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1.
Concentrations and sinking rates of particulate biogenic silica (BSi), chlorophyll a (chl a) and phaeopigments (phae) (< 3 μm, 3–10 μm, > 10 μm and total), as well as the abundances of the major phytoplankton species, were studied during September 1991 in the Eastern Laptev Sea and the lower Lena River (Siberian Arctic). The highest chl a concentrations were found in two major “new” production regimes of the study area: (1) a deep chl a maximum (5.8 mg chl a m−3) (formed by the diatom Chaetoceros socialis) at 30 m depth on the outer shelf of the northern Laptev Sea, and (2) in the Lena River, where the phytoplankton community was dominated by fresh water diatoms (1.5 to 4.5 mg chl a m−3). Elevated chl a concentrations were also found in the river plume phytoplankton community (dominated by brackish water diatoms), NE of the Lena delta. In the Laptev Sea, the low chl a (0.1 to 3 mg chl a m−3) and high phae concentrations (0.5 to 14 mg phae m−3) indicated that the phytoplankton community (dominated by picoplanktic algae and nanoflagellates) was already senescent and affected by grazing losses. Biogenic silica values were highest in the Lena River (4 to 17 μM) as compared to the low values found in the Laptev Sea (0.3 to 4 μM). The large chl a size fraction, phae and BSi in the Lena River samples revealed the highest measured sinking rates (1.4, 2.3, and 1.5 m d−1, respectively). The formation of a strong halocline, decreasing turbulence, and possible nutrient deficiency resulted in death, disintegration and rapid sedimentation of fresh water diatoms. This was accompanied by a decrease in the BSi concentration and growth of the picoplanktic size fraction (< 3 μm) in the estuarine mixing zone (Gulf of Buorkhaya). Only a minor part of BSi was bound to intact diatom cells (< 3%) in the surface layer, most of which being apparently associated with detrital particles. In the Lena River, approximately 12% of the total silica was bound to BSi fraction, yet elsewhere in the Laptev Sea and in the estuarine mixing zone the BSi:total silica ratio was ≤ 5%. Thus, the results reflected the successional stage of a late summer phytoplankton community, characterized by dominance of small autotrophs and patchy distribution of senescent diatoms no longer able to affect the relative high levels of dissolved silica supplied by the Lena River.  相似文献   

2.
The optimum multiparameter(OMP) method was often used to determine the percentages of water masses based on temperature, salinity and other parameters, like nutrient or dissolved oxygen(DO). There are a number of water masses in the East China Sea(ECS), a marginal sea of the western Pacific Ocean. However, it is difficult to clarify the proportion of water masses using traditional parameters, such as temperature, salinity, nutrient or DO because of the occurring of intensive biogeochemical processes in the near shore and shelf areas. Here, we reported the use of ~(234)U/~(238)Uactivity ratio embedded in the OMP method. The results indicate that seawater in the northern ECS mainly consisted of the estuarine water of Changjiang River(CEW), Kuroshio water(KW), and Yellow Sea Coastal Current(YSCC). In March 2017, the CEW only influenced the offshore waters shallower than30 m; the KW affected the east edge and the YSCC contributed more than 75% in the northern ECS.  相似文献   

3.
The optimum multiparameter (OMP) method was often used to determine the percentages of water masses based on temperature, salinity and other parameters, like nutrient or dissolved oxygen (DO). There are a number of water masses in the East China Sea (ECS), a marginal sea of the western Pacific Ocean. However, it is difficult to clarify the proportion of water masses using traditional parameters, such as temperature, salinity, nutrient or DO because of the occurring of intensive biogeochemical processes in the near shore and shelf areas. Here, we reported the use of 234U/238U activity ratio embedded in the OMP method. The results indicate that seawater in the northern ECS mainly consisted of the estuarine water of Changjiang River (CEW), Kuroshio water (KW), and Yellow Sea Coastal Current (YSCC). In March 2017, the CEW only influenced the offshore waters shallower than 30 m; the KW affected the east edge and the YSCC contributed more than 75% in the northern ECS.  相似文献   

4.
The nearshore shelf of the Beaufort Sea is defined by extreme physical and biological gradients that have a distinctive influence on its productivity and trophic structure. Massive freshwater discharge from the Mackenzie River, along with numerous smaller rivers and streams elsewhere along the coast, produce an environment that is decidedly estuarine in character, especially in late spring and summer. Consequently, the Beaufort coast provides a critical habitat for several species of amphidromous fishes, some of which are essential to the subsistence lifestyle of arctic native populations. Because of its low in situ productivity, allochthonous inputs of organic carbon, identifiable on the basis of isotopic composition, are important to the functioning of this arctic estuarine system. Coastal erosion and river discharge are largely responsible for introducing high concentrations of suspended sediment from upland regions into the nearshore zone. The depletion in the 13C content of invertebrate and vertebrate consumers, which drops about 4–5‰ eastward along the eastern Alaskan Beaufort Sea coast, may reflect the assimilation of this terrestrial organic matter into local food webs. In addition, the large range in 13C values of fauna collected in the eastern Beaufort (nearly 8‰) compared to the same species in the northeastern Chukchi (3‰), indicate a lower efficiency of carbon transfer between trophic levels in the eastern Beaufort. The wider spread in stable isotope values in the eastern Beaufort may also reflect a decoupling between benthic and pelagic components. Isotopic tracer studies of amphidromous fishes in the Simpson Island barrier island lagoon revealed that terrestrial (peat) carbon may contribute as much as 30–50% of their total dietary requirements. On the eastern Alaska Beaufort Sea coast, the δ13C values of arctic cod collected in semi-enclosed lagoons were more depleted, by 3–4‰, compared to fish collected in the coastal Beaufort Sea. Calculations from isotopic mixing equations indicate cod from lagoons may derive 70% of their carbon from terrestrial sources. The δ15N values of lagoon fish were also 4‰ lower than coastal specimens, reflective of the lower δ15N values of terrestrially derived nitrogen (0–1.5‰ compared to 5–7‰ for phytoplankton). The role of terrestrial carbon in arctic estuarine food webs is especially important in view of the current warming trend in the arctic environment and the role of advective processes that transport carbon along the nearshore shelf. Biogeochemical studies of the arctic coastal estuarine environment may provide more insights into the function of these biologically complex ecosystems.  相似文献   

5.
Monsoon-driven biogeochemical processes in the Arabian Sea   总被引：3，自引：0，他引：3  
Although it is nominally a tropical locale, the semiannual wind reversals associated with the Monsoon system of the Arabian Sea result annually in two distinct periods of elevated biological activity. While in both cases monsoonal forcing drives surface layer nutrient enrichment that supports increased rates of primary productivity, fundamentally different entrainment mechanisms are operating in summer (Southwest) and winter (Northeast) Monsoons. Moreover, the intervening intermonsoon periods, during which the region relaxes toward oligotrophic conditions more typical of tropical environments, provide a stark contrast to the dynamic biogeochemical activity of the monsoons. The resulting spatial and temporal variability is great and provides a significant challenge for ship-based surveys attempting to characterize the physical and biogeochemical environments of the region. This was especially true for expeditions in the pre-satellite era.Here, we present an overview of the dynamical response to seasonal monsoonal forcing and the characteristics of the physical environment that fundamentally drive regional biogeochemical variability. We then review past observations of the biological distributions that provided our initial insights into the pelagic system of the Arabian Sea. These evolved through the 1980s as additional methodologies, in particular the first synoptic ocean color distributions gathered by the Coastal Zone Color Scanner, became available. Through analyses of these observations and the first large-scale physical–biogeochemical modeling attempts, a pre-JGOFS understanding of the Arabian Sea emerged. During the 1990s, the in situ and remotely sensed observational databases were significantly extended by regional JGOFS activities and the onset of Sea-viewing Wide Field-of-View Sensor ocean color measurements. Analyses of these new data and coupled physical–biogeochemical models have already advanced our understanding and have led to either an amplification or revision of the pre-JGOFS paradigms. Our understanding of this complex and variable ocean region is still evolving. Nonetheless, we have a much better understanding of time–space variability of biogeochemical properties in the Arabian Sea and much deeper insights about the physical and biological factors that drive them, as well as a number of challenging new directions to pursue.  相似文献   

6.
Behaviour of dissolved and particulate proteinaceous substances in the estuary of the Tama River was investigated through field observations and laboratory experiments. Concentrations of dissolved proteinaceous substances in estuarine water were determined at eight stations between the mouth of the Tama River (TA-15) and a point 16km upstream (TA-8), using the colorimetric method of Lowryet al. (1951) that employs Folin phenol reagent. The results were expressed in terms of Folin phenol active substances (FPAS). It was found that FPAS decreased with increasing salinity and that the proportion of high molecular weight FPAS (molecular weight greater than 100,000) decreased rapidly in the estuary.The shapes, sizes and numbers of amorphous particulate substances stained by Amido Black 10B, called Amido Black active substances (ABAS), were determined under a microscope. The numbers of ABAS retained on Millipore HA filters (mean diameter: 10–80µm) amounted to 450ml–1 in the estuarine water about 6km from the mouth of the estuary (Station TA-12M). Some of these aggregates are considered to be producedin situ by flocculation of high molecular weight FPAS during estuarine mixing. ABAS were also produced in experiments by mixing filtered river water with sea water.  相似文献   

7.
Estuaries are elementary geochemical fronts where river water and seawater mix. Within this mixing zone, iron and other non-conservative elements can undergo complex reactions to form new solid phases. In order to understand authigenic iron oxide formation in the Yangtze River Estuary, two onsite water-mixing sets of experiments were conducted, one by mixing variable amounts of unfiltered Yangtze River water with filtered East China Sea water of different salinity (set 1), the other by mixing variable amounts of filtered Yangtze River water with filtered East China Sea water of different salinity (set 2). In set 2, the minerals newly formed in the course of mixing were investigated by means of a scanning electron microscope fitted with an energy-dispersive X-ray analytical system. It was found that ferrihydrite and lepidocrocite were formed in these mixing experiments, coexisting in nearly equal amounts. These iron oxides appear as aggregated particles with a large grain-size range of several microns to more than 100 μm. The electrolytic properties of seawater played an important role in the formation of these authigenic iron oxides. Kaolinite and organic aggregates were also found in the experimentally mixed pre-filtered waters. Amounts of newly formed suspended matter (set 2) were one to three orders of magnitude lower than those of total suspended matter (TSM) (set 1). This implies that newly formed minerals represent only a very small proportion of TSM in the estuarine mixing zone of the Yangtze River.  相似文献   

8.
A sulfur budget for the Black Sea anoxic zone   总被引：1，自引：0，他引：1  
A budget for the sulfur cycle in the Black Sea is proposed which incorporates specific biogeochemical process rates. The average sulfide production in the water column is estimated to be 30–50 Tg yr−1, occurring essentially in the layer between 500 and 2000 m. About 3.2–5.2 Tg sulfide yr−1 form during sulfate reduction in surface sediments of the anoxic zone. Total sulfur burial in anoxic sediments of 1 Tg yr−1 consists of 10–70% (ca. 40–50% is the average) water column formed (syngenetic) component, the rest being diagenetic pyrite. As a maximum, between 3 and 5 Tg yr−1 contribute sulfide to the bottom water or diffuse downward in the sediment. About 20–50 Tg yr−1 sulfide is oxidized mostly at the chemocline and about 10–20% of this amount (4.4–9.2 Tg yr−1) below the chemocline by the oxygen of the Lower Bosphorus Current. A model simulating the vertical distribution of sulfide in the Black Sea water column shows net consumption in the upper layers down to ca. 500 m, essentially due to oxidation at the chemocline, and net production down to the bottom. On the basis of the calculated budget anoxic conditions in the Black Sea are sustained by the balance between sulfide production in the anoxic water column and oxidation at the chemocline. On average the residence time of sulfide in the anoxic zone is about 90–150 yr, comparable to the water exchange time between oxic and anoxic zones. Hydrophysical control on the sulfur cycle appears to be the main factor regulating the extent of anoxic conditions in the Black Sea water column, rather than rates of biogeochemical processes.  相似文献   

9.
Dissolved trace element (copper, nickel, cadmium, zinc, cobalt, and iron) concentrations were measured in surface water samples collected from 27 stations in the San Francisco Bay and Sacramento—San Joaquin Delta during April, August and December of 1989. The trace element distributions were relatively similar for all three sampling periods, and evidenced two distinct biogeochemical regimes within the estuarine system. The two regimes were comprised of relatively typical trace element gradients in the northern reach and anthropogenically perturbed gradients in the southern reach of the estuary. These dichotomous trace element distributions were consistent with previous reports on the distributions of nutrients and some other constituents within the estuary.In the northern reach, trace element and dissolved phosphate concentrations were non-conservative. Simple estuarine mixing models indicated substantial internal sources of dissolved copper (46–150%), nickel (250–500%) and cadmium (630–780%) relative to riverine inputs in April and August, and sizable internal sinks for dissolved cobalt (> 99%) and iron (> 70%) during the same periods. Dissolved zinc fluxes varied temporally, with a relatively large (135%) internal source in April and a relatively small (29%) internal sink in August.Concentrations of many trace elements (copper, nickel, cadmium, zinc, and cobalt) in the southern reach were anomalously high relative to concentrations at comparable salinities in the northern reach. Mass balance calculations indicated that those excesses were primarily due to anthropogenic inputs (waste-water discharges and urban runoff) and diagenetic remobilization from benthic sediments. The magnitude of these excesses was amplified by the long hydraulic residence time of dissolved constituents within the South Bay.The influence of other factors was evident throughout the system. Notably, upwelling appeared to elevate substantially dissolved cadmium concentrations at the mouth of the estuary and authigenic flocculation appeared to dominate the cycling of dissolved iron in both the northern and southern reaches of the system. Biological scavenging, geochemical scavenging and diagenic remobilization were also found to be important in different parts of the estuary. Additional complementary information is required to quantify accurately these processes.  相似文献   

10.
One of the key concerns in estuarine and coastal environments is eutrophication, which is known to be closely connected to nutrient enrichment. To control and improve surface water quality, nutrient criteria are recommended in order to provide reference conditions for the environment. However, the current datasets of nutrient criteria in China are either designed for surface water or sea water, and as such these are not suitable for assessing estuarine water quality, especially given the unique ecosystem and dynamic properties of estuaries. To address this issue in current estuarine water management, nutrient criteria have been developed for a local estuary in the southeast of China. Segmentation of the Jiulong River Estuary, China was firstly analysed through field investigations carried out during 2013–2014, which resulted in the delineation of three segments characterized by their distinct properties in relation to salinity, hydrology, ecosystems, etc. Historical records from 1997 to 2014 were then analysed using statistical modelling to develop candidate nutrient criteria for the estuary.This stage of the analysis was undertaken in combination with the study of nutrient status records from the 1980s,which were used to establish a baseline reference condition. The recommended criteria values of dissolved inorganic nitrogen(DIN) in Segments Ⅰ, Ⅱ and Ⅲ of the Jiulong River Estuary are 64, 21 and 14 μmol/L,respectively, and the corresponding values for soluble reactive phosphorus(SRP) are 0.89, 0.76 and 0.89 μmol/L,respectively. It should be emphasised that these values are site-dependent, and that different results may be achieved at other locations depending on the physical and biogeochemical characteristics of an estuary, or even a single site within a catchment. It is hoped that by demonstrating a possible methodological approach and methods of nutrient criteria derivation in the Jiulong River Estuary, the current study will offer researchers some fundamental basis from which to begin to develop more complete nutrient criteria indices for the study of nutrient conditions in other estuaries throughout China.  相似文献   

11.
Ongoing climate change and anthropogenic activities are introducing stressors that affect the structure and function of coastal ecosystems. This paper focuses on the fluvial fluxes and estuarine transport of nutrients from a tropical river (Mahanadi River) in Northeastern India and compares select nutrient and water quality parameters between 1983 and 2008. This estuary acts as a perennial source of CO2 with a net annual flux to the atmosphere of about 135 tons. The non‐conservative fluxes showed a net annual removal of 650 and 140 tons of phosphorus and nitrogen from the water column, respectively. Negative biogeochemical feedbacks that decreased the availability of N and P in 2008 relative to 1983 levels indicate major changes in biogeochemical responses towards fluvial fluxes of nutrient.  相似文献   

12.
海洋锋面存在于特征明显不同的2种或多种水系或水团交界处,锋面区域形成的次生环流和辐聚作用可显著影响到海洋中的物质输运与生物生产,故受到海洋学家的广泛关注。研究发现,我国近海陆架存在14个永久性的准静止锋面（渤海海峡锋面、山东半岛沿岸锋面、苏北沿岸锋面、西韩湾锋面、京畿湾锋面、济州岛西锋面、长江环形浅滩锋面、闽浙沿岸锋面、黑潮锋面、台湾沿岸锋面、闽粤沿岸锋面、珠江口沿岸锋面、琼东锋面和北部湾锋面）,且部分海域观测到双锋面、穿刺锋面和锋面波等现象。它们与陆架环流及其他动力过程（如：涡旋、内波等）共同控制着我国边缘海的物质能量输运与交换以及生物生产力格局。近岸物质沿锋面、跨锋面输运与锋区的垂向输送过程对我国边缘海生物地球化学循环和生态过程存在显著季节性影响。冬季到春季,沿岸锋面松弛能够加强物质从近岸向陆架的输运,进而在空间上调制春季藻华暴发的时间与量级;夏季到秋季,我国边缘海存在显著的潮汐锋面系统,锋面的辐聚效应以及次级环流可显著提高锋面区域的营养盐浓度和改善光照水平,对浮游植物的生长聚集起到促进作用,故在富营养化的河口与沿岸海域,锋面区域容易成为赤潮或缺氧高发区。此外,锋面的物理屏障作用使得两侧水团保持相对独立的物理与化学特征,因而在我国边缘海生境区划和生物多样性梯度变化等方面扮演重要角色,这些研究对认识我国边缘海物质循环与生物生产的控制机制具有重要作用。未来仍需充分结合观测与卫星资料,运用多过程耦合的高分辨率模型,深入认识锋面的精细结构与动态变化,加强亚中尺度和小尺度过程及其生态效应的研究。  相似文献   

13.
Generally the large tidal estuaries of the eastern United States, such as Delaware Bay, are characterized by rather high suspended particle concentrations at the landward end and high biological activity at the seaward end. As such, these estuaries can be conceptualized as geochemical and biochemical “reactors” for those processes controlling the transmission of trace elements from fresh to the coastal shelf waters. The efficiency of these reaction processes relative to estuarine flushing will control the residence times of microconstituents in such estuaries.Evidence is drawn from the Delaware estuary to illustrate biogeochemical estuarine reaction processes using salinity distribution data and mass balance calculations. The Delaware retains some of its estuarine trace elements as sedimented estuarine particles, while others are more conservative and largely exported. Those retained by sedimenting processes include trace elements in primarily geochemical (particle reactive) chemistries, while those exported appear recycled by biochemical (nutrient reactive) chemistries. Often, the behavior of trace elements (e.g., Fe, Cd) and nutrients (e.g., PO4) appear biogeochemically linked. Other examples are drawn from mixing studies to illustrate particle interaction, and benthic flux measurements to illustrate limited diagenetic reflux.The residence time of estuarine microconstituents should depend seasonally on the relative turbidity, flushing rate, and primary production of tidally dominated estuaries such as the Delaware. Thus, residence times of the more biogeochemically reactive microconstituents must be substantially shorter (days to weeks) than the average flushing times of these larger estuaries, while the residence times of the less reactive ones should approach such flushing times (weeks to months). True estuarine residence times of microconstituents can only be modeled after using large data sets averaged over time (season, tides) and space (salinity).  相似文献   

14.
This is the first detailed study on the distribution of lead-210 in the Japan Sea water. The content of lead-210 ranged from 9.3±2.1 dph/l in the surface water to 3.4+-0.8 dph/l in the deep water—a quite low content as compared to that in the deep water of the North Pacific. Vertical profiles show that the content of lead-210 abruptly decreases below the seasonal thermocline (10–20 m in depth) and nearly uniform in the deep water. It is suggested that a significant amount of air-borne lead-210 deposited over the Japan Sea is transported along with the Tsushima Current to the open ocean. The budget of lead-210 is calculated by using a simple box-model and the mean residence time of lead-210 in the Japan Sea is estimated to be 15 yr.  相似文献   

15.
The contribution of organic matter (humic compounds) to the alkaline reserve of seawater in the Sea of Japan, in the Razdol’naya River estuarine waters, and in the interstitial waters of the sediments of the Sea of Okhotsk was characterized using two procedures for alkalinity measurements: the method by Bruevich and that of the sample equilibrium with air. It was found that the surface waters of the Sea of Japan contained about 20 μmol/kg of alkalinity of organic origin, and this value twofold decreased with depth. For most of the actual cases of the calculations of the seawater carbonate system, this value may be neglected. Meanwhile, the contribution of organic alkalinity to the Razdol’naya River waters amounts to nearly 120 μmol/kg. It was shown that, if this value in the calculation of the carbonate system of the Razdol’naya River estuary-Amur Bay is neglected, this may cause gross errors in the values of the partial pressure of carbon dioxide (the error might be over 1500 μatm) and in the dissolved inorganic carbon (an error over 150 μmol/kg). The maximum absolute contribution of the humic matter (over 300 μmol/kg) was found for the interstitial waters in selected sediments of the Sea of Okhotsk. In the interstitial waters of these sediments, humic matter concentrations as high as 300 mg/l were detected. The data obtained show that the determination of the amount of humic matter must be an indispensable condition for an adequate analysis of estuarine carbonate systems and of the interstitial water in reduced marine sediments.  相似文献   

16.
In order to investigate the photobleaching potential of estuarine waters from different depths and redox conditions and with varying degree of biological activity, filtered, unfiltered and chloroform-poisoned water samples from the Baltic Sea were exposed to ambient sunlight. Fluorescence, at excitation 350 nm and emission 450 nm, was used as an indication of humic substance concentration. Fluorescence and organic carbon concentration were measured at regular time intervals during light exposure. We found that the decrease in humic substance fluorescence can be fitted to an exponential decay function. The fluorescence half-lives were within the range 0.4 – 4.6 days in different water masses, with fluorescence decreasing to between 20% and 60% of initial concentration, respectively. Results from the curve fitting procedure indicate a rest concentration of humic substance fluorescence, similar among the sampled sites, that is resistant to further photochemical degradation. The largest relative decreases in fluorescence were found in deep waters, but samples from deep waters also had a higher fluorescence rest concentration than samples from surface waters. Biological activity was reduced by filtering the samples through 0.2μm pore size filters or adding chloroform. No statistically significant differences were found after 3 days of irradiation between samples with and without treatment to reduce biological activity. The highest initial fluorescence values and the largest fluorescence decrease were found in the anoxic waters of the Gotland Deep. The organic carbon concentrations decreased 3–7% at all stations. The shortest half-life of humic substance, and the largest decrease in organic carbon concentrations, were found in samples from the northern basins of the Baltic Sea.  相似文献   

17.
Suspended matter (SM) and surface sediments were analysed for polycyclic aromatic hydrocarbons (PAH) throughout the Ob and Yenisei River estuaries and in the Kara Sea in order to evaluate the contamination of Arctic shelves by these two major Siberian rivers. PAH concentrations were extremely low, among the lowest measured up to now in the Arctic region. Particle-associated PAH were in many cases non-detectable. A total PAH maximum value of 3·2ngl − 1was found in surface waters. In surficial sediments, they spanned a range from 24 to 115ngg − 2in the Ob River, from 40 to 131ngg − 2in the Yenisei and from 16 to 94ngg − 2in the Kara Sea. Compositional features revealed a contribution of detrital material eroded from soils of the drainage basins and inputs from airborne pyrolytic PAH emitted at lower latitudes and from industrial complexes in Siberia. Particulate and sedimentary PAH distributions were highly variable both in type and concentration. The Ob and Yenisei estuaries are geographically large features where hydro-dynamical and sedimentary processes are complex. As a consequence, inhomogeneities—in the form of patch-structures—develop and make it difficult to resolve the fate of riverborne constituents based on ship measurements only. Remote sensing in conjunction with oceanographic observations may provide further guidance to study large river systems.  相似文献   

18.
1Introduction TheChangjiang(Yangtze)Riverdrainageba sinliesbetween25°and35°N,andbetween91°and122°E,withatotalareaof1.81×106km2anda populationof4×108.Itpassesthroughadensely populatedareawithwell developedindustryandag riculture,includingShanghai,the  相似文献   

19.
The concentration level of cadmium (Cd) and the regeneration related to phosphate (PO4) were examined at two stations (CM10, CM12) in the eastern Japan Basin in July 1998. The observed Cd concentrations were around 0.2–0.3 nM and 0.5–0.6 nM in the surface and deep layers (Japan Sea Proper Water; JSPW), respectively; the concentration of Cd in the JSPW was much lower than that in the Pacific deep water, which is attributed to its specific formation system (which driven by the winter convection of the surface layer within the Japan Sea, thereafter descending to the deep layer) connected with the relatively active vertical mixing in the Japan Sea. A plot of Cd against PO4 showed good linearity with positive y-intercept values, suggesting that the excess Cd was apparently not available in the biogeochemical cycle. The molecular ratios of consumed O2 to regenerated Cd and PO4 in the JSPW were 688,000, 140 and 881,000, 146 for CM10 and CM12, respectively, and a lower preformed Cd concentration (around 0.37 nM) was also estimated in the JSPW, different from that of the North Pacific deep water (613,000 for Cd, 170 for PO4, and 0.64 nM of preformed Cd).  相似文献   

20.
Nutrients, chlorophyll a, primary production (14C), and standard oceanographic parameters were measured seasonally from 1983 to 1988 along the axis of a karstic estuary of the central Adriatic Sea (the Krka River estuary). Because of anthropogenic phosphorus discharges, the surface-layer orthophosphate concentrations (up to 1.7 mmol m−3), phytoplankton biomass (chlorophyll a up to 23 mg m−3) and primary production (up to 108 mg C m−3 h−1) were significantly higher in ibenik Bay (lower estuary) than in the other estuarine subregions, and the coastal sea in particular. In contrast, nitrate and orthosilicate (up to 59 and 65 mmol m−3, respectively) distributions during autumn and winter were ascribed to dilution of Krka River nutrients along the estuary. As a consequence, the surface-layer inorganic N/P ratio was extremely high in the upper estuary (averages up to 180), but this ratio was reduced up to three times in ibenik Bay and the coastal sea. In spring and summer, nitrate and orthosilicate, but not orthophosphate, were almost exhausted from the water because of biological utilization. In the saline layer below the halocline (depth 2–5 m) oxygen saturation varied over a large range, particularly in the upper estuary (16–176%), and nutrient concentration ratios differed from those in the surface layer. A nutrient regeneration stoichiometric model was derived, based on a linear regression analysis: AOU:Si:N:P = 276:16:6:0.4. Anthropogenic nutrient inputs should be urgently reduced to re-establish a natural nutrient environment.  相似文献   

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