High resolution profiles for arsenic in the Seine Estuary. Seasonal variations and net fluxes to the English Channel     

《Continental Shelf Research》1999,19(15-16):2041-2061

Three sampling cruises were conducted in the Seine Estuary from 1993 to 1995 in varying hydrological and seasonal conditions. The site included all of the lower part of the river under the influence of tidal dynamics and the dilution plume in the Baie de Seine. Chemical speciation of arsenic showed high seasonal variations, especially in September when AsIII represented around 50% of dissolved arsenic. The inclusion of organoarsenic compounds not accessible to direct analysis by hydride generation required preliminary mineralisation of the samples. The ratio of dissolved to particulate arsenic distribution was controlled mainly by the iron content of particles. Biological activity had an influence on chemical speciation and thus on the partition coefficient (K_D 10⁻³=6±1 in September and 12±0.9 in February). The zone of conservative mixing used for Seine River flow calculations was limited to a salinity range of approximately 10–30. Dissolved arsenic concentrations extrapolated to null salinities were lower during the high-water period because of dilution (17.6±1.1 nM), and maximal during the low-water period in summer (35.7±0.9 nM). Mean arsenic export to the English Channel was estimated at 33.2±6 T yr⁻¹ for dissolved arsenic. Observation of an arsenic output greater than the upstream input, as well as a simultaneous increase in dissolved and particulate arsenic concentrations during the mixing of freshwater with seawater, strongly suggested the existence of an important intra-estuarine source of arsenic, either of industrial origin or related to the transport and diagenesis of marine sediments.  相似文献   

Fluxes and seasonal changes in composition of organic matter in the English Channel     

Laurent Bodineau  Guy Thoumelin  Michel Wartel 《Continental Shelf Research》1999,19(15-16)

Dissolved and particulate organic matter (DOM and POM) have been investigated along a transect between Cherbourg and the Isle of Wight. In addition, the relative contribution of different sources of POM have been assessed by the use of lipid biomarkers (e.g. fatty acids). Seawater samples were collected at two depths (subsurface and above the bottom) at five stations located on the transect during five cruises (from September 1994 to July 1995). Particulate organic carbon (POC) and dissolved organic carbon (DOC) concentrations vary between 30–530 μg l⁻¹ and 0.5–2.7 mg l⁻¹, respectively, for all the cruises. Fluxes of POM and DOM have been estimated at 0.6×10¹² g yr⁻¹ and 6.5×10¹² g yr⁻¹ of carbon, respectively. General fluxes of water and therefore of DOC and POC are oriented eastward. However, around the Isle of Wight a westward oriented flux exists due to a gyre located in the area. The major DOC and POC fluxes occur in the central part of the Channel where the water column is deepest. Seasonal variations of different sources of POM (algal, bacterial and terrigenous) have been examined for the five cruises. The fresh algal organic fraction is relatively important in September in coastal waters with a predominance of diatom species on the English side, whereas it has a low or undetectable contribution during winter months. The bacterial fraction generally varies in concert with the algal component. It is low during the winter period and more important in bloom or post-bloom conditions, as for example in May. Terrestrial organic matter is restricted to coastal areas in September, and is present at low levels in May and July. Nevertheless, in November and February, terrigenous inputs have been clearly identified for the whole transect even in central waters.  相似文献   

Riparian alder fens — source or sink for nutrients and dissolved organic carbon? — 2. Major sources and sinks     

Lilian B. Busse  Günter Gunkel 《Limnologica》2002,32(1)

Natural riparian forest wetlands are known to be effective in their ability to remove nitrate by denitrification and sediments with attached phosphorus via sedimentation. On the other hand, litter input and decomposition is a process of crucial importance in cycling of nitrogen and phosphorus in a forest ecosystem.In this study we investigated the amount of nitrogen and phosphorus entering the alder fen ecosystem through leaf litter and its decomposition and the removal capacity of nitrogen and phosphorus by measuring denitrification and sedimentation in the alder fen.We found an average input of leaf litter during fall 1998 of 226 g m⁻² yr⁻¹ DW with nutrient concentration of 0.17% P and 1.6% N. This means a yearly input of 0.4 g m⁻² yr⁻¹ P and 3.6 g m⁻² yr⁻¹ N. The decomposition of leaf litter using litter bags with small and large mesh size resulted in bags with macroinvertebrates (large mesh size) and without macroinvertebrates (small mesh size). After 57 days the litter bags with macroinvertebrates had a decomposition rate of 79%.Denitrification was measured in May and June of 1997 using the acetylene inhibition technique on intact soil cores and slurry-experiments. The average annual denitrification rate was 0.2 g m⁻² yr⁻¹ N using data from the core experiments. The denitrification rate was higher after addition of nitrate, indicating that denitrification in the riparian alder fen is mainly controlled by nitrate supply.The sedimentation rate in the investigated alder fen ranged from 0.47 kg m⁻² yr⁻¹ DW to 4.46 kg m⁻² yr⁻¹ DW in 1998 depending on the study site and method we used. Sedimentation rates were lower in newly designed plate traps than in cylinder traps. The alder fen also showed lower rates than the adjacent creek Briese. Average phosphorus removal rate was 0.33 g m⁻² yr⁻¹ P.Input sources for the surface water of the alder fen are sediment mineralization and decomposition of leaf litter; output sources are sedimentation and denitrification. This study showed that a nutrient input of 24.58 kg ha⁻¹ yr⁻¹ N, 8.8 kg ha⁻¹ yr⁻¹ P and 419 kg ha⁻¹ yr⁻¹ DOC into the surface water of the alder fen is possible. Alder fens cannot improve water quality of an adjacent river system. This is only true for a nearly pristine alder fen with the hydrology of 10 months flooded conditions and 2 months non-flooding conditions a year.  相似文献   

The global-average production rate ofBe     

Marc C. Monaghan  S. Krishnaswami  Karl K. Turekian 《Earth and Planetary Science Letters》1986,76(3-4)

Precipitation collected in continuously open containers for about a year at seven sites around the United States was analyzed for¹⁰Be,⁹⁰Sr,²¹⁰Pb and²³⁸U. Based on these data and long-term precipitation,⁹⁰Sr and²¹⁰Pb delivery patterns, the stratospheric, tropospheric and recycled¹⁰Be components in the collections were estimated and the global¹⁰Be production rate was assessed. Single station production rate estimates range from 0.52 × 10⁶ atoms cm⁻² yr⁻¹ to 2.64 × 10⁶ atoms cm⁻² yr⁻¹. The mean value is 1.21 × 10⁶ atoms cm⁻² yr⁻¹ with a standard error of 0.26 × 10⁶ atoms cm⁻² yr⁻¹.  相似文献   

Does quantifying antecedent flow conditions improve stream phosphorus export estimation?     

Stuart Warner  Gerard Kiely  Gerard Morgan  John O&#x;Halloran 《Journal of Hydrology》2009,378(1-2):97-104

A reliable and economical method for the estimation of nutrient export (e.g. phosphorus) in stream flow from catchments is necessary to quantify the impact of land use or land use change upon aquatic systems. The transport of phosphorus (P) from soil to water is known to impact negatively on water quality. A key observation from studies is that most P export occurs during high stream flow. However, it is not yet clear how flood-antecedent conditions affect the P export during flood events. In this study, the P loss from soil to water as represented by soluble reactive phosphorus (SRP) in stream waters from three different catchments, varying in land use, scale and location in Ireland was monitored over 1 year. This study examined the role of antecedent stream flow conditions on SRP export and identifies a catchment-specific relationship between SRP flood event load (EL) and a flow ratio (FR). The FR is defined as the ratio of the flood event volume (EV) to the pre-event volume (PEV). The latter is the cumulative flow volume for a number of days preceding the event. This PEV period was found to be longer (average 81 days) in the grassland catchments which were known to be saturated with soil P than in the forested catchments (average 21 days) with minimal soil P. This FR ratio is a measure of the antecedent hydrological state (wet or dry) of the catchment. For SRP for each catchment, a specific relationship between SRP EL and FR was identified. The annual SRP export was estimated, using this ratio and compared with the concentration/discharge (C/Q) method. The new flow ratio method was used with data from 12 flood events during the year to estimate an annual export of SRP. For the two grassland catchments in the study, using the FR method, we estimated an SRP export of 1.77 and 0.41 kg ha⁻¹ yr⁻¹. Using the C/Q method, for the same sites, our estimate of SRP export was 1.70 and 0.50 kg ha⁻¹ yr⁻¹ respectively. The C/Q method used SRP concentrations covering 40% of the year while the FR method used only 12 flood events covering less than 2% of the year. This new method which takes account of the antecedent flow state of the river is an alternative to and may be more promising than the traditional C/Q method, particularly when short duration or flood sampling of water quality is carried out.  相似文献   

Role of suspended sediments on the distribution of PCB in the Seine Estuary (France)     

Alain Abarnou  Jacques Avoine  Jean Paul Dupont  Robert Lafite  Serge Simon 《Continental Shelf Research》1987,7(11-12)

PCB (polychlorinated biphenyls) contamination and its relationship to SPM (suspended particulate material) have been studied in the Seine Estuary, which is heavily polluted by these persistent and hydrophobic man-made chemicals. Two sampling cruises have been performed during different freshwater discharge conditions. PCB and SPM concentrations, as well as grain-size distributions in the particulate material have been determined. Water samples have been collected at fixed positions during a tidal cycle, and along transects within the estuary.PCB concentrations vary from 2 ng 1⁻¹ in the marine zone to 250 ng 1⁻¹ within the estuary, and reach 1.3 × 10³ ng 1⁻¹ in the turbidity maximum zone. During a tidal cycle, low PCB concentrations are observed at high water, and are in the same range in February as in July. High PCB contamination is observed at low water, but PCB concentrations are about five times higher in February. SPM and PCB variations are well correlated in both periods of observations. Higher PCB contamination during February is explained by higher SPM inputs, mainly due to particles of riverine origin. The transport of PCB within the estuary depends on the quantity and the grainsize composition of suspended material, which varies according to freshwater discharge and tidal amplitude.  相似文献   

Mesoscalic estimation of nitrogen discharge via drainage systems   总被引：2，自引：0，他引：2  

Ulrike Hirt  Torsten Hammann  Burghard C. Meyer   《Limnologica》2005,35(3):206-219

A complex approach has been developed for estimating mesoscalic nitrogen discharges via drainage systems using spatial information about land use, drainage areas, nitrogen balances and soil and site characteristics. Determining the total drainage area involves certain difficulties for larger areas, as on the one hand, the available databases are incomplete, and on the other hand the localisation and digitalisation of large subsurface drainage areas is a very time-consuming process. Knowledge of the history and causes of drainage systems in landscapes is required. To solve this problem a method has been developed to calculate the drainage areas for large catchments. In order to obtain a complete data set of subsurface drainage areas, representative areas were selected to enable the proportion of subsurface drainage area to be determined for various soil and site characteristics. These proportions were extrapolated to the entire area and the approach tested in the Mulde River Catchment Area in Germany.The rate of drained arable land is about 25.2% of the total area, which can be broken down into grassland (19.0%) and arable land (27.4%). The results differ for sandy soils with up to 8% drained areas and 57.8% for stagnant soils. This shows that the proportion of drained land is highly dependent on the nature of the soil in the catchment area, which has profound implications for approaches to nitrogen modelling.Average nitrogen discharge for the whole catchment area via drainage water was 33 kg ha⁻¹ yr⁻¹ in the 1980s and 10 kg ha⁻¹ yr⁻¹ in the 1990s. The nitrogen discharge varies from one soil type to another: in regions with sandy substrate (11,900 ha) discharge was 34 kg ha⁻¹ yr⁻¹ in the 1980s (14 kg ha⁻¹ yr⁻¹ in the 1990s), while in areas with loess lessivé soils (89,200 ha) it was about 26 kg ha⁻¹ yr⁻¹ in the 1980s (9 kg ha⁻¹ yr⁻¹ in the 1990s). The reduction can be explained by the complete change in farming strategy since the demise of the former German Democratic Republic (GDR).The approach shown is well suited to future model approaches on a regional scale. By creating and integrating new data sets derived from modern GIS operations the approach reduces the uncertainty of water and nitrogen modelling. This gives us a better understanding of nitrogen discharges into surface and groundwater and temporal discharge dynamics. The discharge data are highly valuable to predict environmental protection measurements for streams, lakes, coastal waters and groundwaters.  相似文献   

Biogeochemistry of dissolved carbon,major, and trace elements during spring flood periods on the Ob River     

Sergey N. Vorobyev  Oleg S. Pokrovsky  Larisa G. Kolesnichenko  Rinat M. Manasypov  Liudmila S. Shirokova  Jan Karlsson  Sergey N. Kirpotin 《水文研究》2019,33(11):1579-1594

Detailed knowledge of the flood period of Arctic rivers remains one of the few factors impeding rigorous prediction of the effect of climate change on carbon and related element fluxes from the land to the Arctic Ocean. In order to test the temporal and spatial variability of element concentration in the Ob River (western Siberia) water during flood period and to quantify the contribution of spring flood period to the annual element export, we sampled the main channel year round in 2014–2017 for dissolved C, major, and trace element concentrations. We revealed high stability (approximately ≤10% relative variation) of dissolved C, major, and trace element concentrations in the Ob River during spring flood period over a 1‐km section of the river channel and over 3 days continuous monitoring (3‐hr frequency). We identified two groups of elements with contrasting relationship to discharge: (a) DIC and soluble elements (Cl, SO₄, Li, B, Na, Mg, Ca, P, V, Cr, Mn, As, Rb, Sr, Mo, Ba, W, and U) negatively correlated (p < 0.05) with discharge and exhibited minimal concentrations during spring flood and autumn high flow and (b) DOC and particle‐reactive elements (Al, Fe, Ti, Y, Zr, Nb, Cs, REEs, Hf, Tl, Pb, and Th), some nutrients (K), and metalloids (Ge, Sb, and Te), positively correlated (p < 0.05) with discharge and showed the highest concentrations during spring flood. We attribute the decreased concentration of soluble elements with discharge to dilution by groundwater feeding and increased concentration of DOC and particle‐reactive metals with discharge to leaching from surface soil, plant litter, and suspended particles. Overall, the present study provides first‐order assessment of fluxes of major and trace elements in the middle course of the Ob River, reveals their high temporal and spatial stability, and characterizes the mechanism of river water chemical composition acquisition.  相似文献   

An instrument system for the investigation of particle fluxes   总被引：1，自引：0，他引：1  

Edward T. Baker  Hugh B. Milburn 《Continental Shelf Research》1983,1(4):425-435

We present the rationale, design, and use of an instrument system to measure the variability of vertical and horizontal particle fluxes. The system features a new sequentially sampling sediment trap which collects and seals 10 separate samples during a single deployment. Horizontal particle fluxes are simultaneously monitored with a beam transmissometer interfaced to a standard Aanderaa current meter. Results from a 10-week deployment of instruments at several depths in a deep fjord estuary indicate that the trapping rate increases from 0.5g m⁻² day⁻¹ at 20 m to 150g m⁻² day⁻¹ at 200 m (5 m above bottom) because of frequent erosion in the deep waters. Periodic flushing of the deep water by intrusions of marine water over the seaward sill markedly enhances erosion and causes an up-estuary particle transport comparable to the vertical particle flux originating at the surface.  相似文献   

Changes in carbon and nutrient fluxes from headwaters to ocean in a mountainous temperate to subtropical basin          下载免费PDF全文

Macdex Mutema  Pauline Chivenge  Fantine Nivet  Christophe Rabouille  Vincent Thieu  Vincent Chaplot 《地球表面变化过程与地形》2017,42(13):2038-2053

Water erosion provides major links in global cycles of carbon (C), nitrogen (N) and phosphorus (P). Although significant research on erosion mechanisms has been done, there is still little knowledge on C, N and P fluxes across landscapes to the ocean and their controlling factors in subtropical climates. A four‐year study quantifying and comparing particulate and dissolved C, N and P from multiple scales (microplot, plot, microcatchment, subcatchment, catchment, sub‐basin and basin) was performed in Thukela basin (≈30 000 km²), South Africa. The basin climate was largely subtropical‐humid [mean annual precipitation (MAP) > 980 mm yr^‐1], but temperate (MAP >2000 mm yr^‐1) on the highlands. Open grassland, cropland and bushland were the major land uses. On average, 65, 24 and 4 g m^‐2 yr^‐1 C, N and P were displaced from original topsoil positions, but only 0.33, 0.005 and 0.002 mg m^‐2 yr^‐1 were, respectively, exported to the ocean. The fluxes decreased by 95, 97 and 84%, respectively, from plot to microcatchment outlet; and decreased further in downstream direction by >99% from microcatchment to basin outlet. The hillslope (microplot to microcatchment) fluxes correlated strongly with rainfall parameters. Particulate contributions dominated hillslope fluxes at 73, 81 and 76% of total annual C, N and P, respectively. Although particulate C dominated in the microcatchment‐catchment reach (55%), N (54%) and P (69%) were dominated by dissolved forms. The lower basin zone was dominated by dissolved flux contributions at 93, 81 and 78% for C, N and P for the sub‐basin outlet. These results suggested spatially varying drivers of C, N and P losses from the landscape to the ocean, via the river network. Deposition was envisaged the dominant hillslope level loss process, which gradually gave way to mineralization and biotic uptake in the river network as flux contributions shifted from being predominantly particulate to dissolved forms. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Organic carbon and nutrient fluxes to the coastal zone from the Sepik River outflow     

Kathryn A. Burns  Gregg BrunskillDiane Brinkman  Irena Zagorskis 《Continental Shelf Research》2008

The Sepik River is a major contributor of water, sediment and associated organic loads to the coastal waters of northern New Guinea and the Bismarck Sea. We compare dissolved and particulate organic carbon data from September 1997 during an extremely dry El Nino year with those from 1996, 1999 and 2000 during La Nina wet season discharges. Estimated Sepik River flux of DOC is 3.2×10¹⁰ mol yr⁻¹ and POC is 1.1×10¹¹ mol yr⁻¹. The estimates for total river nutrient fluxes to the sea are 1.1×10¹⁰ mol yr⁻¹ for nitrogen and 4.6×10⁸ mol yr⁻¹ for phosphorus. The Sepik DOC flux is about equal to that combined from all four major rivers that enter the Gulf of Papua on the south coast of PNG. The Sepik inorganic PIC flux is low (1.4×10⁸ mol yr⁻¹) as the river does not drain carbonate soils. With a narrow continental shelf, and strong coastal currents, much of this exported material is available for long distance transport into the coastal Bismarck Sea and beyond.  相似文献   

Factors affecting longitudinal dispersion in estuaries of different scale   总被引：1，自引：0，他引：1  

Roy E.?LewisEmail author  Reginald J.?Uncles 《Ocean Dynamics》2003,53(3):197-207

Traditionally, the overall diluting capacity of an estuary is characterized using a coefficient of longitudinal dispersion, K_xe, which is given by the ratio of the dispersive flux of a dissolved substance to its tidally averaged longitudinal gradient. A steady-state model, which assumes a balance between the dispersive and non-dispersive fluxes and an exponential increase in estuary cross-sectional area towards the sea, has been used to derive expressions for the axial salinity distribution and the dispersive flux of salt. The model was set up assuming either a constant dispersion coefficient along the estuary or one that increased with distance towards the sea. By comparing salinity predictions with data from five UK estuaries, estimates were made of the maximum dispersive salt flux and the corresponding maximum salinity gradient for each system. The results indicated that there was an approximately linear relation between the fluxes and gradients, and the slope of a line plotted through the origin provided an estimate of a common K_xe for all five estuaries. The magnitude of K_xe was found to be about 90 m² s^–1 with a standard deviation of approximately ±32 m² s^–1. It is concluded that a representative value of 100 m² s^–1 for K_xe is a reasonable first choice when setting up a cross-sectionally averaged estuary model. The results also showed that larger systems, such as the Thames, had lower salinity gradients and lower dispersive salt fluxes, whilst smaller estuaries displayed the opposite characteristics. The model was used to predict the variation in the non-advective flux of salt along an estuary. The distribution was found to be similar to the corresponding flux distribution estimated from observations at the seaward end of the Tees estuary, despite appreciable spatial variations in the individual flux components. Allowing for a small decrease in freshwater flow, the model indicated that there was a decrease in the maximum dispersive flux between neap and spring tides. It is argued that such a reduction in flux can result in a seaward shift in the salinity distribution to a region of greater cross-section, where the freshwater transport per unit area again balances the reduced upstream dispersive flux, as found in the neap to spring response in the Tees estuary.Responsible Editor: Hans Burchard  相似文献   

Evolution of particle size and concentration in the Rhône river mixing zone: : influence of salt flocculation     

Antoine Thill  Stphane Moustier  Jean-Marie Garnier  Claude Estournel  Jean-Jacques Naudin  Jean-Yves Bottero 《Continental Shelf Research》2001,21(18-19)

The salt induced flocculation phenomenon is often proposed as a major mechanism influencing the deposition of the suspended matter near the mouth of major rivers. However, depending on the particular mixing conditions between fresh water and marine water and on suspended solids (SS) reactivity, salt induced aggregation may be a minor factor controlling fast deposition of SS. This work combines field studies and laboratory experiments in order to assess the importance of salt induced flocculation in the case of the saltwedge estuary of the Rhône river. Sampling of the mixing zone has been performed in contrasted hydrodynamic conditions from a low water discharge period (500 m³ s⁻¹) to a small flood event (2400 m³ s⁻¹) for particle counting and salinity measurements. Through laboratory experiments, it is shown that the Rhône river particulate matter has a poor average reactivity regarding salt induced flocculation. Considering the hydrodynamics of the estuary, we show that the evolution of the concentration of larger particles (>5 μm) can be explained by settling and dilution. In contrast, the smallest measured fraction (2–5 μm) shows a more complex behavior and settling processes alone cannot explain the observed particle concentrations during the field studies. Four hypotheses are discussed for explaining the 2–5 μm particle concentration evolutions.  相似文献   

Seasonal variations between sampling and classical mean turbulent heat flux estimates in the eastern North Atlantic     

Simon A. Josey  Elizabeth C. Kent  Peter K. Taylor 《Annales Geophysicae》1995,13(10):1054-1064

The two commonly used statistical measures of the air-sea heat flux, the sampling and classical means, have been compared using hourly reports over a 7-year-period from a weather ship stationed in the NE Atlantic. The sampling mean is the average over all flux estimates in a given period, where individual flux estimates are determined from ship reports of meteorological variables using the well-known bulk formulae. The classical mean is the flux derived by substituting period-averaged values for each of the meteorological variables into the bulk formula (where the averaging period employed is the same as that over which the fluxes are to be determined). Monthly sampling and classical means are calculated for the latent and sensible heat fluxes. The monthly classical mean latent heat flux is found to overestimate the sampling mean by an amount which increases from 1–2 W m⁻² in summer to 7 W m⁻² in winter, on average, over the 7-year-period. In a given winter month, the excess may be as great as 15 W m⁻², which represents about 10% of the latent heat flux. For the sensible heat flux, any seasonal variation between the two means is of the order of 1 W m⁻² and is not significant compared to the interannual variation. The discrepancy between the two means for the latent heat flux is shown to arise primarily from a negative correlation between the wind speed and sea-air humidity difference, the effects of which are implicitly included in the sampling method but not in the classical. The influence of the dominant weather conditions on the sign and magnitude of this correlation are explored, and the large negative values that it takes in winter are found to depend on the typical track of the mid-latitude depressions with respect to the position sampled. In conclusion, it is suggested that sampling means should be employed where possible in future climatological studies.  相似文献   

Surface areas and porosities of particulate matter in turbid estuaries     

J.G. Titley  G.A. Glegg  D.R. Glasson  G.E. Millward 《Continental Shelf Research》1987,7(11-12)

A vacuum microbalance technique has been used to determine the specific surface areas and porosities of suspended solids and sediments from two turbid estuaries. In the Tamar Estuary, the suspended solids had specific surface areas in the range 8–20 m² g⁻¹ whereas the sediments were in the range 5–15 m² g⁻¹. Sediments from the iron-rich system of Restronguet Creek were in the range 5–26 m² g⁻¹. The specific surface areas and porosities of the particles were influenced by the carbon and non-detrital iron contents. The results are relevant to sorption behaviour of dissolved trace constituents in the presence of natural particles.  相似文献   

Effects of size and origin of natural dissolved organic matter compounds on the redox cycling of iron in sunlit surface waters     

Laurence Meunier  Hansulrich Laubscher  Stephan J. Hug  Barbara Sulzberger 《Aquatic Sciences - Research Across Boundaries》2005,67(3):292-307

  相似文献   

Organic biomarkers for tracing carbon cycling in the Gulf of Papua (Papua New Guinea)   总被引：1，自引：0，他引：1  

K.A. Burns  P. Greenwood  R. Benner  D. Brinkman  G. Brunskill  S. Codi  I. Zagorskis 《Continental Shelf Research》2004,24(19):2373-2394

Sediment traps were deployed in the Gulf of Papua in June–July 1997, to determine fluxes of organic matter and inorganic elements from the photic zone to deeper waters at the base of the continental slope and in the northern Coral Sea. Three stations, ranging from 900 to 1500 m depth, had “shallow” traps at 300 m below the water surface and “deep” traps set 100 m above the bottom. Infiltrex II water samplers collected particulate and dissolved organic matter from the Fly, Purari and Kikori rivers, and near-surface water from the shelf of the Gulf of Papua. Samples were analysed for molecular organic biomarkers to estimate the sources of organic carbon and its cycling processes.Dry weight fluxes from the shallow traps ranged from 115 to 181 mg m⁻² day⁻¹ and particulate organic carbon (POC) fluxes ranged from 1.2 to 1.9 mM OC m⁻² d⁻¹ with molar organic carbon to particulate nitrogen ratios (C/N) ranging from 6.0 to 6.5. Fluxes in deep traps were likely influenced by both early diagenesis and entrapment of resuspended shelf sediments. Dry weight fluxes in deep traps ranged from 106 to 574 mg m⁻² day⁻¹ and POC fluxes ranged from 0.6 to 1.5 mM OC m⁻² d⁻¹, with C/N ratios ranging from 8.5 to 10.8. ¹³C/¹²C ratios were −20.2‰ to −21.7‰ in all trap samples, indicating that most of the settling POC was “marine-derived”. Shallow traps had δ¹⁵N values of 6.3‰ to 7.2‰ while the values in deep traps were 4.9–5.0‰, indicating the N-rich near-surface OC was less degraded than that in the deep traps. The biogenic lipids consisted of hydrocarbon, sterol and fatty acid biomarkers indicative of marine zooplankton, phytoplankton and bacteria. Sterol markers for diatoms and dinoflagellates were abundant in the water samples. Highly branched isoprenoid alkenes, usually attributable to diatoms, were also detected in both water and shallow traps. Traces of C₂₆–C₃₄ n-alcohols indicative of land–plant biomarkers, were found in river water samples and in the shallow sediment traps. A large unresolved complex mixture (UCM) of hydrocarbons, and a uniform distribution of n-alkanes, indicative of petroleum hydrocarbons, were also detected in the traps. Hopane and sterane biomarkers detected in the trap oil were characteristic of a marine carbonate source, and the aromatic hydrocarbon composition distinguished at least two different oil signatures.We concluded that mass and POC fluxes were similar to those reported for other continental shelves and marginal oceans in tropical and subtropical regions. There was a dramatic decrease in POC as particles sank, due to zooplankton repackaging and photochemical and bacterial decomposition. Carbon isotopic and biomarker patterns showed most of the POC in the sediment traps was marine-sourced with only traces of terrestrial input. There was a significant flux of petroleum, which may signal the existence of natural petroleum seeps in this region.  相似文献   

Conductivity as a predictor of a total cations and salinity in Ethiopian lakes and rivers: revisiting earlier models     

Gebre-Mariam Zinabu  Lauren J. Chapman  Colin A. Chapman 《Limnologica》2002,32(1)

We used regression analyses of water samples from 18 lakes, nine rivers, and one spring in Ethiopia to (a) test the hypothesis that water bodies of relatively higher salinity (K₂₅>1000 μS cm⁻¹) have a different conductivity to salinity relationship than waters of lower salinity (K₂₅ < 1000 μS cm⁻¹), and (b) develop models to predict total cations and salinity from conductivity that can be used for Ethiopian waters and other African aquatic systems of similar chemical composition. We found no statistical difference in the bilogarithmic relationships (total cations vs. conductivity; salinity vs. conductivity) for waters of higher salinity (K₂₅ > 1000 μS cm⁻¹) and waters of lower salinity (K₂₅ < 1000 μS cm⁻¹). However, comparison among our models and models from the literature suggests that developing separate equations for low and high salinity water bodies has some merit. We believe that the equations developed in this study can be used for Ethiopian waters and other African waters within the range of conductivity in this study.  相似文献   

Prediction of dissolved inorganic nitrogen (DIN) concentrations in deep,seasonally stratified lakes based on rates of DIN input and N removal processes     

P. Höhener  R. Gächter 《Aquatic Sciences - Research Across Boundaries》1993,55(2):112-131

Mean dissolved inorganic nitrogen concentrations ([DIN]) in deep, seasonally stratified lakes with comparable DIN inputs can differ by up to a factor of 3 depending on hydraulic and morphometric properties and/or different trophic states of the lakes. In such lakes, net N sedimentation rates were estimated with two independent methods (sediment core analysis and input-output mass balances). They were higher in eutrophic lakes (Mean: 5.1; SD: ± 1.6 g m^–2 yr^–1; n = 13) than in oligotrophic lakes (1.6 ± 1.0 g m^–2 yr^–1; n = 3), but independent of [DIN]. Gaseous N loss rates to the atmosphere, as calculated from combined N- and P-mass balances from selected lakes, ranged from 0.9 to 37.4 g m^–2 yr^–1 (n = 10) and were positively correlated with [DIN]. Reduction of NO ₃ ^- to N₂ is assumed to be the main cause for gaseous N losses. A simple one-box mass balance model for [DIN], based on DIN input and rates and kinetics of N removal processes (net sedimentation and gaseous N loss) is proposed, and validated with a data base on [DIN] and DIN input in 19 deep, seasonally stratified lakes of central Europe. The model illustrated that the amount of water loading per unit surface area of a lake (called water discharge height q) is the critical parameter determining mean lake [DIN] relative to mean input [DIN]. Lakes with a q > 50 m yr^–1 have average [DIN] similar to the [DIN] of the inflows regardless of their trophic states, because input and outflow exceed lake-internal N removal processes. A high primary production favors DIN removal in lakes with q < 50 m yr^–1. It is concluded that measures to decrease primary production, e.g. by means of P removal programs, lead to an increase of [DIN] in lakes.  相似文献   

La β-decay constant estimated from geochronological studies     

A. Masuda  H. Shimizu  S. Nakai  A. Makishima  S. Lahti 《Earth and Planetary Science Letters》1988,89(3-4)

LaCe ages are reported for two sets of Finnish pegmatites, Lövböle and Mustikkamäki, and for an Amiˆtsoq gneiss, Greenland. When λ_β¹³⁸La value (2.29 × 10⁻¹² yr⁻¹) obtained by radioactivity measurement [1] is used for the chronological calculation, the LaCe ages (2129, 2325, 3271 Myr) evaluated for these rocks are 18–35% older than the SmNd ages for the same samples. To make the LaCe age fit to the SmNd age for the same sample, a new value of (2.77 ± 0.21) × 10⁻¹² yr⁻¹ is evaluated for λ_β¹³⁸La. In this calculation, the LaCe and SmNd ages reported for a Bushveld gabbro [2] have been also taken into account together with those for the Lövböle pegmatite and the Mustikkamäki pegmatite, while the Amiˆtsoq gneiss (GGU110999) has been omitted because of the complicated thermal history of this sample.  相似文献