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1.
Ethane and acetylene, both of which possess more efficient emission bands than methane, have been incorporated into a thermal structure model for the atmosphere of Jupiter. Choosing for illustrative purposes the mixing ratios and , it is found that these hydrocarbon gases lower the atmospheric temperature within the thermal inversion region by as much as 20 K, subsequently reducing the emission intensity of the 7.7 μm CH4 band below the observed result. It is qualitatively shown, however, that this cooling by C2H6 and C2H2 could be compensated by aerosol heating resulting from a uniformily mixed aerosol which absorbs 15% of the incident solar radiation. Such aerosol heating has been suggested by uv albedo observations. 相似文献
2.
The abundance of H2O is derived from the 1900- to 2100-cm?1 region of the Voyager 1 IRIS spectra. Scale variations of about a factor of 2 are seen in the water abundance between the North and South Equatorial Belts. Averaged over the full disk, the mixing ratio is , if H2O is uniformly mixed in the atmospheric region having temperatures of 230 to 270°K; this result implies a solar depletion by a factor of 100 in this region. In the belts, the best agreement is obtained for a H2O/H2 mixing ratio of 4.0 × 10?6 in the NEB and 7.2 × 10?6 in the SEB, assuming a constant mixing ratio. 相似文献
3.
A mechanism has been proposed for uv-accelerated desorption from Fe2+ sites on mineral surfaces that satisfies kinetic constraints determined in the laboratory by Huguenin. The process is an integral step of the photochemical weathering mechanism for producing dust on Mars, and it now appears that it may play primary roles in stabilizing CO2 against dissociation by sunlight and in controlling the oxidation state of the atmosphere. We propose that adsorption occurs at octahedrally coordinated Fe2+ surface sites to form seven-coordinate transition-state complexes. These complexes acquire 16–18 kcal mole?1 of ligand field stabilization energy. During illumination (λ ≤ 0.35 μm), electrons are photoemitted from the surfaced Fe2+, temporarily oxidizing them to Fe3+. Fe3+ has no ligand field stabilization energy, and the complexes lose 16–18 kcal mole?1 of stabilization energy. This is a large fraction of the 19- to 28-kcal mole?1 activation energy for dissociating the complexes, and desorption should proceed spontaneously. The gases that were observed to undergo adsorption-photodesorption include O2, CO2, CO, H2O, N2, and Ar. Photodesorption can drive several catalytic reactions, one of which is the oxidation of CO to CO2. The rate of this reaction should be limited by the supply of CO and O2 to the surface to ～2 × 1012 cm?2 sec?1 (column photodissociation rate of CO2). By including this surface reaction in models of Martian atmospheric CO2 chemistry, CO2 can be stabilized against photodissociation with eddy diffusion coefficients of only 3 × 105?1 × 107 cm2 sec?1 below 40 km, raising to ～ 109 cm2 sec?1 at 140 km. Odd hydrogen is not needed to catalyze the oxidation of CO below 40 km, and odd hydrogen mixing ratios need only to be to depress ozone concentrations below the observed upper limit in equatorial regions. Another catalytic reaction that should be driven by photodesorption on Mars is . This is an important source of atmospheric O2, amounting to 7 × 1013?2 × 1017 O2 molecules cm?2 yr?1, and it could have a significant effect on atmospheric oxidation state. 相似文献
4.
Kenneth Fox 《Icarus》1975,24(4):454-459
The basis for “quasipolar” absorption (QPA) by CH4 is the existence of a small electric dipole moment in its ground state. The integrated intensity αQPA at a temperature of 90K is calculated to be between 4.8 × 10?5 and 1.9 × 10?2 cm?2 atm?1. With an assumed mean pressure of 0.1 atm and a relative abundance of , it is estimated that the ratio of quasipolar to pressure-induced absorption (PIA) is 0.05 ? αQPA/αPIA ? 18 for the spectral range from 0 to 300 cm?1. This result suggests that quasipolar absorption may contribute to a weak, CH4-induced greenhouse in the atmosphere of Titan. 相似文献
5.
Marcel Nicolet 《Planetary and Space Science》1984,32(7):871-880
The photodissociation of water vapour in the mesosphere depends on the absorption of solar radiation in the region (175–200 nm) of the O2 Schumann-Runge band system and also at H-Lyman alpha. The photodissociation products are OH + H, OH + H, O + 2H and H2 + O at Lyman alpha; the percentages for these four channels are 70, 8, 12 and 10%, respectively, but OH + H is the only channel between 175 and 200 nm. Such proportions lead to a production of H atoms corresponding to practically the total photodissociation of H2O, while the production of H2 molecules is only 10% of the H2O photodissociation by Lyman alpha.The photodissociation frequency (s?1) at Lyman alpha can be expressed by a simple formula where F10.7 cm is the solar radioflux at 10.7 cm and N the total number of O2 molecules (cm?2), and when the following conventional value is accepted for the Lyman alpha solar irradiance at the top of the Earth's atmosphere () qLyα,∞ = 3 × 1011 photons cm?2 s1?.The photodissociation frequency for the Schumann-Runge band region is also given for mesospheric conditions by a simple formula where JSRB,∞(H2O) = 1.2 × 10?6 and 1.4 × 10?6 s?1 for quiet and active sun conditions, respectively.The precision of both formulae is good, with an uncertainty less than 10%, but their accuracy depends on the accuracy of observational and experimental parameters such as the absolute solar irradiances, the variable transmittance of O2 and the H2O effective absorption cross sections. The various uncertainties are discussed. As an example, the absolute values deduced from the above formulae could be decreased by about 25-20% if the possible minimum values of the solar irradiances were used. 相似文献
6.
Absolute spectrophotometry of Neptune from 3390 to 7800 Å, with spectral resolution of 10 Å in the interval 3390–6055 and 20 Å in the interval 6055–7800 Å, is reported. The results are compared with filter photometry (Appleby, 1973; Wamsteker, 1973; Savage et al., 1980) and with synthetic spectra computed on the basis of a parameterization proposed by Podolak and Danielson (1977) for aerosol scattering and absorption. A CH4/H2 ratio of is derived for the convectively mixed part of Neptune's atmosphere, and constrains optical properties of hypothetical aerosol layers. 相似文献
7.
It is shown that Titan's surface and plausible atmospheric thermal opacity sources—gaseous N2, CH4, and H2, CH4 cloud, and organic haze—are sufficient to match available Earth-based and Voyager observations of Titan's thermal emission spectrum. Dominant sources of thermal emission are the surface for wavelenghts λ ? 1 cm, atmospheric N2 for 1 cm ? λ ? 200 μm,, condensed and gaseous CH4 for 200 μm ? λ ? 20 μm, and molecular bands and organic haze for λ ? 20 μm. Matching computed spectra to the observed Voyager IRIS spectra at 7.3 and 52.7° emission angles yields the following abundances and locations of opacity sources: CH4 clouds: 0.1 g cm? at a planetocentric radius of 2610–2625 km, 0.3 g cm?2 at 2590–2610 km, total 0.4 ± 0.1 g cm–2 above 2590 km; organic haze: above 2750 km; tropospheric H2: 0.3 ± 0.1 mol%. This is the first quantitative estimate of the column density of condensed methane (or CH4/C2H6) on Titan. Maximum transparency in the middle to far IR occurs at 19 μm where the atmospheric vertical absorption optical depth is A particle radius in the upper portion of the CH4 cloud is indicated by the apparent absence of scattering effects. 相似文献
8.
Photolysis of NH3 in the presence of CH4 with a 185-nm light source results in the generation of hot hydrogen atoms that abstract hydrogen from the CH4 to produce CH3·. Subsequent reactions of CH3· and NH2· give hydrocarbons, CH3NH2, and HCN. The extent of reaction of CH4 was measured by the ratio of the moles of CH4 reacted per mole of NH3 decomposed (). This ratio increases with diminishing NH3 pressure at constant CH4 pressure but it remains constant if . The ratio is independent of temperature in the range 156–298° K, suggesting that hot hydrogen atoms were responsible for the reaction of CH4. This postulate was confirmed by the observation that this reaction was quenched when H2 or SF6 was added to the reaction mixture. 相似文献
9.
The Stokes parameters of resonance radiation scattered by a Na atom with the angular momentum F aligned by directed unpolarized radiation in a magnetic field H ～ 10?5?10?1 Oe are presented. An influence of the orientation of the magnetic field on these parameters are studied; the intensity ratio changes within ±5%, and the polarization degree P(D2) within ±25%. Measurements of and P(D2), if the geometry of scattering is known, may give information on the direction of the magnetic field in the sodium atmospheres of comets, as well as Io's sodium cloud or man-made cosmic clouds. 相似文献
10.
Louis A. Capone John Dubach Robert C. Whitten Sheo S. Prasad Krishnamurthy Santhanam 《Icarus》1980,44(1):72-84
We have studied the possible synthesis of organic molecules by the absorption of galactic cosmic rays in an N2CH4H2 Titan model atmosphere. The cosmic-ray-induced ionization results in peak electron densities of 2 × 103 cm?3, with NH4+, C3H9+, and C4H9+ being among the important positive ions. Details of the ion and neutral chemistry relevant to the production of organic molecules are discussed. The potential importance of reactions with CH4 and H2 is also demonstrated. Although the integrated production rate of organic matter due to the absorption of the cosmic ray cascade is much less than that by solar ultraviolet radiation, the production of nitrogen-bearing organic molecules by cosmic rays may be greater. 相似文献
11.
Tetsuo Hasegawa Masatoshi Ohishi Masaki Morimoto Hiroko Suzuki Norio Kaifu 《Icarus》1984,60(1):211-214
The search for radio spectral lines from Comet Sugano-Saigusa-Fujikawa (1983e) was conducted using the 45-m telescope of Nobeyama Radio Observatory. The frequency ranges of 44.0–46.0 and 47.5–49.5 GHz were surveyed down to , with a beam size of ～35 arc sec. Upper limits have been established for spectral lines of atomic hydrogen, CS, OCS, SO2, H2CO, CH3OH, HCCCCCN, HCOOCH3, CH3OCH3, and CH3CH2CN. The J = 5?4 line from HCCCN in the vibrational ground state possibly has been detected but not confirmed. The suggested total amount of HCCCN in the coma is consistent with the possible picture that HCCCN is the main parent molecule of CN. 相似文献
12.
Results are given of the calculations of the group delay time propagating τ(ω, φ0) of hydromagnetic whistlers, using outer ionospheric models closely resembling actual conditions. The τ(ω, φ0) dependencies were compared with the experimental data of τexp(ω, φ0) obtained from sonagrams. The sonagrams were recorded in the frequency range at observation points located at geomagnetic latitudes φ0 = (53?66)° and in the vicinity of the geomagnetic poles. This investigation has led us to new and important conclusions.The wave packets (W.P.) forming hydromagnetic whistlers (H.W.) are mainly generated in the plasma regions at L = 3.5?4.0. This is not consistent with ideas already expressed in the literature that their generation region is . The overwhelming majority of the τexp values differ considerably from the times at which wave packets would, in theory, propagate along the magnetic field lines corresponding to those of the geomagnetic latitudes φ0 of the observation points. The second important fact is that the W.P. frequency ω is less than everywhere along its propagation trajectory, including the apogee of the magnetic force line ( is the proton gyrofrequency). Proton flux spectra keV, responsible for H.W. generation, were determined. Comparison of the Explorer-45 and OGO-3 measurements published in the literature, with our data, showed that the proton flux density energy responsible for the H.W. excitation where Ha is the magnetic field force in the generation region of these W.P. The electron concentration is . The values given in the literature are . The e data considered also leads to the conclusion that the generating mechanism of the W.P. studied probably always co-exists with the mechanism of their amplification. 相似文献
13.
Laboratory band-model absorption coefficients of CH4 are used to calculate the Uranus spectrum from 5400 to 10,400 Å. A good fit of both strong and weak bands for the Uranus spectrum over the entire wavelength interval is achieved for the first time. Three different atmospheric models are employed: a reflecting layer model, a homogeneous scattering layer model, and a clear atmosphere sandwiched between two scattering layers. The spectrum for the reflecting layer model exhibits serious discrepancies but shows that large amounts of CH4 (5–10 km-am) are necessary to reproduce the Uranus spectrum. Both scattering models give reasonably good fits. The homogeneous model requires a particle scattering albedo and an abundance per scattering mean free path . The parameters derived from the sandwich layer model are: forsb the upper scattering layer a continuum single scattering albedo () of 0.995 and a scattering optical depth variable with wavelength consistent with Rayleigh scattering; for the clear layer they are a CH4 abundance (a) of 2.2 km-am and an effective pressure (p) ? 0.1 atm; for the lower cloud deck a Lambert reflectivity (L) of 0.9 resulted. A severe depletion of CH4 in the upper scattering layer is required. An enrichment of CH4/H2 over the solar ratio by a factor of 4–14 in the lower atmosphere is, however, indicated. 相似文献
14.
《Chinese Astronomy and Astrophysics》1981,5(2):205-211
We have collected data on 241 galaxies from 13 sources and made a statistical analysis after reduction to a uniform system. We found that the Hubble sequence is one of increasing and , these mean values increasing monotonically from .0016 and .024 at E to .084 and .83 at Im, but the dispersion is large.The HI content in barred spiral is greater than that in ordinary spirals, and this is consistent with their statistics of angular momentum and colour.The HI content is related to colour; it is greater in bluer systems. The large dispersion suggests that it also depends on some other factors, but these are smoothed out when averaged over each type, resulting in a linear relation between and 〈(B ? VOT)〉. Unlike the colour-colour diagram, the large dispersion on the is not related to peculiar galaxies. 相似文献
15.
16.
W.T. Huntress 《Planetary and Space Science》1975,23(2):377-378
Laboratory data shows that the reaction of protons with methane proceeds at thermal ion energies to give both CH3+ and CH4+ ions in the ratio . The overall rate constant for the reaction is 3.8 ± 0.3 × 10?9 cm3/sec. This reaction may lead to the formation of hydrocarbon ions in the lower ionosphere of Jupiter, and the significance of this process for formation of hydrocarbons and HCN in the atmosphere of Jupiter is discussed. 相似文献
17.
Kaichi Maeda 《Planetary and Space Science》1976,24(4):341-347
VLF-emissions with subharmonic cyclotron frequency from magnetospheric electrons have been detected by the S3-A satellite (Explorer 45) whose orbit is close to the magnetic equatorial plane where the wave-particle interaction is most efficient. These emissions are observed during the main phase of a geomagnetic storm in the nightside of the magnetosphere outside of the plasmasphere around L = 3–5. The emissions consist essentially of two frequency regimes, one below the equatorial electron gyro-frequency, , and the other above . The emissions below are whistler mode and there is a sharp band of “missing emissions” along . The emissions above are electrostatic mode and the frequency ranges up to . It is concluded that these emissions are generated by the enhanced relativity low energy (1–5 keV) ring current electrons, penetrating into the nightside magnetosphere during the main phase of a magneto storm. Although the high energy (50–350 keV) electrons showed remarkable changes of pitch angle distribution, their associations with VLF-emissions are not so significant as those of low energy electrons. 相似文献
18.
K.M. Monahan W.T. Huntress A.L. Lane J.M. Ajello T.E. Burke P. Le Breton A. Williamson 《Planetary and Space Science》1974,22(1):143-149
The cross-section for dissociative photoionization of hydrogen by 584 Å radiation has been measured, yielding a value of 5 × 10?20 cm2. The process can be explained as a transition from the ground state to a continuum level of the ionized state of H2 The branching ratio for proton (H+) vs molecular ion (H2+) production at this energy is 8 × 10?3. This process is quite likely an important source of protons in the Jovian ionosphere near altitudes where peak ionization rates are found. 相似文献
19.
The intensities of radiation from the inner comas of comets which are composed primarily of water and carbon monoxide have been calculated. Only “airglow” emissions initiated by the absorption of extreme ultraviolet radiation have been considered. The photoionizations of H2O, CO, CO2, and N2 are the most important emission sources, although photoelectron excitation is also considered. Among the emission features for which intensities were calculated are H2O+ (), CO+ (first negative), CO (fourth positive), CO (Cameron), CO2+ (), N2 (Vegard-Kaplan), N2+ (first negative), and OI (1304 Å). In the inner coma (collision region) these airglow mechanisms are shown to be possible competitors with the usually assumed resonance scattering and flourescence excitation mechanisms which are appropriate for the outer coma and tail. 相似文献