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1.
Abstract Reaction zones of 0.5–10.0 m thick are commonly observed between serpentinite and pelitic schist in the Nishisonogi metamorphic rocks, Kyushu, Japan. Each reaction zone consists of almost monomineralic or bimineralic layers of talc + carbonates, actinolite (or carbonates + quartz), chlorite, muscovite and albite from serpentinite to pelitic schist. Magnesite + quartz veins extend into the serpentinite from the talc + carbonates layer, while dolomite veins extend into the pelitic schist from the muscovite layer. These veins are filled by subhedral minerals with oriented growth features. Primary fluid inclusions yield the same homogenization temperatures (145–150°C) both in the reaction zone and in the veins, suggesting their simultaneous formation. Mass-balance calculations using the isocon method indicate that SiO2 , MgO, H2 O and K2 O are depleted in the reaction zone relative to the protoliths. These components were probably extracted from the reaction zone as fluids during the formation of the reaction zone. 相似文献
2.
Abstract The mineral assemblages of the pumpellyite–actinolite facies such as pumpellyite + actinolite + epidote + chlorite or actinolite + epidote + hematite + chlorite occur in the Sanbagawa low-grade metamorphic region, central Shikoku, southwest Japan. Chemical compositions of these minerals from the eight newly studied areas were analyzed in order to evaluate the areal extent and thermal structure of the region. In the buffered assemblage of pumpellyite + actinolite + epidote + chlorite, the Fe3+ /(Fe3+ + Al) values of epidote decrease slightly with decreasing Fe2+ /(Fe2+ + Mg) values for chlorite. The changes in these values show a general correlation with temperature. The presence of this relationship implies that the Fe3+ /(Fe3+ + Al) values of epidote can be used to divide the Sanbagawa low-grade metamorphic region into low-, medium- and high-grade subzones. The areal distribution of these subzones indicates that: (i) the temperature seems to decrease in the same sense as envisaged by the zonal mapping of the higher-grade pelitic schists; and (ii) there is no significant gap of metamorphic conditions through the boundary between the two structural units (Besshi and Oboke units). It follows that the Sanbagawa low-grade metamorphic region decreases in temperature going up the structural section, and tectonic discontinuities have not affected the thermal structure. 相似文献
3.
通过测试辽宁省15个地震监测站泉水或井水的氢、氧同位素组成及主要离子组分含量,讨论了泉水或井水的化学类型及其成因.测得泉水或井水的δD和δ~(18)O值范围分别为-82.5‰--54.4‰和-11.4‰—-7.3‰,表明所测泉水和井水的主要来源为大气降水.研究区低温泉水为低矿化度的Ca-SO_4·HCO_3型或Ca-HCO_3·SO_4型;而较高温度的花岗岩裂隙水中溶解了较多的钠硅酸盐矿物,水化学类型主要为Na-HCO_3·SO_4型;碳酸盐岩及含砾砂岩含水层分别分布于辽宁省西部及中部地区,水温略低于高温花岗岩裂隙水,水化学类型为Na·Ca-HCO_3型.水中F~-含量较高,且F~-含量与温度、pH值、Na~+和HCO_3~-的浓度呈正相关,表明泉水或井水的化学类型是深部富CO_2流体及大气降水与花岗岩反应的结果. 相似文献
4.
Aragonite and omphacite-bearing metapelite occurs in the albite–biotite zone of the Togu (Tohgu) area, Besshi region, Sambagawa metamorphic belt, central Shikoku, Japan. This metapelite consists of alternating graphite-rich and graphite-poor layers that contain garnet, phengite, chlorite, epidote, titanite, calcite, albite, and quartz. A graphite-poor layer contains a 1.5-cm ivory-colored lens that mainly consists of phengite, calcite, albite, and garnet. Aragonite, omphacite, and paragonite occur as inclusions in the garnet of the ivory lens. The aragonite has a composition that is close to the CaCO3 end-member: the FeCO3 and MnCO3 components are both less than 0.3 mol% and the SrCO3 component is about 1 mol%. The aragonite + omphacite + quartz assemblage in garnet indicates equilibrium conditions of P > 1.1–1.3 GPa and T = 430–550°C. Quartz grains sealed in garnet of the aragonite and omphacite-bearing sample and other metapelites in the Togu area preserve a high residual pressure that is equivalent to the Sambagawa eclogite samples. These facts suggest that: (i) the Togu area experienced eclogite facies metamorphism; and (ii) thus, eclogite facies metamorphism covered the Sambagawa belt more extensively than previously recognized. 相似文献
5.
《Earth and Planetary Science Letters》2006,241(3-4):594-602
Chert and other hard monomineralic quartz grains weather mostly by mechanical processes in modern environments. Their clasts are overrepresented in conglomerates and sands relative to their sources regions. Conversely, macroscopic dissolution features, including quartzite karst, are rare but not nonexistent. The similar rarity of quartz dissolution in Archean deposits provides a paleothermometer for climate on the early Earth. For example, chert is overrepresented in conglomerates and sands of the ∼3.2 Ga Moodies Group (South Africa) relative to the source region. Features related to the far-from-equilibrium dissolution rate are particularly diagnostic as it increases an order of magnitude over 25 °C, much more than solubility. Extrapolating from observed dissolution rates in modern environments that weather at ∼25 °C, we expect obvious dissolution features in ancient climates above ∼50 °C. Polycrystalline quartz and chert would readily disaggregate by solution along grain boundaries, yielding silt and clay. Quartz grains within slowly weathering granite would become friable, yielding silt and clay, rather than sand. At still higher temperatures, Al2O3-rich clays from weathered granite would stand above solution-weathered chert on low-relief surfaces. The observed lack of these features is evidence that the Archean climate was not especially hot. 相似文献
6.
Abstract Thick Middle (–Upper) Miocene turbiditic deposits filled very deep and narrow foredeep basins formed in the western margin of the Hidaka collision zone in central Hokkaido. Cobble- to boulder-sized clasts of eight monzogranites and a single granodiorite in the Kawabata Formation in the Yubari Mountains area yielded biotite K–Ar ages of 44.4 ± 1.0 to 45.4 ± 1.0 Ma and 42.8 ± 1.1 Ma, respectively. Major elemental compositions of the clasts all fall in the field of S-type granite on an NK/A (Na2 O + K2 O/Al2 O3 in molecule) versus A/CNK (Al2 O3 /CaO + Na2 O + K2 O in molecule) diagram, verifying their peraluminous granite character (aluminium saturation index (ASI): 1.12–1.19). These geochronological and petrographical features indicate that the granitoid clasts in the Kawabata Formation correlate with Eocene granitic plutons in the northeastern Hidaka Belt, specifically the Uttsudake (43 Ma) and Monbetsu (42 Ma) plutons. Foredeep basins are flexural depressions developed at the frontal side of thickened thrust wedges. The results presented here suggest that deposition of the Middle Miocene turbidites was coeval with rapid westward up-thrusting and exhumation of the Hidaka Belt. This early mountain building may have occurred in response to thrusting in the Tertiary fold-and-thrust system of central Hokkaido. 相似文献
7.
IntroductionTheArchaeozoicfelsicrocksarethemaincomponentsoftheuppercrustincratonareas,whichmayalsoexistinthelowercrust(ZHANG,SUN,1999).Thereforethestudyontheircompressionalwavevelocitiesofthiskindofrocksisofimportance.Oneofthecharactersofthistypeofrocksisexistingofquartz.Athightemperatureandpressurethe(phaseofquartztransitsinto(phasecompaniedwithvelocitychange.Consequentlythefeatureoftemperature-velocitycurveoffelsicrocksatacertainpressureisexclusiveforothertypeofrocks.FirstFielitz(1971),… 相似文献
8.
文中讨论了库水渗漏在水库诱发地震中的作用,经过分析研究现有的水库诱发地震资料及相关理论,类比蒸汽锅炉与重力热管的热工原理,提出了水库地震成因的超临界水二级相变孕震模型。模型在水库孕震的各阶段表现为:初始阶段,渗漏水在压力注射和重力作用下形成水塞密封盖层,在超临界温区的地层裂隙中引发二级相变循环对流;孕育阶段,地层原生裂隙在高围压条件下形成应力腐蚀、化学蚀变、温差应力破碎作用,从而原生裂隙更加发育,制造了更大的对流循环通道;临震突变阶段,在热管下部热交换区内的临界水热通量剧增,超临界水发生横向流动,向封盖层外部扩散;发震阶段,在超临界水重力热管的通量和热管上部交换区所形成的压力,超过地层或封盖层的破坏极限时,推动上部地层做活塞运动导致地震 相似文献
9.
本文介绍用天然石英岩块等所进行的电磁波发射实验.得到了频段范围和强度.提出岩层突然破裂和断层两侧岩石剧烈摩擦是产生地震电磁波的一种重要机制,其机理是石英晶体破碎时,电偶极子群的产生和消失. 相似文献
10.
Abstract Small-volume plutons of Early to Late Cretaceous ages are widely distributed in the Yamizo Mountains, central Japan. These plutons consist predominantly of granitoids, classified into hornblende gabbro, quartz diorite, hornblende–biotite granodiorite and coarse-grained biotite granite. The quartz diorite (52–64 wt% of SiO2 ) is characterized by a high Sr content (606–769 p.p.m.) associated with a low Y (13–27 p.p.m.) and heavy rare earth element content (Yb content of 1.19–2.13 p.p.m.). On the Sr/Y versus Y diagram, this rock type mainly plots in the adakite and Archean high-Al tonalite, trondhjemite and granodiorite (TTG) field. Together with its initial Sr isotopic ratios, which range from 0.7038 to 0.7046, these data suggest that quartz diorite originated as slab melts. However, geochemical calculations assuming either eclogite or garnet amphibolite as the source material do not support this suggestion. Instead, the chemical compositions of quartz diorite are better explained by the fractional crystallization of hornblende, plagioclase and biotite from a primitive, basaltic melt in a magma chamber. In this case, the formation of the associated hornblende gabbro can also be explained by the accumulation of hornblende and plagioclase. Adakitic rocks of Early Cretaceous ages have also been reported in the Tamba Belt of the inner zone of southwest Japan, located ca 500 km west of the Yamizo Mountains. These rocks can be correlated to the adakitic rocks in the Yamizo Mountains based on the geology, petrography, geochemistry and radiometric ages. Therefore, we propose the possibility that the Early Cretaceous adakitic rocks in the inner zone of southwest Japan were produced by fractional crystallization from basaltic arc magmas generated by a partial melting of metasomatized wedge mantle peridotite. 相似文献
11.
Keika Horiguchi Sadato Ueki Yuji Sano Naoto Takahata Akira Hasegawa George Igarashi 《Island Arc》2010,19(1):60-70
In order to study the precise geographical distribution of helium isotope ratios in northeastern Japan and compare it with geophysical data, we collected 43 gas and water samples from hot and mineral springs in the region where the ratio had never been reported, and measured the 3 He/4 He and 4 He/20 Ne ratios of these samples. It was found that the 3 He/4 He ratios show clear contrasts between the forearc and the back-arc regions in the Tohoku district in northeastern Japan. In the forearc region, the ratios are smaller than 1 RA (1 RA = 1.4 × 10−6 ; RA means the 3 He/4 He ratio of the atmosphere). On the other hand, those along the volcanic front and in the back-arc region are apparently higher. Moreover, we found a variation in the 3 He/4 He ratios along the volcanic front. In Miyagi Prefecture (38–39°N), the ratios range from 2 to 5 RA . On the other hand, the ratios are less than 1 RA in and around the southern border between Iwate and Akita Prefectures (39–39.5°N). Comparing the distribution of helium isotope ratios to results of recent geophysical studies, we found that the features in geographical distribution of helium isotope ratios are similar to those of seismic low-velocity zone distributions and high Qp−1 distributions in the uppermost mantle. These observations strongly suggest that the helium isotope ratios reflect the distribution of melts in the uppermost mantle and are a useful tool for investigating the origin, behavior, and distribution of deep fluids and melts. 相似文献
12.
Abstract Electron spin resonance (ESR) analyses of quartz grains in fault gouge were performed for a core sample taken from the Nojima Fault that moved during the 1995 Kobe earthquake (Hyogo-ken Nanbu earthquake). Distribution of radiation-induced defects in the gouge at a depth of 389.4 m was measured by extracting quartz grains from seven discrete positions within 30 mm of the fault plane on the granite side. The decrease in E'1 and Al centers was observed within 2 mm of the fault plane, suggesting partial annealing due to faulting. Partial annealing even at that depth suggested that conventional ESR dating, which is based on the hypothesis of complete annealing during faulting, was not applicable. Theoretical calculations of the temperature rise and of the thermal annealing of defects have been made by assuming a simple annealing model of heat generation on the fault plane. Thermal energy was calculated to have been approximately 8 MJ/m2 to explain the profile of the heat-affected region. Thermal energy was much larger than the one estimated from hydrothermal solution, and corresponded to the frictional heat calculated for a normal stress of 20 MPa, a displacement of 2 m, and a frictional coefficient of 0.2. 相似文献
13.
The Ina district of the Ryoke Belt is divided into two mineral zones, based on the mineral parageneses of the pelitic and psammitic rocks at the peak metamorphism. A biotite–muscovite zone (quartz + plagioclase + biotite + muscovite with or without K-feldspar) constitutes the northwestern part, and a biotite–cordierite–K-feldspar zone (quartz + plagioclase + biotite + cordierite + K-feldspar) comprises the central to southern and eastern parts. The isograd reaction between two mineral zones is defined by a divariant reaction: Mg-rich biotite + muscovite + quartz = Fe-rich biotite + cordierite + K-feldspar + H2 O (1), which, in the K2 O–FeO–MgO–Al2 O3 –SiO2 –H2 O (KFMASH) system, occurs at ∼ 590 °C at 0.2 GPa and 660 °C at 0.4 GPa. Fibrolite accompanied by andalusite porphyroblasts in aluminous pelitic rocks of the biotite–muscovite zone and the low-grade part of the biotite–cordierite–K-feldspar zone, suggests that sillimanite was the stable aluminosilicate at the peak metamorphic condition throughout the area. In the high-grade part of the biotite–cordierite–K-feldspar zone, fibrolite mostly occurs as inclusions in cordierite or in plagioclase. The phase relations and the compositional zoning of plagioclase in relation to fibrolite inclusions suggest that fibrolite was formed under relatively high-pressure conditions, and that partial melting took place. 相似文献
14.
Evidence from pseudomorphous β-quartz phenocryst for decompression of rock-forming and ore-forming processes in Shapinggou porphyry Mo deposit 总被引：1，自引：0，他引：1
The Shapinggou porphyry molybdenum(Mo) deposit, located in Jinzhai County, Anhui Province, China, is the largest in the Qinling-Dabie Mo Metallogenic Belt. The intrusive rocks in the Shapinggou Mo ore district formed in the Yanshanian can be divided into two stages based on zircon U-Pb dating and geochemical features. This study focuses on the late stage intrusions(quartz syenite and granite porphyry), which are closely genetically related to molybdenum mineralization. Petrographic observations identified two quartz polymorphs in the quartz syenite and granite porphyry, which were derived from the same magmatic sources and similar evolutionary processes. The quartzes were identified as a xenomorphic β-quartz within quartz syenite, while the quartz phenocrysts within the granite porphyry were pseudomorphous b-quartz, characterized by a hexagonal bipyramid crystallography. The pseudomorphous b-quartz phenocrysts within the granite porphyry were altered from b-quartz through phase transformation. These crystals retained b-quartz pseudomorph. Combined with titanium-inzircon thermometry, quartz phase diagrams, and granitic Q-Ab-Or-H_2O phase diagrams, it is suggested that the quartz syenite and granite porphyry were formed under similar magmatic origins, including similar depths and magmatic crystallization temperatures. However, the β-quartz within quartz syenite indicated that the crystallization pressure was greater than 0.7 GPa, while the original b-quartz within the granite porphyry was formed under pressures between 0.4 and 0.7 GPa. The groundmass of the granite porphyry which formed after the phenocryst indicated a crystallizing pressure below 0.05 GPa. This indicates that the granite porphyry was formed under repetitive and rapid decompression. The decompression was significant as it caused the exsolution of the ore-forming fluids, and boiling and material precipitation during the magmatic-fluid process. The volumetric difference during the phase transformation from b-quartz to β-quartz caused extensive fracturing on the granite porphyry body and the wall rocks. As the main ore-transmitting and ore-depositing structures, these fractures benefit the hydrothermal alteration and stockwork-disseminated mineralization of the porphyry deposit. It is considered that the pseudomorphous β-quartz phenocrysts of the porphyritic body are metallogenic indicators within the porphyry deposits. The pseudomorphous β-quartzes therefore provide evidence for the formation of the porphyry deposit within a decompression tectonic setting. 相似文献
15.
Fluid inclusions in quartz from miarolitic cavities, pegmatites, and quartz veins in Miocene biotite-granite plutons, Kofu, Japan, were analyzed by particle-induced X-ray emission to examine chemistries and behaviors of granite-derived fluids in island-arc granite. Most inclusions are aqueous two-phase inclusions, and halite-bearing polyphase inclusions are also observed in quartz veins in the upper part of the plutons. From element contents of fluid inclusions in the miarolitic cavities, the original fluid released from the granite plutons during solidification is inferred to have concentrations of Mn, Fe, Cu, Zn, Ge, Br, Rb, Pb, and Ba of several tens to hundreds of parts per million by weight (ppm) and a salinity of about 10 wt% NaCl equivalent. We estimated the formation conditions of the fluid to have been at about 1.3–1.9 kb and 530–600°C on the basis of the homogenization temperatures of the inclusions and the solidification conditions of the plutons. The polyphase inclusions probably originated from hypersaline fluid by boiling of part of the released fluid during its ascent in the plutons. The polyphase inclusions contain several hundreds to tens of thousands of ppm of Fe and Mn, and tens to several hundreds of ppm of Cu, Zn, Br, Rb, and Pb. The salinities are about 35 wt% NaCl equivalent. Compositional variations in two-phase inclusions from the miarolitic cavities and quartz veins are primarily explained by mineral precipitation with dilution by surface water exerting a secondary influence. Thus, chemistries and behaviors of the granite-derived fluids in the plutons can be explained by mineral precipitation, boiling, and dilution of the originally released fluid. 相似文献
16.
Dissolution of eight clay minerals, four zeolites, and quartz in seawater has been monitored for81/2 years. For most of the minerals, dissolution can be described as a first-order reaction in which dissolved silica approaches from undersaturation steady concentration values with time. Characteristic reaction rate constants (k1) are of the order of 10?7 sec?1. One of the zeolites, clinoptilolite, shows a different dissolution behavior: SiO2 concentration in solution reaches a high value within one year, followed by a decline to a lower value, suggestive of precipitation of another silicate phase (possibly sepiolite).A mathematical solution is given for a kinetic equation combining the parabolic-rate and first-order rate processes. It is shown that in a wide range of silicate dissolution reactions taking place over long periods of time, the presence of the parabolic-rate dissolution processes cannot be detected, thereby making its inclusion in the kinetic equations unnecessary. The experimental rates of dissolution are comparable to the SiO2? dissolution rates in oceanic sediments near the sediment/water interface. But deeper in the sediment, the calculated dissolution rates are significantly lower than the near-interface and experimental values. 相似文献
17.
Biotite granite from the Sierra Nevada batholith was reacted, with known water contents in sealed platinum capsules, in a piston-cylinder apparatus between 10 and 35 kb. With the liquid just over-saturated with respect to water, temperatures for solidus and liquidus (quartz/coesite-out curve), respectively, are: 2 kb, 680°C, 715°C; 10 kb, 620°C, 725°C; 25 kb, 655°C, 800°C; 35 kb, 700°C, 850°C. The temperature interval is 35°C at 2 kb, 105°C at 10 kb, and 150°C at 35 kb, indicating that granite departs from a eutectic composition at depths greater than about 40–50 km. We conclude that crystal-liquid equilibria are not likely to yield primary rhyolite or granite magmas by partial fusion of oceanic crust in subduction zones. The solubility of water in granite liquids, in wt%, is 22.5 ± 2.5 at 25 kb and 810°C and 27 ± 2.5 at 35 kb and 850°C. These results indicate that a miscibility gap persists between water-saturated silicate magmas and aqueous vapor phase at least to pressures corresponding to 100 km depth in the mantle. The formation of kyanite near the liquidus of water over-saturated granite indicates that the aqueous vapor phase is enriched in alkalis and possibly silica, relative to the condensed phases. 相似文献
18.
19.
Akira Usui Ian J. Graham Robert G. Ditchburn Albert Zondervan Hiroshi Shibasaki Hajime Hishida 《Island Arc》2007,16(3):420-430
Abstract Hydrogenetic ferromanganese crusts are widespread on the floor of the northwestern Pacific Ocean, south and east of the Japanese Islands, despite vigorous tectonic activity, such as subduction and back-arc spreading, since at least the Mid-Paleogene over the Philippine Sea Plate region and nearby. The crusts occur mainly at water depths shallower than 3000 m, but also at greater depths of up to 6000 m. Fine-scale 10 Be/9 Be dating was undertaken on several 5–10 cm thick hydrogenetic ferromanganese crusts sampled from different geological environments, including inactive submarine volcanoes, tectonic escarpments and abandoned rifts. The results indicate that the crusts have grown at relatively constant rates of 4–7 mm/my without any significant time breaks. These uniform and constant growth rates suggest that the basins have been exposed constantly to oxygenated bottom waters since their formation in the Middle Miocene ( ca 15 Ma) or earlier. Local geological or oceanographic environmental changes might have slowed or increased some of the growth rates resulting in correlation of some internal structures. The Philippine Sea Plate region could have economic potential in areas of thick hydrogenetic ferromanganese crusts over a wide range of water depths. 相似文献
20.
Abstract Calcretes can be observed on the surface of old moraines around Batura Glacier in the upper Hunza Valley, Karakoram Mountains, Pakistan. They develop as a calcareous crust cementing small gravels under boulders. In order to understand the genesis of the calcrete crust, a variety of methods were employed: (i) study of mineralogy and geochemistry of a calcrete crust precipitated on the lateral moraine using X-ray diffractometer and electron probe microanalysis; (ii) analysis of solute chemistry of surface water and ice bodies around the Batura Glacier; and (iii) accelerator mass spectrometry 14 C dating of the crust itself. The results indicate that the calcrete crust has definite laminated layers composed of a fine-grain and compact calcite layer, and a mineral fragment layer. The chemical composition of the calcite layer is approximately 60% CaO and 1% MgO. The mineral fragment layer consists of rounded grain materials up to 0.2 mm in diameter. It shows a graded bedding structure with fine grains of quartz, albite and muscovite. Meanwhile, as the Paleozoic Pasu limestone is distributed around the terminal of Batura Glacier, Ca cations dissolve in the melt water of the glacier. Accordingly, the calcrete crust is precipitated by decreases in CO2 partial pressure from glacier ice and evaporation of the melt water, including high concentration of Ca2+ at ephemeral streams and small ponds stagnating between the moraine and glacial ice. On the basis of the AMS 14 C age, the calcrete is considered to have formed approximately 8200 calibrated years bp under the Batura glacial stage. 相似文献