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1.
The Es3L (lower sub-member of the third member of the Eocene Shahejie Formation) shale in the Jiyang Depression is a set of relatively thick and widely deposited lacustrine sediments with elevated organic carbon, and is considered to be one of the most important source rocks in East China. We can determine the mineralogy, organic and inorganic geochemistry of the Es3L shale and calculate paleoclimate indexes by using multiple geochemical proxies based on organic chemistry (total organic carbon [TOC] and Rock-Eval pyrolysis), major and trace elements, X-Ray diffraction, and carbon and oxygen isotope data from key wells alongside ECS (Elemental Capture Spectroscopy) well log data. These indicators can be used to analyze the evolution of the paleoenvironment and provide a mechanism of organic matter (OM) accumulation. The Es3L oil shale has high TOC abundance (most samples >3.0%) and is dominated by Type I kerogens. Additionally, the organic-rich shale is rich in CaO and enrichment in some trace metals is present, such as Sr, Ba and U. The positive δ13C and negative δ18O values, high Sr/Ba, B/Ga and Ca/Ca + Fe ratios and low C/S ratios indicate that the Es3L shales were mainly deposited in a semi-closed freshwater-brackish water lacustrine environment. The consistently low Ti/Al and Si/Al ratios reflect a restricted but rather homogeneous nature for the detrital supply. Many redox indicators, including the Th/U, V/(V + Ni), and δU ratios, pyrite morphology and TOC-TS-Fe diagrams suggest deposition under dysoxic to suboxic conditions. Subsequently, the brackish saline bottom water evolved into an anoxic water body under a relatively arid environment, during which organic-lean marls were deposited in the early stage. Later, an enhanced warm-humid climate provided an abundant mineral nutrient supply and promoted the accumulation of algal material. OM input from algal blooms reached a maximum during the deposition of the organic-rich calcareous shale with seasonal laminations. High P/Ti ratios and a strongly positive relationship between the P and TOC contents indicate that OM accumulation in the oil shale was mainly controlled by the high primary productivity of surface waters with help from a less stratified water column. Factors such as the physical protection of clay minerals and the dilution of detrital influx show less influence on OM enrichment. 相似文献
2.
In order to understand the paleoenvironment of the Early Cambrian black shale deposition in the western part of the Yangtze Block, geochemical and organic carbon isotopic studies have been performed on two wells that have drilled through the Qiongzhusi Formation in the central and southeastern parts of Sichuan Basin. It shows that the lowest part of the Qiongzhusi Formation has high TOC abundance, while the middle and upper parts display relative low TOC content. Redox-sensitive element (Mo) and trace elemental redox indices (e.g., Ni/Co, V/Cr, U/Th and V/(V + Ni)) suggest that the high-TOC layers were deposited under anoxic conditions, whereas the low-TOC layers under relatively dysoxic/oxic conditions. The relationship of the enrichment factors of Mo and U further shows a transition from suboxic low-TOC layers to euxinic high-TOC layers. On the basis of the Mo-TOC relationship, the Qiongzhusi Formation black shales were deposited in a basin under moderately restricted conditions. Organic carbon isotopes display temporal variations in the Qiongzhusi Formation, with a positive excursion of δ13Corg values in the lower part and a continuous positive shift in the middle and upper parts. All these geochemical and isotopic criteria indicate a paleoenvironmental change from bottom anoxic to middle and upper dysoxic/oxic conditions for the Qiongzhusi Formation black shales. The correlation of organic carbon isotopic data for the Lower Cambrian black shales in different regions of the Yangtze Block shows consistent positive excursion of δ13Corg values in the lower part for each section. This excursion can be ascribed to the widespread Early Cambrian transgression in the Yangtze Block, under which black shales were deposited. 相似文献
3.
《Marine and Petroleum Geology》2012,36(1):252-268
Detailed bulk geochemistry and organo-petrography of outcrop Cretaceous sediments (with no significant effects of weathering) from the Calabar Flank, southeast Nigeria were performed to understand the organic carbon source, accumulation and degradation, and paleo-climatic, paleoceanographic and paleoenvironmental conditions in West Africa during Early Cretaceous (Aptian) to Maastrichtian times. This study was based on microscopic, elemental analyses (organic carbon, nitrogen, iron and sulphur), Rock-eval pyrolysis and carbon-isotope analyses. In general, the Calabar Flank shales are characterised by highly variable total organic carbon (TOC) contents, which range between 0.1% in Aptian–Albian Mfamosing Limestone and 9.9% in the Awi Formation sediments. The organic matter (OM) is a mixture of immature to early-mature marine and terrigenous OM of types III and IV. This is indicated by low hydrogen indices (HI value (10–190 mg HC/g TOC), Tmax (417–460 °C), vitrinite reflectance %Ro (0.39–0.62 %Ro), low to high C/N ratios (3.4–1158.0) and high amounts of terrigenous macerals (vitrinite + inertinite). Based on carbon isotope, C/N ratios and sulphate reduction index (SRI), OM degradation (up to 70%, SRI > 2.5) is most pronounced for shales deposited in a marine environment. The geochemical and petrographic data indicate that local factors such as low bioproductivity, down slope transport and redeposition of sediments from a fluvial–deltaic basin to nearshore facies, shallower, oxic and mildly oxygen-deficient environments, humid–arid paleogeographic conditions, specifically controlled the amount and quality of the OM during Aptian–Mastrichtian stages where marine sediments have been assumed to be deposited during the global anoxic events. Therefore, the order of the main factors controlling OM content in sediments are: input of terrigenous material transported from the land > low OM productivity by marine photoautotrophs > low preservation. 相似文献
4.
Barremian–Aptian organic-rich shales from Abu Gabra Formation in the Muglad Basin were analysed using geochemical and petrographic analyses. These analyses were used to define the origin, type of organic matters and the influencing factors of diagenesis, including organic matter input and preservation, and their relation to paleoenvironmental and paleoclimate conditions. The bulk geochemical characteristics indicated that the organic-rich shales were deposited in a lacustrine environment with seawater influence under suboxic conditions. Their pyrolysis hydrogen index (HI) data provide evidence for a major contribution by Type I/II kerogen with HI values of >400 mg HC/g TOC and a minor Type II/III contribution with HI values <400 mg HC/g TOC. This is confirmed by kerogen microscopy, whereby the kerogen is characterized by large amounts of structured algae (Botryococcus) and structureless (amorphous) with a minor terrigenous organic matter input. An enhanced biological productivity within the photic zone of the water columns is also detected. The increased biological productivity in the organic-rich shales may be related to enhanced semi-arid/humid to humid-warm climate conditions. Therefore, a high bio-productivity in combination with good organic matter preservation favoured by enhanced algae sizes are suggested as the OM enrichment mechanisms within the studied basin. 相似文献
5.
The lacustrine black shales in the Chang7 Member from the Upper Triassic Yanchang Formation of the Ordos Basin in Central China are considered one of the most important hydrocarbon source rocks. However, the mechanism of organic accumulation in the black shales remains controversial. To resolve the controversy, with the former paleontological data of Yanchang Formation and sedimentation rate data of the Chang7 black shales, we investigated the typical intervals of the Chang7 black shales (TICBS) which were obtained by drilling in Yaowan at the southern margin of the Ordos Basin and performed various sedimentary, isotopic and geochemical analysis, including the sedimentary petrography, pyrite morphology, total organic carbon (TOC) and total sulfur (TS), the ratio of pyritic Fe to total Fe (DOPT), major and trace elements, together with pyritic sulfur isotopes (δ34Spy). The high sulfur content, enrichment of redox-sensitive trace metals, and the lower sedimentation rate of the TICBS in addition to the presence of marine spined acritarchs and coelacanth fossils indicate that the TICBS were deposited in a lacustrine environment possibly influenced by seawater. The petrographic observations show a thick layer of black shale with interlayers of thin layered siltstone (silty mudstone) and laminated tuff, which were related to the turbidity currents and volcanism, respectively. The U/Th, C-S, and Mo-U covariations, pyrite morphology, DOPT, combined with the δ34Spy, suggest that the deposition occurred beneath the anoxic-sulfidic bottom waters, which was intermittently influenced by the oxygen-containing turbidity. The Ni/Al and Cu/Al possibly show extremely high to high primary productivity in the water column, which might be connected with the substantial nutrients input from seawater or frequently erupted volcanic ash entering the lake. In addition, the coincidence of an increased abundance of TOC with increased P/Al, Ni/Al, Cu/Al and U/Th, as well as relatively consistent Ti/Al suggest that the accumulation of the organic matter might be irrelevant to the clastic influx, and was mainly controlled by the high primary productivity and anoxic-sulfidic conditions. Further, the covariations of TOC vs. P/Al and TOC vs. Ba/Al indicate that the high primary productivity led to the elevated accumulation and burial of organic matter, while the anoxic to sulfidic conditions were likely resulted from an intense degradation of the organic matter during the early diagenesis. In summary, the organic matter accumulation is ultimately attributed to the high primary productivity possibly resulted from seawater or volcanic ash entering the lake. 相似文献
6.
The Songliao Basin is a large-scale petroliferous basin in China. With a gradual decline in conventional oil production, the exploration and development of replacement resources in the basin is becoming increasingly important. Previous studies have shown that the Cretaceous Qingshankou Formation (K2qn) has favorable geological conditions for the formation of shale oil. Thus, shale oil in the Qingshankou Formation represents a promising and practical replacement resource for conventional oil. In this study, geological field surveys, core observation, sample tests, and the analysis of well logs were applied to study the geochemical and reservoir characteristics of shales, identify shale oil beds, build shale oil enrichment models, and classify favorable exploration areas of shale oil from the Cretaceous Qingshankou Formation. The organic matter content is high in shales from the first member of the Cretaceous Qingshankou Formation (K2qn1), with average total organic carbon (TOC) content exceeding 2%. The organic matter is mainly derived from lower aquatic organisms in a reducing brackish to fresh water environment, resulting in mostly type I kerogen. The vitrinite reflectance (Ro) and the temperature at which the maximum is release of hydrocarbons from cracking of kerogen occurred during pyrolysis (Tmax) respectively range from 0.5% to 1.1% and from 430 °C to 450 °C, indicating that the K2qn1 shales are in the low-mature to mature stage (Ro ranges from 0.5% to 1.2%) and currently generating a large amount of oil. The favorable depth for oil generation and expulsion is 1800–2200 m and 1900–2500 m, respectively as determined by basin modeling. The reserving space of the K2qn1 shale oil includes micropores and mircofractures. The micropore reservoirs are developed in shales interbedded with siltstones exhibiting high gamma ray (GR), high resistivity (Rt), low density (DEN), and slightly abnormal spontaneous potential (SP) in the well-logging curves. The microfracture reservoirs are mainly thick shales with high Rt, high AC (acoustic transit time), high GR, low DEN, and abnormal SP. Based on the shale distribution, geochemical characteristics, reservoir types, fracture development, and the process of shale oil generation and enrichment, the southern Taikang and northern Da'an are classified as two favorable shale oil exploration areas in the Songliao Basin. 相似文献
7.
Studies of the Mesozoic and Cenozoic sequence crossed by the Barreiro-4 borehole provide an improved understanding of the organic matter deposited in the Lower Tagus sub-basin (Lusitanian Basin, Portugal) and the implications for the potential source rock and depositional environment. This study focused on 43 samples (Middle Jurassic to Neogene) that were subjected to palynofacies and organic geochemistry analyses (Total Organic Carbon, Rock-Eval pyrolysis and molecular biomarker analysis). The palynofacies data indicate that the sequence contains mainly phytoclasts (non-opaque phytoclasts). However, the Middle Jurassic samples are dominated by Amorphous Organic Matter (AOM). Continental and/or marine palynomorphs are present in all the samples. The Cretaceous samples are characterized by small amounts of kerogen that have high contents of solid bitumen. The Total Organic Carbon (TOC) content is generally less than 1 wt.%. The Rock-Eval S1 and S2 parameters vary from 0.01 to 3.50 mgHC/g rock and 0.15 to 34.03 mgHC/g rock, respectively, with the highest values corresponding to the Cretaceous samples. The hydrogen index (HI) and oxygen index (OI) values range from 35 to 552 mgHC/g TOC and 4 to 180 mgHC/g TOC, respectively. The Tmax values range from 416 to 437 °C. The biomarker analysis showed that n-alkanes with 15–30 carbon atoms are present and usually have a unimodal distribution with a predominance of low to medium molecular weight compounds. The CPI values range between 0.63 and 3.65, and the pristane/phytane ratios vary between 0.48 and 1.64, indicating alternation of oxic–anoxic conditions along the sequence. The distribution of terpanes shows small amounts of tricyclic and tetracyclic terpanes in most of the samples (except for some Cretaceous samples) and a predominance of pentacyclic terpanes. The amount of 17α (H),22,29,30-trisnorhopane (Tm) usually exceeds the amount of 18α (H),22,29,30-trinorneohopane (Ts). The 20S/(20S + 20R) and αββ/(ααα + αββ) ratios of the C29 steranes generally have values below the range of equilibrium, indicating an immature stage of the OM. 相似文献
8.
Shales of the Silurian Dadaş Formation exposed in the southeast Anatolia were investigated by organic geochemical methods. The TOC contents range from 0.24 to 1.48 wt% for the Hazro samples and 0.19 to 3.58 wt% for the Korudağ samples. Tmax values between 438 and 440 °C in the Hazro samples indicate thermal maturity; Tmax values ranging from 456 to 541 °C in the Korudağ samples indicate late to over-maturity. Based on the calculated vitrinite reflectance and measured vitrinite equivalent reflectance values, the Korudağ samples have a maximum of 1.91%R(g-v), in the gas generation window, while a maximum value of 0.79%R(amor-v) of one sample from the Hazro section is in the oil generation window. Illite crystallinity (IC) values of all samples are consistent with maturity results.Pr/Ph ratios ranging from 1.32 to 2.28 and C29/C30 hopane ratios > 1.0 indicate an anoxic to sub-oxic marine-carbonate depositional environment.The Hazro shales do not have any shale oil or shale gas potential because of their low oil saturation index values and early to moderate thermal maturation. At first glance, the Korudağ shales can be considered a shale gas formation because of their organic richness, thickness and thermal over-maturity. However, the low silica content and brittle index values of these shales are preventing their suitability as shale gas resource systems. 相似文献
9.
Ever since a breakthrough of marine shales in China, lacustrine shales have been attracting by the policy makers and scientists. Organic-rich shales of the Middle Jurassic strata are widely distributed in the Yuqia Coalfield of northern Qaidam Basin. In this paper, a total of 42 shale samples with a burial depth ranging from 475.5 m to 658.5 m were collected from the Shimengou Formation in the YQ-1 shale gas borehole of the study area, including 16 samples from the Lower Member and 26 samples from the Upper Member. Geochemistry, reservoir characteristics and hydrocarbon generation potential of the lacustrine shales in YQ-1 well were preliminarily investigated using the experiments of vitrinite reflectance measurement, maceral identification, mineralogical composition, carbon stable isotope, low-temperature nitrogen adsorption, methane isothermal adsorption and rock eval pyrolysis. The results show that the Shimengou shales have rich organic carbon (averaged 3.83%), which belong to a low thermal maturity stage with a mean vitrinite reflectance (Ro) of 0.49% and an average pyrolytic temperature of the generated maximum remaining hydrocarbon (Tmax) of 432.8 °C. Relative to marine shales, the lacustrine shales show low brittleness index (averaged 34.9) but high clay contents (averaged 55.1%), high total porosities (averaged 13.71%) and great Langmuir volumes (averaged 4.73 cm−3 g). Unlike the marine and marine-transitional shales, the quartz contents and brittleness index (BI) values of the lacustrine shales first decrease then increase with the rising TOC contents. The kerogens from the Upper Member shales are dominant by the oil-prone types, whereas the kerogens from the Lower Member shales by the gas-prone types. The sedimentary environment of the shales influences the TOC contents, thus has a close connection with the hydrocarbon potential, mineralogical composition, kerogen types and pore structure. Additionally, in terms of the hydrocarbon generation potential, the Upper Member shales are regarded as very good and excellent rocks whereas the Lower Member shales mainly as poor and fair rocks. In overall, the shales in the top of the Upper Member can be explored for shale oil due to the higher free hydrocarbon amount (S1), whereas the shales in the Lower Member and the Upper Member, with the depths greater than 1000 m, can be suggested to explore shale gas. 相似文献
10.
Late Jurassic organic-rich shales from Shabwah sub-basin of western Yemen were analysed based on a combined investigations of organic geochemistry and petrology to define the origin, type of organic matter and the paleoenvironment conditions during deposition. The organic-rich shales have high total sulphur content values in the range of 1.49–4.92 wt. %, and excellent source rock potential is expected based on the high values of TOC (>7%), high extractable organic matter content and hydrocarbon yield exceeding 7000 ppm. The high total sulphur content and its relation with high organic carbon content indicate that the Late Jurassic organic-rich shales of the Shabwah sub-basin were deposited in a marine environment under suboxic-anoxic conditions. This has been evidenced from kerogen microscopy and their biomarker distributions. The kerogen microscopy investigation indicated that the Late Jurassic organic-rich shales contain an abundant liptinitic organic matter (i.e., alginite, structureless (amorphous organic matters)). The presence of alginite with morphology similar to the lamalginite alga and amorphous organic matter in these shale samples, further suggests a marine origin. The biomarker distributions also provide evidence for a major contribution by aquatic algae and microorganisms with a minor terrigenous organic matter input. The biomarkers are characterized by unimodal distribution of n-alkanes, low acyclic isoprenoids compared to normal alkanes, relatively high tricyclic terpanes compared to tetracyclic terpanes, and high proportion of C27 and C29 regular steranes compared to C28 regular sterane. Moreover, the suboxic to anoxic bottom water conditions as evidenced in these Late Jurassic shales is also supported based on relatively low pristane/phytane (Pr/Ph) ratios in the range of 0.80–1.14. Therefore, it is envisaged here that the high content of organic matter (TOC > 7 wt.%) in the analysed Late Jurassic shales is attributed to good organic matter (OM) preservation under suboxic to anoxic bottom water conditions during deposition. 相似文献
11.
Interest in factors controlling lacustrine source rock deposition has increased over the last few decades because this type of deposits contain significant petroleum resources. Generally, tectonic subsidence and climate are the two root causes as they control the accommodation potential, water column properties and sources of organic matter. In this study, coupling organic geochemical and elemental geochemical data, two potential source rocks, i.e., the Eocene Wenchang Formation (E2w) and Oligocene Enping Formation (E3e) were investigated. Two models were finally raised to explain deposition of the two set of source rocks according to their paleoclimatic and tectonic properties. The source rock potential shows a strong heterogeneity. The second member of the Eocene Wenchang Formation (E2w2) is characterized by high organic matter content and oil-prone kerogen type. In contrast, the first member of the Eocene Wenchang Formation (E2w1) and the Oligocene Enping formation (E3e) are characterized by low organic matter content and gas-prone kerogen type. The primary productivity and depositional environment exhibit notable differences between the two potential source rocks horizons and show an obvious variation from the depocenter to the slope and can be best explained by the coevolution of tectonic subsidence and climate. During the E2w depositional stage, low sediment supply led to mudstone deposited in deep lacustrine environment and resulted in underfilled lake basin. The low water inflow provided little terrigenous organic matter (low bicadinane, perylene and floranthene contents) and oxygen. Besides, the low area/depth ratio impeded the water circulation, thus resulted in shallow thermocline and anoxic-suboxic bottom environment (abundant dibenzothiophene and high C35/C3122S hopane ratios). Therefore abundant algae, which contributed to the high amorphous organic matter (AOM) content, can be preserved. The warm and wet climate (high Mn/Mg ratios) gave birth to autochthonous organism, such as dinoflagellates and Pavlova gyrans (abundant 4-methyl sterane). During the E3e depositional stage, the sufficient sedimentary supply resulted in expanding, shallow lacustrine and swamp environment. The higher area/depth ratio and high sediment supply made environment unstable and can be strongly influenced by external environment (broader range of Mn/Mg ratios). Enough terrigenous organic matter (TOM) was transported to the slope but little to the depocenter. The slightly hot and dry climate (low Mn/Mg ratios) led to decreasing autochthonous organism and evaporation environment. The shallow water depth and relative dry climate resulted in saline, suboxic-dysoxic acid bottom environment. The co-variation of organic and inorganic indexes indicates the combination is a valid method in reconstructing source rock depositional models. 相似文献
12.
Shales from the Lower Silurian Longmaxi Formation in the Sichuan Basin are among the most important shale gas reservoirs in China, and have been investigated because of their great shale gas potential. To understand the pore structure and fractal characteristics of the shales, a series of experiments was conducted on core samples from the Lower Silurian Longmaxi Formation in the Sichuan Basin of China, including X-ray diffraction (XRD), total organic carbon (TOC) content and vitrinite reflectance (Ro) analysis, field emission-environmental scanning electron microscope (FE-ESEM) observation, and low-pressure N2 adsorption-desorption experiments. Frenkel-Halsey-Hill (FHH) method was applied to calculate fractal dimensions. In addition, the pore genesis, the relationships between composition and thermal maturity, the pore structure parameters, and the fractal dimensions are discussed. FE-ESEM observation results show that the Longmaxi Formation shales are dominated by organic-matter (OM) pores along with interparticle (interP) pores, intraparticle (intraP) pores and fracture pores. This study identified the fractal dimensions at relative pressures of 0–0.45 and 0.45–1 as D1 and D2 respectively. D1 ranged from 2.60 to 2.71 and D2 ranged from 2.71 to 2.82. D1 was typically smaller than D2, indicating that the smaller pores in shales were more homogeneous than the larger ones. The formation of these OM pores is owing to kerogen deformation during the thermal maturation, which results in a large number of nanopores. The pore structure of the Longmaxi Formation shales is primarily controlled by TOC content and thermal maturity. TOC content is a controlling factor on the fractal dimensions as it exhibited positive correlations with D1 and D2. Fractal dimensions are useful for the characterization of the pore structures complexity of the Longmaxi Formation shales because D1 and D2 correlate well with pore structure parameters as they both increase with the increase of surface area and the decrease of average pore diameter. 相似文献
13.
Cretaceous sedimentary rocks of the Mukalla, Harshiyat and Qishn formations from three wells in the Jiza sub-basin were studied to describe source rock characteristics, providing information on organic matter type, paleoenvironment of deposition and hydrocarbon generation potential. This study is based on organic geochemical and petrographic analyses performed on cuttings samples. The results were then incorporated into basin models in order to understand the burial and thermal histories and timing of hydrocarbon generation and expulsion.The bulk geochemical results show that the Cretaceous rocks are highly variable with respect to their genetic petroleum generation potential. The total organic carbon (TOC) contents and petroleum potential yield (S1 + S2) of the Cretaceous source rocks range from 0.43 to 6.11% and 0.58–31.14 mg HC/g rock, respectively indicating non-source to very good source rock potential. Hydrogen index values for the Early to Late Cretaceous Harshiyat and Qishn formations vary between 77 and 695 mg HC/g TOC, consistent with Type I/II, II-III and III kerogens, indicating oil and gas generation potential. In contrast, the Late Cretaceous Mukalla Formation is dominated by Type III kerogen (HI < 200 mg HC/g TOC), and is thus considered to be gas-prone. The analysed Cretaceous source rock samples have vitrinite reflectance values in the range of 0.37–0.95 Ro% (immature to peak-maturity for oil generation).A variety of biomarkers including n-alkanes, regular isoprenoids, terpanes and steranes suggest that the Cretaceous source rocks were deposited in marine to deltaic environments. The biomarkers also indicate that the Cretaceous source rocks contain a mixture of aquatic organic matter (planktonic/bacterial) and terrigenous organic matter, with increasing terrigenous influence in the Late Cretaceous (Mukalla Formation).The burial and thermal history models indicate that the Mukalla and Harshiyat formations are immature to early mature. The models also indicate that the onset of oil-generation in the Qishn source rock began during the Late Cretaceous at 83 Ma and peak-oil generation was reached during the Late Cretaceous to Miocene (65–21 Ma). The modeled hydrocarbon expulsion evolution suggests that the timing of oil expulsion from the Qishn source rock began during the Miocene (>21 Ma) and persisted to present-day. Therefore, the Qishn Formation can act as an effective oil-source but only limited quantities of oil can be expected to have been generated and expelled in the Jiza sub-basin. 相似文献
14.
The geochemical and petrographic characteristics of saline lacustrine shales from the Qianjiang Formation, Jianghan Basin were investigated by organic geochemical analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM) and low pressure nitrogen adsorption analysis. The results indicate that: the saline lacustrine shales of Eq3 member with high oil content are characterized by type I and type II oil-prone kerogen, variable TOC contents (1.0–10.0 wt%) and an early-maturity stage (Ro ranges between 0.41 and 0.76%). The mineral compositions of Eq3 saline shale show strong heterogeneity: brittle intervals with high contents of quartz and carbonate are frequently alternated with ductile intervals with high glauberite and clay contents. This combination might be beneficial for oil accumulation, but may cause significant challenges for the hydraulic stimulation strategy and long-term production of shale oil. The interparticle pores and intraparticle pores dominate the pore system of Eq3 shale, and organic matter hosted pores are absent. Widely distributed fractures, especially tectonic fractures, might play a key role in hydrocarbon migration and accumulation. The pore network is contributed to by both large size inorganic pores and abundant micro-factures, leading to a relatively high porosity (2.8–30.6%) and permeability (0.045–6.27 md) within the saline shale reservoir, which could enhance the flow ability and storage capacity of oil. The oil content (S1 × 100/TOC, mg HC/g TOC and S1, mg HC/g rock) and brittleness data demonstrate that the Eq33x section has both great potential for being a producible oil resource and hydraulic fracturing. Considering the hydrocarbon generation efficiency and properties of oil, the mature shale of Eq3 in the subsidence center of the Qianjiang Depression would be the most favorable zone for shale oil exploitation. 相似文献
15.
Organic geochemical and palynofacies studies of 172 ditch cuttings samples of possible source rock shales from the Late Cretaceous Gongila and Fika formations in the Chad Basin of NE Nigeria were carried out to determine their paleoenvironments of deposition. Although dominated by amorphous organic matter, C/S ratios and molecular parameters suggest the mostly organic lean shales (TOC contents typically below 1.5%) were deposited in a normal marine environment. Levels of oxygenation influenced by water depth in the depositional environment appear to control organic richness and quality of the dark grey shales.The organic rich (TOC > 2.0%) upper part of the Fika Formation was deposited under anoxic conditions during the Late Cretaceous and could represent an Oceanic Anoxic Event. Mature intervals where such conditions prevailed would have generated liquid hydrocarbon, although none were sampled here.A trend of increasing organic richness towards the central part of the larger Chad Basin observed in this and other studies supports the development of organic rich marine shales (average TOC contents of 2–3%) of equivalent age in the Termit Basin where water depth would have been deeper and oxygen conditions at levels that permitted preservation of marine organic matter. 相似文献
16.
Laurie Biscara Thierry MulderPhilippe Martinez François BaudinHenri Etcheber Jean-Marie JouanneauThierry Garlan 《Marine and Petroleum Geology》2011,28(5):1061-1072
In order to define the nature and distribution of the organic matter (OM) preserved in the modern Ogooué deep sea turbidite system (Gabon), bulk geochemical techniques (Rock-Eval pyrolysis, elemental and isotopic analyses) and palynofacies were applied to three piston cores collected in the Cape Lopez Canyon and lobe and on the continental slope, north of the canyon.The hemipelagic sedimentation in the study area is characterized by high accumulations of well-preserved OM (∼2-3 wt. TOC %). Bulk geochemical and palynofacies analysis indicate both a marine and terrestrial origin of the OM. Contribution of the marine source is higher on the slope than in the canyon and lobe.OM accumulation in turbidites is strongly controlled by the combined influence of the Cape Lopez Canyon and littoral drift. In the canyon and lobe, turbidites show generally low TOC content (0.5 wt. %) and OM is oxidized. The origin of the OM is interpreted as both marine and terrestrial, with a higher contribution of continental source versus marine source. The low TOC contents are due to the large siliciclastic fraction transported by the littoral drift and diverted in the Cape Lopez Canyon during high energy processes (e.g. storms) which tend to dilute the OM in the turbidites. Transport by long-shore currents and/or turbiditic flows leads to oxidation of the OM.On the continental slope located north of the Cape Lopez Canyon, large amounts of OM are deposited in turbidites (up to 14 wt. %). The OM is predominantly derived from terrestrial land plants and has not been subjected to intense oxidation. These deposits are characterized by high hydrocarbon potential (up to 27 kg HC/t rock), indicating a good potential as gas-prone source rock. Because Cape Lopez Canyon captures a significant part of the sediment transported by the littoral drift, the siliciclastic sedimentary flux is reduced north of the canyon; OM is thus concentrated in the turbidites. Variation in TOC content within turbidite laminae can be explained by the burst and sweep deposition process affecting the boundary layer of the turbulent flow.This study confirms that gravity flows play a preponderant role in the accumulation and preservation of OM in deep water and that deep sea turbidite systems could be regarded as an environment where organic sedimentation occurs. 相似文献
17.
A great deal is known about the genetic relationships between biomarkers and their biogenic precursors in organic rich rocks. The same is true of the way in which biomarker compound ratios change during maturation. On the other hand, very little is known about whether a crude oil can fully retain its inherent compositional ancestry during expulsion from a source rock. Thanks to shales being characterized in great detail for their unconventional resource potential, new information is gradually coming to light. Here we report on observations in biomarker geochemistry of a thermally mature core of the Barnett Shale, in which organofacies and maturity are essentially the same, but where intraformational sources and reservoirs have already been reported.Our results indicate that most biomarkers are not fractionated as the primary migration of petroleum within source rocks takes place. The 20S/(20S + 20R) ratio of C27 steranes is uniform in the whole source-rock sequence, while the 20S/(20S + 20R) ratio of C29 steranes shows indistinctly high values in the reservoir unit. The 20S/(20S + 20R) ratio of diasteranes and the 22S/(22S + 22R) ratio of C31 17α-hopanes do not appear to have been fractionated, which may be a result of the thermal isomerization reactions predominating over and masking out the possible fractionation effects. Diasteranes/steranes ratios do not exhibit features that suggest an association with fractionation, but rather are broadly correlated with lithology. However, compared to the diasteranes/steranes ratios, the Ts/(Ts + Tm) ratio is much more sensitive to changes in mineral compositions. Variations in the Ts/(Ts + Tm) ratio show a positive correlation (R2 = 0.73) with mixed-layer illite-smectite content. Fractionation in the Ts/(Ts + Tm) ratio, if it has so occurred, may be subsequently overprinted by in-situ clay-catalyzed reactions. 相似文献
18.
Organic-rich black shale of the Upper Yangtze Basin from the Late Ordovician and Early Silurian is considered an excellent source rock in South China. The formation and preservation conditions of this resource are revealed by its geochemical characteristics in this study. Geochemical indices, including redox indices (V/(V + Ni), V/Cr, V/Sc, and Ni/Co) and primary productivity indices (P/Ti and Ba/Al), and paleoclimate, clastic flux and sedimentary rate analyses are presented to investigate the accumulation mechanism of organic matter. Redox indices suggest that a stagnant, anoxic environment predominated in the Upper Yangtze Basin during accumulation of Wufeng and Longmaxi formations. In contrast, ventilated and oxygenated marine conditions pervaded the Upper Yangtze Basin during deposition of Linxiang and Guanyinqiao formations. The concentrations of V and U demonstrate that accumulation of organic matter was mainly controlled by redox conditions. Besides, such factors as clastic fluxes, fresh water inflows or a mixed deposition with a rapid sedimentary rate cannot be ignored due to their influences on organic matter enrichment and preservation. However, weak co-variance relationship of TOC content and productivity proxies, including P/Ti and Ba/Al, demonstrates that the accumulation of organic matter was not controlled by primary productivity. Results of the present study suggest a depositional model that stresses the importance of tectonic movements and glacial events on the accumulation and preservation of organic matter. The model shows that the Upper Yangtze Basin was a semi-restricted basin system influenced by the isolation of Xuefeng, but also it implies that oxygen-depleted bottom water of the basin favored the accumulation and preservation of sedimentary organic matter, resulting in the formation of organic-rich black shale. 相似文献
19.
《Marine environmental research》2008,65(5):666-678
Temporal and spatial variations in the composition of particulate organic matter (POM) from Florida Bay, USA were examined. The predominance of short-chain homologues for n-alkanes, n-alcohols and n-fatty acids as well as relatively high abundance of C27 and C28 sterols suggested that an autochthonous/marine source of OM was dominant bay-wide. Several biomarker proxies such as Paq [(C23 + C25)/(C23 + C25 + C29 + C31) n-alkanes], short/long chain n-alkanes, (C29 + C31) n-alkanes and taraxerol indicated a spatial shift in OM sources, where terrestrial OM rapidly decreased while seagrass and microbial OM markedly increased along a northeastern to southwestern transect. Regarding seasonal variations, POM collected during the dry season was enriched in terrestrial constituents relative to the wet season, likely as a result of reduced primary productivity of planktonic species and seagrasses during the dry season. Principal component analysis (PCA) classified the sample set into sub-groups based on PC1 which seemed to be spatially controlled by OM origin (terrestrial-mangrove vs. marine-planktonic/seagrass). The PC2 seemed to be more seasonally controlled suggesting that hydrological fluctuations and seasonal primary productivity are the drivers controlling the POM composition in Florida Bay. 相似文献
20.
The Yanshiping section, which includes the Quemo Co, Buqu, Xiali, Suowa and Xueshan Formations (Yanshiping Group) exposes organic-rich Middle to Late Jurassic deposits in the Qiangtang Basin of northern Tibet. The biostratigraphic data, from bivalves, brachiopods as well as dinoflagellate cysts, define a Bajocian to Tithonian age. This study focuses on the biomarkers present in these mudstones and limestones to determine the sources, thermal maturity and depositional environment of the organic matter. Most samples show a clear dominance of short-chain (C15–C20) n-alkanes with a maximum at C19 or C19 with a secondary maximum at C23 except for the sample BP01(22)S1 where the predominant range is C22 to C26 with a maximum at C24, significant CPI and odd-to-even predominance. The hopanoids and steroids suggest that the sources of organic matter were dominated by phytoplankton, especially algae, as the primary source. Furthermore, the Pr/Ph, Pr/nC17 and Ph/nC18, with relatively low values plus high abundance of 17α(H)-hopanes, support deposition in dysoxic to reducing, relatively shallow-water depositional settings, and the presence of gammacerane indicates normal marine salinity and/or water-column stratification. All samples are fairly mature with respect to petroleum generation, a conclusion supported by maturity parameters such as C31 22S/(22S + 22R) hopanes and C29 ααα20S/(20S + 20R) steranes. 相似文献