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1.
The microfabrics of folded quartz veins in fine‐grained high pressure–low temperature metamorphic greywackes of the Franciscan Subduction Complex at Pacheco Pass, California, were investigated by optical microscopy, scanning electron microscopy including electron backscatter diffraction, and transmission electron microscopy. The foliated host metagreywacke is deformed by dissolution–precipitation creep, as indicated by the shape preferred orientation of mica and clastic quartz without any signs of crystal‐plastic deformation. The absence of crystal‐plastic deformation of clastic quartz suggests that the flow stress in the host metagreywacke remained below a few tens of MPa at temperatures of 250–300 °C. In contrast, the microfabric of the folded quartz veins indicates deformation by dislocation creep accompanied by subgrain rotation recrystallization. For the small recrystallized grain size of ~8 ± 6 μm, paleopiezometers indicate differential stresses of a few hundred MPa. The stress concentration in the single phase quartz vein is interpreted to be due to its higher effective viscosity compared to the fine‐grained host metagreywacke deforming by dissolution–precipitation creep. The fold shape suggests a viscosity contrast of one to two orders of magnitude. Deformation by dissolution–precipitation creep is expected to be a continuous process. The same must hold for folding of the vein and deformation of the vein quartz by dislocation creep. The microfabric suggests dynamic recrystallization predominantly by subgrain rotation and only minor strain‐induced grain boundary migration, which requires low contrasts in dislocation density across high‐angle grain boundaries to be maintained during climb‐controlled creep at high differential stress. The record of quartz in these continuously deformed veins is characteristic and different from the record in metamorphic rocks exhumed in seismically active regions, where high‐stress deformation at similar temperatures is episodic and related to the seismic cycle.  相似文献   

2.
We performed high strain (up to 47 %) axial compression experiments on natural quartz single crystals with added rutile powder (TiO2) and ~0.2 wt% H2O to investigate the effects of deformation on the titanium-in-quartz (TitaniQ) geothermobarometer. One of the objectives was to study the relationships between different deformation mechanisms and incorporation of Ti into recrystallized quartz grains. Experiments were performed in a Griggs-type solid-medium deformation apparatus at confining pressures of 1.0–1.5 GPa and temperatures of 800–1,000 °C, at constant strain rates of 1 × 10?6 or 1 × 10?7 s?1. Mobility of Ti in the fluid phase and saturation of rutile at grain boundaries during the deformation experiments are indicated by precipitation of secondary rutile in cracks and along the grain boundaries of newly recrystallized quartz grains. Microstructural analysis by light and scanning electron microscopy (the latter including electron backscatter diffraction mapping of grain misorientations) shows that the strongly deformed quartz single crystals contain a wide variety of deformation microstructures and shows evidence for subgrain rotation (SGR) and grain boundary migration recrystallization (GBMR). In addition, substantial grain growth occurred in annealing experiments after deformation. The GBMR and grain growth are evidence of moving grain boundaries, a microstructure favored by high temperatures. Electron microprobe analysis shows no significant increase in Ti content in recrystallized quartz grains formed by SGR or by GBMR, nor in grains grown by annealing. This result indicates that neither SGR nor moving grain boundaries during GBMR and grain growth are adequate processes to facilitate re-equilibration of the Ti content in experimentally deformed quartz crystals at the investigated conditions. More generally, our results suggest that exchange of Ti in quartz at low H2O contents (which may be realistic for natural deformation conditions) is still not fully understood. Thus, the application of the TitaniQ geothermobarometer to deformed metamorphic rocks at low fluid contents may not be as straightforward as previously thought and requires further research.  相似文献   

3.
The calcite mylonites in the Xar Moron-Changchun shear zone show a significance dextral shearing characteristics. The asymmetric(σ-structure) calcite/quartz grains or aggregates, asymmetry of calcite c-axes fabric diagrams and the oblique foliation of recrystallized calcite grains correspond to a top-to-E shearing. Mineral deformation behaviors, twin morphology, C-axis EBSD fabrics, and quartz grain size-frequency diagrams demonstrate that the ductile shear zone was developed under conditions of greenschist facies, with the range of deformation temperatures from 200 to 300°C. These subgrains of host grains and surrounding recrystallized grains, strong undulose extinction, and slightly curved grain boundaries are probably results of intracrystalline deformation and dynamic recrystallization implying that the deformation took place within the dislocation-creep regime at shallow crustal levels. The calculated paleo-strain rates are between 10~(–7.87)s~(–1) and 10~(–11.49)s~(–1) with differential stresses of 32.63–63.94 MPa lying at the higher bound of typical strain rates in shear zones at crustal levels, and may indicate a relatively rapid deformation. The S-L-calcite tectonites have undergone a component of uplift which led to subhorizontal lifting in an already non-coaxial compressional deformation regime with a bulk pure shear-dominated general shear. This E-W large-scale dextral strike-slip movement is a consequence of the eastward extrusion of the Xing'an-Mongolian Orogenic Belt, and results from far-field forces associated with Late Triassic convergence domains after the final closure of the Paleo-Asian Ocean.  相似文献   

4.
A detailed structural and microstructural analysis of the Miocene Raft River detachment shear zone (NW Utah) provides insight into the thermomechanical evolution of the continental crust during extension associated with the exhumation of metamorphic core complexes. Combined microstructural, electron backscattered diffraction, strain, and vorticity analysis of the very well exposed quartzite mylonite show an increase in intensity of the rock fabrics from west to east, along the transport direction, compatible with observed finite strain markers and a model of ``necking'' of the shear zone. Microstructural evidence (quartz microstructures and deformation lamellae) suggests that the detachment shear zone evolved at its peak strength, close to the dislocation creep/exponential creep transition, where meteoric fluids played an important role on strain hardening, embrittlement, and eventually seismic failure.Empirically calibrated paleopiezometers based on quartz recrystallized grain size and deformation lamellae spacing show very similar results, indicate that the shear zone developed under stress ranging from 40 MPa to 60 MPa. Using a quartzite dislocation creep flow law we further estimate that the detachment shear zone quartzite mylonite developed at a strain rates between 10−12 and 10−14 s−1. We suggest that a compressed geothermal gradient across this detachment, which was produced by a combination of ductile shearing, heat advection, and cooling by meteoric fluids, may have triggered mechanical instabilities and strongly influenced the rheology of the detachment shear zone.  相似文献   

5.
Synseismic loading to very high stresses (>0.5 GPa) and subsequent creep during stress relaxation in the uppermost plastosphere at temperatures of ca. 300–350 °C, near the lower tip of an inferred once seismically active crustal scale fault, was proposed based on peculiar microstructures identified in rocks exposed over >100 km2 in the Sesia Zone, European Western Alps. Here we discuss the conspicuous and highly heterogeneous microstructural record of quartz in disseminated small-scale shear zones. Sub-basal deformation lamellae and arrays of elongate subgrains on the TEM-scale indicate an early stage of glide-controlled deformation at high stresses. Distributed brittle failure is indicated by healed microcracks. Very fine-grained recrystallised aggregates with a pronounced crystallographic preferred orientation reflect intense plastic flow by dislocation creep. Locally, a fine-grained foam microstructure indicates a final stage of static grain growth at low differential stress. For the previously inferred peak stresses of about 0.5 GPa and given temperatures, initial strain rates on the order of 10−10 s−1 are predicted by available flow laws for dislocation creep of quartz. We emphasise the importance of short-term non-steady state deformation in the uppermost plastosphere underlying seismically active upper crust. The related heterogeneous record of quartz is governed by the local stress history at constant temperature.  相似文献   

6.
Deformation experiments on olivine aggregates were performed under hydrous conditions using a deformation-DIA apparatus combined with synchrotron in situ X-ray observations at pressures of 1.5–9.8 GPa, temperatures of 1223–1800 K, and strain rates ranging from 0.8 × 10?5 to 7.5 × 10?5 s?1. The pressure and strain rate dependencies of the plasticity of hydrous olivine may be described by an activation volume of 17 ± 6 cm3 mol?1 and a stress exponent of 3.2 ± 0.6 at temperatures of 1323–1423 K. A comparison between previous data sets and our results at a normalized temperature and a strain rate showed that the creep strength of hydrous olivine deformed at 1323–1423 K is much weaker than that for the dislocation creep of water-saturated olivine and is similar to that for diffusional creep and dislocation-accommodated grain boundary sliding, while dislocation microstructures showing the [001] slip or the [001](100) slip system were developed. At temperatures of 1633–1800 K, a much stronger pressure effect on creep strength was observed for olivine with an activation volume of 27 ± 7 cm3 mol?1 assuming a stress exponent of 3.5, water fugacity exponent of 1.2, and activation energy of 520 kJ mol?1 (i.e., power-law dislocation creep of hydrous olivine). Because of the weak pressure dependence of the rheology of hydrous olivine at lower temperatures, water weakening of olivine could be effective in the deeper and colder part of Earth’s upper mantle.  相似文献   

7.
Shear and extensional veins formed during the reactivation of the Magdala shear system at Stawell in western Victoria, Australia, contribute to the formation of the auriferous Central and Basalt Contact lodes. Within this shear system is a range of fault rocks accompanied by steep-dipping (>65°) quartz-rich laminated shear veins and relatively flat-lying extensional veins. Both vein sets appear to have been a primary source for the host rock permeability during fluid flow in a regime of significant deviatoric stresses. The macro- and microstructures suggest that the dilatancy, that produced mineralized veins, formed under conditions of overpressure generated by fluid infiltration late in a tectonic regime. A new microfabric analysis technique is used to investigate the quartz-rich veins, which allows rapid integration of the microstructure with the crystallographic preferred orientations (CPOs). Both the shear and extensional quartz veins have a random CPO with ∼120° dihedral angles between the quartz–quartz grains, which is typical of a metamorphic equilibrium microfabric. The microstructures indicate that the quartz has undergone extensive grain adjustment in the solid-state, with grain shape and size affected by interfacial solution (pressure solution) effects. These features are consistent with inferences from experimental rock deformation studies, where grain boundary migration is enhanced in a water-rich environment. The onset of solution-transfer processes (pressure solution) developed as the quartz microfabric stabilized and continued to modify the CPO and microstructure significantly. It is concluded that grain growth and pressure solution are coupled diffusive mass transfer processes, related to fluctuations in pore fluid pressures in a region undergoing deformation at near lithostatic pressures.  相似文献   

8.
Polyphase metamorphic paragneisses from the drill core of the continental deep drilling project (KTB; NW Bohemian Massif) are characterized by peak pressures of about 8 kbar (medium‐P metamorphism) followed by strain accumulation at T >650 °C, initially by dislocation creep and subsequently by diffusion creep. U–Pb monazite ages and Rb–Sr whole‐rock data vary in the dm‐scale, indicating Ordovician and Mid‐Devonian metamorphic events. Such age variations are closely interconnected with dm‐scale domainal variations of microfabrics that indicate different predominant deformation mechanisms. U–Pb monazite age variations dependent on microfabric domains exceed grain‐size‐dependent age variations. In ‘mylonitic domains’ recording high magnitudes of plastic strain, dislocation creep and minor static annealing, monazite yields concordant and near concordant Lower Ordovician U–Pb ages, and the Rb–Sr whole‐rock system shows isotopic disequilibrium at an mm‐scale. In ‘mineral growth/mobilisate domains’, in which diffusive mass transfer was a major strain‐producing mechanism promoting diffusion creep of quartz and feldspar, and in which static recrystallization (annealing) reduced the internal free energy of the strained mineral aggregates, concordant U–Pb ages are Mid‐Devonian. Locally, in such domains, Rb–Sr dates among mm3‐sized whole‐rock slabs reflect post‐Ordovician resetting. In ‘transitional domains’, the U–Pb‐ages are discordant. We conclude that medium‐P metamorphism occurred at 484±2 Ma, and a second metamorphic event at 380–370 Ma (Mid‐Devonian) caused progressive strain in the rocks. Dislocation creep at high rates, even at high temperatures, does not reset the Rb–Sr whole‐rock system, while diffusion creep at low rates and stresses (i.e. low ε/Deff ratios), static annealing and the presence of intergranular fluids locally assist resetting. At temperatures above 650 °C, diffusive Pb loss did not reset Ordovician U–Pb monazite ages, and in domains of overall high imposed strain rates and stresses, resetting was not assisted by dynamic recrystallization/crystal plasticity. However, during diffusion creep at low rates, Pb loss by dissolution and precipitation (‘recrystallization’) of monazite produces discordance and Devonian‐concordant U–Pb monazite ages. Hence, resetting of these isotope systems reflects neither changes of temperature nor, directly, the presence or absence of strain.  相似文献   

9.
Biotite‐muscovite‐garnet gneisses at Einasleigh contain quartz‐feldspar veins composed of the same minerals as found in the enclosing rock. The vein‐gneiss boundaries are commonly irregular and on a microscopic scale, gradational.

Certain amphibolite layers contain quartz‐feldspar veins composed of the same minerals as found in the amphibolite. Hornblende‐rich extraction zones surround these veins, and material balance calculations show that all or nearly all of the vein‐forming matter was locally derived. Variation in the abundance of hornblende and plagioclase in the amphibolite as a function of distance from a quartz‐feldspar vein can be expressed by error‐function curves, thus suggesting that the mineral‐segregation process was diffusion‐controlled. During the mineral rearrangement, the Na and Ca contents of plagioclase have evidently remained unchanged, but the vein hornblende has become slightly richer in Fe+3, Mg, and Ca, and poorer in Si and Al relative to hornblende in the adjacent amphibolite.

A certain biotite‐plagioclase rock forms layers and boudins in the gneisses and contains pegmatite veins composed of the same minerals as found in the host rock. The plagioclase in these veins is more sodic than that in the host rock while the biotite contains slightly more Ti and Fe+2 and less Si and Mg than the biotite of the enclosing rock.

The data indicate that significant portions of the vein‐forming matter at Einasleigh were locally derived. The chemistry of some minerals has changed slightly during the segregation process, resulting possibly from different diffusion rates for the different mineral‐forming constituents.  相似文献   

10.
Experimental deformation of partially melted granitic aggregates   总被引:16,自引:1,他引:16  
Abstract The effects of varying amounts of partial melt on the deformation of granitic aggregates have been tested experimentally at conditions (900°C, 1500 MPa, 10-4 to 10-6/s) where melt-free samples deform by dislocation creep, with microstructures approximately equivalent to those of upper greenschist facies. Experiments were performed on samples of various grain sizes, including an aplite (150 μm) and sintered aggregates of quartz-albitemicrocline (10–50 and 2–10 μm). Water was added to the samples to obtain various amounts of melt (1–15% in the aplite, 1–5% in the sintered aggregates). Optical and TEM observations of the melt distribution in hydrostatically annealed samples show that the melt in the sintered aggregates is homogeneously distributed along an interconnected network of triple junction channels, while the melt in the aplites is inhomogeneously distributed. The effect of partial melt on deformation depends an melt amount and distribution, grain size and strain rate. For samples deformed with ? 1% melt, all grain sizes exhibit microstructures indicative of dislocation creep. For samples deformed with 3–5% melt, the 150 μm and 10–50 μm grain size samples also exhibit dislocation creep microstructures, but the 2–10 μm grain size samples exhibit abundant TEM-scale evidence of dissolution-precipitation and little evidence of dislocation activity, suggesting a switch in deformation mechanism to predominantly melt-enhanced diffusion creep. At natural strain rates melt-enhanced diffusion creep would predominate at larger grain sizes, although probably not for most coarse-grained granites. The effects of melt percentage and strain rate have been studied for the 150 μm aplites. For samples with ? 5 and 10% melt, deformation at 10–6/s squeezes excess melt out of the central compressed region allowing predominantly dislocation creep. Conversely, deformation at 10-5/s produces considerable cataclasis presumably because the excess melt cannot flow laterally fast enough and a high pore fluid pressure results. For samples with 15% melt, deformation at both strain rates produces cataclasis, presumably because the inhomogeneous melt distribution resulted in regions of decoupled grains, which would produce high stress concentrations at point contacts. At natural strain rates there should be little or no cataclasis if an equilibrium melt texture exists and if the melt can flow as fast as the imposed strain rate. However, if the melt is confined and cannot migrate, a high pore fluid pressure should promote brittle deformation.  相似文献   

11.
Three different types of permeability tests were conducted on 23 intact and singly jointed rock specimens, which were cored from rock blocks collected from a rock cavern under construction in Singapore. The studied rock types belong to inter-bedded meta-sandstone and meta-siltstone with very low porosity and high uniaxial compressive strength. The transient pulse water flow method was employed to measure the permeability of intact meta-sandstone under a confining pressure up to 30 MPa. It showed that the magnitude order of meta-sandstone’s intrinsic permeability is about 10?18 m2. The steady-state gas flow method was used to measure the permeability of both intact meta-siltstone and meta-sandstone in a triaxial cell under different confining pressures spanning from 2.5 to 10 MPa. The measured permeability of both rock types ranged from 10?21 to 10?20 m2. The influence of a single natural joint on the permeability of both rock types was studied by using the steady-state water flow method under different confining pressures spanning from 1.25 to 5.0 MPa, including loading and unloading phases. The measured permeability of both jointed rocks ranged from 10?13 to 10?11 m2, where the permeability of jointed meta-siltstone was usually slightly lower than that of jointed meta-sandstone. The permeability of jointed rocks decreases with increasing confining pressure, which can be well fitted by an empirical power law relationship between the permeability and confining pressure or effective pressure. The permeability of partly open cracked specimens is lower than that of open cracked specimens, but it is higher than that of the specimen with a dominant vein for the meta-sandstone under the same confining pressure. The permeability of open cracked rock specimens will partially recover during the unloading confining pressure process. The equivalent crack (joint) aperture is as narrow as a magnitude order of 10?6 m (1 μm) in the rock specimens under confining pressures spanning from 1.25 to 5.0 MPa, which represent the typical ground stress conditions in the cavern. The in situ hydraulic conductivity measurements conducted in six boreholes by the injection test showed that the in situ permeability of rock mass varies between 10?18 and 10?11 m2. The lower bound of the in situ permeability is larger than that of the present laboratory-tested intact rock specimens, while the upper bound of the in situ permeability is less than that of the present laboratory-tested jointed rock specimens. The in situ permeability test results were thus compatible with our present laboratory permeability results of both intact and jointed rock specimens.  相似文献   

12.
Contact metamorphism caused by the Glenmore plug in Ardnamurchan, a magma conduit active for 1 month, resulted in partial melting, with melt now preserved as glass. The pristine nature of much of the aureole provides a natural laboratory in which to investigate the distribution of melt. A simple thermal model, based on the first appearance of melt on quartz–feldspar grain boundaries, the first appearance of quartz paramorphs after tridymite and a plausible magma intrusion temperature, provides a time‐scale for melting. The onset of melting on quartz–feldspar grain boundaries was initially rapid, with an almost constant further increase in melt rim thickness at an average rate of 0.5–1.0 × 10?9 cm s?1. This rate was most probably controlled by the distribution of limited amounts of H2O on the grain boundaries and in the melt rims. The melt in the inner parts of the aureole formed an interconnected grain‐boundary scale network, and there is evidence for only limited melt movement and segregation. Layer‐parallel segregations and cross‐cutting veins occur within 0.6 m of the contact, where the melt volume exceeded 40%. The coincidence of the first appearance of these signs of the segregation of melt in parts of the aureole that attained the temperature at which melting in the Qtz–Ab–Or system could occur, suggests that internally generated overpressure consequent to fluid‐absent melting was instrumental in the onset of melt movement.  相似文献   

13.
张波  张进江  郭磊 《地质科学》2006,41(1):158-169
位于北喜马拉雅穹隆带东段的然巴构造穹隆外围发育环形韧性剪切带,带内岩石经韧性剪切形成各类糜棱状岩石。石英为带内变形岩中最为常见的造岩矿物,在不同的温度、应变速率下产生不同的显微构造,其中动态重结晶最为常见。重结晶新晶颗粒边界普遍具有锯齿状或港湾状结构,是应变和变形环境的天然记录。新晶粒分维几何统计分析表明:带内动态重结晶石英颗粒边界形态具有自相似性(1≤D≤2),表现出分形特征,分维数值为1.14~1.19,变形温度大约500℃。同构造变质环境属中——高绿片岩相;初步估算古应变速率可能低于10-9.5S-1;根据重结晶粒径估算变形古应力6.2~58.8MPa。  相似文献   

14.
Strain rate during testing, uniaxial or triaxial, has important influence on the measured mechanical properties of rocks. Uniaxial compression tests were performed at nine pre-specified static-to-quasistatic strain rates (ranging from 1 × 10?5 to 1 × 10?1 s?1) on coarse crystal marble. The aim is to gain deep insight into the influence of strain rate on characteristic stresses, deformation properties and conversion of strain energy of such rock. It is found that the strain rate of 5 × 10?3 s?1 is the threshold to delineate the failure modes the tested coarse marble behaves in. At a strain rate less than this threshold, single-plane shear and conjugate X-shaped shear are the main failure modes, while beyond this threshold, extensile and splitting failures are dominant. The stress for crack initiation, the critical stress for dilation, the peak stress, and Young’s modulus are all found to increase with strain rate, with an exception that the above stresses and modulus appear relatively low compared to the strain rate in the range of between 1 × 10?4 and 5 × 10?3 s?1. The pre-peak absorbed strain energy, damage strain energy and elastic strain energy are found to increase with strain rate. In addition, the elastic strain energy stored before peak point favors brittle failure of the specimen, as the more stored elastic energy in the specimen, the stronger the fragmenting.  相似文献   

15.
The mechanical properties and microstructures of mixed kaolinite/ quartz fault gouge have been studied by means of triaxial tests, wherein a 1 mm thickness of fault gouge was sheared between rigid, sintered alumina sliders. Test conditions ranged up to 200 MPa confining pressure, 175 MPa pore water pressure and temperatures to 600°C. Constant displacement rate tests were carried out at 5×10-4 mm s-1, and the stress relaxation technique was used to access a wide range of lower displacement rates down to 10-10 mm s-1. The effects of different ratios of clay: quartz were studied, and some experiments were cafried out using crushed Tennessee sandstone gouge and pre-faulted cylinders of Tennessee sandstone. Deformation-induced microstructures were studied by optical, scanning and transmission electron microscopy, and mineral chemistry changes were identified using EDS analysis in the STEM. The most important factor determining the strength of these gouges is effective confining pressure, and the effective stress law was obeyed at all test conditions. Increasing the proportion of quartz in the gouge slightly increases the strength, as does increase of temperature. Under all test conditions the gouges deformed by strain-hardening stable sliding. At 2 mm displacement the friction coefficient is similar to that for rock and rock sliding (μ= 0.85). Over wide ranges of strain-rate and temperature the strength of these gouges is little affected if the effective pressure is high, but strength drops rapidly with decreasing strain-rate if effective pressure is low (or if pore water pressure is high). Reloading of the gouge after stress relaxation at high temperatures demonstrated hardening arising from hydrothermal cementation during stress relaxation, which led to sudden rupture of the cemented gouge. This phenomenon may be responsible for cyclic rupture of natural faults. New mineral phases were produced in these experiments only at 600°C. At 400°C, anticipated production of pyrophyllite from kaolinite plus quartz was not found, but recrystallization of kaolinite is believed to have occurred and evidence of healing of cracks in quartz was seen. Microstructural studies revealed the ubiquitous development of P and R1 foliations and other features, which are identical to those found in natural clay-bearing fault zones. Microstructural evolution is associated with the strain-hardening, and apparent hardening is strongly associated with the stress path during loading.  相似文献   

16.
Anhua-Xupu fault belt plays a very important role in the formation of Xuefeng Mountains. The fault belt shows an arc-structure extruding towards NW. Fault rocks, microstructures and homogeneous temperature (concentrated around 160℃) of fluid inclusions in the quartz veins shows that the fault belt mainly underwent shallow brittle deformation and the highest-grade dynamic metamorphic rock is mylonitized sericite phyllite. The ESR (Electron Spin Resonance) dating from the quartz veins in the fault rocks shows that the fault belt underwent two intense fluid movement stages at Yanshanian(156.9-136.2Ma, 119.8-90.6Ma); moreover not only the occurrence and microstructures but also the homogeneous temperature of the quartz veins developed in that two stages show obvious diversity, which can prove that there exists the reversion period of Mesozoic extension and compression movement of Xuefeng mountains between these two stages.  相似文献   

17.
High-temperature decompression experiments demonstrate that crystal textures preserve a record of the style and rate of magmatic ascent. To reinforce this link, we performed a suite of isothermal decompression experiments using starting material from the climactic 1991 Pinatubo eruption. We decompressed experiments from 220 MPa to final, quench pressures of 75 or 30 MPa using continuous decompression rates of 100, 30, 10, 3, 1, and 0.3 MPa h?1. Amphibole, clinopyroxene, and plagioclase crystallized during the experiments, with plagioclase microlites dominating the assemblage. Total microlite number densities range from 107.6±0.4 up to 108.2±0.2 cm?3, with plagioclase accounting for up to 65% of the total number. Plagioclase microlite area increased systematically from 19?±?8 to 937?±?487 µm2 with increasing experiment duration. Our textures provide time-integrated records of crystal kinetics. Average nucleation and areal growth rates of plagioclase are highest in the fastest decompressions (~?107.5 cm?3 h?1 and 10.1?±?4.1 µm2 h?1, respectively) and more than an order of magnitude lower in the slowest experiments (~?105.5 cm?3 h?1 and 0.8?±?0.2 µm2 h?1, respectively). Both nucleation and growth rates are highest at high degrees of disequilibrium. We find that peak supersaturation-dependent instantaneous rates are generally more than an order of magnitude faster than average rates. We use those instantaneous nucleation and growth rates to introduce an iterative model to evaluate the effects of different decompression rates, decompression paths (continuous, single-step or multistep), and the presence of phenocrysts on final crystallinity and microlite size distribution.  相似文献   

18.
Microstructural analysis and microthermometry are useful methods for determining the deformation evolution. To address this issue, rheological behavior of quartz, feldspar and calcite in veins and host rocks during deformation, are presented in the mylonite zone of the dextral reverse Zamanabad Shear Zone (ZSZ), in northern part of Sistan Suture Zone (SSZ), in east of Iran. Microstructure evidences revealed two evolution stages of high and low temperature deformation. Quartz microstructures in the ZSZ show abundant evidences for early high-temperature plastic deformation (e.g. Bulging recrystallization (BLG)) which are as microstructures with SW directed ductile shearing in the central parts of the ZSZ. This shear zone shows progressively decreasing strain away from the central of shear zone toward the wall. High-temperature microstructures are overprinted partly or completely during shearing by the later low-temperature deformation (e.g. Pressure solution, fractures, veinlets). Microstructural observations of veins (quartz and calcite) confirms the results of microstructures in the host rock, as quartz veins occurred from peak metamorphic conditions (<400°C) and then in lower P–T conditions have been formed calcite veins (~250°C). According to microthermometric studies, two primary fluid groups are observed in quartz veins: (1) fluids trapped during peak deformation conditions, with higher-salinity, They were initially trapped at ~300–400°C, (2) smaller fluids by trapping of low-salinity inclusions at ~240–180°C that related to subsequent phases of shear zone exhumation in lower deep. Microthermometry results and microstructural analysis indicate deformation under lower greenschist facies conditions for the ZSZ, and then exhumation of the early of high-temperature rocks within regime of ductile-brittle transition to brittle.  相似文献   

19.
Quartzofeldspathic ultramylonites from the Alpine Fault Zone, one of the world's major, active plate boundary-scale fault zones have quartz crystallographic preferred orientations (CPO) and abundant low-angle (<10° misorientation) boundaries, typical microstructures for dislocation creep-dominated deformation. Geometrically necessary dislocation density estimates indicate mean dislocation densities of ∼109 cm−2. A significant proportion (∼30%) of grain boundaries (>10° misorientation) are decorated by faceted pores, commonly with uniformly-oriented pyramidal shapes. Only grain boundaries with >10° misorientation angles in polymineralic aggregates are decorated by pores. Mean grain boundary pore densities are ∼5 × 108 cm−2. Grain boundary pores are dissolution pits generated during syn-deformational transient grain boundary permeability, nucleating on dislocation traces at dilatant grain boundary interfaces. They have not been removed by subsequent grain boundary closure or annealing. Pore decoration could have led to grain boundary pinning, triggering a switch in the dominant deformation mechanism to grain boundary sliding, which is supported by evidence of CPO destruction in matrix quartz. Pore-decorated grain boundaries have significantly reduced surface area available for adhesion and cohesion, which would reduce the tensile and shear strength of grain boundaries, and hence, the bulk rock. Grain boundary decoration also significantly decreased the mean distance between pores, potentially facilitating dynamic permeability. Consequently, these microstructures provide a new explanation for strain weakening and evidence of fluid flow along grain boundaries in mylonites at mid-crustal conditions.  相似文献   

20.
We extended a previous study on the influence of Mg solute impurity on diffusion creep in calcite to include deformation under a broader range of stress conditions and over a wider range of Mg contents. Synthetic marbles were produced by hot isostatic pressing (HIP) mixtures of calcite and dolomite powders for different intervals (2–30 h) at 850°C and 300 MPa confining pressure. The HIP treatment resulted in high-magnesian calcite aggregates with Mg content ranging from 0.5 to 17 mol%. Both back-scattered electron images and chemical analysis suggested that the dolomite phase was completely dissolved, and that Mg distribution was homogeneous throughout the samples at the scale of about two micrometers. The grain size after HIP varied from 8 to 31 μm, increased with time at temperature, and decreased with increasing Mg content (>3.0 mol%). Grain size and time were consistent with a normal grain growth equation, with exponents from 2.4 to 4.7, for samples containing 0.5–17.0 mol% Mg, respectively. We deformed samples after HIP at the same confining pressure with differential stresses between 20 and 200 MPa using either constant strain rate or stepping intervals of loading at constant stresses in a Paterson gas-medium deformation apparatus. The deformation tests took place at between 700 and 800°C and at strain rates between 10−6 and 10−3 s−1. After deformation to strains of about 25%, a bimodal distribution of large protoblasts and small recrystallized neoblasts coexisted in some samples loaded at higher stresses. The deformation data indicated a transition in mechanism from diffusion creep to dislocation creep. At stresses below 40 MPa, the strength was directly proportional to grain size and decreased with increasing Mg content due to the reductions in grain size. At about 40 MPa, the sensitivity of log strain rate to log stress, (n), became greater than 1 and eventually exceeded 3 for stresses above 80 MPa. At a given strain rate and temperature, the stress at which that transition occurred was larger for samples with higher Mg content and smaller grain size. At given strain rates, constant temperature, and fixed grain size, the strength of calcite in the dislocation creep regime increased with solute content, while the strength in the diffusion creep regime was independent of Mg content. The results suggest that chemical composition will be an important element to consider when solid substitution can occur during natural deformation.  相似文献   

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