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1.
Authigenic carbonates were sampled in methane-enriched piston core sediments collected from gas venting sites on the western continental slope of the Ulleung Basin, East Sea of Korea. Multidisciplinary investigations on these carbonates, including the scanning electronic microscope (SEM) observations and mineralogical-geochemical compositions, were carried out to identify the carbon and oxygen sources and the forming mechanism of these carbonates. The authigenic carbonates from the study area correspond to semi-consolidated, compact concretions or nodules ranging from 2 to 9 cm in size. X-ray diffraction and electron microprobe analyses showed that most of the sampled carbonate concretions were composed of almost purely authigenic high-Mg calcite (10.7–14.3 mol% MgCO3). Characteristically, microbial structures such as filaments and rods, which were probably associated with the authigenic minerals, were abundantly observed within the carbonate matrix. The carbonates were strongly depleted in δ13C (−33.85‰ to −39.53‰ Peedee Belemnite (PDB)) and were enriched in δ18O (5.16–5.60‰ PDB), indicating that the primary source of carbon is mainly derived from the anaerobic oxidation of methane. Such methane probably originated from the destabilization of the underlying gas hydrates as strongly supporting from the enriched 18O levels. Furthermore, the strongly depleted δ13C values (−60.7‰ to −61.6‰ PDB) of the sediment void gases demonstrate that the majority of the gas venting at the Ulleung Basin is microbial methane by CO2 reduction. This study provides another example for the formation mechanism of methane-derived authigenic carbonates associated with gas-hydrate decomposition in gas-seeping pockmark environments.  相似文献   

2.
In the Jungwon area, South Korea, two contrasting types of deep thermal groundwater (around 20–33 °C) occur together in granite. Compared to shallow groundwater and surface water, thermal groundwaters have significantly lower δ18O and δD values (> 1‰ lower in δ18O) and negligible tritium content (mostly < 2 TU), suggesting a relatively high age of these waters (at least pre-thermonuclear period) and relatively long subsurface circulation. However, the hydrochemical evolution yielded two distinct water types. CO2-rich water (PCO2 = 0.1 to 2 atm) is characterized by lower pH (5.7–6.4) and higher TDS content (up to 3300 mg/L), whereas alkaline water (PCO2 = 10− 4.1–10− 4.6 atm) has higher pH (9.1–9.5) and lower TDS (< 254 mg/L). Carbon isotope data indicate that the CO2-rich water is influenced by a local supply of deep CO2 (potentially, magmatic), which enhanced dissolution of silicate minerals in surrounding rocks and resulted in elevated concentrations of Ca2+, Na+, Mg2+, K+, HCO3− and silica under lower pH conditions. In contrast, the evolution of the alkaline water was characterized by a lesser degree of water–rock (granite) interaction under the negligible inflow of CO2. The application of chemical thermometers indicates that the alkaline water represents partially equilibrated waters coming from a geothermal reservoir with a temperature of about 40 °C, while the immature characteristics of the CO2-rich water resulted from the input of CO2 in Na–HCO3 waters and subsequent rock leaching.  相似文献   

3.
The present work aimed at studying the origin of particulate organic matter in Guanabara Bay and in some rivers of the Guanabara basin by using elemental composition, isotopic ratios (δ13C and δ15N) and molecular markers (sterols) in samples collected in two periods (winter and summer). Elemental and isotopic compositions were determined by dry combustion and mass spectrometry, respectively, while sterols were investigated by GC–FID and GC–MS. Higher sterol concentrations were present in the north-western part of the bay in winter (5.10–23.5 μg L–1). The high abundance of algal sterols (26–57% of total sterols), the elemental composition (C/N=6–8) and the isotopic signatures (δ13C=−21.3‰ to −15.1‰ and δ15N=+7.3‰ to +11.1‰) suggested the predominance of autochthonous organic matter, as expected for an eutrophic bay, although seasonal variation in phytoplankton activity was observed. Coprostanol concentration (fecal sterol) was at least one order of magnitude higher in the particulate material from fluvial samples (4.65–55.98 μg L–1) than in the bay waters (<0.33 μg L–1). This could be ascribed to a combination of factors including efficient particle removal to sediments in the estuarine transition zone, dilution with bay water and bacterial degradation during particle transport in the water column.  相似文献   

4.
Iron isotope fractionation during planetary differentiation   总被引：4，自引：0，他引：4  
The Fe isotope composition of samples from the Moon, Mars (SNC meteorites), HED parent body (eucrites), pallasites (metal and silicate) and the Earth's mantle were measured using high mass resolution MC-ICP-MS. These high precision measurements (δ56Fe ≈ ± 0.04‰, 2 S.D.) place tight constraints on Fe isotope fractionation during planetary differentiation.Fractionation during planetary core formation is confined to < 0.1‰ for δ56Fe by the indistinguishable Fe isotope composition of pallasite bulk metal (including sulfides and phosphides) and olivine separates. However, large isotopic variations (≈ 0.5‰) were observed among pallasite metal separates, varying systematically with the amounts of troilite, schreibersite, kamacite and taenite. Troilite generally has the lightest (δ56Fe ≈ − 0.25‰) and schreibersite the heaviest (δ56Fe ≈ + 0.2‰) Fe isotope composition. Taenite is heavier then kamacite. Therefore, these variations probably reflect Fe isotope fractionation during the late stage evolution and differentiation of the S- and P-rich metal melts, and during low-temperature kamacite exsolution, rather than fractionation during silicate-metal separation.Differentiation of the silicate portion of planets also seems to fractionate Fe isotopes. Notably, magmatic rocks (partial melts) are systematically isotopically heavier than their mantle protoliths. This is indicated by the mean of 11 terrestrial peridotite samples from different tectonic settings (δ56Fe = + 0.015 ± 0.018‰), which is significantly lighter than the mean of terrestrial basalts (δ56Fe = + 0.076 ± 0.029‰). We consider the peridotite mean to be the best estimate for the Fe isotope composition of the bulk silicate Earth, and probably also of bulk Earth. The terrestrial basaltic mean is in good agreement with the mean of the lunar samples (δ56Fe = + 0.073 ± 0.019‰), excluding the high-Ti basalts. The high-Ti basalts display the heaviest Fe isotope composition of all rocks measured here (δ56Fe ≈ + 0.2‰). This is interpreted as a fingerprint of the lunar magma ocean, which produced a very heterogeneous mantle, including the ilmenite-rich source regions of these basalts.Within uncertainties, samples from Mars (SNC meteorites), HED (eucrites) and the pallasites (average olivine + metal) have the same Fe isotope compositions as the Earth's mantle. This indicates that the solar system is very homogeneous in Fe isotopes. Its average δ56Fe is very close to that of the IRMM-014 standard.  相似文献   

5.
This article identifies the Pucarilla–Cerro Tipillas Volcanic Complex and its major eruptive source, the Luingo caldera (26° 10′S–66° 40′W). Detailed geological mapping, stratigraphic sections, facies analysis and correlations, including the identification of typical caldera components, allow us to infer the position of a collapse caldera, elongated at N65° and with a diameter of 19 km × 13 km, which is responsible for an eruption of 135 km3 (DRE) of magma. The high-crystal contents of the associated ignimbrites, combined with its tectonic setting, indicate that regional and local tectonic structures played a crucial role in the formation of the caldera.  相似文献   

6.
Our understanding of the ancient ocean-atmosphere system has focused on oceanic proxies. However, the study of terrestrial proxies is equally necessary to constrain our understanding of ancient climates and linkages between the terrestrial and oceanic carbon reservoirs. We have analyzed carbon-isotope ratios from fossil plant material through the Valanginian and Lower Hauterivian from a shallow-marine, ammonite-constrained succession in the Crimean Peninsula of the southern Ukraine in order to determine if the Upper Valanginian positive carbon-isotope excursion is expressed in the atmosphere. δ13Cplant values fluctuate around − 23‰ to − 22‰ for the Valanginian-Hauterivian, except during the Upper Valanginian where δ13Cplant values record a positive excursion to ∼− 18‰. Based upon ammonite biostratigraphy from Crimea, and in conjunction with a composite Tethyan marine δ13Ccarb curve, several conclusions can be drawn: (1) the δ13Cplant record indicates that the atmospheric carbon reservoir was affected; (2) the defined ammonite correlations between Europe and Crimea are synchronous; and (3) a change in photosynthetic carbon-isotope fractionation, caused by a decrease in atmospheric pCO2, occurred during the Upper Valanginian positive δ13C excursion. Our new data, combined with other paleoenvironmental and paleoclimatic information, indicate that the Upper Valanginian was a cool period (icehouse) and highlights that the Cretaceous period was interrupted by periods of cooling and was not an equable climate as previously thought.  相似文献   

7.
The Latera caldera is a well-exposed volcano where more than 8 km3 of mafic silica-undersaturated potassic lavas, scoria and felsic ignimbrites were emplaced between 380 and 150 ka. Isotopic ages obtained by 40Ar/39Ar analysis of single sanidine crystals indicate at least four periods of explosive eruptions from the caldera. The initial period of caldera eruptions began at 232 ka with emplacement of trachytic pumice fallout and ignimbrite. They were closely followed by eruption of evolved phonolitic magma. After roughly 25 ky, several phonolitic ignimbrites were deposited, and they were followed by phreatomagmatic eruptions that produced trachytic ignimbrites and several smaller ash-flow units at 191 ka. Compositionally zoned magma then erupted from the northern caldera rim to produce widespread phonolitic tuffs, tephriphonolitic spatter, and scoria-bearing ignimbrites. After 40 ky of mafic surge deposit and scoria cone development around the caldera rim, a compositionally zoned pumice sequence was emplaced around a vent immediately northwest of the Latera caldera. This activity marks the end of large-scale explosive eruptions from the Latera volcano at 156 ka.  相似文献   

8.
Quantitative X-ray diffraction analysis of about 80 rhyolite and associated lacustrine rocks has characterized previously unrecognized zeolitic alteration throughout the Valles caldera resurgent dome. The alteration assemblage consists primarily of smectite–clinoptilolite–mordenite–silica, which replaces groundmass and fills voids, especially in the tuffs and lacustrine rocks. Original rock textures are routinely preserved. Mineralization typically extends to depths of only a few tens of meters and resembles shallow “caldera-type zeolitization” as defined by Utada et al. [Utada, M., Shimizu, M., Ito, T., Inoue, A., 1999. Alteration of caldera-forming rocks related to the Sanzugawa volcanotectonic depression, northeast Honshu, Japan — with special reference to “caldera-type zeolitization.” Resource Geol. Spec. Issue No. 20, 129–140]. Geology and 40Ar/39Ar dates limit the period of extensive zeolite growth to roughly the first 30 kyr after the current caldera formed (ca. 1.25 to 1.22 Ma). Zeolitic alteration was promoted by saturation of shallow rocks with alkaline lake water (a mixture of meteoric waters and degassed hydrothermal fluids) and by high thermal gradients caused by cooling of the underlying magma body and earliest post-caldera rhyolite eruptions. Zeolitic alteration of this type is not found in the later volcanic and lacustrine rocks of the caldera moat (≤ 0.8 Ma) suggesting that later lake waters were cooler and less alkaline. The shallow zeolitic alteration does not have characteristics resembling classic, alkaline lake zeolite deposits (no analcime, erionite, or chabazite) nor does it contain zeolites common in high-temperature hydrothermal systems (laumontite or wairakite). Although aerially extensive, the early zeolitic alteration does not form laterally continuous beds and are consequently, not of economic significance.  相似文献   

9.
Saronikos Gulf (Greece) practically constitutes the sea border of the metropolitan city of Athens and the alongshore outskirts, and it receives the treated wastes of ∼4 million people from a point source that discharges on the sea bottom at ∼65 m water depth. Total organic carbon (TOC) was measured in 477 seawater samples collected in the Saronikos Gulf, during 10 cruises, from August 2001 to May 2004 and analyzed with the High Temperature Catalytic Oxidation method (HTCO). TOC concentrations ranged from 49 to 198 μmol C L−1 in agreement with other Mediterranean coastal waters. The highest TOC concentrations were found in the upper waters (0–75 m), whereas in the deeper parts of the Gulf (between 100 and 400 m) TOC concentrations were kept constantly low (49–70 μmol C L−1). A general pattern towards higher TOC concentrations during summer was also observed. Calculations of non-refractory (labile+semi-labile) organic material based on a one-dimensional (1D) conceptual model showed that it corresponds to 33% of the bulk TOC during summer and to 27% during winter. Bacterial production (BP) was measured at selected stations of ∼70–80 m depth using the [3H] leucine method. Depth integrated BP values varied from 2.8 to 10.9 mmol m−2 d−1, whereas extraordinary high integrated BP values (126 and 140 mmol m−2 d−1) were observed at the station over the treated sewage outflow. From the turnover time, τ, of the non-refractory TOC by bacteria it was implied that organic matter in the effluents is extremely labile (2–58 days). Moreover, τ values at the other sites showed that during summer non-refractory organic material resisted bacterial degradation (1–8 months), whereas during early spring it was easily degradable (20–50 days). The balance of TOC fluxes for the Inner Gulf for June and September 2003 showed that the Inner Gulf acts as a net producer of TOC during summer. Our results suggest that the presence of the Athens treated sewage outfall does not contribute to the observed summer accumulation of TOC in the Inner Gulf and other causes such as increased bacteria predation and/or nutrient limitation must be responsible.  相似文献   

10.
El Chichón crater lake appeared immediately after the 1982 catastrophic eruption in a newly formed, 1-km wide, explosive crater. During the first 2 years after the eruption the lake transformed from hot and ultra-acidic caused by dissolution of magmatic gases, to a warm and less acidic lake due to a rapid “magmatic-to-hydrothermal transition” — input of hydrothermal fluids and oxidation of H2S to sulfate. Chemical composition of the lake water and other thermal fluids discharging in the crater, stable isotope composition (δD and δ18O) of lake water, gas condensates and thermal waters collected in 1995–2006 were used for the mass-balance calculations (Cl, SO4 and isotopic composition) of the thermal flux from the crater floor. The calculated fluxes of thermal fluid by different mass-balance approaches become of the same order of magnitude as those derived from the energy-budget model if values of 1.9 and 2 mmol/mol are taken for the catchment coefficient and the average H2S concentration in the hydrothermal vapors, respectively. The total heat power from the crater is estimated to be between 35 and 60 MW and the CO2 flux is not higher than 150 t/day or ~ 200 gm− 2 day− 1.  相似文献   

11.
We investigated the effects of salinity (5‰, 15‰, 25‰ and 35‰) on metal ion (Cu and Zn) and nanoparticle (NP) CuO and ZnO toxicity to Tigriopus japonicus. Increasing the test media volume without renewal increased the 96-h LC50 for Cu (32.75 mg L−1) compared to the reported value (3.9 mg L−1). There was no significant difference in acute toxicity at different salinities between acclimated and unacclimated T. japonicus (p > 0.05). Increasing salinity decreased the dissolved concentrations of Cu and Zn ions due to the precipitation of the metal ions, consequently reducing the acute toxicity to T. japonicus. The effect of salinity on acute CuO and ZnO NP toxicity was similar to that on metal ion toxicity. Since the aggregation of NPs generally enhanced at higher salinities, both the dissolution and aggregation of CuO and ZnO NPs may control the effect of salinity on acute toxicity to T. japonicus.  相似文献   

12.
An 8-m continuous sediment core, approximately 250-ky-old at the bottom, from Academician Ridge in Lake Baikal, has been analyzed for the stable isotopes of carbon, nitrogen and sulfur, in order to study the paleoclimatic and paleobiological changes that occurred in the Eurasian continental interior. These isotopic changes are closely related to changes in vertical lake-water circulation between glacial and interglacial periods. Sedimentary organic carbon in cool periods is more enriched in 13C (−23.8‰ on average) than that in warm periods (−27.0‰ on average). The 13C-enrichment of organic carbon suggests a decrease of land-derived organic matter influx to the lake, less precipitation, and loss of terrestrial vegetation around Lake Baikal in cool periods. Pyrite in high total sulfur/total organic carbon (TS/TOC) layers shows strong depletion in 34S (−20.8‰ to −32.4‰) during climate transitions from glacial to interglacial periods at the beginning of oxygen isotope stages (OIS) 1, 5 and 7. The 34S-depleted pyrite indicates augmentation of dissimilatory sulfate reduction by sulfate reducing bacteria (SRB) at the sediment-water interface. Enhancement of aqueous sulfate concentrations and limitation of oxygen circulation to the surface sediments might also occur in the climate transition periods. The δ15N values of total nitrogen increase abruptly by ∼2‰ just after the δ34S negative peaks, which may result from low nutrient concentrations in the euphotic zone associated with water circulation changes in Lake Baikal.  相似文献   

13.
Cruises to Bering Strait and the Chukchi Sea in US waters from late June in 2002 to early September in 2004 and the Russian–American Long-term Census of the Arctic (RUSALCA) research cruise in 2004 covered all major water masses and contributed to a better understanding of the regional physics, nutrient dynamics, and biological systems. The integrated concentration of the high nitrate pool in the central Chukchi Sea was greater in this study than in previous studies, although the highest nitrate concentration (∼22 μM) in the Anadyr Water mass passing through the western side of Bering Strait was consistent with prior observations. The chlorophyll-a concentrations near the western side of the Diomede Islands ranged from 200 to 400 mg chl-a m−2 and the range in the central Chukchi Sea was 200–500 mg chl-a m−2 for the 2002–2004 Alpha Helix (HX) cruises. Chlorophyll-a concentrations for the 2004 RUSALCA cruise were lower than those from previous studies. The mean annual primary production of phytoplankton from this study, using a 13C–15N dual-isotope technique, was 55 g C m−2 for the whole Chukchi Sea and 145 g C m−2 for the plume of Anadyr–Bering Shelf Water in the central Chukchi Sea. In contrast, the averages of annual total nitrogen production were 13.9 g N m−2 (S.D.=±16.2 g N m−2) and 33.8 g N m−2 (S.D.=±14.1 g N m−2) for the Chukchi Sea and the plume, respectively. These carbon and nitrogen production rates of phytoplankton were consistently two-or three-fold lower than those from previous studies. We suggest that the lower rates in this study, and consequently more unused nitrate in the water column, were caused by lower phytoplankton biomass in the Bering Strait and the Chukchi Sea. However, we do not know if the lower rate of production from this study is a general decreasing trend or simply temporal variations in the Chukchi Sea, since temporal and geographical variations are substantially large and presently unpredictable.  相似文献   

14.
Forty-three sediment samples were collected from the beaches of Miri City, Sarawak, Malaysia to identify the enrichment of partially leached trace metals (PLTMs) from six different tourist beaches. The samples were analyzed for PLTMs Fe, Mn, Cr, Co, Cu, Ni, Pb, Sr and Zn. The concentration pattern suggest that the southern side of the study area is enriched with Fe (1821–6097 μg g−1), Mn (11.57–90.22 μg g−1), Cr (51.50–311 μg g−1), Ni (18–51 μg g−1), Pb (8.81–84.05 μg g−1), Sr (25.95–140.49 μg g−1) and Zn (12.46–35.04 μg g−1). Compared to the eco-toxicological values, Cr > Effects range low (ERL), Lowest effect level (LEL), Severe effect level (SEL); Cu > Unpolluted sediments, ERL, LEL; Pb > Unpolluted sediments and Ni > ERL and LEL. Comparative results with other regions indicate that Co, Cr, Cu, Ni and Zn are higher, indicating an external input rather than natural process.  相似文献   

15.
The three-dimensional P-wave velocity structure beneath the Katmai group of volcanoes is determined by inversion of more than 10,000 rays from over 1000 earthquakes recorded on a local 18 station short-period network between September 1996 and May 2001. The inversion is well constrained from sea level to about 6 km below sea level and encompasses all of the Katmai volcanoes; Martin, Mageik, Trident, Griggs, Novarupta, Snowy, and Katmai caldera. The inversion reduced the average RMS travel-time error from 0.22 s for locations from the standard one-dimensional model to 0.13 s for the best three-dimensional model. The final model, from the 6th inversion step, reveals a prominent low velocity zone (3.6–5.0 km/s) centered at Katmai Pass and extending from Mageik to Trident volcanoes. The anomaly has values about 20–25% slower than velocities outboard of the region (5.0–6.5 km/s). Moderately low velocities (4.5–6.0 km/s) are observed along the volcanic axis between Martin and Katmai Caldera. Griggs volcano, located about 10 km behind (northwest of) the volcanic axis, has unremarkable velocities (5.0–5.7 km/s) compared to non-volcanic regions. The highest velocities are observed between Snowy and Griggs volcanoes (5.5–6.5 km/s). Relocated hypocenters for the best 3-D model are shifted significantly relative to the standard model with clusters of seismicity at Martin volcano shifting systematically deeper by about 1 km to depths of 0 to 4 km below sea level. Hypocenters for the Katmai Caldera are more tightly clustered, relocating beneath the 1912 scarp walls. The relocated hypocenters allow us to compare spatial frequency-size distributions (b-values) using one-dimensional and three-dimensional models. We find that the distribution of b is significantly changed for Martin volcano, which was characterized by variable values (0.8 < b < 2.0) with standard locations and more uniform values (0.8 < b < 1.2) after relocation. Other seismic clusters at Mageik (1.2 < b < 2.2), Trident (0.5 < b < 1.5) and Katmai Caldera (0.8 < b < 1.8) had stable b-values indicating the robustness of the observations. The strong high b-value region at Mageik volcano is mainly associated with an earthquake swarm in October, 1996 that possibly indicates a shallow intrusion or influx of gas. The new velocity and spatial b-value results, in conjunction with prior gravity (Bouguer anomalies up to − 40 mgal) and interferometry (several cm uplift) data, provide strong evidence in favor of partially molten rock at shallow depths beneath the Mageik–Katmai–Novarupta region. Moderately low velocities beneath Martin and Katmai suggest that old, mostly solidified intrusions exist beneath these volcanoes. Higher relative velocities beneath the Griggs and Snowy vents suggest that no magma is resident in the shallow crust beneath these volcanoes.  相似文献   

16.
Nitrogen isotope values (δ15N) of surface sediments in the German Bight of the North Sea exhibit a significant gradient from values of 5–6‰ of the open shelf sea to values above 11‰ in the German Bight. This signal has been attributed to high reactive N (Nr) loading enriched in 15N from rivers and the atmosphere. To better understand the processes that determine the intensity and spatial distribution of δ15N anomalies in surface sediments, and to explore their usefulness for reconstructions of pristine N-input from rivers, we modeled the cycling of the stable isotopes 14N and 15N in reactive nitrogen through the ecosystem of the central and southern North Sea (50.9–57.3°N, 3.4°W−9.2°E) for the year 1995. The 3D-ecosystem model ECOHAM amended with an isotope-tracking module was validated by δ15N data of surface sediments within the model domain. A typical marine value (δ15Nnitrate=5‰) was prescribed for nitrate advected into the model domain at the seaside boundaries, whereas δ15Nnitrate of river inputs were those measured bi-monthly over 1 year; δ15N values of atmospheric deposition were set to 6‰ and 7‰ for NOx and NHy, respectively. The simulated δ15N values of different nitrogen compounds in the German Bight strongly depend on the mass transfers in the ecosystem. These fluxes, summarized in a nitrogen budget for 1995, give an estimate of the impacts of hydrodynamical and hydrological boundary conditions, and internal biogeochemical transformations on the nitrogen budget of the bight.  相似文献   

17.
As part of the ECOHAB: Florida Program, we studied three large blooms of the harmful bloom forming dinoflagellate Karenia brevis. These blooms formed on the West Florida Shelf during Fall of 2000 off Panama City, and during Fall 2001 and Fall 2002 off the coastline between Tampa Bay and Charlotte Harbor. We suggest that these blooms represent two different stages of development, with the 2000 and 2001 blooms in an active growth or maintenance phase and the 2002 bloom in the early bloom initiation phase. Each bloom was highly productive with vertically integrated primary production values of 0.47–0.61, 0.39–1.33 and 0.65 g C m−2 d−1 for the 2000, 2001 and 2002 K. brevis blooms, respectively. Carbon specific growth rates were low during each of these blooms with values remaining fairly uniform with depth corresponding to generation times of 3–5 days. Nitrogen assimilation by K. brevis was highest during 2001 with values ranging from 0.15 to 2.14 μmol N L−1 d−1 and lower generally for 2000 and 2002 (0.01–0.64 and 0.66–0.76 μmol N L−1 d−1 for 2000 and 2002, respectively). The highest K. brevis cell densities occurred during the 2001 bloom and ranged from 400 to 800 cells mL−1. Cell densities were lower for each of the 2000 and 2002 blooms relative to those for 2001 with densities ranging from 100 to 500 cells mL−1. The 2000 and 2001 blooms were dominated by K. brevis in terms of its contribution to the total chlorophyll a (chl a) pool with K. brevis accounting generally for >70% of the observed chl a. For those populations that were dominated by K. brevis (e.g. 2000 and 2001), phytoplankton C biomass (Cp,0) constituted <30% of the total particulate organic carbon (POC). However, in 2002 when diatoms and K. brevis each contributed about the same to the total chl a, Cp,0 was >72% of the POC. The fraction of the total chl a that could be attributed to K. brevis was most highly correlated with POC, chl a and salinity. Nitrogen assimilation rate and primary production were highly correlated with a greater correlation coefficient than all other comparisons.  相似文献   

18.
To clarify the sources and transformation of NO3− on the Pacific coast of Japan, observations over the continental shelf were conducted during the summer in 2005 and 2006 when the Kuroshio flowed close to and away from the coastal area, respectively. Below the halocline, there are two prominent salinity peaks that originated in two different waters. In the subsurface layer, the salinity maximum (Smax) was indicative of the Kuroshio Water (KW), while the salinity minimum (Smin) in the middle layer at ∼400 m depth was indicative of the North Pacific Intermediate Water (NPIW). δ15NNO3 ranged from 4.1‰ to 5.1‰ with a mean of 4.8±0.4‰ in the deeper water around Smin. Below 50 m depth over the shelf break, δ15NNO3 values (3.1±0.8‰ in 2005 and 4.6±0.3‰ in 2006) clearly increased as contribution of NPIW increased in 2006. On the contrary, subsurface δ15N of NO3− values (−1.1±0.1‰) remained unchanged in both years, although the contribution of the KW to the subsurface water changed significantly. This suggests that the source of NO3− has little effect on the δ15N of NO3− in this layer. The negative δ15N values also coincided with the base of the chlorophyll maximum layer suggesting that these isotopic signals must be evidence of active nitrification in the upper layer.  相似文献   

19.
The Donguinyó-Huichapan caldera complex is located 110 km to the NNW of Mexico City, in the central sector of the Mexican Volcanic Belt. It is a 10 km in diameter complex apparently with two overlapping calderas, each one related to an ignimbrite sequence that contrasts in composition, mineralogy, welding, distribution, and physical aspect. The geologic evolution of this complex includes the following phases, 1) A first caldera formed at 5.0 ± 0.3 Ma, with the eruption of several discrete pulses of andesitic to trachydacitic pyroclastic flows that produced a series of densely welded ignimbrites; 2) At 4.6 ± 0.3 Ma, several small shield volcanoes and cinder cones built the rim of this caldera and erupted basaltic-andesite and andesitic lava flows; 3) At 4.2 ± 0.2 Ma, a second caldera was formed associated to the eruption of the Huichapan Tuff, which is a rhyolitic pyroclastic sequence consisting of minor unwelded ignimbrites, pumice fall and surge deposits, and a voluminous welded ignimbrite; 4) Also yielding an age of 4.2 ± 0.2 Ma, several trachydacitic lava domes were extruded along the new ring fracture and formed the rim of the Huichapan caldera, as well as five intra-caldera domes of dacitic and trachydacitic composition. Peripheral volcanism includes a large 2.5 ± 0.1 Ma shield volcano that was emplaced on the Huichapan caldera rim.The two calderas that form the Donguinyó-Huichapan complex have contrasting differences in volcanic styles that were apparently due to their differences in composition. Products erupted by the Donguinyó caldera are basaltic-andesite to trachydacitic in composition, whereas Huichapan caldera products are all high-silica rhyolites.  相似文献   

20.
Semi-diurnal and fortnightly surveys were carried out to quantify the effects of wind- and navigation-induced high-energy events on bed sediments above intertidal mudflats. The mudflats are located in the upper fluvial part (Oissel mudflat) and at the mouth (Vasière Nord mudflat) of the macrotidal Seine estuary. Instantaneous flow velocities and mudflat bed elevation were measured at a high frequency and high resolution with an acoustic doppler velocimeter (ADV) and an ALTUS altimeter, respectively. Suspended particulate matter concentrations were estimated by calibrating the ADV acoustic backscattered intensity with bed sediments collected at the study sites. Turbulent bed shear stress values were estimated by the turbulent kinetic energy method, using velocity variances filtered from the wave contribution. Wave shear stress and maximum wave–current shear stress values were calculated with the wave–current interaction (WCI) model, which is based on the bed roughness length, wave orbital velocities and the wave period (TS). In the fluvial part of the estuary, boat passages occurred unevenly during the surveys and were characterized by long waves (TS>50 s) induced by the drawdown effect and by short boat-waves (TS<10 s). Boat waves generated large bottom shear stress values of 0.5 N m−2 for 2–5 min periods and, in burst of several seconds, larger bottom shear stress values up to 1 N m−2. At the mouth of the estuary, west south-west wind events generated short waves (TS<10 s) of HS values ranging from 0.1 to 0.3 m. In shallow-water environment (water depth <1.5 m), these waves produced bottom shear stress values between 1 and 2 N m−2. Wave–current shear stress values are one order of magnitude larger than the current-induced shear stress and indicate that navigation and wind are the dominant hydrodynamic forcing parameters above the two mudflats. Bed elevation and SPM concentration time series showed that these high energy events induced erosion processes of up to several centimetres. Critical erosion shear stress (τce) values were determined from the SPM concentration and bed elevation measurements. Rough τce values were found above 0.2 N m−2 for the Oissel mudflat and about 1 N m−2 for the Vasière Nord mudflat.  相似文献   

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