共查询到20条相似文献，搜索用时 62 毫秒
1.
通过差热-热重分析、X射线粉末衍射（XRD）及磁化率分析等手段,对天然黄铁矿样品在氮气中受热发生的矿物相 变过程进行了综合研究。不同温度下黄铁矿煅烧产物的XRD物相分析结果显示,低于500℃时,黄铁矿无显著变化;随着 温度的升高（500~600℃）,黄铁矿开始转变为单斜磁黄铁矿,进而生成六方磁黄铁矿,磁化率显著升高;700℃~800℃的 煅烧产物主要为六方磁黄铁矿,磁化率明显下降,直至900℃进一步形成更稳定的陨硫铁（FeS）,磁化率接近于零。在黄 铁矿物相开始转变的温度（500~600℃）区间,黄铁矿生成单斜磁黄铁矿的速率大于单斜磁黄铁矿转化为六方磁黄铁矿的速 率;高温（700~900℃）时,黄铁矿转化为单斜磁黄铁矿的速率低于单斜磁黄铁矿转化为六方磁黄铁矿的速率,表现为黄铁 矿直接生成六方磁黄铁矿。 相似文献
2.
磁黄铁矿是铜陵冬瓜山矿床中最重要的矿石矿物之一,其标型特征不仅反映其自身形成环境,对矿床成因也具有指示意义。本文选取矿床中不同层位的磁黄铁矿矿石样品,利用矿相学、X射线衍射、电子探针和同位素分析等手段对磁黄铁矿标型形态、成分、结构以及物质来源进行了分析。研究表明：磁黄铁矿主要分布在矿体的中部,根据磁黄铁矿与其共生矿物之间的交代关系,认为金属矿物的生成顺序是黄铁矿→磁黄铁矿→黄铜矿→磁铁矿。X射线衍射显示磁黄铁矿以六方和单斜相为主,近岩体处主要是六方晶系;远岩体处则以单斜晶系为主。且见单斜沿六方磁黄铁矿的边部有交代现象,显示出热液交代作用的特征。电子探针测试显示磁黄铁矿的Fe元素含量为58.435％～60.978％,平均值为59.737％;S元素含量为38.297％～39.891％,平均值为38.696％,分子式为Fe4S5～Fe9S10,也显示磁黄铁矿有六方和单斜两个相,单颗粒成分剖面显示其核部为六方相,边部为单斜相。磁黄铁矿的δ34S组成均为-0.7‰～+13.5‰之间,δ57Fe的总体分布范围为0.49‰～0.52‰,Fe同位素和S同位素显示它们均来源于岩浆及其热液。说明磁黄铁矿具有岩浆成因和热液交代成因。支持冬瓜山矿床是与燕山期岩浆活动有关的矽卡岩型矿床观点。 相似文献
3.
P.S. Minyuk E.E. Tyukova T.V. Subbotnikova A.Yu. Kazansky A.P. Fedotov 《Russian Geology and Geophysics》2013,54(4):464-474
Dependences of magnetic susceptibility (MS) on the temperature of natural iron sulfide samples (pyrite, marcasite, greigite, chalcopyrite, arsenopyrite, pyrrhotite) from the deposits of northeastern Russia were studied. The thermal MS curves for pyrite and marcasite are the same: On heating, MS increases at 420–450 °C, and unstable magnetite (maghemite) and monoclinic pyrrhotite with a well-defined Hopkinson peak are produced. In oxygen-free media with carbon or nitrogen, magnetite formation is weak, whereas pyrrhotite generation is more significant. The heating curves for chalcopyrite are similar to those for pyrite. They show an increase in MS at the same temperatures (420–450 °C). However, stable magnetite is produced, whereas monoclinic pyrrhotite is absent. In contrast to that in pyrite, marcasite, and chalcopyrite, magnetite formation in arsenopyrite begins at > 500 °C. Arsenopyrite cooling is accompanied by the formation of magnetite (S-rich arsenopyrite) or maghemite (As-rich arsenopyrite) with a dramatic increase in MS. Arsenopyrite with an increased S content is characterized by insignificant pyrrhotite formation. Greigite is marked by a decrease in MS on the heating curves at 360–420 °C with the formation of unstable cation-deficient magnetite.Monoclinic pyrrhotite is characterized by a decrease in MS at ～ 320 °C, and hexagonal pyrrhotite, by a transition to a ferrimagnetic state at 210–260 °C. The addition of organic matter to monoclinic pyrrhotite stimulates the formation of hexagonal pyrrhotite, which transforms back into monoclinic pyrrhotite on repeated heating. The oxidation products of sulfides (greigite, chalcopyrite) show an increase in MS at 240–250 °C owing to lepidocrocite. 相似文献
4.
Lutz Kübler 《Physics and Chemistry of Minerals》1982,8(1):8-13
X-ray diffraction and microprobe analyses of pseudomonocrystalline fragments of pyrrhotite from Bodenmais, Bavaria, revealed continuous gradients in composition and phase distribution. The gradients extend from the well-developed (0001) cleavage surfaces 15–30 μm into the bulk of the crystals. The phase gradient is made up two low-temperature pyrrhotites with monoclinic (4C) and hexagonal (5C) symmetry. The fraction of monoclinic pyrrhotite, expressed on the basis of recorded X-ray intensities, I, decreases exponentially according to I (mon)/[I (hex)+I (mon)] = EXP (aX+b) where a is a constant ranging from ?0.04 to ?0.25, X is the depth from the (0001) cleavage surface in μm, and b is a constant determined by the intensity ratios obtained from the untreated cleavage surfaces. The phase gradient developed during retrograde reactions from a continuous composition gradient. This primary gradient was caused by the extraction of iron from a disordered, high-temperature hexagonal pyrrhotite during oxidation of the cleavage surfaces at temperatures above 254° C (upper stability limit of 4C pyrrhotite), probably above 308° C. The length of the c axis of the monoclinic superstructure slightly increases with the increase in iron and decrease in vacancy content of the bulk. This expansion is probably due to a minor compositional variation of the monoclinic phase controlled by the availability of vacancies during the transition to low-temperature phases. 相似文献
5.
Michael E. Fleet 《Physics and Chemistry of Minerals》1982,8(6):241-246
Smythite and monoclinic Fe3S4 have been identified by X-ray diffraction procedures in quenched ironsulfide compositions. Both phases appear to be metastable under the conditions of the experiments and their development is structurally induced. Smythite occurs as a coherent twinned intergrowth with hexagonal 3C pyrrhotite. Individual single crystals contain about 50% smythite. Reciprocal lattice rows with h-k ≠ 3n show continuous diffraction streaks. The available data suggest that smythite forms via a “polytypic” displacive transformation, by the introduction of stacking faults in the hexagonal close-packed layers of S atoms in high-temperature 1C pyrrhotite. This is analogous to the transformation of 2H wurtzite to intermediate ordered and disordered ZnS layer sequences. The ideal formula of smythite appears to be Fe13S16. Monoclinic Fe3S4 (a=5.93, b=3.42, c=10.64 Å, β=91.9°) is present in amounts up to 25% of total sulfides. It has a derivative NiAs-type structure, and is isomorphous with monoclinic Cr3S4 and Fe3Se4. It occurs as small lenticular lamellae within grains of 3C pyrrhotite, and apparently corresponds to the unidentified lamellar phase of Arnold (1962). The lamellae have a rhombohedral morphology, with a habit plane close to {1011}. In single crystal grains of pyrrhotite, monoclinic Fe3S4 in twinned in a manner consistent with transformation from high-temperature 1C pyrrhotite. Although Fe3S4 lamellae have the general appearance of plate martensite, they do not represent a diffusionless transformation. 相似文献
6.
西藏甲玛铜多金属矿床磁黄铁矿标型矿物学特征及其地质意义 总被引：2，自引：0，他引：2
甲玛矿床位于冈底斯成矿带东段,是西藏地区最大的铜多金属矿床之一。磁黄铁矿是甲玛矿床最常见的金属矿物之一,其标型特征不仅反映其自身形成环境,对其形成机制和矿床成因也具有指示意义。文章选取产于不同岩性中的磁黄铁矿矿石样品,利用矿相学、X射线衍射和电子探针分析等手段对磁黄铁矿的形态、成分和结构进行了分析研究。研究表明,甲玛矿床的磁黄铁矿主要分布在距离岩体中心较远的矿区远端矽卡岩和角岩中。磁黄铁矿的晶胞参数和粉晶X射线衍射曲线显示矽卡岩中的磁黄铁矿主要为高温六方磁黄铁矿,角岩中的磁黄铁矿为高温六方磁黄铁矿和低温单斜磁黄铁矿的交生体,但主要以低温单斜磁黄铁矿为主。通过对矽卡岩和角岩中的磁黄铁矿进行电子探针测试,结果显示:矽卡岩中的磁黄铁矿中w(Fe)为60.09%～60.71%,平均为60.38%,w(S)为38.18%～38.69%,平均38.35%,化学分子式为Fe_8S_9～Fe_(10)S_(11);角岩中的磁黄铁矿中w(Fe)为59.05%～59.57%,平均为59.10%,w(S)为39.28%～39.95%,平均39.59%,化学分子式为Fe_5S_6～Fe_7S_8。根据以上矿物学特征,笔者进一步探讨了该矿床磁黄铁矿的沉淀机制:炽热的岩浆热液上涌,与碳酸盐岩地层和碎屑岩地层接触发生相互作用,并有大气水的加入,使得成矿流体在角岩中先快速降温,形成高温六方磁黄铁矿和低温单斜磁黄铁矿的交生体。同时,大量的含矿热液形成,并充填于有利的成矿空间(主要为层间破碎带)沉淀成矿,形成矽卡岩矿体,然后流体在矽卡岩矿段中经历缓慢降温,形成高温六方磁黄铁矿。结合矿床地质特征和相关元素地球化学特征,认为甲玛矿床类型为斑岩-矽卡岩型。 相似文献
7.
福建丁家山铅锌矿区磁黄铁矿成因矿物学特征研究 总被引：3，自引：0，他引：3
通过野外观察、光学显微镜、矿物场填图、X射线衍射、微区成分分析等手段,针对福建丁家山铅锌矿区磁黄铁矿的成因矿物学特征进行研究。结果表明,丁家山铅锌矿区磁黄铁矿具沿北东向断层串珠状排布,揭示明显的热液成矿特征;矿区内有4类产出形态各异的磁黄铁矿,多为单斜、六方混合相磁黄铁矿,其中单斜磁黄铁矿为六方磁黄铁矿的固溶体分离产物,指示矿区成矿为缓慢的降温过程;六方磁黄铁矿结晶温度在322℃～304℃之间,与同成矿期石英包裹体均一测温结果完全符合。六方磁黄铁矿-黄铁矿-闪锌矿成矿压力计计算结果集中在0.2GPa～0.3GPa之间,与该区燕山期花岗岩成岩压力完全一致。由此认为丁家山铅锌矿为燕山期花岗岩与中-新元古代马面山岩群龙北溪组上段经区域变质的富钙质岩发生接触交代作用而形成的矽卡岩型矿床。 相似文献
8.
安徽铜陵冬瓜山矿床中磁黄铁矿矿石结构特征及其成因意义 总被引：9，自引：3，他引：6
安徽铜陵冬瓜山矿床是长江中下游地区具有代表性的大型层状硫化物矿床,磁黄铁矿为矿床中的主要硫化物矿物.该矿床主要由层状硫化物矿体组成,伴有矽卡岩型和斑岩型矿体.在层状矿体上部,磁黄铁矿主要为块状构造,而层状矿体下部,磁黄铁矿多为层纹状、条带状构造,具有显著的沉积结构构造特征.野外地质观察及室内矿相学研究表明,层状矿体中磁黄铁矿矿石遭受了强烈的变质作用及热液交代作用.进变质过程中形成的结构主要为胶黄铁矿转变为黄铁矿以及进一步变质转变为磁黄铁矿、磁铁矿时形成的交代残留结构.退变质过程则以磁黄铁矿的退火、黄铁矿变斑晶的生长和单纯六方磁黄铁矿的形成为特征.岩浆热液对单纯六方磁黄铁矿的交代作用形成了单斜和六方磁黄铁矿的交生结构.这些结构特征表明层状矿体中的磁黄铁矿并不是岩浆热液成因,而主要为石炭纪同生沉积胶黄铁矿、黄铁矿在燕山期岩浆侵入所引起的热变质作用下脱硫所形成,并在热变质作用之后又受到岩浆热液的叠加交代.磁黄铁矿的结构特征显示冬瓜山矿床的形成经历了同生沉积、热变质、热液交代等多个阶段,支持其为同生沉积-叠加改造型矿床. 相似文献
9.
A. Genkin 《Mineralium Deposita》1971,6(4):348-355
On the basis of microscopic studies a new mode of formation of monoclinic pyrrhotite (from Norilsk) is proposed whereby the monoclinic polymorph formed through a leakage of solutions which, upon seepage along micro-fissures in an oxidizing environment, affected the hexagonal polymorph by carrying away a certain amount of iron. Experimental evidence is considered to be insufficient for using monoclinic pyrrhotite as a geologic thermometer; we only can say that it formed below 300° to 325°C. A similar interpretation is proposed for the formation of troilite and hexagonal pyrrhotite at Voronezh where troilite is replaced by hexagonal pyrrhotite and the process involves partial substitution of ferric for ferrous ions. Replacement during the hydrothermal stage of Cu-Ni ore deposition includes the following changes: pentlandite and chalcopyrite to mackinawite (Norilsk ores); cubanite and magnetite to valleriite. At Norilsk and Monchegorsk, valleriite and mackinawite were formed during late stages of serpentinization of the country rock. A relation between replacement effects in sulfide ore-bodies and serpentinization processes in basic and ultra-basic country rocks is shown to exist. The bearing of alterations involving olivine, secondary silicates, rutile, magnetite and the sulfides is considered.
Zusammenfassung Auf Grund mikroskopischer Studien wird eine neue Bildungsweise für den monoklinen Magnetkies von Norilsk vorgeschlagen: Er soll sich beim Durchsickern von Lösungen in Mikrospalten in einer oxidierenden Umgebung aus der hexagonalen Modifikation gebildet haben. Die Verwendung des monoklinen Magnetkieses als geologisches Thermometer auf Grund experimenteller Resultate ist unzulänglich; wir können nur sagen, daß er sich unter 300°–325°C bildete. Eine ähnliche Interpretation wird vorgeschlagen für die Bildung von Troilit und hexagonalem Magnetkies in Voronezh, wo hexagonaler Magnetkies an die Stelle von Troilit tritt und der Vorgang eine partielle Ablösung von zweiwertigem Eisen durch dreiwertiges Eisen nach sich zieht. Folgende Umwandlungen fanden während des hydrothermalen Stadiums der Cu-Ni-Erzablagerung statt: Pentlandit und Chalcopyrit zu Mackinawit (Norilsk Erze); Cubanit und Magnetit zu Valleriit. In Norilsk und Monchegorsk bildeten sich Valleriit und Mackinawit während der letzten Phasen der Serpentinbildung in Nebengesteinen. Es wird bewiesen, daß eine Verbindung besteht zwischen den Umwandlungen der sulfidischen Erzkörper und der Serpentinisierung der basischen und ultra-basischen Nebengesteine. Auch werden Wirkung und Ausmaß der Umwandlungen von Olivin, sekundären Silikaten, Rutil, Magnetit und Sulfiden untersucht.相似文献
10.
11.
12.
安徽铜陵冬瓜山层控矽卡岩铜矿床形成过程——来自磁黄铁矿的证据 总被引：3，自引：0，他引：3
冬瓜山铜矿床是安徽铜陵地区代表性的层控矽卡岩型铜矿床之一,磁黄铁矿是冬瓜山铜矿床中广泛分布的矿石矿物。野外调研与矿相学观察显示,该矿床中的磁黄铁矿矿石具有沉积、热变质和热液交代结构构造。矿物学研究表明,不同矿石中的磁黄铁矿成分差异较大,其Fe含量变化于57.78%～60.67%之间,分属高温六方相和低温单斜相,主要由黄铁矿变质脱硫而成。冬瓜山铜矿的形成可能经历了早期沉积作用、中期热变质作用和晚期岩浆热液交代作用等复杂成矿过程。 相似文献
13.
The quasiequilibrium directed crystallization technique was used for experimental simulation of zoning characteristic of Cu-rich pyrrhotite-chalcopyrite and pyrrhotite-cubanite-mooihoekite-haycockite ores at the Oktyabr??sky deposit. Directed crystallization of samples I (Fe 32.55, Cu 10.70, Ni 5.40, S. 51.00, Pt = Pd = Rh = Ir= Au = Ag = 0.05 at %) and II (Fe 33.74, Cu 15.94, Ni 1.48, S. 48.75, Pt = Pd = 0.05 at %) was performed. These samples approximate average composition of the ore. Monosulfide (mms) and intermediate (iss) solid solutions progressively crystallized from the melt. The curves of ore element distribution in samples have been drawn. The partition coefficients (k) of ore elements between solid solutions and sulfide melt have been determined depending on melt composition. The paths of melt, mss, and iss compositions are supplemented by tie lines connecting compositions of equilibrium liquid and solid phases. The phase composition of samples after cooling was studied using an optical microscope, XRD, and microprobe. The zoning of sample I is described by the following sequence of phases: monoclinic pyrrhotite ?? hexagonal pyrrhotite + tetragonal chalcopyrite ?? tetragonal and cubic chalcopyrite + pentlandite + bornite. Crystallized sample II consists of four zones: (1) hexagonal pyrrhotite and isocubanite; (2) hexagonal pyrrhotite, cubanite, and pentlandite; (3) low-S pc-phase close to haycockite and pentlandite; and (4) mooihoekite, pentlandite, and bornite mixtures. This sequence corresponds to the secondary zoning, which reflects both the primary fractionation of components and the solid-phase reactions during cooling of the crystallized sample. The Rh, Ru, and Ir partition coefficients between mss and melt have been measured, and speciation of PGM in samples has been identified. The results obtained are compared with typical natural Cu-rich sulfide ore of the Oktyabr??sky deposit. 相似文献
14.
15.
吉林省红旗岭铜镍硫化物矿床矿石学特征 总被引：8，自引：0，他引：8
吉林省红旗岭地区目前正在开采的铜镍硫化物矿床共有5个,均属岩浆熔离型矿床.矿石矿物磁黄铁矿显微镜下可识别出3个同质多象变体:陨硫铁(tr)、六方磁黄铁矿(hpo)和单斜磁黄铁矿(pm).其基本结构主要为NiAs型,具有较高的Ni Cu Co含量,与相应的地幔包体成分相近.镍黄铁矿也有高温结晶型、低温出溶型和低温结晶型3种类型.电子探针微区成分分析显示了同种矿物的不同变种在成分上具有继承与关联性.在该矿床首次发现的辉砷镍矿的存在和黄铁矿的标形特征说明含S-As流体的交代作用在成岩后期普遍存在,为分析红旗岭铜镍硫化物矿床的成矿机制研究提供了矿物学信息. 相似文献
16.
攀西基性岩中共生的陨硫铁和磁黄铁矿的穆斯堡尔效应研究 总被引：1，自引：0，他引：1
使用穆斯堡尔效应研究攀西基性岩中共生的陨硫铁和磁黄铁矿。陨硫铁的分子式为Fe_(1.009)S,晶胞参数a_0=5.96,c_0=11.74,根据Wuensch表示法,可以把它归结为1B,1C型。与陨硫铁共生的磁黄铁矿的分子式为Fe_(0.892)S,属于六方磁黄铁矿。本文确定了共生的陨硫铁和磁黄铁矿的穆斯堡尔参数,它们的谱分别是由一组磁六线谱和三组磁六线谱组成。比较攀西陨硫铁和人工合成陨硫铁及陨石中陨硫铁,可以得出结论,它们之间没有明显差别。 相似文献
17.
镍铜硫化物矿石中磁黄铁矿固溶体的退火及其选矿意义 总被引：3，自引：0，他引：3
磁黄铁矿固治体从硫化物熔体结晶后，在缓慢冷却过程中经历了显著的退火。出治和出治体的租化是固治体退火的两种方式。叶片状的单斜磁黄铁矿和“火焰状”的镍黄铁矿原始出治相在降温过程中均可发生退火和租化。分布于磁黄铁矿等矿物粒间或包于磁黄铁矿粒内的粒状镍黄铁矿，不只是高温出治的直接产物，有一部分可能是由火焰状出治体租化而成的。磁黄铁矿中单斜变体的出治和租化可使矿石的磁性发生改变，镍黄铁矿出治体的租化使含镍矿物的粒度加大。因而，退火作用对矿石的选矿工艺性能有着显著影响。 相似文献
18.
Transmission electron microscopy on the iron monosulfide (FeS) varieties from the Suizhou meteorite (Hubei, China) reveals
the intergrowth of primary hexagonal 2C troilite
and minor monoclinic 4C pyrrhotite (SG: F2/d) phases as nanometer-scale domain microstructure. In addition, anti-phase domain boundaries are found to present in the 2C
troilite superstructure with the displacement vector 1/4[001]2C, which is expected to form during the translational symmetry breaking during cooling from higher symmetry, high-temperature
modification of the NiAs-type (SG: P63/mmc) structure. Furthermore, 60° rotation twinning about the pseudo-hexagonal c-axis is observed in the 4C pyrrhotite superstructure, which may result from rotation symmetry reduction induced by the ordered
arrangements of metal vacancies through solid-state transformation during further cooling. All the above microstructural characteristics
are discussed with consideration to the thermal metamorphism history experienced by the Suizhou meteorite. 相似文献
19.
The unique igneous rock (scapolite–diopside gabbro) from the Ilmeny Mountains in the southern Urals is described. Gabbro fills a segment of dike 1.3 m thick that cuts through calcite–dolomite carbonatite. Medium-grain pyroxenite with scapolite that occurs at selvages gradually passes to scapolite-bearing gabbro in the central part of the dike. Scapolite crystals display surfaces of concurrent growth, which are evidence of their magmatic origin. Scapolite (Me 63–70%) contains numerous pyrrhotite inclusions as platelets 0.001 mm thick oriented parallel to the cleavage plane {100}. The calculated pyrrhotite formula is consistent with its stoichiometry (Fe1–xS). The morphology of the platelets (hexagonal sections) and their optical properties indicate a hexagonal symmetry of pyrrhotite. As follows from the insignificant difference between scapolite grains with and without pyrrhotite inclusions, scapolite and pyrrhotite should be regarded as products of synchronous magmatic melt crystallization. 相似文献
20.
Based on the equation recently determined, formation pressures of skarn-type ore deposits were estimated from the composition of sphalerite coexisting with pyrite and hexagonal pyrrhotite. As criteria for equilibrium among sphalerite, pyrite and hexagonal pyrrhotite, the following three points were carefully checked on each specimen: 1) the presence of hexagonal pyrrhotite, 2) no time sequences among the formation of sulfide minerals, and 3) no compositional variation in sphalerite. Most of the Cu-Fe skarn deposits studied were formed under pressures of more than 1 kb, whereas Zn-Pb(-Cu-Fe) deposits tend to have formed at relatively shallow environments, namely under less than 1 kb. The calculated pressures are qualitatively consistent with the depth of formation of deposits estimated from the geological evidences. The sphalerite geobarometry is quite sensitive even at low pressure ranges, and it is applicable to the deposits formed under shallow conditions. 相似文献