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1.
To try to resolve the conflicts surrounding the influence of salts on frost weathering, chalk cubes were immersed, separately, in solutions of sodium chloride, sodium sulphate, and magnesium sulphate at concentrations of 5·5 per cent and 12·5 per cent, in a mixed solution of sodium chloride and sodium sulphate, and in distilled water. The cubes were subjected to six freeze-thaw cycles with temperatures ranging from either +15 to — 10°C or + 15 to — 30°C. The results confirm that frost weathering can be enhanced by the presence of certain salts, but the degree of enhancement depends both on the concentration and type of salt and on the intensity of the freeze-thaw regime. Some, but not all, of the results can be explained by the phase changes that occur during the freezing of the salt solutions.  相似文献   

2.
Preliminary results from a continuing series of laboratory experiments designed to examine the combined effects of salt and frost weathering indicate that some salts greatly enhance the breakdown of rocks by frost. Samples of Ardingly Sandstone from southeast England were soaked in saturated solutions of sodium chloride or sodium sulphate and subjected to alternating cycles of freezing and thawing. Rapid disintegration of the sandstone occurred within twenty cycles, in each of the salt solutions. In contrast, samples subjected to freezing and thawing in deionized water suffered very little damage unless they were saturated under vacuum. When samples were subjected to twenty cycles of wetting and drying at temperatures above 0°C, those soaked in deionised water or sodium chloride suffered no appreciable damage but those soaked in sodium sulphate rapidly disintegrated. Tentative explanations of these results are offered. The enhancement of frost weathering by salt appears to have been overlooked by many writers yet it is likely to be an important geomorphological process in those areas of mid and high latitudes where rocks are saturated with sodium salts.  相似文献   

3.
A laboratory study has been used to investigate relationships between salts and contour scaling—a weathering feature commonly observed on rock surfaces in salt-rich environments. Surface disaggregation and essentially surface-parallel cracks were produced in sandstone blocks using 10 per cent solutions of sodium sulphate and magnesium sulphate applied daily to single exposed surfaces for sixty days. A control block soaked once in saturated magnesium sulphate and subsequently wetted daily with distilled water showed extensive surface disaggregation, but no cracking. Both surface disaggregation and subsurface cracking were associated with relative concentrations of microcrystalline salt. A tentative model of contour scaling is proposed, which involves linking together potential cracks by salt-induced fracturing of intervening, crack-stopping grains. Further control blocks treated respectively with 10 per cent and saturated sodium chloride showed no evidence of subsurface cracking and only limited surface disaggregation of the ‘saturated’ block.  相似文献   

4.
Five granites from NW Spain were subjected to two salt‐spray weathering tests under controlled atmospheric conditions. Granite samples were exposed to a sodium chloride solution in the first test and to a complex solution (sea water) in the second. Subsequent examination of the rocks by light and petrographic microscopy clearly demonstrated the development of different weathering morphologies in each test. The distribution of dissolved ions in samples taken at different depths from the weathered surfaces at the end of the experiments, and the changes in weight of the samples during the tests, also differed. In our opinion, these results were determined by the nature of the solution used; although sodium chloride is the predominant salt in sea water, the presence of other ions modifies its solubility, thereby varying the dynamics of mobility and precipitation and thus the weathering morphology that develops. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

5.
This research characterizes the weathering of natural building stone using an unsteady‐state portable probe permeameter. Variations between the permeability properties of fresh rock and the same rocks after the early stages of a salt weathering simulation are used to examine the effects of salt accumulation on spatial variations in surface rock permeability properties in two limestones from Spain. The Fraga and Tudela limestones are from the Ebro basin and are of Miocene age. Both stone types figure largely in the architectural heritage of Spain and, in common with many other building limestones, they are prone to physical damage from salt crystallization in pore spaces. To examine feedbacks associated with salt accumulation during the early stages of this weathering process, samples of the two stone types were subjected to simulated salt weathering under laboratory conditions using magnesium sulphate and sodium chloride at concentrations of 5% and 15%. Permeability mapping and statistical analysis (aspatial statistics and spatial prediction) before and after salt accumulation are used to assess changes in the spatial variability of permeability and to correlate these changes with salt movement, porosity change, potential rock deterioration and textural characteristics. Statistical analyses of small‐scale permeability measurements are used to evaluate the drivers for decay and hence aid the prediction of the weathering behaviour of the two limestones. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

6.
Micro- and macroscale experiments which document the dynamics of salt damage to porous stone have yielded data which expose weaknesses in earlier interpretations. Previously unexplained differences are found in crystal morphology, crystallization patterns, kinetics and substrate damage when comparing the growth of mirabilite (Na2SO4. 10H2O) and thenardite (Na2SO4) versus halite (NaCl). The crystallization pattern of sodium sulphate was strongly affected by relative humidity (RH), while a lesser RH effect was observed for sodium chloride. Macroscale experiments confirmed that mirabilite (crystallizing at RH > 50 per cent) and thenardite (crystallizing at RH < 50 per cent) tend to form subflorescence in highly localized areas under conditions of constant RH and temperature. This crystallization pattern was more damaging than that of halite, since halite tended to grow as efflorescence or by filling the smallest pores of the stone in a homogeneous fashion, a result which contradicts Wellman and Wilson's theoretical model of salt damage. Low RH promoted rapid evaporation of saline solutions and higher supersaturation levels, resulting in the greatest damage to the stone in the case of both sodium sulphate and sodium chloride crystallization. At any particular crystallization condition, sodium chloride tended to reach lower supersaturation levels (resulting in the crystallization of isometric crystals) and created negligible damage, while sodium sulphate reached higher supersaturation ratios (resulting in non-equilibrium crystal shapes), resulting in significant damage. ESEM showed no damage from sodium sulphate due to hydration. Instead, after water condensation on thenardite crystals, rapid dissolution followed by precipitation of mirabilite took place, resulting in stone damage by means of crystallization pressure generation. It is concluded that salt damage due to crystallization pressure appears to be largely a function of solution supersaturation ratio and location of crystallization. These key factors are related to solution properties and evaporation rates, which are constrained by solution composition, environmental conditions, substrate properties, and salt crystallization growth patterns. When combined with a critical review of salt damage literature, these experiments allow the development of a model which explains variations in damage related to combinations of different salts, substrates and environmental conditions. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

7.
Bedding‐parallel tafoni are well developed over much of the surface of the Tunnel Spring Tuff (Oligocene) exposed in 300‐m‐high Crystal Peak, an inselberg. The Tunnel Spring Tuff is a crudely stratified, non‐welded rhyolite ash‐flow tuff with > 30 per cent porosity. Clasts of Palaeozoic dolomite, limestone and quartzite make up 10 per cent of the tuff. The tafoni are remarkable because of their size (up to 20 m wide but rarely wider than 4 m), shape of the openings (spherical, arch‐like or crescent‐shaped) and abundance (up to 50 per cent of an outcrop face). They are actively forming today. Calcite is abundant (10 to 40 per cent by weight) in tafoni as an efflorescence in spalling flakes of tuff on their roofs and walls. Halite and gypsum generally make up less than 0·01 per cent of the efflorescence. The absence of corroded quartz and feldspar grains in spall fragments indicates that chemical weathering is unimportant in development of the tafoni. Calcite, aragonite, halite and gypsum dust from modern salt pans less than 20 km from Crystal Peak are potential sources of salt in the tuff, but the prevailing winds are in the wrong direction for significant amounts of these evaporite minerals to reach the inselberg. Calcite is the only evaporite mineral present in the tafoni in more than trace amounts, and this mineral is readily available within the tuff itself as a result of rock weathering. We propose that meteoric water containing carbonic acid infiltrates the tuff, dissolves carbonate clasts, and migrates to the steep flanks (>20°) of the peak through abundant megapores and micropores. There it evaporates and precipitates calcite. Crystallization pressure spalls off grains and sheets as the physical manifestation of salt weathering. The quasi‐uniform spacing of tafoni suggests that a self‐organization process is active in the water flow. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

8.
Discussions regarding weathering in cold environments generally centre on mechanical processes and on the freeze–thaw mechanism in particular. Despite the almost ubiquitous assumption of freeze–thaw weathering, unequivocal proof of interstitial rock water actually freezing and thawing is singularly lacking. Equally, many studies have used the crossing of 0 °C, or values close to that, as the basis for determining the number of ‘freeze–thaw events’. In order to assess the weathering regime at a site in northern Canada, temperatures were collected at the surface, 1 cm and 3 cm depth for sets of paving bricks, with exposures both vertical and at 45°, orientated to the four cardinal directions. Temperature data were collected at 1 min intervals for 1 year. These data provide unequivocal proof for the occurrence of the freezing and thawing of water on and within the rock (freeze–thaw events). The freeze event is evidenced by the exotherm associated with the release of latent heat as the water actually freezes. This is thought to be the ?rst record of such events from a ?eld situation. More signi?cantly, it was found that the temperature at which freezing occurred varied signi?cantly through the year and that on occasion the 1 cm depth froze prior to the rock surface. The change in freeze temperature is thought to be due to the chemical weathering of the material (coupled with on‐going salt inputs via the melting of snowfall), which, it is shown, could occur throughout the winter despite air temperatures down to ?30 °C. This ?nding regarding chemical weathering is also considered to be highly signi?cant. A number of thermal stress events were also recorded, suggesting that rock weathering in cold regions is a synergistic combination of various chemical and mechanical weathering mechanisms. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

9.
Reduced major axis analysis is used to describe monthly temperature averages for daily maxima, minima, means and ranges at a sequence of bedrock microenvironments in the alpine zone of the Colorado Front Range. Seven thermistors buried at 1 cm in bedrock provide comparative data on easterly, southerly and westerly aspects, and also upon the impact of snow accumulation (?0.5m to ≥4.0m deep) against an east-facing rock wall. Intersite temperatures commonly differ by less than 5°C and, rarely, by more than 10°C. The freezing intensity of freeze-thaw cycles occurring within the confines of a seasonal snow patch rarely dropped to ?5°C, while at snowfree, vertical faces freezing dropped to ?5°C quite commonly. Comparison with laboratory established criteria for effective freeze-thaw weathering (abundant moisture and freezing to at least ?5°C) suggests that moisture rich microsites lack adequate freezing intensity, while adequately frozen sites lack moisture. Available data suggest that the overlap between freeze-thaw and hydration weathering requires careful re-evaluation.  相似文献   

10.
Rock moisture during freeze–thaw events is a key factor for frost weathering. Data on moisture levels of natural rockwalls are scarce and difficult to obtain. To close this gap, we can benefit from the extensive knowledge of moisture‐related phenomena in building materials, which is incorporated into simulation software, for example the WUFI® package of the Fraunhofer Institute of Building Physics. In this paper we applied and adapted this type of simulation to natural rockwalls to gain new insights on which moisture‐related weathering mechanisms may be important under which conditions. We collected the required input data on physical rock properties and local climate for two study areas in the eastern European Alps with different elevation [Sonnblick, 3106 m above sea level (a.s.l.) and Johnsbach, 700 m a.s.l.] and different lithologies (gneiss and dolomite, respectively). From this data, moisture profiles with depth and fluctuations in the course of a typical year were calculated. The results were cross‐checked with different thermal conditions for frost weathering reported in the literature (volumetric expansion and ice segregation theories). The analyses show that in both study areas the thresholds for frost cracking by volumetric expansion of ice (90% pore saturation, temperature < ?1 °C) are hardly ever reached (in one year only 0.07% of the time in Johnsbach and 0.4% at Sonnblick, mostly in north‐exposed walls). The preconditions for weathering by ice segregation (?3 to ?8 °C, > 60% saturation) prevail over much longer periods; the time spent within this ‘frost cracking window‘ is also higher for north‐facing sites. The influence of current climate warming will reduce effective frost events towards 2100; however the increase of liquid precipitation and rock moisture will promote weathering processes like ice segregation at least at the Sonnblick site. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

11.
‘The wick effect’ is the upward migration of saline solutions into rocks and their subsequent crystallization. Lower Carboniferous sandstone blocks of rectangular shape have been subjected to this process in the laboratory using a range of salt types, a range of salt concentrations, and various mixtures of salts. Some treatments produced severe disintegration, notably sodium carbonate and a mixture of sodium carbonate with magnesium sulphate, whereas other salts (including sodium chloride and gypsum) were much less effective. The debris produced by this experimental salt weathering included appreciable quantities of silt-sized material, which were analysed with a laser granulometer. Such material could provide a source for desert loess.  相似文献   

12.
In this paper we quantitatively test the hypothesis that soil freeze–thaw (FT) processes significantly increase the potential for upland hillslope erosion during run‐off events that follow thaw. We selected a highly frost‐susceptible silt to obtain an upper bound on FT effects, and completed three series of six experiments each to quantify differences in soil erosion and rill development in a bare soil following a single FT cycle. Each series represented a specific soil moisture range: 16–18 per cent, 27–30 per cent and 37–40 per cent by volume, with nominal flow rates of 0·4, 1·2 and 2·4 L/min and slopes of 8° and 15°. Each experiment used two identical soil bins: one a control (C) that remained unfrozen, and another that was frozen and thawed once. Standard soil characterization tests did not detect significant differences between the FT and C bins. We measured cross‐sectional geometry of an imposed straight rectangular rill before each experiment, sediment load during and rill cross‐sections after. Changes in cross section provided detailed measures of erosion at specific locations, while sediment load from time series run‐off samples integrated the rill erosion. Several parameters, including average maximum rill width, average maximum rill depth, rill cross‐section depth measures and sediment load, all followed similar trends. Each was greater in the FT than in the C, with values that generally increased with slope and flow. However, soil moisture was the only parameter that affected the FT/C ratios. Average sediment load grouped by soil moisture provided FT/C ratios of 2·4, 3·0 and 5·0 for low, mid and high moisture, respectively. In contrast, a ‘dry’ experiment at 4–5 per cent soil moisture had FT/C of 1·02 for sediment load. These results show a dramatic increase with soil moisture in the rate and quantity of bare soil eroded due to the FT cycle. As both FT and C results were highly sensitive to initial conditions, minimum differences in soil weight, bulk density and soil moisture through each series of experiments were required to achieve consistent results, indicating that rill erosion may be chaotic. Published in 2005 by John Wiley & Sons, Ltd.  相似文献   

13.
A laboratory simulation of salt weathering was used to ascertain the effects of sodium sulphate and sodium carbonate under ‘Negev’ conditions using a single immersion technique. Three main points were addressed: what are the grain size and textural characteristics of the debris liberated from limestones and a sandstone, what do scanning electron microscope observations of the weathered samples tell us about the decay processes involved, and how does the rate of debris liberation change during the course of 100 cycles? The grain size characteristics of the liberated debris tended to be multimodal and were related to the original petrological characteristics of the rock. Large amounts of fines were produced which are believed to be analogous to the ‘rock flour’ of arid areas. Blistering was also observed. Scanning electron microscope analysis revealed differences in the style of attack for different rock types and salt treatments, and revealed the pattern of salt crystallization in pores and the nature of cracking. The rate of debris liberation tended to decline or remain constant through time. The reasons for this remain obscure, but it is evident that diurnal cycles of temperature and humidity change can cause continuing rock weathering long after the initial input of salt to the rock has taken place.  相似文献   

14.
Aerial and sub‐aerial climatic data were collected from a station at 1920 m a.s.l. in the Injisuthi region of the South African Drakensberg. Sensors monitored air temperature, soil surface and rock surface temperature, for two rock types, over the summer and winter of 2001/2002. Rainfall was measured from the summer of 2001 to January 2004. These are the first rock and soil surface‐climate data to be collected for an exposed site at this altitude in the area. Rainfall over the two calendar years 2002 and 2003 was found to be below estimates for the region, but patterns imply numerous rock wetting and drying cycles in summer. At the site, air, rock and soil temperatures differ considerably on a diurnal basis with respect to both absolute temperature and daily ranges. Mean rock daily ranges, as conducive to possible thermal fatigue, are found to be similar in the summer and winter periods. Of the two rock types monitored, the darker coloured basalt attained higher maximum and marginally lower minimum temperatures than the sandstone. Soil frost did not occur at 2·5 cm depth, but rock did reach below ?6 °C in winter. Both rock types maintain relatively high rock temperatures in winter (exceeding 25 °C), thus chemical weathering is probably only moisture restricted during this dry period. Findings highlight the importance of directly monitoring rock temperature when attempting to discern the rock weathering environment. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

15.
Sections up to 3·5 m deep cut through the upper rectilinear segment of relict, vegetated talus slopes at the foot of the Trotternish escarpment reveal stacked debris-flow deposits intercalated with occasional slopewash horizons and buried organic soils. Radiocarbon dating of buried soil horizons indicates that reworking of sediment by debris flows predates 5·9–5·6 Cal ka BP , and has been intermittently active throughout the late Holocene. Particle size analyses of 18 bulk samples from these units indicates that c. 27–30 per cent of the talus deposit is composed of fine (<2 mm) sediment. Sedimentological comparison with tills excludes a glacigenic origin for the talus debris, and the angularity of constituent clasts suggests that in situ weathering has been insignificant in generating fine material. We conclude that the fine sediment within the talus is derived primarily by granular weathering of the rockwall, with syndepositional accumulation of both fine and coarse debris, implying that c. 27–30 per cent of rockwall retreat since deglaciation reflects granular weathering rather than rockfall. The abundance of fines within the talus deposits is inferred to have been of critical importance in facilitating build-up of porewater pressures during rainstorms, leading to episodic failure and flow of debris on the upper parts of the slope. A wider implication of these findings is that the mechanical properties of talus slopes cannot be regarded as those of free-draining accumulations of coarse clasts, and that models that treat talus slopes as such have limited value in explaining their form and evolution. Our findings lend support to models that envisage the upper straight slope on talus accumulations as the product of mass-transport as well as rockfall, and indicate that episodic debris flow has been the primary agent of mass-transport at this site. © 1998 John Wiley & Sons, Ltd.  相似文献   

16.
Field experiments were carried out over a five year period with the aim of understanding contemporary weathering and erosional environments in the Sør Rondane Mountains, an Antarctic cold desert region. These include observations of (1) scaling from rockwalls, (2) disintegration of tuff blocks with or without saline solutions, and (3) abrasion of artificial walls by wind. Monitoring was also made of rock surface temperature and wind speed. Despite frequent temperature oscillations across 0°C, rock scaling due to frost action was generally very slow because of low moisture content in the rockwalls. Exposure to the cold, dry climate led to the rapid disintegration of porous tuff blocks including soluble salts like halite and thenardite. This indicates that rates of weathering are increased greatly with the accumulation of such salts in the bedrock. Although gypsum did not cause any visible damage over four years, its widespread occurrence in heavily damaged rocks demonstrates that increasing gypsum contents may also intensify rock breakdown. The snow-laden katabatic wind resulted in rapid wearing of the windward face of an asbestos board with the peak erosion at 30–40 cm above the ground. Nonetheless, the landforms expected from the unidirectional wind characteristics are by no means common features because of lack of abrasive materials, such as snow and sand particles. These experiments suggest that frost weathering and wind erosion are only locally effective where plenty of moisture or an abrasive material is available, whilst salt weathering and removal of the waste by wind play a major role in constructing erosional landforms over the mountains.  相似文献   

17.
Fire has long been recognized as an agent of rock weathering. Our understanding of the impact of fire on stone comes either from early anecdotal evidence, or from more recent laboratory simulation studies, using furnaces to simulate the effects of fire. This paper suggests that knowledge derived from simulated heating experiments is based on the pre‐conceptions of the experiment designer – when using a furnace to simulate fire, the operator decides on the maximum temperature and the duration of the experiment. These are key factors in determining the response of the stone to fire, and if these are removed from real‐world observations then knowledge based on these simulations must be questioned. To explore the differences between heating sandstone in a furnace and a real fire, sample blocks of Peakmoor Sandstone were subjected to different stress histories in combination (lime rendering and removal, furnace heating or fire, frost and salt weathering). Block response to furnace heating and fire is discussed, with emphasis placed on the non‐uniformity of the fire and of block response to fire in contrast to the uniform response to surface heating in a furnace. Subsequent response to salt weathering (by a 10% solution of sodium chloride and magnesium sulphate) was then monitored by weight loss. Blocks that had experienced fire showed a more unpredictable response to salt weathering than those that had undergone furnace heating – spalling of corners and rapid catastrophic weight loss were evidenced in blocks that had been subjected to fire, after periods of relative quiescence. An important physical side‐effect of the fire was soot accumulation, which created a waxy, relatively impermeable layer on some blocks. This layer repelled water and hindered salt ingress, but eventually detached when salt, able to enter the substrate through more permeable areas, concentrated and crystallized behind it, resulting in rapid weight loss and accelerated decay. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

18.
Two groups of fresh crushed Brazilian quartz grains (0.4–0.6 mm) were placed in 10 ml of various saturated salt solutions (sodium sulphate, sodium chloride, magnesium sulphate, sodium carbonate, and sodium carbonate and soil). One group was placed in an environmental cabinet programmed to simulate summer diurnal temperature and relative humidity values recorded in Wheeler Valley, a dry valley in southern Victoria Land, Antarctica. The other group was allowed to remain at normal laboratory conditions. Quartz grains from both groups were removed at pre-selected intervals for examination using the scanning electron microscope. After 50 hours chemical surface textures were formed on the quartz grains in all but the sodium sulphate solution. At the 140 hour interval all the salt solutions used were producing chemical surface textures on the quartz grains. This paper demonstrates that chemical surface textures can be produced on quartz grain surfaces by saturated salt solutions in a short period of time and may prove to be representative of chemical surface textures produced in a saturated saline environment.  相似文献   

19.
Rock glaciers, a feature associated with at least discontinuous permafrost, provide important topoclimatic information. Active and inactive rock glaciers can be used to model current permafrost distribution. Relict rock glacier locations provide paleoclimatic information to infer past conditions. Future warmer climates could cause permafrost zones to shrink and initiate slope instability hazards such as debris flows or rockslides, thus modeling change remains imperative. This research examines potential past and future permafrost distribution in the Colorado Front Range by calibrating an existing permafrost model using a standard adiabatic rate for mountains (0·5 °C per 100 m) for a 4 °C range of cooler and warmer temperatures. According to the model, permafrost currently covers about 12 per cent (326·1 km2) of the entire study area (2721·5 km2). In a 4 °C cooler climate 73·7 per cent (2004·4 km2) of the study area could be covered by permafrost, whereas in a 4°C warmer climate almost no permafrost would be found. Permafrost would be reduced severely by 93·9 per cent (a loss of 306·2 km2) in a 2·0 °C warmer climate; however, permafrost will likely respond slowly to change. Relict rock glacier distribution indicates that mean annual air temperature (MAAT) was once at least some 3·0 to 4·0 °C cooler during the Pleistocene, with permafrost extending some 600–700 m lower than today. The model is effective at identifying temperature sensitive areas for future monitoring; however, other feedback mechanisms such as precipitation are neglected. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

20.
A laboratory salt weathering experiment was performed using five salts to attack eight types of rocks to determine the relative significance of rock durability and salt aggressivity to salt crystallization damage. The influence of individual rock properties on the salt susceptibility of the rocks was also evaluated. To study the relation between pore characteristics, salt uptake, and damage, the pre‐ and post‐experiment pore size distributions of the rocks were also examined. It is observed that both salt type and rock properties influenced the damage pattern. The durability ranking of the rocks became significantly altered with the salt type while the variation in salt efficacy ranking with rock type was less pronounced. Of the five salts used, sodium chloride and aluminium sulfate were invariably ineffective with all rock types while sodium carbonate, sodium sulfate, and magnesium sulfate, were markedly more effective in damaging most types of rock used. Of the rock properties investigated, the microporosity (of pores smaller than 0·05 or 0·1 µm) showed the most significant influence on deterioration of the rocks associated with salt crystallization, whereas microporosity of pores smaller than 5 µm played a more important role in salt uptake. Pore size distribution was thus the key factor controlling salt uptake and damage. Rocks with a large number of pores (<5 µm) and a high proportion of pores (<0·05 or 0·1 µm) were particularly susceptible to salt crystallization damage. However, anomalies arose that could not be explained in terms of rock properties or salt efficacy alone. Overall, the relative influences of salt type/efficacy and rock type/properties on salt damage propensity were not clear enough to draw a reasonable conclusion. Salt crystallization damage appears to be influenced by the individual interactions between salts and rocks, which could explain the anomalous results. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

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