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1.
Forty-six crude oil samples were selected from the Ordovician in the northwestern part of the Tahe oilfield for detailed molecular geochemical and isotopic analysis, including group compositions, carbonhydrogen isotopes and gas chroma-tograms of saturated hydrocarbons, as well as the characteristics of terpane, sterane and other biomarkers, indicating that crude oils are of the same origin from different districts in the Tahe oilfield and were derived from the same source kitchen (or oil source formation), i.e., mainly stemming from marine hydrocarbons. Detailed studies of oil physical properties of 25-honpane revealed that such oils have heavy or thick oil qualities due to biodegradation. Comprehensive assessment in terms of five maturity parameters shows that the oils from the Ordovician with Ro values varying from 0.80% to 1.59% are widely distributed in the northwest of the Tahe oilfield. 相似文献
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1 Introduction Since the 1990’s of the 20th century, oil & gas geochemists have shifted their research focus on hydrocarbon source rocks in the past to that on reservoir rocks and oil reservoirs at present; their research field has been expanded from oil & gas exploration to the assessment of oil reservoirs and production & management. Therefore, reservoir geochemistry as a branch disciplinary of organic geochemistry is now attracting great concern of many oil & gas explorers and oilfield en… 相似文献
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冀中坳陷苏桥-文安地区混源油定量识别模式研究--典型原油混合实验及混源油识别模式 总被引：6，自引：1，他引：6
通过典型原油混合实验及其产物的地球化学剖析,揭示当煤成油和下第三系原油混合时,随着下第三系原油的增加,C19三环萜烷,C24四环萜烷,C30重排藿烷,C29甾烷和重排甾烷逐渐变小;而姥鲛烷和植烷,伽马蜡烷和C27甾烷含量则逐渐增加。利用饱和烃生物标志物和芳烃化合物绝对浓度的变化规律,建立了冀中坳陷苏桥-文安地区混源油定量识别模式图版。根据混源油识别的模式,判断苏49井的混源油是由10%的下第三系原油和90%的煤成油混合而成;相反文1021井混源油则是由90%的下第三系原油和10%的煤成油混合而成。 相似文献
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Well Zheng-1 is located in the combined area of the central uplift and the north Tianshan piedmont depression in the Junggar Basin. Two oil-bearing beds are recognized at 4788–4797 m of the Lower Cretaceous Tugulu Formation (K1tg) and 4808.5–4812.5 m of the Lower Jurassic Sangonghe Formation (J1s). The geochemical characteristics of family composition, carbon isotopic composition, saturated hydrocarbons, sterane and terpane biomarkers and carotane of two crude oils are described in this paper. The results show that the geochemical characteristics of the two crude oils are basically similar to each other, indicating they were all derived mainly from the high mature, brine, algae-rich lake facies sediments. Oil-source correlation revealed that crude oils of the two beds were derived mainly from the source rocks of Permian and mixed by the oil derived from the source rocks of Jurassic and Triassic. This is consistent with the geological background with several sets of source rocks in the area studied. 相似文献
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鄂尔多斯盆地吴堡地区上三叠统延长组原油地球化学特征及油源对比 总被引：1，自引：0，他引：1
鄂尔多斯盆地延长组油源一直存在争议,尤以长8~长10油藏的油源问题最为突出。通过吴堡地区延长组长6~长10原油的物理性质、族组成、生物标志化合物等特征,油-油、油-源对比等综合分析,探讨延长组原油的成因,明确各油层组石油来源,为该区的油气勘探与预测提供地质依据。结果显示,长6~长10原油族组分具有饱和烃含量最高,芳香烃次之,非烃和沥青质含量最低的特征。长6~长10均为成熟原油,显示出低等水生生物和高等植物混合成因,但长6原油与长7~长10原油族组成特征存在明显差异。长6原油为长7烃源岩早期烃类运移的结果,其成熟度最低,长7~长10原油为生烃高峰阶段石油运移结果,成熟度较高。长6和长7油藏的原油主要为长7底部张家滩页岩贡献,此外,长7中上部和长6地层中发育的有效烃源岩也有一定贡献。长8油藏原油为混合成因原油,主要为长7底部烃源岩向下运移结果,其次为长8内部烃源岩和长9顶部李家畔页岩之贡献。长9油藏原油主要为李家畔页岩向下倒灌形成,长10油藏可能主要为长92有效烃源岩向下运移成藏。热成熟度不同是导致远离主力烃源岩原油族组分之间差异性的主要原因。 相似文献
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鄂尔多斯盆地陇东地区延长组原油地球化学特征及成因类型划分 总被引：1，自引：0，他引：1
利用原油与岩样抽提物的族组成分离与定量分析、饱和烃色谱色质、芳烃色谱色质等分析测试资料,系统分析了陇东地区延长组原油的地球化学特征,并研究了原油的成因类型。研究表明,陇东地区延长组原油均为正常油,组分以饱和烃馏分为主;原油的母质来源为低等水生生物与陆源高等植物的双重贡献;形成环境为淡水微咸水的水体环境、弱氧化还原的沉积环境;原油为成熟油,属于烃源岩生烃高峰时期的产物。根据C30重排藿烷的相对含量,可将原油划分为3类,第Ⅰ类原油C30重排藿烷含量最低,第Ⅱ类原油C30重排藿烷含量中等,第Ⅲ类原油C30重排藿烷含量最高。其中第Ⅰ类原油最多,来自于长7油页岩,该类原油分布广泛,白豹、西峰、合水、华庆以及姬塬地区均以该类原油为主;第Ⅱ、Ⅲ类原油样品较少,与暗色泥岩关系密切,零星分布于镇北以北,西峰以东地区。 相似文献
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通过系统采集鄂尔多斯盆地东南部甘泉地区原油、砂岩和烃源岩样品,分析了延长组长8段原油地球化学特征,明确了原油成因和来源。研究表明:长8段原油为正常原油,具有低黏度、低初馏点、低凝点和低含硫量的特征;生物来源为混合型输入,形成于弱氧化-弱还原环境,是生油高峰阶段的产物。根据C30重排藿烷和二环倍半萜类分布特征可将原油分为Ⅰ类和Ⅱ类原油,Ⅰ类原油主要分布于长81段,Ⅱ类原油主要分布于长82段。长9段和长8段烃源岩具低C24TeT/C26TT、高-异常高C30重排藿烷含量、低8β(H)升补身烷和8β(H)补身烷含量的特征,长7段烃源岩与之相反。油源对比结果表明,Ⅰ类原油为长7烃源岩贡献,Ⅱ类原油为长8和长9段烃源岩贡献。甘泉地区主要发育长82油藏,其西部原油为长8和长9烃源岩贡献,而东部原油主要为长9烃源岩贡献,长7烃源岩次之。研究认识到长8和长9烃源岩的烃类贡献可能是促使长82段较长81段富集的重要因素,对下步勘探有指导意义。 相似文献
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鄂尔多斯盆地是我国第二大沉积盆地,中生界延长组富含丰富的油气资源。陇东地区位于鄂尔多斯盆地西南部,延长组长3段是该区重要的含油层系。在长3油层组原油特征和油源条件分析的基础上,对长3原油中含氮化合物组成和分布进行了探讨,结合成藏期分析,研究了鄂尔多斯盆地陇东地区长3油层组石油运移特征和注入方向。结果表明,长3油层组原油含氮化合物的分布与组成在纵向和横向上均存在明显的运移分馏效应,较好地指示了该区石油的运移。晚侏罗世至早白垩世,鄂尔多斯盆地延长组长7优质烃源岩进入生烃门限,并开始大量生烃,且以垂向、侧向、垂向-侧向交替式混合运移的方式,从盆地中心和生烃中心向西部和西南侧向运移和充注,油气充注点位于M18、Z71和Z49等井区周边区域。 相似文献
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鄂尔多斯盆地陕北地区长10油源及成藏条件分析 总被引：4，自引：0，他引：4
在鄂尔多斯盆地的陕北志丹地区勘探发现了长10油藏,原油密度为0．8152g／cm^3,全烃色谱图的主峰为nC13～nC15油质较轻。轻烃组分中环烷烃较为丰富,芳烃含量低,呈姥植均势（Pr／Ph为1．21～1.45）,原油的δ^13CP08值为-31．78％。,甾萜烷分布与主要参数特征为：重排藿烷类相对丰度很高、伽马蜡烷低,Ts／Tm比值很高（5.54～7．26）C30^＊／C50藿烷比值高（0．67～0．72）,C29Ts／C30藿烷比值高（0．38～0．52）,甾烷中重排甾烷较高、αβ和βα构型甾烷丰富。ααα-20R构型甾烷呈不对称“V”型分布,反映了较为典型的湖相油型油特征。油-油、油-源对比显不,该区长10原油来自长7优质烃源岩。石油可能是在湖盆中部长7优质烃源岩发育的地区通过垂向倒灌进入长10油层组、经侧向运聚成藏的。据此,预测盆地长9和长10油层组具备良好的成藏与勘探潜力。 相似文献
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The geochemical characteristics of crude oils from Zao-V oil measures in the Shen-jiapu oilfield are systematically described in terms of the fractional composition of crude oils, GC characteristics of saturated hydrocarbon fraction of crude oils and the characteristics of their bio-markers. The deposifional environment, type and evolution of the biological source are also discussed. All pieces of evidence such as low saturated hydrocarbon fraction, high resin and asphalt, high isoprenoid alkane, weak odd-carbon number predominance ( CPI ranging from 1.23 to 1,29, OEP ranging from 1.14 to 1.16) and low sterane and terpane maturity parameters show these crude oils are immature oils. Low Pr/Ph ratios (0.66 -0.88) and high gammacer-ante/C31 hopane ratios ( 0.59 - 0.86 ) indicate the source rocks were formed in a slightly saline to brackish reducing lake depositional environment. Gas chromatographic characteristics of the saturated hydrocarbon fraction and the predominance of C30 hopane in terpane series and C29 sterane in sterane series indicate the biological source of the crude oils is composed mainly of bacterial and algal organic matter, and some algae are perhaps the main contributor of organic matter to the source rocks. 相似文献
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Huaqing area is an important area for oil and gas exploration and development in the Ordos Basin, within which, the Chang 9 oil group of Triassic Yanchang Formation is one of the main intervals for exploration and development (Zhang et al., 2011). Fluid inclusions record abundant oil and gas accumulation information and important oil and gas migration and accumulation history information(Parnell et al., 1998; Parnell, 2010; Jiang et al., 2018). The occurrence, distribution and intersection of the fluid inclusions in diagenetic minerals were observed under microscope. The accurate formation periods of inclusions are key to determine hydrocarbon accumulation periods (Burrus et al., 1985; Zhou et al., 2000; Zhao, 2002). In addition, the fluorescence color and brightness of organic inclusions observed by fluorescence microscopy could be used to roughly identify the oil and gas evolution stages (Zhang et al., 2010). Therefore, the occurrence, distribution and fluorescence characteristics of oil and gas inclusions were important evidence for judging the hydrocarbon accumulation periods. The fluid inclusions in sandstone reservoirs of Chang 9 oil group in Huaqing Area were observed in detail, and the observation results revealed that fluid inclusions were widespread in Chang 9 sandstone and exhibited various types. Through comprehensive analyses, it was considered that the fluid inclusions in Chang 9 sandstone reservoirs indicated three hydrocarbon accumulation periods. 相似文献
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大庆油田杏南开发区东部过渡带原油特征及油源对比 总被引：2，自引：0，他引：2
杏南开发区东部过渡带的原油具有密度低、粘度低、含胶量低、含蜡量高、凝固点高的物性特征,属于典型的轻质油。其饱和烃含量、总烃含量和饱／芳比高,反映了藻类母质油源的输入特征。其正烷烃碳数分布范围为nC15—nC39,呈单峰态分布,主峰碳数为nC23,nC23。全油及族组分碳同位素值较轻。甾烷化合物含量丰富,并含有一定数量的C30—4甲基甾烷,C27,C28与C29甾烷的分布型式呈“L”字型。原油中的五环三萜类化合物含量丰富,主要有藿烷系列、升藿烷系列和r-蜡烷系列等。油源对比研究表明,研究区原油只具有与其东侧三肇凹陷中青一段泥岩大致相同的碳同位素值和甾、萜烷分布特征,表明原油主要来源于该凹陷中的青一段泥岩。 相似文献
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鄂尔多斯盆地西峰油田原油地球化学特征及其成因 总被引：25，自引：5，他引：20
通过对鄂尔多斯盆地西峰油田原油进行系统地采样和高分辨率的GC-MS、IRMS分析,研究了原油的生物标志化合物和碳同位素组成特征,并且进行了油源对比,探讨了其成因。研究资料指示了所研究原油属于同一成因类型;原油有机母质为菌藻类和高等植物,特别是高等植物为原油的形成作出了贡献;原油形成于弱还原和淡水或微咸水环境;原油均为成熟原油;原油地球化学特征和上三叠统延长组长,油层组具有亲缘关系,反映了原油主要来源于长,油层组。这些研究结果为盆地的石油勘探提供了科学依据。 相似文献
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Molecular fossils and sources of Cambrian heavy oil of Well Tadong-2 in the Tarim Basin,Xinjiang, China 总被引：1，自引：1，他引：0
Research on the molecular fossil characteristics of heavy oil from Well Tadong-2 is of great importance to constrain the source
of marine crude oils in the Tarim Basin, Xinjiang, China. The authors synthetically applied the isotope mass spectrograph,
chromatography and chromatography-mass spectrography to the studies of molecular fossil characteristics of heavy oil from
Well Tadong-2 in the Tarim Basin, and the results obtained revealed that heavy oil from Well Tadong-2 is characterized by
high gammacerane, high C28 sterane, low rearranged sterane and high C27-triaromatic steroid, these characteristics are similar to those of Cambrian-Lower Ordovician source rocks, demonstrating
that Cambrian crude oils came from Cambrian-Lower Ordovician source rocks; condensed compounds (fluoranthene, pyrene, benzo[a]anthracene,
bow, benzo fluoranthene, benzopyrene) of high abundance were detected in heavy oil from Well Tadong-2, and the carbon isotopic
values of whole oil are evidently heavy, all the above characteristics revealed that hydrocarbons in the crude oils became
densified in response to thermal alteration. 相似文献
17.
Junping Huang Xiangbo Li Qilin Chen Zhanlong Yang Yanrong Wan Lihua Wei Liwen Long Xiaoguang Liu 《中国地球化学学报》2012,31(3):327-339
In the lower parts of oil reservoirs Chang 9 and Chang 10 of the Yanchang Formation are oil-bearing layers newly found in oil exploration in the Ordos Basin.Based on GC,GC-MS analyses of saturated hydrocarbons from crude oils and source rocks,reservoir fluid inclusions and BasinMod,the origin of crude oils,accumulation period and accumulation models are discussed in combination with other petroleum geology data in this paper.The result shows that(1) there are two different types of crude oils in oil reservoir Chang 9 in the Longdong and Jiyuan regions:crude oils of typeⅠ(Well D86,Well A44,Well A75,Well B227,Well X62 and Well Z150) are mainly de-rived from the Chang 7 source rocks(including mudstones and shales) and distributed in the Jiyuan and Longdong regions;those of typeⅡ(Well Z14 and Well Y427),are distributed in the Longdong region,which are derived from the Chang 9 source rocks.Crude oils from oil reservoir Chang 10 in the Shanbei region are mainly derived from the Chang-9 source rocks;(2) there are two phases of hydrocarbon filling in oil reservoir Chang 9 in the Jiyuan and Longdong regions and oil reservoir Chang 10 in the Shanbei region:The first phase started at the early stage of J2z.The process of hydrocarbon filling was discontinuous in the Late Jurassic,because of the tectonic-thermal event in the Ordos Basin.The second phase was the main accumulation period,and hydrocarbons began to accumulate from the late stage of J2a to the middle-late of K1,mainly at the middle-late stage of K1;(3) there exist two types of accu-mulation models in oil reservoirs Chang 9 and Chang 10 of the Yanchang Formation:source rocks of the reservoirs in oil reservoir Chang 9 in the Jiyuan region and oil reservoir Chang 10 in the Shanbei region,the mixed type of reservoirs on the lateral side of source rocks and source rocks of the reservoirs in oil reservoir Chang 9 in the Long-dong region. 相似文献
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鄂尔多斯盆地古峰庄—王洼子地区长9油层组流体过剩压力与油气运移研究 总被引：4，自引：0，他引：4
近几年,在鄂尔多斯盆地上三叠统长9油层组中不断有新的油气发现,因而对长9油层组石油运移的认识对进一步的勘探开发愈发重要。本文通过对古峰庄－王洼子地区延长组长7—长9油层组流体过剩压力的计算,并结合地球化学特征分析,对该地区长9油藏形成时的油气运移的动力特征进行了研究。结果表明,古峰庄—王洼子地区延长组长9油层组石油和长7油层组烃源岩具有相似的地球化学特征,长9原油可能主要来自于其上部长7油层组源岩。长7油层组源岩层具有远远大于长9油层的过剩压力分布,二者之间具有14 MPa以上过剩压力差值,成为长7油气向长9油层组储层运移的主要动力。 相似文献
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乌兰花凹陷是二连盆地南部新发现的富油凹陷,对乌兰花凹陷原油物理性质和地球化学性质进行了系统的分析以揭示其特征及来源。原油物理性质显示,乌兰花凹陷原油比重（API gravity）介于20.2°~40.0°之间,主体为正常原油。原油生物标志化合物参数表明,不同构造带之间原油特征存在差异,可以划分为两类原油。一类以土牧尔构造带原油为主,具有低姥值比（Pr/Ph）和C21/C23三环萜烷,相对较高的伽马蜡烷/C31藿烷和规则甾烷/C30藿烷的特征,原油主要为烃源岩在成熟阶段早期的产物,主要以藻类来源为主。另一类原油包括赛乌苏和红井构造带原油,具有高姥值比（Pr/Ph）和C21/C23三环萜烷,相对较低的伽马蜡烷/C31藿烷和规则甾烷/C30藿烷,主要为陆源有机质和藻类有机质混合来源,原油具有更高的成熟度。原油碳同位素和正构烷烃单体烃碳同位素表明这两类原油应是一套烃源岩在不同成熟阶段的产物,原油主要来源于南洼槽阿尔善组烃源岩。阿尔善组烃源岩的非均质性和成熟度导致了两类原油的差异。 相似文献