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1.
At present, in most oceans the lead (Pb) biogeochemical cycling has been disturbed by anthropogenic Pb through atmospheric input. The Pb concentrations in the upper water positively correlate with atmospheric input fluxes of Pb. The North Pacific is affected greatly by atmospheric substances via long-range transport from eastern Asia, especially from Mainland China. Mainland China may export considerable amounts of pollutants into the seas via rivers and the atmosphere owing to its recent fast growth in industry and economy. The East China Sea lies in an important geographical position--a transit between Mainland China and the western North Pacific. However, no data are available for seawater concentrations of Pb, a representative element with anthropogenic origin. In this work seawater samples from both 5 and 30-50 m water layers of 15 stations occupied over a cyclonic eddy in the southern East China Sea were analyzed for particulate Pb (PPb) and dissolved Pb (DPb). The Mean concentration of DPb (approximately 128 ng/l) in the southern East China Sea upper waters (< or = 50 m) is approximately several times higher than those in the Pacific; the high DPb concentrations in the southern East China Sea waters correspond to much higher atmospheric supplies of Pb to the East China Sea. Thus, this study partly fills the 'data gap' of the marginal seas. Also, it indicates that the East China Sea may be considerably contaminated by deposited polluted aerosols. Spatial distributions of DPb in the surface water show a tendency of increasing concentrations with distance offshore, that depends on the magnitudes of atmospheric Pb inputs and on particle scavenging processes. In contrast to DPb, spatial distributions of PPb basically display an 'omega'-like picture and a tendency of decreasing concentrations with distance offshore. These are related to riverine and scavenging sources and to the drive by the eddy. Additionally, the residence times of DPb in the surface water were estimated to be about 2 years, agreeing well with the reported data.  相似文献   

2.
Particulate manganese (Mn) fluxes measured with six time series sediment traps showed that the annual settling fluxes were 3–6 times higher in the west compared to those in the east and central Arabian Sea. Annual detrital Mn (Mndt) flux was nearly the same in the eastern and western Arabian Sea, but excess Mn (Mnex) fluxes were much higher (>4 times) in the western Arabian Sea. Atmospheric inputs cannot account for these high-Mn fluxes. Central and eastern Arabian Sea traps are overlain by a thick and intense denitrification layer, which may cause reductive dissolution of Mn oxides from settling particles and consequently low Mnex fluxes. As the exchange of intermediate waters between the Arabian Sea and the rest of the Indian Ocean is confined largely to the western Arabian Sea, relatively more oxic and dynamic conditions prevail in this region. Increased oxidizing conditions coupled with higher inputs of dissolved Mn through intermediate and surface advective processes might have led to in situ oxidation of Mn, thus resulting in higher vertical fluxes of Mnex. Mnex fluxes in traps at ∼1000 m depth exhibited seasonal variability with a minimum during the winter monsoon (January–February) and maximum during the pre- and early- south-west monsoon (March–June). This variation is correlated with water mass movements and bacterial abundance observed during the Joint Global Ocean Flux Study (JGOFS). The possible involvement of bacteria and the microbial loop is suggested for the concentration and vertical transport of excess Mn.  相似文献   

3.
We examined metal (Al, V, Cr, Mn, Fe, Ni, Cu, Zn, Cd and Pb) and particulate organic carbon (OC) concentrations of the marine vertical export flux at the DYFAMED time-series station in the Northwestern Mediterranean Sea. We present here the first data set of natural and anthropogenic metals from sediment trap moorings deployed at 1000 m-depth between 2003 and 2007 at the DYFAMED site. A highly significant correlation was observed between most metal concentrations, whatever the nature and emission source of the metal. Cu, Zn and Cd exhibit different behaviors, presumably due to their high solubility and complexation with organic ligands. The observed difference of atmospheric and marine fluxes in terms of temporal variability and elemental concentration suggests that dense water convection and primary production and not atmospheric deposition control the marine vertical export flux. This argument is strengthened by the fact that significant Saharan dust events did not result in concomitant marine vertical export fluxes nor did they generate significant changes in metal concentrations of trapped particles.  相似文献   

4.
Analysis of wintertime CLIMODE data for 2007 indicates that a substantial portion of new Eighteen Degree Water (EDW) is likely ventilated within the eastward flowing Gulf Stream (GS) between 67°W and 52°W longitudes, possibly exceeding that formed elsewhere in the northern Sargasso Sea. Use of some global air–sea interaction data sets applied to the study region for Feb/Mar of 2007 indicate that this winter may have been anomalously energetic in air–sea exchange compared to the mean of the prior 19 yr. The largest heat and freshwater fluxes found directly over the meandering warm core of the Gulf Stream are capable of removing most of the subtropical heat anomaly of the GS, but cross-frontal fluxes of salinity are required to account for the observed regional salinity structure. An isopycnal diffusivity of ∼100 m2 s−1 is inferred from the salinity balance. This mixing would also account for the observation that EDW formed in the GS is slightly fresher than that formed in northern Sargasso Sea. The lateral flux of heat across the GS north wall also acts to cool the resulting EDW water, but the heat balance for EDW production is largely determined from GS advection and air–sea fluxes, in contrast to salinity. Based on oxygen saturation data, we estimate that 1.8–3.0 Sv-yr of new EDW is formed in the GS for the winter of 2007. EDW originating from the GS is generated in a separate location from where it is accumulated in the northern Sargasso Sea. This manner of EDW formation will produce unique characteristics of EDW found in the northern Sargasso Sea: ones that differ in T/S properties from that formed south of the GS under the more traditional 1D, cooling-driven convection process.  相似文献   

5.
Aerosol (soluble and total) iron and water-column dissolved (DFe, < 0.2 μm) and total dissolvable (TDFe, unfiltered) iron concentrations were determined in the Canary Basin and along a transect towards the Strait of Gibraltar, in order to sample across the Saharan dust plume. Cumulative dust deposition fluxes estimated from direct aerosol sampling during our one-month cruise are representative of the estimated deposition fluxes based on near surface water dissolved aluminium concentrations measured on board. Iron inventories in near surface waters combined with flux estimates confirmed the relatively short residence time of DFe in waters influenced by the Saharan dust plume (6–14 months). Enhanced near surface water concentrations of DFe (5.90–6.99 nM) were observed at the Strait of Gibraltar mainly due to inputs from metal-rich rivers. In the Canary Basin and the transect towards Gibraltar, DFe concentrations (0.07–0.76 nM) were typical of concentrations observed in the surface North Atlantic Waters, with the highest concentrations associated with higher atmospheric inputs in the Canary Basin. Depth profiles showed that DFe and TDFe were influenced by atmospheric inputs in this area with an accumulation of aeolian Fe in the surface waters. The sub-surface minimum of both DFe and TDFe suggests that a simple partitioning between dissolved and particulate Fe is not obvious there and that export may occur for both phases. At depths of around 1000–1300 m, both regeneration and Meddies may explain the observed maximum. Our data suggest that, in deep waters, higher particle concentrations likely due to dust storms may increase the scavenging flux and thus decrease DFe concentrations in deep waters.  相似文献   

6.
Chromium(VI) concentrations ranging between 3.0 and 6.1 nmol l−1 and 3.1 and 7.3 nmol l−1 were found in the Arctic and Atlantic Oceans, respectively. The vertical profiles show modest depletion of chromium(VI) in surface waters, but poor overall correlations between Cr(VI) and nutrient profiles. Given that Cr(VI) is the dominant oxidation state of chromium in open-ocean waters, these data are combined with literature data to reassess the distribution of Cr in oceanic waters. It is concluded that while Cr shows some characteristics of both “recycled” and “accumulated” vertical profiles, it does not fall clearly within either group.  相似文献   

7.
We report results from the first deployment of a buoy-mounted aerosol sampler on the Bermuda Testbed Mooring (BTM) in the Sargasso Sea, in which a time-series of 21 aerosol samples were collected over the period May 5–September 29, 2004. These aerosol samples were analyzed for iron and soluble sodium (as a proxy for sea salt). Also analyzed was a time-series of 22 aerosol samples collected over the same period at the Tudor Hill atmospheric sampling tower on Bermuda. The buoy sampler worked as intended and successfully collected a time-series of aerosol samples, thus demonstrating that moored buoys can be used as oceanic observatories to provide information on the temporal (weekly, monthly and seasonal) variability in the concentration of aerosol iron (and other trace elements) over the surface ocean. The magnitude and time variation of aerosol Fe concentrations calculated from the BTM buoy samples are in close agreement with the corresponding aerosol Fe record from the Tudor Hill tower, which is located approximately 80 km northwest of the mooring site. Both the BTM and Tudor Hill samples record periods of high aerosol iron loadings in late June and late July 2004, reflecting the transport of soil dust from North Africa, with the highest concentration of aerosol iron at the BTM site (0.83 μg m−3) measured in late June. Concentrations of sea-salt aerosol calculated from the BTM samples are comparable to values measured over the Sargasso Sea and for samples collected at the Tudor Hill tower. Sea-salt aerosols do not appear to impede the collection of mineral aerosols by the buoy-mounted sampler.  相似文献   

8.
The fluorescence of dissolved organic matter in seawater   总被引：3，自引：0，他引：3  
A total of 28 vertical profiles of seawater fluorescence was measured in the Sargasso Sea, the Straits of Florida, the Southern California Borderlands, and the central Pacific Ocean. In all cases, surface seawater fluorescence was low as a result of photochemical bleaching which occurs on the timescale of hours. Fluorescence of deep water was 2–2.5 times higher than that of surface waters, and was constant, implying a long residence time for fluorescent organic matter, possibly of the order of thousands of years. Fluorescence correlates well with nutrients (NO3−, PO43−) in mid-depth waters (100–1000 m) in the Sargasso Sea and the central North Pacific, consistent with results in the central Pacific and the coastal seas of Japan. This suggests that regeneration or formation of fluorescent materials accompanies the oxidation and remineralization of settling organic particles.The various sources and sinks of fluorescent organic matter in the global oceans are assessed. The major sources are particles and in situ formation; rivers, rain, diffusion from sediments, and release from organisms are minor sources. The major sink is photochemical bleaching.  相似文献   

9.

In this study, we investigated the mechanism of eutrophication and hypoxia in the upper Gulf of Thailand from August 2014 to June 2015 based on field observation data, box model analysis, and the unscaled trophic status index (UNTRIX). Fresh water residence time derived from a simple box model was long (38.61 days) during the transition period between the southwest to northeast monsoon in September 2014. In contrast, fresh water residence time was short (2.63 days) during the late northeast monsoon in February 2015. Long residence time was related to the development of widespread strong hypoxia in near-bottom waters in over half of the gulf during the transition between the southwest and the northeast monsoon, when river discharge was also very large. UNTRIX is used to assess water trophic levels, and is based on water qualities including concentrations of chlorophyll-a (Chl-a), dissolved oxygen (DO), dissolved inorganic nitrogen (DIN), and dissolved inorganic phosphorus (DIP). Hypertrophic and eutrophic conditions were observed at river mouths; their seasonal eutrophication was related to river discharge and circulation. Nutrients were mainly increased by river discharge. Water column stratification and long residence time were required for the development of severe hypoxia in the study area.

  相似文献   

10.
The DYFAMED time-series station, located in the open Ligurian Sea, is one of the few pluriannual flux programs in the world and the longest in the Mediterranean Sea. The trap data series is one of only three multi-decadal data sets in existence, and it provides flux information for an environment that is distinct from the other long-term data sets. At DYFAMED, downward fluxes of particles, carbon and other major elements have been regularly measured with sediment traps since 1986 at fixed depths of 200 and 1000 m. An overview is presented of the main trends of particle and carbon fluxes observed during the period 1988–2005, period when the mooring was located on the northern side of the Ligurian Sea. In spite of considerable interannual variability, fluxes displayed a marked seasonal pattern with the highest fluxes occurring during winter and spring and lowest fluxes throughout the stratified season (summer–autumn). Organic carbon fluxes measured at both depths were highly variable over time, ranging from 0.3 to 59.9 (mean 6.8) mg C m−2 d−1 at 200 m, and from 0.2 to 37.1 (mean 4.3) mg C m−2 d−1 at 1000 m. Mass fluxes were maximal in winter, whereas carbon fluxes were maximal in late spring. Reasonably good agreement existed between particle fluxes at both depths over the years, indicating a relatively efficient and rapid transport of particles from the upper ocean to the deep sea. However, during certain periods mass flux increased with depth suggesting lateral inputs of particles that by-pass the upper trap. Since 1999, the system has apparently shifted towards an increasing occurrence of extreme flux events in response to more vigorous mixing of the water column during the winter months. Although annual mass fluxes have increased in the last years, mean POC fluxes have not substantially changed over time, due mainly to lower carbon contents of the sinking particles during maxima of mass flux.  相似文献   

11.
Atmospheric iron and underway sea-surface dissolved (<0.2 μm) iron (DFe) concentrations were investigated along a north–south transect in the eastern Atlantic Ocean (27°N/16°W–19°S/5°E). Fe concentrations in aerosols and dry deposition fluxes of soluble Fe were at least two orders of magnitude higher in the Saharan dust plume than at the equator or at the extreme south of the transect. A weaker source of atmospheric Fe was also observed in the South Atlantic, possibly originating in southern Africa via the north-easterly outflow of the Angolan plume. Estimations of total atmospheric deposition fluxes (dry plus wet) of soluble Fe suggested that wet deposition dominated in the intertropical convergence zone, due to the very high amount of precipitation and to the fact that a substantial part of Fe was delivered in dissolved form. On the other hand, dry deposition dominated in the other regions of the transect (73–97%), where rainfall rates were much lower. Underway sea-surface DFe concentrations ranged 0.02–1.1 nM. Such low values (0.02 nM) are reported for the first time in the Atlantic Ocean and may be (co)-limiting for primary production. A significant correlation (Spearman's rho=0.862, p<0.01) was observed between mean DFe concentrations and total atmospheric deposition fluxes, confirming the importance of atmospheric deposition on the iron cycle in the Atlantic. Residence time of DFe in the surface waters relative to atmospheric inputs were estimated in the northern part of our study area (17±8 to 28±16 d). These values confirmed the rapid removal of Fe from the surface waters, possibly by colloidal aggregation.  相似文献   

12.
根据2006年7～8月和2007年1月对北黄海进行的大面调查,分析研究了夏冬季表层海水中二甲基硫(DMS)的浓度分布和海-气交换通量.研究表明:表层海水以及大气中DMS浓度季节变化明显,夏季平均值分别是冬季的3.2和3.7倍.相关性分析显示,海水中DMS和Chl a浓度存在明显的相关性,说明浮游植物生物量是影响DMS浓度分布的1个重要因素.利用Liss和Merlivat公式(LM86)估算了北黄海夏冬季DMS的海-气交换通量,其平均值分别为7.31和4.98 μmol·m-2·d-1.另外,根据测定的大气中甲基磺酸盐(MSA)和非海盐硫酸盐(Nss-SO2-4)的浓度及比例,估算出夏冬季北黄海生源硫释放对气溶胶中Nss-SO2-4的贡献比例分别为10.1%和2.8%.此结果表明北黄海大气中Nss-SO2-4主要来源于人为排放.  相似文献   

13.
The spatial and seasonal variability of nutrients and dissolved oxygen concentrations as well as the chemical characterization of the different water masses of the Southern Levantine Basin were determined in detail. In summer, the upper 150 m of the water body was stratified and the cross basin distribution of dissolved oxygen and nutrients was fairly constant. Surficial waters were saturated with dissolved oxygen, and a shallow oxygen maximum (oversaturated) was present at about 80 m depth. Oversaturation was attributed mainly to the physical process of rapid capping and trapping of oxygen in the Atlantic water (AW) mass, with only 28% of the excess oxygen originating from biological production. Nutrient concentrations were very low and showed an increase in the intermediate levels, coupled with a decrease in oxygen. The winter cross-section distribution showed an upper mixed layer of 100 m, with dissolved oxygen and nutrient concentrations fairly constant across the basin. The concentration of nitrate was higher than in summer, while phosphate was slightly lower and silicic acid similar. In winter, the influence of the physical features (gyres) could be detected up to the surface, and in summer they were detected by the chemical properties in the 150–600 m layer. In the transition layer between the Levantine intermediate water (LIW) and the deep water (DW) (400–700 m) there was a gradual decrease in dissolved oxygen and an increase in nutrient concentrations eastwards. The DW showed no seasonal variation, only spatial variability: dissolved oxygen decreased and silicic acid increased eastwards. No differences were found in nitrate and phosphate concentrations between the DW in the western and eastern provinces, indicating the oxidation of organic matter poor in N and P.N : P ratios in the upper water masses were seasonally dependent. The largest variation was found in the Levantine surface water (LSW), from an average of 52 in winter to 5 in summer. It is hypothesized that the gradual decrease from winter to summer values was due mainly to preferential atmospheric input of N in winter and P in summer, together with biological consumption and differential regeneration of N and P. In the DW, the N : P ratios were constant throughout the year (25.2±2.7, n=567), and higher than Redfield's ratio. It was speculated that the high N : P ratio in the DW was a result of oxidation of particulate organic matter deficient in P.The winter wet atmospheric input of N provided 12% of new N to the LSW. Average new production for the Southern Levantine Basin was estimated from the new N as 4.75 g C m−2 yr−1. The dry atmospheric contribution of P was estimated to significantly increase the P pool in the LSW. Dry deposition is not evenly distributed and occurs in episodic and localized events, which may have a large effect on productivity in the short periods when deposition occurs.There have been recently reported changes in the deep thermohaline circulation of the Eastern Mediterranean, with main contribution of the Aegean Sea as a source of DW. The data presented here can serve as a reference for assessing future changes in the chemical composition of the water masses in the Southern Levantine.  相似文献   

14.
Dissolved Fe, Mn and Al concentrations (dFe, dMn and dAl hereafter) in surface waters and the water column of the Northeast Atlantic and the European continental shelf are reported. Following an episode of enhanced Saharan dust inputs over the Northeast Atlantic Ocean prior and during the cruise in March 1998, surface concentrations were enhanced up to 4 nmol L− 1 dFe, 3 nmol L− 1 dMn and 40 nmol L− 1 dAl and returned to 0.6 nmol L− 1 dFe, 0.5 nmol L− 1 dMn and 10 nmol L− 1 dAl towards the end of the cruise three weeks later. A simple steady state model (MADCOW, [Measures, C.I., Brown, E.T., 1996. Estimating dust input to the Atlantic Ocean using surface water aluminium concentrations. In: Guerzoni. S. and Chester. R. (Eds.), The impact of desert dust across the Mediterranean, Kluwer Academic Publishers, The Netherlands, pp. 301–311.]) was used which relies on surface ocean dAl as a proxy for atmospheric deposition of mineral dust. We estimated dust input at 1.8 g m− 2 yr− 1 (range 1.0–2.9 g m− 2 yr− 1) and fluxes of dFe, dMn and dAl were inferred. Mixed layer steady state residence times for dissolved metals were estimated at 1.3 yr for dFe (range 0.3–2.9 yr) and 1.9 yr for dMn (range 1.0–3.8 yr). The dFe residence time may have been overestimated and it is shown that 0.2–0.4 yr is probably more realistic. Using vertical dFe versus Apparent Oxygen Utilization (AOU) relationships as well as a biogeochemical two end member mixing model, regenerative Fe:C ratios were estimated respectively to be 20 ± 6 and 22 ± 5 μmol Fe:mol C. Combining the atmospheric flux of dFe to the upper water column with the latter Fe:C ratio, a ‘new iron’ supported primary productivity of only 15% (range 7%–56%) was deduced. This would imply that 85% (range 44–93%) of primary productivity could be supported by regenerated dFe. The open ocean surface data suggest that the continental shelf is probably not a major source of dissolved metals to the surface of the adjacent open ocean. Continental shelf concentrations of dMn, dFe, and to a lesser extent dAl, were well correlated with salinity and express mixing of a fresher continental end member with Atlantic Ocean water flowing onto the shelf. This means probably that diffusive benthic fluxes did not play a major role at the time of the cruise.  相似文献   

15.
Previous studies measuring biogenic silica production in the Sargasso Sea, all conducted when no phytoplankton bloom was in progress, have reported a mean rate of 0.4 mmol Si m?2 d?1 and maximum rate of 0.9 mmol Si m?2 d?1, the lowest rates yet recorded in any ocean habitat. During February/March of 2004 and 2005 we studied the effects of late-winter storms prior to seasonal stratification on the production rate, standing stock and vertical export of biogenic silica in the Sargasso Sea. In 2004, alternating storm and stratification events provided pulsed input of nutrients to the euphotic zone. In contrast, nearly constant storm conditions in 2005 caused the mixed layer to deepen to ～350 m toward the end of the cruise. Biogenic silica production rates in the upper 140 m were statistically indistinguishable between years, averaging ～1.0 mmol Si m?2 d?1. In early March 2004, a storm event entrained nutrients into the euphotic zone and, upon stabilization, vertically integrated biogenic silica in the upper 140 m nearly doubled in 2 days. Within 4 days, 75–100% of the accumulated biogenic silica was exported, sustaining a flux to 200 m of ～0.5 mmol Si m?2 d?1 (4× greater than export measured during February and March in the mid-1990s). In 2005, destabilization without stratification increased biogenic silica flux at 200 m up to two-fold above previously measured export in late winter, with little or no increase in water-column biogenic silica. Despite comprising <5% of total chlorophyll, diatoms accounted for an estimated 25–50% of the nitrate uptake in the upper 140 m and 35–97% of the particulate organic nitrogen export from the upper 200 m during both cruise periods. These previously unobserved brief episodes of diatom production and export in response to late-winter storms increase the estimated production and export of diatom-derived material in the Sargasso Sea in late winter by >150%, and increase estimated annual biogenic silica production in this region by ～8%.  相似文献   

16.
Particulate trace metals (PTM), organic carbon (POC), and organic nitrogen (PON) were measured in a series of surface bucket samples collected between the New England coast of the United States and Bermuda. PTM concentrations were lower or equivalent to the lowest PTM concentrations reported in the literature. Examination of the relative variations in PTM with respect to particulate aluminum and carbon led to the conclusion that organic matter was the probable regulator of PTM abundance in open-ocean surface waters and was important in this respect for continental shelf and slope waters as well.Enrichment factors of trace metals relative to their crustal abundances were found to be similar in the atmosphere sampled in Bermuda and in Sargasso Sea surface water particulate matter. A simplistic vertical flux model was constructed which showed atmospheric input of trace metals to the Sargasso Sea to be of the same approximate magnitude as the rate of removal of PTM from the mixed layer by sinking in association with POC. Essentially all of the particulate Al, Fe, and Mn in the Sargasso Sea mixed layer was attributed to aeolian sources. The fate of other atmospherically derived trace metals in the Sargasso Sea mixed layer was suggested to be a function of their solubility in seawater.  相似文献   

17.
Considerable attention has recently been focused on the role of eddies in affecting biogeochemical fluxes and budgets of the Sargasso Sea. In late November 1996, the Bermuda Testbed Mooring (BTM) and Bermuda Atlantic Time Series (BATS) shipboard sampling evidenced a fall phytoplankton bloom at the Bermuda time-series site which was strongly forced by the interplay between seasonal mixed layer destratification and perturbation of mixed layer dynamics due to passage of a warm mesoscale feature. The feature was characterized by clockwise current vector rotation from near the surface to about 200 m and a thick, warm, low salinity isothermal layer >180 m in depth. Nutrients, chlorophyll fluorescence and pigment profiles indicated high primary production stimulated by enhancement of nutrient entrainment and intermittent deep mixing down to the base of the feature's isothermal layer. Nearly coincident with the arrival of this productive feature at the BTM site, the Oceanic Flux Program (OFP) sediment traps recorded an abrupt, factor of 2.5 increase in mass flux at 3200 m depth. Even more dramatic was the observed increase in flux of labile bioreactive organic matter. Fluxes of primary phytoplankton-derived compounds increased by factors of 7–30, bacteria-derived compounds by 6–9, and early degradation products of sterols by a factor of 10. The covariation of early degradation products and bacteria-derived compounds with phytoplankton-derived compounds indicated that the settling phytoplankton bloom material contained elevated bacterial populations and was undergoing active degradation when it entered the 3200 m trap cup.The increase in the flux of bulk components, especially the residual silicate fraction, and refractory organic compounds clearly preceded the main pulse of the labile, surface-derived phytoplankton organic material. The coincident increase in the flux of refractory and zooplankton-derived compounds suggests that in the initial stage of the deep flux event, the mass flux increased largely as a result of an increase in the flux of refractory materials scavenged from the water column and repackaged into sinking particles and increased zooplankton inputs. These results imply that biological reprocessing of flux material within the water column acts to enhance the coupling between the surface and deep ocean environments.Our results show that transient, upper ocean forcing associated with variable upper ocean physical structure—which includes but is not limited to eddies—and variable meteorological forcing can have an enormous effect on the export flux of bioreactive organic material. The importance of pulsed fluxes of bioreactive material arising from transient physical forcing to the long-term average is not presently known. However, the occurrence of episodic high flux events throughout the OFP time-series record (also inferred from BTM time-series) suggests that such forcing, regardless of specific dynamics, may be responsible for a significant fraction of the total export flux of bioreactive carbon and associated elements to the deep oligotrophic ocean.  相似文献   

18.
The stable form of dissolved chromium in oxygenated seawater is Cr(VI). But Cr(III)-species are also present at an analytically significant level. It is shown that Cr(III) is oxidized only slowly by dissolved oxygen, and that manganese oxide is a strong catalyst for such oxidation. However, the low oceanic concentration of suspended MnO2 impedes the conclusion that the former process is quantitatively less important than the latter one. The distribution of dissolved chromium among Cr(VI)- and Cr(III)-species is probably kinetically controlled.  相似文献   

19.
The impact of bio-optical heating on the properties of the upper Labrador Sea water was investigated by considering changes in light attenuation in water associated with the seasonal change of chlorophyll distribution. The time- and depth-dependent attenuation coefficients were obtained from remotely sensed SeaWiFS ocean-colour data. Sea-surface temperature (SST) and mixed-layer depth (MLD) were computed from a three-dimensional ocean circulation model. The model was integrated from 1999 to 2003 with 6-hourly atmospheric forcing. The changes in SST and MLD attributable to bio-optical heating were determined by comparing the model results using the observed attenuation coefficients (chlorophyll) to those using a weak and constant attenuation (clear water). The model results show that bio-optical heating is controlled mainly by chlorophyll concentration and MLD. The increase in SST is around 1 °C in most parts of the Labrador Sea and the shelves, and up to 2.7 °C in areas of shallow MLD and high chlorophyll concentrations (the Grand Banks and Northeastern Newfoundland Shelf). The increase is much higher than that found in previous studies, which was typically a fraction of a degree. Bio-optical heating also can enhance the stratification of the upper ocean and reduce the MLD by 20–50%.  相似文献   

20.
The redox speciation of dissolved iron in seawater was evaluated at 121 locations in the Pacific Ocean at depths of 15-1000 m, using the method of luminol chemiluminescence. The results indicate that reduced iron, Fe(II), is ubiquitous in surface seawater with a relatively consistent pattern of occurrence. Surface maxima were present in most profiles, with median concentrations of 25-30 pM representing 12-14% of the total dissolved iron. Concentrations decreased monotonically with depth to<12 pM within the upper euphotic zone. This pattern was observed during both day and nighttime sampling events, which suggests that non-photochemical production mechanisms can produce photochemical-like signatures. Further, if theoretical rates of Fe(II) oxidation are applicable to the open ocean, then the employed sampling methods precluded assessment of photochemically-produced Fe(II), regardless of ambient light conditions. For this and other reasons, the concentrations reported here for the upper water column likely represent lower limits of labile iron concentration, and suggest that dissolved iron may be more available for uptake than previously believed. Deeper in the water column, Fe(II) was also frequently detected, though it constituted a small fraction of the total dissolved iron. Possible source mechanisms at these depths include thermal (dark) reduction of Fe(III) organic complexes or remineralization of sinking biogenic particles containing Fe(II). In the northern Philippine Sea between the Japanese coast and the Izu-Bonin volcanic arc system, Fe(II) concentrations were found to be atypically high, possibly because of high atmospheric dust deposition near the surface and transport of sediment-derived iron at depth.  相似文献   

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