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1.
Microthermometric measurements were obtained for 618 fluid inclusions in hydrothermal quartz, fluorite and calcite and magmatic quartz phenocrysts in intracaldera tuffs from the VC-2A core hole in order to study evolutionary processes of the Sulphur Springs hydrothermal system in the Valles caldera. Relatively high Th values in samples from shallow depths indicate erosion of about 200 m of caldera fill since deposition of hydrothermal minerals at shallow depths in the Sulphur Springs hydrothermal system, accompanied by a descent in the water table of the liquid-dominated reservoir. For samples collected below the current water level of the well, the minimum values of homogenization temperature (Th) fit the present thermal profile, whereas minimum Th values of samples from above the water level are several tens of degrees higher than the present thermal profile and fit a paleo-thermal profile following the boiling point curve for pure water, as adjusted to 92 °C at 20 m below the present land surface. This is attributed to development of an evolving vapor zone that formed subsequent to a sudden drop in the water table of the liquid-dominated reservoir. We suggest that these events were caused by the drainage of an intracaldera lake when the southwestern wall of the caldera was breached about 0.5 Ma. This model indicates that vapor zones above major liquid-dominated geothermal reservoirs can be formed due to dramatic changes in geohydrology and not just from simple boiling.  相似文献   

2.
The Bannaya–Karymshina area is situated in southern Kamchatka west of the East Kamchatka Volcanic Belt in the backarc part of the Kuril–Kamchatka island arc. The area is unique in that it contains abundant ejecta of calc-alkaline, acid, mostly ignimbrite, volcanism for a period of 4 Ma. Three rock complexes can be identified with rhyolitic and rhyodacitic compositions: Middle Pliocene ignimbrites, crystalloclastic tuffs of Eopleistocene age that fill in the Karymshina caldera, and Early Pleistocene intrusions. All of these are composed of rocks with normal total alkalinity, while the concentration of potassium places them at the boundary between moderate and high-potassium rocks. We sought to determine the composition of primary acid melts by studying the composition of the silicate phase in homogeneous melt inclusions that were conserved in quartz phenocrysts hosted by volcanic rocks of varying ages. Practically all the melt inclusions we analyzed show increased total alkalies and are in the class of trachyrhyodacites and trachyrhyolites, with the varieties of the highest alkali content being alkaline rhyolites and comendites; the concentration of K2O classifies them as subalkaline rocks; one also notes the increased alumina of the acid melts. The compositions and spatial locations of the melt inclusions in quartz phenocrysts provide evidence of a three-phase crystallization in magma chambers at different depths. According to the experimental data, the quartz phenocrysts crystallized in a water-saturated melt at pressures of 0.1 to 3.5 kbars.  相似文献   

3.
Peralkaline silicic welded ash-flow tuffs differ characteristically in a number of properties from most calc-alkaline welded tuffs, due to their generally lower viscosity and higher temperatures. For example, individual cooling units are relatively small (less than 30 m thick, less than 5 km3 in volume); rocks can be thoroughly welded and crystallized to feldspar, quartz, and mafic minerals; several primary deformational structures (e.g. lineations, stretching of pumice, folds, ramp structures) indicate late stage laminar creep, resulting from the low yield strength of the nearly homogeneous glass of very low viscosity. Theoretical considerations also suggest that peralkaline melts are of low viscosity and high temperature, as inferred from,e.g., their chemical composition (high iron- and alkali-, and low alumina-concentrations). The low viscosity may also be due to trapping of volatiles. Absence or paucity of OH-bearing phenocryst phases, paucity of pyroclastic rocks, other than ash flow tuffs, formed from highly explosive eruptions, and apparently high crystallization temperatures, indicate that peralkaline silicic magmas are comparatively dry. The common occurrence of peralkaline ash-flow tuffs may be due to an increased water content of the magmas, resulting also in amphibole phenocrysts in some welded tuffs, or to specific volcanotectonic conditions. Ash flows of peralkaline composition move as particularly dense particulate flows. This type of flowage and the very rapid welding of the low viscosity glass lead to a high degree of homogenization of the fine glass shards. This in turn inhibits complete degassing of the collapsing ash flow. Semiclosed systems result where gas overpressures can develop and where volatiles play an important role by fluxing crystallization and transporting dissolved matter. Several types of vesicles can form under these conditions: (a) Spherical vesicles within collapsed ash and pumice particles formed after deposition of the ash flow. (b) Round or irregular vesicles transsecting pyroclastic particles, vesicle sheets, and large cavities, several m in diameter, may form in a largely homogenized ash-flow tuff beneath tightly welded layers. (c) Lensoid cavities formed during granophyric crystallization of large pumice particles. Small ash particles of peralkaline composition may assume spherical shapes due to their low viscosity and in some cases, expansion of bubbles. They form during transport and are preserved under low load pressure in the top part of cooling units. Globule lavas and most froth flows are interpreted as welded ash-flow tuffs, some of their unusual features being due to their peralkaline composition.  相似文献   

4.
We describe the mineralogy, geochemistry, and mesomicrostructure of fresh subvolcanic blocks erupted during the 5 April 2003 paroxysm of Stromboli (Aeolian Islands, Italy). These blocks represent ∼50 vol.% of the total erupted ejecta and consist of fine- to medium-grained basaltic lithotypes ranging from relatively homogeneous dolerites to strongly or poorly welded magmatic breccias. The breccia components are represented by angular fragments of dolerites entrapped in a matrix of vesiculated (lava-like to scoriae) crystal-rich (CR) basalt. All of the studied blocks are cognates with the CR basalt of the normal Strombolian activity or lavas and they are often coated by a few-centimeter thick layer of crystal-poor (CP) basaltic pumice erupted during the paroxysm. We suggest that they result from the rapid increase of pressure and related subvolcanic rock failure that occurred shortly before the 5 April 2003 explosion, when the uppermost portion of the edifice inflated and suffered brecciation as the result of the sudden rise of the gas-rich CP basalt that triggered the eruption. Dolerites and magmatic matrix of the breccias show major and trace element compositions that match those of the CR basalts erupted during normal Strombolian activity and effusive events at Stromboli volcano. Dolerites consist of (a) phenocrysts normally found in the CR basalts and (b) late-stage magmatic minerals such as sanidine, An60-28 plagioclase, Fe–Mn-rich olivines (Fo68-48), phlogopite, apatite, and opaque mineral pairs (magnetite and ilmenite), most of which are never found both in lava flows and scoriae erupted during the persistent explosive activity that characterizes typical Strombolian behavior. Subvolcanic crystallization of the Stromboli CR magma, leading to slowly cooled equivalents of basalts, could result from transient drainage of the magma from the summit craters to lower levels. Fingering and engulfing of the material that collapsed from the summit crater floor into the shallow basaltic system during the late evening of 28 December 2002 coupled with the short break in the summit persistent explosions between December 2002 and March 2003 permitted the CR magma pockets to solidify as dolerites, which were confined to the uppermost portion of the system and thus not involved in the ongoing flank effusive activity. Crystal size distribution of the basaltic blocks and crystallization of the finer-grained (<0.1 mm) mafic minerals of the dolerites over a time interval of ∼100 days closely agrees with the above interpretation. Vesicle filling (miarolitic cavities) locally found in some dolerites, with minerals deposited as vapor-phase crystallization is a result of continuous gas percolation through the rocks of the uppermost portion of the volcanic system. Poorly welded magmatic breccias formed during syn-eruptive processes of 5 April 2003, when the paroxysm strongly shattered the shallow subvolcanic system and many dolerite fragments were entrapped in the CR magma. In contrast, the high degree of welding between the dolerite clasts and the CR basaltic matrix in the strongly welded magmatic breccias provides a snapshot of subvolcanic intrusions of the CR basalt into the dolerite when, after a 2-month break in activity, CR magmas started to rise again to the summit craters. Blocks similar to these subvolcanic ejecta of 5 April 2003 were also erupted during previous paroxysms (e.g., 1930) suggesting that changes in the usual Strombolian activity (e.g., short breaks in the persistent mild explosions and/or flank effusive activity) lead to transient crystallization of dolerites in the shallow plumbing system.  相似文献   

5.
Continental Scientific Drilling Program (CSDP) drill hole VC-2B [total depth 1761.7 m (5780 ft); maximum temperature 295 °C] was continuously cored through the Sulphur Springs hydrothermal system in the western ring-fracture zone of the 1.14 Ma Valles caldera. Among other units, the hole penetrated 760.2 m (2494.1 ft) of Paleozoic carbonate and siliciclastic strata underlying caldera fill and precaldera volcanic and epiclastic rocks. Comparison of the VC-2B Paleozoic rocks with corresponding lithologies within and around the 32.1 Ma Socorro caldera, 192 km ( 119 miles) to the south-southwest, provides insight into the variability of alteration responses to similar caldera-related hydrothermal regimes.The Pennsylvanian Madera Limestone and Sandia Formation from VC-2B preserve many of the sedimentological and diagenetic features observed in these units on a regional basis and where unaffected by high temperatures or hydrothermal activity. Micrites in these formations in VC-2B are generally altered and mineralized only where fractured or brecciated, that is, where hydrothermal solutions could invade carbonate rocks which were otherwise essentially impermeable. Alteration intensity (and correspondingly inferred paleopermeability) is only slightly higher in carbonate packstones and grainstones, low to intermediate in siltstones and claystones, and high in poorly cemented sandstones. Hydrothermal fracture-filling phases in these rocks comprise sericite (and phengite), chlorite, allanite, apatite, an unidentified zeolite and sphene in various combinations, locally with sphalerite, galena, pyrite and chalcopyrite. Terrigenous feldspars and clays are commonly altered to chlorite and seriate, and euhedral anhydrite “porphyroblasts” with minor chlorite occur in Sandia Formation siltstone. Fossils are typically unaltered, but the walls of some colonial bryozoans in the Madera Limestone are altered to the assemblage chlorite-sericite-epidote-allanite. La, Ce and Nd are present in an unidentified hydrothermal mineral occurring throughout much of the VC-2B Pennsylvanian sequence.Carboniferous carbonate and siliciclastic formations within and around the Socorro caldera show a similar style of alteration and mineralization to their Valles caldera counterparts, but by contrast locally host commercial, caldera-related, base-metal sulfide deposits. As in the Valles rocks, mineralization and alteration in those of the Socorro caldera were strongly controlled by porosity. Unless disrupted by fractures, breccias, or karst cavities ( not identified in Valles caldera drill holes), the rocks remained relatively unaltered. Where these features allowed ingress of mineralizing hydrothermal solutions, base-metal sulfides and rare-earth-element-bearing minerals were precipitated.  相似文献   

6.
Along the south coast of Arabia, between Aden and the southern entrance to the Red Sea, there are six central vent volcanoes of probable Pliocene age. All are characterised by the interstratification of basic and acidic extrusives, the formation of large central calderas at a late stage in the volcanic cycle and the subsequent infilling of these calderas with horizontal acidic ignimbrites and basic lavas. Lying 60 miles to the west of Aden and of particular interest is Jebel Khariz, the largest and best preserved of the six volcanic centres, covering a roughly circular area of about 100 square miles and rising to a height of 2,766 feet. The volcanic sequence of Jebel Khariz is broadly divisible into two suites: a) alkali-rich rhyolites and trachytes which occur as flows and pyroclastic horizons and form about 80 per cent of the volume of the cone, and b) effusives of basaltic composition that occur in the caldera, locally on the south-east and south-west flanks and in a small parasitic cone on the northern flank. The alkali-rich acidic suite includes lavas, ash-flow and ash-fall rocks as well as vent and flow breccias, Generally, all rocks of this suite have phenocrysts of anorthoclase, and may contain phenocrysts of fayalitic olivine, aegirine-augite, magnetite and/or quartz. The fine grained matrix is composed of the same minerals with skeletal riebeckite and, in some cases, cossyrite. The basaltic suite is characteristically porphyritic, the phenocrysts being of calcic plagioclase, clinopyroxene, olivine and magnetite in a fine-grained mesostasis of plagioclase, olivine, clinopyroxene and ore. The plagioclase, on initial investigation, appears to lie in the labradorite-bytownite range, the olivine is commonly replaced by iddingsite and the clinopyroxene is most commonly a pale mauve titanaugite. Near the centre of the volcanic pile, as exposed in the caldera wall, masses of rhyolitic composition can be seen to form over half of the volcanic sequence. These masses are markedly lenzoid in cross-section normal to the flow direction and display intricate flow folding; they are considered to have been extruded as viscous lava. Further from the volcanic centre, these acidic extrusives become less markedly lenzoid until in the distal areas of individual units, some 5 miles from the caldera, they have spread out to form sheet-like masses covering as much as 10 square miles to a uniform thickness rarely exceeding 25 feet. The presence of agglomeratic bases, hard compact central sections and less compact upper divisions, together with the ubiquitous presence of columnar jointing and occasional shard textures suggest that these distal parts of each extrusive unit have been formed by an ash-flow/ash-fall mechanism. It is postulated that the majority of the Jebel Khariz volcanic pile was formed by emission of acidic material, effusive in the central area, but deposited mainly by an ash-flow mechanism around the flanks of the cone. This could be due to either the synchronous eruption of viscous lava from the central vent with ash flow eruptions on the flanks; or, more probably, to the progression of an individual volcanic episode through an initial ash-flow phase followed by the effusion of viscous lava, all emanating from the central vent.  相似文献   

7.
Leveling surveys in 1923, 1976, and each year from 1983 to 1993 have shown that the east-central part of the Yellowstone caldera, near the base of the Sour Creek resurgent dome, rose at an average rate of 14±1 mm/year from 1923 to 1976 and 22±1 mm/year from 1976 to 1984. In contrast, no detectable movement occurred in the same area from 1984 to 1985 (-2±5 mm/year), and from 1985 to 1993 the area subsided at an average rate of 19±1 mm/year. We conclude that uplift from 1923 to 1984 was caused by: (1) pressurization of the deep hydrothermal system by fluids released from a crystallizing body of rhyolite magma beneath the caldera, then trapped beneath a self-sealed zone near the base of the hydrothermal system; and (2) aseismic intrusions of magma into the lower part of the sub-caldera magma body. Subsidence since 1985 is attributed to: (1) depressurization and fluid loss from the deep hydrothermal system, and (2) sagging of the caldera floor in response to regional crustal extension. Future intrusions might trigger renewed eruptive activity at Yellowstone, but most intrusions at large silicic calderas seem to be accommodated without eruptions. Overpressurization of the deep hydrothermal system could conceivably result in a phreatic or phreatomagmatic eruption, but this hazard is mitigated by episodic rupturing of the self-sealed zone during shallow earthquake swarms. Historical ground movements, although rapid by most geologic standards, seem to be typical of inter-eruption periods at large, mature, silicic magma systems like Yellowstone. The greatest short-term hazards posed by continuing unrest in the Yellowstone region are: (1) moderate to large earthquakes (magnitude 5.5–7.5), with a recurrence interval of a few decdes; and (2) small hydrothermal explosions, most of which affect only a small area (<0.01 km2), with a recurrence interval of a few years.  相似文献   

8.
In this study, the spatio-temporal evolution of Yellowstone deformation between 1992 and 2009 is monitored using interferometric synthetic aperture radar (InSAR) data acquired by the European Remote-Sensing Satellites (ERS-1 and ERS-2) and the Environmental Satellite (ENVISAT). These data are combined with continuous global positioning system (GPS) measurements to identify four discrete episodes of caldera subsidence and uplift, these episodes are: 1992–1995 (subsidence of 2.7 cm/year), 1996–2000 (subsidence of 0.5 cm/year, with local uplift of 1.7 cm/year at Norris), 2000–2004 (subsidence of 0.7 cm/year, with local uplift of 0.6 cm/year at Norris), and 2004–2009 (uplift of 3–8 cm/year, with local subsidence of 1–4 cm/year at Norris). We construct the full three-dimensional velocity field of Yellowstone deformation for 2005–2006 from ascending and descending ENVISAT orbits. The InSAR three-dimensional velocity field and three-component GPS measurements indicate that the majority of the observed deformation (3–8 cm/year) across the Yellowstone caldera and near Norris Geyser Basin (NGB) occurred in the vertical direction between the summers of 2005 and 2006. During this time, significant lateral displacements of 3–7 cm/year also occurred in the east–west direction at the southeastern and western rims of the Yellowstone caldera and in the area between Hebgen Lake and NGB. Minor north–south displacements of about 0.2 cm/year also occurred, however, in the southwestern section of the caldera and near Yellowstone Lake during the same period. The calculated three-dimensional velocity field for 2005–2006 implies the existence of two pressure-point sources, beneath the two structural resurgent domes in the Yellowstone caldera, connected by a planar conduit, rather than a single, large sill as proposed in previous studies. Furthermore, no measurable displacements occurred along any fault zone across the caldera during the entire period of observation (1992–2009). Therefore, we infer that magmatic and hydrothermal processes beneath the Yellowstone caldera and NGB were the main sources of deformation.  相似文献   

9.
Following a period of net uplift at an average rate of 15±1 mm/year from 1923 to 1984, the east-central floor of Yellowstone Caldera stopped rising during 1984–1985 and then subsided 25±7 mm during 1985–1986 and an additional 35±7 mm during 1986–1987. The average horizontal strain rates in the northeast part of the caldera for the period from 1984 to 1987 were: 1 = 0.10 ± 0.09 strain/year oriented N33° E±9° and 2 = 0.20 ± 0.09 strain/year oriented N57° W±9° (extension reckoned positive). A best-fit elastic model of the 1985–1987 vertical and horizontal displacements in the eastern part of the caldera suggests deflation of a horizontal tabular body located 10±5 km beneath Le Hardys Rapids, i.e., within a deep hydrothermal system or within an underlying body of partly molten rhyolite. Two end-member models each explain most aspects of historical unrest at Yellowstone, including the recent reversal from uplift to subsidence. Both involve crystallization of an amount of rhyolitic magma that is compatible with the thermal energy requirements of Yellowstone's vigorous hydrothermal system. In the first model, injection of basalt near the base of the rhyolitic system is the primary cause of uplift. Higher in the magmatic system, rhyolite crystallizes and releases all of its magmatic volatiles into the shallow hydrothermal system. Uplift stops and subsidence starts whenever the supply rate of basalt is less than the subsidence rate produced by crystallization of rhyolite and associated fluid loss. In the second model, uplift is caused primarily by pressurization of the deep hydrothermal system by magmatic gas and brine that are released during crystallization of rhyolite and them trapped at lithostatic pressure beneath an impermeable self-sealed zone. Subsidence occurs during episodic hydrofracturing and injection of pore fluid from the deep lithostatic-pressure zone into a shallow hydrostatic-pressure zone. Heat input from basaltic intrusions is required to maintain Yellowstone's silicic magmatic system and shallow hydrothermal system over time scales longer than about 105 years, but for the historical time period crystallization of rhyolite can account for most aspects of unrest at Yellowstone, including seismicity, uplift, subsidence, and hydrothermal activity.  相似文献   

10.
Thirteen pumice samples from the D and E ignimbrite units of Kalymnos Tuff have been analyzed for their biotite and feldspar phenocryst mineral chemistry and for bulk major and 20 trace, including 14 Rare Earth elements, to define and compare their petrochemistry with the Kos Plateau Tuff (KPT). For the same purpose major element analyses were obtained from Kalymnos Tuff and KPT glasses. Both KPT and Kalymnos pumice lapilli are rhyolites characterized by a well-developed ‘silky’ texture and roundish quartz. Phenocrysts of biotite and feldspars (sanidine, oligoclase) from both tuffs display compositional overlap. Crystals are charac-terized by undulatory extinction (quartz), fractures (sanidine, oligoclase) and bent cleavages (biotite) due to the explosive origin of their host. Both tuffs show well-defined petrogenetic trends and extensive compositional overlaps on major and trace element variation diagrams suggesting that they are consanguineous. However, D ignimbrite samples are more evolved than those obtained from E ignimbrite as indicated from major elements, alkali earths (Ba, Rb, Sr), immobile (Zr, Y), compatible (V) and hygromagmatophile trace element (Th) distributions. This evidence indicates a stratified magma chamber under a ～16 Km caldera superstructure which is mostly submarine.  相似文献   

11.
The Tertiary Taylor Creek Rhyolite of southwest New Mexico comprises at least 20 lava domes and flows. Each of the lavas was erupted from its own vent, and the vents are distributed throughout a 20 km by 50 km area. The volume of the rhyolite and genetically associated pyroclastic deposits is at least 100 km3 (denserock equivalent). The rhyolite contains 15%–35% quartz, sanidine, plagioclase, ±biotite, ±hornblende phenocrysts. Quartz and sanidine account for about 98% of the phenocrysts and are present in roughly equal amounts. With rare exceptions, the groundmass consists of intergrowths of fine-grained silica and alkali feldspar. Whole-rock major-element composition varies little, and the rhyolite is metaluminous to weakly peraluminous; mean SiO2 content is about 77.5±0.3%. Similarly, major-element compositions of the two feldsparphenocryst species also are nearly constant. However, whole-rock concentrations of some trace-elements vary as much as several hundred percent. Initial radiometric age determinations, all K–Ar and fission track, suggest that the rhyolite lava field grew during a period of at least 2 m.y. Subsequent 40Ar/39Ar ages indicate that the period of growth was no more than 100 000 years. The time-space-composition relations thus suggest that the Taylor Creek Rhyolite was erupted from a single magma reservoir whose average width was at least 30 km, comparable in size to several penecontemporaneous nearby calderas. However, this rhyolite apparently is not related to a caldera structure. Possibly, the Taylor Creek Phyolite magma body never became sufficiently volatile rich to produce a large-volume pyroclastic eruption and associated caldera collapse, but instead leaked repeatedly to feed many relatively small domes and flows.The new 40Ar/39Ar ages do not resolve preexisting unknown relative-age relations among the domes and flows of the lava field. Nonetheless, the indicated geologically brief period during which Taylor Creek Rhyolite magma was erupted imposes useful constraints for future evaluation of possible models for petrogenesis and the origin of trace-element characteristics of the system.  相似文献   

12.
Silica oversaturated lavas and pyroclastic flows, 9 to 7,5 M.Y. old, have been emplaced during the sinking of the central volcanotectonic caldera of alkalic stratovolcano Cantal. They can be grouped in a non linear fractional crystallisation series ranging from mugearites to rhyolitic trachytes, comenditic trachytes and comendites through benmoreites. Their evolution results mainly from plagioclase fractionation, alkali feldspar and ferromagnesian minerals playing only a restricted role. We consider this oversaturated group, which follows primordial basanitic lavas in the history of the stratovolcano, as the most evolved liquids resulting from differentiation under high water pressures and oxygen fugacities of alkali basic magmas in a great magma chamber. The less evolved liquids (intermediate and basic) would have been emplaced later, building the greatest part of the volcanic pile.  相似文献   

13.
Experimental determinations of the dry liquidus temperatures of two pantellerite, and two pantelleritic trachyte glasses in the pressure range 0–2 kilobars, show minima in the liquidus curves between 0.1 and 0.2 kb. The pantellerite minima are 830°–850° C; the trachyte minima are 920°–940° C. At pressures below the minima a separate vapour phase co-exists with liquid, at higher pressures the intrinsic volatiles are completely soluble in the liquid and the liquidus curves have a positivedT/dP. Similar results have been obtained from a range of other pantelleritic glasses, and together with consistent alkali feldspar compositions (from a wide range of experimental conditions) are indicative of a close approach to equilibrium. The form of the liquidus curves above the minima, if rellecting natural conditions, offers a ready explanation of the near-or super-liquidus aspect of many peralkaline lavas. The temperatures in these anhydrous experiments are 100°–150° C higher than those for similar compositions in the presence of excess water. (Also, in the presence of excess water, the crystallization sequences in the natural glasses are profoundly modified, with pyroxene appearing on the liquidus). At lower pressures, feldspar is the liquidus phase in the dry pantellerites, but is joined by quartz around 1 kb, and superseded by quartz at higher pressures. As pantellerites with quartz phenocrysts are uncommon, low pressure equilibration is perhaps normal in these magmas. Feidspar is the usual liquidus phase in the trachytes, except at very low pressures where it is preceded by iron oxide. Preliminary studies at 5 kb indicate that the pantelleritic and trachytic liquidus curves are converging (in the range 950°–1000° C). Crystallization sequences, and the forms and positions of the solidus curves are therefore of vital importance. These, together with the vapour-present/vapour-absent conditions, are currently under investigation.  相似文献   

14.
Gabbro breccias were recovered from an anomalously shallow level of the ocean crust during DSDP Leg 82. The rocks display evidence of metamorphic crystallization related either to localized deformation or to hydrothermal circulation of a seawater-derived fluid under static conditions. Secondary phases consist of plagioclase, amphibole and minor clinopyroxene, ilmenite, sphene and chlorite. Petrological study indicates that deformation took place at high temperature, under anhydrous conditions, and was followed by hydrothermal circulation. The compositions of secondary minerals (i.e. strong zonations, presence of chlorine in amphiboles, varying compositions of secondary plagioclase) indicate that reactions of the gabbros with the fluids occurred at a low water/rock ratio. Relations between Cl, Na and K in amphiboles suggest penetration of at least two distinct fluids of different compositions. Metamorphic crystallization stopped when greenschist facies conditions were reached( 350°C), probably because hydrothermal circulation faded out.  相似文献   

15.
The Shapinggou porphyry molybdenum(Mo) deposit, located in Jinzhai County, Anhui Province, China, is the largest in the Qinling-Dabie Mo Metallogenic Belt. The intrusive rocks in the Shapinggou Mo ore district formed in the Yanshanian can be divided into two stages based on zircon U-Pb dating and geochemical features. This study focuses on the late stage intrusions(quartz syenite and granite porphyry), which are closely genetically related to molybdenum mineralization. Petrographic observations identified two quartz polymorphs in the quartz syenite and granite porphyry, which were derived from the same magmatic sources and similar evolutionary processes. The quartzes were identified as a xenomorphic β-quartz within quartz syenite, while the quartz phenocrysts within the granite porphyry were pseudomorphous b-quartz, characterized by a hexagonal bipyramid crystallography. The pseudomorphous b-quartz phenocrysts within the granite porphyry were altered from b-quartz through phase transformation. These crystals retained b-quartz pseudomorph. Combined with titanium-inzircon thermometry, quartz phase diagrams, and granitic Q-Ab-Or-H_2O phase diagrams, it is suggested that the quartz syenite and granite porphyry were formed under similar magmatic origins, including similar depths and magmatic crystallization temperatures. However, the β-quartz within quartz syenite indicated that the crystallization pressure was greater than 0.7 GPa, while the original b-quartz within the granite porphyry was formed under pressures between 0.4 and 0.7 GPa. The groundmass of the granite porphyry which formed after the phenocryst indicated a crystallizing pressure below 0.05 GPa. This indicates that the granite porphyry was formed under repetitive and rapid decompression. The decompression was significant as it caused the exsolution of the ore-forming fluids, and boiling and material precipitation during the magmatic-fluid process. The volumetric difference during the phase transformation from b-quartz to β-quartz caused extensive fracturing on the granite porphyry body and the wall rocks. As the main ore-transmitting and ore-depositing structures, these fractures benefit the hydrothermal alteration and stockwork-disseminated mineralization of the porphyry deposit. It is considered that the pseudomorphous β-quartz phenocrysts of the porphyritic body are metallogenic indicators within the porphyry deposits. The pseudomorphous β-quartzes therefore provide evidence for the formation of the porphyry deposit within a decompression tectonic setting.  相似文献   

16.
In this paper we study the variation of Vp/Vs and Poisson's ratio (δ) in the Yellowstone National Park region, using earthquakes which were well recorded by a local seismic network. We find that the average Vp/Vs value within the geothermally active Yellowstone caldera is about 7% lower than in the area outside the caldera. Within the caldera itself there may be a further 2–7% reduction of Vp/Vs in the hydrothermally active Norris Geyser Basin, the Upper and Lower Geyser Basins, and the Yellowstone Lake and Mud Volcano regions. After considering various possible causes for Vp/Vs changes, such as geologic and structural differences, thermal effects, partial melting, and hydrothermal activity, we conclude that the most plausible explanation for the observed Vp/Vs reduction is the presence of hot-water at temperatures and pore-pressures near the water steam transition in the caldera geothermal reservoirs.  相似文献   

17.
Using Fourier transform infrared spectroscopy (FTIR), we measured water contents of quartz and feldspar for four thin sections of felsic mylonite and two thin sections of banded granitic gneiss col- lected from a ductile shear zone of middle crust along the Red Rivers-Ailaoshan active fault. The ab- sorbance spectra and peak position suggest that water in quartz and feldspar of granitic gneiss and felsic mylonite occurs mainly as hydroxyl in crystal defect, but also contains inclusion water and grain boundary water. The water contents of minerals were calculated based on the absorbance spectra. Water content of feldspar in granitic gneiss is 0.05 wt%-0.15 wt%, and that of quartz 0.03 wt%-0.09 wt%. Water content of feldspar ribbon and quartz ribbon in felsic mylonite is 0.095 wt%-0.32 wt%, and those of fine-grained feldspar and quartz are 0.004 wt%-0.052 wt%. These data show that the water content of weakly deformed feldspar and quartz ribbons is much higher than that of strongly deformed fine-grained feldspar and quartz. This suggests that strong shear deformation leads to breakage of the structures of constitutional water, inclusion and grain boundary water in feldspar and quartz, and most of water in minerals of mylonite is released to the upper layer in the crust.  相似文献   

18.
The electron spin resonance (ESR) dating method was employed on quartz phenocrysts separated from pumice of the El Cajete and Battleship Rock Members of the Valles Rhyolite in the Valles caldera, New Mexico. The results of heating experiments indicate that Ti impurity centers have two components; a thermally stable one and a less stable, temperature sensitive one. ESR dates using the stable Ti center yield eruption ages of 59 ± 6 ka for the Battleship Rock Member and 53 ± 6 ka for the El Cajete Member while recent 14C dates (S. Reneau and J. Gardner, unpub. data) from carbonized logs in the El Cajete pumice indicate that its age is older than 50 ka. Our results indicate that volcanism in the Valles caldera is much younger than previously thought (≥ 130 ka) and that recent revisions to the post-0.5 Ma stratigraphy of Valles caldera are probably in error. The results suggest that ESR dating of quartz may be a useful method for obtaining ages of units in other Quaternary volcanic areas.  相似文献   

19.
The Moshirabad pluton is located southwest of the Sanandaj–Sirjan Metamorphic Belt, Qorveh, western Iran. The pluton is composed of diorite, monzodiorite, quartz diorite, quartz monzodiorite, tonalite, granodiorite, granite, aplite, and pegmatite. In this study 31 samples from various rocks were chosen for whole‐rock analyses and 15 samples from different lithologies were chosen for mineral chemical studies. The compositions of minerals are used to describe the nature of magma and estimate the pressure and temperature at which the Moshirabad pluton was emplaced. Feldspar compositions are near the binary systems in which plagioclase compositions range from An5 to An53 and alkali‐feldspar compositions range from Or91 to Or97. Mafic minerals in the plutonic rocks are biotite and hornblende. Based on the composition of biotites and whole‐rock chemistry, the Moshirabad pluton formed from a calc‐alkaline magma. Amphiboles are calcic amphiboles (magnesio‐hornblende or edenite). Temperatures of crystallization, calculated with the hornblende–plagioclase thermometer, range 550–750°C. These temperatures indicate that plutonic rocks have undergone some retrogressive changes in their mineral compositions. Aluminum‐in‐hornblende geobarometry indicates that the Moshirabad pluton was emplaced at pressures of 2.3–6.0 kbar, equal to depths of 7–20 km, but with consideration of regional geology, lower pressures than the above pressure range are more probable. Alteration of amphiboles can be the reason for some overestimation of pressures.  相似文献   

20.
Quartz is a preferred mineral which is widely used for optically stimulated luminescence (OSL) and cosmogenic radionuclide (CRN) dating methods. Any contamination in the sample may mislead and result in erroneous results for both the dating methods (e.g. OSL or CRN). Therefore it is essential to get pure quartz before the measurements of OSL and CRN. Presence of other minerals can introduce unaccounted luminescence signal in the case of OSL, similarly in the case of CRN unaccounted concentration of 10Be and 26Al may be introduced. Therefore, in order to get reliable ages from CRN and OSL, extraction of pure quartz from the sediment becomes necessary. Protocols have been developed to extract pure quartz from the sediment, e.g., the separation of quartz from feldspar and other heavy minerals can be achieved by applying 2-step density separation. This is followed by HF leaching which usually removes the feldspar contamination from the quartz (if any left). However, in some cases, this method is not successful, especially in the case of feldspar rich samples or in the samples with intergrowth of feldspar in quartz crystals. This paper reports a method that is effective in separating quartz and feldspar. A small amount of fine grained iron powder was used to make feldspar as magnetic mineral and it is separated from quartz using isodynamic magnetic separator effectively. Efficacy of the method was tested with different analytical instruments such as scanning electron microscope (SEM), OSL/TL reader and inductively coupled plasma mass spectromete (ICP-MS). The analytical tests showed that the proposed method eliminates feldspar by ~95%.  相似文献   

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