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1.
The Volcanic Sedimentary Complex (VSC) of the Iberian Pyrite Belt (IPB) in southern Portugal and Spain, comprises an Upper Devonian to Lower Carboniferous submarine succession with a variety of felsic volcanic lithofacies. The architecture of the felsic volcanic centres includes felsic lavas/domes, pyroclastic units, intrusions and minor mafic units that define lava–cryptodome–pumice cone volcanoes. The diversity of volcanic lithofacies recognized in different areas of the IPB mainly reflects variations in proximity to source, but also differences in the eruption style. The IPB volcanoes are intrabasinal, range in length from 2 km to > 8 km and their thickest sections vary from ∼ 400 m to > 800 m. These volcanoes are dominated by felsic lavas/domes that occur at several stratigraphic positions within the volcanic centre, however the pyroclastic units are also abundant and are spatially related to the lavas/domes. The intrusions are minor, and define cryptodomes and partly-extrusive cryptodomes. The hydrothermal systems that formed the Neves Corvo and Lousal massive sulfide ore deposits are associated with effusive units of felsic volcanic centres. At Neves Corvo, the massive sulfide orebodies are associated to rhyolitic lavas that overlie relatively thick fiamme-rich pyroclastic unit. In several other locations within the belt, pyroclastic units contain sulfide clasts that may have been derived from yet to be discovered coeval massive sulfide deposits at or below the sea floor, which enhances the exploration potential of these pyroclastic units and demonstrates the need for volcanic facies analysis in exploration.  相似文献   

2.
In this study are discussed new SEM-EDS analyses performed on glass shards from five cores collected in the Central Adriatic Sea and two cores recovered from the South Adriatic Sea. A total of 26 tephra layers have been characterized and compared with the geochemical features of terrestrial deposits and other tephra archives in the area (South Adriatic Sea and Lago Grande di Monticchio, Vulture volcano). The compositions are compatible with either a Campanian or a Roman provenance. The cores, located on the Central Adriatic inner and outer shelf, recorded tephra referred to explosive events described in the literature: AP3 (sub-Plinian activity of the Somma-Vesuvius, 2710 ± 60 14C years BP); Avellino eruption (Somma–Vesuvius, 3548 ± 129 14C years BP); Agnano Monte Spina (Phlegrean Fields, 4100 ± 400 years BP); Mercato eruption (Somma–Vesuvius, 8010 ± 35 14C years BP; Agnano Pomici Principali eruption (Phlegrean Fields, 10,320 ± 50 14C years BP); Neapolitan Yellow Tuff (Phlegrean Fields, 12,100 ± 170 14C years BP). Some of these layers were also observed in the South Adriatic core IN68-9 in addition to younger (AP2, sub-Plinian eruption, Somma–Vesuvius, 3225 ± 140 14C years BP), and older layers (Pomici di Base eruption, Somma–Vesuvius, 18,300 ± 150 14C years BP). Significant is the tephra record of core RF95-7 that, for the first time in the Adriatic Sea, reports the occurrence of tephra layers older than 60 ka: the well known Mediterranean tephra layers X2 (ca. 70 ka), W1 (ca. 140 ka) and V2 (Roman origin, ca. 170 ka) as well as other tephra layers attributed, on the basis of geochemistry and biostratigraphy, to explosive eruptions occurred at Vico (138 ± 2 and 151 ± 3 ka BP) and Ischia (147–140 ka BP).  相似文献   

3.
Chimborazo is a Late Pleistocene to Holocene stratovolcano located at the southwest end of the main Ecuadorian volcanic arc. It experienced a large sector collapse and debris avalanche (DA) of the initial edifice (CH-I). This left a 4 km wide scar, removing 8.0 ± 0.5 km3 of the edifice. The debris avalanche deposit (DAD) is abundantly exposed throughout the Riobamba Basin to the Río Chambo, more than 35 km southeast of the volcano. The DAD averages a thickness of 40 m, covers about 280 km2, and has a volume of > 11 km3. Two main DAD facies are recognized: block and mixed facies. The block facies is derived predominantly from edifice lava and forms > 80 vol.% of the DAD, with a probable volume increase of 15–25 vol.%. The mixed facies was essentially created by mixing brecciated edifice rock with substratum and is found mainly in distal and marginal areas. The DAD has clear surface ridges and hummocks, and internal structures such as jigsaw cracks, injections, and shear-zone features are widespread. Structures such as stretched blocks along the base contact indicate high basal shear. Substratum incorporation is directly observed at the base and is inferred from the presence of substratum-derived material in the DAD body. Based on the facies and structural interpretation, we propose an emplacement model of a lava-rich avalanche strongly cataclased before and/or during failure initiation. The flow mobilises and incorporates significant substrata (10–14 vol.%) while developing a fine lubricating basal layer. The substrata-dominated mixed facies is transported to the DAD interior and top in dykes invading previously-formed fractures.  相似文献   

4.
Previously unrecognized pulses of rhyolite volcanism occurred in the Salton Trough between 420 ± 8 ka and 479 ± 38 ka (2σ), based on high-spatial resolution U–Pb zircon geochronology. Presently, these rhyolite lavas, tuffs and shallow subvolcanic sills are buried to depths between ~ 1.6 and 2.7 km at ambient temperatures between 200 and 300 °C, and are overprinted by propylitic to potassic hydrothermal alteration mineral assemblages consisting of finely intergrown quartz, K-feldspar, chlorite, epidote, and minor pyrite. Alteration resistant geochemical indicators (whole-rock Nd-isotopes, zircon oxygen-isotopes) reveal that these rhyolites are derived from remelting of MORB-type crust that was chilled and hydrothermally altered by deep-circulating hydrothermal waters. U–Pb zircon dating confirms the presence of Bishop Tuff in well State 2-14 at ~ 1.7 km depth, approximately 5 km NE of the geothermal wells that penetrated the buried rhyolites. These results indicate accelerated subsidence towards the center of the Salton Trough, increasing from 2.2 mm/a to 3.8 mm/a. Based on these results, the present-day Salton Sea geothermal field is identified as a focus zone of episodic rhyolitic volcanism, intense heat flow and metamorphism that predates present-day geothermal activity and Holocene volcanism by at least ~ 400 ka.  相似文献   

5.
The Puyo scoria cones and the Mera lava flows, two newly recognized volcanic formations dated between Late Pliocene to Middle Pleistocene, extend the limits of the Ecuadorian rear-arc volcanic province some 100 km to the south. The Puyo scoria cones have erupted K-rich absarokites containing olivine, diopside and phlogopite, whereas the Mera lava flows display a basic andesite composition, with olivine and minor augite phenocrysts. In addition to high contents in LILE, LREE and HFSE, the Puyo absarokites exhibit many characteristics of primitive melts, namely high Cr (590–310 ppm) and Ni (330–154 ppm) contents, high Mg# (64–70) and they contain forsteritic olivine (Fo82–89). The composition of the most primary Puyo absarokite was used in petrogenetic models, in order to constrain the genesis of these high-K magmas. Major and trace elements models, as well as isotopic data, indicate that the source of Puyo magmas is a hydrated phlogopite- and garnet-bearing lherzolite. Phlogopite crystallization in the mantle wedge is triggered by the metasomatism by 3–5% of a SiO2-, H2O-rich liquid generated by slab melting. Partial melting of the subducted oceanic crust beneath Ecuador is allowed by the subduction of the young and warm Carnegie Ridge, which modifies the thermal regime of the Benioff zone. A low degree (1–4%) of partial melting of the metasomatized mantle wedge, leaving a variable garnet (4–7%) ± phlogopite (0–4%) lherzolitic residual assemblage, leads to the compositions of the entire Puyo absarokite series and is consistent with previous petrogenetic models developed for the Ecuadorian volcanic arc. Indeed, the homogeneity of isotopic data across the arc suggests a similar source for the whole Ecuadorian magmas.  相似文献   

6.
The inclination (I), declination (D) and total intensity (F) of the geomagnetic field were measured on Mount Etna in 1989-1991 at a dozen sites previously sampled for archeomagnetic studies. The purpose of the work was to determine the variations of these parameters at 30 cm above ground level, and how the distortion from the main field can affect the archeomagnetic record of volcanic rocks. Ten measurements were usually performed at each site with a three-component flux-gate magnetometer, whose estimated precision is ±0.2° on direction and ±50 nT on intensity. This was considered sufficient on volcanic areas with highly magnetized rocks and where the geomagnetic gradient may be in excess of 1000 nT/m. Results averaged for each site generally show small variations in intensity (±3% of the total field) and direction (±1.5°). The averaged values of the 12 sites (I=52.6°, D=0.3°, F=44010 nT) are very close to those measured in sedimentary terrain away from the volcano (I=52.9°, D=0.35°, F=44110 nT), themselves consistent with the interpolated IGRF in eastern Sicily. The largest deviations of the geomagnetic direction have been observed on four sites, three of them located on the South flank between 1900 and 700 m elevation. It is suggested that these anomalies are mainly related to dyke swarms which are common within the South Rift Zone of Mount Etna. Our findings show that reliable archeomagnetic results can be obtained from volcanic rocks, provided that lavas of the same eruption are sampled on several sites distributed over the largest possible area.  相似文献   

7.
Surface sediment and biota were collected from 12 sampling sites – seven along the Pearl River Delta and five along the Hong Kong coastline. Perfluorinated compound (PFC) concentrations were detected using a high-performance-liquid-chromatogram–tandem-mass-spectrometry system. Analytical results indicated that the total PFC concentrations were in the range of 0.15–3.11 ng/g dry weight in sediments, while the total PFC concentrations in oyster and mussel samples were between 0.46–1.96 and 0.66–3.43 ng/g wet weight, respectively. The major types of PFCs detected in the sediment samples were perfluorooctanesulfonic acid (PFOS) and perfluorobutanoic acid (PFBA), with concentrations ranging from low limits of quantification to 0.86 ± 0.12 ng/g dry weight and 1.50 ± 0.26 ng/g dry weight, respectively. In bivalve samples, PFOS was the dominant contaminant with concentrations ranging from 0.25 ± 0.09 to 0.83 ± 0.12 ng/g wet weight in oysters and 0.41 ± 0.14 to 1.47 ± 0.25 ng/g wet weight in mussels. An increase in PFC concentration was found to be correlated with increased human population density in the study areas.  相似文献   

8.
210Po and 210Pb in mussel (Mytilus galloprovincialis) and sediment samples collected at Candarl? Gulf during the period of 2010–2012 are presented and discussed. The activity concentrations of 210Po and 210Pb were measured by means of alpha spectrometry. Activity concentrations of 210Po and 210Pb in mussels are in the ranged of 332 ± 17–776 ± 23 Bq kg−1 dw and 14 ± 1–40 ± 5 Bq kg−1 dw, for sediments the ranges for 52 ± 5–109 ± 8 Bq kg−1 dw and 38 ± 5–92 ± 9 Bq kg−1 dw, respectively. The estimated consequent annual effective ingestion dose due to 210Po and 210Pb from mussel consumption in Candarl? Gulf coastal region were calculated. The highest dose due to 210Po and 210Po were calculated to be 4232 ± 126 μSv and 126 ± 16 μSv, respectively.  相似文献   

9.
The Mascota volcanic field is located in the Jalisco Block of western Mexico, where the Rivera Plate subducts beneath the North American Plate. It spans an area of ∼ 2000 km2 and contains ∼ 87 small cones and lava flows of minette, absarokite, basic hornblende lamprophyre, basaltic andesite, and andesite. There are no contemporary dacite or rhyolite lavas. New 40Ar/39Ar ages are presented for 35 samples, which are combined with nine dates from the literature to document the eruptive history of this volcanic field. The oldest lavas (2.4 to 0.5 Ma) are found in the southern part of the field area, whereas the youngest lavas (predominantly < 0.5 Ma) are found in the northern portion. On the basis of these ages, field mapping, and the use of ortho aerial photographs and digital elevation models, it is estimated that a combined volume of 6.8 ± 3.1 km3 erupted in the last 2.4 Myr, which leads to an average eruption rate of ∼ 0.003 km3/kyr, and an average volume per eruptive unit of < 0.1 km3. The dominant lava type is andesite (2.1 ± 0.9 km3), followed by absarokite (1.6 ± 0.8 km3), basaltic andesite (1.2 ± 0.5 km3), basic hornblende lamprophyre (1.0 ± 0.4 km3), and minette (0.9 ± 0.5 km3). Thus, the medium-K andesite and basaltic andesite comprise approximately half (49%) of the erupted magma, with twice as much andesite as basaltic andesite, and they occur in close spatial and temporal association with the highly potassic, lamprophyric lavas. There is no time progression to the type of magma erupted. A wide variety of evidence indicate that the high-MgO (8–9 wt.% ) basaltic andesites (52–53% wt.% SiO2) were formed by H2O flux melting of the asthenopheric arc mantle wedge, whereas the mafic minettes and absarokites were formed by partial melting (induced by thermal erosion) of depleted lithospheric mantle containing phlogopite-bearing veins. There is only limited differentiation of the potassic magmas, with none more evolved than 55.4 wt.% SiO2 and 4.4 wt.% MgO. This may be attributable to rapid crystallization of the mantle-derived melts in the deep crust, owing to their low volumes. Thus, the andesites (58–63 wt.% SiO2) are notable for being both the most voluminous and the most evolved of all lava types in the Mascota volcanic field, which is not consistent with their extraction from extensively crystallized (60–70%), low-volume intrusions. Instead, the evidence supports the origin of the andesites by partial melting of amphibolitized, mafic lower crust, driven by the emplacement of the minettes, absarokites, and the high-Mg basaltic andesites.  相似文献   

10.
The ages of most of calderas, large explosive craters and active volcanoes in the Kuril-Kamchatka region have been determined by extensive geological, geomorphological, tephrochronological and isotopic geochronological studies, including more than 600 14C dates. Eight Krakatoa-type and three Hawaiian-type calderas and no less than three large explosive craters formed here during the Holocene. Most of the Late Pleistocene Krakatoa-type calderas were established around 30 000–40 000 years ago. The active volcanoes are geologically very young, with maximum ages of about 40 000–50 000 years. The overwhelming majority of recently active volcanic cones originated at the very end of the Late Pleistocene or in the Holocene. These studies show that all Holocene stratovolcanoes in Kamchatka were emplaced in the Holocene only in the Eastern volcanic belt. Periods of synchronous, intensified Holocene volcanic activity occurred within the time intervals of 7500–7800 and 1300–1800 14C years BP.  相似文献   

11.
Cruises to Bering Strait and the Chukchi Sea in US waters from late June in 2002 to early September in 2004 and the Russian–American Long-term Census of the Arctic (RUSALCA) research cruise in 2004 covered all major water masses and contributed to a better understanding of the regional physics, nutrient dynamics, and biological systems. The integrated concentration of the high nitrate pool in the central Chukchi Sea was greater in this study than in previous studies, although the highest nitrate concentration (∼22 μM) in the Anadyr Water mass passing through the western side of Bering Strait was consistent with prior observations. The chlorophyll-a concentrations near the western side of the Diomede Islands ranged from 200 to 400 mg chl-a m−2 and the range in the central Chukchi Sea was 200–500 mg chl-a m−2 for the 2002–2004 Alpha Helix (HX) cruises. Chlorophyll-a concentrations for the 2004 RUSALCA cruise were lower than those from previous studies. The mean annual primary production of phytoplankton from this study, using a 13C–15N dual-isotope technique, was 55 g C m−2 for the whole Chukchi Sea and 145 g C m−2 for the plume of Anadyr–Bering Shelf Water in the central Chukchi Sea. In contrast, the averages of annual total nitrogen production were 13.9 g N m−2 (S.D.=±16.2 g N m−2) and 33.8 g N m−2 (S.D.=±14.1 g N m−2) for the Chukchi Sea and the plume, respectively. These carbon and nitrogen production rates of phytoplankton were consistently two-or three-fold lower than those from previous studies. We suggest that the lower rates in this study, and consequently more unused nitrate in the water column, were caused by lower phytoplankton biomass in the Bering Strait and the Chukchi Sea. However, we do not know if the lower rate of production from this study is a general decreasing trend or simply temporal variations in the Chukchi Sea, since temporal and geographical variations are substantially large and presently unpredictable.  相似文献   

12.
The three-dimensional P-wave velocity structure beneath the Katmai group of volcanoes is determined by inversion of more than 10,000 rays from over 1000 earthquakes recorded on a local 18 station short-period network between September 1996 and May 2001. The inversion is well constrained from sea level to about 6 km below sea level and encompasses all of the Katmai volcanoes; Martin, Mageik, Trident, Griggs, Novarupta, Snowy, and Katmai caldera. The inversion reduced the average RMS travel-time error from 0.22 s for locations from the standard one-dimensional model to 0.13 s for the best three-dimensional model. The final model, from the 6th inversion step, reveals a prominent low velocity zone (3.6–5.0 km/s) centered at Katmai Pass and extending from Mageik to Trident volcanoes. The anomaly has values about 20–25% slower than velocities outboard of the region (5.0–6.5 km/s). Moderately low velocities (4.5–6.0 km/s) are observed along the volcanic axis between Martin and Katmai Caldera. Griggs volcano, located about 10 km behind (northwest of) the volcanic axis, has unremarkable velocities (5.0–5.7 km/s) compared to non-volcanic regions. The highest velocities are observed between Snowy and Griggs volcanoes (5.5–6.5 km/s). Relocated hypocenters for the best 3-D model are shifted significantly relative to the standard model with clusters of seismicity at Martin volcano shifting systematically deeper by about 1 km to depths of 0 to 4 km below sea level. Hypocenters for the Katmai Caldera are more tightly clustered, relocating beneath the 1912 scarp walls. The relocated hypocenters allow us to compare spatial frequency-size distributions (b-values) using one-dimensional and three-dimensional models. We find that the distribution of b is significantly changed for Martin volcano, which was characterized by variable values (0.8 < b < 2.0) with standard locations and more uniform values (0.8 < b < 1.2) after relocation. Other seismic clusters at Mageik (1.2 < b < 2.2), Trident (0.5 < b < 1.5) and Katmai Caldera (0.8 < b < 1.8) had stable b-values indicating the robustness of the observations. The strong high b-value region at Mageik volcano is mainly associated with an earthquake swarm in October, 1996 that possibly indicates a shallow intrusion or influx of gas. The new velocity and spatial b-value results, in conjunction with prior gravity (Bouguer anomalies up to − 40 mgal) and interferometry (several cm uplift) data, provide strong evidence in favor of partially molten rock at shallow depths beneath the Mageik–Katmai–Novarupta region. Moderately low velocities beneath Martin and Katmai suggest that old, mostly solidified intrusions exist beneath these volcanoes. Higher relative velocities beneath the Griggs and Snowy vents suggest that no magma is resident in the shallow crust beneath these volcanoes.  相似文献   

13.
We report new palaeointensity results concerning the Auckland geomagnetic excursions using the double heating technique of the Shaw method with low temperature demagnetisation (LTD-DHT Shaw method). The excursional palaeodirections recorded in six volcanoes of the Auckland volcanic field, New Zealand, have been classified into three groups: north-down (ND), west-up (WU) and south-up (SU) directions. In the present study, five to six consistent palaeointensities have been obtained from each of five volcanoes recording the Auckland geomagnetic excursions. The Wiri (27 ka), Crater Hill and Puketutu volcanoes (ND group) yielded mean palaeointensities of 10.6 ± 1.2 (1σ), 11.8 ± 2.8 and 11.1 ± 0.4 μT, respectively. The Hampton Park volcano (55 ka; WU group) gave 9.5 ± 1.2 μT while the McLennan Hills volcano (SU group) gave 2.5 ± 0.5 μT. It is notable that consistent palaeointensities have been obtained from the three different volcanoes which have almost the same palaeodirections (ND group), possibly supporting the reliability of the palaeointensity data. These five palaeointensities for the Auckland geomagnetic excursions correspond to virtual dipole moments (VDMs) of 0.6-2.1 × 1022 A m2, whereas three mean palaeointensities obtained from the Auckland volcanoes having non-excursional palaeodirections are 13.1-40.0 μT giving stronger VDMs of 2.1-6.9 × 1022 A m2. These results suggest that the dipole component of the geomagnetic field reduced to about 2 × 1022 A m2 or less during the Auckland geomagnetic excursions.  相似文献   

14.
How soil erosion rates evolved over the last about 100 ka and how they relate to environmental and climate variability is largely unknown. This is due to a lack of suitable archives that help to trace this evolution. We determined in situ cosmogenic beryllium-10 (10Be) along vertical landforms (tors, boulders and scarps) on the Sila Massif to unravel their local exhumation patterns to develop a surface denudation model over millennia. Due to the physical resistance of tors, their rate of exhumation may be used to derive surface and, thus, soil denudation rates over time. We derived soil denudation rates that varied in the range 0–0.40 mm yr-1. The investigated boulders, however, appear to have experienced repositioning processes about ~20–25 ka bp and were therefore a less reliable archive. The scarps of the Sila upland showed a rapid bedrock exposure within the last 8–15 ka. Overall, the denudation rates increased steadily after 75 ka bp but remained low until about 17 ka bp . The exhumation rates indicate a denudation pulse that occurred about 17–5 ka bp . Since then the rates have continuously decreased. We identify three key factors for these developments – climate, topography and vegetation. Between 75 and 17 ka bp , climate was colder and drier than today. The rapid changes towards warmer and humid conditions at the Pleistocene–Holocene transition apparently increased denudation rates. A denser vegetation cover with time counteracted denudation. Topography also determined the extent of denudation rates in the upland regime. On slopes, denudation rates were generally higher than on planar surfaces. By determining the exhumation rates of tors and scarps, soil erosion rates could be determined over long timescales and be related to topography and particularly to climate. This is key for understanding geomorphic dynamics under current environmental settings and future climate change. © 2019 John Wiley & Sons, Ltd. © 2019 John Wiley & Sons, Ltd.  相似文献   

15.
Six sediment cores collected at four contaminated river mouths and two harbor entrances in Kaohsiung Harbor (Taiwan) were analyzed to evaluate the sources and potential toxicity of polycyclic aromatic hydrocarbons (PAHs). PAHs presented the wide variations ranging from 369 ± 656 to 33,772 ± 14,378 ng g−1 at the six sampling sites. The composition of PAHs presented a uniform profile reflecting the importance of atmospheric input from vehicle exhausts or coal combustion in the river mouths. PAHs diagnostic ratios indicated a stronger influence of coal combustion in the Salt River mouth and the prevalence of petroleum combustion and mixed sources in the other rivers and harbor entrances. PAHs toxicity assessment using the mean effect range-median quotient (m-ERM-q: 0.011–1.804), benzo[a]pyrene-toxicity equivalent (TEQcarc: 22–2819 ng TEQ g−1), and dioxin-toxicity equivalent (TEQfish: 37–5129 pg TEQ g−1) identified the Salt River mouth near the industrial area of the harbor as the most affected area.  相似文献   

16.
Stratification (throughout the year) and low solar radiation (during monsoon periods) have caused low chlorophyll a and primary production (seasonal average 13–18 mg m−2 and 242–265 mg C m−2 d−1, respectively) in the western Bay of Bengal (BoB). The microzooplankton (MZP) community of BoB was numerically dominated by heterotrophic dinoflagellates (HDS) followed by ciliates (CTS). The highest MZP abundance (average 665±226×104 m−2), biomass (average 260±145 mg C m−2) and species diversity (Shannon weaver index 2.8±0.42 for CTS and 2.6±0.35 for HDS) have occurred during the spring intermonsoon (SIM). This might be due to high abundance of smaller phytoplankton in the western BoB during SIM as a consequence of intense stratification and nitrate limitation (nitracline at 60 m depth). The strong stratification during SIM was biologically evidenced by intense blooms of Trichodesmium erythraeum and frequent Synechococcus–HDS associations. The high abundance of smaller phytoplankton favors microbial food webs where photosynthetic carbon is channeled to higher trophic levels through MZP. This causes less efficient transfer of primary organic carbon to higher trophic levels than through the traditional food web. The microbial food web dominant in the western BoB during SIM might be responsible for the lowest mesozooplankton biomass observed (average 223 mg C m−2). The long residence time of the organic carbon in the surface waters due to the active herbivorous pathways of the microbial food web could be a causative factor for the low vertical flux of biogenic carbon during SIM.  相似文献   

17.
The anti-microbial agent triclosan (TCS), and its derivative methyl-triclosan (Me-TCS), are discharged with treated effluents from wastewater treatment plants to receiving environments. We investigated the bioconcentration of TCS and Me-TCS in mussels (Mytilus galloprovincialis) exposed to TCS (100 ng L−1) for 30 days in seawater aquaria (19 ± 2 °C) with fresh phytoplankton as a food source. Bioconcentration increased with time reaching a steady-state around 24–30 days. The bioconcentration factor (log BCF) for TCS were 2.81 L kg−1 (dry weight) and 4.13 L kg−1, when lipid normalised concentrations were used. Mussels were also deployed in cages at four marine locations receiving effluents from WWTPs. The mean (±SD) TCS and Me-TCS concentrations for mussels from these sites were 9.87 (±1.34) and 6.99 (±2.44) μg kg−1. The study showed that mussels can be a useful tool for monitoring pollution of TCS and Me-TCS in marine and estuarine environments.  相似文献   

18.
The Galilee study area, northern Israel, is at present an uplifted, steep continental margin that formed mainly during the Jurassic and has a large positive isostatic anomaly. Since the Jurassic, it was modified by several tectonomagmatic events, which this study attempts to define and classify by updating, reprocessing and reinterpreting gravity, aeromagnetic and geological data. The prominent Rehovot-Carmel N–S positive reduced-to-pole (RTP) magnetic anomaly caused by the Gevim Volcanics, as well as the coexisting Helez-Gaash high Bouguer gravity and the Pleshet low Bouguer gravity, represent the deep (>5 km) Permo-Triassic dominant horst and graben structure of Israel. The Jonah Ridge and Beirut high SW–NE RTP magnetic anomalies in the Levant basin delineate the Levant continental edge that is marked by a deeply buried horst covered by a Late Cretaceous volcanic complex. The Asher and Devora Jurassic volcanics appear to be responcible for the Atlit and Galilee negative magnetic anomalies and for significant negative gravity anomalies which became clear after removing gravity effect of the upper (post-Turonian) light density sediments from the observed gravity. The volcanics extend along a SW–NE belt parallel to the strike of the Moho. It is suggested here that the Carmel-Gilboa fault propagated during the Late Cretaceous from the Levant basin across the Galilee area southeastward to form the Azraq-Sirhan graben in Jordan. As such, it forms a right-step, en echelon, dextral strike-slip fault with associated tectonic basins of various shapes. During the Oligocene and before formation of the Dead Sea transform (DST), the reactivation of the Azraq-Sirhan graben was accompanied by tectonic driven rift propagation in the opposite direction, from Azraq-Sirhan to northwest. It dispersed into many faults and terminated ∼10 km west of the present DST. During the Miocene it propagated in the same direction and includes internal volcanic activity. The numerous Miocene-Pliocene volcanic centers on the margins of the DST indicate that the preferred pathway for magmas at that time was not within the deep basins of the DST.  相似文献   

19.
Heat transfer coefficients used in numerical simulations of volcanic eruptions are typically borrowed from industrial settings where the coefficients are well determined for non-permeable, machined (spherical) materials. Volcanic clasts, in contrast, are permeable and have irregular shapes. We performed a series of laboratory experiments to determine heat transfer coefficients for natural volcanic particles. We measured the surface and interior temperatures during cooling at wind speeds ranging from 0 to 10 m/s. We also measured the permeability and density of the particles. We find that the permeability of the particles has little effect on clast cooling. In the absence of any wind, heat loss occurs by free convection, and we find no relationship between the heat transfer coefficient and particle density. However, for non-zero Reynolds numbers (finite wind speed), the heat transfer coefficient decreases with increasing porosity. We obtain a correlation for the dimensionless heat loss, or Nusselt number, of the form Nu = 2 + aRe1/2Pr1/3 where a is a density dependent coefficient given by a = 0.00022ρ + 0.31, with ρ in kg/m3, and Re and Pr are the Reynolds number and Prandtl number, respectively. Compared with non-porous particles, heat transfer coefficients for natural pumice clasts are reduced by a factor of 2–3 for particles with similar Re. Numerical simulations show that this leads to an increase in depositional temperature by 50–90 °C.  相似文献   

20.
The metabolic balance between production and respiration in plankton communities of the Gulf of Papua was investigated in May 2004. Water samples taken at 19 stations were allocated to groups on the basis of physico-chemical characteristics. Oxygen consumption and production in flasks incubated in the dark and in the light was determined by micro-Winkler titration. Dark bottle respiration in samples influenced by the estuarine plume averaged 3.09±1.92 (SD) mmol O2 m−3 d−1 and production within surface light bottles averaged 7.63±3.36 (SD)  mmol O2 m−3 d−1. Corresponding values in stations more typical of the central Gulf of Papua were 1.68±1.30 (SD) mmol O2 m−3 d−1 and 1.08±2.25 (SD) mmol O2 m−3 d−1. Despite a shallow (<10 m) euphotic zone within the plume stations, phytoplankton production in the surface layers was sufficiently high to subsidise total water column respiration. Integrating production and respiration over the water column resulted in a calculation of net community production (NCP) of 626±504 (SD) mg C m−2 d−1, and community respiration (CR) of 712±492 mg C m−2 d−1 at the plume stations, with an average P:R ratio of 1.97. In the offshore group NCP was 157±450 (SD) mg C m−2 d−1 and CR was 1620±1576 mg C m−2 d−1. The average P:R ratio was 1.27. Three of the 7 stations allocated to the offshore group were net heterotrophic. In contrast to earlier studies in the area indicating that the Gulf of Papua waters is heterotrophic [Robertson, A.I., Dixon, P., Alongi, D.M., 1998. The influence of fluvial discharge on pelagic production in the Gulf of Papua, Northern Coral Sea. Estuarine, Coastal and Shelf Science 46, 319–331], our data indicate that in May 2004 the Gulf was in positive metabolic balance, but by only ∼120 mg C m−2 d−1. We conclude that waters of the Gulf of Papua under riverine influence are net autotrophic, but that within the central Gulf there is a fine metabolic balance alternating between autotrophy and heterotrophy.  相似文献   

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