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1.
Stable isotope geochemistry of the Archean Val-d‘Or (Canada) orogenic gold vein field 总被引：2，自引：0，他引：2
A systematic study of the auriferous quartz veins of the Val-dOr vein field, Abitibi, Quebec, Canada, demonstrates that the C, O, S isotope composition of silicate, carbonate, borate, oxide, tungstate and sulphide minerals have a range in composition comparable to that previously determined for the whole Superior Province. The oxygen isotope composition of quartz from early quartz–carbonate auriferous veins ranges from 9.4 to 14.4 whereas later quartz-tourmaline-carbonate veins have 18Oquartz values ranging from 9.2 to 13.8 . Quartz-carbonate veins have carbonate (18O: 6.9–12.5 ; 13C: –6.2– –1.9 ) and pyrite (34S: 1.2 and 1.9 ) isotope compositions comparable to those of quartz-tourmaline-carbonate veins (18O: 7.9–11.7 ; 13C: –8.0 – –2.4 ; 34S: 0.6–6.0 ). 18Oquartz values in quartz-tourmaline-carbonate veins have a variance comparable to analytical uncertainty at the scale of one locality, irrespective of the type of structure, the texture of the quartz or its position along strike, across strike or down-dip a vein. In contrast, the oxygen isotope composition of quartz in quartz-tourmaline-carbonate veins displays a regional distribution with higher 18O values in the south-central part of the vein field near the Cadillac Tectonic Zone, and which 18O values decrease regularly towards the north. Another zone of high 18O values in the northeast corner of the region and along the trace of the Senneville Fault is separated by a valley of lower 18O values from the higher values near the Cadillac Tectonic Zone. Oxygen isotope isopleths cut across lithological contacts and tectonic structures. This regional pattern in quartz-tourmaline-carbonate veins is interpreted to be a product of reaction with country rocks and mixing between (1) a deep-seated hydrothermal fluid of metamorphic origin with minimum 18O=8.5 , 13C=0.6 and 34S=–0.4 , and (2) a supracrustal fluid, most likely Archean seawater with a long history of water-rock exchange and with maximum 18O=3.9 , 13 C=–5.6 and 34S=5.0 . 相似文献
2.
The oxygen isotope geochemistry and chemical composition of clinopyroxene crystals from Alban Hills pyroclastic deposits constrain the petrological evolution of ultrapotassic Roman-type rocks. Volcanic eruptions in the 560–35 ka time interval produced thick pyroclastic deposits bearing clinopyroxene phenocrysts with recurrent chemical characteristics. Clinopyroxenes vary from Si–Mg-rich to Al–Fe-rich with no compositional break, indicating that they were derived from a continuous process of crystal fractionation. Based on the 18O and trace element data no primitive samples were recovered: monomineralic clinopyroxene cumulates set the oxygen isotope composition of primary magmas in the range of uncontaminated mantle rocks (5.5), but their REE composition resulted from extensive crystal fractionation. Departing from these mantle-like 18OCpx values the effects of crustal contamination of clinopyroxene O-isotope composition were identified and used to monitor chemical variations in the parental magma. 18O values in Si–Mg-rich clinopyroxene are slightly higher than typical mantle values (5.9–6.2), and the low REE contents are representative of early stages of magmatic differentiation. 18O values as high as 8.2 are associated with Al–Fe3+-rich clinopyroxene showing high REE contents. These 18O values are characteristic of crystals formed during the late magmatic stages of each main eruptive phase. Geochemical modelling of 18O values vs. trace element contents indicates that these ultrapotassic magmas were derived from fractional crystallization plus assimilation of limited amounts of carbonate wall rocks starting from a primary melt, and from interaction with CO2 derived from country rocks during crystal fractionation. 相似文献
3.
The 18O and D values in mud-volcanic waters of the Taman Peninsula and Kakhetia vary from +0.7 to +10.0 and from –37 to –13 , respectively. These values increase as the Greater Caucasus is approached. The increase in 18O and D also positively correlates with fluid generation temperatures based on hydrochemical geothermometers. This is accompanied by changes in the chemical composition of waters, in which contents of alkali metals, HCO–
3 ion, and boron increase, while the content of halogen ions (Cl, Br, J) decreases. Changes in the isotopic composition of water are also accompanied by the increase of 13 in methane and decrease of 11 B in clays. Analysis of formal models of the evolution of isotopic composition of mud-volcanic waters showed that mud volcanoes are recharged by freshened water from the Maikop paleobasin with an inferred isotopic composition of D –40 and 18 O –6. Based on this assumption, the 18O and D values observed in mud-volcanic waters can be explained not only by processes of distillation and condensation in a closed system, but also by combined processes of isotopic reequilibration in the water-illite-methane system.Translated from Litologiya i Poleznye Iskopaemye, No. 2, 2005, pp. 143–158.Original Russian Text Copyright © 2005 by Lavrushin, Dubinina, Avdeenko. 相似文献
4.
Oxygen and hydrogen isotope studies of a number of granite suites and mineral separates from the New England Batholith indicate that O18 can be used to discriminate the major granite protoliths. The granite suites previously subdivided on the basis of mineralogical and geochemical criteria into S-type (sedimentary) and I-type (igneous) have O18 values consistently higher in the S-type granites (10.4–12.5) than in the spatially related I-type plutons (7.7–9.9). There appears to be a systematic variation in O18 from the most S-type to the most I-type granites, the dividing point between the two occuring at O18 equal to 10. A group of leucocratic granites that form about half of the batholith and difficult to classify mineralogically and geochemically is found to have low O18 values (6.4–8.1), suggesting an affinity to the most I-type granites. A single leucogranite pluton with minor muscovite has a O18 of 9.6 which is significantly higher than other leucogranites indicating a different origin perhaps involving amphibole fractionation.The behavior of D in the plutonic rocks is much less systematic than O18. Excluding samples collected adjacent to major faults, the D values show a rough positive correlation with water content similar to, but less pronounced than, the trend previously observed in the Berridale Batholith, southeastern Australia. This relation is considered to reflect an interaction between meteoric water and the granites, the largest effect being observed in samples with the least amount of water. Of note is the generally lower D values of the upper Paleozoic New England Batholith compared with the Silurian Berridale Batholith. This difference may be related to a near equatorial paleolatitude of 22 °S in the Silurian and near polar paleolatitudes in the late Carboniferous that have been inferred for these regions. Granite samples collected from near major faults, and one ignimbrite sample of rhyodacite composition, have very low D values (less than –120) suggesting a much greater degree of interaction with meteoric water. 相似文献
5.
In closed magma systems SiO2 approximately measures differentiation progress and oxygen isotopes can seem to obey Rayleigh fractionation only as a consequence of the behaviour of SiO2. The main role of
18O is as a sensitive indicator of contamination, either at the start of differentiation (
18Oinit) or as a proportion of fractionation in AFC. Plots of
18O vs SiO2-allow to determine initial
18O values for different sequences for source comparison. For NBS-28=9.60, the
18O at 48% SiO2-varies between a high 6.4 for Kiglapait (Kalamarides 1984), 5.9 for Transhimalaya, 5.8 for Hachijo-Jima (Matsuhisa 1979), 5.6 for Koloula (Chivas et al. 1982) and a low 5.3 for the Darran Complex, New Zealand. The Transhimalayan batholiths (Gangdese belt) were emplaced in the Ladakh-Lhasa terrane, between the present-day Banggong-Nujiang, and Indus-Yarlung Tsangbo suture zones, after its accretion to Eurasia. The gradient of the least contaminated continuous (
18O vs SiO2-igneous trend line is similar to that of Koloula, and AFC calculations suggest a low secondary assimilation rate of less than 0.05 times the rate of crystallisation. Outliers enriched in 18O are frequent in the Lhasa, and apparently rare in the Ladakh transsect. Low-
18O (5.0–0) granitoids and andesites on the Lhasa-Yangbajain axis are the result of present day or recent near-surface geothermal activity; their quartzes still trace the granitoids to the Transhimalaya
18O trend line, but the distribution of low total rock or feldspar
18O values could be a guide to more recent heat flow and thermally marked tectonic lineaments. Two ignimbrites from Maqiang show hardly any 18O-contamination by crustal material. 相似文献
6.
Preliminary studies have been made on the distributions of oxygen and sulphur isotopes in the Rosebery, Mount Farrell, and Mount Lyell ores. These ores lie in Cambrian geosynclinal volcanic rocks in West Tasmania. At each locality the sulphur of the sulphide minerals has a distinctive degree of enrichment in 34S in relation to sulphur in meteorites and a narrow range of 34S values. The dominant ore at Mount Lyell (mainly pyrite-chalcopyrite) has an average 34S value of +7.0, the main lode at Rosebery (pyrite-sphalerite-galenachalcopyrite) averages +10.9, and the Mount Farrell ore (galena-sphalerite) averages +14.1. The degree of enrichment does not appear to be related to local, near-surface geological factors. Other ores of geosynclinal volcanic type with similar mineralogy also show narrow ranges in 34S and varying enrichments in 34S. Barite from a concordant sulphide-barite-carbonate lode at Rosebery has an average 34S of +38.1 and an average 18O of +10.7. Barite from veins at Mount Lyell has an average 34S of +25.3 and an average 18O of +10.6.
Die Verteilung von Sauerstoff- und Schwefel-Isotopen in den Erzkörpern von Rosebery, Mount Farrell und Mount Lyell wurde untersucht. Die Erzkörper sind in kambrische, geosynklinale vulkanische Gesteine Westtasmaniens eingebettet. An jeder dieser Lagerstätten zeigt der Schwefel der Sulfiderze einen charakteristischen Anreicherungsgrad an 34S im Verhältnis zum Meteoritenschwefel und einen eng begrenzten Bereich der 34S-Werte. Die Erze des Mount Lyell-Lagers (hauptsächlich Pyrit-Chalkopyrit) zeigen überwiegend einen 34S-Durchschnittswert von +7.0, das Hauptlager von Rosebery (Pyrit-Sphalerit-Galenit-Chalkopyrit) +10.9, und des Mount Farrell-Erz (Galenit-Sphalerit) +14.1. Der Anreicherungsgrad scheint nicht mit den lokalen geologischen Faktoren verbunden zu sein. Auch andere Erzkörper geosynklinaler vulkanischer Art von ähnlicher mineralogischer Struktur zeigen eng begrenzte 34S-Werte und 34S-Anreicherungsvariationen. Der Baryt des konkordant aufgebauten Sulfid-Baryt-Carbonat-Lagers bei Rosebery hat einen 34S-Durchschnitt von +38.1 und einen 18O-Durchschnitt von +10.7. Der Baryt aus den Erzgängen von Mount Lyell ist durch einen 34S-Durchschnitt von +25.3 und einen 18O-Durchschnitt von +10.6 charakterisiert.相似文献
7.
Stibnite mineralisation in the antimony province of New England can be divided into Central type ores (veins of stibnite + quartz ± berthierite) and Peripheral type ores of stibnite + quartz + native antimony ± berthierite. The Central stibnites have 34SCDT values of –5±2 (1) which may represent equilibrium precipitation from mantle sulfur at about 200°C. Peripheral stibnites have 34S values between 0 and –25, with a large group at 0±2. They represent precipitation from a limited supply of mantle sulfur and the acquisition of sedimentary sulfur. We consider that the different ore types were produced from distinct ore solutions derived from two immiscible melts. These originated in the deep mantle, were mobilised by tectonic activity and supplied the antimony and most of the sulfur to the ores. 相似文献
8.
Summary A set of 354 sulphur isotope data from the Bleiberg deposit, the type deposit of Alpine low temperature carbonate hosted Pb–Zn deposits (APT deposits), is critically evaluated applying statistical methods. The sulphur isotope patterns vary significantly among the ore horizons. This suggests a long lasting and polyphase mineralisation system. The sulphur isotope composition of barite corresponds to that of Carnian seawater (i.e. 16 34S). The 34S values of the iron sulphides correspond to data from sedimentary iron sulphides. Pb and Zn sulphides are characterized by three normally distributed 34S populations with mean values of –6 to –8, –13 to –18, and –25 to –29. Heavy sulphur (>–10 34S) indicates contribution of sulphide sulphur from epigenetic-hydrothermal fluids, whereas light sulphide sulphur (<–21 34S) was produced by sulphur – reducing bacteria. The intermediate population is explained by mixing of sulphur derived from these two sources. Other sources of local importance, however, can not be excluded. The isotope populations correspond only partly to the paragenetic ore stages. The sulphur isotope patterns in the APT deposits are regionally different. Data from other low-temperature sediment-hosted Pb–Zn deposits support the proposed interpretation. A comparison demonstrates that the sulphur isotope patterns of APT deposits correspond to patterns of the Irish type deposits, but are different to those of Mississippi Valley type deposits.Supplementary material to this paper is available in electronic form at http://dx.doi.org/10.1007/s00710-004-0071-3 相似文献
9.
Peter Torssander 《Contributions to Mineralogy and Petrology》1989,102(1):18-23
Sulfur isotope ratios have been determined in 27 selected volcanic rocks from Iceland together with their whole rock chemistry. The
34S of analyzed basalts ranges from –2.0 to +0.4 with an average value of –0.8 Tholeiitic and alkaline rocks exhibit little difference in
34S values but the intermediate and acid rocks analyzed have higher
34S values up to +4.2 It is suggested that the overall variation in sulfur isotope composition of the basalts is caused by degassing. The small range of the
34S values and its similarity to other oceanic and continental basalts, suggest that the depleted mantle is homogeneous in its sulfur isotope composition. The
34S of the depleted mantle is estimated to be within the range for undegassed oceanic basalts, –0.5 to +1.0 相似文献
10.
The world-class Idrija mercury deposit (western Slovenia) is hosted by highly deformed Permocarboniferous to Middle Triassic sedimentary rocks within a complex tectonic structure at the transition between the External Dinarides and the Southern Alps. Concordant and discordant mineralization formed concomitant with Middle Triassic bimodal volcanism in an aborted rift. A multiple isotopic (C, O, S) investigation of host rocks and ore minerals was performed to put constraints on the source and composition of the fluid, and the hydrothermal alteration. The distributions of the 13C and 18O values of host and gangue carbonates are indicative of a fracture-controlled hydrothermal system, with locally high fluid-rock ratios. Quantitative modeling of the 13C and 18O covariation for host carbonates during temperature dependent fluid-rock interaction, and concomitant precipitation of void-filling dolomites points to a slightly acidic hydrothermal fluid (13C–4 and 18O+10), which most likely evolved during isotopic exchange with carbonates under low fluid/rock ratios. The 34S values of hydrothermal and sedimentary sulfur minerals were used to re-evaluate the previously proposed magmatic and evaporitic sulfur sources for the mineralization, and to assess the importance of other possible sulfur sources such as the contemporaneous seawater sulfate, sedimentary pyrite, and organic sulfur compounds. The 34S values of the sulfides show a large variation at deposit down to hand-specimen scale. They range for cinnabar and pyrite from –19.1 to +22.8, and from –22.4 to +59.6, respectively, suggesting mixing of sulfur from different sources. The peak of 34S values of cinnabar and pyrite close to 0 is compatible with ore sulfur derived dominantly from a magmatic fluid and/or from hydrothermal leaching of basement rocks. The similar stratigraphic trends of the 34S values of both cinnabar and pyrite suggest a minor contribution of sedimentary sulfur (pyrite and organic sulfur) to the ore formation. Some of the positive 34S values are probably derived from thermochemical reduction of evaporitic and contemporaneous seawater sulfates.Editorial handling: P. Lattanzi 相似文献
11.
Zusmmenfassung Die Ergebnisse der Schwefelisotopenanalysen von sechs Sulfid- und vier Sulfatmineralproben von Bleiberg/Kreuth (Österreich) variieren von –6,9 bis –25,9 34S in den Sulfiden und von +14,8 bis +18,9 34S in den Sulfaten. Die große Variationsbreite der Schwefelisotopen und die Bevorzugung des leichten Schwefels deutet vermutlich auf bakterielle Prozesse der Sulfidfällung. Die Sulfatschwefel fallen in den Bereich der Schwefelisotopenzusammensetzung des mesozoischen (postskytischen) Meerwassers.
Determination of the sulfur isotopic composition in some sulfide and sulfate minerals of the lead zinc deposit, Bleiberg/Kreuth, Carinthia
Summary Results of sulfur isotope analyses on 6 sulfides and 4 sulfates from Bleiberg/Kreuth (Austria) range from –6.9 to –25.9 34S (in sulfides) and from +14.8 to +18.9 34S (in sulfates). A large range of sulfide sulfur isotope fractionation with appreciable light sulfur probably indicates a bacterial sulfur source in sulfide precipiation. The sulfate sulfur plots in the range of Mesozoic (post-Skytian) seawater sulfur isotopic composition.相似文献
12.
D. E. Lee Irving Friedman J. D. Gleason 《Contributions to Mineralogy and Petrology》1984,88(3):288-298
Stable isotope data have been determined for 13 Mesozoic and Tertiary plutons in eastern Nevada and nearby Utah. In the southern Snake Range of eastern Nevada, where relations are best exposed and have been most intensively studied, D,
18O, and apparent K-Ar ages depend on proximity to the Snake Range decollement. Where stresses resulting from late movement on the decollement have caused cataclasis of Oligocene (37 Ma) granitoid rock,
18O, D, and K-Ar age values as low as –2.5, –155, and 18 Ma, respectively, have been determined. Where there has been no cataclasis,
18O values of Jurassic, Cretaceous, and Oligocene granitoid rocks are apparently unaffected, but both D values and K-Ar ages have been modified for distances of tens of meters below the decollement.Results similar to those in the southern Snake Range have been observed in other eastern Nevada granitoid rocks spatially related to regional thrust faults, as in the Kern Mountains, the Toana Range, and the northern Egan Range. In each of these areas cataclasis or deformation of granitoid rocks has resulted in lowered
18O, D, and K-Ar age values. Where there has been no cataclasis or deformation,
18O values are unaffected, but both D and K-Ar age values have been lowered by stresses resulting from postcrystallization movement along overlying thrust faults.Many of the plutons discussed have not been deeply eroded, and spatially related thrust faults crop out. Where thrust faults are not in evidence and the granitoid rocks give D values lower than about –130 along with spuriously low K-Ar age results, modification of the D and K-Ar age values may have been caused by stresses related to late movement along an overlying (now eroded) thrust fault. 相似文献
13.
Richard J. Lisle 《International Journal of Earth Sciences》1985,74(3):657-663
Twenty-eight quartz c-axis fabrics from individual pebbles from a single outcrop of deformed conglomerate have been measured. These pebbles vary in composition and have undergone different amounts of strain. Contrary to expectations based on published results of computer simulated deformation by intracrystalline slip of pure quartzites, it is observed that fabrics are not stronger in the more highly deformed pebbles. Instead, the fabric strength is related to the quartz content of the pebbles. Pure quartzites show the strongest fabrics. As the percentage of non-quartz minerals increases up to 25% the strength of the fabrics rapidly decreases, though the influence of composition becomes less marked when impurities exceed 25%. These observations can be explained if the deformation of the impure quartzites included a contribution from a non-intracrystalline mechanism such as grain boundary sliding.
Zusammenfassung Von einem einzelnen Aufschluß eines deformierten Konglomerates wurden 28 Quarz c-Achsen Gefügebilder aufgenommen, jeweils von verschiedenen Geröllen. Diese Gerölle unterschieden sich in ihrer Zusammensetzung sowie in ihrem Deformationsgrad. Im Gegensatz zu den Erwartungen, basierend auf veröffentlichten Computersimulationen von intrakristallinen Gleitungen in reinem Quarzit, wurde beobachtet, daß die Gefüge von stark deformierten Kieseln nicht entsprechend stärker ausgeprägt sind, sondern, das Gefüge ist abhängig vom jeweiligen Quarzgehalt der Kiesel: reiner Quarzit zeigt das ausgeprägteste Gefüge. Wenn aber die Fremdanteile bis zu 25% betragen, verringert sich die Stärke der Gefügeausrichtung. Dieser Einfluß geht jedoch erneut zurück, sobald der Fremdanteil 25% übersteigt. Diese Beobachtungen können erklärt werden, wenn die Deformation des unreinen Quarzites auch mit nicht intrakristallin bezogenen Mechanismen im Zusammenhang steht, zum Beispiel mit Gleitungen an Korngrenzen.
Résumé Vingt-huit mesures de fabriques d'axes c de quartz ont été effectuées dans des cailloux différents provenant d'une même affleurement de conglomérat déformé. Ces cailloux varient en composition et ont été déformés à des degrés divers. Contrairement à ce que laissent prévoir les résultats publiés de la simulation par ordinateur de déformations par glissement intracristallin dans des quartzites purs, on constate que les fabriques ne sont pas plus orientées dans les cailloux les plus déformés. En effet, l'intensité de la fabrique est en relation avec la teneur en quartz des cailloux. Les quartzites purs montrent les fabriques les mieux exprimées. Lorsque la proportion des minéraux autres que le quartz augmente jusque 25%, l'orientation de la fabrique décroît rapidement, tandis qu'au-delà de 25%, l'influence de la composition se marque moins. On peut interpréter ces observations en admettant que dans la déformation des quartzites impurs, intervient un mécanisme non intracristallin, tel qu'un glissement le long des surfaces des grains.
, . , , . , : , , : . 25%, . , 25%, . , , , .: .相似文献
14.
Isotopic compositions were determined for quartz, sericite and bulk rock samples surrounding the Uwamuki no. 4 Kuroko ore body, Kosaka, Japan.
18O values of quartz from Siliceous Ore (S.O.), main body of Black Ore B.O.) and the upper layer of B.O. are fairly uniform, +8.7 to +10.5. Formation temperatures calculated from fractionation of 18O between sericite and quartz from B.O. and upper S.O. are 250° to 300° C. The ore-forming fluids had
18O values of +1 and D values of –10, from isotope compositions of quartz and sericite.Tertiary volcanic rocks surrounding the ore deposits at Kosaka have uniform
18O values, +8.1±1.0 (n=50), although their bulk chemical compositions are widely varied because of different degrees of alteration. White Rhyolite, which is an intensely altered rhyolite occurring in close association with the Kuroko ore bodies, has also uniform
18O values, +7.9±0.9 (n=19). Temperatures of alteration are estimated to be around 300° C from the oxygen isotope fractionation between quartz and sericite. Paleozoic basement rocks phyllite and chert, have high
18O values, +18 and +19. The Sasahata formation of unknown age, which lies between Tertiary and Paleozoic formations, has highly variable
18O, +8 to +16 (n=4). High
18O values of the basement rocks and the sharp difference in
18O at their boundary suggest that the hydrothermal system causing Kuroko mineralization was mainly confined within permeable Tertiary rocks. D values of altered Tertiary volcanic rocks are highly variable ranging from –34 to –64% (n=12). The variation of D does not correlate with change of chemical composition,
18O values, nor distance from the ore deposits. The relatively high D values of the altered rocks indicate that the major constituent of the hydrothermal fluid was sea water. However, another fluid having lower D must have also participated. The fluid could be evolved sea water modified by interaction with rocks and the admixture of magmatic fluid. The variation in D may suggest that sea water mixed dispersively with the fluid. 相似文献
15.
Fluid venting activity on the Costa Rica margin: new results from authigenic carbonates 总被引：8，自引：1，他引：7
Carbonate precipitates on mounds and along tectonic scarps off the Costa Rica margin are manifestations of subduction-induced dewatering. The long-term dewatering history is recorded in mineralogical, petrological and isotope signals of carbonates recovered from these sites. The carbonates are strongly depleted in 13C (–11 to –53 PDB) and enriched in 18O (+4 to +8 PDB). Thermogenic methane and biogenic methane were identified as sources of the carbon. Chemoherm carbonates and seepage-associated carbonates formed in a focused flow regime have lighter 13C values, while others formed in a more diffusive flow regime have slightly enriched C isotope values. Three fluid components were inferred based on the calculation of equilibrium 18O: clay dehydration water, gas hydrate water and seawater. Calculated equilibrium 18O values of carbonates from different down-core depths as well as from different precipitation stages show that the 18O of the precipitating fluid is progressively depleted with time. Dolostones showing a methane-C source and a well constrained O-isotope signature are thought to have formed at depth in the sediment and subsequently became exhumed. Glauconitic sandstones cemented by methane-derived carbonate provide evidence that fluid and solid material have been expelled by the mud volcano. 相似文献
16.
Further support for the view that mineralization at Mount Isa comprises two separate events is provided by 34S/32S measurement. Isotopic exchange between sulphides in lead-zinc-silver ores appears to have been promoted locally during metamorphism, whereas isotopic disequilibrium persists in the copper ores. These isotopic data are explained by a model in which sedimentary deposition of lead, zinc and silver was succeeded by the post-metamorphic emplacement of copper. Past biological activity is inferred from the occurrence of low concentrations of organic carbon with 13C values ranging from –21 to –26 PDB. Carbonate contents, expressed as carbon, vary from <0.1% to 10.9%. The 13C and 18O values for the carbonates are relatively constant at –4.4±1.1 and –17.6±1.1 PDB respectively. These values are interpreted as reflecting isotopic changes induced in original marine carbonates by isotopic exchange during lower greenschist metamorphism. 相似文献
17.
Sulfur isotope analyses were made on 14 alunites from volcanic and sedimentary rocks widely different in chemistry and age from southern Tuscany and northern Latium, central Italy. The 34S values range from +0.7 to +9.6, and appear not to be related to the nature of the host rock. Geological and isotopic evidence suggests that all the alunites formed by supergenic oxidation of sulfides. Sulfides occurring with alunites in the volcanic rocks of Latium can be divided into an isotopically light group of probably magmatic origin (34S=–1.5 to +3.4) and a heavy one with 34S=+6.0 to +10.3, tentatively interpreted as deposited by hydrothermal fluids that leached sulfides of similar 34S/32S from the deep basement. Such an interpretation is consistent with recent studies indicating that in the perityrrhenian belt of Latium exists a continuation, at depth, of the Tuscan stratigraphic series, rich in sulfides with 34 from +6 to +12. 相似文献
18.
Grenville dolomitic marbles and calc-silicates at Stephen Cross Quarry, Québec, underwent contact metamorphism and metasomatism associated with the intrusion of the Wakefield syenite at ambient pressures of 0.4GPa at 1090–1070Ma. Fluid infiltration produced exoskarns, calcite+periclase+forsterite±diopside±orthoclase assemblages in the marbles, and quartz±calcite±wollastonite±diopside±anorthite assemblages in the calc-silicates. Phase-equilibria in the CaO–MgO–Al2O3–SiO2–H2O–CO2 system suggest that fluid infiltration occurred close to the thermal peak of contact metamorphism (715–815°C) and that the fluids hadXCO20.15. In the metasediments, 18O values of calcite (Cc) are as low as 8.6, suggesting that the fluids were in isotopic equilibrium with the syenites (18O =8.8–10.2). Marble 13C(Cc) values are-0.1 to-3.2; the lack of correlation between 13C(Cc) and 18O(Cc) is consistent with the infiltration of water-rich fluids. The resetting of stable isotopes and the mineralogical changes can be explained by time-integrated fluid fluxes of up to 110 m3/m2 (4×106 mol/m2), corresponding to actual fluxes of 3×10-11 to 3×10-12 m3/m2-s and intrinsic permeabilities of 10-18 to 10-20 m2 for fluid flow lasting 0.1-1Ma. Marble 18O(Cc) values do not correlate well with distance from the syenite, and fluids were probably channelled across lithological layering. The correlation between the degree of resetting of marble 18O(Cc) values with the abundance of submillimetre-wide veins, suggests that fluid focussing may have resulted from variations in fracture density. Late, lower temperature (<500°C), fluid flow formed serpentine (Serp) and brucite (Br) from periclase and forsterite. 18O(Br) and 18O(Scrp) values correlate with 18O(Cc), suggesting that retrogression involved only limited volumes of fluid. The observation that 18O(Cc-Br) and 18O(Cc-Serp) values are higher in marbles that have lower 18O(Cc) values is interpreted as indicating that fluid flow persisted to lower temperatures in those rocks due to higher intrinsic permeabilities. Calcite in the syenite was also formed by the influx of fluids during cooling. Syenite 18O(Cc) values are approximately in isotopic equilibrium with the high-temperature silicate minerals, suggesting that again only minor volumes of fluid were involved. In detail fluid flow was prolonged and complex, creating problems for the application of quantitative fluid flow models.This paper is a contribution to IGCP 304, Lower Crustal Processes 相似文献
19.
Low grade hydrothermally metamorphosed mafic rocks from the Iberian Pyrite Belt are enriched in 18O relative to the oxygen isotopic ratio of fresh basalt (+6.5±1). The observed
18O whole rock values range from +0.87 to +15.71 corresponding to positive isotopic shifts of +5 to +10, thus requiring isotopic exchange with fluids under conditions of high water:rock ratios at low temperatures. The lowest
18O observed corresponds to an albitized dolerite still and is compatible with independent geochemical data suggesting lower water: rock ratios for the alteration of these rocks.The isotope data are consistent with the hypothesis that the spilites from the Pyrite Belt were produced by interaction of basaltic material with sea water.Significant leaching of transition metals from the mafic rocks during alteration coupled with available sulphur isotopic data for the sulphide ores also suggest that sea water may have played an important role in the formation of ore deposits in the Iberian Pyrite Belt. 相似文献
20.
T. K. Kyser W. E. Cameron E. G. Nisbet 《Contributions to Mineralogy and Petrology》1986,93(2):222-226
18O values of unaltered olivine and pyroxene phenocrysts in boninites from several areas range from 5.8 to 7.4 and indicate that the source for most boninites is more 18O-rich than MORBs and other oceanic basalts. The source for oxygen and other major elements is most likely a refractory portion of the mantle having a
18O value of up to 7.0 to which must be added a small amount of H2O-rich fluid to induce partial melting. This fluid, which is derived from subducted crust, is the vehicle for LREEs including Nd. The variable, normally low
Nd values typical of boninites do not correlate with the
18O values.Post eruptive exchange of oxygen in the glass of boninites with that of sea water at low temperatures (<150° C) produces
18O values of >10 in optically fresh glass. Hydration of the glass has increased the water contents of most boninites from estimated magmatic values of 1–2 wt% to 2–4 wt% and produced D values of < –80, which may be lower than the original magmatic D values. In contrast to most submarine pillow basalts, the magmatic volatile composition of boninite lavas has been extensively modified as a result of post eruptive interaction with seawater. 相似文献