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1.
The budget equations of turbulent kinetic energy and shear stress contain interaction terms of velocity-pressure and velocity-pressure gradient. These terms were estimated in the surface layer using the air pressure observed at the surface and wind velocity components over plant canopies. The magnitude of the pressure interaction terms was significantly large; it was not negligible compared with the production terms in each budget equation. The present results obtained over a rough surface also confirmed previous results that pressure terms play an important role in the turbulent kinetic energy budgets and the shear stress budget. The height dependency of nondimensional pressure terms versus (z - d)/z 0 was not clear.  相似文献   

2.
Vertical profiles of wind speed, temperature and humidity were used to estimate the roughness lengths for momentum (z 0), heat (z H ) and moisture (z Q) over smooth ice and snow surfaces. The profile-measurements were performed in the vicinity of a blue ice field in Queen Maud Land, East Antarctica. The values ofz 0 over ice (3·10–6 m) seem to be the smallest ever obtained over permanent, natural surfaces. The settling of snow on the ice and the loss of momentum at saltating snow particles serve as momentum dissipating processes during snow-drift events, expressed as a strong dependence ofz 0 on u#.The scalar roughness lengths and surface temperature can be evaluated from the temperature and humidity profile measurements if the ratioz H /z Q is specified. This new method circumvents the difficult measurement of surface temperature. The scalar roughness lengths seem to be approximately equal toz0 for a large range of low roughness Reynolds numbers, despite the frequent occurrence of drifting snow. Possible reasons for this agreement with theory of non-saltating flow are discussed.  相似文献   

3.
Downward fluxes of turbulent kinetic energy have been frequently observed in the air layer just above plant canopies. In order to investigate the mechanism for such downward transport, analysis of observational data is attempted. Height-dependency of turbulent kinetic energy flux and turbulence statistics including higher order moments is represented as a function of a non-dimensional height z/H, where z is an observational height and H an average height of plant canopies. Downward fluxes and non-Gaussianity of wind velocity fluctuations are predominant just above plant canopies and decrease with increasing height. The downward flux is closely related to the high intensity of turbulence and the non-Gaussianity of wind velocity fluctuations, especially with a positive skewness in the longitudinal wind and a negative skewness in the vertical wind. The analysis method of conditional sampling and averaging is applied to the present observations. The results show that the predominance of the intermittent inrush phase over the intermittent ejection phase leads to the above-mentioned non-Gaussianity. Finally, a simple explanation is given in order to interpret the turbulent flow structure in the air layer near the plant canopies, which is associated with the downward energy transport process.  相似文献   

4.
Using the relationship between the bulk Richardson numberR z and the Obukhov stability parameterz/L (L is the Obukhov length), formally obtained from the flux-profile relationships, methods to estimatez/L are discussed. Generally,z/L can not be uniquely solved analytically from flux-profile relationships, and it may be defined using routine observations only by iteration. In this paper, relationships ofz/L in terms ofR z obtained semianalytically were corrected for variable aerodynamic roughnessz 0 and for aerodynamic-to-temperature roughness ratiosz 0/z T, using the flux-profile iteration procedure. Assuming the so-called log-linear profiles to be valid for the nearneutral and moderately stable region (z/L<1), a simple relationship is obtained. For the extension to strong stability, a simple series expansion, based on utilisation of specified universal functions, is derived.For the unstable region, a simple form based on utilisation of the Businger-Dyer type universal functions, is derived. The formulae yield good estimates for surfaces having an aerodynamic roughness of 10–5 to 10–1 m, and an aerodynamic-to-temperature roughness ratio ofz 0/z T=0.5 to 7.3. When applied to the universal functions, the formulae yield transfer coefficients and fluxes which are almost identical with those from the iteration procedure.  相似文献   

5.
Rate constants have been measured for the gas-phase reactions of hydroxyl radical with partly halogenated alkanes using the discharge-flow-EPR technique over the temperature range 298–460 K. The following Arrhenius expressions have been derived (units 10–13 cm3 molecule–1 s–1): (8.1 –1.2 +1.5 ) exp{–(1516±53)/T} for CHF2Cl (HCFC-22); (10.3 –1.5 +1.8 ) exp{–(1588±52)/T} for CH2FCF3 (HFC-134a); (11.3 –1.6 +2.1 ) exp{–(918±52)/T} for CHCl2CF2Cl (HCFC-122); (9.2 –2.0 +2.5 ) exp{–(1281±85)/T} for CHFClCF2Cl (HCFC-123a).The atmospheric lifetimes for the substances have been estimated to be 12.6, 12.9, 1.05, and 4.8 years, respectively, and the accuracy of the estimates is discussed.  相似文献   

6.
Impacts of different closure schemes in the Mixed Spectral Finite-Difference model (Beljaarset al., 1987) for neutrally stratified atmospheric surface-layer flow over complex terrain are studied. Six different closure schemes, (Z+z 0), Mixing Length,E–(Z+z 0),E–,E–– andq 2 l are compared. Model results for flow over an infinite series of sinusoidal ridges are examined in the context of the inner and outer layers defined by Jackson and Hunt (1975). Results are compared with rapid distortion estimates of the changes in normal stresses. The effects of streamline curvature are also examined in a qualitative sense.  相似文献   

7.
Source/sink distributions of heat, water vapour andCO2 within a rice canopy were inferred using aninverse Lagrangian dispersion analysis and measuredmean profiles of temperature, specific humidity andCO2 mixing ratio. Monin–Obukhov similarity theorywas used to account for the effects of atmosphericstability on w(z), the standard deviation ofvertical velocity and L(z), the Lagrangian timescale of the turbulence. Classical surface layer scaling was applied in the inertial sublayer (z > zruf)using the similarity parameter = (z - d)/L, where z is height above ground, d is the zero plane displacementheight for momentum, L is the Obukhov length,and zruf 2.3hc, where hc iscanopy height. A single length scale hc, was usedfor the stability parameter 3 = hc/L in the height range 0.25 < z/hc < 2.5. This choice is justified by mixing layer theory, which shows that within the roughness sublayer there is one dominant turbulence length scaledetermined by the degree of inflection in the windprofile at the canopy top. In the absence of theoretical or experimental evidence for guidance,standard Monin–Obukhov similarity functions, with = hc/L, were used to calculate the stabilitydependence of w(z) and L(z) in the roughness sublayer. For z/hc < 0.25 the turbulence length and time scales are influenced by the presence of the lowersurface, and stability effects are minimal. With theseassumptions there was excellent agreement between eddycovariance flux measurements and deductions from theinverse Lagrangian analysis. Stability correctionswere particularly necessary for night time fluxes whenthe atmosphere was stably stratified.The inverse Lagrangian analysis provides a useful toolfor testing and refining multilayer canopy models usedto predict radiation absorption, energy partitioningand CO2 exchanges within the canopy and at thesoil surface. Comparison of model predictions withsource strengths deduced from the inverse analysisgave good results. Observed discrepancies may be dueto incorrect specification of the turbulent timescales and vertical velocity fluctuations close to theground. Further investigation of turbulencecharacteristics within plant canopies is required toresolve these issues.  相似文献   

8.
We have devised a partial differential equation for the prediction of dust concentration in a thin layer near the ground. In this equation, erosion (detachment), transport, deposition and source are parameterised in terms of known quantities. The interaction between a wind prediction model in the boundary layer and this equation affects the evolution of the dust concentration at the top of the surface layer. Numerical integrations are carried out for various values of source strength, ambient wind and particle size. Comparison with available data shows that the results appear very reasonable and that the model should be subjected to further development and testing.Notation (x, y, z, t) space co-ordinates and time (cm,t) - u, v components of horizontal wind speed (cm s–1) - u g, vg components of the geostrophic wind (cm s–1) - V=(u2+v2)1/2 (cm s–1) - (û v)= 1/(h – k) k h(u, v)dz(cm s–1) - V * friction velocity (cm s–1) - z 0 roughness length (cm) - k 1 von Karman constant =0.4 - V d deposition velocity (cm s–1) - V g gravitational settling velocity (cm s–1) - h height of inversion (cm) - k height of surface layer (cm) - potential temperature (°K) - gr potential temperature at ground (°K) - K potential temperature at top of surface layer (°K) - P pressure (mb) - P 0 sfc pressure (mb) - C p/Cv - (t)= /z lapse rate of potential temperature (°K cm–1) - A(z) variation of wind with height in transition layer - B(z) variation of wind with height in transition layer - Cd drag coefficient - C HO transfer coefficient for sensible heat - C dust concentration (g m–3) - C K dust concentration at top of surface layer (g m–3) - D(z) variation with height of dust concentration - u, v, w turbulent fluctuations of the three velocity components (cm s–1) - A 1 constant coefficient of proportionality for heat flux =0.2 - Ri Richardson number - g gravitational acceleration =980 cm s–2 - Re Reynolds number = - D s thickness of laminar sub-layer (cm) - v molecular kinematic viscosity of air - coefficient of proportionality in source term - dummy variable - t time step (sec) - n time index in numerical equations On sabbatical leave at University of Aberdeen, Department of Engineering, September 1989–February 1990.  相似文献   

9.
The spray content in the surface boundary layer above an air—water interface was determined by a series of measurements at various feteches and wind speeds in a laboratory facility. The droplet flux density N(z) can be described in terms of the scaling flux density N* and von Karman constant K throguh the equation, N(z)/N* = −(1/K) ln(z/z0d) where z is height above the mean water level and z0d is the droplet boundary layer thickness. N* is given by a unique relationship in terms of the roughness Reynolds number u*σ/ν where σ is the root-mean-square surface displacement. Spray inception occurred for u* 0.3. The dominant mode of spray generation in the present and most other laboratory tests, as well as in available field data, appears to be bubble bursting.  相似文献   

10.
The kinetics of the aqueous phase reactions of NO3 radicals with HCOOH/HCOO– and CH3COOH/CH3COO– have been investigated using a laser photolysis/long-path laser absorption technique. NO3 was produced via excimer laser photolysis of peroxodisulfate anions (S2O 8 2– ) at 351 nm followed by the reactions of sulfate radicals (SO 4 – ) with excess nitrate. The time-resolved detection of NO3 was achieved by long-path laser absorption at 632.8 nm. For the reactions of NO3 with formic acid (1) and formate (2) rate coefficients ofk 1=(3.3±1.0)×105 l mol–1 s–1 andk 2=(5.0±0.4)×107 l mol–1 s–1 were found atT=298 K andI=0.19 mol/l. The following Arrhenius expressions were derived:k 1(T)=(3.4±0.3)×1010 exp[–(3400±600)/T] l mol–1 s–1 andk 2(T)=(8.2±0.8)×1010 exp[–(2200±700)/T] l mol–1 s–1. The rate coefficients for the reactions of NO3 with acetic acid (3) and acetate (4) atT=298 K andI=0.19 mol/l were determined as:k 3=(1.3±0.3)×104 l mol–1 s–1 andk 4=(2.3±0.4)×106 l mol–1 s–1. The temperature dependences for these reactions are described by:k 3(T)=(4.9±0.5)×109 exp[–(3800±700)/T] l mol–1 s–1 andk 4(T)=(1.0±0.2)×1012 exp[–(3800±1200)/T] l mol–1 s–1. The differences in reactivity of the anions HCOO– and CH3COO– compared to their corresponding acids HCOOH and CH3COOH are explained by the higher reactivity of NO3 in charge transfer processes compared to H atom abstraction. From a comparison of NO3 reactions with various droplets constituents it is concluded that the reaction of NO3 with HCOO– may present a dominant loss reaction of NO3 in atmospheric droplets.  相似文献   

11.
A two-dimensional mesoscale model has been developed to simulate the air flow over the Gulf Stream area where typically large gradients in surface temperature exist in the winter. Numerical simulations show that the magnitude and the maximum height of the mesoscale circulation that develops downwind of the Gulf Stream depends on both the initial geostrophic wind and the large-scale moisture. As expected, a highly convective Planetary Boundary Layer (PBL) develops over this area and it was found that the Gulf Stream plays an important role in generating the strong upward heat fluxes causing a farther seaward penetration as cold air advection takes place. Numerical results agree well with the observed surface fluxes of momentum and heat and the mesoscale variation of vertical velocities obtained using Doppler Radars for a typical cold air outbreak. Precipitation pattern predicted by the numerical model is also in agreement with the observations during the Genesis of Atlantic Lows Experiment (GALE).List of Symbols u east-west velocity [m s–1] - v north-south velocity [m s–1] - vertical velocity in coordinate [m s–1] - w vertical velocity inz coordinate [m s–1] - gq potential temperature [K] - q moisture [kg kg–1] - scaled pressure [J kg–1 K–1] - U g the east-south component of geostrophic wind [m s–1] - V g the north-south component of geostrophic wind [m s–1] - vertical coordinate following terrain - x east-west spatial coordinate [m] - y north-south spatial coordinate [m] - z vertical spatial coordinate [m] - t time coordinate [s] - g gravity [m2 s–1] - E terrain height [m] - H total height considered in the model [m] - q s saturated moisture [kg kg–1] - p pressure [mb] - p 00 reference pressure [mb] - P precipitation [kg m–2] - vertical lapse rate for potential temperature [K km–1] - L latent heat of condensation [J kg–1] - C p specific heat at constant pressure [J kg–1 K–1] - R gas constant for dry air [J kg–1 K–1] - R v gas constant for water vapor [J kg–1 K–1] - f Coriolis parameter (2 sin ) [s–1] - angular velocity of the earth [s–1] - latitude [o] - K H horizontal eddy exchange coefficient [m2 s–1] - t integration time interval [s] - x grid interval distance inx coordinate [m] - y grid interval distance iny coordinate [m] - adjustable coefficient inK H - subgrid momentum flux [m2 s–2] - subgrid potential temperature flux [m K s–1] - subgrid moisture flux [m kg kg–1 s–1] - u * friction velocity [m s–1] - * subgrid flux temperature [K] - q * subgrid flux moisture [kg kg–1] - w * subgrid convective velocity [m s–1] - z 0 surface roughness [m] - L Monin stability length [m] - s surface potential temperature [K] - k von Karman's constant (0.4) - v air kinematic viscosity coefficient [m2 s–1] - K M subgrid vertical eddy exchange coefficient for momentum [m2 s–1] - K subgrid vertical eddy exchange coefficient for heat [m2 s–1] - K q subgrid vertical eddy exchange coefficient for moisture [m2 s–1] - z i the height of PBL [m] - h s the height of surface layer [m]  相似文献   

12.
Potential temperature, specific humidity and wind profiles measured by radiosondes under unstable but windy conditions during FIFE in northeastern Kansas were analyzed within the framework of Monin-Obukhov similarity. Around 86% of these profiles were found to have a height range over which the similarity, formulated in terms of the Businger-Dyer functions, is valid and for which the resulting surface fluxes are in good agreement with independent measurements at ground stations. When scaled with the surface roughness z 0 = 1.05 m and the displacement height d 0 = 26.9 m, for the potential temperature this height range was 45 (±31) (z – d 0 )/z 0 104 (±54) and the comparison of the profile-derived surface fluxes with the independent measurements gave a correlation coefficient of r = 0.96. For the specific humidity these values are 42 (±29) (z – d 0 )/z 0 96 (±38) and r = 0.94. In terms of the height of the bottom of the inversion H i , in the morning hours the upper limit of (z – d 0 ) in the Monin-Obukhov layer is approximately 0.3H i , whereas for a fully developed ABL it is closer to 0.1H i . Probably, as a result of the short sampling times and perhaps also of the small gradients under the windy conditions, the exact height range of validity was difficult to establish from a mere inspection of these profiles.  相似文献   

13.
Mean wind velocity profiles were measured by means of radio-windsondes over the Landes region in southwestern France, which consists primarily of pine forests with scattered villages and clearings with various crops. Analysis of neutral profiles indicated the existence of a logarithmic layer between approximately z – d 0 = 67(±18)z 0 and 128(+-32)z 0 (z is the height above the ground, z 0 the surface roughness and d 0 the displacement height). The upper limit can also be given as z – d 0 = 0.33 (±0.18)h, where h is the height of the bottom of the inversion. The profiles showed that the surface roughness of this terrain is around 1.2 m and the displacement height 6.0 m. Shear stresses derived from the profiles were in good agreement with those obtained just above the forest canopy at a nearby location with the eddy correlation method by a team from the Institute of Hydrology (Wallingford, England).  相似文献   

14.
Vapor phase concentrations of acetone, acetaldehyde and acetonitrile over their aqueous solutions were measured to determine Henry's law partition coefficients for these compounds in the temperature range 5–40 °C. The results are for acetone: ln(H 1/atm)=–(5286±100)T+(18.4±0.3); acetaldehyde: ln(H 1/atm)=–(5671±22)/T+(20.4±0.1); and acetonitrile: ln(H 1/atm)=–(4106±101)/T+(13.8±0.3). Artificial seawater of 3.5% salinity in place of deiionized water raisesH 1 by about 15%. A similar technique has been used to measure the equilibrium constants for the addition compounds of acetone and acetaldehyde with bisulfite in aqueous solution. The results are ln(K 1/M –1)=(4972±318)/T–(11.2±1.1) and ln(K 1/M –1)=(6240±427)/T–(8.1±1.3), respectively. The results are compared and partly combined with other data in the literature to provide an average representation.  相似文献   

15.
Frequency spectra of atmospheric turbulenceS (f) in the inertial subrange are considered in the free convection regime over the sea surface in a case of motionless instrument measurements (Eulerian frequency spectra). The frequency spectra formulaef * S (f)/ 2 =c (f */f)5/3 for wind velocity (=1–3), temperature (=t) and humidity (=e) fluctuations are derived on the basis of similarity theory and the –5/3 law. These relations also can be derived from a consideration of convective large-scale advection of small eddies. The frequency scalef * = (N 1 2/)1/2 (H/z 2)1/3 is the lower bound of the inertial subrange and it is of order 10–2 Hz.The spectra formulae are compared with direct measurements of atmospheric turbulence from the fixed research tower in the coastal zone of the Black Sea in calm weather. It is shown that these formulae are realized at least over two to three decades of the frequency range (approximately from 10–2 to 10 Hz) and values of the numerical coefficients are found. The derived formulae can be used for calculations of sensible and latent heat fluxes by measuring the high-frequency range of spectra at a fixed point at low wind speeds when the conventional inertial dissipation method is not applicable.  相似文献   

16.
Turbulent fluctuations in CO2 concentrations over a paddy field are measured by a fastresponse device with an open sensing path. This IR device coupled with a sonic anemometer constitutes an eddy correlation instrument to measure CO2 fluxes. Three experiments were conducted in the surface layer over paddy 90 cm high. The stability (z – d)/L ranged from -0.14 to 0.20, where L denotes the Monin-Obukhov length.CO2 power spectra show the range of applicability of the -2/3 power law to be between f = 0.2 and f = 2, where f is the frequency normalized by wind speed and height. The cospectral estimate between CO2 and vertical component of wind speed ranging from f = 0.005 to f = 2 shows a peak at about f = 0.15 under near-neutral stratification.Hourly means of CO2 flux measured by the eddy correlation method increase with intensity of net radiation. The maximum value of downward flux of CO2 rises to 0.6 mg cm-2 hr-1 over the paddy field at the stage of ear emergence.Some turbulence statistics relating to the CO2 transport are evaluated: the correlation coefficient between CO2 and vertical velocity is about -0.3, and that between CO2 and humidity attains -0.7 ~ -0.8 under unstable stratification; nondimensional gradients c for CO2 and m for wind speed are 0.89 and 0.99, respectively.  相似文献   

17.
The following temperature-dependent rate coefficients (k/cm3 molecule–1 s–1) of the reactions of hydroxyl radicals with aliphatic ethers have been determined over the temperature range 247–373 K by a competitive flow technique: diethyl ether,k OH=5.2×10–12 exp[(262±150)/T]; methyln-butyl ether,k OH=5.4×10–12 exp[(309±150)/T]; ethyln-butyl ether,k OH=7.3×10–12 exp[(335±150)/T]; di-n-butyl ether,k OH=5.5×10–12 exp[(502±150)/T] and di-n-pentyl ether,k OH=8.5×10–12 exp[(417±150)/T]. The data have been measured relative to the rate coefficientk(OH + 2,3-dimethylbutane)=6.2×10–12 cm3 molecule–1 s–1 independent of temperature.Previous discrepancies in the room-temperature rate coefficients for the OH reactions with ethyln-butyl ether and di-n-butyl ether, obtained in the flow and static experiments of Bennett and Kerr (J. Atmos. Chem. 8, 87–94, 1989;10, 29–38, 1990) compared with those of Wallingtonet al. (Int. J. Chem. Kinet. 20, 541–547, 1988;21, 993–1001, 1989) and of Nelsonet al. (Int. J. Chem. Kinet. 22, 1111–1126, 1990) have been resolved. The results are considered in relation to the available literature data and evaluated rate expressions are deduced where possible. The data are also discussed in terms of structure-activity relationships.  相似文献   

18.
Numerical simulation of turbulent convective flow over wavy terrain   总被引：1，自引：1，他引：0  
By means of a large-eddy simulation, the convective boundary layer is investigated for flows over wavy terrain. The lower surface varies sinusoidally in the downstream direction while remaining constant in the other. Several cases are considered with amplitude up to 0.15H and wavelength ofH to 8H, whereH is the mean fluid-layer height. At the lower surface, the vertical heat flux is prescribed to be constant and the momentum flux is determined locally from the Monin-Obukhov relationship with a roughness lengthz o=10–4 H. The mean wind is varied between zero and 5w *, wherew * is the convective velocity scale. After rather long times, the flow structure shows horizontal scales up to 4H, with a pattern similar to that over flat surfaces at corresponding shear friction. Weak mean wind destroys regular spatial structures induced by the surface undulation at zero mean wind. The surface heating suppresses mean-flow recirculation-regions even for steep surface waves. Short surface waves cause strong drag due to hydrostatic and dynamic pressure forces in addition to frictional drag. The pressure drag increases slowly with the mean velocity, and strongly with /H. The turbulence variances increase mainly in the lower half of the mixed layer forU/w *>2.  相似文献   

19.
The absolute rate constants for the gas-phasereactions of the NO3 radical with a series ofaldehydes such as acetaldehyde, propanal, butanal,pentanal, hexanal and, heptanal were measured overthe temperature range 298–433 K, using a dischargeflow system and monitoring the NO3 radical byLaser Induced Fluorescence (LIF).The measured rate constants at 298 K for thereaction of NO3, in units of 10–14 cm3molecule–1 s–1, were as follows:acetaldehyde 0.32 ± 0.04, propanal 0.60 ± 0.06, butanal 1.46± 0.16, pentanal 1.75 ±0.06, hexanal 1.83 ± 0.36, and heptanal 2.37 ±0.42. The proposed Arrhenius expressions arek1 = (6.2 ± 7.5) × 10–11 exp[–(2826 ± 866)/T] (cm3 molecule–1s–1),k2 = (1.7 ± 1.0) × 10–11 exp[–(2250 ± 192)/T] (cm3 molecule–1s1), k3 =(7.6 ± 9.8) × 1011 exp[–(2466 ± 505)/T] (cm3 molecule–1s–1),k4 = (2.8 ± 1.4) × 10–11 exp[–(2189 ± 156)/T] (cm3 molecule–1s–1), k5 = (7.0 ± 1.8) ×10–11 exp [–(2382 ± 998)/T](cm3 molecule–1 s–1), andk6 = (7.8 ± 1.0) × 10–11 exp[–(2406 ± 481)/T](cm3 molecule–1 s–1).Tropospheric lifetimes for these aldehydes werecalculated at night and during the day for typicalNO3 and OH average concentrations and showed thatboth radicals provide an effective tropospheric sinkfor these compounds and that the night-time reactionwith the NO3 radical can be an important, if notdominant, loss process for these emitted organics andfor NO3 radicals.  相似文献   

20.
Rate constants have been measured for the gas-phase reactions of hydroxyl radical with two halons and three of their proposed substitutes and also with CHClBr-CF3 using the discharge-flow-EPR technique over the temperature range 298–460 K. The following Arrhenius expressions have been derived (units are 10–13 cm3 molecule–1 s–1): (9.3 –0.9 +1.0 ) exp{–(1326±33)/T} for CHF2Br; (7.2 –0.6 +0.7 ) exp{–(1111±32)/T} for CHFBrCF3; (8.5 –0.8 +0.9 ) exp{–(1113±35)/T} for CH2BrCF3; (12.8 –1.2 +1.5 ) exp{–(995±38)/T} for CHClBrCF3. The rate constants at 298 K have been estimated to be <2×10–17 cm3 molecule–1 s–1 for CF3Br and CF2Br—CF2Br. The atmospheric lifetimes due to hydroxyl attack have been estimated to be 5.5, 3.3, 2.8, and 1.2 years for CHF2Br, CHFBr—CF3, CH2Br—CF3 and CHClBr—CF3, respectively.  相似文献   

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