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1.
Groundwaters and surface water in the Shihongtan sandstone-hosted U ore district, Xinjiang, NW China, were sampled and analyzed for their major-, and trace element concentrations and oxygen, hydrogen, boron and strontium isotope compositions in order to assess the possible origins of the waters and water–rock interactions that occurred in the deep aquifer system. The waters in the study district have been grouped into three hydrochemical facies: Facies 1, potable spring-water, is a pH neutral (7.0), Na–Ca–HCO3 type water with low total dissolved solids (TDS; 0.2 g/l, fresh) and has δ18O of − 8.3‰, δD of − 48.2‰,δ11B of 1.5‰, and 87Sr/86Sr of 0.70627. Facies 2 groundwaters are mildly acidic to mildly alkaline (pH of 6.5–8.0, mean 7.3), Na–Ca–Mg–Cl–SO4 type waters with moderate TDS (8.2 g/l–17.2 g/l, mean 9.3 g/l, brackish) and haveδ18O values in the − 5.8‰ to − 9.3‰ range (mean − 8.1‰), δD values in the − 20.8‰ to − 85.5‰ range (mean − 47.0‰),δ11B values in the + 9.5‰ to + 39.1‰ range (mean + 17.1‰), and 87Sr/86Sr values in the 0.70595 to 0.70975 range (mean 0.70826). Facies 3, Aiting Lake water, is a mildly alkaline (pH = 7.4), Na–Ca–Mg–Cl–SO4 type water with the highest TDS (249.1 g/l, brine) and has δ18O of − 2.8‰, δD of − 45.8‰,δ11B of 21.2‰, and 87Sr/86Sr of 0.70840. The waters from the study district show a systematic increase in major, trace element and TDS concentrations and δ11B values along the pathway of groundwater migration which can only be interpreted in terms of water–rock interaction at depth and strong surface evaporation. The hydrochemical and isotopic data presented here confirm that the groundwaters in the Shihongtan ore district are the combined result of migration, water–rock interaction and mixing of meteoric water with connate waters contained in sediments.  相似文献   

2.
Combined stable isotope (δ18O and δ13C) and trace element (Mg, Sr) geochemistry from bulk tufa calcite and ostracod shell calcite from an early Holocene British tufa reveal clear records of Holocene palaeoclimatic change. Variation in δ18O is caused principally by change in the isotopic composition of Holocene rainfall (recharge), itself caused mainly by change in air temperature. The δ13C variability through much of the deposit reflects increasing influence of soil‐zone CO2, owing to progressive woodland soil development. Bulk tufa Mg/Ca and Sr/Ca are controlled by their concentrations in the spring water. Importantly, Mg/Ca ratios are not related to δ18O values and thus show no temperature dependence. First‐order sympathetic relationships between δ13C values and Mg/Ca and Sr/Ca are controlled by aquifer processes (residence times, CO2 degassing and calcite dissolution/reprecipitation) and probably record intensity of palaeorainfall (recharge) effects. Stable isotope records from ostracod shells show evidence of vital effects relative to bulk tufa data. The ostracod isotopic records are markedly ‘spiky’ because the ostracods record ‘snapshots’ of relatively short duration (years), whereas the bulk tufa samples record averages of longer time periods, probably decades. The δ18O record appears to show early Holocene warming, a thermal maximum at ca. 8900 cal. yr BP and the global 8200 yr BP cold event. Combined δ13C, Mg/Ca and Sr/Ca data suggest that early Holocene warming was accompanied by decreasing rainfall intensity. The Mg/Ca data suggest that the 8200 yr BP cold event was also dry. Warmer and wetter conditions were re‐established after the 8200 yr BP cold event until the top of the preserved tufa sequence at ca. 7100 cal. yr BP. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

3.
We present a continuous ∼14-yr-long (1985 to 1999) high-resolution record of trace element (Mg, Sr, Ba, U) and stable isotope (δ13C, δ18O) variations in a modern freshwater tufa from northwestern Queensland, Australia. By utilizing the temperature dependence of the δ18O signal, an accurate chronology was developed for the sampled profile, which allowed a comparison of the chemical records with hydrological and meteorological observations. As a consequence, it was possible to constrain the relevant geochemical processes relating climate variables, such as temperature and precipitation, to their chemical proxies in the tufa record. Temperatures calculated from the Mg concentrations of the tufa samples provide close approximations of average annual water temperature variations. Furthermore, we demonstrate that temporal changes in (Mg/Ca)water can be estimated using an empirically derived equation relating (Mg/Ca)water to the (Sr/Ba) ratio measured in the tufa samples. By means of this relationship, it is theoretically possible to determine the (Mg/Ca) ratio of paleowaters, and hence to derive reliable estimates of former water temperatures from the Mg concentrations of fossil tufas from the study area. Sympathetic variations in Sr, Ba, and δ13C along the sampled profile record changes in water chemistry, which are most probably caused by variable amounts of calcite precipitation within the vadose zone of the karst aquifer. This process is thought to be markedly subdued whenever the amount of wet-season precipitation exceeds a given threshold. Accordingly, distinct minima in Sr, Ba, and δ13C are interpreted to reflect years with above-average rainfall. The pronounced seasonal and annual variability of the U concentration along the profile is thought to primarily record changes in the U flux from the soil to the water table. We suggest that during intensive rain events U is transported to the phreatic zone by complexing organic colloids, giving rise to conspicuous U maxima in the tufa after above-average wet seasons. This study demonstrates the potential of freshwater tufas to provide valuable information on seasonal temperature and rainfall variations. If tufa deposits turn out to be reasonably resistant to secondary processes, combined investigation of speleothems and tufas from the same area could become a promising approach in future research. While speleothems offer continuous records of long-term paleoenvironmental changes, tufas could provide high-resolution time windows into selected periods of the past.  相似文献   

4.
Thirty-nine samples of both cold and thermal karst groundwater from Taiyuan, northern China were collected and analyzed with the aim of developing a better understanding of the geochemical processes that control the groundwater quality evolution in the region’s carbonate aquifers. The region’s karst groundwater system was divided into three geologically distinct sub-systems, namely, the Xishan Mountain karst groundwater subsystem (XMK), the Dongshan Mountain karst groundwater subsystem (DMK) and the Beishan Mountain karst groundwater subsystem (BMK). Hydrochemical properties of the karst groundwaters evolve from the recharge zones towards the cold water discharge zones and further towards the thermal water discharge zones. In the XMK and the DMK, the hydrochemical type of the groundwater evolves from HCO3-Ca·Mg in the recharge - flow-through zone, to HCO3·SO4-Ca·Mg/SO4·HCO3-Ca·Mg in the cold water discharge zone, and further to SO4-Ca·Mg in the thermal water discharge zone. By contrast, the water type changes from HCO3-Ca·Mg to HCO3·SO4-Ca·Mg in the BMK, with almost invariable TDS and temperatures all along from the recharge to the discharge zone. The concentrations of Sr, Si, Fe, F− and of some trace elements (Al, B, Li, Mn, Mo, Co, Ni) increase as groundwater temperature increases. Different hydrogeochemical processes occur in the three karst groundwater sub-systems. In the XMK and the DMK, the geochemical evolution of the groundwater is jointly controlled by carbonate dissolution/precipitation, gypsum dissolution and dedolomitization, while only calcite and dolomite dissolution/precipitation occurs in the BMK without dedolomitization. The hydrogeochemical data of the karst groundwaters were used to construct individual geochemical reaction models for each of the three different karst groundwater sub-systems. The modeling results confirm that dedolomization is the major process controlling hydrochemical changes in the XMK and the DMK. In the thermal groundwaters, the dissolution rates of fluorite, siderite and strontianite were found to exceed those of the cold karst groundwater systems, which can explain the higher concentrations of F−, Fe and Sr2+ that are found in these waters.  相似文献   

5.
Tufa domes and towers are common around the margins of Winnemucca Dry Lake, Nevada, USA, a desiccated sub‐basin of pluvial Lake Lahontan. A 2·5 m diameter concentrically‐layered tufa mound from the southern end of the playa was sampled along its growth axis to determine timing, rate and geochemical conditions of tufa growth. A radiocarbon‐based age model indicates an 8200‐year tufa depositional record that begins near the end of the Last Glacial Maximum (ca 23 400 cal yr bp ) and concludes at the end of the most recent Lahontan highstand (ca 15 200 cal yr bp ). Petrography, stable isotopes and major and minor elemental compositions are used to evaluate the rate and timing of tufa growth in the context of the depositional environment. The deposit built radially outward from a central nucleation point, with six decimetre‐scale layers defined by variations in texture. Two distinct tufa types are observed: the inner section is composed of two layers of thinolite pseudomorphs after ikaite, with the innermost layer comprised of very small pseudomorphs (<0·25 cm) and an outer layer composed of larger, ca 3 cm long pseudomorphs, followed by a transitional layer where thinolite pseudomorphs grade into calcite fans. The outer section consists of three distinct layers of thrombolitic micrite with a branching mesofabric. The textural change occurred as lake levels began to rise towards the most recent Lahontan highstand interval and probably was prompted by warming of lake waters caused by increased groundwater flux during highstand lake levels. The Mg/Ca and Sr/Ca variations suggest a warming trend in the tufa growth environment and may also reflect increasing growth rates of tufa associated with increased fluxes of groundwater. This systematic study of tufa deposition indicates the importance of the hydrology of the lacustrine tufa system for reconstructing palaeoenvironmental records, and particularly the interaction of ground and surface waters.  相似文献   

6.
The tufa record and hydrochemical characteristics of the River Piedra in the Monasterio de Piedra Natural Park (NE Spain) were studied for 6 years. The mean discharge of this river was 1.22 m3/s. The water was supersaturated with calcium carbonate. The HCO3 −, Ca2+ and TDIC concentrations decreased along the 0.5-km-long studied stretch, whereas the calcite SI showed no systematic downstream or seasonal variation over the same stretch. Several sedimentary subenvironments exist in which four broad types of tufa facies form: (1) Dense laminated tufa (stromatolites), (2) Dense to porous, massive tufa, (3) Porous, coarsely laminated tufa with bryophytes and algae, and (4) Dense, hard, laminated deposits in caves. The half-yearly period thickness and weight of sediment accumulated on 14 tablets installed in several subenvironments showed that the deposition rate was greater in fast flowing river areas and in stepped waterfalls, and lower in slow flowing or standing river areas and in spray and splash areas. Mechanical CO2 outgassing is the main factor controlling calcite precipitation on the river bed and in waterfalls, but this process does not explain the seasonal changes in depositional rates. The deposition rates showed a half-yearly period pattern recorded in all fluvial subenvironments persistent over time (5.26 mm, 0.86 g/cm2 in warm periods; 2.26 mm, 0.13 g/cm2 in cool periods). Mass balance calculations showed higher calcite mass values in warm (21.58 mg/L) than in cool (13.68 mg/L) periods. This biannual variation is mainly attributed to the seasonal differences in temperature that caused changes in inorganic calcite precipitation rate and in biomass and the correlative photosynthetic activity. Tufa sedimentation was therefore controlled by both physicochemical and biological processes. The results of this study may help test depositional rates and their environmental controls and thus assess the climatic and hydrological significance of ancient tufas in semi-arid conditions, in particular in the Quaternary.  相似文献   

7.
The Kangan Aquifer (KA) is located below a gas reservoir in the crest of the Kangan Anticline, southwest of Iran. This aquifer is composed of Permo-Triassic limestone, dolomite, sandstone, anhydrite and shale. It is characterized by a total dissolved solid of about 332,000 mg/L and Na–Ca–Cl-type water. A previous study showed that the source of the KA waters is evaporated seawater. Chemical evolution of the KA is the main objective of this study. The major, minor and trace element concentrations of the KA waters were measured. The chemical evolution of KA waters occurred by three different processes: evaporation of seawater, water–rock and water–gas interactions. Due to the seawater evaporation process, the concentration of all ions in the KA waters increased up to saturation levels. In comparison to the evaporated seawater, the higher concentrations of Ca, Li, Sr, I, Mn and B and lower concentrations of Mg, SO4 and Na and no changes in concentrations of Cl and K ions are observed in the KA waters. Based on the chemical evolution after seawater evaporation, the KA waters are classified into four groups: (1) no evolution (Cl, K ions), (2) water–rock interaction (Na, Ca, Mg, Li and Sr ions), (3) water–gas interaction (SO4 and I ions) and (4) both water–rock and water–gas interactions (Mn and B ions). The chemical evolution processes of the KA waters include dolomitization, precipitation, ion exchange and recrystallization in water–rock interaction. Bacterial reduction and diagenesis of organic material in water–gas interaction also occur. A new type of chart, Caexcess versus Mgdeficit, is proposed to evaluate the dolomitization process.  相似文献   

8.
The Central African Belt in the Nkambe area, northwestern Cameroon represents a collisional zone between the Saharan metacraton and the Congo craton during the Pan-African orogeny, and exposes a variety of granitoids including foliated and massive biotite monzogranites in syn- and post-kinematic settings. Foliated and massive biotite monzogranites have almost identical high-K calc-alkaline compositions, with 73–67 wt.% SiO2, 17–13 wt.% Al2O3, 2.1–0.9 wt.% CaO, 4.4–2.7 wt.% Na2O and 6.3–4.4 wt.% K2O. High concentrations of Rb (264–96 ppm), Sr (976–117 ppm), Ba (3680–490 ppm) and Zr (494–99 ppm), with low concentrations of Y (mostly< 20 ppm with a range 54–6) and Nb (up to 24 ppm) suggest that the monzogranites intruded in collisional and post-collisional settings. The Sr/Y ratio ranges from 25 to 89. K, Rb and Ba resided in a single major phase such as K-feldspar in the source. Garnet was present in the source and remained as restite at the site of magma generation. This high K2O and Sr/Y granitic magma was generated by partial melting of a granitic protolith under high-pressure and H2O undersaturated conditions where garnet coexists with K-feldspar, albitic plagioclase. CHIME (chemical Th–U-total Pb isochron method) dating of zircon yields ages of 569 ± 12–558 ± 24 Ma for the foliated biotite monzogranite and 533 ± 12–524 ± 28 Ma for the massive biotite monzogranite indicating that the collision forming the Central African Belt continued in to Ediacaran (ca 560 Ma).  相似文献   

9.
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10.
The Alkaline porphyries in the Beiya area are located east of the Jinshajiang suture, as part of a Cenozoic alkali-rich porphyry belt in western Yunnan. The main rock types include quartz-albite porphyry, quartz-K-feldspar porphyry and biotite–K-feldspar porphyry. These porphyries are characterised by high alkalinity [(K2O + Na2O)% > 10%], high silica (SiO2% > 65%), high Sr (> 400 ppm) and 87Sr/86Sr (> 0.706)] ratio and were intruded at 65.5 Ma, between 25.5 to 32.5 Ma, and about 3.8 Ma, respectively. There are five main types of mineral deposits in the Beiya area: (1) porphyry Cu–Au deposits, (2) magmatic Fe–Au deposits, (3) sedimentary polymetallic deposits, (4) polymetallic skarn deposits, and (5) palaeoplacers associated with karsts. The porphyry Cu–Au and polymetallic skarn deposits are associated with quartz–albite porphyry bodies. The Fe–Au and polymetallic sedimentary deposits are part of an ore-forming system that produced considerable Au in the Beiya area, and are characterised by low concentrations of La, Ti, and Co, and high concentrations of Y, Yb, and Sc.The Cenozoic porphyries in western Yunnan display increased alkalinity away from the Triassic Jinshajiang suture. Distribution of both the porphyries and sedimentary deposits in the Beiya area are interpreted to be related to partial melting in a disjointed region between upper mantle lithosphere of the Yangtze Plate and Gondwana continent, and lie within a shear zone between buried Palaeo-Tethyan oceanic lithosphere and upper mantle lithosphere, caused by the subduction and collision of India and Asia.  相似文献   

11.
Two different field-based methods are used here to calculate feldspar dissolution rates in the Topopah Spring Tuff, the host rock for the proposed nuclear waste repository at Yucca Mountain, Nevada. The center of the tuff is a high silica rhyolite, consisting largely of alkali feldspar (60 wt%) and quartz polymorphs (35 wt%) that formed by devitrification of rhyolitic glass as the tuff cooled. First, the abundance of secondary aluminosilicates is used to estimate the cumulative amount of feldspar dissolution over the history of the tuff, and an ambient dissolution rate is calculated by using the estimated thermal history. Second, the feldspar dissolution rate is calculated by using measured Sr isotope compositions for the pore water and rock. Pore waters display systematic changes in Sr isotopic composition with depth that are caused by feldspar dissolution. The range in dissolution rates determined from secondary mineral abundances varies from 10−16 to 10−17 mol s−1 kg tuff−1 with the largest uncertainty being the effect of the early thermal history of the tuff. Dissolution rates based on pore water Sr isotopic data were calculated by treating percolation flux parametrically, and vary from 10−15 to 10−16 mol s−1 kg tuff−1 for percolation fluxes of 15 mm a−1 and 1 mm a−1, respectively. Reconciling the rates from the two methods requires that percolation fluxes at the sampled locations be a few mm a−1 or less. The calculated feldspar dissolution rates are low relative to other measured field-based feldspar dissolution rates, possibly due to the age (12.8 Ma) of the unsaturated system at Yucca Mountain; because oxidizing and organic-poor conditions limit biological activity; and/or because elevated silica concentrations in the pore waters (50 mg L−1) may inhibit feldspar dissolution.  相似文献   

12.
There are 59 springs at the Gevas–Gurp?nar–Güzelsu basins, 38 of these springs emerge from the fractured karst aquifers (recrystallized limestone and travertine) and 21 emerge from the Yuksekova ophiolites, K?rkgeçit formation and alluvium. The groundwater samples collected from 38 out of the total of 59 springs, two streams, one lake and 12 wells were analyzed physico-chemically in the year 2002. EC and TDS values of groundwater increased from the marble (high altitude) to the ophiolites and alluvium (toward Lake Van) as a result of carbonate dissolution and connate seawater. Five chemical types of groundwater are identified: Ca–Mg–HCO3, Mg–Ca–HCO3, Mg–Na–HCO3, Na–Ca–HCO3 and Mg–Ca–Na–HCO3. The calculations and hydrochemical interpretations show that the high concentrations of Ca2+, Mg2+ and HCO3 ? as predominant ions in the waters are mainly attributed to carbonate rocks and high pCO2 in soil. Most of the karst springs are oversaturated in calcite, aragonite and dolomite and undersaturated in gypsum, halite and anhydrite. The water–rock interaction processes that singly or in combination influence the chemical composition of each water type include dissolution of carbonate (calcite and dolomite), calcite precipitation, cation exchange and freshening of connate seawater. These processes contribute considerably to the concentration of major ions in the groundwater. Stable isotope contents of the groundwater suggest mainly direct integrative recharge.  相似文献   

13.
We report analyses of noble gases and Nd–Sr isotopes in mineral separates and whole rocks of late Pleistocene (< 0.2 Ma) monzonites from Ulleungdo, South Korea, a volcanic island within the back arc basin of the Japan island arc. A Rb–Sr mineral isochron age for the monzonites is 0.12 ± 0.01 Ma. K–Ar biotite ages from the same samples gave relatively concordant ages of 0.19 ± 0.01and 0.22 ± 0.01 Ma. 40Ar/39Ar yields a similar age of 0.29 ± 0.09 Ma. Geochemical characteristics of the felsic plutonic rocks, which are silica oversaturated alkali felsic rocks (av., 12.5 wt% in K2O + Na2O), are similar to those of 30 alkali volcanics from Ulleungdo in terms of concentrations of major, trace and REE elements. The initial Nd–Sr isotopic ratios of the monzonites (87Sr/86Sr = 0.70454–0.71264, 143Nd/144Nd = 0.512528–0.512577) are comparable with those of the alkali volcanics (87Sr/86Sr = 0.70466–0.70892, 143Nd/144Nd = 0.512521–0.512615) erupted in Stage 3 of Ulleungdo volcanism (0.24–0.47 Ma). The high initial 87Sr/86Sr values of the monzonites imply that seawater and crustally contaminated pre-existing trachytes may have been melted or assimilated during differentiation of the alkali basaltic magma.A mantle helium component (3He/4He ratio of up to 6.5 RA) associated with excess argon was found in the monzonites. Feldspar and biotite have preferentially lost helium during slow cooling at depth and/or during their transportation to the surface in a hot host magma. The source magma noble gas isotopic features are well preserved in fluid inclusions in hornblende, and indicate that the magma may be directly derived from subcontinental lithospheric mantle metasomatized by an ancient subduction process, or may have formed as a mixture of MORB-like mantle and crustal components. The radiometric ages, geochemical and Nd–Sr isotopic signatures of the Ulleungdo monzonites as well as the presence of mantle-derived helium and argon, suggests that these felsic plutonic rocks evolved from alkali basaltic magma that formed by partial melting of subcontinental lithospheric mantle beneath the back arc basin located along the active continental margin of the southeastern part of the Eurasian plate.  相似文献   

14.
This paper describes a technique, which allows precise and accurate Sr isotope measurement combined with trace element analysis of individual melt inclusions, of sample sizes  1 ng of Sr. The technique involves sampling by micro-milling, chemical dissolution, micro Sr column chemistry, TIMS, and ICPMS analyses. A 10% aliquot of each sample solution is used for trace element analysis by double focusing magnetic sector field ICPMS, while Sr is chemically separated from the remaining 90% and used for 87Sr/86Sr determinations by TIMS.During the development of the technique outlined above, we documented in detail the potential sources of blank contributions and their magnitude. The average size and Sr isotope composition of our laboratory total procedural blank during this study was 5.4 pg ± 0.3 pg Sr (n = 21) with an 87Sr/86Sr of 0.7111 ± 0.0002 (2SE, n = 3). The total procedural Rb blank was 1.9 ± 0.7 pg (n = 21). The total procedural blank was found to have minimal effect (< 150 ppm shift) on the 87Sr/86Sr of sample material containing down to  250 pg Sr. Applying a blank correction allows ‘in house’ standards of this size to be corrected back to within 175 ppm of their accepted values. By applying blank corrections we can confidently measure the Sr isotope composition on sample sizes down to  25 pg Sr to an accuracy better than 400 ppm.The utility of the technique is illustrated by application to a suite of melt inclusions from NW Iceland and their host olivines. It is shown that the effect of a small amount of entrainment of the host olivine during sampling of 50 μm melt inclusions has a negligible effect on the measured Sr isotope and trace element composition. Furthermore, where melt inclusions are < 50 μm it is possible to obtain Sr isotope and trace element data on multiple melt inclusions hosted in a single olivine. This provides similar information to that of the single melt inclusions.  相似文献   

15.
Photosynthetic influences on tufa stromatolite formation and ambient water chemistry were investigated at two well-studied streams depositing tufa in Southwestern Japan (Shirokawa and Shimokuraida). The tufa stromatolites in both streams are composed of fine-grained calcite crystals showing annual lamination, and colonized by a number of filamentous cyanobacteria as well as non-phototrophic bacteria. Microelectrode measurements of pH, O2, and Ca2+ near the stromatolite surface (the diffusive boundary layer; DBL) revealed that the investigated tufa stromatolites are formed by photosynthesis-induced CaCO3 precipitation (PCP): cyanobacterial photosynthesis induces calcite precipitation under light conditions, while respiration of cyanobacteria and non-phototrophic bacteria inhibits precipitation in the dark. The bulk water chemistry at the lower sites of the investigated streams showed the daytime decreases of Ca2+ concentration and alkalinity that was expected for significant influence of PCP, while the other expected change, increased pH, was not observed. In order to examine this discrepancy, a novel approach using semi-in situ microelectrode measurements was applied to perform precise quantitative calculations. The calculation results demonstrated that the observed Ca2+ concentration and alkalinity decreases were caused by PCP, and that the concomitant pH increase was expected to be under the detection level of a conventional pH meter. Although the amount of PCP is supposed to be significantly affected by light intensity, observations in Shimokuraida revealed that the amount of PCP on cloudy day nonetheless accounted for about 80% of that on sunny day. Despite the significant role of PCP for tufa stromatolite formation, PCP accounted for only about 10% of the precipitated calcite in the investigated streams, which indicates that tufa stromatolites, the characteristic deposits in the streams, are responsible for only a small portion of calcite precipitation, and the rest is considered to precipitate inorganically at biofilm-free substrates.  相似文献   

16.
A geochemical and isotopic study was carried out for the Mesozoic Yangxin, Tieshan and Echeng granitoid batholiths in the southeastern Hubei Province, eastern China, in order to constrain their petrogenesis and tectonic setting. These granitoids dominantly consist of quartz diorite, monzonite and granite. They are characterized by SiO2 and Na2O compositions of between 54.6 and 76.6 wt.%, and 2.9 to 5.6 wt.%, respectively, enrichment in light rare earth elements (LREE) and large ion lithophile elements (LILE), and relative depletion in Y (concentrations ranging from 5.17 to 29.3 ppm) and Yb (0.34–2.83 ppm), with the majority of the granitoids being geochemically similar to high-SiO2 adakites (HSA). Their initial Nd (εNd = − 12.5 to − 6.1) and Sr ((87Sr/86Sr)i = 0.7054–0.7085) isotopic compositions, however, distinguish them from adakites produced by partial melting of subducted slab and those produced by partial melting of the lower crust of the Yangtze Craton in the Late Mesozoic. The granitoid batholiths in the southeastern Hubei Province exhibit very low MgO ranging from 0.09 to 2.19 wt.% with an average of 0.96 wt.%, and large variations in negative to positive Eu anomalies (Eu/Eu = 0.22–1.4), especially the Tieshan granites and Yangxin granite porphyry (Eu/Eu = 0.22–0.73). Geochemical and Nd–Sr isotopic data demonstrate that these granitoids originated as partial melts of an enriched mantle source that experienced significant contamination of lower crust materials and fractional crystallization during magma ascent. Late Mesozoic granitoids in the southeastern Hubei Province of the Middle–Lower Yangtze River belt were dominantly emplaced in an extensional tectonic regime, in response to basaltic underplating, which was followed by lithospheric thinning during the early Cretaceous.  相似文献   

17.
Hydrogeochemical assessment of groundwater in Moro area,Kwara state,Nigeria   总被引：1，自引：0，他引：1  
Detailed study of chemical analysis results of several groundwater samples (UNICEF-Assisted Water project, Kwara state, Nigeria) were carried out in an attempt to assess the quality and usability of groundwaters in the Moro area. Chemical analysis results indicate higher concentrations of Ca2+, Mg2+, and HCO3 – as compared to Na+, K+, Cl–, and SO4 2–. With exception of few locations where Fe is relatively higher, the concentrations of these ions together with other water quality parameters are all within permissible limits of the domestic and agricultural standards.On the basis of the analytical results, groundwaters in the study area are largely characterized as Ca-(Mg)-HCO3 type reflecting (possibly) young facies with limited migratory history. The occurrence of Ca-(Mg)-Na-HCO3 water type in certain areas is attributed to cation exchange processes. In addition, the observed scattered relationship between the TDS and the thickness of weathered horizons in the boreholes indicates the contribution of precipitation (recharge) to the ionic inputs in the groundwaters in addition to the weathering and dissolution processes.  相似文献   

18.
Shoshonitic series volcanic rocks (SSVR) and adakites are widely distributed in the Permian terrestrial volcanic strata of the Yishijilike–Awulale range of west Tianshan, north Xinjiang, China. Isotopic dating yields Permian ages of 280–250 Ma. The SSVR include absarokite, shoshonite and banakite which are characterized by enrichment of alkalis, particularly in K, combined with lower Ti, higher Al (A/NKC = 0.70–0.99, metaluminous) and Fe2O3 > FeO. The SSVR that are rich in LILE with high REE contents and Eu/Eu range from 0.59 to 1.30. They are rich in LREE ((La/Yb)N 2.15–11.97) and depleted in Nb, Ta and Ti (TNT negative anomalies). The adakites are metaluminous to weakly peraluminous (A/NKC = 0.85-1.16) and belong to the high-SiO2 type of adakite (HSA, SiO2 = 62%–71%). They are characterized by lower ΣREE with strong LREE enrichment ((La/Yb)N 13–35). Pronounced positive Eu anomalies (Eu/Eu = 1.02–1.27), very low Yb contents and distinct TNT-negative anomalies are evident. The SSVR have εNd(t) (+ 1.28 to + 4.92) and (87Sr/86Sr)i (0.7041–0.7057) that are similar to adakites in the regions which are characterized by εNd(t) = 0.95 to + 5.69 and (87Sr/86Sr)i = 0.7050–0.7053. Trace element, REE and Sr/Nd isotopic compositions suggest that both SSVR and adakites possess similar source regions associated with underplated mantle-derived basaltic materials. Lithosphere extension driven by magmatic underplating was responsible for the generation of both the SSVR and adakites. This magmatism serves as a petrological indicator of underplating during the Permian. Obviously thickened crust (62–52 km), a complex Moho discontinuity, high heat flow (~ 100 mw·m− 2), widespread contemporary alkali-rich granites, basic dike swarms (K–Ar ages of 187–271 Ma, Ar–Ar ages of 174–270 Ma and Rb–Sr ages of 255 ± 28 Ma; εNd(t) + 1.84 to + 10.1; (87Sr/86Sr)i 0.7035 and 0.7065), and basic granulites (SHRIMP U–Pb age of 268–279 ± 5.6 Ma) provide additional evidences for the underplating event in this area during Permian.  相似文献   

19.
In this study a typical coastal karst aquifer, developed in lower Cretaceous limestones, on the western Mediterranean seashore (La Clape massif, southern France) was investigated. A combination of geochemical and isotopic approaches was used to investigate the origin of salinity in the aquifer. Water samples were collected between 2009 and 2011. Three groundwater groups (A, B and C) were identified based on the hydrogeological setting and on the Cl− concentrations. Average and maximum Cl− concentrations in the recharge waters were calculated (ClRef. and ClRef.Max) to be 0.51 and 2.85 mmol/L, respectively). Group A includes spring waters with Cl− concentrations that are within the same order of magnitude as the ClRef concentration. Group B includes groundwater with Cl− concentrations that range between the ClRef and ClRef.Max concentrations. Group C includes brackish groundwater with Cl− concentrations that are significantly greater than the ClRef.Max concentration. Overall, the chemistry of the La Clape groundwater evolves from dominantly Ca–HCO3 to NaCl type. On binary diagrams of the major ions vs. Cl, most of the La Clape waters plot along mixing lines. The mixing end-members include spring waters and a saline component (current seawater or fossil saline water). Based on the Br/Clmolar ratio, the hypothesis of halite dissolution from Triassic evaporites is rejected to explain the origin of salinity in the brackish groundwater.Groundwaters display 87Sr/86Sr ratios intermediate between those of the limestone aquifer matrix and current Mediterranean seawater. On a Sr mixing diagram, most of the La Clape waters plot on a mixing line. The end-members include the La Clape spring waters and saline waters, which are similar to the deep geothermal waters that were identified at the nearby Balaruc site. The 36Cl/Cl ratios of a few groundwater samples from group C are in agreement with the mixing hypothesis of local recharge water with deep saline water at secular equilibrium within a carbonate matrix. Finally, PHREEQC modelling was run based on calcite dissolution in an open system prior to mixing with the Balaruc type saline waters. Modelled data are consistent with the observed data that were obtained from the group C groundwater. Based on several tracers (i.e. concentrations and isotopic compositions of Cl and Sr), calculated ratios of deep saline water in the mixture are coherent and range from 3% to 16% and 0% to 3% for groundwater of groups C and B, respectively.With regard to the La Clape karst aquifer, the extension of a lithospheric fault in the study area may favour the rise of deep saline water. Such rises occur at the nearby geothermal Balaruc site along another lithospheric fault. At the regional scale, several coastal karst aquifers are located along the Gulf of Lion and occur in Mezosoic limestones of similar ages. The 87Sr/86Sr ratios of these aquifers tend toward values of 0.708557, which suggests a general mixing process of shallow karst waters with deep saline fossil waters. The occurrence of these fossil saline waters may be related to the introduction of seawater during and after the Flandrian transgression, when the highly karstified massifs invaded by seawater, formed islands and peninsulas along the Mediterranean coast.  相似文献   

20.
The Sr, Ba, and rare earth elements (REEs) concentrations and Sr isotopic composition of anhydrite and gypsum have been determined for samples from the Matsumine, Shakanai, and Hanaoka Kuroko-type massive sulfide–sulfate deposits of northern Japan to evaluate the mechanisms of sekko (anhydrite and gypsum) ore formation. The Sr isotopic compositions of the samples fall in the range of 0.7077–0.7087, intermediate between that for middle Miocene (13–15 Ma) seawater (0.7088) (Peterman et al., Geochim Cosmochim Acta, 34:105–120, 1970) and that for country rocks (e.g., 0.7030–0.7050) (Shuto, Assn Geol Collab Japan Monograph 18:91–105, 1974). The Kuroko anhydrite samples exhibit two types of chondrite-normalized REE patterns: one with a decrease from light REEs (LREEs) to heavy REEs (HREEs) (type I), and another with a LREE-depleted pattern (type II). Based on the Sr content and isotopic ratio (assuming an Sr/Ca (mM/M) of 8.7 for seawater), anhydrite is considered to have formed by mixing of preheated seawater with a hydrothermal solution of Sr/Ca (mM/M) = ca. 0.59–1.36 under the condition in which the partition coefficient (Kd) ranges between ca. 0.5 and 0.7. This results in the formation of anhydrite with higher Sr content with an Sr isotopic value close to that of seawater under seawater-dominant conditions. Larger crystals of type II anhydrite are partly replaced by smaller ones, indicating that anhydrite dissolution and recrystallization occurred after or during the formation of sekko ore. Gypsum, which partially replaces anhydrite in the Kuroko deposits, also exhibits two distinct chondrite-normalized REE patterns. Because LREEs are likely to be more readily mobilized during dissolution and recrystallization, it is hypothesized that LREEs are leached from type I anhydrite, resulting in the formation of type II anhydrite with LREE-depleted profiles.  相似文献   

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