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1.
The radionuclides137Cs,210Pb and7Be have been examined in the alpine Rhoˆne watershed (Switzerland) during a period of two years in order to evaluate their usefulness as tracers of the removal and transport rate of top-soil particles and particle-reactive contaminants of atmospheric origin. The specific activities of the radionuclides in fluvial suspension show a distinct seasonal pattern which depends on the hydrologic regime of the stream and the sources of the suspended matter. Input-output budgets based on the atmospheric deposition and fluvial removal of three radionuclides in the alpine Rhoˆne watershed are used to estimate their erosional residence times. The simplest one box model yields mean residence times of about 800 and 1400 years for137Cs and210Pb, respectively. The removal rate of short-lived7Be suggests that a part of the watershed (0.6–2.3% of the total surface) is exposed to a rapid erosion, in which the mean residence time of the radionuclides is in the range of 1–220 days. This has little influence on the calculated residence time of137Cs but increases the estimated residence time of210Pb in soil to over 1800 years. The use of210Pb-7Be pair in fluvial output may be very helpful in the assessment of the impact of atmospheric pollutants on the water quality in rivers and lakes.  相似文献   

2.
This paper discusses major environmental alteration processes and describes a set of chemical tests that have been developed to monitor compositional changes in hydrocarbon fuels released into the environment. The methods examine various homologous series of hydrocarbons including straight chain (paraffins or n-alkanes), branched chain (isoparaffins or isoprenoids), alicyclic (naphthenes or alkylated cyclohexanes), polycyclic (steranes and terpanes), and aromatic structures (benzene, toluene, ethylbenzene. xylenes, alkylated benzenes, polycyclic aromatic hydrocarbons, and aromatic steranes). Each one of these groups of hydrocarbons has a different tolerance to environmental alteration by evaporation, dissolution (water washing), and biodegradation. When used as an analytical system on environmental samples, the data obtained provide information on fuel type recognition patterns and on degradation levels of the various fuels, allowing for an estimate of residence time.  相似文献   

3.
The toxicity of ten polynuclear aromatic hydrocarbons (PNAs) to Neanthes arenaceodentata was studied in replicate 96 h bioassays with specific hydrocarbons in solution. Relative solubilities for each PNA were derived in short-term equilibration experiments. Disappearance of representative di-, tri, tetra- and pentacyclic-aromatic hydrocarbons from test solutions was also characterized by ultraviolet spectrophotometry. PNA toxicity and residence time in test solutions were directly related to molecular weight (MW), while relative solubility is inversely related to MW. 96 h TLm values for the diaromatic PNAs naphthalene, 2,6-dimethylnaphthalene, and 2,3,6-trimethylnaphthalene were 3.8, 2.6 and 2.0 ppm, respectively. Phenanthrene, fluorene and 1-methylphenanthrene (triaromatics) exhibited 96 h TLm values of 0.6, 1.0 and 0.3 ppm, respectively. None of the tetra- and pentacyclic-aromatics (chrysene, 3,4-benzo(a)pyrene, 1,2,5,6-dibenzanthracene) were toxic up to the highest concentration tested (1 ppm), excepting fluoranthene, with a 96 h TLm of 0.5 ppm. PNA toxicity appears to be related to both solubility and residence time in test solutions.  相似文献   

4.
Gorgan Bay is a semi-enclosed basin located in the southeast of the Caspian Sea, Iran. The bay is recognized as a resting place for migratory birds as well as a spawning habitat for native fish. However, apparently, no detailed research on its physical processes has previously been conducted. In this study, a 3D coupled hydrodynamic and solute transport model was used to investigate general circulation, thermohaline structure, and residence time in Gorgan Bay. Model outputs were validated against a set of field observations. Bottom friction and attenuation coefficient of light intensity were tuned in order to achieve optimum agreement with the observations. Results revealed that, due to the interaction between bathymetry and prevailing winds, a barotropic double-gyre circulation, dominating the general circulation, existed during all seasons in Gorgan Bay. Furthermore, temperature and salinity fluctuations in the bay were seasonal, due to the seasonal variability of atmospheric fluxes. Results also indicated that under the prevailing winds, the domain-averaged residence time in Gorgan Bay would be approximately 95 days. The rivers discharging into Gorgan Bay are considered as the main sources of nutrients in the bay. Since their mouths are located in the area with a residence time of over 100 days, Gorgan Bay could be at risk of eutrophication; it is necessary to adopt preventive measures against water quality degradation.  相似文献   

5.
Fundamental concepts of exchange and transport time scales in a coastal sea   总被引：1，自引：0，他引：1  
Concepts of age, residence time, transit time, and turn-over time are summarized which are useful for describing the exchange and transport of water or materials in a coastal sea. The age of a particle is defined as a time which has elapsed since it entered the reservoir, and the residence time is defined as a time which will be taken for a particle to reach the outlet. Time scales based on the age are simply related with those based on the residence time. It is shown that a suitable time scale for representing the exchange characteristics is the average residence time and not the turnover time, which has often been used as the exchange time scale. Further, the ‘remnant function’ which describes the phenomena of exchange or transport is introduced, and is related to the residence time. Exchange and transport time scales in a coastal sea are discussed on the basis of the residence time which can be applied to not only steady-state cases, but also the cases where material is injected instantaneously. The average residence time in a one-dimensional channel and bay is obtained from the solutions of the advection-diffusion equation. If we know a flow speed and diffusion coefficient in a channel or bay regarded as one-dimensional, we can translate them into the average residence time. As an example, the average residence time of the Seto Inland Sea is discussed.  相似文献   

6.
Contemporary patterns in river basin sediment dynamics have been widely investigated but the timescales associated with current sediment delivery processes have received much less attention. Furthermore, no studies have quantified the effect of recent land use change on the residence or travel times of sediment transported through river basins. Such information is crucial for understanding contemporary river basin function and responses to natural and anthropogenic disturbances or management interventions. To address this need, we adopt a process‐based modelling approach to quantify changes in spatial patterns and residence times of suspended sediment in response to recent agricultural land cover change. The sediment budget model SedNet was coupled with a mass balance model of particle residence times based on atmospheric and fluvial fluxes of three fallout radionuclide tracers (7Be, excess 210Pb and 137Cs). Mean annual fluxes of suspended sediment were simulated in seven river basins (38–920 km2) in south‐west England for three land cover surveys (1990, 2000 and 2007). Suspended sediment flux increased across the basins from 0.5–15 to 1.4–37 kt y‐1 in response to increasing arable land area between consecutive surveys. The residence time model divided basins into slow (upper surface soil) and rapid (river channel and connected hillslope sediment source area) transport compartments. Estimated theoretical residence times in the slow compartment decreased from 13–48 to 5.6–14 ky with the increase in basin sediment exports. In contrast, the short residence times for the rapid compartment increased from 185–256 to 260–368 d as the modelled connected source area expanded with increasing sediment supply from more arable land. The increase in sediment residence time was considered to correspond to longer sediment travel distances linked to larger connected source areas. This novel coupled modelling approach provides unique insight into river basin responses to recent environmental change not otherwise available from conventional measurement techniques. © 2014 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.  相似文献   

7.
Trace concentrations of highly reactive hydrocarbons of biogenic origin have been proposed for some time as being important in aerosol formation processes in the atmosphere. More recently, assessments of potential photochemical reactions in the troposphere have proposed a role in the atmospheric ozone cycle for hydrocarbons, even for compounds such as methane that had previously been considered nonreactive. An assessment of the atmospheric hydrocarbon reaction system has been limited by a lack of observational information on the nature of conditions in the remote or non-urban atmosphere. Recent data on terpene concentrations and other biogenic hydrocarbon compounds are presented. Data on ethane and acetylene from aircraft samples taken over the north and south Pacific Ocean show concentrations in the 0.5 to 1 /m3 range for ethane and in the 0.05 to 0.3 g/m3 range for acetylene. A concentration gradient is present for these compounds between the northern and southern hemisphere. A rudimentary global concentration pattern for these C2 compounds has been developed on the basis of recent data.  相似文献   

8.
Experimental evidence for an ascending microflow of geogas in the ground   总被引：2，自引：0，他引：2  
A microflow of free ascending gas has been observed in 26 out of 30 tested boreholes at three different sites. The flow rates vary between 60 × 10−4 and 4 cm3/min m2 horizontally projected borehole area. Sampling has been made in ground boreholes as well as in holes drilled downwards from the lowest levels in two mines. The composition of the gas varies considerably. The main components of the gas are nitrogen, argon, oxygen and methane. Traces of heavier hydrocarbons are observed. At the site of the ground holes, only traces of methane are observed. In all sampled holes the existence of free oxygen is observed. The nitrogen/argon quotient is close to the atmospheric quotient in all sampled holes, indicating a partly atmospheric origin of the gas. The existence of methane and traces of heavier hydrocarbons indicates the existence of a second source.  相似文献   

9.
Concentrations of rare earth elements (REE) and Nd isotopic ratios were analyzed for seawater, filtered suspension and sediment trap samples collected in the tropical Atlantic Ocean (EUMELI program, EUtrophic, MEsotrophic and oLIgotrophic sites, 20°N, 18°–21°W). This is the first REE/Nd dataset on solution and different-sized particles collected at the same site. We present direct evidence of the Nd isotopic exchange between particulate lithogenic fraction and seawater without significant mass transfer. This exchange is probably one of the main factors that simultaneously constrains the Nd concentration and isotopic ratio budget. We propose a new approach to estimate the residence time of Nd in the ocean (τNd) based on isotopic exchange: 200 yr < τNd< 1000 yr. The exchange requires a partial dissolution of lithogenic Nd. We estimate that the fraction of soluble Nd proportion in atmospheric dust is of the order of 20% based on the isotopic ratios. We suggest that the partial dissolution of atmospheric fallout is probably one of the main REE sources of the ocean.  相似文献   

10.
A Monte Carlo-based approach to assess uncertainty in recharge areas shows that incorporation of atmospheric tracer observations (in this case, tritium concentration) and prior information on model parameters leads to more precise predictions of recharge areas. Variance-covariance matrices, from model calibration and calculation of sensitivities, were used to generate parameter sets that account for parameter correlation and uncertainty. Constraining parameter sets to those that met acceptance criteria, which included a standard error criterion, did not appear to bias model results. Although the addition of atmospheric tracer observations and prior information produced similar changes in the extent of predicted recharge areas, prior information had the effect of increasing probabilities within the recharge area to a greater extent than atmospheric tracer observations. Uncertainty in the recharge area propagates into predictions that directly affect water quality, such as land cover in the recharge area associated with a well and the residence time associated with the well. Assessments of well vulnerability that depend on these factors should include an assessment of model parameter uncertainty. A formal simulation of parameter uncertainty can be used to delineate probabilistic recharge areas, and the results can be expressed in ways that can be useful to water-resource managers. Although no one model is the correct model, the results of multiple models can be evaluated in terms of the decision being made and the probability of a given outcome from each model.  相似文献   

11.
The role of oceanic tide, wind stress, freshwater river inflows, and waves in the long-term circulation and residence time in óbidos Lagoon is investigated using a sensitivity analysis carried out by means of a two-dimensional model. MOHID modeling system coupled to Steady-State Spectral Wave model for simulate óbidos Lagoon circulation were implemented. For residence time calculus, a Lagrangian transport model was used. Tidal forcing is shown to be the dominant forcing, although storm waves must be considered to simulate accurately the long-term circulation. Tidal forcing enhances a spatial distribution in water residence time. Renewal time scales varies from values of 2 days in the near-ocean areas and 3 weeks in the inner areas. Freshwater river inflows decrease the residence time, while waves increase. In heavy rain periods, the water residence time decreases by about 40% in the upper lagoon. When wave forcing is considered, the residence time increases between 10% and 50% depending on lagoon area. The increase in residence time is explained by the sea level rise within lagoon (~1 m above average lagoon sea level) during storm wave periods. Average residence time is 16 days for tidal forcing, 9 days when the rivers are included (wet period), and 18 days when the waves are considered.  相似文献   

12.
A 2D Hydrodynamic-Particle Analysis model was applied to the Gulf of Kachchh (GoK) to estimate the residence time of pollutants. The tidal currents in the Gulf have a strong E-W component, which prevents the material in the north being transported towards south. In the regions situated very close to the open boundary, where the GoK waters exchange freely with the northern Arabian Sea, dilution takes place rapidly with the incoming waters and hence, the residence time is on the order of 1 day. Influence of eddies and a dynamic barrier across the Sikka-Mundra section on the residence time is apparent. Eastern GoK shows a relatively large residence time, on the order of 2-4 days, warranting caution while releasing industrial wastes in the northeastern Gulf. The region around location-5 behaves like a bay; the dissolved matter gets trapped in this bay and the residence time increases by 3-4 days.  相似文献   

13.
Profiles of226Ra and dissolved210Pb have been measured at several stations in the Red Sea. At one station in the central Red Sea an expanded profile was measured including226Ra and dissolved and particulate210Pb and210Po. These profiles show several distinct features: (1)226Ra displays a mid-depth maximum of about 13 dpm/100 kg at about 500 m; (2) dissolved210Pb concentrations are uniformly low at about 2 dpm/100 kg with little lateral or vertical variation; (3) the surface-water210Pb excess which is commonly observed in low-latitude open ocean regions is entirely lacking; (4)210Pb and210Po activities are essentially identical to each other in both particulate and dissolved phases although210Po activities appear somewhat lower; (5) about 20% of the210Pb and210Po in the water column residues on particulate matter.Assuming the atmospheric210Pb flux to be in the dissolved form and at the lower level of the normal range i.e. 0.5 dpm/cm2 yr, the residence time of the dissolved Pb is about 1.5 years. However, if the same atmospheric flux is entirely in particulate form, then the residence time of the dissolved Pb is about 5 years. The residence time of Pb in the particulate phase is less than 0.4 years if all the Pb is removed only by sinking particles.  相似文献   

14.
Five typical water volumes in the Seto Inland Sea are defined, and their average residence times, remnant functions, and residence time distribution functions are obtained, mainly from results of hydraulic model experiments; the average residence times and the functions well describe characteristics of exchange and transport of materials in the sea. A representative residence time, which is the average residence time of the total water in the inland sea, is about 15 months.  相似文献   

15.
Helium isotope measurements show that water on the crest and flanks of the East Pacific Rise has the highest enrichment in 3He so far observed in the oceans; the 3He/4He ratio anomaly relative to atmospheric helium is + 32% at the mid-depth maximum in the profiles. The corresponding 3He solubility anomaly relative to saturation with atmospheric helium is +50%. These data indicate that active sea-floor spreading sites on the crests of the mid-ocean rises are the sources of primordial helium injected into the ocean from the earth's interior. The 3He/4He ratio in this flux is approximately 1.6 × 10?5, about 11 times the atmospheric ratio of 1.4 × 10?6. The total flux of 3He into the atmosphere is 4.6 atoms cm?2 earth-surface sec?1, most of which (4.0 atoms cm?2 sec?1) is supplied by the oceanic flux. The corresponding atmospheric residence time for 3He is 106 years, which, within the large uncertainties of supply and demand (thermal escape), is consistent with the requirement for a steady state.  相似文献   

16.
At high Peclet number, the residence time exhibits a boundary layer adjacent to incoming open boundaries. In a Eulerian model, not resolving this boundary layer can generate spurious oscillations that can propagate into the area of interest. However, resolving this boundary layer would require an unacceptably high spatial resolution. Therefore, alternative methods are needed in which no grid refinement is required to capture the key aspects of the physics of the residence time boundary layer. An extended finite element method representation and a boundary layer parameterisation are presented and tested herein. It is also explained how to preserve local consistency in reversed time simulations so as to avoid the generation of spurious residence time extrema. Finally, the boundary layer parameterisation is applied to the computation of the residence time in the Scheldt Estuary (Belgium/The Netherlands). This timescale is simulated by means of a depth-integrated, finite element, unstructured mesh model, with a high space–time resolution. It is seen that the residence time temporal variations are mainly affected by the semi-diurnal tides. However, the spring–neap variability also impacts the residence time, particularly in the sandbank and shallow areas. Seasonal variability is also observed, which is induced by the fluctuations over the year of the upstream flows. In general, the residence time is an increasing function of the distance to the mouth of the estuary. However, smaller-scale fluctuations are also present: they are caused by local bathymetric features and their impact on the hydrodynamics.  相似文献   

17.
This work proposes a space/time estimation method for atmospheric PM2.5 components by modelling the mass fraction at a selection of space/time locations where the component is measured and applying the model to the extensive PM2.5 monitoring network. The method we developed utilizes the nonlinear Bayesian maximum entropy framework to perform the geostatistical estimation. We implemented this approach using data from nine carcinogenic, particle-bound polycyclic aromatic hydrocarbons (PAHs) measured from archived PM2.5 samples collected at four locations around the World Trade Center (WTC) from September 22, 2001 to March 27, 2002. The mass fraction model developed at these four sites was used to estimate PAH concentrations at additional PM2.5 monitors. Even with limited PAH data, a spatial validation showed the application of the mass fraction model reduced the mean squared error (MSE) by 7–22%, while in the temporal validation there was an exponential improvement in MSE positively associated with the number of days of PAH data removed. Our results include space/time maps of atmospheric PAH concentrations in the New York area after 9/11.  相似文献   

18.
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19.
Lagoons interspersed within wetlands are expected to increase the residence time of the flow in the system which, in turn, will lead to enhanced pollutant removal thus ensuring a good ecological status of the ecosystem. In this study, lagoons interspersed in vegetated wetlands have been mimicked in the laboratory to develop a theoretical model to establish the impact three major driving parameters (the vegetation density surrounding a lagoon, the depth aspect ratio [length vs. depth] of the lagoon and the circulating flow – through the Reynolds number) have on determining the residence time of the flow in the lagoon. The results indicate that, according to the maximum free available area of the flow, the presence of vegetation (Juncus maritimus) decreases the residence time. In addition, an increase in the Reynolds number of the circulating flow in the wetlands also resulted in a decrease in the lagoon residence time. Nevertheless, lagoon residence times were found to depend on the depth of the lagoon, with deeper lagoons having higher residence times. The length of the lagoon, however, was found not to affect the residence time. High lagoon residence times in either natural or constructed wetlands are desirable because they enhance pollutant removal from the water. Although, if the residence times are too long, this may lead to anoxic water conditions that could in fact threaten the wetland's ecosystem.  相似文献   

20.
Demidov  D. A.  Krasnochub  A. V.  Shepelin  A. V. 《Water Resources》2001,28(4):466-468
A hydraulic system for testing water disinfection plants is described. A method for determining the residence time distribution function from tracer experiments is suggested. The effect of tracer injection mode and the plant construction on residence time distribution function is investigated.  相似文献   

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