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1.
Potential source rocks on the Laminaria High, a region of the northern Bonaparte Basin on the North West Shelf of Australia, occur within the Middle Jurassic to Lower Cretaceous early to post-rift sequences. Twenty-two representative immature source rock samples from the Jurassic to Lower Cretaceous (Plover, Laminaria, Frigate, Flamingo and Echuca Shoals) sequences were analysed to define the hydrocarbon products that analogous mature source rocks could have generated during thermal maturation and filled the petroleum reservoirs in the Laminaria High region. Rock-Eval pyrolysis data indicate that all the source rocks contain type II–III organic matter and vary in organic richness and quality. Open system pyrolysis-gas chromatography on extracted rock samples show a dominance of aliphatic components in the pyrolysates. The Plover source rocks are the exception which exhibit high phenolic contents due to their predominant land-plant contribution. Most of the kerogens have the potential to generate Paraffinic–Naphthenic–Aromatic oils with low wax contents. Bulk kinetic analyses reveal a relatively broad distribution of activation energies that are directly related to the heterogeneity in the kerogens. These kinetic parameters suggest different degrees of thermal stability, with the predicted commencement of petroleum generation under geological heating conditions covering a relatively broad temperature range from 95 to 135 °C for the Upper Jurassic−Lower Cretaceous source rocks. Both shales and coals of the Middle Jurassic Plover Formation have the potential to generate oil at relatively higher temperatures (140–145 °C) than those measured for crude oils in previous studies. Hence, the Frigate and the Flamingo formations are the main potential sources of oils reservoired in the Laminaria and Corallina fields. Apart from being a reservoir, the Laminaria Formation also contains organic-rich layers, with the potential to generate oil. For the majority of samples analysed, the compositional kinetic model predictions indicate that 80% of the hydrocarbons were generated as oil and 20% as gas. The exception is the Lower Cretaceous Echuca Shoals Formation which shows the potential to generate a greater proportion (40%) of gas despite its marine source affinity, due to inertinite dominating the maceral assemblage. 相似文献
2.
The Upper Jurassic marlstones (Mikulov Fm.) and marly limestones (Falkenstein Fm.) are the main source rocks for conventional hydrocarbons in the Vienna Basin in Austria. In addition, the Mikulov Formation has been considered a potential shale gas play. In this paper, organic geochemical, petrographical and mineralogical data from both formations in borehole Staatz 1 are used to determine the source potential and its vertical variability. Additional samples from other boreholes are used to evaluate lateral trends. Deltaic sediments (Lower Quarzarenite Member) and prodelta shales (Lower Shale Member) of the Middle Jurassic Gresten Formation have been discussed as secondary sources for hydrocarbons in the Vienna Basin area and are therefore included in the present study.The Falkenstein and Mikulov formations in Staatz 1 contain up to 2.5 wt%TOC. The organic matter is dominated by algal material. Nevertheless, HI values are relative low (<400 mgHC/gTOC), a result of organic matter degradation in a dysoxic environment. Both formations hold a fair to good petroleum potential. Because of its great thickness (∼1500 m), the source potential index of the Upper Jurrasic interval is high (7.5 tHC/m2). Within the oil window, the Falkenstein and Mikulov formations will produce paraffinic-naphtenic-aromatic low wax oil with low sulfur content. Whereas vertical variations are minor, limited data from the deep overmature samples suggest that original TOC contents may have increased basinwards. Based on TOC contents (typically <2.0 wt%) and the very deep position of the maturity cut-off values for shale oil/gas production (∼4000 and 5000 m, respectively), the potential for economic recovery of unconventional petroleum is limited. The Lower Quarzarenite Member of the Middle Jurassic Gresten Formation hosts a moderate oil potential, while the Lower Shale Member is are poor source rock. 相似文献
3.
Geochemical characteristics and hydrocarbon generation modeling of the Jurassic source rocks in the Shoushan Basin, north Western Desert, Egypt 总被引：1，自引：0，他引：1
Mohamed Ragab ShalabyMohammed Hail Hakimi Wan Hasiah Abdullah 《Marine and Petroleum Geology》2011,28(9):1611-1624
The Shoushan Basin is an important hydrocarbon province in the Western Desert, Egypt, but the origin of the hydrocarbons is not fully understood. In this study, organic matter content, type and maturity of the Jurassic source rocks exposed in the Shoushan Basin have been evaluated and integrated with the results of basin modeling to improve our understanding of burial history and timing of hydrocarbon generation. The Jurassic source rock succession comprises the Ras Qattara and Khatatba Formations, which are composed mainly of shales and sandstones with coal seams. The TOC contents are high and reached a maximum up to 50%. The TOC values of the Ras Qattara Formation range from 2 to 54 wt.%, while Khatatba Formation has TOC values in the range 1-47 wt.%. The Ras Qattara and Khatatba Formations have HI values ranging from 90 to 261 mgHC/gTOC, suggesting Types II-III and III kerogen. Vitrinite reflectance values range between 0.79 and 1.12 VRr %. Rock−Eval Tmax values in the range 438-458 °C indicate a thermal maturity level sufficient for hydrocarbon generation. Thermal and burial history models indicate that the Jurassic source rocks entered the mature to late mature stage for hydrocarbon generation in the Late Cretaceous to Tertiary. Hydrocarbon generation began in the Late Cretaceous and maximum rates of oil with significant gas have been generated during the early Tertiary (Paleogene). The peak gas generation occurred during the late Tertiary (Neogene). 相似文献
4.
Palynological and biomarker characteristics of organic facies recovered from Cretaceous–Miocene well samples in the Ras El Bahar Oilfield, southwest Gulf of Suez, and their correlation with lithologies, environments of deposition and thermal maturity have provided a sound basis for determining their source potential for hydrocarbons. In addition to palynofacies analysis, TOC/Rock-Eval pyrolysis, kerogen concentrates, bitumen extraction, carbon isotopes and saturated and aromatic biomarkers enable qualitative and quantitative assessments of sedimentary organic matter to be made. The results obtained from Rock-Eval pyrolysis and molecular biomarker data indicate that most of the samples come from horizons that have fair to good hydrocarbon generation potential in the study area. The Upper Cretaceous–Paleocene-Lower Eocene samples contain mostly Type-II to Type-III organic matter with the capability of generating oil and gas. The sediments concerned accumulated in dysoxic–anoxic marine environments. By contrast, the Miocene rocks yielded mainly Type-III and Type-II/III organic matter with mainly gas-generating potential. These rocks reflect deposition in a marine environment into which there was significant terrigenous input. Three palynofacies types have been recognized. The first (A) consists of Type-III gas-prone kerogen and is typical of the Early–Middle Miocene Belayim, Kareem and upper Rudeis formations. The second (B) has mixed oil and gas features and characterizes the remainder of the Rudeis Formation. The third association (C) is dominated by amorphous organic matter, classified as borderline Type-II oil-prone kerogen, and is typical of the Matulla (Turonian–Santonian) and Wata (Turonian) formations. Rock-Eval Tmax, PI, hopane and sterane biomarkers consistently indicate an immature to early mature stage of thermal maturity for the whole of the studied succession. 相似文献
5.
《Marine and Petroleum Geology》2012,37(1):13-34
Structured organic matters of the Palynomorphs of mainly dinoflagellate cysts are used in this study for dating the limestone, black shale, and marl of the Middle Jurassic (Bajocian–Bathonian) Sargelu Formation, Upper Jurassic (Upper Callovian – Lower Oxfordian) Naokelekan Formation, Upper Jurassic (Kimeridgian and Oxfordian) Gotnia and Barsarine Formations, and Upper Jurassic – Lower Cretaceous (Tithonian-Beriassian) Chia Gara source rock Formations while spore species of Cyathidites australis and Glechenidites senonicus are used for maturation assessments of this succession. Materials' used for this palynological study are 320 core and cutting samples of twelve oil wells and three outcrops in North Iraq.Terpane and sterane biomarker distributions, as well as stable isotope values, were determined for oils potential source rock extracts of Jurassic-Lower Cretaceous strata to determine valid oil-to-source rock correlations in North Iraq. Two subfamily carbonate oil types-one of Middle Jurassic age (Sargelu) carbonate rock and the other of mixed Upper Jurassic/Cretaceous age (Chia Gara) with Sargelu sources as well as a different oil family related to Triassic marls, were identified based on multivariate statistical analysis (HCA & PCA). Middle Jurassic subfamily A oils from Demir Dagh oil field correlate well with rich, marginally mature, Sargelu source rocks in well Mk-2 near the city of Baiji. In contrast, subfamily B oils have a greater proportion of C28/C29 steranes, indicating they were generated from Upper Jurassic/Lower Cretaceous carbonates such as those at Gillabat oil field north of Mansuriyah Lake. Oils from Gillabat field thus indicate a lower degree of correlation with the Sargelu source rocks than do oils from Demir Dagh field.Palynofacies assessments are performed for this studied succession by ternary kerogen plots of the phytoclast, amorphous organic matters, and palynomorphs. From the diagram of these plots and maturation analysis, it could be assessed that the formations of Chia Gara and Sargelu are both deposited in distal suboxic to anoxic basin and can be correlated with kerogens classified microscopically as Type A and Type B and chemically as Type II. The organic matter, comprised principally of brazinophyte algae, dinoflagellate cysts, spores, pollen, foraminifera test linings, and phytoclasts in all these formations and hence affected with upwelling current. These deposit contain up to 18 wt% total organic matters that are capable to generate hydrocarbons within mature stage of thermal alteration index (TAI) range in Stalplin's scale (Staplin, 1969) of 2.7–3.0 for the Chia Gara Formation and 2.9–3.1 for the Sargelu Formation. Case study examples of these oil prone strata are; one 7-m (23-ft) thick section of the Sargelu Formation averages 44.2 mg HC/g S2 and 439 °C Tmax (Rock-Eval pyrolysis analyses) and 16 wt% TOC especially in well Mk-2 whereas, one 8-m (26-ft) thick section of the Chia Gara and 1-m (3-ft) section of Naokelekan Formations average 44.5 mg HC/g S2 and 440 °C Tmax and 14 wt% TOC especially in well Aj-8. One-dimension, petroleum system models of key wells using IES PetroMod Software can confirm their oil generation capability.These hydrocarbon type accumulation sites are illustrated in structural cross sections and maps in North Iraq. 相似文献
6.
华南陆缘出露的上三叠统-白垩系,累计厚度超过10 000m,露头调查未见油苗,烃源岩主要为泥岩、碳质泥岩和煤线,有机质类型以Ⅱ-Ⅲ型为主。上三叠统小水组,发育较深水的海相、Ⅱ型良好烃源岩,TOC为1.17%～5.43%;下侏罗统桥源组发育海陆过渡环境的Ⅲ型良好烃源岩,TOC为1.36%～10.37%;下侏罗统其他层系(金鸡组、银瓶山组、上龙水组、长埔组、吉水门组)发育浅海-半深海相的中等-好的烃源岩,TOC为0.5%～1.76%。烃源岩均已处于成熟-过成熟阶段。小水组、蓝塘群烃源岩品质良好,厚度巨大,在南海北部海域开展中生界烃源岩研究时,值得重点关注是否有与之相当的烃源岩层系发育。 相似文献
7.
Cretaceous sedimentary rocks of the Mukalla, Harshiyat and Qishn formations from three wells in the Jiza sub-basin were studied to describe source rock characteristics, providing information on organic matter type, paleoenvironment of deposition and hydrocarbon generation potential. This study is based on organic geochemical and petrographic analyses performed on cuttings samples. The results were then incorporated into basin models in order to understand the burial and thermal histories and timing of hydrocarbon generation and expulsion.The bulk geochemical results show that the Cretaceous rocks are highly variable with respect to their genetic petroleum generation potential. The total organic carbon (TOC) contents and petroleum potential yield (S1 + S2) of the Cretaceous source rocks range from 0.43 to 6.11% and 0.58–31.14 mg HC/g rock, respectively indicating non-source to very good source rock potential. Hydrogen index values for the Early to Late Cretaceous Harshiyat and Qishn formations vary between 77 and 695 mg HC/g TOC, consistent with Type I/II, II-III and III kerogens, indicating oil and gas generation potential. In contrast, the Late Cretaceous Mukalla Formation is dominated by Type III kerogen (HI < 200 mg HC/g TOC), and is thus considered to be gas-prone. The analysed Cretaceous source rock samples have vitrinite reflectance values in the range of 0.37–0.95 Ro% (immature to peak-maturity for oil generation).A variety of biomarkers including n-alkanes, regular isoprenoids, terpanes and steranes suggest that the Cretaceous source rocks were deposited in marine to deltaic environments. The biomarkers also indicate that the Cretaceous source rocks contain a mixture of aquatic organic matter (planktonic/bacterial) and terrigenous organic matter, with increasing terrigenous influence in the Late Cretaceous (Mukalla Formation).The burial and thermal history models indicate that the Mukalla and Harshiyat formations are immature to early mature. The models also indicate that the onset of oil-generation in the Qishn source rock began during the Late Cretaceous at 83 Ma and peak-oil generation was reached during the Late Cretaceous to Miocene (65–21 Ma). The modeled hydrocarbon expulsion evolution suggests that the timing of oil expulsion from the Qishn source rock began during the Miocene (>21 Ma) and persisted to present-day. Therefore, the Qishn Formation can act as an effective oil-source but only limited quantities of oil can be expected to have been generated and expelled in the Jiza sub-basin. 相似文献
8.
低勘探程度盆地模拟研究——以南黄海盆地北部坳陷为例 总被引：5，自引：0，他引：5
盆地模拟已成为当前沉积盆地研究的重要工具。南黄海盆地北部坳陷自裂陷期演化以来沉积了巨厚的中-新生代碎屑沉积,近年来的地质调查获取的数据为其盆地模拟研究提供了条件,本次研究在收集相关基础数据的基础上,首先对盆地构造热演化史进行了模拟,重建了盆地热史,模拟结果显示其古热流在中-晚侏罗世平均值约为61mW/m2,在约145-74Ma间不断上升至约80 mW/m2,随后缓慢下降至65 mW/m2,并持续到渐新世末期,据此将盆地演化阶段划分为裂前期、裂陷期及裂后期。盆地模拟结果显示北部坳陷在白垩纪逐步进入强裂陷演化阶段并经历快速沉积过程,至晚白垩纪裂陷发育程度中等,在此基础上,对研究区进行了三维盆地模拟,结果显示北部坳陷生烃门限深度大致位于古近系阜宁组顶部,下伏的侏罗系及白垩系烃源岩基本完成生排烃过程,其中侏罗系烃源岩生排烃主要发生在盆地发育的裂陷期及裂后期,而白垩系及古近系烃源岩生排烃主要发生在裂后期。尽管研究区尚处在低勘探程度阶段,但盆地模拟结果已能为研究区下一步的勘探提供重要的信息,此外,本次研究对模拟过程中的主要不确定性也进行了分析。 相似文献
9.
Jurassic-Cretaceous rift successions and basin geometries of the Sverdrup Basin are reconstructed from a review and integration of stratigraphy, igneous records, outcrop maps, and subsurface data. The rift onset unconformity is in the Lower Jurassic portion of the Heiberg Group (approximately 200–190 Ma). Facies transgress from early syn-rift sandstones of the King Christian Formation to marine mudstones of the Jameson Bay Formation. The syn-rift succession of marine mudstones in the basin centre, Jameson Bay to Deer Bay formations, ranges from Early Jurassic (Pleinsbachian) to Early Cretaceous (Valanginian). Early post-rift deposits of the lower Isachsen Formation are truncated by the sub-Hauterivian unconformity, which is interpreted as a break up unconformity at approximately 135–130 Ma. Cessation of rift subsidence allowed for late post-rift sandstone deposits of the Isachsen Formation to be distributed across the entire basin. Marine deposition to form mudstone of the Christopher Formation throughout the Canadian Arctic Islands and outside of the rift basin records establishment of a broad marine shelf during post-rift thermal subsidence at the start of a passive margin stage. The onset of the High Arctic Large Igneous Province at approximately 130 Ma appears to coincide with the breakup unconformity, and it is quite typical that magma-poor rifted margins have mainly post-rift igneous rocks. We extend the magma-poor characterization where rifting is driven by lithospheric extension, to speculatively consider that the records from Sverdrup Basin are consistent with tectonic models of retro-arc extension and intra-continental rifting that have previously been proposed for the Amerasia Basin under the Arctic Ocean. 相似文献
10.
In the Chelif basin, the geochemical characterization reveals that the Upper Cretaceous and Messinian shales have a high generation potential. The former exhibits fair to good TOC values ranging from 0.5 to 1.2% with a max. of 7%. The Messinian series show TOC values comprised between 0.5 and 2.3% and a high hydrogen index (HI) with values up to 566 mg HC/g TOC. Based on petroleum geochemistry (CPLC and CPGC) technics, the oil-to source correlation shows that the oil of the Tliouanet field display the same signature as extracts from the Upper Cretaceous source rocks (Cenomanian to Campanian). In contrast, oil from the Ain Zeft field contains oleanane, and could thus have been sourced by the Messinian black shale or older Cenozoic series. Two petroleum systems are distinguished: Cretaceous (source rock) – middle to upper Miocene (reservoirs) and Messinian (source rock)/Messinian (reservoirs). Overall, the distribution of Cretaceous-sourced oil in the south, directly connected with the surface trace of the main border fault of the Neogene pull-apart basin, rather suggests a dismigration from deeper reservoirs located in the parautochthonous subthrust units or in the underthrust foreland, rather than from the Tellian allochthon itself (the latter being mainly made up of tectonic mélange at the base, reworking blocks and slivers of Upper Cretaceous black shale and Lower Miocene clastics). Conversely, the occurrence of Cenozoic-sourced oils in the north suggests that the Neogene depocenters of the Chelif thrust-top pull-apart basin reached locally the oil window, and therefore account for a local oil kitchen zone. In spite of their limited extension, allochthonous Upper cretaceous Tellian formations still conceal potential source rock layers, particularly around the Dahra Mountains and the Tliouanet field. Additionally they are also recognized by the W11 well in the western part of the basin (Tahamda). The results of the thermal modelling of the same well shows that there is generation and migration of oil from this source rock level even at recent times (since 8 Ma), coevally with the Plio-Quaternary traps formation. Therefore, there is a possibility of an in-situ oil migration and accumulation, even from Tellian Cretaceous units, to the recent structures, like in the Sedra structure. However, the oil remigration from deep early accumulations into the Miocene reservoirs is the most favourable case in terms of hydrocarbon potential of the Chelif basin. 相似文献
11.
We describe (1) bedding-parallel veins of fibrous calcite (beef) and (2) thrust detachments, which we believe provide good evidence for fluid overpressure in source rocks for petroleum. Our examples are from the surface or subsurface of the Magallanes-Austral Basin, which lies at the southern tip of South America. There, the best source rocks for petroleum are of Early Cretaceous age. In the central parts of the basin these source rocks have become overmature, but at the eastern edge, onshore and offshore, they are today either immature or in the oil window.In Tierra del Fuego, the foothills of the Andes consist mainly of sedimentary rocks, which have undergone thin-skinned thrusting. In the Vicuña area (Chile), Early Cretaceous source rocks have reached the surface above thrust detachments, which are visible on seismic data and well data. At the surface, we have found calcite beef, containing hydrocarbons (solid and/or fluid), in the Rio Jackson and Vicuña formations, which have reached the wet gas window. In the Rio Gallegos area (Argentina), the source rocks have not reached the surface, but seismic and well data provide good evidence for thin-skinned thrusting above flat-lying detachments in Early Cretaceous source rock, where it is in the early oil window. In contrast, there is little or no deformation where the source rock is still immature. Thus the deformation front coincides with the maturity front. Next to the central parts of the basin, where the source rocks have reached the surface within the Andes proper, they have undergone low-grade metamorphism. Within these source rocks, we have found beef veins, but of quartz, not calcite. To the east, within the foreland basin, seismic and well data provide evidence for a few compressional structures, including thin-skinned detachments in the deeply buried source rock. Finally, in the northern part of the basin (Santa Cruz province, Argentina), where it is shallower, the source rocks have reached the surface in the foothills, above a series of back-thrusts. At Lago San Martín, the source rocks have reached the oil window and they again contain calcite beef.In conclusion, where we have examined Early Cretaceous source rocks at the surface, they contain either calcite beef (if they have reached the late oil window or wet gas window) or quartz beef (if they are overmature). Independent evidence for overpressure, in the form of source-rock detachments, comes from subsurface data, especially at the southern end of the basin, where the source rocks are not overmature and deformation is relatively intense. Thus we argue that hydrocarbon generation has led to overpressure, as a result of chemical compaction and load transfer, or volume changes, or both. 相似文献
12.
鄂尔多斯盆地北部主力气源岩太原组、山西组煤系地层热成熟史的研究对本区天然气充注过程和有利目标区预测具有重要的参考价值。在对研究区烃源岩评价和一维、二维地质建模研究的基础上。利用BasinMod盆地模拟软件对单井以及研究区内二维剖面、平面进行了煤系烃源岩热演化史模拟研究。研究结果表明：（1）该区在中三叠世进入生烃门限，中侏罗世以后，烃源岩持续埋深，早白垩世末期至最大埋深（4000m左右），绝大多数的天然气都在这一阶段生成，早白垩世末构造抬升以后只有少量天然气生成；（2）研究区上古生界太原组和山西组煤系源岩最大累积生烃强度可达到2200×10^8m^3／km^2，对现今天然气的分布具有较强的控制作用。 相似文献
13.
《Marine and Petroleum Geology》2012,32(1):53-69
The objectives of our study were to assess the thickness, lateral extent, organic richness and maturity of the potential source rocks in Hungary and to estimate the volumes of hydrocarbons generated, in order that potential shale gas and shale oil plays could be identified and characterised.The Upper Triassic Kössen Marl in south-west Hungary could represent the best potential shale gas/shale oil play, due to its high organic richness, high maturity and the presence of fracture barriers. The area of gas- and oil-generative maturity is around 720 km2 with the unexpelled petroleum estimated to be up to 9 billion barrel oil-equivalent.The Lower Jurassic sediments of the Mecsek Mountains and under the Great Plain contain fair quality gas-prone source rocks, with low shale gas potential, except for a thin Toarcian shale unit which is richer in organic matter. The latter could form a potential shale gas play under the Great Hungarian Plain, if it is thicker locally.The Lower Oligocene Tard Clay in north-east Hungary could represent the second best potential shale oil play, due to its organic richness, favourable maturity and large areal extent (4500 km2) with around 7 billion barrel oil-equivalent estimated in-place volume of petroleum.Middle Miocene marine formations could represent locally-developed shale gas plays; they have fair amounts of organic matter and a mixture of type II/III kerogen, but their vertical and lateral variability is high.The Upper Miocene lacustrine Endrőd Marl contains less organic matter and the kerogen is mainly type III, which is not favourable for shale gas generation. The high carbonate and clay content, plus the lack of upper and lower fracture barriers would represent additional production challenges. 相似文献
14.
Reinhard Gratzer Achim BechtelReinhard F. Sachsenhofer Hans-Gert LinzerDoris Reischenbacher Hans-Martin Schulz 《Marine and Petroleum Geology》2011,28(6):1171-1186
The Alpine Foreland Basin is a minor oil and moderate gas province in central Europe. In the Austrian part of the Alpine Foreland Basin, oil and minor thermal gas are thought to be predominantly sourced from Lower Oligocene horizons (Schöneck and Eggerding formations). The source rocks are immature where the oil fields are located and enter the oil window at ca. 4 km depth beneath the Alpine nappes indicating long-distance lateral migration. Most important reservoirs are Upper Cretaceous and Eocene basal sandstones.Stable carbon isotope and biomarker ratios of oils from different reservoirs indicate compositional trends in W-E direction which reflect differences in source, depositional environment (facies), and maturity of potential source rocks. Thermal maturity parameters from oils of different fields are only in the western part consistent with northward displacement of immature oils by subsequently generated oils. In the eastern part of the basin different migration pathways must be assumed. The trend in S/(S + R) isomerisation of ααα-C29 steranes versus the αββ (20R)/ααα (20R) C29 steranes ratio from oil samples can be explained by differences in thermal maturation without involving long-distance migration. The results argue for hydrocarbon migration through highly permeable carrier beds or open faults rather than relatively short migration distances from the source. The lateral distance of oil fields to the position of mature source rocks beneath the Alpine nappes in the south suggests minimum migration distances between less than 20 km and more than 50 km.Biomarker compositions of the oils suggest Oligocene shaly to marly successions (i.e. Schoeneck, Dynow, and Eggerding formations) as potential source rocks, taking into account their immature character. Best matches are obtained between the oils and units a/b (marly shale) and c (black shale) of the “normal” Schöneck Formation, as well as with the so-called “Oberhofen Facies”. Results from open system pyrolysis-gas chromatography of potential source rocks indicate slightly higher sulphur content of the resulting pyrolysate from unit b. The enhanced dibenzothiophene/phenanthrene ratios of oils from the western part of the basin would be consistent with a higher contribution of unit b to hydrocarbon expulsion in this area. Differences in the relative contribution of sedimentary units to oil generation are inherited from thickness variations of respective units in the overthrusted sediments. The observed trend towards lighter δ13C values of hydrocarbon fractions from oil fields in a W-E direction are consistent with lower δ13C values of organic matter in unit c. 相似文献
15.
The Upper Cretaceous Mukalla coals and other organic-rich sediments which are widely exposed in the Jiza-Qamar Basin and believed to be a major source rocks, were analysed using organic geochemistry and petrology. The total organic carbon (TOC) contents of the Mukalla source rocks range from 0.72 to 79.90% with an average TOC value of 21.50%. The coals and coaly shale sediments are relatively higher in organic richness, consistent with source rocks generative potential. The samples analysed have vitrinite reflectance in the range of 0.84–1.10 %Ro and pyrolysis Tmax in the range of 432–454 °C indicate that the Mukalla source rocks contain mature to late mature organic matter. Good oil-generating potential is anticipated from the coals and coaly shale sediments with high hydrogen indices (250–449 mg HC/g TOC). This is supported by their significant amounts of oil-liptinite macerals are present in these coals and coaly shale sediments and Py-GC (S2) pyrograms with n-alkane/alkene doublets extending beyond nC30. The shales are dominated by Type III kerogen (HI < 200 mg HC/g TOC), and are thus considered to be gas-prone.One-dimensional basin modelling was performed to analysis the hydrocarbon generation and expulsion history of the Mukalla source rocks in the Jiza-Qamar Basin based on the reconstruction of the burial/thermal maturity histories in order to improve our understanding of the of hydrocarbon generation potential of the Mukalla source rocks. Calibration of the model with measured vitrinite reflectance (Ro) and borehole temperature data indicates that the present-day heat flow in the Jiza-Qamar Basin varies from 45.0 mW/m2 to 70.0 mW/m2 and the paleo-heat flow increased from 80 Ma to 25 Ma, reached a peak heat-flow values of approximately 70.0 mW/m2 at 25 Ma and then decreased exponentially from 25 Ma to present-day. The peak paleo-heat flow is explained by the Gulf of Aden and Red Sea Tertiary rifting during Oligocene-Middle Miocene, which has a considerable influence on the thermal maturity of the Mukalla source rocks. The source rocks of the Mukalla Formation are presently in a stage of oil and condensate generation with maturity from 0.50% to 1.10% Ro. Oil generation (0.5% Ro) in the Mukalla source rocks began from about 61 Ma to 54 Ma and the peak hydrocarbon generation (1.0% Ro) occurred approximately from 25 Ma to 20 Ma. The modelled hydrocarbon expulsion evolution suggested that the timing of hydrocarbon expulsion from the Mukalla source rocks began from 15 Ma to present-day. 相似文献
16.
Maturity and source rock potential of organic rich beds in the Triassic Schei Point Group in the Sverdrup Basin, Arctic Canada have been investigated using reflected light microscopy and the results are compared with other maturity parameters determined geochemically (i.e. Rock Eval, and biomarker maturation parameters). The samples evaluated belong to the Eden Bay Member of the Hoyle Bay Formation and contain a predominance of marine algal material, in the form of Tasmanales, and dinoflagellates, along with mixed terrestrial organics.The rock matrix is dominantly carbonate with some shaly input, indicating that the rocks were deposited in an iron-poor highly euxinic environment. With few exceptions there is good agreement between parameters,determined using microscopy; namely %Ro, λmax and
and geochemical parameters, Tmax, HI,
steranes,
C29 steranes. The ternary diagram showing the abundance of normalized C27, C28 and C29 regular steranes indicates a mostly marine depositional environment for the Schei Point source rock. This is confirmed by the abundance of marine fauna and flora in these samples.Analytical results from several different techniques indicate that the source rocks become more mature from the margin towards the axis of the Sverdrup Basin. This is due, in part, to the increase in overburden of sediments in the axis of the basin. Also the high thermal conductivity of salt has strongly influenced the maturity of Schei Point source rocks over the crest of the salt cored structures, i.e. Well Hazen F-54, and the proximity of salt has enhanced maturation levels at Well Rock Point J-43. The sections investigated were also considered to have an excellent gas potential due to their higher than average TOC content. 相似文献
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17.
The Unst Basin is situated in the northern North Sea between the East Shetland Basin and the Shetland Isles. The basin is essentially a three-armed, Permo-Triassic fault-controlled basin containing up to 3600 m of red-beds. This is overlain by a westerly thickening Jurassic and early Cretaceous sequence, the stratigraphy of which is very similar to that of the East Shetland Basin. In particular, the Brent Group (140 m), Humber Group (685 m) and Cromer Knoll Group (300 m) are well represented.As a result of Laramide uplift of the area, the thick Upper Cretaceous and Palaeocene strata of the East Shetland Basin are absent from the Unst Basin. This uplift resulted in substantial erosion within the Unst Basin providing the major source for Palaeocene sands in the Viking Graben and the Faeroes Basin. Late Palaeocene and younger Tertiary strata transgress westwards across this erosion surface.Petroleum exploration within the basin culminated in the drilling of two exploration wells. These wells encountered potential reservoir and source rocks in the Jurassic section. However, geochemical analyses indicate these source rocks are immature for hydrocarbon generation within the Unst Basin. It is concluded that the Unst Basin has a low petroleum potential. 相似文献
18.
Mixed layer clay minerals, vitrinite reflectance and geochemical data from Rock-Eval pyrolysis were used to constrain the burial evolution of the Mesozoic–Cenozoic successions exposed at the Kuh-e-Asmari (Dezful Embayment) and Sim anticlines (Fars province) in the Zagros fold-and-thrust belt. In both areas, Late Cretaceous to Pliocene rocks, show low levels of thermal maturity in the immature stages of hydrocarbon generation and early diagenetic conditions (R0 I–S and Ro% values < 0.5). At depths of 2–4 km, Tmax values (435–450 °C) from organic-rich layers of the Sargelu, Garau and Kazhdumi source rocks in the Kuh-e-Asmari anticline indicate mid to late mature stages of hydrocarbon generation. One dimensional thermal models allowed us to define the onset of oil generation for the Middle Jurassic to Eocene source rocks and pointed out that sedimentary burial is the main factor responsible for measured levels of thermal maturity. Specifically, the Sargelu and Garau Formations entered the oil window prior to Zagros folding in Late Cretaceous times, the Kazhdumi Formation during middle Miocene (syn-folding stage), and the Pabdeh Formation in the Late Miocene–Pliocene after the Zagros folding. In the end, the present-day distribution of oil fields in the Dezful Embayment and gas fields in the Fars region is primarily controlled by lithofacies changes and organic matter preservation at the time of source rock sedimentation. Burial conditions during Zagros folding had minor to negligible influence. 相似文献
19.
Identification of the main hydrocarbon source rocks of the large Puguang gas field (northeastern Sichuan Basin, southwest China) has been the subject of much discussion in recent years. A key aspect has been the lack of a comprehensive understanding of the development of hydrocarbon source rocks of the Upper Permian Longtan Formation, which had been thought to contain mainly coal seams and thick carbonate layers. In this paper, based on geological data from more than ten wells and outcrops and their related mineralogy and geochemistry, we investigated the depositional environment and main factors controlling organic matter enrichment in the Longtan Formation. We propose a model which combines information on the geological environment and biological changes over time. In the model, organic matter from prolific phytoplankton blooms was deposited in quiescent platform interior sags with rising sea-levels. During the Longtan period, the area from Bazhong to Dazhou was a platform interior sag with relatively deep water and a closed environment, which was controlled by multiple factors including syngenetic fault settling, isolation of submarine uplifts and rising sea-levels leading to water column stratification. Although the bottom water was anoxic, the phytoplankton were able to bloom in the well-lit upper euphotic zone thus giving rise to a set of sapropelic black shales and marlstones containing mostly algal organic matter with minor terrestrial contributions. As a consequence, these rocks have a high hydrocarbon generation potentials and can be classified as high-quality source rocks. The area from Bazhong to Dazhou is a center of hydrocarbon generation, being the main source of reservoired paleo-oils and presently discovered as pyrobitumen in the Puguang gas field. The identification of these source rocks is very important to guide future petroleum exploration in the northeastern Sichuan Basin. 相似文献
20.
Uppermost Jurassic and Lower Cretaceous strata of the Silesian Nappe of the Outer Western Carpathians contain large amounts of shale, which can, under favourable conditions, become source rocks for hydrocarbons. This study analysed 45 samples from the area of Czech Republic by the means of palynofacies analysis, thermal alteration index (TAI) of palynomorphs and total organic carbon (TOC) content to determine the kerogen type, hydrocarbon source rock potential, and to interpret the depositional environment. Uppermost Jurassic Vendryně Formation and Lower Cretaceous Formations (Těšín Limestone, Hradiště and Lhoty) reveal variable amount of mostly gas prone type III kerogen. Aptian Veřovice Formation has higher organic matter content (over 3 wt.%) and oil-prone type II kerogen. Organic matter is mature to overmature and hydrocarbon potential predisposes it as a source of gas. Aptian black claystones of the Veřovice Fm. are correlatable with oceanic anoxic event 1 (OAE1). 相似文献