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1.
朝鲜甑山“群”变质岩中锆石-榍石-金红石U-Pb体系:古元古代-中生代构造-热事件记录 总被引：5，自引：4，他引：1
朝鲜甑山地区甑山"群"(杂岩)的主要岩石类型包括石榴云母片麻岩、石榴角闪岩,并有少量大理岩。其原岩为泥质岩为主的碎屑岩,并含有少量火山岩和碳酸盐岩,经历了角闪岩相到麻粒岩相变质作用。本文对甑山"群"2件石榴云母片麻岩和1件石榴角闪岩样品进行了锆石-榍石-金红石U-Pb体系年代学研究。石榴云母片麻岩中分选出的锆石均为变质新生锆石,Pb-Pb加权平均年龄为1850±5Ma,没有发现继承锆石组分,暗示原岩为缺乏碎屑锆石的泥质岩。石榴角闪岩中的榍石根据成因不同,可分为两期,即早期麻粒岩相变质生长的榍石和后期热事件生长榍石。早期榍石具有高U、高Th/U比值特点,U-Pb分析构成一条不一致线,上交点年龄1831±5Ma代表了早期变质热事件冷却到榍石U-Pb体系封闭温度时代,下交点年龄155±3Ma代表后期热事件造成Pb丢失时代;另一种榍石具有低U低Th/U比值特点,U-Pb年龄为单一的153±3Ma,为中生代构造热事件的新生榍石。两类样品中的金红石少量颗粒保存有早期U-Pb年龄信息,绝大多数在~155Ma发生完全重置,并直到~110Ma一直处于U-Pb体系开放状态。以上数据说明,甑山"群"在~1850Ma前发生高级变质,1850~1830Ma开始抬升出露,并成为中新元古界沉积岩物源与沉积基底,中生代受到朝鲜广泛发育的岩浆-热事件的影响。 相似文献
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长期以来,陇山杂岩的归属问题一直存在争议。本文对出露于秦岭-祁连山结合部位的陇山杂岩中石榴黑云斜长片麻岩和石榴斜长角闪岩进行了详细的岩石学、P-T温压计算、独居石和榍石U-Pb年代学研究。通过详细的岩相学观察,石榴黑云斜长片麻岩的变质峰期矿物组合为石榴子石+黑云母+斜长石+石英;石榴斜长角闪岩中则识别出了以石榴子石+单斜辉石+角闪石+斜长石+石英为峰期的变质矿物组合。通过传统温压计计算,石榴黑云斜长片麻岩(样品21LS40)和石榴斜长角闪岩样品(样品21LS42-1)的峰期变质P-T条件分别为700℃、0.72GPa和710℃、0.74GPa。激光剥蚀电感耦合等离子体质谱(LA-ICP-MS) U-Pb数据表明,石榴黑云斜长片麻岩中独居石的206Pb/238U的加权平均年龄为407~435Ma。石榴斜长角闪岩中榍石的下交点年龄分别为410±7Ma、409±5Ma和426±10Ma,榍石中Zr含量温度计的计算结果分别为750℃、751℃和748℃(假定压力为0.7GPa)。本文从变质作用的角度出发,将陇山杂岩与秦岭杂岩进行温压条件和变质时代对比研究,认为陇山杂岩与东秦岭杂岩高压-超高压岩石的最后一期退变质作用和西秦岭天水地区的秦岭杂岩麻粒岩相变质作用类似,可能为北秦岭造山带的西延。 相似文献
3.
榍石LA-SF-ICP-MS U-Pb定年及对结晶和封闭温度的指示 总被引：1，自引：0，他引：1
榍石富含U、Th,贫Pb,是U-Pb定年的理想矿物之一。本文采用激光剥蚀-高分辨等离子体质谱建立榍石U-Pb定年方法,采用25~30μm激光斑束,准确测定榍石U-Pb标准样品BLR-1（~1048Ma）、OLT-1（~1014Ma）和Pakistan（~21.4Ma）,以及年轻榍石样品（<100Ma）U-Pb年龄,提高了检测准确性和空间分辨率。综合对比共生锆石和榍石U-Pb年龄、榍石颗粒微量元素和U-Pb年龄环带及不同成分岩浆岩（SiO2含量48.1%~77.0%）中岩浆榍石的结晶温度,结果表明：岩浆演化过程中,榍石具有宽泛的结晶温度（600~900℃,峰值~750℃）,主要集中于岩浆演化中晚期结晶,榍石U-Pb同位素封闭温度接近或略低于锆石,因此同一岩浆体系中锆石与榍石的年龄差异可能反映了该熔体较晚达到榍石饱和,而非熔体热演化历史或封闭温度信息。 相似文献
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应用LA-ICP-MS方法对新疆西南天山高压-超高压变质带中的榴辉岩及其高压脉体中的金红石和榍石进行了Zr含量的检测和Zr温度计的计算。榴辉岩中位于石榴石幔部且与绿辉石共生的金红石包体Zr含量都集中于10~20μg/g;而基质金红石的Zr含量为30~50μg/g,高于包体金红石。榍石均为金红石退变质的产物,且各样品间的榍石Zr含量较均一,都集中在3~5μg/g之间。脉体金红石Zr含量则与榴辉岩中基质金红石的Zr含量相当甚至偏高一些,为30~60μg/g。金红石和榍石的Zr温度计研究也表明,榴辉岩石榴石中的金红石包体生长于压力峰期阶段,温压条件为480~540℃、2.7~3.0 GPa;基质金红石随温度增加达到退变质再平衡,记录了温度峰期的条件,约530~590℃、2.4~2.7 GPa;榴辉岩中高压脉体中的金红石则生长于退变质榴辉岩相阶段,金红石Zr温度计给出结果为540~580℃、1.5~2.1 GPa,记录了近等温降压的过程;榴辉岩中的榍石在1.0 GPa左右达到平衡,榍石Zr温度计给出的温度为540~560℃,记录了进一步的近等温降压的过程。根据以上4个阶段的分析结果,得出一个较完整的顺时针p-T轨迹,且与相平衡模拟所限定的p-T轨迹相一致。金红石的Zr含量可以作为压力的指示,表明压力校正在金红石Zr温度计中起到了重要作用。在对金红石和榍石Zr温度计进行应用时,要结合细致的岩相学观察,综合考虑压力、活度、扩散速率、退变质作用和流体影响等方面的因素,才能得到比较精确的温压估算结果和pT轨迹。 相似文献
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榍石LA-ICP-MS U-Pb定年技术研究 总被引：3，自引：0，他引：3
榍石具有较高的U含量和封闭温度,是一种重要的适用于U-Pb定年的副矿物。然而,基体效应与普通Pb校正成为制约榍石LA-ICP-MS U-Pb定年发展的主要因素。本文以~(206)Pb/~(238)U为例,采用基体归一化因子(F_(AVG))评估了锆石与榍石U-Pb定年标准的基体效应,结果显示榍石F_(AVG)几乎都大于1.20,而锆石F_(AVG)明显都小于1.20,表明锆石与榍石U-Pb定年标准存在显著的基体效应。以BLR-1榍石标准为外部校准标样,OLT1榍石获得的谐和年龄1014.9±4.8Ma(95%置信水平,n=23,MSWD=0.32)与SHRIMP谐和年龄1017.1±3.6Ma及ID-TIMS谐和年龄1014.6±1.3 Ma在误差范围内一致,同时获得~(206)Pb/~(238)U、~(207) Pb/~(235) U、~(207) Pb/~(206) Pb加权平均年龄在误差范围内与其谐和年龄一致;而以91500锆石为外部校准标样,OLT1榍石获得的~(206)Pb/~(238)U加权平均年龄为891.3±9.5 Ma(n=23,MSWD=5.3),与ID-TIMS测得的谐和年龄相比偏低约12%。经~(207)Pb法校正后,TCB榍石获得的~(206)Pb/~(238) U加权平均年龄1015.6±6.2 Ma(n=16,MSWD=0.84)与ID-TIMS谐和年龄1018.1±1.7Ma在误差范围内一致。本研究表明,采用基体匹配的榍石标准为外部标样,利用LA-ICP-MS对榍石进行U-Pb定年也能获得与ID-TIMS相一致的年龄,精度(2RSE)小于2%。 相似文献
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同位素地质年代学是探索地质体时空演化及地球动力学等问题的基础学科,应用最为广泛的当属含铀副矿物的U-Pb定年技术。榍石具有相对较低的U-Pb体系封闭温度,并广泛发育于岩浆岩、各类变质岩、热液成因岩石以及少量沉积岩中,是一种理想的中高温地质事件定年矿物。利用电感耦合等离子体质谱法(ICP-MS)测定榍石U-Pb年龄时,不可避免地要解决高普通铅以及元素分馏效应对测试的影响。本文对榍石LA-ICP-MS实验过程中的元素分馏行为进行研究,采用相同基体的标准样品与未知样品对比,发现了榍石不同颗粒之间元素分馏行为不一致的现象;同时采用不同的元素分馏校正方法,分别应用于锆石、独居石和榍石进行对比研究,认为分馏行为一致的副矿物定年可以采用"指数法"和"均值法"对数据进行校正,但是对于榍石这种分馏行为不一致的副矿物,定年时只有采用"截距法"对数据进行校正才可以获得正确的年龄。进而将此结论应用于秦岭造山带老牛山地区岩浆成因榍石样品,得到的结果与锆石年龄一致,表明"截距法"可以避免分馏行为不一致导致的校正不准确的问题。本研究成果为榍石LA-ICP-MS U-Pb定年方法的完善提供了一种思路。 相似文献
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榍石作为副矿物在哀牢山-红河剪切带新生代富碱侵入岩中广泛存在。原位获取榍石矿物内部微量元素、U-Pb年龄和Sm-Nd同位素的空间变化对获取矿物和岩石的成因演化信息具有重要意义。本文使用四级杆/多接收电感耦合等离子体质谱(Quadrupole/Multi-Collector Inductively Coupled Plasma Mass Spectrometry,Q/MC-ICP-MS)与激光剥蚀系统(Laser Ablation,LA)联用,对哀牢山-红河剪切带5个富碱侵入岩体(桃花岩体、宁蒗-永胜岩体、哈播岩体、铜厂岩体和十里村岩体)中榍石开展了微区原位微量元素、U-Pb年代学和Sm-Nd同位素研究。微量元素分析结果表明,三江富碱侵入岩中榍石为岩浆成因,亏损Rb、Ba、Pb、Sr等大离子亲石元素,富集Th、U、Nb、Ta、Zr、Hf等高场强元素。榍石的稀土配分图均表现为明显右倾,不具有或具有弱的Eu负异常。与云南北衙、马厂箐矽卡岩矿床中的热液榍石相比,本文榍石在稀土元素组成上,具有较高的稀土元素总量、较高的Th/U、LREE/HREE和Ce/Ce*比值,具有较低的Eu/Eu*、Nb/Ta、Zr/Hf比值。微区原位LA-Q-ICP-MS U-Pb定年结果表明,研究区富碱岩体中榍石结晶年龄在32.5～37.9Ma之间,代表了岩体形成时代,与三江地区哀牢山-红河剪切带及其附近新生代富碱岩浆活动高峰期(～35Ma)一致,属于青藏高原晚碰撞期岩浆作用的产物。榍石微区原位LA-MCICP-MS Sm-Nd同位素分析结果显示,榍石颗粒的Nd同位素组成均一,表明榍石结晶过程中寄主岩浆的Nd同位素组成没有发生明显变化。各个富碱岩体之间的榍石Nd同位素组成变化范围在-6.8～-2.1之间,与全岩的同位素特征一致,表明榍石的原位微区Sm-Nd同位素可以作为富碱侵入岩研究中有效的示踪手段之一。 相似文献
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胶北地块位于华北克拉通东部陆块,胶-辽-吉活动带的南端.胶北地区荆山杂岩中存在一组与高压基性麻粒岩密切共生的斜长角闪岩,是构成前寒武纪变质基底的重要组成部分.岩石学矿物学研究表明,斜长角闪岩记录了3个阶段的变质作用:峰期变质矿物组合（M1）为角闪石1+斜长石+榍石,根据NCKFMASHTO体系的成分视剖面图和角闪石压力计估算出温度条件T=660~715 ℃,压力条件P=0.65~0.71 GPa;其后经历了退变质作用（M2）,矿物组合为角闪石2+绿帘石+斜长石+绿泥石+钠长石,估算温压条件为537~630 ℃/0.41~0.58 GPa;晚期发生前绿片岩相退变质作用（M3）,其矿物组合为钠长石+葡萄石+绿泥石+方解石,其温压条件 < 400 ℃/0.35 GPa.斜长角闪石的CL图像显示其具有较弱的阴极发光效应和弱震荡环带,Th/U比值相对较小（0.06~0.43）,锆石形态和内部结构指示锆石形成于深熔作用过程,21个锆石的LA-ICP-MS定年研究的结果表明,斜长角闪岩记录的最老206Pb/238U年龄为2 075±25 Ma,上交点年龄为1 845±23 Ma（MSWD=0.35）,该组年龄记录了斜长角闪岩峰期变质作用时代的上限.斜长角闪岩在原岩形成以后,可能曾经历麻粒岩相变质作用,并记录了在胶-辽-吉带~1.85 Ga碰撞闭合过程中的深熔事件,此后经历了角闪岩相变质作用,及其二次退变质作用,终结于前绿片岩相的变质温压条件. 相似文献
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金红石-榍石转变过程中元素地球化学行为——以雅鲁藏布江缝合带角闪岩为例 总被引：2，自引：1，他引：1
金红石边缘形成榍石冠状边结构在变质中-基性岩中普遍存在,是金红石与退变质流体携带的SiO_2与CaO作用的结果,反应形成的榍石微量元素特征受到金红石和流体的共同影响。雅鲁藏布江缝合带中角闪岩LZ06-04在抬升过程经历近等温降压退变质作用,石榴子石分解导致同一样品中含石榴子石部分与不含石榴子石部分的退变质流体成分的差异。两种流体分别与金红石反应,对应形成的榍石具有相似的Nb、Ta含量和Nb/Ta比值特征,但截然不同的REE特征。榍石的Nb、Ta来源于金红石,残余金红石与含水流体再平衡Nb、Ta的分配系数增大,且D_(Nb)~(Rt/Fluid)≥D_(Ta)~(Rt/Fluid);虽然Nb和Ta在含水流体中都表现为不活动元素,但相对于Nb,Ta在含水流体中活动性较高。榍石的Zr-Hf体系特征受到锆石、石榴子石等矿物的综合影响,并且Zr-Hf在含水流体中表现出比Nb-Ta更高的活动性。榍石的REE特征受流体中REE特征、榍石与流体配分系数以及共生矿物的影响。在岩浆或变质体系,榍石形成过程中,REE富集矿物(如石榴子石、锆石、褐帘石、独居石、磷灰石等)形成或分解将影响榍石的REE分布特征或形成REE环带结构。含水流体中金红石退变质形成榍石反应的进行受流体中TiO_2、CaO和SiO_2活度的影响。因此榍石常见于钙碱性岩浆岩、富Ca基性变质岩和矽卡岩中。流体中CaO活度的变化影响榍石的形成,进而影响Ti、Nb、Ta在流体中的运移能力。俯冲板片产生流体在交代上覆富Ca地幔楔物质过程中形成榍石残留同样可以造成部分熔融体具有亏损HFSE特征。 相似文献
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Polygenetic titanite records the composition of metamorphic fluids during the exhumation of ultrahigh‐pressure metagranite in the Sulu orogen 
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下载免费PDF全文 Y.‐X. Chen K. Zhou Y.‐F. Zheng X.‐Y. Gao Y. H. Yang 《Journal of Metamorphic Geology》2016,34(6):573-594
An integrated study of U–Pb ages and trace elements was carried out for titanite and zircon from ultrahigh‐pressure (UHP) metagranites in the Sulu orogen, east‐central China. The results provide constraints on the composition of metamorphic fluids during the exhumation of deeply subducted continental crust. Titanite has two domain types based on REE patterns and trace element variations, Ttn‐I and Ttn‐II respectively. These two domains show indistinguishable U–Pb ages of 232 ± 14 to 220 ± 8 Ma, in general agreement with anatectic zircon U–Pb ages of 223 ± 4 to 219 ± 2 Ma for the partial melting event during early exhumation. The Ttn‐I domains have significantly higher REE, Th, Ta and Sr, and higher Th/U ratios than the Ttn‐II domains, indicating that the two domains have grown from metamorphic fluids with different compositions. For the Ttn‐I domains, Zr‐in‐titanite thermometry yields high temperatures of 773–851 °C at 2.5 GPa, and petrographic observations reveal the presence of melt pseudomorphs. Thus, they are interpreted to have grown from hydrous melts in the early exhumation stage. In contrast, the Ttn‐II domains were texturally equilibrated with amphibolite facies minerals such as biotite and plagioclase and contain inclusions of plagioclase and quartz. The Zr‐in‐titanite thermometry yields lower temperatures of 627–685 °C at 1.0 GPa. In combination with their REE patterns, they are interpreted to have grown from aqueous solutions at amphibolite facies metamorphic conditions during further exhumation. The differences in Th and Sr contents are prominent between the Ttn‐I and Ttn‐II domains, signifying the compositional difference between the hydrous melts and aqueous solutions. Therefore, the polygenetic titanite in the UHP metamorphic rocks provides insights into the geochemical property of metamorphic fluids during the continental subduction‐zone processes. 相似文献
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U–Pb analyses of rutile and titanite commonly yield ages that constrain the timing of cooling rather than the timing of their crystallization. Rutile which grew at or close to peak temperature conditions in a mafic granulite, intermediate granulite and mafic amphibolite within juxtaposed litho/tectonostratigraphic units in the Greater Himalayan Sequence (GHS) of NW Bhutan yield LA–MC–ICP–MS U–Pb lower intercept cooling ages of 10.1 ± 0.4, 10.8 ± 0.1 and 10.0 ± 0.3 Ma, respectively. Numerical finite‐difference diffusion models constrained by previously published temperature–time and Pb diffusion data suggest that these ages are best explained by rapid cooling from peak temperature conditions of ～800 °C at 14 Ma in the granulite‐bearing unit and ～650 °C at 12 Ma in the amphibolite‐bearing unit. The good fit between the model and analysed ages confirms the relatively high retention of Pb in rutile suggested by the experimental data. Titanite that grew during an exhumation‐related amphibolite facies overprint on an eclogite facies mineral assemblage from the neighbouring Jomolhari Massif yields a U–Pb lower intercept cooling age of 14.6 ± 1.2 Ma. Diffusion modelling suggests that this age is too old to be consistent with the temperature–time paths inferred for the rutile‐bearing samples. Instead, the titanite age suggests cooling from ～650 °C at an earlier time of 17–15 Ma, implying that the high‐grade rocks in the Jomolhari Massif experienced a different cooling history from the rest of the GHS in NW Bhutan. Together these data show that high‐grade rocks from three apparently different structural levels of the GHS in NW Bhutan experienced rapid cooling at >40 °C Ma?1 at varying times. The highest grade granulite facies rocks were exhumed from deeper structural levels that are not exposed, not preserved, or not yet recognized west of eastern Nepal. A progressive along‐strike change in tectonic regime, metamorphic history and/or exhumation mechanism across the orogen is implied by these thermochronologic data. 相似文献
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High‐pressure metamorphic evolution of eclogite and associated metapelite from the Chuacús complex (Guatemala Suture Zone): Constraints from phase equilibria modelling coupled with Lu‐Hf and U‐Pb geochronology 下载免费PDF全文
下载免费PDF全文 Roberto Maldonado Bodo Weber Fernando Ortega‐Gutiérrez Luigi A. Solari 《Journal of Metamorphic Geology》2018,36(1):95-124
As is common in suture zones, widespread high‐pressure rocks in the Caribbean region reached eclogite facies conditions close to ultrahigh‐pressure metamorphism. Besides eclogite lenses, abundant metapelitic rocks in the Chuacús complex (Guatemala Suture Zone) also preserve evidence for high‐pressure metamorphism. A comprehensive petrological and geochronological study was undertaken to constrain the tectonometamorphic evolution of eclogite and associated metapelite from this area in central Guatemala. The integration of field and petrological data allows the reconstruction of a previously unknown segment of the prograde P–T path and shows that these contrasting rock types share a common high‐pressure evolution. An early stage of high‐pressure/low‐temperature metamorphism at 18–20 kbar and 530–580°C is indicated by garnet core compositions as well as the nature and composition of mineral inclusions in garnet, including kyanite–jadeite–paragonite in an eclogite, and chloritoid–paragonite–rutile in a pelitic schist. Peak high‐pressure conditions are constrained at 23–25 kbar and 620–690°C by combining mineral assemblages, isopleth thermobarometry and Zr‐in‐rutile thermometry. A garnet/whole‐rock Lu‐Hf date of 101.8 ± 3.1 Ma in the kyanite‐bearing eclogite indicates the timing of final garnet growth at eclogite facies conditions, while a Lu‐Hf date of 95.5 ± 2.1 Ma in the pelitic schist reflects the average age of garnet growth spanning from an early eclogite facies evolution to a final amphibolite facies stage. Concordant U‐Pb LA‐ICP‐MS zircon data from the pelitic schist, in contrast, yield a mean age of 74.0 ± 0.5 Ma, which is equivalent to a U‐Pb monazite lower‐intercept age of 73.6 ± 2.0 Ma in the same sample, and comparable within errors with a less precise U‐Pb lower‐intercept age of 80 ± 13 Ma obtained in post‐eclogitic titanite from the kyanite‐bearing eclogite. These U‐Pb metamorphic ages are interpreted as dating an amphibolite facies overprint. Protolith U‐Pb zircon ages of 167.1 ± 4.2 Ma and 424.6 ± 5.0 Ma from two eclogite samples reveal that mafic precursors in the Chuacús complex originated in multiple tectonotemporal settings from the Silurian to Jurassic. The integration of petrological and geochronological data suggests that subduction of the continental margin of the North American plate (Chuacús complex) beneath the Greater Antilles arc occurred during an Albian‐Cenomanian pre‐collisional stage, and that a subsequent Campanian collisional stage is probably responsible of the amphibolite facies overprint and late syncollisional exhumation. 相似文献
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Abstract Concordant U–Pb ages of c. 530–510 Ma and c. 470–420 Ma on titanite from calcsilicate, orthogneiss and amphibolite rocks constrain the age of high‐T metamorphism in the Early Palaeozoic mobile belt at the western margin of Proterozoic Gondwana (Argentina, 26–29°S). The U–Pb ages document the time of titanite formation at high‐T conditions according to the stable mineral paragenesis and occurrence of titanite in the metamorphic fabric. The presence of migmatite at all sample sites indicates temperatures were > c. 650 °C. Titanite formed at similar metamorphic conditions at different times on the regional and on the outcrop scale. The titanite crystals preserved their U–Pb isotopic signatures and chemical composition under ongoing upper amphibolite to granulite facies temperatures. Different thermal peaks or deformations are only detected by the different U–Pb ages and not by changes in the mineral paragenesis or metamorphic fabric of the samples. The range of U–Pb ages, e.g. in the Ordovician and Silurian (c. 470, 460, 440, 430, 420 Ma), is interpreted as the effect polyphase deformation with deformation‐enhanced recrystallization of titanite and/or different thermal peaks during a long‐standing, geographically fixed, high‐T regime in the mid‐crust of a continental magmatic arc. A clear correlation of the different ages with distinct tectonic events, e.g. collision of terranes, is not possible based on the present knowledge of the region. 相似文献
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Recently, a huge ultrahigh‐pressure (UHP) metamorphic belt of oceanic‐type has been recognized in southwestern (SW) Tianshan, China. Petrological studies show that the UHP metamorphic rocks of SW Tianshan orogenic belt include mafic eclogites and blueschists, felsic garnet phengite schists, marbles and serpentinites. The well‐preserved coesite inclusions were commonly found in eclogites, garnet phengite schists and marbles. Ti‐clinohumite and Ti‐chondrodite have been identified in UHP metamorphic serpentinites. Based on the PT pseudosection calculation and combined U‐Pb zircon dating, the P‐T‐t path has been outlined as four stages: cold subduction to UHP conditions before ～320 Ma whose peak ultrahigh pressure is about 30 kbar at 500oC, heating decompression from the Pmax to the Tmax stage before 305 Ma whose peak temperature is about 600oC at 22kbar, then the early cold exhumation from amphibolite eclogite facies to epidote‐amphibolite facies metamorphism characterized by ITD PT path before 220 Ma and the last tectonic exhumation from epidote amphibolite facies to greenschist facies metamorphism. Combining with the syn‐subduction arc‐like 333‐326 Ma granitic rocks and 280‐260 Ma S‐type granites in the coeval low‐pressure and high‐temperature (LP‐HT) metamorphic belt, the tectonic evolution of Tianshan UHP metamorphic belt during late Cambrian to early Triassic has been proposed. 相似文献
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本文主要对沂水青龙峪出露的超镁铁质岩石和基性麻粒岩进行了锆石SHRIMP U-Pb定年研究。超镁铁质岩石以捕掳体形式存在于沂水杂岩中,不发育鬣刺结构,氧化物组成具有超镁铁质科马提岩的高MgO、富CaO、低SiO2、TiO2、K2O和Na2O含量特征;矿物组合以单斜辉石+橄榄石±斜方辉石+铬铁矿为主;变质矿物以角闪石+蛇纹石化为特征;该岩石以稀土元素总含量(∑REE)低、LREE/HREE=3.35～4.40及Ce和Eu负异常为特征。微量元素组成以Ba、Nb、Zr负异常和Nd、Sm正异常为特征。根据锆石SHRIMP U-Pb定年法对该超镁铁质岩石中捕获的早期岩浆结晶锆石和新生的变质锆石进行的研究,年龄值分别为2657～2702Ma和2551～2585Ma,表明该超镁铁质岩石形成年龄为2585～2657Ma。基性麻粒岩的氧化物组成特征表明其属高Mg的洋岛拉斑玄武岩,麻粒岩相——高角闪岩相变质作用与新太古代的深熔和岩浆侵入作用有关,矿物组合以紫苏辉石+单斜辉石±角闪石+斜长石±石榴子石为特征;晚期蚀变作用与辉长岩墙、辉绿岩脉及石英闪长岩买的侵入有关,矿物组合以滑石化+绢云母化+绿泥石化为特征;稀土元素组成以轻重稀土元素无分异和无Eu异常为特征;微量元素组成以Nb、Zr、P、Ti负异常和Sr、K正异常为特征;锆石SHRIMP U-Pb定年结果表明麻粒岩相——角闪岩相变质作用年龄为2498.4±7.6Ma,导致麻粒岩相——角闪岩相变质的深熔和岩浆结晶年龄为2551±24Ma,晚期蚀变作用的年龄分别为2231～2235Ma和1850±19Ma。 相似文献
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Laser ablation inductively coupled plasma mass spectrometry analyses of U–Pb isotopes and trace elements in zircon and titanite were carried out on epoxy mounts and thin sections for ultrahigh‐pressure (UHP) eclogite in association with paragneiss in the Dabie orogen. The results provide a direct link between metamorphic ages and temperatures during continental subduction‐zone metamorphism. Zircon U–Pb dating gives two groups of concordant ages at 242 ± 2 to 239 ± 5 Ma and 226 ± 2 to 224 ± 6 Ma, respectively. The Triassic zircon U–Pb ages are characterized by flat heavy rare earth element (HREE) patterns typical of metamorphic growth. Ti‐in‐zircon thermometry for the two generations of metamorphic zircon yields temperatures of 697 ± 27 to 721 ± 8 °C and 742 ± 19 to 778 ± 34 °C, respectively. We interpret that the first episode of zircon growth took place during subduction prior to the onset of UHP metamorphism, whereas the second episode in the stage of exhumation from UHP to HP eclogite facies regime. Thus, the continental subduction‐zone metamorphism of sedimentary protolith is temporally associated with two episodes of fluid activity, respectively, predating and postdating the UHP metamorphic phase. The significantly high Ti‐in‐zircon temperatures for the younger zircon at lower pressures indicate the initial ‘hot’ exhumation after the peak UHP metamorphism. There are two types of titanite. One exhibits light rare earth element (LREE) enrichment, steep MREE–HREE patterns and no Eu anomalies, and yields Zr‐in‐titanite temperatures of 551 to 605 °C at 0.5 GPa, and the other shows LREE depletion and flat MREE–HREE patterns, and gives Zr‐in‐titanite temperatures of 782–788 °C at 2.0 GPa. The former is amenable for U–Pb dating, yielding a discordia lower intercept age of 252 ± 3 Ma. Thus, the first type of titanite is interpreted to have grown in the absence of garnet and plagioclase and thus in the early stage of subduction. In contrast, the second one occurs as rims surrounding rutile cores and thus grew in the presence of garnet during the ‘hot’ exhumation. Therefore, there is multistage growth of zircon and titanite during the continental subduction‐zone metamorphism. The combined studies of chronometry and thermobarometry provide tight constraints on the P–T–t path of eclogites during the continental collision. It appears that the mid‐T/UHP eclogite facies zone would not only form by subduction of the continental crust in a P–T path slightly below the wet granite solidus, but also experience decompression heating during the initial exhumation. 相似文献
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北秦岭松树沟榴辉岩的确定及其地质意义 总被引：9，自引：8，他引：1
松树沟石榴石角闪岩(榴闪岩)呈透镜状产于松树沟超镁铁岩旁侧的斜长角闪岩中,一直以来被认为是形成于接触交代变质或麻粒岩相变质过程。详细岩相学及矿物元素分析,在榴闪岩的基质矿物、石榴石幔部及锆石包体中发现残留的绿辉石,而且石榴石也保存了明显的进变质主、微量元素成分环带,表明松树沟榴闪岩为榴辉岩退变质的产物,至少经历了从角闪岩相到榴辉岩相再到角闪岩相的三阶段顺时针PT演化过程。锆石定年结果得到榴辉岩的变质年龄为500±8Ma,原岩结晶时代为796±16Ma,与秦岭岩群北侧官坡超高压榴辉岩的变质年龄和原岩年龄完全一致,也与北秦岭区域高压-超高压变质时代和原岩的结晶时代一致。表明松树沟榴辉岩与北秦岭造山带已发现的高压-超高压变质岩石一起都应是古生代大陆深俯冲作用的结果,而松树沟超镁铁岩可能是俯冲的大陆板片在折返过程中携带的俯冲隧道中的交代地幔岩。 相似文献
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华北克拉通古元古代晚期地壳演化和荆山群形成时代制约——胶东地区变质中-基性侵入岩锆石SHRIMP U-Pb定年 总被引：15，自引：12，他引：3
胶东地区的荆山群呈近东西向环绕太古宙TTG花岗质片麻岩展布,主要由成熟度高的含石墨变泥砂质岩石、钙硅酸岩和大理岩组成,变质程度达高角闪岩相-麻粒岩相,具孔兹岩系性质。变质中-基性岩侵入到荆山群。它们的侵位时代对于探讨华北克拉通东部元古宙构造演化以及对荆山群沉积时代的制约,都有重要意义。锆石SHRIMP U-Pb定年结果表明,遭受低级变质的闪长岩(S0835)岩浆锆石年龄为1852±9Ma (MSWD=2.1),遭受中高级变质的辉长岩(S0816)变质锆石年龄为1865±11Ma (MSWD=0.76)。结合区域资料,可得出如下结论:(1)荆山群孔兹岩系形成于古元古代晚期(2.2~1.9Ga);(2)古元古代期间,胶东地区从挤压体制转入伸展体制的时间在1.87Ga之前。在华北克拉通中西部的恒山、大青山地区,存在1.97~1.92Ga辉长岩,在1.92~1.83Ga期间发生变质,与本文研究结果类似。这表明华北克拉通中-西部和东部具有类似的古元古代演化历史。 相似文献