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1.
Darrell F. Strobel 《Icarus》2010,208(2):878-886
The third most abundant species in Titan’s atmosphere is molecular hydrogen with a tropospheric/lower stratospheric mole fraction of 0.001 derived from Voyager and Cassini infrared measurements. The globally averaged thermospheric H2 mole fraction profile from the Cassini Ion Neutral Mass Spectrometer (INMS) measurements implies a small positive gradient in the H2 mixing ratio from the tropopause region to the lower thermosphere (∼950-1000 km), which drives a downward H2 flux into Titan’s surface comparable to the H2 escape flux out of the atmosphere (∼2 × 1010 cm−2 s−1 referenced to the surface) and requires larger photochemical production rates of H2 than obtained by previous photochemical models. From detailed model calculations based on known photochemistry with eddy, molecular, and thermal diffusion, the tropospheric and thermospheric H2 mole fractions are incompatible by a factor of ∼2. The measurements imply that the downward H2 surface flux is in substantial excess of the speculative threshold value for methanogenic life consumption of H2 (McKay, C.P., Smith, H.D. [2005], Icarus 178, 274-276. doi:10.1016/j.icarus.2005.05.018), but without the extreme reduction in the surface H2 mixing ratio.  相似文献   

2.
To constrain the properties of Oval BA before and after it reddened, we use Hubble methane band images from 1994 to 2009 to find that the distribution of upper tropospheric haze atop the oval and its progenitors remained unchanged, with reflectivity variations of less than 10% over this time span. We quantify measurement uncertainties and short-term fluctuations in velocity fields extracted from Cassini and Hubble data, and show that there were no significant changes in the horizontal velocity field of Oval BA in 2000, 2006, and 2009. Based on models of the oval’s dynamics, the static stability of the oval’s surroundings was also unchanged.The vertical extent of the oval did not change, based on the unchanged haze reflectivity and unchanged stratification. Published vortex models require Brunt-Väisälä frequencies of about 0.08 s−1 at the base of the vortex, and we combine this value with a review of prior constraints on the vertically variable static stability in Jupiter’s troposphere to show that the vortex must extend down to the condensation level of water in supersolar abundance.The only observable change was an increase in short-wavelength optical absorption that appeared not at the core of the oval, but in a red annulus. The secondary circulation in the vortex keeps this red annulus warmer than the vortex core. Although the underlying cause of the color change cannot be proven, we explore the idea that the new chromophores in the red annulus may be related to a global or hemispheric temperature change.  相似文献   

3.
We obtained longitudinally resolved thermal infrared spectra (8-13 μm and 17-25 μm) of Jupiter’s impact debris at the Gemini South Telescope on July 24, 2009; five days after the July 19th collision. These were used to study the mechanisms responsible for the redistribution of thermal energy and material (ammonia and stratospheric particulates) following the impact. Upwelling of (8.5 ± 4.1) × 1014 g of tropospheric air was sufficient to deposit (6.7 ± 4.1) × 1012 g of NH3 over a 6° longitude range above the impact core. The NH3 was distributed over the 20-80 mbar region with a peak abundance of 1.0 ± 0.6 ppm at 45 mbar. Only a 10th of this abundance was observed over the western ejecta, and it is unlikely that these observations were sensitive to NH3 entrained in the ballistic plume itself. The pattern of excess thermal energy was markedly different from that of Shoemaker-Levy 9 (SL9), with a localized tropospheric perturbation of 2.0 ± 1.0 K at 200-300 mbar and a broader stratospheric warming of up to 3.5 ± 2.0 K at 10-30 mbar. We find no evidence of residual warmth at p < 1 mbar five days after the impact. The excess thermal energy places lower limits on the total energy of the impact (1.8-15.7 × 1026 ergs), which limits the impactor diameter to 70-510 m (depending on the bulk density chosen for the material).The models of the Gemini spectra required three distinct aerosol features, indicative of the mineralogy of the dark particulate debris, centred at 9.1, 10.0 and 18.5 μm. The retrieved opacities for each of these features were distributed over a larger area (9-10° longitude) and at higher altitudes (above the 10-mbar level) than the stratospheric NH3, and they are more spatially inhomogeneous. This implies the particulates were either entrained with the rising hot plume or created upon plume re-entry and are subsequently redistributed by stratospheric winds. The three particulate features were consistent with a mixture of amorphous iron and magnesium-rich silicates and silicas in the debris field. A broad 10-μm signature was coincident with peaks expected from material rich in amorphous olivines (but poor in pyroxenes), and similar to silicate features observed during SL9. A narrow 9.1-μm signature was interpreted as a combination of amorphous and crystalline silica. Finally, a broad 18.5-μm emitter was not adequately reproduced by a mixture of simple olivines and pyroxenes and remains to be identified.  相似文献   

4.
Mid-infrared 7-20 μm imaging of Jupiter from ESO’s Very Large Telescope (VLT/VISIR) demonstrate that the increased albedo of Jupiter’s South Equatorial Belt (SEB) during the ‘fade’ (whitening) event of 2009-2010 was correlated with changes to atmospheric temperature and aerosol opacity. The opacity of the tropospheric condensation cloud deck at pressures less than 800 mbar increased by 80% between May 2008 and July 2010, making the SEB (7-17°S) as opaque in the thermal infrared as the adjacent equatorial zone. After the cessation of discrete convective activity within the SEB in May 2009, a cool band of high aerosol opacity (the SEB zone at 11-15°S) was observed separating the cloud-free northern and southern SEB components. The cooling of the SEBZ (with peak-to-peak contrasts of 1.0 ± 0.5 K), as well as the increased aerosol opacity at 4.8 and 8.6 μm, preceded the visible whitening of the belt by several months. A chain of five warm, cloud-free ‘brown barges’ (subsiding airmasses) were observed regularly in the SEB between June 2009 and June 2010, by which time they too had been obscured by the enhanced aerosol opacity of the SEB, although the underlying warm circulation was still present in July 2010. Upper tropospheric temperatures (150-300 mbar) remained largely unchanged during the fade, but the cool SEBZ formation was detected at deeper levels (p > 300 mbar) within the convectively-unstable region of the troposphere. The SEBZ formation caused the meridional temperature gradient of the SEB to decrease between 2008 and 2010, reducing the vertical thermal windshear on the zonal jets bounding the SEB. The southern SEB had fully faded by July 2010 and was characterised by short-wave undulations at 19-20°S. The northern SEB persisted as a narrow grey lane of cloud-free conditions throughout the fade process.The cool temperatures and enhanced aerosol opacity of the SEBZ after July 2009 are consistent with an upward flux of volatiles (e.g., ammonia-laden air) and enhanced condensation, obscuring the blue-absorbing chromophore and whitening the SEB by April 2010. These changes occurred within cloud decks in the convective troposphere, and not in the radiatively-controlled upper troposphere. NH3 ice coatings on aerosols at p < 800 mbar are plausible sources of the suppressed 4.8 and 8.6-μm emission, although differences in the spatial distribution of opacity at these two wavelengths suggest that enhanced attenuation by a deeper cloud (p > 800 mbar) also occurred during the fade. Revival of the dark SEB coloration in the coming months will ultimately require sublimation of these ices by subsidence and warming of volatile-depleted air.  相似文献   

5.
Mid- and far-infrared spectra from the Composite InfraRed Spectrometer (CIRS) have been used to determine volume mixing ratios of nitriles in Titan's atmosphere. HCN, HC3N, C2H2, and temperature were derived from 2.5 cm−1 spectral resolution mid-IR mapping sequences taken during three flybys, which provide almost complete global coverage of Titan for latitudes south of 60° N. Three 0.5 cm−1 spectral resolution far-IR observations were used to retrieve C2N2 and act as a check on the mid-IR results for HCN. Contribution functions peak at around 0.5-5 mbar for temperature and 0.1-10 mbar for the chemical species, well into the stratosphere. The retrieved mixing ratios of HCN, HC3N, and C2N2 show a marked increase in abundance towards the north, whereas C2H2 remains relatively constant. Variations with longitude were much smaller and are consistent with high zonal wind speeds. For 90°-20° S the retrieved HCN abundance is fairly constant with a volume mixing ratio of around 1 × 10−7 at 3 mbar. More northerly latitudes indicate a steady increase, reaching around 4 × 10−7 at 60° N, where the data coverage stops. This variation is consistent with previous measurements and suggests subsidence over the northern (winter) pole at approximately 2 × 10−4 m s−1. HC3N displays a very sharp increase towards the north pole, where it has a mixing ratio of around 4 × 10−8 at 60° N at the 0.1-mbar level. The difference in gradient for the HCN and HC3N latitude variations can be explained by HC3N's much shorter photochemical lifetime, which prevents it from mixing with air at lower latitude. It is also consistent with a polar vortex which inhibits mixing of volatile rich air inside the vortex with that at lower latitudes. Only one observation was far enough north to detect significant amounts of C2N2, giving a value of around 9 × 10−10 at 50° N at the 3-mbar level.  相似文献   

6.
The latitudinal variation of Saturn’s tropospheric composition (NH3, PH3 and AsH3) and aerosol properties (cloud altitudes and opacities) are derived from Cassini/VIMS 4.6-5.1 μm thermal emission spectroscopy on the planet’s nightside (April 22, 2006). The gaseous and aerosol distributions are used to trace atmospheric circulation and chemistry within and below Saturn’s cloud decks (in the 1- to 4-bar region). Extensive testing of VIMS spectral models is used to assess and minimise the effects of degeneracies between retrieved variables and sensitivity to the choice of aerosol properties. Best fits indicate cloud opacity in two regimes: (a) a compact cloud deck centred in the 2.5-2.8 bar region, symmetric between the northern and southern hemispheres, with small-scale opacity variations responsible for numerous narrow light/dark axisymmetric lanes; and (b) a hemispherically asymmetric population of aerosols at pressures less than 1.4 bar (whose exact altitude and vertical structure is not constrained by nightside spectra) which is 1.5-2.0× more opaque in the summer hemisphere than in the north and shows an equatorial maximum between ±10° (planetocentric).Saturn’s NH3 spatial variability shows significant enhancement by vertical advection within ±5° of the equator and in axisymmetric bands at 23-25°S and 42-47°N. The latter is consistent with extratropical upwelling in a dark band on the poleward side of the prograde jet at 41°N (planetocentric). PH3 dominates the morphology of the VIMS spectrum, and high-altitude PH3 at p < 1.3 bar has an equatorial maximum and a mid-latitude asymmetry (elevated in the summer hemisphere), whereas deep PH3 is latitudinally-uniform with off-equatorial maxima near ±10°. The spatial distribution of AsH3 shows similar off-equatorial maxima at ±7° with a global abundance of 2-3 ppb. VIMS appears to be sensitive to both (i) an upper tropospheric circulation (sensed by NH3 and upper-tropospheric PH3 and hazes) and (ii) a lower tropospheric circulation (sensed by deep PH3, AsH3 and the lower cloud deck).  相似文献   

7.
We report on the detection of H2 as seen in our analysis of twilight observations of the lunar atmosphere observed by the LAMP instrument aboard NASA’s Lunar Reconnaissance Orbiter. Using a large amount of data collected on the lunar atmosphere between September 2009 and March 2013, we have detected and identified, the presence of H2 in the native lunar atmosphere, for the first time. We derive a surface density for H2 of 1.2 ± 0.4 × 103 cm−3 at 120 K. This is about 10 times smaller than originally predicted, and several times smaller than previous upper limits from the Apollo era data.  相似文献   

8.
The chromophores responsible for coloring the jovian atmosphere are embedded within Jupiter’s vertical aerosol structure. Sunlight propagates through this vertical distribution of aerosol particles, whose colors are defined by ?0(λ), and we remotely observe the culmination of the radiative transfer as I/F(λ). In this study, we employed a radiative transfer code to retrieve ?0(λ) for particles in Jupiter’s tropospheric haze at seven wavelengths in the near-UV and visible regimes. The data consisted of images of the 2008 passage of Oval BA to the south of the Great Red Spot obtained by the Wide Field Planetary Camera 2 on-board the Hubble Space Telescope. We present derived particle colors for locations that were selected from 14 weather regions, which spanned a large range of observed colors. All ?0(λ) curves were absorbing in the blue, and ?0(λ) increased monotonically to approximately unity as wavelength increased. We found accurate fits to all ?0(λ) curves using an empirically derived functional form: ?0(λ) = 1 − A exp(−Bλ). The best-fit parameters for the mean ?0(λ) curve were A = 25.4 and B = 0.0149 for λ in units of nm. We performed a principal component analysis (PCA) on our ?0(λ) results and found that one or two independent chromophores were sufficient to produce the variations in ?0(λ). A PCA of I/F(λ) for the same jovian locations resulted in principal components (PCs) with roughly the same variances as the ?0(λ) PCA, but they did not result in a one-to-one mapping of PC amplitudes between the ?0(λ) PCA and I/F(λ) PCA. We suggest that statistical analyses performed on I/F(λ) image cubes have limited applicability to the characterization of chromophores in the jovian atmosphere due to the sensitivity of I/F(λ) to horizontal variations in the vertical aerosol distribution.  相似文献   

9.
The Cassini Composite Infrared Spectrometer (CIRS) has been used to derive the vertical and meridional variation of temperature and phosphine (PH3) abundance in Saturn's upper troposphere. PH3 has a significant effect on the measured radiances in the thermal infrared and between May 2004 and September 2005 CIRS recorded thousands of spectra in both the far (10-600 cm−1) and mid (600-1400 cm−1) infrared, at a variety of latitudes covering the southern hemisphere. Low spectral resolution (15 cm−1) data has been used to constrain the temperature structure of the troposphere between 100 and 500 mbar. The vertical distributions of phosphine and ammonia were retrieved from far-infrared spectra at the highest spectral resolution (0.5 cm−1), and lower resolution (2.5 cm−1) mid-infrared data were used to map the meridional variation in the abundance of phosphine in the 250-500 mbar range. Temperature variations at the 250 mbar level are shown to occur on the same scale as the prograde and retrograde jets in Saturn's atmosphere [Porco, C.C., and 34 colleagues, 2005. Science 307, 1243-1247]. The PH3 abundance at 250 mbar is found to be enhanced at the equator when compared with mid-latitudes. At mid latitudes we see anti-correlation between temperature and PH3 abundance at 250 mbar, phosphine being enhanced at 45° S and depleted at 25 and 55° S. The vertical distribution is markedly different polewards of 60-65° S, with depleted PH3 at 500 mbar but a slower decline in abundance with altitude when compared with the mid-latitudes. This variation is similar to the variations of cloud and aerosol parameters observed in the visible and near infrared, and may indicate the subsidence of tropospheric air at polar latitudes, coupled with a diminished sunlight penetration depth reducing the rate of PH3 photolysis in the polar region.  相似文献   

10.
The vertical profile of H2SO4 vapor is calculated using current atmospheric and thermodynamic data. The atmospheric data include the H2O profiles observed at 70-112 km by the SOIR solar occultations, the SPICAV-UV profiles of the haze extinction at 220 nm, the VeRa temperature profiles, and a typical profile of eddy diffusion. The thermodynamic data are the saturated vapor pressures of H2O and H2SO4 and chemical potentials of these species in sulfuric acid solutions. The calculated concentration of sulfuric acid in the cloud droplets varies from 85% at 70 km to a minimum of 70% at 90 km and then gradually increasing to 90-100% at 110 km. The H2SO4 vapor mixing ratio is ∼10−12 at 70 and 110 km with a deep minimum of 3 × 10−18 at 88 km. The H2O-H2SO4 system matches the local thermodynamic equilibrium conditions up to 87 km. The column photolysis rate of H2SO4 is 1.6 × 105 cm−2 s−1 at 70 km and 23 cm−2 s−1 at 90 km. The calculated abundance of H2SO4 vapor at 90-110 km and its photolysis rate are smaller than those presented in the recent model by Zhang et al. (Zhang, X., Liang, M.C., Montmessin, F., Bertaux, J.L., Parkinson, C., Yung, Y.L. [2010]. Nat. Geosci. 3, 834-837) by factors of 106 and 109, respectively. Assumptions of 100% sulfuric acid, local thermodynamic equilibrium, too warm atmosphere, supersaturation of H2SO4 (impossible for a source of SOX), and cross sections for H2SO4·H2O (impossible above the pure H2SO4) are the main reasons of this huge difference. Significant differences and contradictions between the SPICAV-UV, SOIR, and ground-based submillimeter observations of SOX at 70-110 km are briefly discussed and some weaknesses are outlined. The possible source of high altitude SOX on Venus remains unclear and probably does not exist.  相似文献   

11.
We present results regarding the dynamical meteorology of Jupiter’s White Ovals at different points in their evolution. Starting from the era with three White Ovals FA, BC, and DE (Galileo), continuing to the post-merger epoch with only one Oval BA (Cassini), and finally to Oval BA’s current reddened state (New Horizons), we demonstrate that the dynamics of their flow have similarly evolved along with their appearance. In the Galileo epoch, Oval DE had an elliptical shape with peak zonal wind speeds of ∼90 m s−1 in both its northern and southern peripheries. During the post-merger epoch, Oval BA’s shape was more triangular and less elliptical than Oval DE; in addition to widening in the north-south direction, its northern periphery was 20 m s−1 slower, and its southern periphery was 20 m s−1 faster than Oval DE’s flow during the Galileo era. Finally, in the New Horizons era, the reddened Oval BA had evolved back to a classical elliptical form. The northern periphery of Oval BA increased in speed by 20 m s−1 from Cassini to New Horizons, ending up at a speed nearly identical to that of the northern periphery of Oval DE during Galileo. However, the peak speeds along the southern rim of the newly formed Oval BA were consistently faster than the corresponding speeds in Oval DE, and they increased still further between Cassini and New Horizons, ending up at ∼140-150 m s−1. Relative vorticity maps of Oval BA reveal a cyclonic ring surrounding its outer periphery, similar to the ring present around the Great Red Spot. The cyclonic ring around Oval BA in 2007 appears to be moderately stronger than observed in 1997 and 2001, suggesting that this may be associated with the coloration of the vortex. The modest strengthening of the winds in Oval BA, the appearance of red aerosols, and the appearance of a turbulent, cyclonic feature to Oval BA’s northwest create a strong resemblance with the Great Red Spot from both a dynamical and morphological perspective.In addition to the White Ovals, we also measure the winds within two compact cyclonic regions, one in the Galileo data set and one in the Cassini data set. In the images, these cyclonic features appear turbulent and filamentary, but our wind field reveals that the flow manifests as a coherent high-speed collar surrounding relatively quiescent interiors. Our relative vorticity maps show that the vorticity likewise concentrates in a collar near the outermost periphery, unlike the White Ovals which have peak relative vorticity magnitudes near the center of the vortex. The cyclones contain several localized bright regions consistent with the characteristics of thunderstorms identified in other studies. Although less studied than their anticyclonic cousins, these cyclones may offer crucial insights into the planet’s cloud-level energetics and dynamical meteorology.  相似文献   

12.
Five years of thermal infrared spectra from the Cassini Composite Infrared Spectrometer (CIRS) are analyzed to determine the response of Saturn’s atmosphere to seasonal changes in insolation. Hemispheric mapping sequences at 15.0 cm−1 spectral resolution are used to retrieve the variation in the zonal mean temperatures in the stratosphere (0.5-5.0 mbar) and upper troposphere (75-800 mbar) between October 2004 (shortly after the summer solstice in the southern hemisphere) and July 2009 (shortly before the autumnal equinox).Saturn’s northern mid-latitudes show signs of dramatic warming in the stratosphere (by 6-10 K) as they emerge from ring-shadow into springtime conditions, whereas southern mid-latitudes show evidence for cooling (4-6 K). The 40-K asymmetry in stratospheric temperatures between northern and southern hemispheres (at 1 mbar) slowly decreased during the timespan of the observations. Tropospheric temperatures also show temporal variations but with a smaller range, consistent with the increasing radiative time constant of the atmospheric response with increasing pressure. The tropospheric response to the insolation changes shows the largest magnitude at the locations of the broad retrograde jets. Saturn’s warm south-polar stratospheric hood has cooled over the course of the mission, but remains present.Stratospheric temperatures are compared to a radiative climate model which accounts for the spatial distribution of the stratospheric coolants. The model successfully predicts the magnitude and morphology of the observed changes at most latitudes. However, the model fails at locations where strong dynamical perturbations dominate the temporal changes in the thermal field, such as the hot polar vortices and the equatorial semi-annual oscillation (Orton, G., and 27 colleagues [2008]. Nature 453, 196-198). Furthermore, observed temperatures in Saturn’s ring-shadowed regions are larger than predicted by all radiative-climate models to date due to the incomplete characterization of the dynamical response to the shadow. Finally, far-infrared CIRS spectra are used to demonstrate variability of the para-hydrogen distribution over the 5-year span of the dataset, which may be related to observed changes in Saturn’s tropospheric haze in the spring hemisphere.  相似文献   

13.
We use a radiative-conductive model to least-squares fit Pluto stellar occultation light curve data. This model predicts atmospheric temperature based on surface temperature, surface pressure, surface radius, and CH4 and CO mixing ratios, from which model light curves are to be calculated. The model improves upon previous techniques for deriving Pluto’s atmospheric thermal structure from stellar occultation light curves by calculating temperature (as a function of height) caused by heating and cooling by species in Pluto’s atmosphere, instead of a general assumption that temperature follows a power law with height or some other idealized function. We are able to fit for model surface radius, surface pressure, and CH4 mixing ratio with one of the 2006 datasets and for surface pressure and CH4 mixing ratio for other datasets from the years 1988, 2002, 2006, and 2008. It was not possible to fit for CO mixing ratio and surface temperature because the light curves are not sensitive to these parameters. We determine that the model surface radius, under the assumption of a stratosphere only (i.e. no troposphere) model in radiative-conductive balance, is . The CH4 mixing ratio results are more scattered with time and are in the range of 1.8-9.4 × 10−3. The surface pressure results show an increasing trend from 1988 to 2002, although it is not as dramatic as the factor of 2 from previous studies.  相似文献   

14.
We show that the peak velocity of Jupiter’s visible-cloud-level zonal winds near 24°N (planetographic) increased from 2000 to 2008. This increase was the only change in the zonal velocity from 2000 to 2008 for latitudes between ±70° that was statistically significant and not obviously associated with visible weather. We present the first automated retrieval of fast (∼130 m s−1) zonal velocities at 8°N planetographic latitude, and show that some previous retrievals incorrectly found slower zonal winds because the eastward drift of the dark projections (associated with 5-μm hot spots) “fooled” the retrieval algorithms.We determined the zonal velocity in 2000 from Cassini images from NASA’s Planetary Data System using a global method similar to previous longitude-shifting correlation methods used by others, and a new local method based on the longitudinal average of the two-dimensional velocity field. We obtained global velocities from images acquired in May 2008 with the Wide Field Planetary Camera 2 (WFPC2) on the Hubble Space Telescope (HST). Longer-term variability of the zonal winds is based on comparisons with published velocities based on 1979 Voyager 2 and 1995-1998 HST images. Fluctuations in the zonal wind speeds on the order of 10 m s−1 on timescales ranging from weeks to months were found in the 1979 Voyager 2 and the 1995-1998 HST velocities. In data separated by 10 h, we find that the east-west velocity uncertainty due to longitudinal fluctuations are nearly 10 m s−1, so velocity fluctuations of 10 m s−1 may occur on timescales that are even smaller than 10 h. Fluctuations across such a wide range of timescales limit the accuracy of zonal wind measurements. The concept of an average zonal velocity may be ill-posed, and defining a “temporal mean” zonal velocity as the average of several zonal velocity fields spanning months or years may not be physically meaningful.At 8°N, we use our global method to find peak zonal velocities of ∼110 m s−1 in 2000 and ∼130 m s−1 in 2008. Zonal velocities from 2000 Cassini data produced by our local and global methods agree everywhere, except in the vicinity of 8°N. There, the local algorithm shows that the east-west velocity has large variations in longitude; vast regions exceed ∼140 m s−1. Our global algorithm, and all of the velocity-extraction algorithms used in previously-published studies, found the east-west drift velocities of the visible dark projections, rather than the true zonal velocity at the visible-cloud level. Therefore, the apparent increase in zonal winds between 2000 and 2008 at 8°N is not a true change in zonal velocity.At 7.3°N, the Galileo probe found zonal velocities of 170 m s−1 at the 3-bar level. If the true zonal velocity at the visible-cloud level at this latitude is ∼140 m s−1 rather than ∼105 m s−1, then the vertical zonal wind shear is much less than the currently accepted value.  相似文献   

15.
We obtained time-resolved, near-infrared spectra of Io during the 60-90 min following its reappearance from eclipse by Jupiter on five occasions in 2004. The purpose was to search for spectral changes, particularly in the well-known SO2 frost absorption bands, that would indicate surface-atmosphere exchange of gaseous SO2 induced by temperature changes during eclipse. These observations were a follow-on to eclipse spectroscopy observations in which Bellucci et al. [Bellucci et al., 2004. Icarus 172, 141-148] reported significant changes in the strengths of two strong SO2 bands in data acquired with the VIMS instrument aboard the Cassini spacecraft. One of the bands (4.07 μm [ν1 + ν3]) observed by Bellucci et al. is visible from ground-based observatories and is included in our data. We detected no changes in Io’s spectrum at any of the five observed events during the approximately 60-90 min during which spectra were obtained following Io’s emergence from Jupiter’s shadow. The areas of the three strongest SO2 bands in the region 3.5-4.15 μm were measured for each spectrum; the variation of the band areas with time does not exceed that which can be explained by the Io’s few degrees of axial rotation during the intervals of observation, and in no case does the change in band strength approach that seen in the Cassini VIMS data. Our data are of sufficient quality and resolution to show the weak 2.198 μm (4549.6 cm−1) 4ν1 band of SO2 frost on Io for what we believe is the first time. At one of the events (June 22, 2004), we began the acquisition of spectra ∼6 min before Io reappeared from Jupiter’s shadow, during which time it was detected through its own thermal emission. No SO2 bands were superimposed on the purely thermal spectrum on this occasion, suggesting that the upper limit to condensed SO2 in the vertical column above Io’s surface was ∼4 × 10−5 g cm−2.  相似文献   

16.
P. Hedelt  Y. Ito  L. Esposito 《Icarus》2010,210(1):424-435
Based on measurements performed by the Hydrogen Deuterium Absorption Cell (HDAC) aboard the Cassini orbiter, Titan’s atomic hydrogen exosphere is investigated. Data obtained during the T9 encounter are used to infer the distribution of atomic hydrogen throughout Titan’s exosphere, as well as the exospheric temperature.The measurements performed during the flyby are modeled by performing Monte Carlo radiative transfer calculations of solar Lyman-α radiation, which is resonantly scattered on atomic hydrogen in Titan’s exosphere. Two different atomic hydrogen distribution models are applied to determine the best fitting density profile. One model is a static model that uses the Chamberlain formalism to calculate the distribution of atomic hydrogen throughout the exosphere, whereas the second model is a Particle model, which can also be applied to non-Maxwellian velocity distributions.The density distributions provided by both models are able to fit the measurements although both models differ at the exobase: best fitting exobase atomic hydrogen densities of nH = (1.5 ± 0.5) × 104 cm−3 and nH = (7 ± 1) × 104 cm−3 were found using the density distribution provided by both models, respectively. This is based on the fact that during the encounter, HDAC was sensitive to altitudes above about 3000 km, hence well above the exobase at about 1500 km. Above 3000 km, both models produce densities which are comparable, when taking into account the measurement uncertainty.The inferred exobase density using the Chamberlain profile is a factor of about 2.6 lower than the density obtained from Voyager 1 measurements and much lower than the values inferred from current photochemical models. However, when taking into account the higher solar activity during the Voyager flyby, this is consistent with the Voyager measurements. When using the density profile provided by the particle model, the best fitting exobase density is in perfect agreement with the densities inferred by current photochemical models.Furthermore, a best fitting exospheric temperature of atomic hydrogen in the range of TH = (150-175) ± 25 K was obtained when assuming an isothermal exosphere for the calculations. The required exospheric temperature depends on the density distribution chosen. This result is within the temperature range determined by different instruments aboard Cassini. The inferred temperature is close to the critical temperature for atomic hydrogen, above which it can escape hydrodynamically after it diffused through the heavier background gas.  相似文献   

17.
S. Carles  J.-C. Guillemin 《Icarus》2011,211(1):901-905
Rate coefficient of the cyanide anion (CN−) with cyanoacetylene (HC3N) reaction, has been studied in gas phase at room temperature using a Flowing Afterglow Langmuir Probe - Mass Spectrometer (FALP-MS) apparatus. The rate constant for the CN− + HC3N reaction is k = 4.8 × 10−9 cm3/s with an uncertainty of 30%.  相似文献   

18.
Far infrared spectra (10-600 cm−1) from Cassini's Composite InfraRed Spectrometer (CIRS) were used to determine improved upper limits of hydrogen halides HF, HCl, HBr, and HI in Saturn's atmosphere. Three observations, comprising a total of 3088 spectra, gave 3σ upper limits on HF, HCl, HBr, and HI volume mole fractions of 8.0×10−12, 6.7×10−11, 1.3×10−10, and 1.4×10−9, respectively, at the 500 mbar pressure level. These upper limits confirm sub-solar abundances of halide species for HF, HCl, and HBr in Saturn's upper atmosphere—consistent with predictions from thermochemical models and influx of material from meteoroids. Our upper limit for HCl is 16 times lower than the tentative detection at 1.1×10−9 reported by Weisstein and Serabyn [Weisstein, E.W., Serabyn, E., 1996. Icarus 123, 23-36]. These observations are not sensitive to the deep halide abundance, which is expected to be enriched relative to the solar composition.  相似文献   

19.
Thermal-IR imaging from space-borne and ground-based observatories was used to investigate the temperature, composition and aerosol structure of Jupiter’s Great Red Spot (GRS) and its temporal variability between 1995 and 2008. An elliptical warm core, extending over 8° of longitude and 3° of latitude, was observed within the cold anticyclonic vortex at 21°S. The warm airmass is co-located with the deepest red coloration of the GRS interior. The maximum contrast between the core and the coldest regions of the GRS was 3.0-3.5 K in the north-south direction at 400 mbar atmospheric pressure, although the warmer temperatures are present throughout the 150-500 mbar range. The resulting thermal gradients cause counter-rotating flow in the GRS center to decay with altitude into the lower stratosphere. The elliptical warm airmass was too small to be observed in IRTF imaging prior to 2006, but was present throughout the 2006-2008 period in VLT, Subaru and Gemini imaging.Spatially-resolved maps of mid-IR tropospheric aerosol opacity revealed a well-defined lane of depleted aerosols around the GRS periphery, and a correlation with visibly-dark jovian clouds and bright 4.8-μm emission. Ammonia showed a similar but broader ring of depletion encircling the GRS. This narrow lane of subsidence keeps red aerosols physically separate from white aerosols external to the GRS. The visibility of the 4.8-μm bright periphery varies with the mid-IR aerosol opacity of the upper troposphere. Compositional maps of ammonia, phosphine and para-H2 within the GRS interior all exhibit north-south asymmetries, with evidence for higher concentrations north of the warm central core and the strongest depletions in a symmetric arc near the southern periphery. Small-scale enhancements in temperature, NH3 and aerosol opacity associated with localized convection are observed within the generally-warm and aerosol-free South Equatorial Belt (SEB) northwest of the GRS. The extent of 4.8-μm emission from the SEB varied as a part of the 2007 ‘global upheaval,’ though changes during this period were restricted to pressures greater than 500 mbar. Finally, a region of enhanced temperatures extended southwest of the GRS during the survey, restricted to the 100-400 mbar range and with no counterpart in visible imaging or compositional mapping. The warm airmass was perturbed by frequent encounters with the cold airmass of Oval BA, but no internal thermal or compositional effects were noted in either vortex during the close encounters.  相似文献   

20.
We present suggestive evidence for an inverse energy cascade within Jupiter’s atmosphere through a calculation of the power spectrum of its kinetic energy and its cloud patterns. Using Cassini observations, we composed full-longitudinal mosaics of Jupiter’s atmosphere at several wavelengths. We also utilized image pairs derived from these observations to generate full-longitudinal maps of wind vectors and atmospheric kinetic energy within Jupiter’s troposphere. We computed power spectra of the image mosaics and kinetic energy maps using spherical harmonic analysis. Power spectra of Jupiter’s cloud patterns imaged at certain wavelengths resemble theoretical spectra of two-dimensional turbulence, with power-law slopes near −5/3 and −3 at low and high wavenumbers, respectively. The slopes of the kinetic energy power spectrum are also near −5/3 at low wavenumbers. At high wavenumbers, however, the spectral slopes are relatively flatter than the theoretical prediction of −3. In addition, the image mosaic and kinetic energy power spectra differ with respect to the location of the transition in slopes. The transition in slope is near planetary wavenumber 70 for the kinetic energy spectra, but is typically above 200 for the image mosaic spectra. Our results also show the importance of calculating spectral slopes from full 2D velocity maps rather than 1D zonal mean velocity profiles, since at large wavenumbers the spectra differ significantly, though at low wavenumbers, the 1D zonal and full 2D kinetic energy spectra are practically indistinguishable. Furthermore, the difference between the image and kinetic energy spectra suggests some caution in the interpretation of power spectrum results solely from image mosaics and its significance for the underlying dynamics. Finally, we also report prominent variations in kinetic energy within the equatorial jet stream that appear to be associated with the 5 μm hotspots. Other eddies are present within the flow collar of the Great Red Spot, suggesting caution when interpreting snapshots of the flow inside these features as representative of a time-averaged state.  相似文献   

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