首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 140 毫秒
1.
A measure of the degree of preferred orientation of directional data defined by Woodcock as the ratio of the maximum and minimum eigenvalues of the orientation tensor (S1/S3) has a disadvantage when used as the statistic for a test of uniformity. This drawback arises because the distribution of S1/S3 under random sampling is not independent of the shape or K value of the sample. An alternative strength parameter also based on the eigenvalues, is proposed.  相似文献   

2.
We ask the question whether petrofabric data from anisotropy of magnetic susceptibility (AMS) analysis of deformed quartzites gives information about shape preferred orientation (SPO) or crystallographic preferred orientation (CPO) of quartz. Since quartz is diamagnetic and has a negative magnetic susceptibility, 11 samples of nearly pure quartzites with a negative magnetic susceptibility were chosen for this study. After performing AMS analysis, electron backscatter diffraction (EBSD) analysis was done in thin sections prepared parallel to the K1K3 plane of the AMS ellipsoid. Results show that in all the samples quartz SPO is sub-parallel to the orientation of the magnetic foliation. However, in most samples no clear correspondance is observed between quartz CPO and K1 (magnetic lineation) direction. This is contrary to the parallelism observed between K1 direction and orientation of quartz c-axis in the case of undeformed single quartz crystal. Pole figures of quartz indicate that quartz c-axis tends to be parallel to K1 direction only in the case where intracrystalline deformation of quartz is accommodated by prism <c> slip. It is therefore established that AMS investigation of quartz from deformed rocks gives information of SPO. Thus, it is concluded that petrofabric information of quartzite obtained from AMS is a manifestation of its shape anisotropy and not crystallographic preferred orientation.  相似文献   

3.
In this work, the inorganic chemical profiles of soil samples collected at different sites in the Salentum peninsula (Italy, Apulia region) are discussed. The samples were re-suspended in the laboratory, for PM10 sampling, using a ventilated wooden chamber and were then chemically analysed measuring the abundances of 17 elements. Different land use categories of soils (olive grove, arable land, vineyards, sand, and urban dust) were included in the 50 samples analysed: 45 collected in background areas and five collected in the urban area of Lecce. The objectives were to compare the chemical profiles of raw soil and re-suspended PM10 for different crustal sources and to estimate the potential improvements in the calculation of the enrichment factors of atmospheric PM10. The variability of elemental abundances in samples of the same category of soil collected in different zones was of the same order of magnitude as the differences observed between the various categories of soil. This allows the calculation of a weighted average composition of soil and urban dust and the corresponding weighted average composition of re-suspended PM10. In re-suspended PM10 from average background soil, all of the elements except Ca, Na, K and V have larger abundances with respect to raw soil. In urban dust, this is limited to Ca, V and Mg. The crustal enrichment factors (EFs) of atmospheric PM10 were evaluated by considering different reference elements and different reference tables. Results indicated that it is possible to apply a two-threshold (S1 and S2) scheme for the interpretation of EF, with thresholds derived from uncertainty in soil categories and from the choice of the reference element. A specific element is likely of crustal origin if EF < S1 and likely of anthropogenic origin if EF > S2. Between the two thresholds, the element can be considered of mixed origin. The thresholds vary according to the geological composition used in the evaluation of EF. If the average composition of local re-suspended soils is used, the thresholds are S1 = 2 and S2 = 4. If raw soil is used, the thresholds become S1 = 5 and S2 = 10. If the average upper-crust composition from literature data is used, the thresholds further increase to S1 = 10 and S2 = 20.  相似文献   

4.
Heat capacity (CV) and entropy (S) as a function of temperature were calculated for phases in the CaO-Al2O3 system from vibrational spectra using a quasi-harmonic model. Calculated values of CV at 298 K for the calcium aluminates may have uncertainties as small as ±1%, based on comparison with published calorimetric data for CaO, Al2O3, and CaAl2O4. For hibonite (CaAl12O19), we predict CP as 519.3 J/mol-K and S as 391.7 J/mol-K, at 298 K. For grossite (CaAl4O7), calculated values of CP as 195.9 J/mol-K and of S as 172.0 J/mol-K are slightly smaller than the available calorimetric data at 298 K, consistent with calorimetric data having been obtained from samples containing ∼10 wt% hibonite impurities. Thermal conductivity at 298 K (k0) is predicted from peak widths of the vibrational modes using the damped harmonic oscillator model of a phonon gas. Calculations of k0 for CaO and Al2O3 differ from the measurements by 17% and 5%, respectively. The discrepancy for lime is larger due to uncertainties in its peak widths. This comparison suggests that our results for the calcium aluminates should be more accurate than conventional measurements of k0 which are commonly uncertain by ∼25%.  相似文献   

5.
Smythite and monoclinic Fe3S4 have been identified by X-ray diffraction procedures in quenched ironsulfide compositions. Both phases appear to be metastable under the conditions of the experiments and their development is structurally induced. Smythite occurs as a coherent twinned intergrowth with hexagonal 3C pyrrhotite. Individual single crystals contain about 50% smythite. Reciprocal lattice rows with h-k ≠ 3n show continuous diffraction streaks. The available data suggest that smythite forms via a “polytypic” displacive transformation, by the introduction of stacking faults in the hexagonal close-packed layers of S atoms in high-temperature 1C pyrrhotite. This is analogous to the transformation of 2H wurtzite to intermediate ordered and disordered ZnS layer sequences. The ideal formula of smythite appears to be Fe13S16. Monoclinic Fe3S4 (a=5.93, b=3.42, c=10.64 Å, β=91.9°) is present in amounts up to 25% of total sulfides. It has a derivative NiAs-type structure, and is isomorphous with monoclinic Cr3S4 and Fe3Se4. It occurs as small lenticular lamellae within grains of 3C pyrrhotite, and apparently corresponds to the unidentified lamellar phase of Arnold (1962). The lamellae have a rhombohedral morphology, with a habit plane close to {1011}. In single crystal grains of pyrrhotite, monoclinic Fe3S4 in twinned in a manner consistent with transformation from high-temperature 1C pyrrhotite. Although Fe3S4 lamellae have the general appearance of plate martensite, they do not represent a diffusionless transformation.  相似文献   

6.
We conducted hydraulic fracturing (HF) in situ stress measurements in Seokmo Island, South Korea, to understand the stress state necessary to characterize a potential geothermal reservoir. The minimum horizontal principal stress was determined from shut-in pressures. In order to calculate the maximum horizontal principal stress (S Hmax) using the classical Hubbert–Willis equation, we carried out hollow cylinder tensile strength tests and Brazilian tests in recovered cores at depths of HF tests. Both tests show a strong pressure rate dependency in tensile strengths, from which we derived a general empirical equation that can be used to convert laboratory determined tensile strength to that suitable for in situ. The determined stress regime (reverse-faulting) and S Hmax direction (ENE–WSW) at depths below ~300 m agrees with the first order tectonic stress. However the stress direction above ~300 m (NE–SW) appears to be interfered by topography effect due to a nearby ridge. The state of stress in Seokmo Island is in frictional equilibrium constrained by optimally oriented natural fractures and faults. However, a severe fluctuation in determined S Hmax values suggests that natural fractures with different frictional coefficients seem to control stress condition quite locally, such that S Hmax is relatively low at depths where natural fractures with low frictional coefficients are abundant, while S Hmax is relatively high at depths where natural fractures with low frictional coefficients are scarce.  相似文献   

7.
The dependence of P- and S-wave attenuation on strain amplitude and frequency has been studied experimentally in dry and water-saturated sandstone samples under a confining pressure of 20 MPa. Attenuation of P and S reflections was measured at a frequency of 1 MHz in a strain range of ε ～(0.3?2.0) × 106. The measured P-wave attenuation (QP?1) in dry sandstone and S-wave attenuation (QS?1) in dry and saturated samples turned out to be inversely proportional to strain amplitude while QP?1 in saturated sandstone showed no strain dependence. The frequency-dependent attenuation spectra in dry and saturated sandstone differed considerably in S waves but were generally similar for P reflections. Strain amplitude variations were found out to influence the frequency dependence of attenuation and to shift the relaxation spectra of S waves toward high frequencies relative to those of P waves. As strain increased, the S-wave attenuation peak in saturated sandstone became notably (to 40%) narrower. The unusual strain amplitude-dependent behavior of attenuation may be due to joint action of viscoelastic and microplastic mechanisms. The reported results may be useful for improving geological interpretation of acoustic and seismic data.  相似文献   

8.
The magnitude of the in situ stresses in the Cooper–Eromanga Basins have been determined using an extensive petroleum exploration database from over 40 years of drilling. The magnitude of the vertical stress (Sv) was calculated based on density and velocity checkshot data in 24 wells. Upper and lower bound values of the vertical stress magnitude are approximated by Sv = (14.39 × Z)1.12 and Sv = (11.67 × Z)1.15 functions respectively (where Z is depth in km and Sv is in MPa). Leak-off test data from the two basins constrain the lower bound estimate for the minimum horizontal stress (Shmin) magnitude to 15.5 MPa/km. Closure pressures from a large number of minifrac tests indicate considerable scatter in the minimum horizontal stress magnitude, with values approaching the magnitude of the vertical stress in some areas. The magnitude of the maximum horizontal stress (SHmax) was constrained by the frictional limits to stress beyond which faulting occurs and by the presence of drilling-induced tensile fractures in some wells. The maximum horizontal stress magnitude can only be loosely constrained regionally using frictional limits, due to the variability of both the minimum horizontal stress and vertical stress estimates. However, the maximum horizontal stress and thus the full stress tensor can be better constrained at individual well locations, as demonstrated in Bulyeroo-1 and Dullingari North-8, where the necessary data (i.e. image logs, minifrac tests and density logs) are available. The stress magnitudes determined indicate a predominantly strike-slip fault stress regime (SHmax > Sv > Shmin) at a depth of between 1 and 3 km in the Cooper–Eromanga Basins. However, some areas of the basin are transitional between strike-slip and reverse fault stress regimes (SHmax > Sv ≈ Shmin). Large differential stresses in the Cooper–Eromanga Basins indicate a high upper crustal strength for the region, consistent with other intraplate regions. We propose that the in situ stress field in the Cooper–Eromanga Basins is a direct result of the complex interaction of tectonic stresses from the convergent plate boundaries surrounding the Indo-Australian plate that are transmitted into the center of the plate through a high-strength upper crust.  相似文献   

9.
The composition and structure of aktashite from the Aktash deposit, Gorny Altai, Russia, have been studied by electron microprobe and X-ray structural analysis. On the basis of close compositions and crystal structures, the identity of aktashite from the Gal-Khaya and Aktash deposits has been demonstrated. Crystals of aktashite are of trigonal symmetry; the unit-cell dimensions are: a = 13.7500(4), c = 9.3600(3) Å, V = 532.54(8) Å3, space group R3, Z = 3 for the composition of Cu6Hg3As4S12, R = 0.043. The structure of aktashite as a framework of vertex-shared HgS4? and CuS4? tetrahedrons of the same orientation is intimately related to the sphalerite-type structure. The earlier identified uncommon cluster group [As4] has been verified and its parameters have been refined. It is shown that the structure may be represented as construction blocks (As4S12)12? packed according to the law of the distorted cubic I-cell.  相似文献   

10.
XANES analyses at the sulfur K-edge were used to determine the oxidation state of S species in natural and synthetic basaltic glasses and to constrain the fO2 conditions for the transition from sulfide (S2−) to sulfate (S6+) in silicate melts. XANES spectra of basaltic samples from the Galapagos spreading center, the Juan de Fuca ridge and the Lau Basin showed a dominant broad peak at 2476.8 eV, similar to the spectra obtained from synthetic sulfide-saturated basalts and pyrrhotite. An additional sharp peak at 2469.8 eV, similar to that of crystalline sulfides, was present in synthetic glasses quenched from hydrous melts but absent in anhydrous glasses and may indicate differences in sulfide species with hydration or presence of minute sulfide inclusions exsolved during quenching. The XANES spectra of a basalt from the 1991 eruption of Mount Pinatubo, Philippines, and absarokitic basalts from the Cascades Range, Oregon, USA, showed a sharp peak at 2482.8 eV, characteristic of synthetic sulfate-saturated basaltic glasses and crystalline sulfate-bearing minerals such as hauyne. Basaltic samples from the Lamont Seamount, the early submarine phase of Kilauea volcano and the Loihi Seamount showed unequivocal evidence of the coexistence of S2− and S6+ species, emphasizing the relevance of S6+ to these systems. XANES spectra of basaltic glasses synthesized in internally-heated pressure vessels and equilibrated at fO2 ranging from FMQ − 1.4 to FMQ + 2.7 showed systematic changes in the features related to S2− and S6+ with changes in fO2. No significant features related to sulfite (S4+) species were observed. These results were used to construct a function that allows estimates of S6+/ΣS from XANES data. Comparison of S6+/ΣS data obtained by S Kα shifts measured with electron probe microanalysis (EPMA), S6+/ΣS obtained from XANES spectra, and theoretical considerations show that data obtained from EPMA measurements underestimate S6+/ΣS in samples that are sulfate-dominated (most likely because of photo-reduction effects during analysis) whereas S6+/ΣS from XANES provide a close match to the expected theoretical values. The XANES-derived relationship for S6+/ΣS as a function of fO2 indicates that the transition from S2− to S6− with increasing fO2 occurs over a narrower interval than what is predicted by the EPMA-derived relationship. The implications for natural systems is that small variation of fO2 above FMQ + 1 will have a large effect on S behavior in basaltic systems, in particular regarding the amount of S that can be transported by basaltic melts before sulfide saturation can occur.  相似文献   

11.
Rietveld refinement of neutron powder diffraction data on four samples of synthetic, iron-bearing tetrahedrite (Cu12?xFexSb4S13) with x = 0.28, 0.69, 0.91, 2.19 and four samples of synthetic tennantite (Cu12?xFexAs4S13) with x = 0.33, 0.38, 0.86, 1.5 indicate unambiguously that iron is incorporated into tetrahedral M1 (12d) sites and not into triangular M2 (12e) sites in the cubic crystal structure (space group I $ \ifmmode\expandafter\bar\else\expandafter\=\fi{4} Rietveld refinement of neutron powder diffraction data on four samples of synthetic, iron-bearing tetrahedrite (Cu12−xFexSb4S13) with x = 0.28, 0.69, 0.91, 2.19 and four samples of synthetic tennantite (Cu12−xFexAs4S13) with x = 0.33, 0.38, 0.86, 1.5 indicate unambiguously that iron is incorporated into tetrahedral M1 (12d) sites and not into triangular M2 (12e) sites in the cubic crystal structure (space group I 3 m). The refinement results also confirm that M2 is a split (24g), flat-pyramidal site situated statistically on both sides of the S1−S1–S2 triangle. In tetrahedrite, this split is about 0.6 ?, in tennantite about 0.7 ?. Trends in bond lengths and magnitude of the M2 split were evaluated by means of linear regression with Fe concentration as the independent variable.  相似文献   

12.
Grüneisen’s parameters are central to studies of Earth’s interior because these link elastic data to thermodynamic properties through the equation of state and can be measured using either microscopic or macroscopic techniques. The original derivation requires that the mode Grüneisen parameter (γi) of the longitudinal acoustic (LA) mode equals the thermodynamic parameter (γth) for monatomic solids. The success of the Debye model indicates that γLA = γth is generally true. Available elasticity data for crystalline solids contain 30 reliable measurements, covering 10 structures, of the pressure derivatives of the bulk (KS) and the shear (G) moduli. For these phases, the measured values of γth and γLA agree well. Other solids in the database have disparate γLA values, suggesting large experimental uncertainties within which γLA = γth. This relationship allows inference of the pressure (P) derivative of the shear modulus (∂G/∂P = G′) from widely available measurements of γth, the isothermal bulk modulus (KT), ∂KT/∂P, and G. We predict G′ as 1.55 for stishovite, 1.6 to 2.15 for MgSiO3 ilmenite, 1.0 for γ-Mg1.2Fe0.8SiO4, and 0 for FeS (troilite). Similarly, G′ measured for MgSiO3 perovskite suggests that KS′ = 4, corroborating volume-pressure data. For many materials, pairs of G′ and KS′ = ∂KS/∂P from independent elasticity studies of a given phase define a nearly linear trend, suggesting systematic errors. Non-hydrostatic conditions and/or pressure calibration likely cause the observed variance in KS′ and G′. The best values for pressure derivatives can be ascertained because the trend defined by measured pairs of G′ with KS′ intersects the relationship of G′ to K′ defined by γLA = γth at a steep angle. Our results for isostructural series show linear correlations of KS′ with KS and of G′ with G. Values of KS′ are nearly 4 for high-pressure phases, which is consistent with the harmonic oscillator model, whereas G′ has a wide range of −1 to 3. Hence, inference of a detailed mineralogy inside the Earth is best constrained by comparing seismic determinations of shear moduli to laboratory measurements.  相似文献   

13.
  相似文献   

14.
Mining of hard rock ore deposits produces large amounts of tailings. The safe disposal and management of these tailings require an extensive characterization that should include their drying and desaturation behaviour. Desiccation tests have been performed to characterize the shrinkage response of low plasticity tailings having an initially loose state. The testing procedure developed for this purpose is briefly described here. The main shrinkage tests results are then presented. The experimental data are compared with those obtained from water retention tests performed in a pressure plate with volume change measurements. These two types of results are combined to define unsaturated (drying and shrinkage) relationships in six complementary planes that include the volumetric shrinkage curve and the water retention curve. Specific material characteristics are then determined, including the shrinkage limit w S, final void ratio e f, and air entry value ψ a. Additional tests were also performed to define critical parameters at the initiation of cracking in terms of suction ψ, water content w, and degree of saturation S r. The original results presented here indicate that the onset of desaturation is closely linked with the end of volumetric straining and with crack initiation. Results also show that the shrinkage limit w S is a function of the specimen initial water content w 0. Other related characteristics are also presented and discussed.  相似文献   

15.
In the present study, four different heuristic techniques viz. multi-layer perceptron (MLP), radial basis function (RBF), self-organizing maps (SOM), and co-active neuro-fuzzy inference system (CANFIS) with hyperbolic tangent and sigmoid transfer functions and two regression-based techniques, i.e., multiple linear regression (MLR) and sediment-rating curve (SRC), were used for suspended sediment modeling. Gamma test (GT), correlation function (CF), M test, and trail–error procedure were applied for estimation of appropriate input variables as well as training data length. The results of the GT and CF suggested the five input variables (Qt, Qt?1, Qt?2, St?1, and St?2, where Qt?1 and St?1 indicate the discharge and sediment values of one previous day) as the best combination. The optimal training data length (75% of total data) was estimated by M test and trail–error procedure for development of the applied models. The MLP with sigmoid transfer function (M-2) performed better than the all other models. The results of sensitivity analysis indicated that the present-day discharge (Qt), 1-day lag discharge (Qt?1) and 1-day lag suspended sediment (St?1) are the most influenced parameters in modeling current day suspended sediment (St).  相似文献   

16.
We discuss the results of deep surveys of a ±10′ strip of the sky, centered on the declination of SS 433, carried out on the Northern sector of the RATAN-600 telescope at 2.7 and 7.6 cm in 1987–2000. The survey objects are cross-identified with sources in the NVSS catalog and the corresponding two-frequency spectral indices determined. We find a decrease in the mean spectral index in the transition from objects with flux densities S 21 ≥ 30 mJy to those with 15 < S 21 < 30 mJy. The constructed log N — logS relation at 2.7 cm has a slope of 3/2 at flux densities ≥300 mJy and flattens at weaker flux densities. The 1.4 GHz (NVSS), 3.94 GHz (RATAN-600), and 11.11 GHz (RATAN-600) data are used to estimate the number of objects per square degree at a wavelength of 1 cm.  相似文献   

17.
The influence of ferrous and ferric iron on the low-temperature heat capacity and vibrational entropy of silicate glasses has been determined by adiabatic calorimetry. Two pairs of samples based on sodium disilicate and calcium Tschermak molecule compositions have been studied. Along with previous data for another Fe-bearing glass, these results have been used to complement the available set of composition independent partial molar relative entropies of oxides in silicate glasses with S298 − S0 values of 56.7 and 116 J/mol for FeO and Fe2O3, respectively. The calorimetric data indicate that the fraction of fivefold coordinated Al is significant in the CaO-“FeO”-Al2O3-SiO2 system and that association of Ca2+ and Na+ with Fe3+ in tetrahedral coordination for charge compensation does not entail significant changes in coordination for these two cations. At very low temperatures, however, the heat capacity is no longer an additive function of composition because of unexpectedly high positive deviations from Debye laws. These anomalies are stronger for the reduced than the oxidized glasses and considerably larger than for iron-free glasses, but their origin cannot be established from the present measurements.  相似文献   

18.
In the Saint-Barthélemy Massif, French Pyrenees, a ductile thrust zone developed in gneisses during retrogression from lower amphibolite facies conditions to the upper greenschist facies. The last major structures formed in the zone are isolated shear bands, divided into three types.Anastomosing, inhomogenous ultramylonitic shear bands (Type I) are subparallel to the mylonitic foliation in the gneiss (Sg). Most of these bands developed by ductile deformation processes only.Planar, homogeneous ultramylonite bands (Type II) are usually oblique to Sg. They generated as pseudotachylyte bands by brittle fracturing and underwent strong subsequent ductile deformation.Type III shear bands are planar and oblique to Sg. They consist of pseudotachylyte, weakly affected by ductile deformation.Type I, II and III bands seem to represent progressively younger structures on a local scale, linked to falling P-T conditions. The systematic variation in orientation of the different shear bands with respect to Sg is interpreted as being due to a different response of brittle and ductile structures to the orientation of the kinematic frame and the rock anisotropy.  相似文献   

19.
We analyzed the instrumental seismicity of Southern Italy in the area including the Lucanian Apennines and Bradano foredeep, making use of the most recent seismological data base available so far. P- and S-wave arrival times, recorded by the Italian National Seismic Network (RSNC) operated by the Istituto Nazionale di Geofisica e Vulcanologia (INGV), were re-picked along with those of the SAPTEX temporary array deployed in the region in the period 2001–2004. For some events located in the upper Val d'Agri, we also used data from the Eni-Agip oil company seismic network. We examined the seismicity occurred during the period between 2001 and 2006, considering 514 events with magnitudes M ≥ 2.0. We computed the VP/VS ratio obtaining a value of 1.83 and we carried out an analysis for the one-dimensional (1D) velocity model that approximates the seismic structure of the study area. Earthquakes were relocated and, for well- recorded events, we also computed 108 fault plane solutions. Finally, using 58 solutions, the most constrained, we computed regional stress field in the study area.Earthquake distribution shows three main seismic regions: the westernmost (Lucanian Apennines) characterized by high background seismicity, mostly with shallow hypocenters, the easternmost below the Bradano foredeep and the Murge with deeper and more scattered seismicity, and finally the more isolated and sparse seismicity localized in the Sila Range and in the offshore area along the northeastern Calabrian coast. Focal mechanisms computed in this work are in large part normal and strike-slip solutions and their tensional axes (T-axes) have a generalized NE–SW orientation. The denser station coverage allowed us to improve hypocenters determination compared to those obtained by using only RSNC data, for a better characterization of the crustal and subcrustal seismicity in the study area.  相似文献   

20.
《Applied Geochemistry》1997,12(1):97-103
Analyses for δ34S of 13 bedded, marine anhydrite samples from the “C” anhydrite member of the Red River Formation (Upper Ordovician) in the North Dakota portion of the Williston basin represent an addition of δ34S data to a portion of the S isotope age curve with few data. Previously published estimates of δ34S for Upper Ordovician marine sulfates apparently are limited to 4 samples from the Saskatchewan portion of the same basin. An adjusted mean value of +25.5‰ was calculated for all known Upper Ordovician δ34S determinations. This value is approximately 2 to 3‰ lighter than the previous estimate, which suggests that δ34S of the world ocean during the Upper Ordovician may have been lighter than previously thought. However, because all δ34S data are from one sedimentary basin, additional S isotopic data from several globally-distributed evaporite basins are needed to evaluate this hypothesis and further constrain δ34S for the Upper Ordovician. Similar re-examination of other portions of the S isotope age curve with limited amounts of data may increase our understanding of the secular variation in δ34S.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号