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1.
研究区主要由麻粒岩相变质的孔兹岩系组成，经历了初期、主期、峰期和晚期四个变质阶段。采用多种矿物对地质温压计方法估算，各变质阶段的温压条件分别为６５０－７００℃，０．５ＧＰａ；６７０－８３７℃，０．５３－０．７４ＧＰａ；６８７－９１１℃，０．３４－０５７ＧＰａ；６５０℃，０．３５ＧＰａ。温压条件的变化反映了变质作用 的动态力学过程，表现为顺时的Ｐ－Ｔｔ轨变。具有典型大造山带环境的变质演化特点和动力学 相似文献
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通过评价和优化有关热力学数据，利用冶金物理化学原理建立了钢铁冶金中最为重的Ｆｅ－Ｓｉ－Ｃ三元体系与ＣＯ－ＣＯ２－ＳｉＯ混合气体间硅，碳迁移的热力学数学模型，计算了相关热力学数据并计算机绘制了该体系的Ｐｃｏ２－Ｐｓｉｏ和ｌｇＰｓｉｏ相平衡图。该模型的可靠性１８７３Ｋ高温条件下的一系列的平衡实验中得到了检验。 相似文献
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邻羧基苯基重氮氨基—4—苯基—2—噻唑光度法测定微量铜的研究 总被引：3，自引：0，他引：3
研究了新试剂邻羧基苯基重氮氨基－４－苯基－２－噻唑与Ｃｕ＾２＋的显色反应,在非离子表面活性剂ＴｎｉｔｏｎＸ－１００存在下,于ＰＨ８．６的Ｎａ２Ｂ４Ｏ７－ＨＣｌ缓冲介质中,Ｃｕ＾２＋与该试剂生成１：１的红色配合物,其配合物的最大吸收波长为５１０ｎｍ,摩尔吸光系数为５．４＊１０＾４Ｌ．ｍｏｌ＾－１．ｃｍ＾－１。 相似文献
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This paper presents the results of experiments on the physicochemical conditions for the formation of picaromerite in the five-component brine system K-Na-Mg-Cl-SO4-H2O and the process of isothermal evaporation-crystallization of picromerite from brines.The metastable phase fields of picromerite at 15,10 and 5℃and its stable equilibrium phase field at -5℃ have been established.In addition,the phase equilibrium relationships have also been established for other salt minerals.The lower limit of formation temperature of picromerite has been deduced on the basis of experi-mental results.The isothermal evaporation crystallization path of the invariant assemblage(point D) of picromerite,epsomite,sylvite and halite at 25,15,10 and 5℃ has been revealed.Furthermore,some controversial problems are approached concerning the 25℃“solar” diagram and the 25℃ metastable phase diagram of this system. 相似文献
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Discussed in this paper are the processes of albitization and iron activation during the formation of iron deposits, the transport
and hydrolysis of iron, chemical reaction characteristic of wall-rock alteration responsible for the localization of iron
deposits, the dynamic factors affecting these reactions and systematic variations in pH of ore-forming solutions. A metasomatic
series of Na→ Ca→ Fe is noticed when diorite and dark minerals + anorthite + quartz react with 1–3m NaCl solutions at 400°–500°C.
Hydrolysis of FeCl2 has been experimentally studied as a function of temperature and pressure. It is suggested that the pH of ore-forming solutions
varies in the direction of alkalic→intermediate→acid→intermediate←kalic from early to late stages. 相似文献
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Situated in the Henan-Shaanxi fault-uplift area on the southern margin of the Sino-Korean Paraplatform, the Jinduicheng porphyry
molybdenum deposit is the most important molybdenum producer in China. During Yenshanian the Jinduicheng granite porphyry
was emplaced in metaspilite of the Proterozoic Xionger Group, controlled by a NW-trending fault. Mineral compositions are
mainly quartz (25–40%), microcline and microcline-perthite (27–40%) and plagioclase (An 8–14, 14–32%), associated with minor
biotite and muscovite, and phenocrysts are made up of K-feldspar, quartz and plagioclase. Accessory minerals include magmatite,
apatite and zircon. The porphyry contains SiO2 73.83% and K2O + Na2O 8.06% (with K2O/Na2O ratio being 1.82), beloning to the calc-alkaline series.
Mineralization occurs in the porphyry body and biotitized and hornfelsized spilite within the exocontact zone. The maximum
depth of mineralization reaches 1000 meters below the surface. According to mineral assemblage, ore veins are classified into
five types: (1) pyrite-quartz; (2) pyrite-K-feldspar-quartz; (3) pyrite-molybdenite-quartz; (4) pyrite-molybdenite-K-feldspar-quartz;
and (5) muscovitefluorite-pyrite-molybdenite-quartz.
As the most important economic molybdenum mineral, molybdenite occurs in various forms. Wall-rock alterations show a gross
zonation of K-feldspathization-greisenization → silicification → propylitization from the porphyry outwards, of which silicification
is most intense and has close genetic relationship with Mo mineralization.
Fluid inclusion studies yield homogeneous temperatures ranging from 250 to 240°C, with the main stage between 400 and 300°C.
Gas inclusions frequently coexist with multiphase inclusions containing such daughter minerals as halite, sylvite, molybdenite
and K-feldspar. Under moderate-high temperatures, lowerfo2, highfs2 and weak acidity conditions, boiling of ore-forming fluids is a prerequisite for the precipitation of molybdenite.
Sulfur, oxygen and carbon isotopic compositions suggest that at the high temperature stage (450°C) magmatic water is dominant
and at the main ore-forming stage a mixture of magmatic water and meteoric water is expected. At the late stage, the mixture
is predominated by meteoric water. Sulfur and molybdenum are mostly of magmatic origin. 相似文献
13.
Alfons M. van den Kerkhof Geoffrey H. Grantham 《Contributions to Mineralogy and Petrology》1999,137(1-2):115-132
In the Port Edward area of southern Kwa-Zulu Natal, South Africa, charnockitic aureoles up to 10 m in width in the normally
garnetiferous Nicholson's Point Granite, are developed adjacent to intrusive contacts with the Port Edward Enderbite and anhydrous
pegmatitic veins. Mineralogical differences between the country rock and charnockitic aureole suggest that the dehydration
reaction Bt + Qtz → Opx + Kfs + H2O and the reaction of Grt + Qtz → Opx + Pl were responsible for the charnockitization. The compositions of fluid inclusions
show systematic variation with: (1) the Port Edward Enderbite being dominated by CO2 and N2 fluid inclusions; (2) the non-charnockitized granite by saline aqueous inclusions with 18–23 EqWt% NaCl; (3) the charnockitic
aureoles by low-salinity and pure water inclusions (<7 EqWt% NaCl); (4) the pegmatites by aqueous inclusions of various salinity
with minor CO2. As a result of the thermal event the homogenization temperatures of the inclusions in charnockite show a much larger range
(up to 390 °C) compared to the fluid inclusions in granite (mostly <250 °C). Contrary to fluid-controlled charnockitization
(brines, CO2) which may have taken place along shear zones away from the intrusive body, the present “proximal” charnockitized granite
formed directly at the contact with enderbite. The inclusions indicate contact metamorphism induced by the intrusion of “dry”
enderbitic magma into “wet” granite resulting in local dehydration. This was confirmed by cathodoluminescence microscopy showing
textures indicative for the local reduction of structural water in the charnockite quartz. Two-pyroxene thermometry on the
Port Edward Enderbite suggests intrusion at temperatures of ∼1000–1050 °C into country rock with temperature of <700 °C. The
temperature of aureole formation must have been between ∼700 °C (breakdown of pyrite to form pyrrhotite) and ∼1000 °C. Charnockitization
was probably controlled largely by heat related to anhydrous intrusions causing dehydration reactions and resulting in the
release and subsequent trapping of dehydration fluids. The salinity of the metamorphic fluid in the contact zones is supposed
to have been higher at an early stage of contact metamorphism, but it has lost its salt content by K-metasomatic reactions
and/or the preferential migration of the saline fluids out of the contact zones towards the enderbite. The low water activity
inhibited the localized melting of the granite. Mineral thermobarometry suggests that after charnockite aureole genesis, an
isobaric cooling path was followed during which reequilibration of most of the aqueous inclusions occurred.
Received: 8 November 1998 / Accepted: 21 June 1999 相似文献
14.
The paper presents data on naturally quenched melt inclusions in olivine (Fo 69–84) from Late Pleistocene pyroclastic rocks
of Zhupanovsky volcano in the frontal zone of the Eastern Volcanic Belt of Kamchatka. The composition of the melt inclusions
provides insight into the latest crystallization stages (∼70% crystallization) of the parental melt (∼46.4 wt % SiO2, ∼2.5 wt % H2O, ∼0.3 wt % S), which proceeded at decompression and started at a depth of approximately 10 km from the surface. The crystallization
temperature was estimated at 1100 ± 20°C at an oxygen fugacity of ΔFMQ = 0.9–1.7. The melts evolved due to the simultaneous
crystallization of olivine, plagioclase, pyroxene, chromite, and magnetite (Ol: Pl: Cpx: (Crt-Mt) ∼ 13: 54: 24: 4) along the tholeiite evolutionary trend and became progressively enriched in FeO, SiO2, Na2O, and K2O and depleted in MgO, CaO, and Al2O3. Melt crystallization was associated with the segregation of fluid rich in S-bearing compounds and, to a lesser extent, in
H2O and Cl. The primary melt of Zhupanovsky volcano (whose composition was estimated from data on the most primitive melt inclusions)
had a composition of low-Si (∼45 wt % SiO2) picrobasalt (∼14 wt % MgO), as is typical of parental melts in Kamchatka and other island arcs, and was different from MORB.
This primary melt could be derived by ∼8% melting of mantle peridotite of composition close to the MORB source, under pressures
of 1.5 ± 0.2 GPa and temperatures 20–30°C lower than the solidus temperature of “dry” peridotite (1230–1240°C). Melting was
induced by the interaction of the hot peridotite with a hydrous component that was brought to the mantle from the subducted
slab and was also responsible for the enrichment of the Zhupanovsky magmas in LREE, LILE, B, Cl, Th, U, and Pb. The hydrous
component in the magma source of Zhupanovsky volcano was produced by the partial slab melting under water-saturated conditions
at temperatures of 760–810°C and pressures of ∼3.5 GPa. As the depth of the subducted slab beneath Kamchatkan volcanoes varies
from 100 to 125 km, the composition of the hydrous component drastically changes from relatively low-temperature H2O-rich fluid to higher temperature H2O-bearing melt. The geothermal gradient at the surface of the slab within the depth range of 100–125 km beneath Kamchatka
was estimated at 4°C/km. 相似文献
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Located adjacent to the Banded Gneissic Complex, Rampura–Agucha is the only sulfide ore deposit discovered to date within
the Precambrian basement gneisses of Rajasthan. The massive Zn–(Pb) sulfide orebody occurs within graphite–biotite–sillimanite
schist along with garnet–biotite–sillimanite gneiss, calc–silicate gneisses, amphibolites, and garnet-bearing leucosomes.
Plagioclase–hornblende thermometry in amphibolites yielded a peak metamorphic temperature of 720–780°C, whereas temperatures
obtained from Fe–Mg exchange between garnet and biotite (580–610°C) in the pelites correspond to postpeak resetting. Thermodynamic
considerations of pertinent silicate equilibria, coupled with sphalerite geobarometry, furnished part of a clockwise P–T–t path with peak P–T of ∼6.2 kbar and 780°C, attained during granulite grade metamorphism of the major Zn-rich stratiform sedimentary exhalative
deposits orebody and its host rocks. Arsenopyrite composition in the metamorphosed ore yielded a temperature [and log f(S
2)] range of 352°C (−8.2) to 490°C (−4.64), thus indicating its retrograde nature. Contrary to earlier research on the retrogressed
nature of graphite, Raman spectroscopic studies on graphite in the metamorphosed ore reveal variable degree of preservation
of prograde graphite crystals (490 ± 43°C with a maximum at 593°C). The main orebody is mineralogically simple (sphalerite,
pyrite, pyrrhotite, arsenopyrite, galena), deformed and metamorphosed while the Pb–Ag-rich sulfosalt-bearing veins and pods
that are irregularly distributed within the hanging wall calc–silicate gneisses show no evidence of deformation and metamorphism.
The sulfosalt minerals identified include freibergite, boulangerite, pyrargyrite, stephanite, diaphorite, Mn–jamesonite, Cu-free
meneghinite, and semseyite; the last three are reported from Agucha for the first time. Stability relations of Cu-free meneghinite
and semseyite in the Pb–Ag-rich ores constrain temperatures at >550°C and <300°C, respectively. Features such as (1) low galena–sphalerite
interfacial angles, (2) presence of multiphase sulfide–sulfosalt inclusions, (3) microcracks filled with galena (±pyrargyrite)
without any hydrothermal alteration, and (4) high contents of Zn, Ag (and Sb) in galena, indicate partial melting in the PbS–Fe0.96S–ZnS–(1% Ag2S ± CuFeS2) system, which was critical for metamorphic remobilization of the Rampura–Agucha deposit. 相似文献
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Rajib Kar 《Journal of Earth System Science》2007,116(1):21-35
The granulite complex around Jenapore, Orissa, Eastern Ghats granulite belt, bears the imprint of two episodes of strong deformation
(D1 and D2) attended with foliation (fabric) development (S1 and S2). Two distinct metamorphic events at P-T conditions of ∼900°C at ∼9 kbar and ∼600°C at ∼6 kbar are correlated with D1 and D2 respectively. The reaction textures in S1-microdomains are interpreted to be the product of near isobaric cooling at ∼9 kbar from 950°C to 600°C, whereas those in
the S2-microdomains are considered to be the result of an up-pressure trajectory from ∼6 kbar at 600°C. The D1-M1 high P-T granulite event is interpreted to be Archean in age (ca. 3 Ga) on the basis of the isotopic data obtained from the charnockite
suite of the area. The later relatively low P-T granulite facies event, attendant to D2-S2 is considered to be related to the Grenvillian orogeny as represented by the dominant isotopic record in the belt. 相似文献
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An experimental study of dissolution kinetics of Calcite, Dolomite, Leucogranite and Gneiss in buffered solutions at temperature 25 and 5°C 总被引：1，自引：0，他引：1
Laboratory experiments were carried out continuously for 30–35 days at 25 and 5°C in three different buffer solutions of pH
4.0, 2.2 and 8.4 to calculate dissolution rates of two minerals, calcite (CC) and dolomite (DM) and two rocks, leucogranite
(LG) and gneiss (GN) from the Himalayan range. Calculated rates in terms of release of targeted elements versus time (Ca for
CC; Mg for DM; Si for LG and GN) demonstrate direct correlation with temperature. Dissolution rates are higher at 25°C compared
to 5°C. CC and DM were experimented only at pH 8.4 and results show that both undergo congruent dissolution with CC dissolving
∼5 times faster than DM. Ca and Mg exhibit average apparent activation energies (E
a) of 13.98 and 9.98 kcal mol−1 respectively at pH 8.4 which reflects greater sensitivity of CC dissolution than DM dissolution towards an increase in temperature.
Scanning Electron Microscope attached with Energy Dispersive X-Ray Analyser (SEM-EDX) data indicates that dissolution is controlled
primarily by surface-reaction processes, with dislocation sites contributing maximum to the dissolution. As compared to CC
and DM dissolution, LG and GN undergo relatively slower incongruent dissolution with precipitation of some secondary minerals
as revealed from X-ray diffractometer (XRD) results. Rates of dissolution of LG is maximum at pH 2.2, moderate at pH 8.4 and
least at pH 4.0, whereas GN shows maximum dissolution at pH 2.2, moderate at pH 4.0 and least at pH 8.4. A comparison in dissolution
behavior of LG and GN at experimental conditions reveals that increase in Si-release rate in the temperature range between
5 and 25°C is maximum at pH 8.4 (∼3.4–4.5 times), moderate at pH 4.0 (∼3–1.8 times) and least at pH 2.2 (∼1.0–1.5 times).
Within the experimental temperature range, calculated values of E
a for Si release during LG and GN dissolution advocates positive correlation with pH. A substantial decrease in initial values
of Brunauer–Emmett–Teller (BET) surface area of DM, LG, and GN has been encountered at the end of the experiment, except for
CC for which an increase is observed. The study clearly demonstrates the dissolution behavior of pure minerals and rocks under
controlled conditions. The dissolution rates assume enormous significance for the release of trace elements from rocks/minerals
to the reacting water. 相似文献
18.
Factors controlling copper solubility and chalcopyrite deposition in the Sungun porphyry copper deposit, Iran 总被引：14，自引：0，他引：14
The Sungun porphyry copper deposit is hosted in a Diorite/granodioritic to quartz-monzonitic stock that intruded Eocene volcanosedimentary
and Cretaceous carbonate rocks. Copper mineralization is associated mainly with potassic alteration and to a lesser extent
with sericitic alteration. Based on previously published fluid inclusion and isotopic data by Hezarkhani and Williams-Jones
most of the copper is interpreted to have deposited during the waning stages of orthomagmatic hydrothermal activity at temperatures
of 400 to 300 °C. These data also indicate that the hydrothermal system involved meteoric waters, and boiled extensively.
In this work, thermodynamic data are used to delineate the stability fields of alteration and ore assemblages as a function
of fS2, fO2 and pH. The solubility of chalcopyrite was evaluated in this range of conditions using recently published experimental data.
During early potassic alteration (>450 °C), Copper solubility is calculated to have been >50 000 ppm, whereas the copper content
of the initial fluid responsible for ore deposition is estimated, from fluid inclusion data, to have been 1200–3800 ppm. This
indicates that initially the fluid was highly undersaturated with respect to chalcopyrite, which agrees with the observation
that veins formed at T > 400 °C contain molybdenite but rarely chalcopyrite. Copper solubility drops rapidly with decreasing temperature, and at
400 °C is approximately 1000 ppm, within the range estimated from fluid inclusion data, whereas at 350 °C it is only 25 ppm.
These calculations are consistent with observations that the bulk of the chalcopyrite deposited at Sungun is hosted by veins
formed at temperatures of 360 ± 60 °C. Other factors that, in principle, may reduce chalcopyrite solubility are increases
in pH, and decreases in fO2 and aCl−. Our analysis shows, however, that most of the change in pH occurred at high temperature when chalcopyrite was grossly undersaturated
in the fluid, and that the direction of change in fO2 increased chalcopyrite solubility. We propose that the Sungun deposit formed mainly in response to the sharp temperature
decrease that accompanied boiling, and partly as a result of the additional heat loss and decrease in aCl−, which occurred as a result of mixing of acidic Cu-bearing magmatic waters with cooler meteoric waters of lower salinity.
Received: 8 July 1998 / Accepted: 8 April 1999 相似文献
19.
Geological and structural controls on gold mineralization in the Tanami District, Northern Territory
Gold mineralization in the Tanami district is hosted within moderately northwest dipping turbiditic sedimentary and basaltic
volcanic rocks of the Paleoproterozoic Mt. Charles Formation. The gold occurs within a complex sinistral wrench-fault array
and associated veins and alteration haloes. The main mineralized faults have a northerly trend and dip steeply east. Subsidiary
structures trend at 030° and 070° and dip towards the southeast. Paleostress calculations based on fault striation populations
and geometry (strike and dip) of faults indicate that at the time of the mineralizing event, σ
1 was sub-horizontal and SE–NW directed with σ
2 subvertical. Structural studies indicate that the mineralization occurred after the regional folding event and synchronous
with the emplacement of felsic dykes into the mine sequence. Gold veins in the Tanami district are interpreted to be part
of an outer thermal aureole gold system that formed during the emplacement of granitoids in the nearby ∼1,815 to ∼1,799 Ma
Frankenia and/or Coomarie domes. Economic gold mineralization occurred late in the paragenetic history of the district. Gold
is hosted by quartz-carbonate veins within shear zones, and also in the surrounding sericite- quartz- pyrite ± carbonate-altered
wallrocks. Gold-mineralized veins precipitated at depths of 3 to 6 km from high temperature (∼300°C), low salinity (∼5 wt%
NaCl equivalent) fluids with low CO2 contents. Barren quartz, dolomite and calcite veins that occur in pre- and post-mineralization thrust faults formed from
high salinity (∼20 wt% NaCl equivalent), low temperature (∼120–150°C) basinal brines. Pyrite in the gold mineralized veins
and alteration halos has lower δ
34S values (6.8 to 12.5‰) than local diagenetic pyrite (17.8 to 19.2‰) or pyrite in pre-mineralization thrust faults (31.7 to
37.1‰). The mineralizing fluids are inferred to have contained a well-homogenized mixture of magmatic and sedimentary-derived
sulfur.
Editorial handling: D. Huston 相似文献
20.
1IntroductionTheHongshijinggolddepositislocatedinthenorthofLuobupouLakeofRuoqiang ,about 30 0kmsouthwestofHamiCity ,Xinjiang .ItwasdiscoveredbytheSixthGeologicalTeamofXinjiangduringgeo chemicalexploration .TheHongshijinggolddeposit,whichoccursinthegold bearingformationcomposedofMiddleandLateCarboniferousvolcanicandpyroclasticrocks ,isabrittle ductileshearzonetypegolddepositcontrolledbyariftbelt.TheHongshijinggolddepositislocatedinthesouthwestoftheHongshi jing -Maotoushanmineralizationb… 相似文献