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1.
The deep groundwater in the quaternary gravel sequence of the southern Upper Rhine Graben locally contains high chloride concentrations near the river Rhine between Fessenheim (France) in the South and Breisach (Germany) in the North. This historical pollution is mainly due to past infiltration from the former brine storage basins of the French potash mines on the Fessenheim Island and—to a lesser extent—from the leaching of the salt dumps of the German potash mines in Buggingen and Heitersheim. The spreading of the salt plume was investigated by means of a groundwater model. The aim of the model was to understand the brine movement, the present distribution of chloride as defined by recent hydrochemical investigations, and to select locations for new reconnaissance boreholes. The geological structure was reproduced by a three layer model, which was calibrated for steady state flow conditions. The hydraulic conductivity of the first layer was determined by comparing measured and calculated heads in the model area. The vertical resolution was refined to simulate the density-dependent salt transport processes. The transport of the salt plumes was simulated over a 40-year period, starting at the beginning of brine storage in the 1950s. The relevant transport parameters have been estimated in a sensitivity analysis, where the simulated breakthrough curves of chloride concentration have been compared with the measured data. The results of the groundwater model indicate that brines containing approximately 1 million tons of chloride are still present at the bottom of the aquifer. These highly concentrated salt brines mix with fresh water from the upper part of the aquifer. This dispersive process leads to the formation of a plume of chloride-rich water extending downstream, where pumping wells for several local water supplies are located.  相似文献   

2.
左文喆  任永强  杨豹  刘帅洲 《地球科学》2020,45(4):1427-1438
为了解沉积变质型铁矿床开采后矿区地下水化学特征的变化趋势,在充分掌握矿区含水系统划分和流动系统发育规律的基础上,通过对四含上、四含下、基岩含水层148个水样常规离子的相关性、水化学类型及公因子的分析,得出水化学类型分区和公因子得分等值线,将二者叠加,分析各含水层潜在的形成作用及其控制因素.研究结果表明,四含上以碳酸盐溶滤、污染、氧化作用为主;四含下以污染、溶滤、局部脱硫酸作用为主;基岩含水层以离子交换吸附、第四系水的混合、硅酸盐矿物的不全等溶解作用为主.除了背景因素外,矿山开采后的三维流场控制了基岩含水层的形成作用和原生水化学类型,影响了第四系含水层的局部形成作用,水化学类型分区界线明显移动.   相似文献   

3.
A 3D geological model of the area east of Basel on the southeastern border of the Upper Rhine Graben, consisting of 47 faults and six stratigraphic horizons relevant for groundwater flow, was developed using borehole data, geological maps, geological cross sections, and outcrop data. This model provides new insight into the discussions about the kinematics of the area between the southeastern border of the Upper Rhine Graben and the Tabular Jura east of Basel. A 3D analysis showed that both thin-skinned and thick-skinned tectonic elements occur in the modeled area and that the Anticline and a series of narrow graben structures developed simultaneously during an extensional stress-field varying from E–W to SSE–NNW, which lasted from the Middle Eocene to Late Oligocene. In a new approach the faults and horizons of the 3D geological model were transferred into discrete elements with distributed hydrogeological properties in order to simulate the 3D groundwater flow regime within the modeled aquifers. A three-layer approach with a horizontal regularly spaced grid combined with an irregular property distribution of transmissivity in depth permitted the piezometric head of the steady-state model to be automatically calibrated to corresponding measurements using more than 200 piezometers. Groundwater modeling results demonstrated that large-scale industrial pumping affected the groundwater flow field in the Upper Muschelkalk aquifer at distances of up to 2 km to the south. The results of this research will act as the basis for further model developments, including salt dissolution and solute transport in the area, and may ultimately help to provide predictions for widespread land subsidence risks.  相似文献   

4.
Significant upward movement of mineralized water takes place in the Puebla aquifer system. Preferential groundwater flow paths related to the geological structure and the lowering of the potentiometric surface are suspected to be the prime factors for this intrusion. A combined approach of geochemical and isotope analyses was used to assess the sources of salinity and processes that are controlling the changes in groundwater chemical composition in the Puebla aquifer. Geochemical and isotope data indicate that the likely source of increased solutes is mineralized water from the dissolution of evaporites of the Cretaceous age at the base of the Upper deep aquifer, which is deeper than the intakes of the shallow wells. Dedolomitization and cation exchange seems also to occur along flow paths where sulphate concentrations tend to increase. The deep regional flow paths controls the chemical stratification of groundwater in response to decreased heads through interconnecting vertical and horizontal pathways, such as in the Fosa Atlixco. The results also suggest that high sulphate concentrations originating in the Lower deep aquifer are currently affecting shallow production wells. It is concluded that hydrodynamic aspects together with hydrogeochemical characteristics need to be taken into account to correctly explain the hydrochemical evolution in the stratified aquifer.  相似文献   

5.
同位素与水文地球化学方法在矿井突水水源判别中的应用   总被引：1，自引：0，他引：1  
通过对抚顺老虎台矿区各类水体的同位素及水化学特征研究,阐述了地表水与矿井各开采水平及73003#突水点的同位素和水化学特征及其相互关系,论证了矿井上覆白垩系砾岩含水层与73003#突水点的联系。研究表明：73003#突水点的同位素及水化学特征与地表水及其他开采水平差异较大,而与白垩系砾岩水的同位素及水化学特征相似。根据同位素、水化学特征及混合计算发现,突水点的水是白垩系地下水与第四系地下水的混合,且白垩系砾岩水占67%,占主导作用;矿井突水通道为活化的F1断层。  相似文献   

6.
In the southern Upper Rhine Valley, groundwater has undergone intensive saline pollution caused by the infiltration of mining brines, a consequence of potash extraction carried out during the 20th century. Major and trace elements along with Sr and U isotopic ratios show that groundwater geochemical characteristics along the saline plumes cannot reflect conservative mixing between saline waters resulting from the dissolution of waste heaps and one or more unpolluted end-members. The results imply the occurrence of interactions between host rocks and polluted waters, and they suggest that cationic exchange mechanisms are the primary controlling process. A coupled hydrogeochemical model has been developed with the numerical code KIRMAT, which demonstrates that cationic exchange between alkalis from polluted waters and alkaline-earth elements from montmorillonite present in the host rock of the aquifer is the primary process controlling the geochemical evolution of the groundwater. The model requires only a small amount of montmorillonite (between 0.75% and 2.25%), which is in agreement with the observed mineralogical composition of the aquifer. The model also proves that a small contribution of calcite precipitation/dissolution takes places whereas other secondary mineral precipitation or host rock mineral dissolution do not play a significant role in the geochemical signature of the studied groundwater samples. Application of the model demonstrates that it is necessary to consider the pollution history to explain the important Cl, Na and Ca concentration modifications in groundwater samples taken over 2 km downstream of waste heaps. Additionally, the model shows that the rapidity of the cationic exchange reactions insures a reversibility of the cation fixation on clays in the aquifer.  相似文献   

7.
A combined hydrochemical and stable isotope approach was used to investigate the origin of nitrate in the shallow unconfined groundwater of Kharkiv city, Eastern Ukraine. The contamination was investigated in the context of land use within the catchment area. The observed enrichment of sulfate, chloride and nitrate suggests significant groundwater contamination in the shallow urban aquifer, which is widely used as drinking water source for the urban population. Characteristic nitrate/chloride ratios as well as stable isotope ratios (N and O) of nitrate in the most contaminated springs confirmed that septic waste from leaky sewer systems was the main source of nitrate contamination in the groundwater. Nitrate contamination is linked to the type of land use and sewage treatment regime in the catchment area. It is also modulated by the regional hydrogeology, which determines the susceptibility of a given aquifer toward groundwater pollution. A more quantitative assessment of nitrate sources based on the nitrate isotope analysis alone is rather difficult. However, our study confirms that the combination of hydrochemical tracers, robust land-use analysis and nitrate stable isotope measurements represents a valuable approach to identify the origin of the nitrate contamination.  相似文献   

8.
Major element chemistry, rare-earth element distribution, and H and O isotopes are conjointly used to study the sources of salinisation and interaquifer flow of saline groundwater in the North East German Basin. Chemical analyses from hydrocarbon exploration campaigns showed evidence of the existence of two different groups of brines: halite and halite Ca–Cl brines. Residual brines and leachates are identified by Br?/Cl? ratios. Most of the brines are dissolution brines of Permian evaporites. New analyses show that the pattern of rare-earth elements and yttrium (REY) are closely linked to H and O isotope distribution. Thermal brines from deep wells and artesian wells indicate isotopically evaporated brines, which chemically interacted with their aquifer environment. Isotopes and rare-earth element patterns prove that cross flow exists, especially in the post-Rupelian aquifer. However, even at depths exceeding 2,000 m, interaquifer flow takes place. The rare-earth element pattern and H and O isotopes identify locally ascending brines. A large-scale lateral groundwater flow has to be assumed because all pre-Rupelian aquifer systems to a depth of at least 500 m are isotopically characterised by Recent or Pleistocene recharge conditions.  相似文献   

9.
The thermal history of the south-westernmost Black Forest (Germany) and the adjacent Upper Rhine Graben were constrained by a combination of apatite and zircon fission-track (FT) and microstructural analyses. After intrusion of Palaeozoic granitic plutons in the Black Forest, the thermal regime of the studied area re-equilibrated during the Late Permian and the Mesozoic, interrupted by enhanced hydrothermal activity during the Jurassic. At the eastern flank of the Upper Rhine Graben along the Main Border Fault the analysed samples show microstructural characteristics related to repeated tectonic and hydrothermal activities. The integration of microstructural observations of the cataclastic fault gouge with the FT data identifies the existence of repeated tectonic-related fluid flow events characterised by different thermal conditions. The older took place during the Variscan and/or Mesozoic time at temperatures lower than 280°C, whereas the younger was probably contemporary with the Cenozoic rifting of the Upper Rhine Graben at temperatures not higher than 150°C.  相似文献   

10.
The groundwater extracted from the unconfined Quaternary aquifer is the main source of water supply in El-Tur area. The area is bounded from the east by the elevated basement complex of Southern Sinai and from the west by El-Qabaliyat Ridge. The wadis dissecting these highlands form effective watersheds of the Quaternary aquifer. These wadis form areas of focused recharge. Recharge also occurs directly via the Quaternary sediments covering El-Qaa Plain. Subsurface lateral groundwater flow from the fractured basement contributes significant recharge to the aquifer as well. The aquifer sediment facies affect the type and quality of groundwater. In the eastern part where the aquifer is composed mainly of gravel and coarse sand with fragments of weathered basement, the Na-Cl-SO4 water dominates. In the west where the facies change is rapid and complex, many water types arise. The base exchange index (BEX) is positive in this part reflecting the role of clay minerals in changing the water types via cation exchange. In the east where clays are insignificant in the aquifer, the BEX is negative. In the western part next to El-Qabaliyat Ridge, the wells discharging from the calcareous sand zone have low groundwater salinities compared to the wells discharging from the alluvium. In general, the groundwater salinity increases in the direction of groundwater flow from the northeast to the southwest which reflects the dissolution of aquifer sediments. The concentration relationships between the major ions on one hand and chloride on the other reflect the dissolution of calcium carbonates, precipitation of K- and Mg-bearing minerals, and cation exchange of Ca for Na on clay minerals. The hydrochemical models support these reactions. In addition, they show that the effect of evaporation on the recharge water in the western catchment is about four times its effect on the eastern recharge water which reflects the rapid recharge through the wadis draining the fractured basement. Moreover, the contribution from the eastern catchment in sample No. 23 is more than four-folds the contribution from the western recharge area. The stable isotopes (2H and 18O) show that the Quaternary aquifer is recharging from recent rainfall. However, upward leakage of Paleogene groundwater (depleted in 18O) also occurs. The groundwater level map shows strong overpumping impact especially in the areas close to El-Tur city.  相似文献   

11.
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12.
This paper integrates the results of different techniques—local and regional travel time tomography, reflection seismics, and surface geology. With this integration of different techniques, working on different scales, it is possible to derive a comprehensive picture of the present-day structures in the lithosphere of the Upper Rhine Graben. It is shown that the stucture of the lithosphere is dominated by structures related to the Variscan orogeny. Late stage strike-slip reactivation of the internal faults of the Rhine Graben is observed in the field. This reactivation is of dominant influence on the geomorphology in the southern end of the Upper Rhine Graben.  相似文献   

13.
Thermal water samples and related young and fossil mineralization from a geothermal system at the northern margin of the Upper Rhine Graben have been investigated by combining hydrochemistry with stable and Sr isotope geochemistry. Actively discharging thermal springs and mineralization are present in a structural zone that extends over at least 60 km along strike, with two of the main centers of hydrothermal activity being Wiesbaden and Bad Nauheim. This setting provides the rare opportunity to link the chemistry and isotopic signatures of modern thermal waters directly with fossil mineralization dating back to at least 500–800 ka. The fossil thermal spring mineralization can be classified into two major types: barite-(pyrite) fracture filling associated with laterally-extensive silicification; and barite, goethite and silica impregnation mineralization in Tertiary sediments. Additionally, carbonatic sinters occur around active springs. Strontium isotope and trace element data suggest that mixing of a hot (>100 °C), deep-sourced thermal water with cooler groundwater from shallow aquifers is responsible for present-day thermal spring discharge and fossil mineralization. The correlation between both Sr and S isotope ratios and the elevation of the barite mineralization relative to the present-day water table in Wiesbaden is explained by mixing of deep-sourced thermal water having high 87Sr/86Sr and low δ34S with shallow groundwater of lower 87Sr/86Sr and higher δ34S. The Sr isotope data demonstrate that the hot thermal waters originate from an aquifer in the Variscan crystalline basement at depths of 3–5 km. The S isotope data show that impregnation-type mineralization is strongly influenced by mixing with SO4 that has high δ34S values. The fracture style mineralization formed by cooling of the thermal waters, whereas impregnation-type mineralization precipitated by mixing with SO4-rich groundwater percolating through the sediments.  相似文献   

14.
The changing palaeogeographical pattern of Alpine deposits across the European forelands can be traced by identifying mineral assemblages and establishing the chronology of Pliocene-Pleistocene deposits in Alpine foreland. In the late Miocene, the upper courses of the Rhine and the Aar flowed east from the Swiss molasse plain towards the Danube. In the early Pliocene (Brunssumian, 5-3.2 Ma), these same rivers headed north wards towards the Rhine Graben of Alsace. In the early Reuverian, these streams were captured south of the Rhine Graben by the Doubs. They ceased their northward flow and headed west to feed the Bresse Graben. This phase is dated to the Lower and Middle Reuverian (3.2-2.6 Ma). From the Upper Reuverian (2.6 Ma) to the present day, the Rhine has adapted approximately its present course towards the North Sea, south to north along the Rhine Graben and across the Rhine Schist Massif to feed the Dutch Grabens. This changing pattern of capture and alteration of the hydrographic system of the upper reaches of the Rhine and the Aar can be explained by local tectonic movements.  相似文献   

15.
The study of groundwater impact on the hydrochemical characteristic of groundwater within Mullusi aquifer, west Iraq was conducted using the chemical analysis results in 14 production wells and groundwater levels observation in 17 water wells. The interpretation of hydrochemical phenomena related to ions sources was determined based on spatial analysis maps of various hydrochemical ratios using ArcGis software. The study also determined the relation of groundwater velocity and static water levels with the hydrochemical ratios using statistical application of Curve expert v1.3 program. The variations of ion concentration were examined using the statistical significant differences for chemical constituents of water within Mullusi aquifer. The impact of dewatering due to high exploitation was explained by increasing the magnesium and chloride concentrations and lowering static water levels. Magnesium and chloride concentration may reach their maximum limits for drinking at a groundwater level of 485 m asl. Accordingly, any decline in the water level of Mullusi aquifer that occurs from 4.5 to 30.5 m may cause deterioration in groundwater quality. This study modeled the effect of groundwater depletion on the groundwater quality in a theoretical equations approach.  相似文献   

16.
A large-scale transfer zone subdivides the northern parts of the Upper Rhine Graben into a northern and a southern sub-basin. These sub-basins display the geometry of asymmetric half-grabens with opposing tilt directions. The transfer zone connects the western master fault of the northern half-graben with the eastern master fault of the southern half-graben. In the northern Upper Rhine Graben early syn-rift sedimentation (Late Priabonian to Late Rupelian) was controlled by the tectonically induced subsidence of these half-grabens (autogenetic), as well as by regional third-order sea level variations (allogenetic). Within the graben, lateral changes in subsidence rates (in dip and strike direction of fault blocks) controlled the development of accommodation space and thus, sediment thickness and facies. Furthermore, a low-displacement segment along the western border fault acted as a sediment entry point. Tectonics controlled the distribution of early syn-rift deposits and the palaeogeography of the northern Upper Rhine Graben.  相似文献   

17.
The Upper Rhine Graben (URG) is characterized by a thickness of up to 500 m of unconsolidated Quaternary sediments, providing excellent records of the Rhine river system and its responses to tectonic and climatic changes. The most complete Quaternary sequence of fluvial and limnic-fluvial deposits is found in the Heidelberg Basin, due to its long-term subsidence since the mid-Eocene. The aim of this study is to provide a chronological framework using optically stimulated luminescence (OSL) dating of aeolian and fluvial sands derived from the upper 33 m of a sediment core, which was drilled into the Heidelberg Basin infill close to the village of Viernheim, Germany. The OSL ages demonstrate that the dated fluvial sediments were deposited during the last glacial period (Weichselian) and that there were at least three aggradation periods during this episode. The coversands that cap the sequence were emplaced during the early Holocene.  相似文献   

18.
Groundwater is the most important source of water supply in the Yeniceoba Plain in Central Anatolia,Turkey.An understanding of the geochemical evolution of groundwater is important for the sustainable development of water resources in this region.A hydrogeochemical investigation was conducted in the Plio-Quaternary aquifer system using stable isotopes(δ~(18)O andδD),tritium(~3H),major and minor elements(Ca,Na,K,Mg,Cl,SO_4,NO_3,HCO_3 and Br)in order to identify groundwater chemistry patterns and the processes affecting groundwater mineralization in this system.The chemical data reveal that the chemical composition of groundwater in this aquifer system is mainly controlled by rock/water interactions including dissolution of evaporitic minerals,weathering of silicates,precipitation/dissolution of carbonates,ion exchange,and evaporation.Based on the values of Cl/Br ratio(300 mg/l)in the Plio-Quaternary groundwater,dissolution of evaporitic minerals in aquifer contributes significantly to the high mineralization.The stable isotope analyses indicate that the groundwater in the system was influenced by evaporation of rainfall during infiltration.Low tritium values(generally1 tritium units)of groundwater reflect a minor contribution of recent recharge and groundwater residence times of more than three or four decades.  相似文献   

19.
The present work provides an online Bench II-IRMS technique for the measurement of stable chlorine isotope ratio, which is used to measure the δ37Cl of 38 groundwater samples from the Karst and Quaternary aquifers in Anyang area. The regional distribution and signature of δ37Cl value are characterized on the base of isotopic data. The results suggest that the δ37Cl value of Quaternary groundwater decreases with increasing Cl? concentration, and has no correlation with δ18O and δD values, but closely correlates with the depth to water table. The fractionation mechanism of the chlorine isotope is expounded according to the type of groundwater. The δ37Cl value of karst water is generally positive, which is relevant to the dissolution of evaporite (gypsum mine), and may be caused by the mixing of groundwater and precipitation. The groundwater of Quaternary unconfined aquifer is mainly recharged by precipitation, and the δ37Cl value of groundwater is generally negative. The δ37Cl value of groundwater in Quaternary confined aquifer is more negative with increasing the depth to water level and elevated Cl? concentration, which is possible to result from the isotope fractionation of ion filtration. The groundwater with inorganic pollutants in Quaternary unconfined aquifer has generally a positive δ37Cl value.  相似文献   

20.
本文以水文地球化学理论为指导,基于研究区水文地质条件及矿山水害研究基础,构建了不同充水含水层水化学和氢、氧同位素基础特征值,结合不同煤层埋深煤矿含隔水层组合特征和导水裂隙带发育高度,综合识别了浅埋、中深埋和深埋多个煤矿的矿井水来源。研究结果显示,受水岩作用和水动力条件等因素影响,煤层上覆不同充水含水层地下水水化学类型和氢、氧同位素值差异明显;随着煤层埋深的增大,矿井水的矿化度呈显著增加趋势,氢、氧同位素整体呈减小趋势;在此基础上,综合采用水化学和环境同位素的方法对研究区不同煤层埋深煤矿的矿井涌水进行识别,认为浅埋煤矿矿井水为第四系松散含水层地下水和侏罗系砂岩含水层地下水的混合水,深埋和中深埋煤矿矿井水主要为侏罗系砂岩含水层地下水。  相似文献   

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