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1.
Liners are commonly used in engineered waste disposal landfill to minimize the potential contamination of the aquatic environment. The adsorption behavior of Cu(II) from aqueous solution onto clay admixed with various mix ratios of quarry fines was investigated. The amount of Cu(II) adsorption increases with increase in contact time. The copper removal efficiencies of the composite mixture gradually decrease from 94.53 % (raw clay) to 85.59 % (20 % of quarry fines with clay), and appreciable decrease in percent removal 75.61 % was found with 25 % of quarry fines with clay. The kinetic adsorption data were analyzed by pseudo-first-order, pseudo-second-order, Bhattacharya–Venkobachar and Natarajan–Khalaf kinetic models to classify adsorption process mechanisms. Kinetic experimental data were good agreement with pseudo-second-order kinetic model with the degree of fitness of the data (R 2) 0.9999 for the adsorption of Cu(II). The results revealed that quarry fines can be used with optimum of 20 % replacement of natural clay for removal of Cu(II) as a liner material in landfills.  相似文献   

2.
The bentonite deposit of Lahij Province, Yemen, has very promising commercial applications due to its mineralogy and physical and chemical properties. It was examined to determine its mineralogical composition, chemical and physical properties of the bentonite deposit, purity and sodium-exchanged bentonite. Modified bentonite was synthesized by exchanging cetyltrimethylammonium cations for inorganic ions on the bentonite and its adsorption properties for ammonium were characterized in batch experiments. Analytical methods were carried out to study the bentonite comprising X-ray diffraction (XRD), scanning electron microscopy (SEM), infrared spectroscopy, chemical analysis and kinetic and isotherm models were also tested. The results have shown that the purification of bentonite resulted in a bentonite fractions of the total sample composed of montmorillonite and <5 % quartz. The XRD data showed that the interlayer spacing (d 001) of bentonite decreased from 15.3 to 12.5 Å and then increased to 19.7 Å. Moreover, high cation exchange capacity, good water absorption and high swelling capacity were also obtained. The results have shown that the modified bentonite was more effective than the natural bentonite for ammonium removal. In addition to that, pseudo-second-order kinetic model, Freundlich and the Langmuir models described the adsorption kinetics and isotherm well. It was concluded that Yemen (Alaslef) bentonite can be potential adsorbents for ammonium removal.  相似文献   

3.
Three mixtures (M1, M2, and M3) of the Eocene clay deposits were collected from Ain M’Dheker (Enfidha, Tunisia). These mixtures have been treated by hydrochloric acid in order to improve their physico-chemical characteristics. Optimum conditions for activation were conducted by varying several parameters such as the acid concentration, time, and temperature activation. The activation condition effect on surface area is studied. A representative raw (M3) and activated (AM3) mixtures were used in industrial application: Sunflower oil and Black 194 dyes (textile waste). M3 and AM3 were used to leach sunflower oil by varying the clay amount introduced. Results of the bleaching power of used samples were compared to that found by commercial bentonite imported from Germany (Tonsil), having a surface area of 725 m2/g. Indeed, an amount of 1% of AM3 gives a 60% decolorization similar to that found by commercial clay. Also, the ability of raw and activated clay to remove the dye (Acid Black 194) from effluent has been studied firstly at different pH and in second time by varying the adsorbent amount. Then, an amount of 0.025 g is sufficient to give a higher adsorption capacity for M3 than AM3. Consequently, Ain M’Dheker clay deposits can be use in other environmental application even without any treatment.  相似文献   

4.
Compacted soil–bentonite mixtures are finding wide application as buffer material for waste repositories for their favorable self-sealing qualities. The swelling properties of such materials which serve as a measure of their self-sealing capabilities and, thus, the efficiency of the repository in sealing off their contents from the environment are closely related to the chemistry of the leachate that emanate from the wastes. For this reason, the swelling parameters (namely swelling potential and pressure) of compacted lateritic soil–bentonite mixtures under consideration for use as barrier in municipal waste landfill were evaluated. Series of swelling potential and pressure tests were performed using variable content (0–10 %) of bentonite at predetermined optimum moisture content. Soil mixtures were compacted with British Standard Heavy compactive effort and saturated with processed tap water as well as three leachate solutions of varying ionic strength that were generated in active open dump landfills. Experimental results showed that swelling potential based on the free swell together with the maximum swell pressures of compacted soil mixtures measured at equilibrium increased approximately linearly with increase in the amount of bentonite when inundated with processed tap water and the three leachate solutions. On the other hand, these swelling parameters decreased as the ionic strength of the leachate solutions measured by their electrical conductivity increased for the various soil mixtures. These results provide an insight into the swelling behavior and the possible degradation in the efficiency of the proposed lateritic soil–bentonite mixtures in relation to their use as buffer material in waste landfills.  相似文献   

5.
A binary mixture of humic acid and geothite was prepared and used to modify kaolinite to produce geothite–humic acid (GHA)-modified kaolinite adsorbent useful for the adsorption of Pb2+, Cd2+, Zn2+, Ni2+ and Cu2+ from Single and Quinary (5) metal ion systems. The cation exchange capacity (CEC) and specific surface area of GHA-modified kaolinite clay adsorbent were found to be 40 meq/100 g and 13 m2/g, respectively, with the CEC being five times that of raw kaolinite clay (7.81 meq/100 g). The Langmuir–Freundlich equilibrium isotherm model gave better fit to experimental data as compared with other isotherm models. In Quinary metal ion system, the presence of Zn2+ and Cu2+ appears to have an antagonistic effect on the adsorption of Pb2+, Cd2+ and Ni2+, while the presence of Pb2+, Cd2+ and Ni2+ shows a synergistic effect on the adsorption of Zn2+ and Cu2+. The GHA-modified kaolinite showed strong preference for the adsorption of Pb2+ in both metal ion systems. Brouers–Weron–Sotolongo (BWS) kinetic model gave better fit to kinetic data compared with other kinetic models used. Data from BWS kinetic model indicate that adsorption of metal ions onto GHA-modified adsorbent in both metal ion systems followed strictly, diffusion-controlled mechanism with adsorption reaction proceeding to 50 % equilibrium in <2 min in the Single metal ion system and <1 min in the Quinary metal ion system. Adsorption of metal ions onto GHA-modified kaolinite is fairly spontaneous and endothermic in nature in both metal ion systems although the rate of metal ion uptake and spontaneity of reaction are reduced in the Quinary metal ion system.  相似文献   

6.
A novel polyurethane foam/organobentonite/iron oxide nanocomposite adsorbent was successfully prepared via in situ polymerization of toluene diisocyanate and polyol in presence of 5 wt% organobentonite/iron oxide. The obtained nanocomposite was characterized in detail, and the results revealed that the clay layers are exfoliated and/or intercalated in the polymer matrix forming a nanocomposite structure. The application of the prepared nanocomposite for adsorption of cadmium ions from aqueous solution was tested as a function of various experimental parameters using batch procedures. Adsorptive removal of Cd(II) onto the nanocomposite attained maximum at adsorbent content 1.5 g/L, pH 6, and the equilibrium was established within 60 min. Kinetic studies showed that the experimental data fit very well to pseudo-second-order model, and the adsorption process proceeds through three steps. It was found that external liquid film and intraparticle diffusion steps deeply affect the rate of Cd2+ ions adsorption onto the synthesized nanocomposite. Langmuir isotherm model fitted the adsorption data better than Freundlich with a maximum adsorption capacity (q m) for Cd(II) equal to 78 mg/g under the specified experimental conditions. The synthesized nanocomposite afforded effective extraction for Cd2+ ions from natural water samples and excellent reusability feature. This study declares the potential efficiency of a new clay/polymer nanocomposite as alternative for wastewater remediation.  相似文献   

7.
Swelling behavior of expansive soil has always created problems in the field of geotechnical engineering. Generally, the method used to assess the swelling potential of expansive soil from its plasticity index, shrinkage limit and colloidal content. Alternative way to evaluate swelling behavior is from its expansive index (EI) and swelling pressure value. The present study investigates the reduction of EI and swelling pressure for kaolinite and bentonite clay when mixed with various percentages of Ottawa sand and Class C fly ash. The percentages of Ottawa sand and Class C fly ash used were 0–50 % by weight. The results show that there is a significant reduction in the swelling properties of expansive soil with the addition of Ottawa sand and Class C fly ash. The reduction in EI ranged approximately from 10 to 50 and 4 to 49 % for kaolinite and bentonite clay, respectively. Also the maximum swelling pressure of kaolinite and bentonite clay decreased approximately 93 and 64 %, respectively with the addition of various percentages of Ottawa sand and Class C fly ash. Standard index properties test viz., liquid limit, plastic limit and linear shrinkage test were conducted to see the characteristics of expansive soil when mixed with less expansive sand and fly ash. Also, for these expansive soils one dimensional consolidation test have been conducted with sand and fly ash mixtures and the results were compared with pure kaolinite and bentonite clay.  相似文献   

8.
This study aimed to develop a low-cost and effective clay liner material for solid waste landfills in Sri Lanka. A locally available clayey soil and its admixtures with 5 and 10% bentonite were examined for this purpose. Laboratory experiments to determine soil plasticity and swell index were carried out on the tested samples. Hydraulic conductivity (k) tests were carried out in the laboratory using water and an aqueous solution of CaCl2 on unconsolidated samples prepared by either dry or slurry packing and pre-consolidated samples with five different consolidation pressures (p) from 10 to 200 kPa. Measured liquid limits for tested admixtures increased with increasing bentonite contents and correlated well with measured values of the swell index. The difference in permeant solutions had little effect on measured k values for both unconsolidated and pre-consolidated samples. The hydraulic conductivities were highly affected by changing p, i.e., the k values decreased on two orders of magnitude as p increased from 10 to 200 kPa. The Kozeny–Carman equation, a theoretical permeability model that expresses the k-porosity relationship, was applied to measured data including reported values. Results showed the Kozeny–Carman equation captured well the porosity-dependent k values for tested soils and their admixtures with bentonite under a wide range of void ratios, suggesting that the Kozeny–Carman equation is a useful tool to estimate the magnitude of k values for differently compacted soil and its bentonite admixtures.  相似文献   

9.
This paper assesses the use of certified Iraqi montmorillonite clay as a potential sorbent for the removal of oxytetracycline (OTC) from aqueous solutions. The clay is characterized by a cation exchange capacity of 0.756 meq g?1 and a zero point charge at pH 8.7. Aqueous solutions of OTC were equilibrated with montmorillonite under various experimental conditions, such as OTC concentration, pH and clay content, for 24 h at fixed ionic strength. Two forms of montmorillonite were evaluated: regular and iron-modified form. The effect of pH was minor on OTC adsorption. Kinetic study revealed that the sorption follows a pseudo-second-order model. Sorption isotherm showed a good fit with the Freundlich model. OTC sorption onto Fe-saturated montmorillonite was analyzed statistically using a response surface design to study the effects of experimental conditions. The introduction of iron improved the adsorption characteristics of the clay due to the ability of ferric ions to make stable complexes with OTC. The most favorable operating conditions for the treatment were deemed as follows: clay content, 6.85 g L?1, oxytetracycline concentration, 1.0 mmol L?1 and pH, 5.5 for the iron-modified form.  相似文献   

10.
Compacted clay can minimize infiltration of liquid into waste or control the release of contaminated liquids to the surrounding soils and groundwater. Compacted lateritic soil treated with up to 12 % bagasse ash and municipal solid waste (MSW) leachate sourced from a domestic waste land fill were used in diffusion test studies to access the diffusion characteristics of some inorganic species present in the municipal solid waste leachate. Diffusion set-up were prepared containing 0, 4, 8 and 12 % bagasse ash—soil mixes compacted at 2 % wet of optimum using the modified proctor effort. The set up was saturated with water for 30 days before the introduction of MSW leachate and initiation of diffusion test for another 90 days. After diffusion testing, water content within the soil column showed a decrease with depth. Diffusion test results generally showed that diffusion is an active means of transport of chemical species even at very low flow rates in the compacted soil-bagasse ash mixes, and the effective diffusion coefficient is affected by bagasse ash. The pore fluid concentration profile for the various chemical species tested showed that the compacted soil-bagasse ash mix has the capacity to attenuate Ca2+, Pb2+ and Cr3+ ions.  相似文献   

11.
Earthen barriers or clay liners are a major concern in geo-environmental engineering. They are designed to preclude or reduce leachate migration. Hence, a low hydraulic conductivity (k) is an important parameter in the design of clay liners. Materials such as bentonite and lateritic clays, which have a low hydraulic conductivity at high dry densities, are used in the construction of clay liners. Compacted expansive clays which are high in montmorillonite content also have a very low hydraulic conductivity. When expansive clays are blended with fly ash, an industrial waste, the hydraulic conductivity further reduces as the ash-clay blends result in increased dry densities at increased fly ash contents. Hence, fly ash-stabilised expansive clay can also be proposed as an innovative clay liner material. It is, therefore, required to study various physical and engineering properties of this new clay liner material. Liquid limit (LL) and free swell index (FSI) are important index properties to be studied in the case of this clay liner material. The hydraulic conductivity of this new clay liner material depends on the fly ash content in the blend. Further, parameters such as solute concentration and kinematic viscosity also influence hydraulic conductivity of clay liners. This paper presents experimental results obtained on hydraulic conductivity (k) of fly ash-stabilised expansive clay liner at varying fly ash content and solute concentration. The tests were performed with deionised water (DIW), CaCl2, NaCl and KCl as permeating fluids. Fly ash content in the blend was varied as 0, 10, 20 and 30 % by weight of the expansive clay, and the solute concentration was varied as 5 mM (milli molar), 10, 20, 50, 100 and 500. It was found that hydraulic conductivity (k) decreased with increasing fly ash content, solute concentration and kinematic viscosity. Further, hydraulic conductivity (k) was correlated with LL and FSI of the clay liner material for different fly ash contents and solute concentrations. Useful correlations were obtained.  相似文献   

12.
Smectite clay has been proposed for embedding canisters with highly radioactive waste in deep repositories because of its isolating capacity. Montmorillonite-rich bentonite is a premier buffer candidate for many national organizations that are responsible for disposal of such waste. Experience from the use of drilling mud at large depths indicates that other smectite clay minerals are more stable chemically and saponite is one of them. The physical properties of smectitic mixed-layer minerals like Friedland clay are known to be less sensitive to high salt contents and such clay may also be a buffer candidate. Montmorillonite-rich MX-80 clay, Greek saponite with a minor amount of palygorskite, and Friedland clay were investigated in hydrothermal tests with dense samples confined in oedometers with 95 °C temperature at one end, which was made of copper, and 35 °C at the other, for 8 weeks. A 1 % CaCl2 solution was circulated through a filter at the cold end. At the end of the tests, the samples were sliced into three parts, which were tested with respect to expandability, hydraulic conductivity, and chemical composition. The tests showed that while the saponite was hardly changed at all and did not take up any copper, MX-80 underwent substantial changes in physical performance and adsorbed significant amounts of copper. The Friedland clay sample was intermediate in both respects.  相似文献   

13.
In the present work, the adsorption of Ag+ ions on hydrolyzed plant biomass (willow, paulownia, wheat straw and maize stalks) was investigated. Chemical analyses were performed to establish the composition of the obtained materials. Adsorption mechanism, adsorption sites and specific surface areas of these materials were examined by BET analysis, IR spectroscopy, XPS and EPR. The effects of contact time, acidity of initial solutions and Ag+ ion concentrations were followed. Pseudo-first-order, pseudo-second-order and intra-particle diffusion models were used to analyze kinetic data. In all cases, the adsorption was significantly affected by the pH value. Different types of adsorption isotherms of Ag+ ions (either Langmuir or Freundlich) were registered depending on the adsorbing material. The adsorption mechanism is complex, and the process passes through different stages as clustering of Ag+ ions and formation of elemental Ag. The maximal adsorption capacities varied from 2.05 to 6.07 mg g?1. The obtained results revealed that the examined waste lignocellulosic materials are promising adsorbents for Ag+ ions.  相似文献   

14.
Compacted expansive clays swell due to crystalline swelling and osmotic/double layer swelling mechanisms. Crystalline swelling is driven by adsorption of water molecules at clay particle surfaces that occurs at inter-layer separations of 10–22 Å. Diffuse double layer swelling occurs at inter-layer separations >22 Å. The tendency of compacted clay to develop osmotic or double layer swelling reduces with increase in solute concentration in bulk solution. This study examines the consequence of increase in solute concentration in bulk solution on the relative magnitudes of the two swelling modes. The objective is achieved by inundating compacted expansive clay specimens with distilled water and sodium chloride solutions in free-swell oedometer tests and comparing the experimental swell with predictions from Van’t Hoff equation. The results of the study indicate that swell potential of compacted expansive clay specimens wetted with relatively saline (0.4, 1 and 4 M sodium chloride) solutions are satisfied by crystalline swelling alone. Comparatively, compacted clay specimens inundated with less saline solutions (0.005–0.1 M sodium chloride) require both crystalline and osmotic swelling to satiate the swell potential.  相似文献   

15.
Shrinkage Properties of Soft Clay Treated with Cement and Geofibers   总被引：4，自引：2，他引：2  
In this study, effects of two types of geofibers, namely polypropylene and recycled carpet, on three dimensional shrinkage properties of cement treated kaolinite and bentonite clays are investigated. Cement treated clay specimens were prepared with cement contents of 5, 10, and 15 % by weight of dry soil for kaolinite samples, and 30, 40 and 50 % for bentonite samples. To investigate and understand the influence of different fiber types and contents, three different percentages of fiber content (i.e. 0.1, 0.2 and 0.5 % polypropylene fibers; and 0.5, 0.75 and 1 % carpet fibers) were adopted. The results of shrinkage tests on 126 cylindrical samples of cement treated clay with various cement and fiber contents were analysed to understand the relationships between these parameters and the shrinkage percentage of treated soil. Results of this study indicate that combination of cement and fiber is effective in reducing the volume change of clayey soils undergoing drying process. In the applied ranges of cement and fiber contents, the influence of cement addition on the shrinkage reduction is more significant than the addition of fibers for the treated kaolinite. However, addition of fibers in curtailing the shrinkage of bentonite clay is more significant than the cement addition.  相似文献   

16.
The influence of alkaline aqueous solutions on the properties of bentonite was investigated to evaluate the performance of bentonitic engineered barriers when contacted with alkaline groundwater. Batch and hydraulic conductivity tests were conducted on Na-bentonite using six different alkaline aqueous solutions. For the batch tests, almost no change in the montmorillonite fraction of the bentonite was observed after reacting with alkaline solutions (pH = 8.4–13.1), regardless of the solution type. On the other hand, aluminosilicate minerals (e.g., albite) were dissolved and secondary minerals (e.g., anorthite) were formed in alkaline NaOH solutions (pH > 13). The cation (Ca or Na) concentration primarily affected the swelling properties of bentonite rather than the pH of the solution, which was comparable to the results of the hydraulic conductivity tests. For the Ca solutions, the hydraulic conductivity of the bentonite specimen to the 0.02 mol/L Ca(OH)2 solution (6.5 × 10?9 cm/s) was approximately an order of magnitude lower than that of the bentonite specimen to the 0.02 mol/L Ca(OH)2 + 1 mol/L CaCl2 solution (5.0 × 10?8 cm/s), whereas the hydraulic conductivity to the 0.02 mol/L Ca(OH)2 + 1 mol/L CaCl2 solution (pH = 11.3) (5.0 × 10?8 cm/s) was slightly higher than that to the 1 mol/L CaCl2 solution (pHi = 8.4) (4.4 × 10?8 cm/s). For the NaOH solutions with pH > 13, the hydraulic conductivity of the bentonite specimen decreased with increasing Na concentration, suggesting that the effect of Na concentration was more dominant than that of permeant pH.  相似文献   

17.
Due to their potential retention capacity, clay minerals have been proposed for use in the engineered barriers for the storage of high-level radioactive actinides in deep geological waste repositories. However, there is still a lack of data on the sorption of actinides in clays in conditions simulating those of the repositories. The present article examines the sorption of two lanthanides (actinide analogues) in a set of smectitic clays (FEBEX bentonite, MX80 bentonite, hectorite, saponite, Otay montmorillonite, and Texas montmorillonite). Distribution coefficients (Kd) were determined in two media: water and 0.02 mol L−1 Ca, the latter representing the cement leachates that may modify the chemical composition of the water in contact with the clay. The Kd values of the lanthanides used in the experiments (La and Lu) varied greatly (25-50 000 L kg−1) depending on the ionic medium (higher values in water than in the Ca medium), the initial lanthanide concentration (up to three orders of magnitude decrease inversely with lanthanide concentration), and the examined clay (up to one order of magnitude for the same lanthanide and sorption medium). Freundlich and Langmuir isotherms were used to fit sorption data to allow comparison of the sorption parameters among smectites. The model based on the two-site Langmuir isotherms provided the best fit of the sorption data, confirming the existence of sorption sites with different binding energies. The sites with higher sorption affinity were about 6% of the total sorption capacity in the water medium, and up to 17% in the Ca medium, although in this latter site sorption selectivity was lower. The wide range of Kd values obtained regarding the factors examined indicated that the retention properties of the clays should also be considered when selecting a suitable clay for engineered barriers.  相似文献   

18.
Opalinus clay (OPA) is currently being investigated as a potential host rock for radioactive waste repository. The construction of this repository will lead to an excavation-damaged zone (EDZ) in the surrounding. Its sealing ability is crucial for the safety assessment of the geological repository. The sealing ability of OPA has a close relationship with its water retention and gas permeability behaviours. For this purpose, the water retention and gas permeability of OPA and its comparison with the artificial barrier (i.e. bentonite) were investigated in this study. The results show that OPA absorbed less water than granular bentonite material with equal suction. Compared with the other two similar materials (Boom clay and COx argillite), which were selected as natural engineering barriers for nuclear waste storage in Belgium and France, the suction behaviours of OPA are similar to those of COx argillite but notably different from those of Boom clay. The gas permeability tests show that OPA sample is quite sensitive to the changes in confining pressures but is less sensitive to applied gas pressures. Further, it is found that the OPA is more permeable than bentonite barrier after 10.5 years of hydration. Then, the OPA samples were artificially water-saturated. We find that the sealing ability can be recovered after long-time water saturation. However, when comparing with bentonite barrier, it is still a weak zone. This indicates that the EDZ should be paid more attention for the assessment the performance of the nuclear repository.  相似文献   

19.
In this study, the effect of ground granulated blast furnace slag (GGBFS) and recycled construction waste (CW) on bentonite clay stabilisation were investigated. The unconfined compressive strength (UCS) of specimens was evaluated with different combinations of GGBFS and CW over various curing periods. A series of micro analysis tests consisting of scanning electron microscope, energy dispersive spectrometer and X-ray diffraction were also conducted to determine the microstructural arrangement and mineralogical effect of the stabilisation treatment. The UCS results showed an increment in strength after introduction of GGBFS and CW and the longer curing period produced more pronounced results. The optimum additive ratio was calculated as 5 % of slag and 20 % of construction waste under all curing conditions. The micro analytical results also indicated formation of structural bonds between admixtures and bentonite in stabilised specimens, as slag crystals and bentonite particles were observed to occupy the cavities and vesicles on the construction waste grains. However, the experimental data shows that the strength improvement is not significant with the addition of only construction waste.  相似文献   

20.
Shales or highly compacted engineered clay layers are being used as buffers in deep surface nuclear waste repositories. Due to the complex natural structure and fabric of clay and non-clay minerals associated with high in situ stresses, high temperatures, and the practical difficulties in the replication of the field stress and temperature conditions in the lab testing facilities, swell potential from the macro and micro investigations does not provide reliable and universally applicable results. In this study, a comprehensive molecular-level simulation-based volume change constitutive model has been developed for clay minerals incorporating the effects of cation exchange capacity, density, water content, in situ stress state, temperature, exchangeable-cations type and proportion, pore fluids, and the dissolved salts. The molecular simulations were performed using molecular mechanics, molecular dynamics, and Monte Carlo simulation techniques. Comparing the model predictions with the results of the lab tests, the model has been proven to be quite precise in the prediction of the swell potential of these strata under various overburden pressures and temperatures. There is several fold increase in swelling of clay samples at 80 °C as compared to the equivalent specimen tested at 25 °C. The effect of higher temperature is lesser at lower initial water content (higher density) while at higher water content (lower density) the structure has been found to be more vulnerable at higher temperatures. About 100 times higher confining pressure results in the same swell at 80 °C as in its counterpart specimen at 25 °C, the corresponding swell increase factor in case of 50 °C specimens is about 45. A sharp increase in swelling with a drop in in situ pressure emphasizes the probability of higher swell as a result of an accidental reduction in in situ pressure such as the higher concentration of nuclear reactions. In this study, the cohesive energy density (CED) was found to be highly sensitive to various volume change variables, such as water content, density, CEC, type, and percentage of exchangeable and non-exchangeable cations. Contrary to all the previous models, CED-based model developed in this study is universal in nature and can be adopted for any case with minimal basic material input parameters. The good agreement found between the predicted and real values for the swell potential of the undisturbed samples suggests that the model presented here can effectively be used for the assessment of the swelling potential of shale/clay deposits to be used as buffers to the nuclear waste storage.  相似文献   

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