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1.
西太平洋分布了全球大部分的洋内俯冲带,也是全球沟-弧-盆体系最发育的地区。勘察加(Kamchatka)半岛位于俄罗斯远东地区,地处太平洋西北部(51°~60°N、155°~164°E),是全球环太平洋岛弧的重要组成部分。前人对勘察加岛弧岩石地幔源区性质、熔融过程、岩浆结晶分异及熔/流体交代过程进行了详细的研究,并获得了丰硕的成果。最新的研究进展表明:(1)勘察加岛弧前缘火山和中部火山的源区主要为亏损地幔,而弧后区域则存在较为富集的地幔贡献;(2)勘察加岛弧不同区域的地幔源区流体性质具有一定的差异,导致从前缘火山至中部火山,地幔熔融程度逐渐降低;(3)勘察加岛弧不同区域岩石地球化学成分存在差异,而且,沿穿弧剖面某些元素或同位素(如δ11 B)表现出系统变化的特征,反应了俯冲板片流体通量和流体性质的差异;(4)勘察加半岛部分多期次火山(如Klyuchevskoy火山)地球化学成分复杂,可能反应了源区熔融条件的不同和岩浆结晶分异过程;(5)勘察加岛弧北部与阿留申岛弧近直角相交,导致异常的构造背景,促使该区域形成了具有埃达克质特征的岛弧岩浆。  相似文献   

2.
《International Geology Review》2012,54(12):1506-1522
Garnet orthopyroxenites from Maowu (Dabieshan orogen, eastern China) were formed from a refractory harzburgite/dunite protolith. They preserve mineralogical and geochemical evidence of hydration/metasomatism and dehydration at the lower edge of a cold mantle wedge. Abundant polyphase inclusions in the cores of garnet porphyroblasts record the earliest metamorphism and metasomatism in garnet orthopyroxenites. They are mainly composed of pargasitic amphibole, gedrite, chlorite, talc, phlogopite, and Cl-apatite, with minor anhydrous minerals such as orthopyroxene, sapphirine, spinel, and rutile. Most of these phases have high XMg, NiO, and Ni/Mg values, implying that they probably inherited the chemistry of pre-existing olivine. Trace element analyses indicate that polyphase inclusions are enriched in large ion lithophile elements (LILE), light rare earth elements (LREE), and high field strength elements (HFSE), with spikes of Ba, Pb, U, and high U/Th. Based on the P–T conditions of formation for the polyphase inclusions (?1.4 GPa, 720–850°C), we suggest that the protolith likely underwent significant hydration/metasomatism by slab-derived fluid under shallow–wet–cold mantle wedge corner conditions beneath the forearc. When the hydrated rocks were subducted into a deep–cold mantle wedge zone and underwent high-pressure–ultrahigh-pressure (HP–UHP) metamorphism, amphibole, talc, and chlorite dehydrated and garnet, orthopyroxene, Ti-chondrodite, and Ti-clinohumite formed during prograde metamorphism. The majority of LILE (e.g. Ba, U, Pb, Sr, and Th) and LREE were released into the fluid formed by dehydration reactions, whereas HFSE (e.g. Ti, Nb, and Ta) remained in the cold mantle wedge lower margin. Such fluid resembling the trace element characteristics of arc magmas evidently migrates into the overlying, internal, hotter part of the mantle wedge, thus resulting in a high degree of partial melting and the formation of arc magmas.  相似文献   

3.
Subduction zone geochemistry   总被引：1，自引：0，他引：1  
Crustal recycling at convergent plate boundaries is essential to mantle heterogeneity.However,crustal signatures in the mantle source of basaltic rocks above subduction zones were primarily incorporated in the form of liquid rather than solid phases.The physicochemical property of liquid phases is determined by the dehydration behavior of crustal rocks at the slab-mantle interface in subduction channels.Because of the significant fractionation in incompatible trace elements but the full inheritance in radiogenic isotopes relative to their crustal sources,the production of liquid phases is crucial to the geochemical transfer from the subducting crust into the mantle.In this process,the stability of specific minerals in subducting crustal rocks exerts a primary control on the enrichment of given trace elements in the liquid phases.For this reason,geochemically enriched oceanic basalts can be categorized into two types in terms of their trace element distribution patterns in the primitive mantle-normalized diagram.One is island arc basalts(IAB),showing enrichment in LILE,Pb and LREE but depletion in HFSE such as Nb and Ta relative to HREE,The other is ocean island basalts(OIB),exhibiting enrichment in LILE and LREE,enrichment or non-depletion in HFSE but depletion in Pb relative to HREE.In either types,these basalts show the enhanced enrichment of LILE and LREE with increasing their incompatibility relative to normal mid-ocean ridge basalts(MORB).The thermal regime of subduction zones can be categorized into two stages in both time and space,The first stage is characterized by compressional tectonism at low thermal gradients.As a consequence,metamorphic dehydration of the subducting crust prevails at forearc to subarc depths due to the breakdown of hydrous minerals such as mica and amphibole in the stability field of garnet and rutile,resulting in the liberation of aqueous solutions with the trace element composition that is considerably enriched in LILE,Pb and LREE but depleted in HFSE and HREE relative to normal MORB.This provides the crustal signature for the mantle sources of IAB.The second stage is indicated by extensional tectonism at high thermal gradients,leading to the partial melting of metamorphically dehydrated crustal rocks at subarc to postarc depths.This involves not only the breakdown of hydrous minerals such as amphibole,phengite and allanite in the stability field of garnet but also the dissolution of rutile into hydrous melts.As such,the hydrous melts can acquire the trace element composition that is significantly enriched in LILE,HFSE and LREE but depleted in Pb and HREE relative to normal MORB,providing the crustal signature for the mantle sources of OIB.In either case,these liquid phases would metasomatize the overlying mantle wedge peridotite at different depths,generating ultramafic metasomatites such as serpentinized and chloritized peridotites,and olivine-poor pyroxenites and hornblendites.As a consequence,the crustal signatures are transferred by the liquid phases from the subducting slab into the mantle.  相似文献   

4.
吴凯  袁洪林  吕楠  张丽鹏 《岩石学报》2020,36(1):141-153
蛇纹石是大洋岩石圈和俯冲带内水和流体活动性元素最重要的载体之一。研究蛇纹石化和蛇纹岩变质脱水过程中流体活动性元素的行为是认识俯冲带元素地球化学循环的关键。蛇纹岩是指主要由蛇纹石类矿物构成的岩石,包括利蛇纹石、纤蛇纹石和叶蛇纹石。蛇纹石化过程中会造成流体活动性元素(B、Li、As、Sb、Pb、Cs、U、Sr和Ba等)的显著富集,并且由于原岩性质、流体成分和氧逸度等条件的不同,大洋岩石圈蛇纹岩和弧前蛇纹岩的特征也略有不同。例如,弧前蛇纹岩具有相对高的As、Sb、B和相对低的U,这反映了俯冲沉积物来源流体的贡献。在俯冲带蛇纹岩的变质脱水过程中,利蛇纹石向叶蛇纹石的转变伴随着矿物内超过50%F和Cl的释放,以及一些流体活动性元素(如B和Li)的迁出;此外,蛇纹石分解形成的变质橄榄石中的流体包裹体指示,蛇纹石脱水分解所产生的流体具有高于原始地幔几个数量级的Cl、Cs、Pb、As、Sb、Ba、Rb、B、Sr、Li和U含量。由于利蛇纹石中的Fe~(3+)含量较叶蛇纹石高,这种矿物相转变过程中也伴随着俯冲通道内的一系列氧化还原过程,从而影响流体性质和新形成的叶蛇纹石的成分。蛇纹岩与岛弧岩浆在流体活动性元素富集规律上的相似性说明蛇纹岩在俯冲带元素循环中扮演着重要的角色。此外,蛇纹石矿物相转变过程中F、Cl、B等元素的释放,可能对于斑岩型金矿、蛇绿岩中的金矿和某些蛇纹岩作为赋矿围岩的硼矿的形成起到重要的作用。  相似文献   

5.
对中国大陆科学钻探工程主孔榴辉岩退变质过程中的微量元素地球化学行为进行了研究。对退变质程度连续变化样品的不同部分的对比研究表明，流体作用下的退变质过程中大离子亲石元素（Cs、Rb、Ba、Sr、K、Th、U）和轻稀土元素表现出较大的活动性，重稀土元素和高场强元素变化相对较小。退变质后大离子亲石元素的显著增加和高场强元素、重稀土元素的轻微变化（甚至相对降低），表明与退变质作用有关的流体中的络阴离子含量很少，并不富集高场强元素和重稀土元素。退变质后总体上表现出的Si、大离子亲石元素和轻稀土元素的明显变化，表明外来流体参与了榴辉岩的退变质过程，带入和带出了一些元素。结合榴辉岩中单矿物微量元素组成以及前人对D^Mineral/Fluid的研究成果，对流体-榴辉岩作用形成的退变质分带（富石英条带→角闪岩→退变质榴辉岩→新鲜榴辉岩）的微量元素组成变化进行了详细研究。结果表明在流体作用下的榴辉岩退变质过程中，大离子亲石元素、轻稀土元素和高场强元素含量的变化除了受退变质流体性质的影响外，更大程度上取决于退变质过程中的矿物相（尤其是副矿物）的变化。  相似文献   

6.
The transfer of fluid and elements from subducting crust to the overlying mantle wedge is a fundamental process affecting arc magmatism and the chemical differentiation of the Earth. While the production of fluid by breakdown of hydrous minerals is well understood, the liberation of trace elements remains generally unconstrained. In this paper, we evaluate the behaviour of trace elements during prograde metamorphism and dehydration using samples of high-pressure, low-temperature metamorphic rocks from New Caledonia. Samples examined include mafic and pelitic rock-types that range in grade from lawsonite blueschist to eclogite facies, and represent typical lithologies of subducting crust. Under lawsonite blueschist facies conditions, the low temperatures of metamorphism inhibit equilibrium partitioning between metamorphic minerals and allow for the persistence of igneous and detrital minerals. Despite this, the most important hosts for trace-elements include lawsonite, (REE, Pb, Sr), titanite (REE, Nb, Ta), allanite (LREE, U, Th), phengite (LILE) and zircon (Zr, Hf). At epidote blueschist to eclogite facies conditions, trace-element equilibrium may be attained and epidote (REE, Sr, Th, U, Pb), garnet (HREE), rutile (Nb, Ta), phengite (LILE) and zircon (Zr, Hf) are the major trace-element hosts. Chlorite, albite, amphibole and omphacite contain very low concentrations of the investigated trace elements. The comparison of mineral trace-element data and bulk-rock data at different metamorphic grades indicates that trace elements are not liberated in significant quantities by prograde metamorphism up to eclogite facies. Combining our mineral trace-element data with established phase equilibria, we show that the trace elements considered are retained by newly-formed major and accessory minerals during mineral breakdown reactions to depths of up to 150 km. In contrast, significant volumes of fluid are released by dehydration reactions. Therefore, there is a decoupling of fluid release and trace element release in subducting slabs. We suggest that the flux of trace elements from the slab is not simply linked to mineral breakdown, but results from complex fluid-rock interactions and fluid-assisted partial melting in the slab.Electronic Supplementary Material Supplementary material is available in the online version of this article at http://dx.doi.org/10.1007/s00410-003-0495-5.Editorial responsibility: J. Hoefs  相似文献   

7.
INTRODUCTIONCompositionally ,the term“boninite”refers to alarge variety of pri mary or near-pri mary ( Mg#=0 .60 -0 .85) magmas with a wide variation of CaO/Al2O3(most range from0 .55 to 0 .75) (Crawford etal .,1989) . With regard to its definition as recom-mended bythe I UGS (Deng et al .,1993) and Hickeyand Frey (1982) ,the classification of boninitic rocksis still a matter of petrological debate ( Qiu et al .,2004) .In general ,rock with some typical geochemi-cal features of bon…  相似文献   

8.
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9.
The prograde deserpentinized peridotites from the talc zone in the Happo-O’ne complex, central Japan, show differences in their field relation and mineral assemblage with the high-P retrograde peridotites of the other part of the complex. They show a mineral assemblage, olivine + talc + antigorite ± prograde tremolite ± chlorite, formed by thermal metamorphism around the granitic intrusion at T, 500-650 °C and P < 7 kbar. The olivine has numerous opaque inclusions and high Fo (91.5-96.5) relative to the retrograde olivine, reflecting its formation by deserpentinization. The prograde tremolite, which is low in Al2O3 (<1.0 wt.%), Cr2O3 (<0.35 wt.%), and Na2O (<0.6 wt.%) but high in Mg# (up to 0.98) and SiO2 (up to 59.9 wt.%), is different in size, shape and chemistry from the retrograde tremolite. The prograde peridotites display a U-shaped REE pattern (0.02-0.5 times PM), similar to diopside-zone retrograde metaperidotites, possible protoliths. They are enriched in LILE (e.g., Cs, Pb, Sr, Rb) relative to HFSE (e.g., Ta, Hf, Zr, Nb), like their protoliths, because of their local re-equilibration with the fluid released during dehydration of the protoliths. They have high contents of REE and some trace elements (e.g., Cs, Th, U, Ta) relative to their protoliths because of an external-element addition from the granitic magma. In-situ analyses of peridotitic silicates confirmed that the prograde tremolite and talc display a spoon-shaped primitive mantle (PM)-normalized REE pattern (0.1-3 times PM) in which LREE are higher than HREE contents. The prograde tremolite is depleted in Al, Na, Cr, Sc, V, Ti, B, HREE and Li, but is enriched in Si, Cs, U, Th, HFSE (Hf, Zr, Nb, Ta), Rb and Ba relative to the retrograde tremolite; the immobile-element depletion in this tremolite is inherited from its source (antigorite + secondary diopside), whereas the depletion of mobile elements (e.g., Li, B, Na, Al) is ascribed to their mobility during the deserpentinization and/or the depleted character of the source of tremolite. The enrichment of HFSE and LILE in the prograde tremolite is related to an external addition of these elements from fluid/melt of the surrounding granitic magma and/or in situ equilibrium with LILE-bearing fluid released during dehydration of serpentinized retrograde metaperidotites and olivine-bearing serpentinites (protoliths). The prograde olivine is higher in REE and most trace-element contents than the retrograde one due to the external addition of these elements; it is enriched in B, Co and Ni, but depleted in Li that was liberated during deserpentinization by prograde metamorphism.  相似文献   

10.
Mafic dikes, which transect the Mesoarchaean Singhbhum Granitoid Complex, are the most abundant members of the Newer Dolerite dikes of the Singhbhum Orissa craton. These dikes are subalkaline and exhibit a tholeiitic differentiation trend. Studied dikes underwent fractional crystallization of clinopyroxene and plagioclase. They show enriched patterns for the light rare earth elements (LREE) and large ion lithophile elements (LILE). On primitive mantle-normalized multi-element patterns, they possess Ba, Nb, Sr, P, and Ti depletions similar to subduction-related basaltic rocks. The high (La/Yb) n and (Gd/Yb) n ratios suggest that the studied mafic dikes were derived by low degrees of partial melting of a garnet-bearing source. Judging by trace elemental ratios (e.g. Ba/Y, Nb/Y, Ba/Th and Th/Nb), the studied dikes were derived from a mantle source metasomatized by a subduction component (e.g. fluids derived by dehydration of the subducting slab). We conclude that interaction between these fluids and the overlying mantle was the main cause of (LREE and LILE) enrichment and Nb (high field strength elements) depletion in the mafic dikes.  相似文献   

11.
Island arc volcanism in the Greater Antilles persisted for >70m.y. from Middle Cretaceous to Late Eocene time. During theinitial 50 m.y., lavas in central Puerto Rico shifted from predominantlyisland arc tholeiites (volcanic phase I, Aptian to Early Albian,120–105 Ma), to calc-alkaline basalts (phase II, LateAlbian, 105–97 Ma), and finally to high-K, incompatible-element-enrichedbasalts (phases III and IV, Cenomanian–Maastrichtian,97–70 Ma). Following an island-wide eruptive hiatus, geochemicaltrends were reversed in the Eocene with renewed eruption ofcalc-alkaline basalts (phase V, 60–45 Ma). Progressiveincreases in large-ion lithophile elements (LILE)/light rareearth elements (LREE), LILE/high field strength elements (HFSE),LREE/HFSE, and HFSE/heavy rare earth elements (HREE) characterizethe compositional evolution of the first four volcanic phases.The shift in trace element compositions is mirrored by increasingradiogenic content of the lavas. Pb  相似文献   

12.
Major and trace element and Sr–Nd–Pb isotopic variationsin mafic volcanic rocks hve been studied in a 220 km transectacross the Kamchatka arc from the Eastern Volcanic Front, overthe Central Kamchatka Depression to the Sredinny Ridge in theback-arc. Thirteen volcanoes and lava fields, from 110 to 400km above the subducted slab, were sampled. This allows us tocharacterize spatial variations and the relative amount andcomposition of the slab fluid involved in magma genesis. TypicalKamchatka arc basalts, normalized for fractionation to 6% MgO,display a strong increase in large ion lithophile, light rareearth and high field strength elements from the arc front tothe back-arc. Ba/Zr and Ce/Pb ratios, however, are nearly constantacross the arc, which suggests a similar fluid input for Baand Pb. La/Yb and Nb/Zr increase from the arc front to the back-arc.Rocks from the Central Kamchatka Depression range in 87Sr/86Srfrom 0·70334 to 0·70366, but have almost constantNd isotopic compositions (143Nd/144Nd 0·51307–0·51312).This correlates with the highest U/Th ratios in these rocks.Pb-isotopic ratios are mid-ocean ridge basalt (MORB)-like butdecrease slightly from the volcanic front to the back-arc. Theinitial mantle source ranged from N-MORB-like in the volcanicfront and Central Kamchatka Depression to more enriched in theback-arc. This enriched component is similar to an ocean-islandbasalt (OIB) source. Variations in (CaO)6·0–(Na2O)6·0show that degree of melting decreases from the arc front tothe Central Kamchatka Depression and remains constant from thereto the Sredinny Ridge. Calculated fluid compositions have asimilar trace element pattern across the arc, although minordifferences are implied. A model is presented that quantifiesthe various mantle components (variably depleted N-MORB-mantleand enriched OIB-mantle) and the fluid compositions added tothis mantle wedge. The amount of fluid added ranges from 0·7to 2·1%. The degree of melting changes from  相似文献   

13.
后弧岩浆作用（rear arc magmatism）是一个新的术语,国内文献大多认为与弧后（back arc）相当,也译为弧后。实际上rear arc 不同于back arc,前者仍然属于弧的范围,而后者已不属于弧结构。目前,对后弧岩浆作用的研究还十分有限, 原因一是 rear arc 出露较少,二是 rear arc 的鉴别标志不清楚。本文尝试对后弧玄武岩（rear arc basalt, RAB）作一个简单的介绍, 并采用对大量数据进行分析比较的方法与典型的岛弧玄武岩（IAB）和弧后盆地玄武岩（BAB）作一个对比。研究表明,后弧玄武岩主要由中-高 K 钙碱性和钾玄岩系列组成, 与典型的 IAB 和 BAB 相比, RAB 富集 Na2O、K2O、P2O5 ,贫CaO。后弧岩浆作用的微量元素具有典型的弧岩浆岩的特点,但LILE 及HFSE 比典型的岛弧岩浆的含量更富集,LREE 明显高于岛弧岩浆岩。 与岛弧岩浆相似,后弧岩浆同样具有明显的Nb-Ta 负异常。研究表明,上述3 类玄武岩很难区分开。但是,BAB 和RAB之间还是有一些不同的,如Sc/Nb-Ba/Y、Cu/P2O5-Y/Zr、Sc/Nb-Sr/Y 以及F2O3 /Zr-Y/Zr 等判别图。本文作者指出,后弧岩浆作用的提出完善了弧结构：一个完整的弧,从海沟向弧的方向,随着板块的俯冲作用,岩浆源区深度增加,地壳混染程度增加,依次出现前弧、弧和后弧岩浆作用, 至弧的后部,洋壳拉张,出现弧后盆地。前弧以玻安岩为代表,弧主要是IAB,后弧为碱性玄武岩,弧后则为MORB（+IAB 的印记）。显然,后弧岩浆作用的提出,对古造山带岛弧结构的恢复、古俯冲方向的确定是有积极意义的。  相似文献   

14.
Peridotites that sample Archean mantle roots are frequentlyincompatible trace element enriched despite their refractorymajor element compositions. To constrain the trace element budgetof the lithosphere beneath the Canadian craton, trace elementand rare earth element (REE) abundances were determined fora suite of garnet peridotites and garnet pyroxenites from theNikos kimberlite pipe on Somerset Island, Canadian Arctic, theirconstituent garnet and clinopyroxene, and the host kimberlite.These refractory mantle xenoliths are depleted in fusible majorelements, but enriched in incompatible trace elements, suchas large ion lithophile elements (LILE), Th, U and light rareearth elements (LREE). Mass balance calculations based on modalabundances of clinopyroxene and garnet and their respectiveREE contents yield discrepancies between calculated and analyzedREE contents for the Nikos bulk rocks that amount to LREE deficienciesof 70–99%, suggesting the presence of small amounts ofinterstitial kimberlite liquid (0·4–2 wt %) toaccount for the excess LREE abundances. These results indicatethat the peridotites had in fact depleted or flat LREE patternsbefore contamination by their host kimberlite. LREE and Sr enrichmentin clinopyroxene and low Zr and Sr abundances in garnet in low-temperatureperidotites (800–1100°C) compared with high-temperatureperidotites (1200–1400°C) suggest that the shallowlithosphere is geochemically distinct from the deep lithospherebeneath the northern margin of the Canadian craton. The Somersetmantle root appears to be characterized by a depth zonationthat may date from the time of its stabilization in the Archean. KEY WORDS: Canada; mantle; metasomatism; peridotite; trace elements  相似文献   

15.
分布于羌塘中部各拉丹冬一带鄂尔陇巴组火山岩，锆石U—Pb同位素年龄值为212Ma，时代属晚三叠世。岩性主要为由玄武岩、安山岩、英安岩、流纹岩和凝灰岩等组成的一套基性一中性一中酸性一酸性岩石组合。主元素以低TiO2、富碱(K2O Na2O)为特征，为钙碱性系列至碱性系列，球粒陨石标准化的稀土元素配分模式为LREE中等富集型，MORB标准化的微量元素配分型式表现为大离子亲石元素K、Rb、Ba及高场强元素Th的高度富集和Ti的亏损，Ba／L平均为32．46，显示岩浆形成于岛弧构造环境。Sr、Nd同位素地球化学也支持这一结论。地质、地球化学及年代学综合分析研究表明，各拉丹冬一带鄂尔陇巴组火山岩形成于晚三叠世岛弧构造环境。  相似文献   

16.
藏北新生代两套钾玄质火山岩系列地球化学特征   总被引：8，自引：2，他引：8  
岩石学和元素地球化学特征研究表明，藏北新生代自南向北沿可可西里岩带和喀喇昆仑—玉门岩带出露有两套钾玄质系列火山岩。它们富集大离子亲石元素(LILE)和轻稀土(LREE)及明显亏损Nb—Ta—Ti，同时具有板内和岛弧(陆弧)的双重特征。源区来源于可能与俯冲带流体有关的相似交代富集地幔，成岩过程主要经历了低度(＜10％)辉石分离结晶作用，同时，源区伴有地壳物质的混染作用。  相似文献   

17.
New 40Ar/39Ar and published 14C ages constrain voluminous mafic volcanism of the Kamchatka back-arc to Miocene (3–6 Ma) and Late Pleistocene to Holocene (<1 Ma) times. Trace elements and isotopic compositions show that older rocks derived from a depleted mantle through subduction fluid-flux melting (>20%). Younger rocks form in a back arc by lower melting degrees involving enriched mantle components. The arc front and Central Kamchatka Depression are also underlain by plateau lavas and shield volcanoes of Late Pleistocene age. The focus of these voluminous eruptions thus migrated in time and may be the result of a high fluid flux in a setting where the Emperor seamount subducts and the slab steepens during rollback during terrain accretions. The northern termination of Holocene volcanism locates the edge of the subducting Pacific plate below Kamchatka, a “slab-edge-effect” is not observed in the back arc region.  相似文献   

18.
The peridotite bodies of the Ulten Zone (Upper Austroalpine, Italian Eastern Alps) are enclosed in Variscan migmatites and derive from a mantle wedge environment. They display the progressive transformation of porphyroclastic spinel peridotites (T=1,200°C; P=1.5 GPa) into fine-grained garnet–amphibole peridotites (T=850°C; P=3 GPa). Detailed bulk-rock and mineral trace element analyses of a sample suite documenting the entire metamorphic evolution of the peridotites revealed several stages of metasomatism. The spinel peridotites derive from a depleted mantle that became enriched in some large ion lithophile element (LILE) and light rare earth elements (LREE). The same signature pertains to clinopyroxene and orthopyroxene, indicating that this metasomatic signature was acquired at the recorded temperature of 1,200°C. Such a temperature is considerably above the wet peridotite solidus and hence the metasomatic agent must have been a hydrous melt. Moreover, the Li-enrichment of the spinel-facies pyroxenes (up to 24 ppm Li) reflects disequilibrium distribution after exchange with a presumably mafic melt. cpx/opx D Li=3–7 and cpx/ol D Li=2.7–8 indicate that the spinel-facies clinopyroxene hosts higher Li amounts than the coexisting minerals. LREE fractionation, variable LREE enrichment, LILE enrichment with respect to HFSE (average clinopyroxene Pb N /Nb N =16–90) in spinel lherzolites can be related to chromatographic effects of porous melt flow. The significant enrichment of pyroxenes from the spinel lherzolites in Pb, U and Li indicates that the metasomatic melt was subduction-related. All these features suggest that the spinel lherzolites formed a mantle wedge layer percolated by melts carrying recycled crustal components and rising from a deeper source of subduction magmas. The garnet + amphibole peridotites equilibrated at temperatures well below the wet solidus in the presence of an aqueous fluid. Bulk-rock trace element patterns display pronounced positive anomalies in Cs, Ba, Pb and U and moderate enrichment in Li, indicating addition of a crustal component to the mantle rocks. Amphibole hosts most of these trace elements. Clinopyroxene displays high LILE/HFSE (Pb N /Nb N =300–600), low Ce/Pb (1.4–2.7 in garnet-facies clinopyroxene compared with 2.6–24.5 in the spinel-facies one) and variable LILE and LREE enrichments. The coupled increase of modal amphibole, Sr and Pb, together with positive Pb–Sr and Pb–U correlations, further indicate that incompatible element influx in these samples was fluid-mediated. In the garnet-facies samples, amphibole and, interestingly, olivine have similarly high Li concentrations as clinopyroxene, leading to cpx/amph D Li=0.7 and cpx/ol D Li=0.7–0.8, the latter being up to ten times lower than in the spinel-facies rocks. Due to its high modal abundance, olivine is the main host of Li in the garnet–amphibole peridotites. The observed metasomatic features provide evidence for the infiltration of an aqueous fluid in the mantle wedge above a subducting slab. This fluid most likely derived from subducted crustal rocks that underwent partial melting. Successive retrograde re-equilibration during exhumation of the garnet peridotite is accompanied by garnet and clinopyroxene breakdown and amphibole formation. This process produced minor changes, such as an increase of HREE and Li in amphibole, and an increase of Li in olivine. The general trace element signature remains essentially unchanged during retrogression and further hydration, indicating that fluids with a similar composition to the one present at the garnet–amphibole peridotite formation, were responsible for increased amphibole formation. The combined evidence from the metamorphic and metasomatic evolution indicates that the peridotites experienced first corner flow in a mantle wedge, followed by subduction and finally entrapment and exhumation within a crustal slab. During their entire history the Ulten peridotites were percolated first by melts and then by aqueous fluids, which added recycled crustal components to the mantle wedge.  相似文献   

19.
Quaternary monogenetic volcanism in the High Cascades of Oregonis manifested by cinder cones, lava fields, and small shields.Near Crater Lake caldera, monogenetic lava compositions include:low-K (as low as 0?09% K2O) high-alumina olivine tholeiite (HAOT);medium-K. calc-alkaline basalt, basaltic andesite, and andesite;and shoshonitic basaltic andesite (2?1% K2O, 1750 ppm Sr at54% SiO2). Tholeiites have MORB-like trace element abundancesexcept for elevated Sr, Ba, and Th and low high field strengthelements (HFSE), and they represent near-primary liquids. Theyare similar to HAOTs from the Cascades and adjacent Basin andRange, and to many primitive basalts from intraoceanic arcs.Calc-alkaline lavas show a well-developed arc signature of highlarge-ion lithophile elements (LILE) and low HFSE. Their Zrand Hf concentrations are at least partly decoupled from thoseof Nb and Ta; HREE are low relative to HAOT. Incompatible elementabundances and ratios vary widely among basaltic andesites.Some calc-alkaline lavas vented near Mount Mazama contain abundantgabbroic microxcnoliths, and are basaltic andesitic magmas contaminatedwith olivine gabbro. A calc-alkaline basalt and a few basaltic andesites have MgOand compatible trace element contents that suggest only minorfractionation. There appears to be a compositional continuumbetween primitive tholeiitic and calc-alkaline lavas. Compositionalvariation within suites of comagmatic primitive lavas, boththoleiitic and calc-alkaline, mainly results from differentdegrees of partial melting. Sources of calc-alkaline primarymagmas were enriched in LILE and LREE by a subduction componentand contained residual garnet, whereas sources of HAOTs hadlower LILE and LREE concentrations and contained residual clinopyroxene.High and variable LILE and LREE contents of calc-alkaline lavasreflect variations in fluid-transported subduction componentadded to the mantle wedge, degree of partial melting, and possiblyalso interaction with rocks or partial melts in the lower crust. Andesites were derived from calc-alkaline basaltic andesitesby fractionation of plagioclase+augite+magnetite+apatite ? orthopyroxeneor olivine, commonly accompanied by assimilation. Many andesitesare mixtures of andesitic or dacitic magma and a basaltic orbasaltic andesitic component, or are contaminated with gabbroicmaterial. Mingled basalt, andesite, and dacite of Williams Craterformed by multi-component, multi-stage mixing of basaltic andesiticmagma, gabbro, and dacitic magma. The wide range of compositionsvented from monogenetic volcanoes near Crater Lake is a resultof the thick crust coupled with mild tectonic extension superimposedon a subduction-related magmatic arc.  相似文献   

20.
滴水沟闪长岩体位于华北板块北缘西段狼山构造带。结合前人的锆石U Pb测年资料,可确定其形成于晚石炭世—早二叠世早期。岩石学及地球化学分析显示岩体属钙碱性系列,相对富集Rb、Ba、Th、K、P等大离子亲石元素,亏损Nb、Ta、Ti等高场强元素,具有低Rb/Sr(005～010)值、高Ba/Rb(1145～2216)值,且A/CNK＜11;REE含量显示,滴水沟闪长岩体为轻稀土富集型,轻、重稀土元素高度分异,轻稀土元素发生明显的分馏作用,铕异常不明显(δEu=092～113),反映了俯冲带岩浆岩的特征,推测其物质来源为幔壳混源型。结合区域构造演化,认为其形成于活动板块边缘(碰撞前)火山弧环境,与晚石炭世晚期古亚洲洋板块向华北板块北缘西段的俯冲有关。  相似文献   

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