg dry weight (dw), 1 971-37 632 ng/kg dw and 33.1-284.4 ng/kg dw, respectively. The total TEQ values varied from 0.37 to 4.08 ng/kg dw, with the dominant contributions by PCDD/Fs, then by PCBs and PCNs. The spatial distributions of PCDD/Fs, PCBs and PCNs in the river estuary were much related to hydrodynamic conditions. The risk of contamination to the deeper sea was increased in the flood seasons. Moreover, our data confirmed that both organic matter in sediments and molecular properties of dioxin-like compounds were the factors which strongly influenced the partition behavior of these dioxin-like compounds between sediments and water phase in the estuarine zone.  相似文献   

15.
The influence of the sediment’s physico-chemical properties and black carbon content, on the distribution of polycyclic aromatic hydrocarbons and polychlorinated biphenyls in benthic sediments of the Gulf of Gdansk (Baltic Sea) was determined. Sediments from port, marine dump site of dredged spoils, the Vistula river mouth, Gdansk Deep were selected.The concentrations of ∑PAHs (fluoranthene, pyrene, benzo(a)anthracene, benzo(k)fluoranthene, benzo(a)pyrene, dibenzo(ah)anthracene, benzo(ghi)perylene) were 294-2200 ng/g d.w. and for ∑PCBs (28, 52, 101, 118, 138, 153, 180) were 2.4-11.3 ng/g d.w.The sediments content of loss on ignition was 1.13-16.15%, total organic carbon was 0.89-7.15%, black carbon was 0.20-1.15%. The highest correlation coefficient values (r = 0.76-0.92, p < 0.05) for a relationship between the concentrations of organic pollutants, and organic matter, organic and black carbon contents were obtained in harbor sediments with low content of organic matter (<5%) and high share of black carbon in total carbon (up to 40%).  相似文献   

16.
《Marine pollution bulletin》2014,85(1-2):373-378
The surficial coastal sediments in Kendari Bay are sampled in the field to determine the concentration and pollution level of three heavy metals (Pb, Cd and Cr). Twenty-five sampling points ranging from the inner (Wanggu River) to the outer area of the bay have been chosen. The physicochemical properties, such as temperature, pH, salinity and TDS of the overlying water, as well as the sediment type and TOC of the surficial sediments, are also measured. The total concentrations of the Pb, Cd and Cr in the sediment samples are quantified using inductively-coupled plasma mass spectrometry (ICP-MS). The concentrations of the heavy metals (Pb, Cd and Cr) ranged from 0.84 to 17.02 μg/g, 0.02 to 0.17 μg/g and 1.92 to 40.11 μg/g (dry weight), respectively, following the Cr > Pb > Cd sequence. To assess the degree of contamination, a geoaccumulation index (Igeo) is measured. Kendari Bay is not a contaminated area regarding Pb, Cd and Cr.  相似文献   

17.
Perfluorinated compounds (PFCs) in water, sediment, soil, and biota collected from estuarine and coastal areas of the north Bohai Sea, China, were determined by use of HPLC-MS/MS. Significant concentrations of PFCs were found in water (mean: 18.4 ng/l) and biologic samples (fish: 265 ng/g dw), while concentrations of PFCs in soils and sediments were less. The predominately detected compound was perfluorooctanesulfonate (PFOS), with a maximum concentration of 30.9 ng/l in water and 791 ng/g dw in fish. Concentrations of PFCs were significantly greater in the Liaohe River system than other locations, which suggests point sources in this urbanized and industrialized region. PFOS concentrations in water and biota were both less than the reported threshold concentrations. Detection of PFCs at relatively great concentrations in various environmental matrices from this region suggested that further studies characterizing concentrations of PFCs, their sources and potential risk to both humans and wildlife are needed.  相似文献   

18.
A total of 33 surficial sediments from riverine and coastal waters from Surabaya, Indonesia were analyzed for PCBs and BFRs. Concentrations of PCBs (62 congeners), PBDEs (14 congeners) and HBCDs (3 isomers) varied from <DL-420, <DL-35 and <DL-5.4 ng g−1 dw, respectively. Higher concentrations of these compounds were found in riverine than coastal sediments. Their levels and distribution were influenced by proximity to the point sources and TOC. The predominant congeners were CB-153, -28, -138, -149, -180, -33 and BDE-209, -207, -206, -197, -196, -183, -99, -47 for PCBs and PBDEs, respectively, and γ-isomer for HBCDs. Debromination of BDE-209 might be taking place producing lower toxic congeners in sediment. Levels of PCBs in riverine sediments were comparable with some polluted areas worldwide, but PBDEs and HBCDs were lower. Hazard assessment of PCBs indicated possible toxic potential, particularly in areas close to point sources.  相似文献   

19.
Surface sediments and porewater from 12 sites within Xiamen offshore areas and organisms from a heavily contaminated site Yuandang Lagoon were sampled and analyzed for eight polybrominated diphenyl ethers (PBDEs) congeners (-28, -47, -99, -100, -153, -154, -183 and -209). The total concentrations of eight PBDEs (∑8PBDEs) and BDE-209 in sediments ranged from 0.27 to 76.54 ng/g with an average of 16.31 ng/g and from 0.10 to 70.11 ng/g with an average of 14.94 ng/g, respectively. Concentrations of ∑8PBDEs in porewater ranged from 2.5 to 34.1 ng/L, with a mean value of 15.3 ng/L. In this study, the partition coefficients (log ) of PBDE congeners (without -209) were significantly correlated with their octanol-water partition coefficients (log KOW) (r2 = 0.74, P < 0.01). ∑8PBDE concentrations ranged from 0.33 to 1.26 ng/g (lipid weight) in marine organisms, and PBDE congener patterns were significantly different between fish and clam, crab.  相似文献   

20.
Organohalogen contaminants including PCBs, DDTs, CHLs, HCHs, HCB, PBDEs and HBCDs were determined in striped dolphins (Stenella coeruleoalba) found stranded at Gogo-shima (n = 6, 2003) and collected from Taiji (n = 15, 1978-1992) in Japan. All target compounds were significantly detected in all the specimens, indicating ubiquitous contamination of oceanic cetaceans in northwest Pacific Ocean. Examination of body distribution of organohalogens in the six specimens from Gogo-shima showed no significant difference in concentrations among the analyzed tissues, except for brain, which had lower levels possibly due to the existence of blood-brain barrier. For evaluating temporal trends, archived blubber samples of adult male stripped dolphins collected in 1978, 1979, 1986 and 1992 were analyzed. Concentrations of PCBs, DDTs and HCHs did not change significantly during 1978-2003. In contrast, remarkable increasing trends of PBDEs and HBCDs were observed, suggesting growing consumption in Japan and surrounding countries in recent years.  相似文献   

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