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1.
In the present investigation all the working lignite seams of Cambay basin of Gujarat have been studied to see the distribution and geochemistry of selected major/minor elements like Fe, Ca, Na, K, Mg, and Mn and trace elements like Cu, Co, Cr, Cd, Ni, Pb and Zn. The vertical variation of these elements along the seam profiles has been studied to see the pattern of distribution of these elements and also to know the horizons of their enrichment and the probable cause. Further, these elements have been correlated among themselves and also with organic and inorganic matter of lignite. The correlation study indicates that in Tadkeshwar upper seam Fe has its affinity with huminite while Mg and Na have their affinity with liptinite and in Tadkeshwar lower seam Na has an affinity with liptinite. In Vastan upper seam Mn and Cu are associated with inertinite and Na with huminite while in Vastan lower seam Cu relates to huminite and Cd to liptinite and huminite. In Rajpardi seam Ca and Co are associated with huminite. The study provides information on the mode of occurrence of elements of less studied lignites of western India.  相似文献   

2.
A biaxial testing program has been performed to study the process of brittle failure in crystalline rocks. Dental plaster has been selected as a model material, and mixing with different ratios of distilled water, different types of common minerals of crystalline rocks have been simulated in the form of brick-like small elements. These elements have been interlocked together according to four systematic patterns and final specimens with 180 × 180 × 76 mm dimensions have been obtained. Details of different types of cracks observed during loading process, effects of mechanical, geometrical and confining pressure on the cracking intensity, the influence of different types of heterogeneity on the macroscopic properties of a system of interlocked elements, and the sequence of events during the failure process are presented in this paper. Based on these observations, a revised mechanism for brittle failure is proposed.  相似文献   

3.
The Borrobol Tephra has been identified as one of the key tephra horizons for the Lateglacial time period but it also exemplifies many of the promises and problems of tephrochronology. Additional horizons with similar major element composition and approximately the same age have been identified around the North Atlantic region. Here, we revisit the Borrobol Tephra identified at two Swedish sites, Hässeldala port and Skallahult, and also the Borrobol type‐site in Scotland. We present the first set of minor element data (trace and rare earth analyses) along with new analyses of major elements from these three sites. The analysed minor and the trace elements have a similar signature; however, the glass from the Scottish type‐site seems to imply two populations. To answer if this truly represents two populations, or if it reflects magmatic differentiation additional and larger data sets of minor elements are needed. The new major elements are compared to other Borrobol‐type tephras identified in the North Atlantic region. Our results are in line with earlier investigations, which showed no differences in major elements. Further, comparison of minor elements from glass analyses from our sites with those for eruptions associated with Icelandic central volcanoes implies an Icelandic origin for the Borrobol‐type tephras.  相似文献   

4.
Radiometrically anomalous tuffaceous rocks occur as conformable lenses in a volcano-sedimentary sequence of Neogene age near the village of Sarkhanlu, northwest Iran. The anomalous rocks have been extensively altered by hydrothermal fluids, and kaolinization and silicification are widespread. 250 samples of the anomalous and background tuffs and other sediments have been analyzed for Fe, Mn and 18 trace elements. Enhanced levels of Ag, As, Mo, Pb, Sn, Sr, Th, U, W and Zr indicate an alkaline volcanic origin of the tuffaceous material, and the elements of this association dominate the statistical analysis of the geochemical data. Maximum U and Th values are among the highest ever recorded in extrusive volcanic rocks. A zone of kaolinization contains increased levels of U, Th, Pb and Sr relative to the unaltered country rock, although nine other elements are depleted in the zone. This association of elements is recognized in the radiometrically anomalous lithologies, particularly in the kaolinized tuffs, and indicates the availability of U in the hydrothermal fluids causing the alteration. Although U mineralization has not yet been found at Sarkhanlu, comparisons with the similar geological environment in central Italy and elsewhere suggest possible exploration criteria for the future. Distinct sedimentary U associations have been defined in tuffs with only background radioactivity and in dark, calcareous shales.  相似文献   

5.
New data have been obtained on the distribution of the petrogenetic and rare-earth elements in the meimechite-series of rocks in Polar Siberia. It is shown that the meimechites, alkali picrites, and khatangites are comagmatic. The compositions of the primitive melts for the meimechite series have been estimated. It is suggested that the primary meimechite magmas were produced during the melting of lithosphere harzburgites that were enriched in incompatible elements due to infiltration of diapir melts with a low degree of partial melting.  相似文献   

6.
高任 《地质与勘探》2022,58(3):514-531
江西城门山铜矿床通过开展深边部找矿勘查,发现其探明的伴生稀散金属资源量达到大型甚至超大型规模,其中碲、铊、镉、硒等稀散金属已综合回收利用,但研究程度还很低。本文收集整理城门山矿床的编录及化验资料,总结该矿床稀散金属的矿化特征和空间分布规律,并探讨稀散金属富集机理和控制因素。结果表明,城门山矿床的稀散元素多倾向于富集在似层状硫化物型矿石中,赋存状态以独立稀散金属矿物和赋存于黄铁矿、黄铜矿和闪锌矿等硫化物晶格为主,具有随金属硫化物总量变化而变化的空间分带特征。矿石中的w(Cd)与w(Zn)具明显的正相关性(R^(2)=0.65),其他稀散元素的含量与Cu多呈弱正相关性。本文提出碲与铊与似层状硫化物矿石密切相关,镉的超常富集主要与锌的成矿作用有关,它们在热液流体萃取、运移、沉淀过程中元素分离相对较少,岩浆结晶分异导致热液流体中铟含量降低,铼主要赋存在辉钼矿中,与幔源物质参与密切相关。同时,还建立了城门山含稀散金属铜矿床的成矿模式。  相似文献   

7.
花岗岩类化学元素丰度研究是花岗岩类地球化学和地壳丰度研究的一项重要内容,一直为国际上所关注,并有很多学者先后发表了不同的花岗岩类化学成分和元素丰度的数据,但迄今为止世界上还没有花岗岩类地球化学图的出版。本文以中国56种元素花岗岩类地球化学图为基础,探讨了中国大陆花岗岩类各元素地球化学图所展示的多元素的区域分布特征、空间分布规律和分布模式。结果显示,花岗岩类各元素的空间分布模式与中国花岗岩类的分布和特征密切相关。花岗岩类地球化学图能够清晰地反映出花岗岩类化学成份的空间变化规律和特征。  相似文献   

8.
济阳坳陷第三纪火成岩地球化学特征研究   总被引:1,自引:0,他引:1       下载免费PDF全文
张玉涛 《地质科学》2014,(1):275-286
对济阳坳陷第三纪火成岩样品进行了系统的地球化学分析,分析结果表明:这些火成岩的SiO2含量较低(大部分低于50%),属于基性火成岩,岩石类型主要为玄武岩和粗面玄武岩。绝大部分样品的TiO2含量较高,为1.64%~2.09%,不同于TiO2含量较低的岛弧火山岩。碱性样品和亚碱性样品数量相当,Na2O含量都高于K2O含量,Na2O/K2O最高可达2.75。这些样品具有富集大离子亲石元素(LILE)如Rb和Ba,亏损重稀土元素(HREE)如Yb和Lu。具有右倾的球粒陨石标准化稀土元素配分模式和原始地幔标准化不相容元素分布模式。源区分析表明,这些火成岩的源区为富集的受过流体交代的岩石圈地幔。运用不活动元素对这些样品进行了构造环境的判别,结果表明这些样品的主体形成于板块内部环境。  相似文献   

9.
自20世纪50年代河南滦川钼(钨)矿床的发现,经几十年勘查研究和对区域水沉积物测量的资料分析,各构造单元元素丰度、富集系数和富集分布特征表明,区内富集元素为Mo、W、Au、Ag、Pb、Cu、Bi,尤其是Mo、W是区内重要的成矿元素处于中朝板块南缘的东秦岭—大别山钼(钨)矿带,是我国重要的钼(钨)矿带之一。研究表明,主要钼矿床属斑岩型,其次为矽卡岩型、脉型。成因多与中生代花岗质斑岩有关。文章着重对大别地区矿化中酸性小岩体地球化学特征进行讨论,以期为在该区普查找矿起到借鉴作用。  相似文献   

10.
新兴关键矿产——三稀(稀有、稀土、稀散)金属是支撑国家“十四五、十五五”节能环保、新一代信息技术、生物、高端装备制造、新材料、新能源以及新能源汽车7大战略性新兴产业发展的关键矿产资源。四川省三稀金属矿产资源非常丰富。但以往对三稀资源重视不够,资源家底不清,相关成矿作用的研究较为粗浅。笔者在总结三稀资源分布特点、分析研究成矿地质背景、典型矿床以及元素富集规律的基础上,估算了17种三稀金属的资源量,预测了资源潜力,提出四川进一步找矿勘查方向。  相似文献   

11.
笔者从岩性地层、孢粉组合、地层对比等方面,对西河盆地红层的地层时代与沉积环境,进行深入的研究和探讨并追朔其地质演化历程。本区首次发现的孢粉组合是以草本植物蒿属为优势种,松、胡桃及禾本科为次优势种的疏林灌丛草原,其中胡桃属、榆属为典型的古—新近纪属种。根据岩性特征及生物特征综合分析研究,认为西河盆地“红土”地层属于新近系上新统宝格达拉组(N2b),地层层序类型在平面上体现出从盆地边缘到中心沉积环境由河流、冲积扇、三角洲到湖泊的变化规律。  相似文献   

12.
谢彪武 《地质与勘探》2012,48(4):807-814
[摘 要] 本文通过对阿里住浪铜银矿区1:10000 地质填图和1:10000 构造地球化学测量,系统 总结了西藏阿里住浪铜银矿区构造地球化学特征,并得出以下几点认识:住浪矿区不同岩性中Ag、Cu、 As、Sb 浓度克拉克值和变异系数均较大,元素分布型式具对数双峰分布,表明这些元素卷入了成矿作 用;元素组合分析具成矿多阶段性,矿区主成矿元素组合为Cu、Ag,可作为找矿的指示元素;综合分析地 质和地球化学资料,在矿区圈定5 个构造地球化学异常区,其中玉号、芋号异常带具较好的找矿前景。  相似文献   

13.
Major and trace element analyses are reported for 70 lavas from the Tertiary succession of eastern Iceland. The low grade regional metamorphism responsible for the zeolite zones appears to have caused significant mobilization of some elements, particularly Si, Mg, K, Rb, Sr and light rare earth elements (LREE). In contrast, values for Ti, P, Zr, Y, Nb, Ta, Hf and some of the rare earth elements show a high degree of correlation and this is taken to imply that these elements have been relatively unaffected by metasomatic transport. The demonstrated mobility of Sr and LREE suggest that Sr isotopic and rare earth data obtained from the eastern Iceland lavas must be interpreted with caution.  相似文献   

14.
丁祖国  傅家谟 《沉积学报》1992,10(1):108-117
运用中子活化分析方法对江汉油田原油和生油岩有机抽提物中过渡族微量元素Sc、V、CrMn、Fe、Co、Ni、Zn等进行了重点研究,测定了这些元素的丰度值。研究了这些元素在原油和有机抽提物族组份:沥表质、非烃和芳香烃中的变化规律。在此基础上,讨论了这些微量元素的相关性,并运用它们的丰度比值对数分布和归一化对数分布,进行了油-源对比的尝试。  相似文献   

15.
On the modeling of the state dependency of granular soils   总被引:3,自引:0,他引:3  
Experimental studies have revealed that principal elements of the mechanical behavior of granular soils like the angles of internal peak friction and dilatancy are highly influenced by the combined effect of soil density and mean principal effective stress. In the literature, various empirical correlations between these elements and some parameters indicating soil state have been suggested. Herein, by using two well-known empirical expressions for state dependent peak friction and dilatancy angles, proper constitutive equations are derived and implemented in a stress ratio-based bounding surface plasticity framework. It is shown that the modified model is capable of simulating sand response in either loose or dense states using a unique set of parameters.  相似文献   

16.
Instrumental neutron activation analysis has been applied to the analysis of recently issued NBS reference materials SRM 1633a Fly Ash and SRM 1632a Bituminous Coal. Only the nuclides with half-lives of less than 48 hours have been used. The results for the determination of 18 elements (Fly Ash) and 19 elements (Coal) are compared with the values given by NBS and with recent results obtained by other investigators.  相似文献   

17.
Early (>3 Gy) wetter climate conditions on Mars have been proposed, and it is thus likely that pedogenic processes have occurred there at some point in the past. Soil and rock chemistry of the Martian landing sites were evaluated to test the hypothesis that in situ aqueous alteration and downward movement of solutes have been among the processes that have transformed these portions of the Mars regolith. A geochemical mass balance shows that Martian soils at three landing sites have lost significant quantities of major rock-forming elements and have gained elements that are likely present as soluble ions. The loss of elements is interpreted to have occurred during an earlier stage(s) of weathering that may have been accompanied by the downward transport of weathering products, and the salts are interpreted to be emplaced later in a drier Mars history. Chemical differences exist among the sites, indicating regional differences in soil composition. Shallow soil profile excavations at Gusev crater are consistent with late stage downward migration of salts, implying the presence of small amounts of liquid water even in relatively recent Martian history. While the mechanisms for chemical weathering and salt additions on Mars remain unclear, the soil chemistry appears to record a decline in leaching efficiency. A deep sedimentary exposure at Endurance crater contains complex depth profiles of SO4, Cl, and Br, trends generally consistent with downward aqueous transport accompanied by drying. While no model for the origin of Martian soils can be fully constrained with the currently available data, a pedogenic origin is consistent with observed Martian geology and geochemistry, and provides a testable hypothesis that can be evaluated with present and future data from the Mars surface.  相似文献   

18.
All data reported by 200 analysts (106 laboratories) are presented for the four ANRT samples: Diorite DR-N, Serpentine UB-N, Bauxite BX-N and Disthène DT-N. Recommended values are given for the major and minor elements. As far as the as trace elements are concerned, DR-N has been characterized for 35 elements whereas the other three samples have been for only 20 elements. Wherever possible, brief comments have been inserted so as to explain our way of assigning recommended or proposed values.
After more than a decade of existence the total number of data reported for all the four samples reach only 3200 units which are not sufficient enough for a valid evaluation of compiled data. It is also pointed out that these samples are most likely to be available even during the next century as they have been prepared in large quantities of the order of one ton. A plea is therefore made for contribution of more data particularly for trace elements and for major elements which are present as trace elements in UB-N, BX-N and DT-N.  相似文献   

19.
The epidioritc and quartzite of the Malin Head district, (Ireland) are considered by Holmes and Reynolds [7] to be metasomatically transformed into skarn-rocks and mica-schist respectively. The trace element contents of these rocks were investigated using semi-quantitative methods in order to study the behaviour of the different trace elements during the metasomatic changes which have taken place. The elements which have been determined are Rb, Ba, Ag and Pb; Sr, Y and La; Li, Cr, Ni, Co, V, Cu, Sc, Sn and Mo; Ga; Zr, Be, Tl, Ge and In. The trace elements follow the major elements for which they can substitute in favourable crystal lattices, the substitution being in accord with Goldschmidts rules. Rb, Ba and probably Pb and Ag follow and substitute for K; Sr and Y for Ca and probably K; Li, Cr, Ni, Co, V, Cu, Sc, Sn and Mo for Mg, Fe2 and Fe3; and Ga for Al.  相似文献   

20.
The effect of low grade hydrous burial metamorphism (prehnite-pumpellyite facies) upon the rare earth elements (REE) has been studied by using samples from the Cliefden Outcrop, New South Wales. The REE, together with other reputedly immobile elements, have been mobilised during the metamorphism. Although mobile, the REE have behaved remarkably coherently with little light rare earth (LREE) fractionation. This is reflected in the chondrite normalised patterns which are sub-parallel to parallel in shape. High correlations of REE with other elements can be used to predict the maximum likely variation of these elements in the studied outcrop. The high correlations do not necessarily mean that, for similarly metamorphosed terrains, crystallisation-differentiation processes have operated but may rather have resulted from strong geochemical coherence during post-crystallisation elemental redistribution. The REE do not appear to be strongly domain controlled within the Cliefden Outcrop.  相似文献   

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