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1.
Estimates of daily lake evaporation based on energy‐budget data are poor because of large errors associated with quantifying change in lake heat storage over periods of less than about 10 days. Energy‐budget evaporation was determined during approximately biweekly periods at a northern Minnesota, USA, lake for 5 years. Various combinations of shortwave radiation, air temperature, wind speed, lake‐surface temperature, and vapour‐pressure difference were related to energy‐budget evaporation using linear‐regression models in an effort to determine daily evaporation without requiring the heat‐storage term. The model that combined the product of shortwave radiation and air temperature with the product of vapour‐pressure difference and wind speed provided the second best fit based on statistics but provided the best daily data based on comparisons with evaporation determined with the eddy‐covariance method. Best‐model daily values ranged from ?0.6 to 7.1 mm/day over a 5‐year period. Daily averages of best‐model evaporation and eddy‐covariance evaporation were nearly identical for all 28 days of comparisons with a standard deviation of the differences between the two methods of 0.68 mm/day. Best‐model daily evaporation also was compared with two other evaporation models, Jensen–Haise and a mass‐transfer model. Best‐model daily values were substantially improved relative to Jensen–Haise and mass‐transfer values when daily values were summed over biweekly energy‐budget periods for comparison with energy‐budget results. 相似文献
2.
This paper consists of two parts. In the first part, the significance of five major factors, including solar radiation, vapour pressure deficit, relative humidity, wind speed and air temperature, that control evaporation were evaluated comparatively at different time-scales using the data from Changines station in Switzerland. The comparative evaluation was made at hourly, daily, 10-day and monthly time-scales. It was found that the role of controlling variables in evaporation varied with the time-scale. The vapour pressure deficit was best correlated with pan evaporation at all time-scales, while the wind speed was least correlated with pan evaporation, especially when the time period was longer than a day. In the second part, four equations for calculating evaporation, including temperature-based methods, humidity-based methods, mass transfer methods and radiation-based methods, were compared with pan evaporation. Of these four equations, the Penman equation, representing the mass transfer method, resulted in monthly evaporation values that agreed most closely with pan evaporation values. The Romanenko equation, representing the humidity method, also compared reasonably well with pan evaporation. The Turc equation, representing the radiation method, and the Thornthwaite equation, representing the temperature method, were found to underestimate evaporation significantly, especially for cold months. © 1998 John Wiley & Sons, Ltd. 相似文献
3.
水面蒸发与散热系数公式研究(二) 总被引：16，自引：0，他引：16
根据自1976年以来全国水面蒸发与散热研究协作组在我国各典型地区的原体与室内实验资料和大量水文站历史资料,通过理论分析和统计检验,确定了影响水面蒸发的诸因子及其非线性相互作用,引入了新的无量纲参数和公式结构,用实测资料统计确定了公式中的常系数,得到了用开敞湖面一般水文气象资料计算逐日蒸发和散热系数的公式。经全国务典型气候带内务季节湖泊(水库)和受热污染水体上原体观测和室内专题实验共1860组日平均检验,公式的精度高于现有其他公式。全文分两部分,本文刊出第二部分,内容包括:公式的检验;水文气象要素对α的影响;水面散热系数的计算和结语。 相似文献
4.
The scenario assumed for this study was that of a region with a complete or first‐order weather station surrounded by a network of second‐order stations, where only monthly air temperature data were available. The objective was to evaluate procedures to estimate the monthly α parameter of the Priestley–Taylor equation in the second‐order stations by adjusting and extrapolating α values determined at the first‐order station. These procedures were applied in two climatic zones of north‐east Spain with semi‐arid continental and semi‐arid Mediterranean climates, respectively. Procedure A assumed α to be constant over each zone for each month (direct extrapolation). Procedure B accounted for differences in vapour pressure deficit and available energy for evapotranspiration between the first‐ and second‐order stations. Procedure C was based on equating the Penman–Monteith (P–M) and Priestley–Taylor (P–T) equations on a monthly basis to solve for α. Methods to estimate monthly mean vapour pressure deficit, net radiation and wind speed were developed and evaluated. A total of 11 automated first‐order weather stations with a minimum period of record of 6 years (ranging from 6 to 10 years) were used for this study. Six of these stations were located in the continental zone and five in the Mediterranean zone. One station in each zone was assumed to be first‐order whereas the remainder were taken as second‐order stations. Monthly α parameters were calibrated using P–M reference crop evapotranspiration (ET0) values, calculated hourly and integrated for monthly periods, which were taken as ‘true’ values of ET0. For the extrapolation of monthly α parameters, procedure A was found to perform slightly better than procedure B in the Mediterranean zone. The opposite was true in the continental zone. Procedure C had the worst performance owing to the non‐linearity of the P–M equation and errors in the estimation of monthly available energy, vapour pressure deficit and wind speed. Procedures A and B are simpler and performed better. Overall, monthly P–T ET0 estimates using extrapolated α parameters and Rn?G values were in a reasonable agreement with P–M ET0 calculated on an hourly basis and integrated for monthly periods. The methods presented for the spatial extrapolation of monthly available energy, vapour pressure deficit and wind speed from first‐ to second‐order stations could be useful for other applications. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献
5.
Özgür Kişi 《水文研究》2009,23(2):213-223
This paper reports on investigations of the abilities of three different artificial neural network (ANN) techniques, multi‐layer perceptrons (MLP), radial basis neural networks (RBNN) and generalized regression neural networks (GRNN) to estimate daily pan evaporation. Different MLP models comprising various combinations of daily climatic variables, that is, air temperature, solar radiation, wind speed, pressure and humidity were developed to evaluate the effect of each of these variables on pan evaporation. The MLP estimates are compared with those of the RBNN and GRNN techniques. The Stephens‐Stewart (SS) method is also considered for the comparison. The performances of the models are evaluated using root mean square errors (RMSE), mean absolute error (MAE) and determination coefficient (R2) statistics. Based on the comparisons, it was found that the MLP and RBNN computing techniques could be employed successfully to model the evaporation process using the available climatic data. The GRNN was found to perform better than the SS method. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
6.
AbstractThis paper develops an algorithm for computing spatially-distributed monthly potential evaporation (PE) over a mountainous region, the Lhasa River basin in China. To develop the algorithm, first, correlation analysis of different meteorological variables was conducted. It was observed that PE is significantly correlated with vapour pressure and temperature differences between the land surface and the atmosphere. Second, the Dalton model, which was developed based on the mass transfer mechanism, was modified by including the influence of the related meteorological variables. Third, the influence of elevation on monthly temperature, vapour pressure and wind velocity was analysed, and functions for extending these meteorological variables to any given altitude were developed. Fourth, the inverse distance weighting method was applied to integrate the extended meteorological variables from five stations adjacent to and within the Lhasa River basin. Finally, using the modified Dalton model and the integrated meteorological variables, we computed the spatially-distributed monthly PE. This study indicated that spatially-distributed PE can be obtained using data from sparse meteorological stations, even if only one station is available; the results show that in the Lhasa River basin PE decreases when elevation increases. The new algorithm, including the modified model and the method for spatially extending meteorological variables can provide the basic inputs for distributed hydrological models.
Editor Z.W. Kundzewicz 相似文献
7.
水面蒸发与散热系数公式研究(一) 总被引：16，自引：1，他引：15
根据自1976年以来全国水面蒸发与散热研究协作组在我国各典型地区的原体与室内实验资料和大量水文站历史资料,通过理论分析和统计检验,确定丁影响水面蒸发的诸因子及其非线性相互作用,引入了新的无量纲参数(w_e、Pv、Pe)和公式结构,用实测资料统计确定厂公式中的常系数,得到了用开敞湖面一般水文气象资料计算逐日蒸发和散热系数的公式。经全国各典型气候带内各季节湖泊(水库)和受热污染水体上原体观测和室内专题实验共1860组口平均资料检验,公式的精度高于现有其他公式。全文分两部分,这是第一部分,内容包括:影响水面蒸发的土要无量纲参数;感热输送和大气饱和度对蒸发影响的修正;水面蒸发计算公式的结构及其经验系数。 相似文献
8.
Morton's complementary relationship areal evapotranspiration (CRAE) model was originally designed to provide regional estimates of monthly evapotranspiration. Often, however, hydrologists and others require estimates of evapotranspiration for field-sized land units under a specific land use, for shorter intervals of time. This paper examines CRAE with respect to the algorithms used to describe different terms and its applicability to reduced spatial and temporal scales.
Daily estimates by CRAE of atmospheric radiation fluxes during the summer months are compared with monitored values. It is shown that errors in estimation of the extra-terrestrial flux, the transmittancy of clouds to short-wave radiation, the surface albedo and the net long-wave flux result in standard deviations of the difference between ‘modelled’ and ‘measured’ net all-wave radiation for 1-, 5- and 10-day periods of 2.58, 1.8 and 1.50 MJm−2 day−1 respectively.
The assumption in CRAE that the vapour transfer coefficient is independent of wind speed may lead to appreciable error in computing evapotranspiration. A procedure for incorporating a wind correction factor is described and the improvement in estimating regional evaporation is illustrated.
Comparisons of evapotranspiration estimates by CRAE and measurements obtained from soil moisture and precipitation observations in the semi-arid, cold-climate Prairie region of western Canada demonstrate that the assumptions that the soil heat flux and storage terms are negligible, lead to large overestimation by the model during periods of soil thaw. 相似文献
9.
鄱阳湖夏季水面蒸发与蒸发皿蒸发的比较 总被引：3，自引：1，他引：2
水面蒸发是湖泊水量平衡要素的重要组成部分.基于传统蒸发皿观测蒸发不能代表实际水面蒸发,而实际水面蒸发特征仍不清楚.本研究基于涡度相关系统观测的鄱阳湖水体实际水面蒸发过程,在小时和日尺度分析了水面蒸发的变化规律及其主要影响因子,并与蒸发皿蒸发进行比较.研究表明,实际水面蒸发日变化波动剧烈,变化范围在0~0.4 mm/h之间.水面蒸发的日变化特征主要受风速的影响.鄱阳湖8月份日水面蒸发量与蒸发皿蒸发量在总体趋势上具有很好的一致性.8月份平均日水面蒸发速率(5.90 mm/d)比蒸发皿蒸发速率(5.65 mm/d)高4.6%.水面日蒸发量与蒸发皿蒸发量的比值在8月上、中、下旬平均值分别为1.24、1.00、0.92,呈现下降的趋势.鄱阳湖夏季水面日蒸发量与风速和相对湿度相关性显著,而蒸发皿蒸发与净辐射、气温、饱和水汽压差和相对湿度均呈显著相关.这是由于蒸发皿水体容积小,与湖泊相比其水体热存储能力小,因此更容易受到环境因子的影响. 相似文献
10.
Evaporative flux is a key component of hydrological budgets. Water loss through evapotranspiration reduces volumes available for run‐off. The transition from liquid to water vapour on open water surfaces requires heat. Consequently, evaporation act as a cooling mechanism during summer. Both river discharge and water temperature simulations are thus influenced by the methods used to model evaporation. In this paper, the impact of evapotranspiration estimation methods on simulated discharge is assessed using a semidistributed model on two Canadian watersheds. The impact of evaporation estimation methods on water temperature simulations is also evaluated. Finally, the validity of using the same formulation to simulate both of these processes is verified. Five well‐known evapotranspiration models and five evaporation models with different wind functions were tested. Results show a large disparity (18–22% of mean annual total evapotranspiration) among the evapotranspiration methods, leading to important differences in simulated discharge (3–25% of observed discharge). Larger differences result from evaporation estimation methods with mean annual divergences of 34–48%. This translates into a difference in mean summer water temperature of 1–15%. Results also show that the choice of model parameter has less influence than the choice of evapotranspiration method in discharge simulations. However, the parameter values influence thermal simulations in the same order of magnitude as the choice of evaporation estimation method. Overall, the results of this study suggest that evapotranspiration and open water evaporation should be represented separately in a hydrological modelling framework, especially when water temperature simulations are required. 相似文献
11.
Sensitivity analysis is crucial in assessing the impact of climatic variables on reference evapotranspiration estimations. The sensitivity of the standardized ASCE–Penman–Monteith evapotranspiration equation for daily estimations to climatic variables has not yet been studied in Spain. Andalusia is located in southern Spain where almost 1 million ha are irrigated under quite different conditions; it has a high inter‐annual variability in rainfall. In this study, sensitivity analyses for this equation were carried out for temperature, relative humidity, solar radiation and wind speed data from 87 automatic weather stations, including coastal and inland locations, from 1999 to 2006. Topography and Mediterranean climate characterize the heterogeneous landscape and vegetation of this region. Simulated random and systematic errors have been added to meteorological data to obtain ET0 deviations and sensitivity coefficients for different time periods. BIAS and SEE (standard error of estimate) have been used to evaluate the effect of both types of errors. The results showed a large degree of daily and seasonal variability, especially for temperature and relative humidity. In general, the effect on ET0 values of introduced random errors was larger than that of systematic errors. ET0 overestimations were produced using positive errors in temperature, solar radiation and wind speed data, while these errors in relative humidity resulted in ET0 underestimations. The sensitivity of ET0 to the same climatic variables showed significant differences among locations. The geographical distribution of sensitivity coefficients across this region was also studied. As an example, during spring months, ET0 equation was more sensitive to temperature in stations located along the Guadalquivir Valley. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
12.
Long‐term variations and temporal scaling of hydroclimatic time series with focus on the German part of the Elbe River Basin 
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下载免费PDF全文 Long‐term variations and temporal scaling of mean monthly time series of river flow, precipitation, temperature, relative humidity, air pressure, duration of bright sunshine, degree of cloud cover, short wave radiation, wind speed and potential evaporation within or in vicinity of the German part of the Elbe River Basin are analyzed. Statistically significant correlations between the 2–15 year scale‐averaged wavelet spectra of the hydroclimatic variables and the North Atlantic Oscillation‐ and Arctic Oscillation index are found which suggests that such long‐term patterns in hydroclimatic time series are externally forced. The Hurst parameter estimates (H) based on the Detrended Fluctuation Analysis (DFA) indicate persistence for discharge, precipitation, wind speed, air pressure and the degree of cloud cover, all having an annual cycle and a broad low‐frequency distribution. Also, DFA H parameter estimates are higher for discharge than for precipitation. The major long‐term quasi‐periodic variability modes of precipitation detected using Singular Spectrum Analysis coincide with those detected in the discharge time series. Upon subtraction of these low‐frequency quasi‐periodic modes, the DFA H parameter estimates suggest absence of the persistence for both precipitation and discharge. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
13.
Pérez-Bella José M. Domínguez-Hernández Javier Cano-Suñén Enrique del Coz-Díaz Juan J. Álvarez Rabanal Felipe P. 《Stochastic Environmental Research and Risk Assessment (SERRA)》2018,32(6):1799-1815
Both semi-empirical methods and CFD simulations use real climate datasets as a basis for determining the building facade exposure to wind-driven rain and simultaneous wind pressure. The time resolution of these datasets and the number of variables considered (commonly rainfall intensity, wind speed and wind direction) determine the required calculation effort and the accuracy of the result. Omitting the wind direction, a former article (Part I of this research) has analysed the effect of this time resolution on two scalar exposure indices obtained by semi-empirical methods: driving rain index (aDRI) and driving-rain wind pressure (DRWP). However, the wind direction during precipitation events also causes significant exposure variations between possible facade orientations. Thus, it is also necessary to clarify the influence of the time resolution of the dataset, on the accuracy of the directional semi-empirical calculation of aDRI and DRWP. To meet this challenge, the article examines 10-min climate records collected between 2001 and 2016 at 6 Spanish locations, uses them to obtain hourly, daily, monthly and annual datasets, and analyses the accuracy of the directional exposure indices associated with each time resolution. The results show that a daily dataset would allow identifying the most exposed orientation with an error less than 45°. However, even the hourly datasets cause errors close to 10% in the exposure values identified on each facade orientation. Finally, adjustment relationships that allow estimating the maximum value of directional exposure from simple scalar indices are obtained.
相似文献14.
Spatially distributed hydrometeorological and plant information within the mountainous tropical Panama Canal watershed is used to estimate parameters of the Penman–Monteith evapotranspiration formulation. Hydrometeorological data from a few surface climate stations located at low elevations in the watershed are complemented by (a) typical wet‐ and dry‐season fields of temperature, wind, water vapour and pressure produced by a mesoscale atmospheric model with a 3 × 3 km2 spatial and hourly temporal resolution, and (b) leaf area index fields estimated over the watershed during a few years using satellite data with two different spatial and temporal resolutions. The mesoscale model estimates of spatially distributed surface hydrometeorological variables provide the basis for the extrapolation of the surface climate station data to produce input for the Penman–Monteith equation. The satellite information and existing digital spatial databases of land use and land cover form the basis for the estimation of Penman–Monteith spatially distributed parameter values. Spatially distributed 3 × 3 km2 potential evapotranspiration estimates are obtained for the 3300 km2 Panama Canal watershed. Estimates for Gatun Lake within the watershed are found to reproduce well the monthly and annual lake evaporation obtained from submerged pans. Sensitivity analysis results of potential evapotranspiration estimates with respect to cloud cover, dew formation, leaf area index distribution and mesoscale model estimates of surface climate are presented and discussed. The main conclusion is that even the limited spatially distributed hydrometeorological and plant information used in this study contributes significantly toward explaining the substantial spatial variability of potential evapotranspiration in the watershed. These results also allow the determination of key locations within the watershed where additional surface stations may be profitably placed. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
15.
Lake E?irdir is located in the Lakes District in southwestern Turkey and it is the second largest freshwater resource lake. Evaporation is an important parameter in hydrological and meteorological practical studies. This study has three objectives: (1) to develop models for the estimation of daily evaporation using measured data from the automated GroWeather meteorological station located near Lake E?irdir; (2) to compare the evaporation models with the classical Penman approach; (3) to evaluate the potential of each model. The comparisons are based on daily and monthly available data from 2001 and 2002. The evaporation estimation models (EEMs) developed in this paper have lower mean absolute errors and higher coefficient of determination R2 values than the Penman method. In order to evaluate the potential of the EEMs, daily evaporation values are calculated by the Priestley–Taylor, Brutsaert–Stricker, de Bruin, Makkink and Hamon methods. The EEMs are statistically indistinguishable from the classical methods on the basis of the parameters of mean, standard deviation, etc. In the evaluation of daily and monthly values, the relative error percentage for daily evaporation has lower values than for monthly evaporation. It can be seen that the EEMs help in calculating daily evaporation rather than monthly. Final evaluation and comparison indicate that there is a good agreement between the results of EEMs and the Penman approach than with the classical methods. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
16.
Junfeng Chen Xue Xie Xiuqing Zheng Jing Xue Chunyan Miao Qi Du Yongxin Xu 《水文研究》2020,34(13):2830-2842
Control of evaporation from seasonally frozen soil is an important method for alleviating water shortages in arid and semi-arid areas. To investigate the inhibition of soil evaporation by sand and the major factors that influence soil evaporation, a series of field experiments with five sand-mulch thicknesses (0 cm, bare soil [BS], 1 cm [T1], 2 cm [T2], 3 cm [T3] and 4 cm [T4], with an average diameter of 1 mm) were conducted during the freeze–thaw period in Northern China. Soil evaporation characteristics in the three freeze–thaw stages were revealed and the major factors influencing soil evaporation were analysed using grey correlation analysis. The results showed that the cumulative soil evaporation decreased with increasing sand-mulch thickness during the freeze–thaw period, and only small differences in soil evaporation were observed between the T3 and T4 treatments. The reduction in soil evaporation under different sand-mulch thicknesses was 19.2–62.6% in the unstable freezing stage (P1), 2.0–28.3% in the stable freezing stage (P2) and 4.8–20.4% in the thawing stage (P3). In P1, solar radiation was a major factor influencing soil evaporation in all treatments and vapour pressure was a major factor in the sand-mulch treatments, and the influence of relative humidity on soil evaporation decreased in the T4 treatment. During the coldest P2, solar radiation was lowest so that relative humidity and wind speed became the more dominant influence factors on soil evaporation in all treatments, and surface soil water content was a major factor in the sand-mulch treatments. In P3, average air temperature and solar radiation were major factor influencing soil evaporation in all treatments and vapour pressure was a major factor in the BS and T1 treatments, whereas water surface evaporation was the major factor in the T2, T3 and T4 treatments. The results suggest that the addition of sand mulch in agricultural fields may be a beneficial practice to reduce water stress in arid and semi-arid areas. 相似文献
17.
The Wind Erosion Prediction System (WEPS) and Revised Wind Erosion Equation (RWEQ) are widely used for estimating wind‐induced soil erosion at a field scale. Wind is the principal erosion driver in the two models. Wind erosivity, which describes the capacity of wind to cause soil erosion, is defined as erosive wind power density (WPD) in WEPS, and wind value (W) in RWEQ. In this study, the daily average WPD (AWPD) and the daily average W (Wf) were chosen to investigate the effect of averaging time on wind erosivity estimation based on observed wind data. We compare the daily AWPD and Wf calculated from 1, 5, 10, 15, 30, and 60 minute average wind speed data. The results of comparisons indicate that averaging wind speed can significantly influence estimates of wind erosivity. Compared with the daily AWPD and Wf calculated from one minute average wind speed data, all daily AWPD and Wf values calculated from 5, 10, 15, 30, and 60 minute averaged wind speeds tend to be significantly lower than values calculated from one minute values. In general, longer averaging times tend to produce smaller values of daily AWPD or Wf, which may lead to an under‐estimation of wind erosion. Further studies are needed to extend and apply the findings obtained in this study to actual wind erosion predictions. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
18.
Sublimation from thin snow cover at the edge of the Eurasian cryosphere in Mongolia was calculated using the aerodynamic profile method and verified by eddy covariance observations using multiple‐level meteorological data from three sites representing a variety of geographic and vegetative conditions in Mongolia. Data were collected in the winter and analysed from three sites. Intense sublimation events, defined by daily sublimation levels of more than 0·4 mm, were predominant in their effect on the temporal variability of sublimation. The dominant meteorological elements affecting sublimation were wind speed and air temperature, with the latter affecting sublimation indirectly through the vapour deficit. Seasonal and interannual variations in sublimation were investigated using long‐interval estimations for 19 years at a mountainous‐area meteorological station and for 24 years at a flat‐plain meteorological station. The general seasonal pattern indicated higher rates of sublimation in both the beginning and ending of the snow‐covered period, when the wind speed and vapour deficit were higher. Annual sublimation averaged 11·7 mm at the flat‐plain meteorological station, or 20·3% of the annual snowfall, and 15·7 mm at the site in the mountains, or 21·6% of snowfall. The sum of snow sublimation and snowmelt evaporation represented 17 to 20% of annual evapotranspiration in a couple observation years. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
19.
蓝藻水华频繁暴发是太湖面临的主要环境问题之一,蓝藻聚集上浮是表层水华形成的前提。为探究蓝藻垂向迁移与水华日变化之间的关系,阐明蓝藻垂向迁移的关键影响因素,基于2015-2020年地球静止海洋彩色成像仪(GOCI)数据,分析了太湖不同湖区蓝藻水华日变化过程,发现太湖蓝藻水华垂向迁移的日变化主要呈现上升、下降、先上升后下降三种类型,且不同湖区存在差异。统计分析和偏最小二乘法结构方程模型(PLS-SEM)结果表明,水环境因子对蓝藻垂向迁移过程影响较小,累积光辐射是驱动蓝藻垂向迁移的主要气象因子。气温升高有利于蓝藻持续维持上浮能力,前一天风速较大且当天风速较小会加速蓝藻上浮。相较于沿岸湖区,湖心区受累积光辐射、风速的影响更大,蓝藻水华日变化过程更剧烈。本研究水环境因子数据为逐月数据,为深入探究水环境因子对蓝藻垂向迁移的影响后续还需进行高频监测研究。本文结果有助于探明浅水湖泊蓝藻水华形成机制,为富营养化湖泊蓝藻水华预测预警及治理提供理论支撑。 相似文献
20.
Isotopic exchange with atmospheric vapour can strongly influence the isotopic values of evaporating surface water bodies (e.g., lakes), influencing our understanding of hydrological processes across aquatic and terrestrial environments. Rather than measure the isotopic values of the atmosphere directly, it is much more common to estimate values by assuming equilibrium with local precipitation. This assumption may introduce large errors, thereby biasing hydrological inferences and understanding. The pattern and magnitude of this error has been quantified only in a few circumstances. We compared observations of vapour and precipitation isotope values over a four-year record collected in a montane environment in the central Rocky Mountains of North America. We further investigated factors and conditions promoting disequilibrium. Scenario comparisons assessed the impact of theoretical and methodological elements on the accuracy of the equilibrium assumption. We found that the equilibrium assumption was not well supported by direct and continuous observations of vapour isotopes using tower-based laser isotope spectroscopy, particularly during the summer months. Across all scenarios, errors associated with the equilibrium assumption were high, credibly ranging from 14 to 154 ‰ for δ2H and 1.5 to 16.3 ‰ for δ18O. Environmental covariates (e.g., vapour pressure deficit, air pressure) helped explain some of the apparent disequilibrium. Although the equilibrium assumption for estimating atmospheric vapour isotope values may not be applicable in a continental montane environment, our findings highlight opportunities for using direct vapour isotope measurements to better understand vapour sources, air mass mixing, and phase changes over complex mountainous terrain, which in turn may better constrain regional- to global-scale hydrological process estimates, such as evapotranspiration rates and the water budgets of mountain lakes. 相似文献