共查询到19条相似文献，搜索用时 579 毫秒
1.
铝对铬成矿地球化学的依存性和对抗性 总被引：3，自引：0，他引：3
戚长谋 《长春地质学院学报》1997,27(4):375-378
基于岩浆铬矿床与超镁铁质岩石的关系，从元素亲合生和共生规律的角度揭示了铝对铬成矿制约的主导作用，分析了铝和铬亲石、亲氧的二重性及其晶体化学的依存关系。论证了超镁铁－Ｓｉ－Ｏ体系中铝在度过高或过低不利于铬的成矿。揭示了制约元素分散富集的因素都是一一条件下互为依存和转化的是在动态中的矛盾的对立和统一。 相似文献
2.
基于岩浆铬矿床与超镁铁质岩石的关系,从元素亲合性和共生规律的角度揭示了铝对铬成矿制约的主导作用。分析了铝和铬亲石、亲氧的二重性及其晶体化学的依存关系。论证了超镁铁Ｓｉ－Ｏ体系中铝丰度过高或过低均不利于铬的成矿。揭示了制约因素分散富集的因素都是在一定条件下互为依存和转化的。是在动态中的矛盾的对立和统一。 相似文献
3.
战新志 《矿物岩石地球化学通报》2000,19(4):326-327
镁铁岩-超镁铁岩侵人体中常常含有少量及微量硫化物,它们是硅酸盐岩浆与硫化物熔体不混溶作用的产物。由于岩石圈环境下铂族元素亲硫性的制约,当硅酸盐岩浆与硫化物熔体呈液态熔离时,铂族元素便被硫化物熔体所捕集和运载,尔后在重力分异过程中下沉到岩盆底部富集成矿。能否依据岩盆上部岩浆熔离硫化物的铂族元素丰度值来判断岩盆深部铂族元素潜在成矿能力呢?这是本试图回答的问题。 相似文献
4.
镁铁- 超镁铁岩是揭示地幔物质组成和壳幔相互作用的重要窗口，也是Ni- Cu- PGE- Cr等金属矿产资源的重要载体。不同的镁铁- 超镁铁岩体赋矿特征明显不同：蛇绿岩以产出铬铁矿床为特征，阿拉斯加型岩体主要赋含铂族元素(PGE)矿床，大型层状岩体则可同时产出铬铁矿床、PGE矿床和Cu- Ni硫化物矿床。这种成矿差异显然与赋矿岩体形成的构造背景、母岩浆经历的岩浆演化过程有关，但缺少关键控制因素的研究。前人对上述不同种类矿床的研究工作主要集中于地幔源区的部分熔融、上升过程中或岩浆房内的围岩混染和结晶分异等岩浆过程，而极少关注流体作用。近年来，实验岩石学和岩石地球化学的研究均表明幔源岩浆演化过程中的流体活动可能对成矿元素的富集迁移起到至关重要的作用，同时这些成矿元素的赋存状态和分配系数也在不断更新。厘清Cr和PGE在熔体演化——尤其是流体出溶过程中的地球化学行为，刻画并揭示其迁移富集、分离和再富集的成矿过程及控制因素，已成为当前岩浆矿床研究的热点。本文围绕富水流体与铬铁矿和PGE成矿关系的科学问题，总结了不同镁铁- 超镁铁岩体的成矿差异以及铬铁矿和PGE矿床成矿过程中的流体活动记录，提出流体性质和组分对铬铁矿和PGE迁移富集的控制作用，强调有必要开展蛇绿岩、大型层状镁铁- 超镁铁岩体和阿拉斯加型岩体的对比研究。 相似文献
5.
秦岭造山带勉略缝合带超镁铁质岩的地球化学特征 总被引：13，自引：1，他引：13
勉略缝合带中广泛出露的超镁铁质岩构造块体是D～T_2期间勉咯洋盆古洋壳残片的重要标志之一，属贫铝、贫碱的镁质超基性岩类，其原岩类型主要为方辉橄榄岩和纯橄榄岩。稀土特征有两种类型：轻稀土亏损，Eu富集型；以及轻稀土低度富集，Elf弱亏损型。与原始地慢比较，本区超镁铁质岩中Cs、Rb、Th、U、K、Ta、Nb等强不相容元素大多呈富集状态，暗示古地慢经历过一种富集大离子亲石元素的上地幔流体交代作用。 相似文献
6.
锂（Li）同位素体系是示踪镁铁-超镁铁质岩成岩成矿过程（如结晶分异、地壳混染和熔/流体-矿物相互作用等）的全新工具.通过实例研究综述了原位Li同位素在镁铁-超镁铁质岩中应用的主要进展,主要包括:（1）美国Yellow Hill阿拉斯加型杂岩体Li同位素研究揭示弧岩浆早期堆晶过程可发生明显的Li同位素分馏;（2）土耳其和西藏蛇绿岩的Li同位素研究证明其在示踪蛇绿岩地幔序列岩石成因及豆荚状铬铁矿演化过程中的潜力;（3）Stillwater层状岩体超镁铁岩带Li同位素研究揭示流体对于大型层状岩体各矿物形成及铬铁岩中矿物元素交换的作用;（4）橄榄石Li含量与同位素分析在揭示岩浆铜镍矿床成矿过程的应用. 相似文献
7.
金伯利岩中的镁铝榴石是寻找金刚石的重要指示矿物。镁铝榴石的Cr2O3、CaO等氧化物含量及其颜色、折光率等物理光学性质可作为这种石榴石的标型特征。 本文将山东、辽宁等地金伯利岩中的石榴石的电子探针分析结果按分子数配分的方法计算了端员分子百分数及其他化学参数。用MPV—1显微光度仪测定了石榴石的透射率色散值,通过计算求得颜色指数。按Dawson等人的分类,本次研究样品以铬镁铝榴石为主,其次是低钙-铬镁铝榴石、钙铬-镁铝榴石和镁铬-钙铬-镁铝榴石;钛镁铝榴石和钙镁铝-铁铝榴石等少量。作者用铬、钙、镁三组份数绘制了石榴石与金刚石关系判别图解,分为五个区(A、B、C、D、E)、落入A区的低钙-铬镁铝榴石、铬镁铝榴石和钙铬-镁铝榴石等与金刚石的形成关系最密切。 相似文献
8.
缅甸翡翠矿物与自然类型 总被引：2，自引：1，他引：1
ＮａＡｌＳｉ２Ｏ６分子〉５０％称为硬玉。按杂质元素将硬玉分为纯硬玉,钙硬玉、铬硬玉、绿硬玉。依据硬玉亚种及结构变化,划分为四个自然类型和１１个硬玉岩类别以及与之相对应的１１个翡翠玉种。硬玉岩的成矿作用有两个系列：纯硬玉－钙硬玉和（纯硬玉）－铬硬玉－氟镁纳闪石系列。前者参与成矿的特征元素是钠和钙;后者是钠、铬、镁。从残晶矿物提供的证据分析：前者发生在基性蚀变岩中;后者主要发生在超基性基中。硬玉岩经受 相似文献
9.
V.I.STAROSTIN O.G.SOROKHTIN 《地学前缘》2004,11(1):225-235
现有的矿产资源分布资料可以说明地球历史中亲铁和亲铜元素成矿的一般规律。铁矿床在元古宙地核分离之后最为发育。除个别显著成矿高峰外 ,金的储量分布与铁类似。亲铁元素矿物的成矿潜力在古元古代也最大 ,以后逐渐降低 ,只是在显生宙 ,因地壳的再循环和古老矿床中矿石物质的活化而再次增大。元素的行为则完全不同 ,在前寒武纪时期它们的活动性为中等。亲铜矿物矿床的总量 ,在显生宙因再循环而达到最高 ,亲铜矿物矿床成矿能力较之亲铁矿物强得多 ,因为硫化物比铁金属氧化物更为活泼。地球演化的旋回性表现为超大陆形成的周期性 ,它与矿产的分布颇为一致。铁矿、亲铁元素和金成矿作用的突然激增 ,显然是在超大陆形成之后 ,并且与其早期裂解的脉动相对应。亲铜元素堆积的高峰期往往与超大陆的形成期相对应。尽管亲铜元素成矿的第三次脉动与中生代古陆 (Mesogea)的形成并不一致 ,但却与劳亚古陆及冈瓦纳古陆的裂解相一致。此种成矿堆积现象可以借助地幔内非稳态化学密度对流所诱发的地壳发展周期性来解释。根据超大陆形成的周期性推断地幔对流巨旋回的主期应为 80 0Ma ,此种周期性亦反映了具原始地幔印记的亲铁、金和亲铜元素的聚集作用过程。因此 ,地球圈层中地幔对流作用的周期性亦显著地控制了包括地幔 相似文献
10.
云海铜镍矿位于觉罗塔格构造带西段,成矿岩体为多期次侵入的杂岩体,岩体分异演化充分,镁铁质和超镁铁质岩石均有发育,主要岩石类型为角闪辉石岩、橄榄苏长岩、辉长岩、闪长岩。主量元素化学组成表明,该杂岩体属拉斑玄武岩系列,岩石具同源演化特征,显示高铁、高镁、低钛、低铝特征,富集大离子亲石元素Rb,Ba,亏损Nb,Ta,轻稀土富集。岩浆源区有部分熔融而交代的岩石圈地幔,岩浆在上升过程中受到地壳物质混染,发生橄榄石、斜方辉石、斜长石的分离结晶。岩体形成于早二叠世,为构造活动和地幔柱双重作用下的产物。 相似文献
11.
PP3超镁铁岩主要岩石类型有纯橄岩和石榴石橄榄岩,两者为渐变,主要矿物为橄榄石、铬尖晶石、石榴石、单斜辉石和斜方辉石.铬尖晶石的Cr#[Cr/(Cr+Mg) ×100]从51~89变化,TiO2和MnO2值分别低于0.26%和0.46%.铬尖晶石矿物表现为4期次演化的特点,反映了从岩浆期、榴辉岩相、角闪岩相和绿片岩相演化特征.随着超镁铁岩的演化,铬尖晶石表现为Cr#不断增大,而Mg#[Mg×100/(Mg+Fe2+) ]不断减少、氧逸度不断增加的过程.PP3铬尖晶石反映了地幔来源,为大陆岩石圈超镁铁岩特征,后期随折返而演化.从石榴石与铬尖晶石相互转变过程看出,PP3超镁铁岩经历了深度加大的过程,超镁铁岩曾经到达100km以上的岩石圈地幔深处.在绿片岩相-绿片角闪岩相变质过程中,铬尖晶石中Cr、Mg和Al减少,Fe相对增加,产生富Cr尖晶石变质作用样式.晚期剪切变形等次生变化影响了铬尖晶石矿物成分. 相似文献
12.
Sh. N. Jamal B.Sc. M.Sc. M. Z. Iqbal B.Sc. M.Sc. Ph.D. M. Athar M.Sc. M.Phil. Ph.D. D.Sc. 《International Journal of Environmental Science and Technology》2006,3(2):173-176
Prosopis seeds were grown under controlled environment in solution of aluminum and chromium at different concentration alone as well as combined together. The effect of these metals was studied on seed germination, root length, shoot length, seedling length and dry biomass. Aluminum and chromium alone, and combined together showed no effects on germination and dry biomass. Chromium alone was found toxic to root, shoot and seedling length. However, application of different concentrations of aluminum increased the root, shoot and seedling growth. It may be concluded that aluminum is not as toxic as chromium, and their combined treatment showed the intermediate effect by ameliorating the impact of one another. 相似文献
13.
岗上超镁铁质岩主要由纯橄岩和石榴橄榄岩组成,主要组成矿物有橄榄石、铬尖晶石、石榴子石、单斜辉石和斜方辉石等。铬尖晶石的Cr#[Cr/(Cr+Mg)×100]从51到89变化,铬尖晶石矿物表现为4期次演化的特点,反映了从岩浆期向榴辉岩相、角闪岩相和绿片岩相演化特征。随着超镁铁质岩的演化,铬尖晶石中Cr#不断增大(51增大到89),而铬尖晶石Mg#[Mg×100/(Mg+Fe2+)]不断减少,氧逸度不断增加。在绿片岩相—绿片角闪岩相退变质过程中,铬尖晶石中Cr、Mg和Al减少,Fe相对增加,产生富Cr尖晶石变质作用样式。晚期剪切变形等次生变化有利于富铬铬尖晶石矿物的形成和铬尖晶石的富集。同时,角闪岩相和绿片岩相变质作用使铬尖晶石富集呈现容易开采的条带状,降低了铬尖晶石与其他硅酸盐矿物的结合强度,降低了开采强度和成本,使原本不易于开采的铬铁矿矿体变得可以开采。这些意味着铬铁矿矿体展布要结合后期变质作用进行综合分析。 相似文献
14.
S. N. Jamal M. Z. Iqbal M. Athar 《International Journal of Environmental Science and Technology》2006,3(4):411-416
A greenhouse experiment was conducted to determine the phytotoxic effect of aluminum and chromium on the germination and early growth of two wheat (Triticum aestivum) varieties Anmol and Kiran. Seed were treated with 40, 80, 120 and 160 ppm of aluminum and chromium solution individually and in combined form. Observations were made on seed germination, root, shoot and seedling length, and dry biomass. Seed germination and dry biomass showed no effect of aluminum, chromium and combined treatment. Root, shoot and seedling length of both the varieties showed significant (P<0.05) decrease as compared to control. The growth was also reduced as the concentration of aluminum and chromium increased. Seedling length decreased in both the varieties at all the concentration of different treatment of aluminum, chromium and combined treatment. Attempts are being made in different laboratories to construct novel plants using genetic manipulation technologies that may have a greater tolerance to the presence of toxic metals. The results of the present study may help in understanding the mechanisms involved and their possible use in pytoremediation. 相似文献
15.
利用铝型材厂碱蚀渣为主要原料,采用二步煅烧工艺制备铝方柱石材料。探索二次煅烧温度对铝型材厂碱蚀渣制备铝方柱石材料相组成、结晶度、微观结构的影响,进而研究氧化铬对铝方柱石材料相组成、微观结构的影响。采用同步热分析、X射线衍射、扫描电镜及相关分析软件表征制备的铝方柱石材料的相组成和显微结构。结果表明：铝型材厂碱蚀渣中有大量可烧失成分,物料需要进行致密化处理,再经过1500℃煅烧后的铝方柱石材料结构中具有明显的铝方柱石条柱状结构,结晶度增大,铝方柱石相对含量达到91%。随着氧化铬加入量增加,结构中的铝铬酸钙相增加。当氧化铬加入量为2%时,试样中结晶相的结晶度最高,形成条柱状铝方柱石相与立方状铝铬酸钙相共存的结构。当氧化铬加入量4%时,试样中铝方柱石相几乎消失,结晶度降低。 相似文献
16.
Jan Paava Ilja Knésl Anna Vymazalová Ivan Vavrín Ludmila Ivanovna Gurskaya Leonid Ruslanovich Kolbantsev 《地学前缘(英文版)》2011,(1)
The Polar Urals region of northern Russia is well known for large chromium(Cr)-bearing massifs with major chromite orebodies,including the Centralnoye I deposit in the Ray-Iz ultramafic massif of the Ural ophiolite belt.New data on platinum(Pt)-group elements(PGE).geochemistry and mineralogy of the host dunite shows that the deposit has anomalous iridium(Ir) values.These values indicate the predominance of ruthenium-osmium-iridium(Ru-Os-Ir)-bearing phases among the platinum-group mineral (PGM) assemblage... 相似文献
17.
S. N. Jamal B. Sc. M. Sc. M. Zafar Iqbal B.Sc. M.Sc Ph.D. M. Athar M.Sc MPhil. Ph.D. D.Sc 《International Journal of Environmental Science and Technology》2006,3(1):53-58
The study deals with the effect of metal toxicity (aluminum, chromium and combination of both the metals) on seed germination, root length, shoot length, seedling length and dry biomass of Vigna radiata and V. sinensis. Chromium adversely affected the seedling by significantly reducing the growth whereas aluminum did not show such effect in both the species. Percentage of germination was good in both the species at different concentration of treatment (aluminum, chromium and combined treatment). Shoot length was also not much affected in V. sinensis as it was greatly inhibited in V. radiata. Both the species showed the purpling of stem. Dry biomass of V. radiata showed positive effect than V. sinensis. However, dry biomass decreased to a lesser extent when treated with aluminum, chromium and combined treatment as compared to control. 相似文献
18.
Among the dominant species of chromium, the trivalent form widely occurs in nature in chromite ores or in silicate minerals and is extremely immobile. The higher oxidation state Cr(VI), is, however, rarely found in nature, is more mobile, and several times more toxic than Cr(III). Cr(VI) occurs in chromates and dichromates manufactured from chromite ores. The hexavalent state is stable in an oxidizing alkaline environment, whereas the trivalent state is stable in a reducing acidic environment. Serpentinization and Mg release during deuteric alteration of ultramafic rocks create alkaline pore water and lateritization is an intensive oxidation process. Chromite ore bodies in oxidized serpentinite therefore may generate hexavalent chromium from the inert chromites and cause hazardous chromium pollution of the water. With this end in view, a combined field and laboratory study has been made on chromite-bearing oxidized serpentinite rocks of Sukinda in Orissa, India. Laboratory leaching studies on mine overburden samples, chemical analyses of streamwater, and hydrolysate incrustation on detrital grains taken from stream beds have indicated the possibility of chromium mobilization from the chromite ores into the waterbodies. 相似文献
19.
The sources and the potential availability of chromium were investigated in ultramafic soils from Niquelândia (Goïas State, Brazil), with chemical extractions associated to mineralogical studies, in order to evaluate its bioavailability and its potential impact on the soil biodiversity. Cr contents are particularly high in the studied soils and its partitioning among the solid phase varies with the position in the landscape and depth. Most of the Cr is associated to Fe-oxides but the amount of exchangeable Cr(VI) is high, particularly in one soil profile. Cr availability is higher than expected, and Cr-tolerant vegetation is probably growing on these soils. 相似文献