The possible effects of translationally excited nitrogen atoms on lower thermospheric odd nitrogen     

Susan Solomon 《Planetary and Space Science》1983,31(1):135-139

In the quiet lower thermosphere, photolysis of N₂ produces translationally excited $\text{N}\text{(}{}^4\text{S}\text{)}$ and $\text{N}\text{(}{}^2\text{D}\text{)}$ atoms. A fraction of these $\text{N}\text{(}{}^4\text{S}\text{)}$ atoms may react rapidly with O₂ while still translationally hot. This results in substantially larger calculated NO densities than those obtained if translational excitation is not considered. The sensitivity of the calculated NO density in the lower thermosphere to this process is examined.  相似文献   

A discussion of the energy transfer from N₂(A³Σ_u⁺) to $\text{O}\text{(}{}^1\text{S}$) in pulsating aurora     

Asgeir Brekke 《Planetary and Space Science》1973,21(4):698-702

In a recent paper, Brekke and Pettersen (1972) have introduced a method for estimating any indirect process in the production of the $\text{O}\text{(}{}^1\text{S}$) atoms in pulsating aurora; for 38 per cent of their data they found that the decay time for the indirect mechanism was shorter than the effective lifetime of the ${}^1\text{S}$ state. These data are related to the energy transfer from the N₂(A³Σ) molecules to the $\text{O}\text{(}{}^1\text{S)}$ state, and evidence is found for this process to contribute in the altitude range below 125 km.  相似文献   

Emission line shapes produced by dissociative excitation of atmospheric gases     

E.C. Zipf  W.C. Wells 《Planetary and Space Science》1980,28(8):859-866

Special line shapes are derived fro the λ 1356 Å (${}^5\text{S}{}^0\text{-}{}^3\text{P}$) transition of atomic oxygen from metastable (${}^5\text{S}{}^0\text{-}{}^3\text{P}$) time-of-flight spectra produced by electron impact dissociative excitation of O₂, CO₂, CO, and NO, and they are compared with the broadened λ 1304 A resonance line shapes deduced by Poland and Lawrence (1973) from atomic oxygen absorption studies. The non-thermal line shapes for both airglow emission features are shown to have an effective width comparable to a 60,000 K thermal doppler line shape for an electron impact energy of 100eV. The variation of the effective line width with electron-impact energy from threshold to 300 eV is given. Since the effective line width of the resonance radiation produced by dissociative excitation is very large compared with the doppler absorption widths of the ambient O atoms at normal exospheric temperatures, the anomalously broadened resonance lines will propagate through a planetary atmosphere as though they were optically thin. Thus, electron-impact dissociation of CO and CO₂ will contribute to the observed optically thin component of the λ 1304 Å emission in the upper atmospheres of Venus and Mars. However, the process cannot account for more than 10% of the observed optically thin emission because of the small magnitude of the excitation cross-section and the comparatively high-energy threshold for the process. The possibility that the source of the kinetically energetic $\text{O}\text{(}{}^3\text{S}$) atoms is the dissociative recombination of vibrationally excited CO₂⁺ ions is discussed.  相似文献   

Aeronomical determination of the efficiency of O¹D) production by dissociative recombination of O₂⁺     

L.L. Cogger  L.S. Smith  R.M. Harper 《Planetary and Space Science》1977,25(2):155-159

Simultaneous measurements of the 6300 Å airglow intensity, the electron density profile, and F-region ion temperatures and vertical ion velocities taken at the Arecibo Observatory in March 1971 are utilized in the height integrated continuity equation to extract the number of photons'of 6300 Å emitted per recombination. After accounting for quenching of $\text{O}\text{(}{}^1\text{D}\text{)}$ and the electrons lost via NO⁺ recombination, the efficiency of $\text{O}\text{(}{}^1\text{D}\text{)}$ production by the dissociative recombination of O₂⁺ is determined to be 0.6 ± 0.2 including cascading from the $\text{O}\text{(}{}^1\text{S}\text{)}$ state. The uncertainty includes both random measurement errors and estimates of possible systematic errors.  相似文献   

The O(1S) quantum yield from O2+ dissociative recombination     

D.R. Bates  E.C. Zipf 《Planetary and Space Science》1980,28(11):1081-1086

Recent laboratory studies show that the $\text{O}\text{(}{}^1\text{S}\text{)}$ quantum yield, $\text{f}\text{(}{}^1\text{S}\text{)}$, from O₂⁺ dissociative recombination varies considerably with the degree r of vibrational excitation. However, the suggestion that the high values for $\text{f}\text{(}{}^1\text{S}\text{)}$ deduced from airglow and auroral observations can be explained by invoking vibrational excitation, creates a number of problems. Firstly, the rapid vibrational deactivation of O₂⁺ ions by collisions with O atoms will keep r too low to account for the magnitude of $\text{f}\text{(}{}^1\text{S}\text{)}$; secondly, r varies considerably from one atmospheric source to another but its relative values (which should be reliable) do not co-vary with those of $\text{f}\text{(}{}^1\text{S}\text{)}$; thirdly, because r increases markedly above the peak of the $\text{X5577}\text{A}\text{?}$ dissociative recombination layer, the fits which theorists have obtained to the observed volume emission rate profiles would have to be regarded as fortuitious. It is tentatively suggested that $\text{f}\text{(}{}^1\text{S}\text{)}$ is higher in the airglow and aurora than in the laboratory plasma studied by Zipf (1980) because of the electron temperature dependence of the $\text{O}\text{(}{}^1\text{S}\text{)}$ specific recombination coefficient for O₂⁺(v^' ? 3) ions.The repulsive ${}^1\text{Σ}{}_{\mathrm{<mtext>u</mtext>}}\text{[}{}^1\text{D}\text{+}{}^1\text{s}\text{]}$ state of O₂ does not provide a suitable channel for the dissociative recombination. A possible alternative is the bound ${}^3\text{Π}{}_{\mathrm{<mtext>u</mtext>}}\text{[}{}^5\text{S}\text{+}{}^3\text{s}\text{]}$ state with predissociation to the repulsive ${}^3\text{Π}{}_{\mathrm{<mtext>u</mtext>}}\text{[}{}^3\text{P}\text{+}{}^1\text{s}\text{]}$ state.  相似文献   

The excitation of the 557.7 nm line and Herzberg bands in the nightglow     

L. Thomas  R.G.H. Greer  P.H.G. Dickinson 《Planetary and Space Science》1979,27(7):925-931

Measurements of the emission intensities of the 557.7 nm line and Herzberg bands and of O(³P) concentrations carried out on two coordinated rocket flights at South Uist during the night of 8/9 September 1975 are presented. An examination of the 557.7 nm emission and $\text{O}\text{(}{}^3\text{P}\text{)}$ data on the basis of recent data on relevant rate coefficients has shown that the results can be interpreted on the basis of the Barth mechanism for the production of $\text{O}\text{(}{}^1\text{S}\text{)}$ atoms but not the Chapman mechanism. Evidence is provided that the A³Σ⁺_u state of O₂ could be responsible for the $\text{O}\text{(}{}^1\text{S}\text{)}$ production in the Barth mechanism. Values of the rate coefficients involved are deduced from a comparison of the 557.7 nm and Herzberg emission rates.  相似文献   

Auroral implications of recent measurements on O(1S) and O(1S) formation in the reaction of N+ with O2     

Andrew O. Langford  Veronica M. Bierbaum  Stephen R. Leone 《Planetary and Space Science》1985,33(10):1225-1228

Recent flowing afterglow measurements have shown that the reaction of N⁺ with O₂ produces 70 ± 30% of the oxygen atom product as $\text{O}\text{(}{}^1\text{D}\text{)}$ and < 0.1% as $\text{O}\text{(}{}^1\text{S}\text{)}$. These results indicate that this reaction does not contribute to the auroral green line emission (5577 Å), but can account for ～10% of the observed red line (6300 Å) auroral emission.  相似文献   

Contamination of ground-based measurements of OI (6300 Å) and NI (5200 Å) airglow by OH emissions     

R.G. Burnside  J.W. Meriwether  M.R. Torr 《Planetary and Space Science》1977,25(10):985-988

High resolution spectra of the 6300 Å and 5200 Å regions of the night sky have been obtained using a 1 m spectrometer. Typical errors in measurements of $\text{O}\text{(}{}^1\text{D}\text{)}$ 6300 Å and $\text{N}\text{(}{}^2\text{D}\text{)}$ 5200 Å intensities due to contanimation by overlapping OH emissions have been calculated for a fixed-filter photometer, a tilting-filter photometer and a spectrophotometer. The importance of careful selection of certain instrumental parameters in order to minimize measurement errors is emphasized.  相似文献   

Observations and interpretation of spectra and rapid time variations of type-B aurora     

R.L. Gattinger  A.Vallance Jones 《Planetary and Space Science》1979,27(2):169-181

Observations of type-B red and normal aurora were made with a high-speed multichannel photometer and a digital grating spectrometer. The ratio $\text{I}\text{(}\text{O}{}_2{}^{\mathrm{+}}\text{1N; 2, 0 + 3, 1)}\text{I}\text{(}\text{N}{}_2{}^{\mathrm{+}}\text{1N; 0, 3)}$ measured in the 5200–5300 Å region with the spectrometer was found to increase by about 16% from normal to type-B aurora. This small change is difficult to reconcile with a height below 90 km for the red border. In the type-B aurora, λ 5577 was weakened by a factor between 1.9 and 3.8 while the ratio $\text{I}\text{(}\text{N}{}_2\text{1P; 5, 2)}\text{I}\text{(}\text{N}{}_2{}^{\mathrm{+}}\text{1N)}$ was enhanced less than 20%. Rapid intensity variations in the type-B lower border were observed in the λ 5577 and other channels of the photometer. A revised time dependent auroral excitation-ion chemistry model is used in an attempt to reproduce the observations. The observed weakening of λ 5577 could be produced at heights equal to or less than 100 km while the short observed time lag of λ 5577 on the N₂⁺ 1N emission is easier to explain at 100 km than at 80 km. It is concluded that some type-B lower borders may occur near 100 km although it is recognized that there is good evidence rare deep crimson lower borders lie at 80 km or below. The mechanism for the excitation of O(¹S) is considered in the light of these results. None of the mechanisms examined is satisfactory on the basis of currently accepted atmospheric models and quenching rate coefficients.  相似文献   

Changes in the concentration of mesospheric ozone during the total solar eclipse     

V.V. Agashe  S.M. Rathi 《Planetary and Space Science》1982,30(5):507-513

Measurements of dayglow radiance of $\text{O}{}_2\text{(}{}^1\text{Δ}{}_{\mathrm{g}}\text{)}$ and OH(7,2) bands are reported. Ground based photometers were used to monitor zenith radiance of 1270 and 694 nm emissions during the total solar eclipse of 16 February 1980. Altitude distribution of 1270 nm intensity was derived from ground based observations. A set of altitude distributions of $\text{O}{}_2\text{(}{}^1\text{Δ}{}_{\mathrm{g}}\text{)}$ were thus obtained throughout the eclipse. These altitude distributions were converted into ozone distributions using the rate equations for formation and loss of ozone and $\text{O}{}_2\text{(}{}^1\text{Δ}{}_{\mathrm{g}}\text{)}$ molecules. Results indicate an increase in the ozone concentration at mid-eclipse. OH(7,2) emission did not show enhancement during totality. This may mean that there was no increase in OH concentration during the eclipse.  相似文献   

Quenching of O⁺(²D) by electrons in the thermosphere     

Marsha R. Torr  D.G. Torr  P. Richards 《Planetary and Space Science》1980,28(6):581-584

A major loss process for the metastable species, O⁺(²D), in the thermosphere is quenching by electrons .To date no laboratory measurement exists for the rate coefficient of this reaction. Thermospheric models involving this process have thus depended on a theoretically calculated value for the rate coefficient and its variation with electron temperature. Earlier studies of the O⁺(²D) ion based on the Atmosphere Explorer data gathered near solar minimum, could not quantify this process. However, Atmosphere Explorer measurements made during 1978 exhibit electron densities that are significantly enhanced over those occurring in 1974, due to the large increases that have occurred in the solar extreme ultraviolet flux. Under such conditions, for altitudes ? 280 km, the electron quenching process becomes the major loss mechanism for O⁺(²D), and the chemistry of the N⁺₂ ion, from which the O⁺(²D) density is deduced, simplifies to well determined processes. We are thus able to use the in situ satellite measurements made during 1978 to derive the electron quenching rate coefficient. The results confirm the absolute magnitude of the theoretical calculation of the rate coefficient, given by the analytical expression k(T_e) = 7.8 × 10^?8 (T_e/300)^?0.5cm³s^?1. There is an indication of a stronger temperature dependence, but the agreement is within the error of measurement.  相似文献   

A self-consistent evaluation of the rate constants for the production of the OI 6300 Å airglow     

R. Link  J.C. McConnell  G.G. Shepherd 《Planetary and Space Science》1981,29(6):589-594

The quenching rate k_N2 of $\text{O(}{}^1\text{D)}$ by N₂ and the specific recombination rate α_1D of O₂⁺ leading to $\text{O(}{}^1\text{D)}$ are re-examined in light of available laboratory and satellite data. Use of recent experimental values for the $\text{O(}{}^1\text{D)}$ transition probabilities in a re-analysis of AE-C satellite 6300 Å airglow data results in a value for k_N2 of 2.3 × 10^?11 cm³s^?1 at thermospheric temperatures, in excellent agreement with the laboratory measurements. This implies a value of J_O2 = 1.5 × 10^?6s^?1 for the O₂ photodissociation rate in the Schumann-Runge continuum. The specific recombination coefficient α_1D = 2.1 × 10^?7cm³s^?1 is also in agreement with the laboratory value. Implications for the suggested $\text{N}\text{(}{}^2\text{D) + O}{}_2\text{→ O(}{}^1\text{D) + NO}$ reaction are discussed.  相似文献   

The excitation of atomic oxygen to the $\text{O(}{}^1\text{S)}$ level by energy transfer from N₂(A³∑_u⁺) molecules in aurora     

Kjell Henriksen 《Planetary and Space Science》1973,21(5):863-871

The part that the energy transfer reaction $\text{N}{}_2\text{(A}{}^3\text{∑}{}_{\mathrm{u}}{}^{\mathrm{+}}\text{) + O(}{}^3\text{P) → N}{}_2\text{(X}{}^1\text{∑}{}_{\mathrm{g}}{}^{\mathrm{+}}\text{) + O(}{}^1\text{S)}$ plays in the excitation of the auroral green line has been investigated. The contribution is estimated to be 40 per cent in this case, containing pulsating aurora in class IBC 1. Due to greater quenching of the A³∑_u⁺ state, the centroid of the VK emission is displaced 10 km upwards of the green line height, which is centred at 110 km.  相似文献   

Branching ratios for the photoionization cross section of atomic oxygen     

A.K. Pradhan 《Planetary and Space Science》1980,28(2):165-167

Branching ratios $\text{σ(}\text{O}{}^0{}^3\text{P}\text{→}\text{O}{}^{\mathrm{+}}{}^2\text{D}{}^0\text{)}\text{σ(}\text{O}{}^0{}^3\text{P}\text{→}\text{O}{}^{\mathrm{+}}{}^4\text{S}{}^0\text{)}$ and $\text{σ(}\text{O}{}^0{}^3\text{P}\text{→}\text{O}{}^{\mathrm{+}}{}^2\text{P}{}^0\text{)}\text{σ (}\text{O}{}^0{}^3\text{P}\text{→}{}^4\text{S}{}^0\text{)}$ are calculated at 584 Å and 304 A employing the close-coupling approximation to compute the photoionization cross section values. The coupled channels include the states dominated by the ground configuration 1s²2s²p³ of O⁺and the next excited configuration ls²2s2p⁴. It is found that the partial c section $\text{σ(}{}^2\text{D}{}^0\text{)}$ decreases more rapidly than $\text{σ(}{}^2\text{P}{}^0\text{)}$, and at the lower wavelength 304 Å, the ratio $\text{σ(}{}^2\text{D}{}^0\text{)}\text{σ(}{}^4\text{S}{}^0\text{)}\text{<}\text{σ(}{}^2\text{P}{}^0\text{)}\text{σ(}{}^4\text{S}{}^0\text{)}$. Present results at 304 Å differ considerably from previous work.  相似文献   

Direct measurement of conjugate photoelectrons and predawn 630 nm airglow     

G.G. Shepherd  J.F. Pieau  T. Ogawa  T. Tohmatsu  K. Oyama  Y. Watanabe 《Planetary and Space Science》1978,26(3):211-217

A sounding rocket was flown during the predawn on 17 January, 1976 from Uchinoura, Japan, to measure directly the behaviour of the conjugate photoelectrons at magnetically low latitudes. On board the rocket were an electron energy analyzer, 630 nm airglow photometer, and plasma probes to measure electron density and temperature. The incoming flux of the photoelectrons was measured in the altitude range between 210 and 340 km. The differential flux at the top of the atmosphere was determined to be $\text{F = (1.3 ± 0.4) × 10}{}^{11}\text{exp}\text{[?}\text{E(}\text{eV}\text{)}\text{12}\text{]}$ electron · m^?2 · sr^?1 · s^?1 in the energy range 10 ? E ? 50 eV. The emission rate of the 630 nm airglow was observed in the altitude range between 90 and 360 km. The apparent emission rate observed at 80 km was 32 ± 5 R. From a theoretical calculation of the optical excitation rate using the observed electron flux data along with a model distribution of atomic oxygen, it was estimated that more than 65% of the emission could be produced by direct impact of the photoelectrons with atomic oxygen in the thermosphere between 200 and 360 km. Using the observed electron density and the model distribution of oxygen molecules the residual of the emission was ascribed to the excitation of O(¹D) through dissociative recombination, $\text{O}{}_2{}^{\mathrm{+}}\text{+}\text{e}\text{→}\text{O}{}^1\text{+}\text{O}{}^7$. The direct collisional excitation by ambient electrons is estimated to be negligibly small at the level of observed electron temperature.  相似文献   

A global study of $\text{O}{}_2\text{(}{}^1\text{Δ}{}_{\mathrm{g}}\text{)}$ airglow: Day and twilight     

J.F. Noxon 《Planetary and Space Science》1982,30(6):545-557

Aircraft measurements of $\text{O}{}_2\text{(}{}^1\text{Δ}{}_{\mathrm{g}}\text{)}$ emission made over a 10-yr period provide information on the variation of ozone with latitude and season in the altitude region 50–90 km. Between 50 and 70 km there appears to be little variation (< ± 25%) whereas the abundance between 80 and 90 km exhibits a large seasonal change north of 30°N and much less at lower latitude. At mid and high latitude the column abundance above ～ 80 km changes from ? 1 × 10¹⁴ cm^?2 in summer to about 3 × 10¹⁴ cm^?2 in winter. There are occasional enhancements in both the day and twilight airglow which almost always occur in association with auroral activity or, at least, where such activity is statistically most likely. These enhancements appear to reflect a corresponding increase in the ozone mixing ratio in the upper stratosphere. While the gradient in ozone mixing ratio with latitude is generally small at altitudes between 50 and 90km there are occasions when a temporary latitude structure can be seen, particularly above 80 km.  相似文献   

Thermospheric neutral composition from auroral ion ratios     

W. Swider 《Planetary and Space Science》1983,31(1):49-52

For nighttime auroras, we find that positive ion ratios are only a function of the neutral atmospheric composition and of the pertinent ionic processes if the ions are depleted mainly by ion-molecule reactions. Ionic ratios calculated for $\text{[}\text{N}{}^{\mathrm{+}}\text{]}\text{[}\text{N}{}_2{}^{\mathrm{+}}\text{]}$ using the 1976 U.S. Standard Atmosphere and laboratory rate coefficients (with one exception) rise smoothly with altitude: 0.1 (120 km), 0.3 (140 km), 0.6 (160 km), 1.0 (180 km) and 1.5 (200 km). These values compare favorably with experimental ratios from three different auroral experiments. The exception refers to our use of a larger rate coefficient for N₂⁺ + O → NO⁺ + N than found in the laboratory. We also determine an $\text{[}\text{N}{}_2{}^{\mathrm{+}}\text{]}\text{[}\text{O}{}^{\mathrm{+}}\text{]}$ ratio with altitude: 0.36 (120 km), 0.078 (140 km), 0.030 (160 km), 0.014 (180 km) and 0.0075 (200 km). These values compare favorably with results from the same three auroral experiments. However, the match with a fourth auroral experiment is poor. Except for this last case, we conclude that the neutral composition at auroral latitudes in late winter is similar to the U.S. Standard for the altitudes examined.  相似文献   

Detection of [Ol] 1S-1D in Comet IRAS-Araki-Alcock     

William D. Cochran 《Icarus》1984,58(3):440-445

Spectra of the $\text{[}\text{OI}\text{]}{}^1\text{D-}{}^3\text{P}$ “red” doublet and the ¹S-¹D “green” line in Comet IRAS-Araki-Alcock (1983d) were obtained during its close approach to the Earth. This is the first unequivocal photoelectric detection of the green line in a cometary spectrum. The population ratio of the O (¹S) state to the O (¹D) state in the inner coma is ≦0.03. This ratio eliminates CO or CO₂ and points strongly to H₂O as the primary parent for excited oxygen atoms.  相似文献   

Cross-section for the dissociative photoionization of hydrogen by 584 Å radiation: The formation of protons in the Jovian ionosphere     

K.M. Monahan  W.T. Huntress  A.L. Lane  J.M. Ajello  T.E. Burke  P. Le Breton  A. Williamson 《Planetary and Space Science》1974,22(1):143-149

The cross-section for dissociative photoionization of hydrogen by 584 Å radiation has been measured, yielding a value of 5 × 10^?20 cm². The process can be explained as a transition from the $\text{X}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}$ ground state to a continuum level of the $\text{X}{}^2\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}$ ionized state of H₂ The branching ratio for proton (H⁺) vs molecular ion (H₂⁺) production at this energy is 8 × 10^?3. This process is quite likely an important source of protons in the Jovian ionosphere near altitudes where peak ionization rates are found.  相似文献   

Charge exchange of metastable D oxygen ions with N₂ in the thermosphere     

D. G. Torr  N. Orsini 《Planetary and Space Science》1977,25(12):1171-1176

Measurements of N₂⁺ and supporting data made on the Atmosphere Explorer-C satellite in the ionosphere are used to study the charge exchange process The equality k = (5 ± 1.7) × 10^?10cm³s^?1. This value lies close to the lower limit of experimental uncertainty of the rate coefficient determined in the laboratory. We have also investigated atomic oxygen quenching of O⁺(²D) and find that the rate coefficient is 2 × 10^?11 cm³s^?1 to within approximately a factor of two.  相似文献