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1.
Although the ingestion of vanadium (V) in drinking water may have possible adverse health effects, there have been relatively few studies of V in groundwater. Given the importance of groundwater as a source of drinking water in many areas of the world, this study examines the potential sources and geochemical processes that control the distribution of V in groundwater on a regional scale. Potential sources of V to groundwater include dissolution of V rich rocks, and waste streams from industrial processes. Geochemical processes such as adsorption/desorption, precipitation/dissolution, and chemical transformations control V concentrations in groundwater. Based on thermodynamic data and laboratory studies, V concentrations are expected to be highest in samples collected from oxic and alkaline groundwater. However, the extent to which thermodynamic data and laboratory results apply to the actual distribution of V in groundwater is not well understood. More than 8400 groundwater samples collected in California were used in this study. Of these samples, high (≥50 µg/L) and moderate (25 to 49 µg/L) V concentrations were most frequently detected in regions where both source rock and favorable geochemical conditions occurred. The distribution of V concentrations in groundwater samples suggests that significant sources of V are mafic and andesitic rock. Anthropogenic activities do not appear to be a significant contributor of V to groundwater in this study. High V concentrations in groundwater samples analyzed in this study were almost always associated with oxic and alkaline groundwater conditions, which is consistent with predictions based on thermodynamic data. 相似文献
2.
GEORG MATTHESS 《水文科学杂志》2013,58(4):617-628
Abstract The changes in groundwater quality that result from man's activities are reviewed. This paper considers the various geochemical reactions, the biochemical processes and the physical processes that take place as well as the sources of pollution. Suggestions are made for future research and practical guidance given for avoidance of pollution of groundwater or minimizing its effects. 相似文献
3.
Generalized observational data on groundwater chemistry and the results of modeling geochemical processes allowed us to establish that the formation of high-carbonate alkaline waters follows two ways, i.e., calcium and soda. It is shown that the formation of alkaline waters in semiarid and arid zones can be facilitated by acid atmospheric precipitation, which forms the concentration of Ca in groundwater sufficiently high to initiate ion exchange processes resulting in the formation of H2CO3–Na waters. Ion exchange is shown to be a boundary process, which facilitates the transition from calcium to soda way of groundwater metamorphization with subsequent increase in the carbonate content and alkalinity of groundwater. 相似文献
4.
Annadasankar Roy Hemant Mohokar Diksha Pant Uday Kumar Sinha G. N. Mendhekar 《水文科学杂志》2020,65(6):951-968
ABSTRACTMultivariate statistical analysis and inverse geochemical modelling techniques were employed to deduce the mechanism of groundwater evolution in the hard-rock terrain of Telangana, South India. Q-mode hierarchical cluster analysis (HCA) and principal component analysis (PCA) were used to extract the hydrogeochemical characteristics and classify the groundwater samples into three principal groups. Use of thermodynamic stability diagrams and inverse geochemical modelling in PHREEQC identified the chemical reactions controlling hydrogeochemistry of each of the groups obtained from statistical analysis. The model output showed that a few phases are governing the water chemistry in this area and the geochemical reactions responsible for evolution of groundwater chemistry along the flow path are (i) dissolution of evaporite minerals (dolomite, halite); (ii) dissolution of primary silicate minerals (albite, anorthite, K-feldspar, biotite); (iii) precipitation of secondary silicate minerals (kaolinite, quartz, gibbsite, Ca-montmorillonite) along with anhydrite and calcite; and (iv) reverse ion exchange processes. 相似文献
5.
Geochemical processes involving redox reactions and leading to either formation or transformation of geochemical barriers may be largely induced or enhanced by microbial activity. The microbial reduction of uranium is studied as a strategy for rehabilitation of uranium-containing groundwater. The bioremediation mechanism converts dissolved uranium(VI) into low-solubility U(IV). The processes involving dissimilatory reducing bacteria, which facilitate the reduction and retention of U(VI) in soils and rocks, are considered. The diversity of microorganisms involved in anaerobic reduction of uranium is shown. The geochemical conditions that may affect the rate of microbial reduction of U(VI) are specified, i.e., the presence of nitrate ions, phosphate ions, calcium ions, and iron oxides. The mechanisms of their action are examined. Geochemical barriers with the participation of microorganisms are proposed for the rehabilitation of groundwater with uranium removed from groundwater and deposited locally as a result of microbial reduction of U(VI). 相似文献
6.
Kinmen is located in the south‐west of Mainland China and mainly has two islands, Large Kinmen and Leiyu. Residents in Kinmen have drunk groundwater over several decades. This work characterized the quality of groundwater in Kinmen using factor analysis (FA), cluster analysis (CA) and geochemical simulation. The factor scores were plotted spatially to illustrate the groundwater quality and were used to discuss the grouped relationship using CA. Salinization, redox and organic matter factors are identified from 17 hydrochemical measurements in 18 wells. Acidic and oxidizing groundwater with nitrate‐N pollution is distributed mainly in the west of Large Kinmen. Saline groundwater is distributed to the north‐east of Large Kinmen and in the south of Leiyu. Groundwater with organic matter is present throughout Leiyu. Five groups of the groundwater quality divided by CA can be interpreted according to one to three factors. The grouped characteristics of the groundwater quality help the local government and industries to plan the use and protection of groundwater resources. Furthermore, a geochemical simulation was used to demonstrate the formation processes of the acidic and oxidizing groundwater properties in granitic sediments. A large amount of the precipitation of the kaolinite and magnetite releases concentrations of hydrogen ion and raises the redox potential in the aquifers. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
7.
Synthesis of empirical natural materials and thermodynamic computer modeling of geochemical processes in water–rock systems at different boundary conditions (solid-to-liquid ratio,
, T) were used to determine the genetic causes of the inverse geochemical zonality that forms in deep horizons of oil-and-gas bearing structures. The geochemical pattern of inversion water was found to form chiefly because of changes in the Eh–pH-conditions of the original groundwater under the effect of organic components of rocks and because of an increase in temperature to 100°C at low values of solid-to-liquid ratios and at
no higher than 10–2 bar. 相似文献
8.
The hydrogeochemistry of shallow groundwater has been characterized in the Allt a'Mharcaidh catchment in the Scottish Cairngorms in order to: (i) assess the spatial and temporal variation in groundwater chemistry; (ii) identify the hydrogeochemical processes regulating its evolution; and (iii) examine the influence of groundwater on the quality and quantity of stream flow. Shallow groundwater in superficial drift deposits is circumneutral (pH∽7·1) and base cation concentrations are enriched compared with precipitation and drainage water from overlying podzolic soils. Modelling with NETPATH suggests that the dominant geochemical processes that account for this are the dissolution of plagioclase, K-feldspar and biotite. Groundwater emerging as springs from weathered granite underlying high altitude (>900 m) alpine soils shows similar characteristics, though weathering rates are lower, probably as a result of reduced residence times and lower temperatures. Chemical hydrograph separation techniques using acid neutralizing capacity (ANC) and Si as tracers show that groundwater is the dominant source of baseflow in the catchment and also buffers the chemistry of stream water at high flows: groundwater may account for as much as 50–60% of annual runoff in the catchment. Climate and land use in the Cairngorms are vulnerable to future changes, which may have major implications for hydrogeological processes in the area. © 1998 John Wiley & Sons, Ltd. 相似文献
9.
《水文科学杂志》2013,58(6):1149-1162
AbstractGroundwater quality problems have emerged in many geographical areas due to natural environmental processes and human intervention in the geosystems. Hydrogeochemical appraisal of fluoride contaminated groundwater in Mehsana District, Gujarat State, India is carried out by means of groundwater quality investigations together with X-ray diffraction analysis of soil samples in the delineated high fluoride areas. Results show that fluoride has negative relationships with calcium, whereas relationships with sodium, alkalinity and sulphate are positive. Results obtained from aqueous speciation modelling using PHREEQC reveal that the groundwater is undersaturated with fluorite and oversaturated with calcite. The factor analysis indicates that sodium plus potassium bicarbonate groundwater have high factor loading for fluoride, whereas that for calcium chloride and magnesium chloride groundwater is low. The plausible geochemical reactions in the study area are precipitation of calcite and dissolution of dolomite, carbon dioxide and sulphate minerals with ion exchange. 相似文献
10.
Jie Ma Hui Liu Lei Tong Yan Wang Rong Chen Shan Liu Lei Zhao Zhimin Li Liegang Cai 《水文研究》2019,33(14):1993-2005
This study explores linkages between the microbial composition and hydrochemical variables of pristine groundwater to identify active redox conditions and processes. Two confined aquifers underlying the city of Qianjiang in the Jianghan Plain in China were selected for this study, having different recharge sources and strong hydrochemical gradients. Typical methods for establishing redox processes according to threshold concentration criteria for geochemical parameters suggest iron or sulphate reduction processes. High‐throughput 16S rRNA sequencing was used to obtain diversity and taxonomic information on microbial communities. Instead of revealing iron‐ and sulphate‐reducing bacteria, salt‐ and alkali‐tolerant bacteria, such as the phylum Firmicutes and the class Gammaproteobacteria, and in particular, the family Bacillaceae, were dominant in the downstream groundwater of the first aquifer that had high ion concentrations caused by the dissolution of calcite and dolomite; meanwhile, the heterotrophic microaerophilic families Comamonadaceae and Rhodocyclaceae prevailed in the upstream groundwater of the first aquifer. Sulphate‐reducing bacteria were extremely abundant in the upstream groundwater of the second aquifer, as the SO42? concentration was especially high. Methanogens and methanotrophs were predominant in the downstream groundwater of the second aquifer even though the concentration of SO42? was much higher than 0.5 mg L?1. The microbial communities, together with the geochemical parameters, indicated that the upstream region of the first aquifer was suboxic, that Fe(III) and Mn(IV) reductions were not the main redox processes in the downstream groundwater of the first aquifer with high Fe and Mn concentrations, and that the redox processes in the upstream and downstream regions of the second confined aquifer were SO42? reduction and methanogenesis, respectively. This study expands understanding of the linkages between microbial communities and hydrogeochemistry in pristine groundwaters and provides more evidence for identifying active redox conditions and processes. 相似文献
11.
Pankaj Kumar 《Water Resources》2012,39(5):601-609
In order to delineate geochemical processes and its relation with groundwater quality evolution, hydrochemical and isotopic analysis were carried out in coastal groundwater of Saijo plain, western Japan. From analytical results, even within a small distance from the coast; ionic concentration of water samples varies a lot which infers non-homogenous and patchy distribution of different aquifer system (complex geology). From stable isotopic results, it was found that most of sample points plotted near the local meteoric water line (LMWL) i.e. origin of ground water is meteoric in principle; however point away from the LMWL might favors exchange with rock minerals. 相似文献
12.
Pankaj Kumar 《Water Resources》2013,40(2):208-216
In order to delineate geochemical processes and its relation with groundwater quality evolution, hydrochemical and isotopic analysis were carried out in coastal groundwater of Saijo plain, western Japan. From analytical results, even within a small distance from the coast; ionic concentration of water samples varies a lot which infers non-homogenous and patchy distribution of different aquifer system (complex geology). From stable isotopic results, it was found that most of sample points plotted near the local meteoric water line (LMWL) i.e. origin of ground water is meteoric in principle; however point away from the LMWL might favors exchange with rock minerals. 相似文献
13.
Hydrogeochemistry and factor analysis were conducted together to assess the distribution and the major geochemical processes in fluoride-contaminated shallow groundwater in the Yuncheng Basin.Spatially,fluoride concentration was low(<1.5 mg/L)in the southern piedmont plain,medium(<4 mg/L)in the central basin,and high(up to 14.1 mg/L)in Kaolao lowland areas in shallow aquifers.A three-factor principal component analysis model explained over 75.1%of the total variance.Sediment weathering leaching and evapotranspiration were recognized as the first primary hydrochemical processes response for the groundwater chemistry and explained the largest portion(42.1%)of the total variance.Factor two reflects the negative influence of human activities,with a positive loading of NO3^-and HCO3^-,and negative loading of well depth.Fluoride-bearing mineral dissolution and alkaline condition was ranked as the third factors responding for groundwater chemistry and explained 11.2%of the total variance. 相似文献
14.
Stable isotopic and geochemical identification of groundwater evolution and recharge sources in the arid Shule River Basin of Northwestern China 总被引：5，自引：0，他引：5 
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下载免费PDF全文 Xiaoyan Guo Qi Feng Wei Liu Zongxing Li Xiaohu Wen Jianhua Si Haiyang Xi Rui Guo Bing Jia 《水文研究》2015,29(22):4703-4718
Stable isotopic (δDVSMOW and δ18OVSMOW) and geochemical signatures were employed to constrain the geochemical evolution and sources of groundwater recharge in the arid Shule River Basin, Northwestern China, where extensive groundwater extraction occurs for agricultural and domestic supply. Springs in the mountain front of the Qilian Mountains, the Yumen‐Tashi groundwater (YTG), and the Guazhou groundwater (GZG) were Ca‐HCO3, Ca‐Mg‐HCO3‐SO4 and Na‐Mg‐SO4‐Cl type waters, respectively. Total dissolved solids (TDS) and major ion (Mg2+, Na+, Ca2+, K+, SO42?, Cl? and NO3?) concentrations of groundwater gradually increase from the mountain front to the lower reaches of the Guazhou Basin. Geochemical evolution in groundwater was possibly due to a combination of mineral dissolution, mixing processes and evapotranspiration along groundwater flow paths. The isotopic and geochemical variations in melt water, springs, river water, YTG and GZG, together with the end‐member mixing analysis (EMMA) indicate that the springs in the mountain front mainly originate from precipitation, the infiltration of melt water and river in the upper reaches; the lateral groundwater from the mountain front and river water in the middle reaches are probably effective recharge sources for the YTG, while contribution of precipitation to YTG is extremely limited; the GZG is mainly recharged by lateral groundwater flow from the Yumen‐Tashi Basin and irrigation return flow. The general characteristics of groundwater in the Shule River Basin have been initially identified, and the results should facilitate integrated management of groundwater and surface water resources in the study area. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
15.
Geochemical precursors to seismic activity 总被引：7，自引：0，他引：7
Donald Thomas 《Pure and Applied Geophysics》1988,126(2-4):241-266
Studies of earthquake precursory phenomena during the last several decades have found that significant geophysical and geochemical changes can occur prior to intermediate and large earthquakes. Among the more intensely investigated geochemical phenomena have been: (1) changes in the concentrations of dissolved ions and gases in groundwaters and (2) variations in the concentrations of crustal and mantle volatiles in ground gases. The concentration changes have typically showed no conanomalies trend (either increasing or decreasing), and the spatial and temporal distribution of the observed anomalies have been highly variable. As a result, there is little agreement on the physical or chemical processes responsible for the observed anomalies. Mechanisms proposed to account for precursory groundwater anomalies include ultrasonic vibration, pressure sensitive solubility, pore volume collapse, fracture induced increases in reactive surfaces, and aquifer breaching/fluid mixing. Precursory changes in soil gas composition have been suggested to result from pore volume collapse, micro-fracture induced exposure of fresh reactive silicate surfaces, and breaching of buried gas-rich horizons. An analysis of the available field and laboratory data suggests that the aquifer breaching/fluid mixing (AB/FM) model can best account for many of the reported changes in temperature, dissolved ion and dissolved gas concentrations in groundwater. Ultrasonic vibration and pressure sensitive solubility models cannot reasonably account for the geochemical variations observed and, although the pore collapse model could explain some of the observed chemical changes in groundwater and ground gas, uncertainties remain regarding its ability to generate anomalies of the magnitude observed. Other geochemical anomalies, in particular those associated with hydrogen and radon, seem best accounted for by increases in reactive surface areas (IRSA model) that may accompany precursory deformation around the epicenter of an impending earthquake. Analysis of the probable response of these models to the earthquake preparation process, as well as to other environmental factors, suggests that geochemical monitoring programs can provide information that may be valuable in forecasting the probability of an earthquake; however, because of the complexity of the earthquake preparation process, the absolute prediction of seismic events using geochemical methods alone, does not presently appear to be feasible. 相似文献
16.
Understanding the nature of communication between aquifers can be challenging when using traditional physical and geochemical groundwater sampling approaches. This study uses two multiport wells completed within Edwards and Trinity aquifers in central Texas to determine the degree of groundwater inter‐flow between adjacent aquifers. Potentiometric surfaces, hydraulic conductivities, and groundwater major ion concentrations and Sr isotope values were measured from multiple zones within three hydrostratigraphic units (Edwards and Upper and Middle Trinity aquifers). Physical and geochemical data from the multiport wells were combined with historical measurements of groundwater levels and geochemical compositions from the region to characterize groundwater flow and identify controls on the geochemical compositions of the Edwards and Trinity aquifers. Our results suggest that vertical groundwater flow between Edwards and Middle Trinity aquifers is likely limited by low permeability, evaporite‐rich units within the Upper and Middle Trinity. Potentiometric surface levels in both aquifers vary with changes in wet vs. dry conditions, indicating that recharge to both aquifers occurs through distinct recharge areas. Geochemical compositions in the Edwards, Upper, and Middle Trinity aquifers are distinct and likely reflect groundwater interaction with different lithologies (e.g., carbonates, evaporites, and siliceous sediments) as opposed to mixing of groundwater between the aquifers. These results have implications for the management of these aquifers as they indicate that, under current conditions, pumping of either aquifer will likely not induce vertical cross‐formational flow between the aquifers. Inter‐flow between the Trinity and the Edwards aquifers, however, should be reevaluated as pumping patterns and hydrogeologic conditions change. 相似文献
17.
Jianjun Wang Xing Liang Yanfeng Liu Menggui Jin Peter S.K. Knappett Yalei Liu 《Ground water》2019,57(4):575-589
The impacts of long-term pumping on groundwater chemistry remain unclear in the Manas River Basin, Northwest China. In this study, major ions within five surface water and 105 groundwater samples were analyzed to identify hydrogeochemical processes affecting groundwater composition and evolution along the regional-scale groundwater flow paths using the multivariate techniques of hierarchical cluster analysis (HCA) and principal components analysis (PCA) and traditional graphical methods for analyzing groundwater geochemistry. HCA classified the groundwater samples into four clusters (C1 to C4). PCA reduced the dimensionality of geochemical data into three PCs, which explained 86% of the total variance. The results of HCA and PCA were used to identify three zones: “recharge,” “transition,” and “discharge.” In the recharge zone the groundwater type is Ca-HCO3-SO4 and is primarily impacted by the dissolution of calcite and silicate weathering. In the transition zone the groundwater type is Ca-HCO3-SO4-Cl and is impacted by rock dissolution and reverse ion exchange. In the discharge zone the groundwater type is Na-Cl and is impacted by evaporation and reverse ion exchange. In addition, anthropogenic activities impact the groundwater chemistry in the study area. The groundwater type generally changes from Ca-HCO3-SO4 in the recharge area to Na-Cl in the discharge area along the regional-scale groundwater flow paths. This study provides a process-based knowledge for understanding the interaction of groundwater flow patterns and geochemical evolution within the Manas River Basin. 相似文献
18.
ABSTRACTWater quality in the arid regions has long been an issue of great concern in the world. In this study, quantitative research was carried out to create new knowledge to understand the processes that determine the variation in the groundwater chemical composition of the Yinchuan Plain, China. In this context, the distribution and zonation characteristics of groundwater in this area were assessed using geochemical modelling of groundwater quality evolution. The results show the existence of an obvious zonation from the recharge area to the discharge area in the study area. Dominant anions transform from HCO3 in the inclined pluvial area to HCO3·SO4·Cl in the discharge region, while the main cations vary from Ca and Mg to Na and Mg. The simulation results indicate that the evaporation process triggers 2–35% of groundwater loss, leading to an increase in the total dissolved solids. The irrigation leakage mixes with the groundwater at about 8:2, suggesting that the irrigation leakage dilutes the groundwater. 相似文献
19.
Anis Chekirbane Maki Tsujimura Atsushi Kawachi Hiroko Isoda Jamila Tarhouni Abdallah Benalaya 《水文科学杂志》2013,58(5):1097-1110
Abstract The Wadi Al Ayn plain is a coastal system on the eastern coast of Cap Bon in northeastern Tunisia. The area is known for its intensive agriculture, which is based mainly on groundwater exploitation. The aim of this study is to identify the sources of groundwater salinization in the Wadi Al Ayn aquifer system and deduce the processes that drive the mineralization. Surface water and groundwater samples were taken and analysed for major ions and stable isotopes. The geochemical data were used to characterize and classify the water samples based on a variety of ion plots and diagrams. Stable isotopes are useful tools to help us understand recharge processes and to differentiate between salinity origins. The oilfield brines infiltrated from the sandy bed of Wadi Al Ayn comprise the main source of groundwater salinization in the central part of the plain, while seawater intrusion is mainly responsible for the increased salinity in the groundwater of the coastal part of the plain (at Daroufa). Citation Chekirbane, A., Tsujimura, M., Kawachi, A., Isoda, H., Tarhouni, J., and Benalaya, A., 2013. Hydrogeochemistry and groundwater salinization in an ephemeral coastal flood plain: Cap Bon, Tunisia. Hydrological Sciences Journal, 58 (5), 1097–1110. 相似文献
20.
Chander Kumar Singh Rina Kumari Neha Singh Javed Mallick Saumitra Mukherjee 《水文研究》2013,27(17):2462-2474
The groundwater is the only source of drinking water in the Jaisalmer district of Rajasthan, India. The study area is a part of the Thar Desert. It has low and scattered population and no industries; hence, the possibility of anthropogenic input of fluoride is almost negligible. Thus, the enrichment of fluoride is only possible due to geochemical processes taking place in the groundwater of the region. A total of 100 groundwater samples, 34 samples from Jaisalmer and 66 samples from the Pokharan administrative blocks, were collected. It was observed that the concentration of fluoride ranged from 0.08 mg/l to 4.56 mg/l in the groundwater of Jaisalmer and from 0.56 mg/l to 6.60 mg/l in the samples of the Pokharan block. The alkaline condition (average pH, 7.7 ± 0.22 and 8.01 ± 0.25 in Jaisalmer and the Pokharan administrative block, respectively) in the region favours fluorite dissolution. Ion exchange, dissolution of calcite, semi‐arid climate, alkaline conditions and weathering are responsible for fluoride enrichment in the groundwater of the study area. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献