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1.
The Middle–Upper Jurassic succession of the Marguareis–Mongioie area (Ligurian Briançonnais Domain), developed in a protected shelf environment evolving into a pelagic plateau, bears clear evidence of synsedimentary tectonics such as: growth fault-related structures; neptunian dykes; marked lateral variations in stratigraphic thicknesses testifying to the juxtaposition of sectors characterized by different sedimentation and subsidence rates; discordant, anomalous stratigraphic contacts corresponding to paleoescarpments; nodular beds showing evidence of fluidification interpreted as seismites; and the occurrence of sand-sized quartz grains pointing to denudation of Permo-Triassic quartz-rich rocks. Such evidence documents an important Middle-Late Jurassic post-breakup tectonic activity, which was more effective in controlling the basin topography than the Early Jurassic syn-rift tectonic phase. Two main tectono-sedimentary stages, one occurring during the Bathonian, the other falling within the Callovian–Kimmeridgian interval, were reconstructed. The first stage can be referred to a fault-related activity occurring shortly after the initial stages of oceanic spreading of the Ligurian Tethys; the second can be genetically related to the far effects of the first rifting stage of the Bay of Biscay and the Valais basin.  相似文献   

2.
The Bracco–Gabbro Complex (Internal Liguride ophiolite), that intruded subcontinental mantle peridotite, contains layers of chromitite that are associated with ultramafic differentiates. The chromitites and disseminated chromites in the ultramafics have Al contents similar to the Al-rich podiform chromitites [0.40 < Cr# = Cr/(Cr + Al) < 0.55]. TiO2 contents of the chromitites are unusually high and range up to 0.82 wt%. The calculated Al2O3 and TiO2 content of the parental melt suggest that the melt was a MORB type. Geothermobarometrical calculations on few preserved silicate inclusions revealed formation temperatures between 970 and 820 °C under a relatively high oxygen fugacity (ΔlogfO2 at +2.0–2.4). Chromitites were altered during the post-magmatic tectono-metamorphic uplift and the final exposure at the seafloor, as evidenced by the formation of ferrian chromite. The PGE contents of the chromitites and associated ultramafics are unusually low (PGEmax 83 ppb). The chondrite-normalized PGE spidergrams show positive PGE patterns and to some extent similarities with the typical trend of stratiform chromitites. No specific PGM have been found but low concentrations of PPGE (Rh, Pt, and Pd) have been detected in the sulphides that occur interstitially to or enclosed in chromite. Recently, it has been shown that the Internal Liguride gabbroic intrusions have formed by relatively low degrees of partial melting of the asthenospheric mantle. We conclude that the low degree of partial melting might be the main factor to control the unusual low PGE contents and the rather unique PGE distribution in the Bracco chromitites.  相似文献   

3.
《Applied Geochemistry》2002,17(8):1081-1092
Different types of fine-grained chemical precipitates were characterized in the surroundings of the pyrite-chalcopyrite mine of Libiola (Northern Italy). Both water chemistry and sediment composition were used to investigate metal mobility near the mine area. Local drainage waters were very acidic (with a pH as low as 2.5) and were rich in dissolved metals (Fe, Al, Cu, Zn, Mn, Ni). Sediments associated with low pH water (pH <4.5) were ochreous mixtures of schwertmannite and goethite with traces of jarosite. Their chemistry was dominated by Fe and they had, compared to other sediments investigated, low concentrations of other metals. When the acidity decreased gradually, other precipitates formed. At a pH of approximately 5, a poorly crystalline, whitish, Al-rich precipitate occurred. At a pH between 6 and 7, a poorly crystalline, blue, Cu (Zn) rich phase was present. These “sequential” precipitation events progressively reduced the metal loading typical of the acidic mine water when there was a gradual mixing with normal water. When a sudden mixing between normal waters (pH ∼8, Ca–HCO3, low metal bearing) and acidic waters took place, a rapid flocculation occurred of mixed precipitates containing Fe, Al and trace elements.  相似文献   

4.
Slow–ultraslow spreading oceans are mostly floored by mantle peridotites and are typified by rifted continental margins, where subcontinental lithospheric mantle is preserved. Structural and petrologic investigations of the high-pressure (HP) Alpine Voltri Massif ophiolites, which were derived from the Late Jurassic Ligurian Tethys fossil slow–ultraslow spreading ocean, reveal the fate of the oceanic peridotites/serpentinites during subduction to depths involving eclogite-facies conditions, followed by exhumation.

The Ligurian Tethys was formed by continental extension within the Europe–Adria lithosphere and consisted of sea-floor exposed mantle peridotites with an uppermost layer of oceanic serpentinites and of subcontinental lithospheric mantle at the rifted continental margins. Plate convergence caused eastward subduction of the oceanic lithosphere of the Europe plate and the uppermost serpentinite layer of the subducting slab formed an antigorite serpentinite-subduction channel. Sectors of the rather unaltered mantle lithosphere of the Adria extended margin underwent ablative subduction and were detached, embedded, and buried to eclogite-facies conditions within the serpentinite-subduction channel. At such P–T conditions, antigorite serpentinites from the oceanic slab underwent partial HP dehydration (antigorite dewatering and growth of new olivine). Water fluxing from partial dehydration of host serpentinites caused partial HP hydration (growth of Ti-clinohumite and antigorite) of the subducted Adria margin peridotites. The serpentinite-subduction channel (future Beigua serpentinites), acting as a low-viscosity carrier for high-density subducted rocks, allowed rapid exhumation of the almost unaltered Adria peridotites (future Erro–Tobbio peridotites) and their emplacement into the Voltri Massif orogenic edifice. Over in the past 35 years, this unique geologic architecture has allowed us to investigate the pristine structural and compositional mantle features of the subcontinental Erro–Tobbio peridotites and to clarify the main steps of the pre-oceanic extensional, tectonic–magmatic history of the Europe–Adria asthenosphere–lithosphere system, which led to the formation of the Ligurian Tethys.

Our present knowledge of the Voltri Massif provides fundamental information for enhanced understanding, from a mantle perspective, of formation, subduction, and exhumation of oceanic and marginal lithosphere of slow–ultraslow spreading oceans.  相似文献   

5.
In recent years, the high incidence of harmful health effects through inhalation of airborne asbestos from amphibole-bearing rock mélanges has been thoroughly documented. Here, we present a field-based, multi-scale geological approach aimed at illustrating the occurrence of amphibole fibrous mineralisation in an ophiolitic suite from the Ligurian Alps (Italy) and discussing the implication on in situ determination of the asbestos hazard. The rock mélange is composed of plurimetre-sized blocks of different lithotypes (metagabbro, serpentinite, chloritoschist) juxtaposed by the meaning of tectonic structures. The geological-structural survey revealed that the fibrous mineralisation is localised in specific structural sites of the rock volume, including veins and schistosity. Both micro-chemical and crystal structure analyses on selected fibrous samples revealed that actinolite fibres grow in veins within the metagabbro and in chloritoschists, while fibrous tremolite occurs in serpentinite schistosity. The morphological features of these amphibole fibres have been analysed in TEM images and used for classifying them as “asbestiform” or “non-asbestiform”. The results show that the asbestos hazard determination is not unequivocally identified when different procedures for asbestos fibre identification and classification are applied. This may have impact on normatives and regulations in defining environmental hazards due to asbestos occurrence.  相似文献   

6.
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7.
Geological mapping coupled with structural investigations carried out in the Voltri Massif (eastern Ligurian Alps, Italy) provide new data for the interpretation of the tectonic context controlling main fabric development during exhumation of its high-pressure core. The Voltri Massif is here interpreted as a c. 30 km-long eclogite-bearing, asymmetric dome formed by the progressive verticalisation of the regional, second-phase mylonitic foliation developed during retrogressive greenschist metamorphic conditions. In this light, the exhumation history is driven by a ductile-to-brittle extensional process, operating through low-angle, top-to-the-W multiple detachment systems. A Late Eocene–Early Oligocene age for this extensional episode is proposed on the basis of structural correlations, stratigraphic and radiometric constraints. In this scenario, the Voltri Massif is interpreted as an extensional domain developed to accommodate the Late Eocene–Early Oligocene arching of the Western Alps–Northern Apennines orogenic system.  相似文献   

8.
In the Northern Apennines of Italy, mud-rich olistostromes (sedimentary mélanges) occur at different stratigraphic levels within the late Oligocene–early Miocene sedimentary record of episutural/wedge-top basins. They are widely distributed along the exhumed outer part of the Ligurian accretionary complex, atop the outer Apenninic prowedge, over an area about 300 km long and 10–15 km wide. Olistostromes represent excellent examples of ancient submarine mass-transport complexes (MTCs), consisting of stacked cohesive debris flows that can be directly compared to some of those observed in modern accretionary wedges. We describe the internal arrangement of olistostrome occurrences in the sector between Voghera and the Monferrato area, analysing their relationships with mesoscale liquefaction features, which are commonly difficult to observe in modern MTCs. Slope failures occurred in isolated sectors along the wedge front, where out-of-sequence thrusting, seismicity, and different pulses of overpressured tectonically induced fluid flows acted concomitantly. Referring to the Northern Apennines regional geology, we also point out a gradual lateral rejuvenation (from late Oligocene to early Miocene) toward the SE and an increasing size and thickness of the olistostromes along the strike of the frontal Apenninic prowedge. This suggests that morphological reshaping of the outer prowedge via mass-transport processes balanced, with different pulses over a short time span, the southeastward migration and segmentation of accretionary processes. The latter were probably favoured by the occurrence in the northwestern part of the Northern Apennines of major, inherited palaeogeographic features controlling the northward propagation of the prowedge. Detailed knowledge of olistostromes, as ancient examples of MTCs related to syn-sedimentary tectonics and shale diapirism, and of their lateral variations in term of age and size, provides useful information in regard to better understanding of both the tectono-stratigraphic evolution of the Apenninic prowedge and the submarine slope failures in modern accretionary wedges.  相似文献   

9.
Analyses were made of samples of the several classes of iron meteorites: (hexahedrites, octahedrites, ataxites, and troilite inclusions) in further study of the isotopic composition of primordial lead and toward establishing correlation between the distribution of lead among the mineral inclusions and the nickel-iron mass of the meteorite. Two groups of iron meteorites can be distinguished on the basis of isotopic composition lead suggesting two ages for the parent bodies of common iron meteorites. The distribution of lead in iron meteorites ranges markedly but no relation could be found between isotopic composition of lead and the several structures and compositions. The content of lead in troilites are one or two orders of magnitude higher than in the nickel-iron phase.-- M. Russell.  相似文献   

10.
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