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1.
We have investigated the abundances of Titan's stratospheric oxygen compounds using 0.5 cm−1 resolution spectra from the Composite Infrared Spectrometer on the Cassini orbiter. The CO abundance was derived for several observations of far-infrared nadir spectra, taken at a range of latitudes (75° S-35° N) and emission angles (0°-60°), using rotational lines that have not been analysed before the arrival of Cassini at Saturn. The derived volume mixing ratios for the different observations are mutually consistent regardless of latitude. The weighted mean CO volume mixing ratio is 47±8 ppm if CO is assumed to be uniform with latitude. H2O could not be detected and an upper limit of 0.9 ppb was determined. CO2 abundances derived from mid-infrared nadir spectra show no significant latitudinal variations, with typical values of 16±2 ppb. Mid-infrared limb spectra at 55° S were used to constrain the vertical profile of CO2 for the first time. A vertical CO2 profile that is constant above the condensation level at a volume mixing ratio of 15 ppb reproduces the limb spectra very well below 200 km. This is consistent with the long chemical lifetime of CO2 in Titan's stratosphere. Above 200 km the CO2 volume mixing ratio is not well constrained and an increase with altitude cannot be ruled out there.  相似文献   

2.
Régis Courtin 《Icarus》1982,51(3):466-475
The pressure-induced absorptions of gaseous nitrogen (N2) and methane (CH4) are computed on the basis of the collisional lineshape theory of G. Birnhaum and E.R. Cohen [Canad. J. Phys.54, 593–602 (1976)]. Laboratory data at 300 and 124°K for N2 and at 296 and 195°K for CH4 are used to determine the collisional time constant and their temperature dependence. The spectrum of Titan from the microwave to the far-infrared region (0.1–600 cm?1) is then modeled using these opacities and a temperature profile of Titan's atmosphere derived from the Voyager 1 radio occultation experiment. The model atmosphere is composed of N2 and CH4, their relative proportions being determined by the vapor pressure law of CH4. A model with gaseous opacity alone is ruled out by the far-infrared observations. An additional opacity, thought to be associated with a methane cloud, is confirmed. The effective temperature of Titan is estimated at Te = 83.2 ± 1.4°K.  相似文献   

3.
SCIAMACHY (SCanning Imaging Absorption spectrometer for Atmospheric CHartographY) is a space based spectrometer designed to measure sunlight transmitted, reflected and scattered by the Earth atmosphere or surface. It is a contribution to the Envisat-1 satellite to be launched in late 1999.SCIAMACHY measurements will provide amounts and distribution of 03, BrO, OCl0, ClO, S02, H2CO, N02, CO, CO2, CH4, H2O, N20, pressure, temperature, aerosol, radiation, cloud cover and cloud top height from atmospheric measurements in nadir, limb and occultation geometry.By the combination of the near simultaneous limb and nadir observations SCIAMACHY is one of a limited number of instruments which is able to detect tropospheric column amounts of 03, N02, CO, CH4, H2O, N20, S02, H2CO, and BrO down to the planetary boundary layer under cloud free conditions.  相似文献   

4.
In March 1979, the spectrum of Venus was recorded in the far infrared from the G.P. Kuiper Airborne Observatory when the planet subtended a phase angle of 62°. The brightness temperature was observed to be 275°K near 110 cm?1, dropping to 230°K near 270 cm?1. Radiance calculations, using temperature and cloud structure formation from the Pioneer Venus mission and including gaseous absorption by the collision-induced dipole of CO2, yield results consistently brighter than the observations. Supplementing the spectral data, Pioneer Venus OIR data at similar phase angles provide the constraint that any additional infrared opacity must be contained in the upper cloud, H2SO4 to the Pioneer-measured upper cloud structure serves to reconcile the model spectrum and the observations, but cloud microphysics strongly indicates that such a high particle density haze (N ? 1.6 × 107cm?3) is implausible. The atmospheric environment is reviewed with regard to the far infrared opacity and possible particle distribution modifications are discussed. We conclude that the most likely possibility for supplementing the far-infrared opacity is a population of large particles (r ? 1 μm) in the upper cloud with number densities less than 1 particle cm?3 which has remained undetected by in situ measurements.  相似文献   

5.
Spectra from the Voyager 1 infrared interferometer spectrometer (IRIS) obtained near the time of closest approach to Jupiter were analyzed for the purpose of inferring ammonia cloud properties associated with the Equatorial Region. Comparisons of observed spectra with synthetic spectra computed from a radiative transfer formulation, that includes multiple scattering, yielded the following conclusions: (1) very few NH3 ice particles with radii less than 3 μm contribute to the cloud opacity; (2) the major source of cloud opacity arises from particles with radii in excess of 30 μm; (3) column particle densities are between 1 and 2 orders of magnitude smaller than those derived from thermochemical considerations alone, implying the presence of important atmospheric motion; and (4) another cloud system is confirmed to exist deeper in the Jovian troposphere.  相似文献   

6.
High spatial resolution infrared and visible data obtained by the Voyager 1 spacecraft have been analyzed simultaneously to infer properties of the deep cloud structure of the Jovian troposphere in the 1- to 4-bar pressure range. Influence of the ammonia upper cloud layer, in the 5μm Jovian window, has been investigated through a cloud model derived from far ir Voyager IRIS measurements. The attenuation, computed with an anisotropic scattering formulation, is too weak to explain 5-μm measurements and provides evidence for existence of a cloud structure at deeper levels. The main conclusions derived from the present analysis are summarized below: (1) the deep cloud structure appears to be vertically associated with the NH3 upper layer; (2) the ammonia cloud is mainly responsible for the visible appearance of the Jovian equatorial region; (3) the deep cloud structure exhibits a grey opacity in the 5-μm window; (4) coldest 5-μm spectra can be interpreted by the existence of a thick cloud layer located at levels in the 180–195°K temperature range. Implications of these results are discussed in conjunction with predictions of dynamical and thermochemical models. NH4SH is shown to be a likely candidate for the main deep cloud constituent. An even deeper thick H2O cloud may be present too, but should not be responsible for the observed spread in 5-μm brightness temperatures.  相似文献   

7.
R. de Kok  P.G.J. Irwin  N.A. Teanby 《Icarus》2008,197(2):572-578
In Titan's north polar region stratospheric clouds are expected to form due to a combination of low temperatures and downward motion of volatile-enriched air. Here we investigate possible sources of stratospheric clouds at Titan's pole using data from the Cassini Composite Infrared Spectrometer and a simple condensation model. An upper limit for C4N2 gas was determined to be 9×10−9, which is less than required to make the C4N2 cloud at the Voyager epoch. Hence, the presence of this cloud after equinox remains a mystery. The largest cloud seen in far-infrared spectra has a feature around 220 cm−1 and is located around an altitude of 140 km. The upper limit for propionitrile (C2H5CN) gas shows that the feature around 220 cm−1 is probably not due to pure propionitrile ice. Instead, our model calculations show that HCN should cause by far the largest cloud around 140 km. We therefore propose that HCN ice plays an important role in the formation of the massive polar cloud, because of the unavailability of sufficient condensable gas other than HCN to produce a strong enough condensate feature. However, the signature at 220 cm−1 is not consistent with that of pure HCN ice at 172 cm−1 and mixing of HCN ice with other ices, or chemical alteration of HCN ice might mask the HCN ice signature.  相似文献   

8.
The Galileo Probe sampled Jupiter's atmosphere at the edge of a 5-μm hot spot, where it found very little cloud opacity above the 700 mb level. Only τ=1-2 at λ=0.5 μm was inferred from Net Flux Radiometer observations (Sromovsky et al. 1998, J. Geophys. Res.103, 22,929-22,977), in seeming conflict with Chanover et al. (1997, Icarus128, 294-305) who inferred τ=6-8 above the 700 mb level (at λ∼0.9 μm) from 893-nm and 953-nm WFPC2 observations of a group of hot spots. Postulating a heterogeneous cloud structure is one way to resolve the conflict. We obtained a more satisfying resolution by reinterpretation of the HST observations with Probe-compatible assumptions about the vertical distribution of cloud particles. Assuming a physically thin upper (putative NH3) cloud with adjustable optical depth and effective pressure (peff<440 mb) and a physically thin midlevel (putative NH4SH) cloud with adjustable optical depth but a fixed pressure of 1.2 bars, we are able to fit WPFC2 observations with probe-consistent opacities in hot spot regions. With the same cloud pressures, but higher middle cloud opacities, we are even able to fit the visibly bright regions. Little variability is seen in the upper cloud. Best fits to October 1995 WFPC2 observations in dark regions (5-μm hot spots) yielded τupper=1.3-1.9 at 0.9 μm and peff=240 mb−270 mb, while in visibly bright regions between hot spots we obtained τupper=1.6-2.2 and peff=250 mb−290 mb. May 1996 observations yielded slightly higher values of τupper (1.8-2.3 and 2.0-2.8) and peff (250 mb−310 mb and 265 mb−320 mb). We found that the most important variable parameter is the opacity of the middle cloud, which ra nged from τ=1, 2 in dark regions, to τ=8-30 in bright regions. From limb darkening characteristics, we inferred a wavelength-dependent haze opacity ranging from 0.2±0.05 at 660 nm to 0.35±0.05 at 953 nm, and an effective haze pressure near 120 mb. We did not find it necessary to use low single scattering albedos that require effective imaginary indices, that are several orders of magnitude larger than the values of the main putative cloud components.  相似文献   

9.
The effects of collision-induced absorption on the far infrared spectrum of Titan have been investigated. After a review of the procedure for the theoretical calculation of the N2 translation-rotational spectrum, new results for the temperature range of 70 to 120°K are reported. These are used as input data for a simple atmospheric model in order to compute the far infrared radiance, brightness temperature, and spectral limb function. This source of opacity alone is not capable of explaining the Voyager results. When the collision-induced methane is included, the results are in closer agreement in the range between 200 and 300 cm?1, suggesting that a more complete treatment of collision-induced absorption including particularly CH4N2, N2H2, and H2H2 results, may provide sufficient opacity to reduce or obviate the need for opacities due to clouds or aerosols in order to explain the observed spectra.  相似文献   

10.
Mesospheric clouds have been previously observed on Mars in a variety of datasets. However, because the clouds are optically thin and most missions have performed surface-focussed nadir sounding, geographic and seasonal coverage is sparse. We present new detections of mesospheric clouds using a limb spectra dataset with global coverage acquired by NASA’s Mars Climate Sounder (MCS) aboard Mars Reconnaissance Orbiter. Mesospheric aerosol layers, which can be CO2 ice, water ice or dust clouds, cause high radiances in limb spectra, either by thermal emission or scattering of sunlight. We employ an object recognition and classification algorithm to identify and map aerosol layers in limb spectra acquired between December 2006 and April 2011, covering more than two Mars years. We use data from MCS band A4, to show thermal signatures of day and nightside features, and A6, which is sensitive to short wave IR and visible daytime features only. This large dataset provides several thousand detections of mesospheric clouds, more than an order of magnitude more than in previous studies.Our results show that aerosol layers tend to occur in two distinct regimes. They form in equatorial regions (30°S–30°N) during the aphelion season/northern hemisphere summer (Ls < 150°), which is in agreement with previous published observations of mesospheric clouds. During perihelion/dust storm season (Ls > 150°) a greater number of features are observed and are distributed in two mid-latitude bands, with a southern hemisphere bias. We observe temporal and longitudinal clustering of cloud occurrence, which we suggest is consistent with a formation mechanism dictated by interaction of broad temperature regimes imposed by global circulation and the propagation to the mesosphere of small-scale dynamics such as gravity waves and thermal tides.Using calculated frost point temperatures and a parameterization based on synthetic spectra we find that aphelion clouds are present in generally cooler conditions and are spectrally more consistent with H2O or CO2 ice. A significant fraction has nearby temperature retrievals that are within a few degrees of the CO2 frost point, indicating a CO2 composition for those clouds. Perihelion season clouds are spectrally most similar to H2O ice and dust aerosols, consistent with temperature retrievals near to the clouds that are 30–80 K above the CO2 frost point.  相似文献   

11.
Far-IR (25-50 μm, 200-400 cm−1) nadir and limb spectra measured during Cassini's four year prime mission by the Composite InfraRed Spectrometer (CIRS) instrument have been used to determine the abundances of cyanogen (C2N2), methylacetylene (C3H4), and diacetylene (C4H2) in Titan's stratosphere as a function of latitude. All three gases are enriched at northern latitudes, consistent with north polar subsidence. C4H2 abundances agree with those derived previously from mid-IR data, but C3H4 abundances are about 2 times lower, suggesting a vertical gradient or incorrect band intensities in the C3H4 spectroscopic data. For the first time C2N2 was detected at southern and equatorial latitudes with an average volume mixing ratio of 5.5±1.4×10−11 derived from limb data (>3-σ significance). This limb result is also corroborated by nadir data, which give a C2N2 volume mixing ratio of 6±3×10−11 (2-σ significance) or alternatively a 3-σ upper limit of 17×10−11. Comparing these figures with photochemical models suggests that galactic cosmic rays may be an important source of N2 dissociation in Titan's stratosphere. Like other nitriles (HCN, HC3N), C2N2 displays greater north polar relative enrichment than hydrocarbons with similar photochemical lifetimes, suggesting an additional loss mechanism for all three of Titan's main nitrile species. Previous studies have suggested that HCN requires an additional sink process such as incorporation into hazes. This study suggests that such a sink may also be required for Titan's other nitrile species.  相似文献   

12.
We examine the effects of NH3 ice particle clouds in the atmosphere of Jupiter on outgoing thermal radiances. The cloud models are characterized by a number density at the cloud base, by the ratio of the scale height of the vertical distribution of particles (Hp) to the gas scale height (Hg), and by an effective particle radius. NH3 ice particle-scattering properties are scaled from laboratory measurements. The number density for the various particle radius and scale height models is inferred from the observed disk average radiance at 246 cm?1, and preliminary lower limits on particle sizes are inferred from the lack of apparent NH3 absorption features in the observed spectral radiances as well as the observed minimum flux near 2100 cm?1. We find lower limits on the particle size of 3 μm if Hp/Hg = 0.15, or 10μmif Hp/Hg = 0.50 or 0.05. NH3 ice particles are relatively dark near the far-infrared and 8.5-μm atmospheric windows, and the outgoing thermal radiances are not very sensitive to various assumptions about the particle-scattering function as opposed to radiances at 5 μm, where particles are relatively brighter. We examined observations in these three different spectral window regions which provide, in principle, complementary constraints on cloud parameters. Characterization of the cloud scale height is difficult, but a promising approach is the examination of radiances and their center-to-limb variation in spectral regions where there is significant opacity provided by gases of known vertical distribution. A blackbody cloud top model can reduce systematic errors due to clouds in temperature sounding to the level of 1K or less. The NH3 clouds provide a substantial influence on the internal infrared flux field near the 600-mbar level.  相似文献   

13.
The latitudinal variation of Saturn’s tropospheric composition (NH3, PH3 and AsH3) and aerosol properties (cloud altitudes and opacities) are derived from Cassini/VIMS 4.6-5.1 μm thermal emission spectroscopy on the planet’s nightside (April 22, 2006). The gaseous and aerosol distributions are used to trace atmospheric circulation and chemistry within and below Saturn’s cloud decks (in the 1- to 4-bar region). Extensive testing of VIMS spectral models is used to assess and minimise the effects of degeneracies between retrieved variables and sensitivity to the choice of aerosol properties. Best fits indicate cloud opacity in two regimes: (a) a compact cloud deck centred in the 2.5-2.8 bar region, symmetric between the northern and southern hemispheres, with small-scale opacity variations responsible for numerous narrow light/dark axisymmetric lanes; and (b) a hemispherically asymmetric population of aerosols at pressures less than 1.4 bar (whose exact altitude and vertical structure is not constrained by nightside spectra) which is 1.5-2.0× more opaque in the summer hemisphere than in the north and shows an equatorial maximum between ±10° (planetocentric).Saturn’s NH3 spatial variability shows significant enhancement by vertical advection within ±5° of the equator and in axisymmetric bands at 23-25°S and 42-47°N. The latter is consistent with extratropical upwelling in a dark band on the poleward side of the prograde jet at 41°N (planetocentric). PH3 dominates the morphology of the VIMS spectrum, and high-altitude PH3 at p < 1.3 bar has an equatorial maximum and a mid-latitude asymmetry (elevated in the summer hemisphere), whereas deep PH3 is latitudinally-uniform with off-equatorial maxima near ±10°. The spatial distribution of AsH3 shows similar off-equatorial maxima at ±7° with a global abundance of 2-3 ppb. VIMS appears to be sensitive to both (i) an upper tropospheric circulation (sensed by NH3 and upper-tropospheric PH3 and hazes) and (ii) a lower tropospheric circulation (sensed by deep PH3, AsH3 and the lower cloud deck).  相似文献   

14.
L.A. Sromovsky  P.M. Fry 《Icarus》2008,193(1):252-266
Grism spectra of Uranus obtained at the Keck Observatory in 2006, using the NIRC2 instrument and adaptive optics, provide new constraints on the vertical structure of Uranus' cloud bands and on the volume mixing ratio of methane. The best model fits to H-band spectra (1.49-1.635 μm) are found for a methane volume mixing ratio of 1.0 ± 0.25% for latitudes near 43° S and 1-1.6% for latitudes of 12° S and 33° N. Analysis of the J-band spectra are confused by discrepancies between short-wave and long-wave sides of the 1.28 μm window region. The short-wave side of the window (1.23-1.30 μm) is best fit with 1.6% CH4, but if the fitted spectral range is extended to include the long-wave side of the window (1.2-1.34 μm), the best fit CH4 mixing ratio is 4% or more, although many small scale spectral features are poorly fit over this range even at high methane mixing ratios, suggesting that models of methane opacity may be inconsistent in this spectral region. Most of the latitudinal variability of the H-band spectra can be fit with clouds near 2-3 and 6-8 bar, with cloud reflectivity of the deeper layer increasing from ∼2% at 33° N to 3-4% in the southern hemisphere. This layer is most likely made of H2S particles and appears weakly reflective because it is optically thin and possibly also contaminated by absorbing materials. The reflectivity of the 2-3-bar cloud increases from 0.5% at 33° N to ∼1% at the bright band centered near 43° S, where the upper cloud is a little higher (pressure is 10% lower) and ∼25% more reflective than at nearby latitudes. The bright band is also associated with lowering of the deep cloud pressure, by ∼1.4 bar. The bright band parameters are roughly consistent with those obtained from 1975 disk-averaged spectra, obtained when the southern hemisphere was more exposed to the Sun. The lack of significant cloud particle contributions near 1.2 bar, where occultation results suggested a methane cloud, is confirmed by both spectra and HST imaging observations.  相似文献   

15.
Glenn S. Orton 《Icarus》1975,26(2):142-158
Observations of Jovian limb structure at 8.11 and 8.45 microns are reported. These are used along with other limb structure and spectral data in the 8–14 micron region to derive a model of the thermal and cloud structure within the 1.0-0.01 bar pressure regime. The model is generally consistent with models derived from Pioneer 10 infrared radiometer data reported by Orton (1975b). The temperature is about 165K at 1.00 bar, 108K at 0.01 bar, and 143K at 0.03 bar. In zones, an optically opaque cloud of NH3 exists near the 143K (0.60 bar) level. A partly transparent haze of solid NH3 particles overlies the cloud. Belts are free of the cloud and have a much lower abundance of NH3 haze than the zones. The data are consistent with an NH3 gas abundance defined by saturation equilibrium, with a mixing ratio of 1.5 × 10?4 deep in the atmosphere, and with a CH4 mixing ratio of 2 × 10?3, about three times the currently accepted value.  相似文献   

16.
Four broad spectral features were identified in far-infrared limb spectra from the Cassini Composite Infrared Spectrometer (CIRS), two of which have not been identified before. The features are broader than the spectral resolution, which suggests that they are caused by particulates in Titan's stratosphere. We derive here the spectral properties and variations with altitude for these four features for six latitudes between 65° S and 85° N. Titan's main aerosol is called Haze 0 here. It is present at all wavenumbers in the far-infrared and is found to have a fractional scale height (i.e., the aerosol density scale height divided by the atmospheric density scale height) between 1.5 and 1.7 with a small increase in opacity in the north. A second feature around 140 cm−1 (Haze A) has similar spatial properties to Haze 0, but has a smaller fractional scale height of 1.2-1.3. Both Haze 0 and Haze A show an increase in retrieved abundance below 100 km. Two other features (Haze B around 220 cm−1 and Haze C around 190 cm−1) have a large maximum in their density profiles at 140 and 90 km, respectively. Haze B is much more abundant in the northern hemisphere compared to the southern hemisphere. Haze C also shows a large increase towards the north, but then disappears at 85° N.  相似文献   

17.
By using the Mariner 5 temperature profile and a homogeneous cloud model, and assuming that CO2 and cloud particles are the only opacity sources, the wavelength dependence of the Venus cloud opacity is infrared from the infrared spectrum of the planet between 450 and 1250 cm?1. Justification for applying the homogeneous cloud model is found in the fact that numerous polarization and infrared data are mutually consistent within the framework of such a model; on the other hand, dense cloud models are not satisfactory.Volume extinction coefficients varying from 0.5 × 10?5 to 1.5 × 10?5 cm?1, depending on the wavelength, are determined at the tropopause level of 6110 km. By using all available data, a cloud mass mixing ratio of approximately 5 × 10?6 and a particle concentration of about 900 particles cm?3 at this level are also inferred. The derived cloud opacity compares favorably with that expected for a haze of droplets of a 75% aqueous solution of sulfuric acid.  相似文献   

18.
Neptune was observed by the Infrared Space Observatory (ISO) Long-Wavelength Spectrometer (LWS) between 46 and 185 μm. At wavelengths between 50 and 110 μm the accuracy of these measurements is ?0.3 K. Observations of this planet made by the ISO Short-Wavelength Spectrometer between 28 and 44 μm were combined with the LWS data to determine a disk-averaged temperature profile and derive several physical quantities. The combined spectra are matched best by a He/(H2+He) mass ratio of 26.4+2.6−3.5%, reflecting a He molar fraction of 14.9+1.7−2.2%, assuming the molar fraction of CH4 to be 2% in the troposphere. This He abundance is consistent with one derived from analysis of joint Voyager-2 IRIS and radio occultation experiment data, a technique whose accuracy has recently been called into question. For a disk average, the para-H2 fraction is found to be no more than ∼1.5% different from its equilibrium value, and the N2 mixing ratio is probably less than 0.7%. The composite spectrum is best fit by invoking a CH4 ice condensate cloud. Using a Mie approximation to particle scattering and absorption, best-fit particle sizes lie between 15 and 40 μm. The composite spectra are relatively insensitive to the vertical distribution of the cloud, but the particle scale height must be greater than 5% of the gas scale height. The best models are consistent with an effective temperature for Neptune that is 59.5±0.6 K, a value slightly lower than derived by the Voyager IRIS experiment—possibly Neptune's mid- and far-infrared emission has changed during the seven years that lie between its encounter with Voyager 2 and the first spectra taken of this planet with ISO. The model spectra are also ostensibly lower than ground-based observations in the spectral range of 17-24 μm, but this discrepancy can be relieved by perturbing the temperature of the lower stratosphere where the LWS spectrum is not particularly sensitive, combined with the uncertainty in the absolute calibration of the ground-based measurements.  相似文献   

19.
It is shown that Titan's surface and plausible atmospheric thermal opacity sources—gaseous N2, CH4, and H2, CH4 cloud, and organic haze—are sufficient to match available Earth-based and Voyager observations of Titan's thermal emission spectrum. Dominant sources of thermal emission are the surface for wavelenghts λ ? 1 cm, atmospheric N2 for 1 cm ? λ ? 200 μm,, condensed and gaseous CH4 for 200 μm ? λ ? 20 μm, and molecular bands and organic haze for λ ? 20 μm. Matching computed spectra to the observed Voyager IRIS spectra at 7.3 and 52.7° emission angles yields the following abundances and locations of opacity sources: CH4 clouds: 0.1 g cm? at a planetocentric radius of 2610–2625 km, 0.3 g cm?2 at 2590–2610 km, total 0.4 ± 0.1 g cm–2 above 2590 km; organic haze: 4 ± 2 × 10?6, g cm, ?2 above 2750 km; tropospheric H2: 0.3 ± 0.1 mol%. This is the first quantitative estimate of the column density of condensed methane (or CH4/C2H6) on Titan. Maximum transparency in the middle to far IR occurs at 19 μm where the atmospheric vertical absorption optical depth is ?0.6 A particle radius r ? 2 μm in the upper portion of the CH4 cloud is indicated by the apparent absence of scattering effects.  相似文献   

20.
P.G.J. Irwin  K. Sihra  F.W. Taylor 《Icarus》2005,176(2):255-271
New measurements of the low-temperature near-infrared absorption of methane (Sihra, 1998, Laboratory measurements of near-infrared methane bands for remote sensing of the jovian atmosphere, Ph.D. thesis, University of Oxford) have been combined with existing, longer path-length, higher-temperature data of Strong et al. (1993, Spectral parameters of self- and hydrogen-broadened methane from 2000 to 9500 cm−1 for remote sounding of the atmosphere of Jupiter, J. Quant. Spectrosc. Radiat. Trans. 50, 309-325) and fitted with band models. The combined data set is found to be more consistent with previous low-temperature methane absorption measurements than that of Strong et al. (1993, J. Quant. Spectrosc. Radiat. Trans. 50, 309-325) but covers the same wider wavelength range and accounts for both self- and hydrogen-broadening conditions. These data have been fitted with k-coefficients in the manner described by Irwin et al. (1996, Calculated k-distribution coefficients for hydrogen- and self-broadened methane in the range 2000-9500 cm−1 from exponential sum fitting to band modelled spectra, J. Geophys. Res. 101, 26,137-26,154) and have been used in multiple-scattering radiative transfer models to assess their impact on our previous estimates of the jovian cloud structure obtained from Galileo Near-Infrared Mapping Spectrometer (NIMS) observations (Irwin et al., 1998, Cloud structure and atmospheric composition of Jupiter retrieved from Galileo NIMS real-time spectra, J. Geophys. Res. 103, 23,001-23,021; Irwin et al., 2001, The origin of belt/zone contrasts in the atmosphere of Jupiter and their correlation with 5-μm opacity, Icarus 149, 397-415; Irwin and Dyudina, 2002, The retrieval of cloud structure maps in the equatorial region of Jupiter using a principal component analysis of Galileo/NIMS data, Icarus 156, 52-63). Although significant differences in methane opacity are found at cooler temperatures, the difference in the optical depth of the atmosphere due to methane is found to diminish rapidly with increasing pressure and temperature and thus has negligible effect on the cloud structure inferred at deeper levels. Hence the main cloud opacity variation is still found to peak at around 1-2 bar using our previous analytical approach, and is thus still in disagreement with Galileo Solid State Imager (SSI) determinations (Banfield et al., 1998, Jupiter's cloud structure from Galileo imaging data, Icarus 135, 230-250; Simon-Miller et al., 2001, Color and the vertical structure in Jupiter's belts, zones and weather systems, Icarus 154, 459-474) which place the main cloud deck near 0.9 bar. Further analysis of our retrievals reveals that this discrepancy is probably due to the different assumptions of the two analyses. Our retrievals use a smooth vertically extended cloud profile while the SSI determinations assume a thin NH3 cloud below an extended haze. When the main opacity in our model is similarly assumed to be due to a thin cloud below an extended haze, we find the main level of cloud opacity variation to be near the 1 bar level—close to that determined by SSI and moderately close to the expected condensation level of ammonia ice of 0.85 bar, assuming that the abundance of ammonia on Jupiter is (7±1)×10−4 (Folkner et al., 1998, Ammonia abundance in Jupiter's atmosphere derived from the attenuation of the Galileo probe's radio signal, J. Geophys. Res. 103, 22,847-22,855; Atreya et al., 1999, A comparison of the atmospheres of Jupiter and Saturn: deep atmospheric composition, cloud structure, vertical mixing, and origin, Planet. Space Sci. 47, 1243-1262). However our data in the 1-2.5 μm range have good height discrimination and our lowest estimate of the cloud base pressure of 1 bar is still too great to be consistent with the most recent estimates of the ammonia abundance of 3.5 × solar. Furthermore the observed limited spatial distribution of ammonia ice absorption features on Jupiter suggests that pure ammonia ice is only present in regions of localised vigorous uplift (Baines et al., 2002, Fresh ammonia ice clouds in Jupiter: spectroscopic identification, spatial distribution, and dynamical implications, Icarus 159, 74-94) and is subsequently rapidly modified in some way which masks its pure absorption features. Hence we conclude that the main cloud deck on Jupiter is unlikely to be composed of pure ammonia ice and instead find that it must be composed of either NH4SH or some other unknown combination of ammonia, water, and hydrogen sulphide and exists at pressures of between 1 and 2 bar.  相似文献   

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