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《Marine and Petroleum Geology》2012,35(1):96-110
We present a methodology for generating pre-drill estimations of hydrate saturations using conventional 3D seismic data. These seismic-based estimates will be compared with well log derived saturations from the subsequently drilled wells of the Gulf of Mexico Gas Hydrate Joint Industry Project Leg II (JIP Leg II) expedition.Predicting saturation of gas hydrates (Sh-seismic) combines pre-stack seismic inversion, rock physics modeling and stratigraphic interpretation. Before the wells were drilled, no nearby sonic and density logs were available to define and calibrate the elastic property trends for the shallow target interval containing the gas hydrate stability zone. Therefore, rock property trends were established by applying principles of rock physics and shallow sediment compaction, constrained by known regional geological parameters. Sh-seismic volumes were generated by inverting pre-stack data to acoustic impedance (PI) and shear impedance (SI) volumes, and then analyzing deviations from modeled impedance trends. To enhance the quality of the inversion, the signal-to-noise ratio of the offset data was maximized by conditioning the seismic prior to inversion. Seismic stratigraphic interpretation plays an important role by identifying the more promising strata and structures for the presence of gas hydrates.The pre-drill Sh-seismic results are compared with saturations calculated from log data, Sh-log, of the wells drilled in the JIP Leg II campaign. Due to weaker seismic reflections, predictions may be less accurate for low concentrations, such as saturations less than 40%, and for thin intervals below the vertical resolution of the seismic data (about 15 m). However, the integrated geophysical workflow is very effective for identifying and quantifying significant hydrate concentrations, making the method a promising prospecting technique. 相似文献
3.
Einaudi Florence Pezard Philippe A. Cochemé Jean-Jacques Coulon Christian Laverne Christine Godard Marguerite 《Marine Geophysical Researches》2000,21(3-4):387-408
As opposed to ocean crustal drilling that often yields a discontinuous core, ophiolites provide a unique opportunity to study continuous sections of oceanic basalts. In order to provide high frequency constraints on the construction of the upper oceanic crust, a continuous 280 m thick volcanic transect was sampled in the Semail ophiolite in Oman. The analyzed section is located in the Sarami Massif, in the central part of the ophiolite, and exposed along Wadi Shaffan. A multidisciplinary study was carried out after sampling in the field. Core measurements including porosity, grain density, compressional velocity, magnetic susceptibility and electrical resistivity for over 100 samples from this transect have been made. Geochemical analyses including major, trace and Rare Earth Elements were also performed on 23 selected samples from this transect. The Wadi Shaffan transect appears as composed of two main petrological and geochemical members providing the main lithostratigraphic signal. The boundary between the two sequences is marked by the presence of a massive flow unit equating to the most primitive lava and across which significant changes in mineralogy and texture are observed. The physical properties equally record significant changes. In all, the section is characterized by chemical compositions coherent with that of V1-Geotime volcanism and appears as built through two main sequences of volcanic activity. The magnetic susceptibility profile correlated to geochemical variations present the most detailed evolution allowing to individualize a succession of at least 4 volcanic phases. These phases are interpreted as magmatic cycles characterized by differentiation processes, allowing one to place high frequency constraints on the volcanic behavior of fast spreading ridges. Some of the physical properties also reflect this series of differentiation trends, as noticed in the past from downhole measurements recorded in the context of deep ocean drilling into the crust. 相似文献
4.
The Ocean Drilling Program (ODP) initiated drilling at Site 1256D in the Guatemala Basin, about 1,000 km off the East Pacific
Rise to penetrate plutonic rocks, anticipated to be relatively shallow in this region, formed at an ultra-fast spreading rate.
IODP Expedition E312 successfully drilled into gabbros at ~1,150 m in basement. Multi-channel seismic traces show weak laterally
coherent sub-basement reflections at borehole depths. Synthetic reflectivity seismograms were computed using a Ricker wavelet
and impedance profiles from borehole sonic logs. These seismograms show significant sub-basement amplitude peaks. A zero-offset
vertical seismic profile, shot on E312, was processed to investigate the authenticity of these reflections and their relationship
to borehole geology. A dual scheme of the median filtering and F–K dip filtering was used. Tests with synthetic seismograms
indicate the approach is effective at reasonable SNR levels. Downgoing energy is clearly identified but negligible upgoing
energy is visible over random noise. These results indicate that lava flows and igneous contacts in upper ocean crust have
significant topography on lateral scales less than the Fresnel Zone (~300 m) due to igneous and tectonic processes. 相似文献
5.
Philippe A. Pezard Roger N. Anderson William B. F. Ryan Keir Becker Jeffrey C. Alt Pascal Gente 《Marine Geophysical Researches》1992,14(2):93-123
Downhole measurements recorded in the context of the Ocean Drilling Program in Hole 504B, the deepest hole drilled yet into the oceanic crust, are analyzed in terms of accretion processes of the upper oceanic crust at intermediate spreading-rate. The upper part of the crust is found to support the non steady-state models of crustal accretion developed from seafloor observations (Kappel and Ryan, 1986; Gente, 1987). The continuous and vertical nature of borehole measurements provides stratigraphic and structural data that cannot be obtained solely from seafloor studies and, in turn, these models define a framework to analyze the structural, hydrological, and mineralogical observations made in the hole over the past decade.Due to the observed zonation with depth of alteration processes, and its relation to lava morphologies, the 650-m-thick effusive section penetrated in Hole 504B is postulated to be emplaced as the result of two main volcanic sequences. Massive lava flows are interpreted as corresponding to the onset of these sequences emplaced on the floor of the axial graben. The underlying lava made of structures with large porosity values and numerous cm-scale fractures is thus necessarily accreted at the end of the previous volcanic episode. On top of such high heterogeneous and porous intervals, the thick lava flows constitute crustal permeability barriers, thereby constraining the circulation of hydrothermal fluids.Accreted in the near vicinity of the magma chamber, the lower section is that exposed to the most intense hydrothermal circulation (such as black smokers activity). Once capped by a massive flow at the onset of the second volcanic phase, the lower interval is hydrologically separated from ocean-waters. A reducing environment develops then below it resulting, for example, in the precipitation of sulfides. Today, whereas the interval corresponding to the first volcanic episode is sealed by alteration minerals, the second-one is still open to fluid circulation in its upper section. Thus, upper part of the volcanic edifice is potentially never exposed to fluids reaching deep into the crust, while the lower one is near the ridge axis.Considering that most of the extrusives are emplaced within a narrow volcanic zone, the first unit extruded for a given vertical cross-section is necessarily emplaced at the ridge-axis. In Hole 504B, the 250-m-thickTransition Zone from dikes to extrusives is interpreted as the relict massive unit flooding the axial graben at the onset of the first volcanic sequence, and later ruptured by numerous dikes. Further from the axis, the same massive unit constitutes a potential permeability cap for vertical crustal sections accreted earlier. Also, the upper 50 meters of the basement might be considered as the far-end expression of massive outpours extruded near the ridge-axis. 相似文献
6.
The magnetostratigraphy of sediments drilled at two sites (998 and 1001) in the Caribbean Sea during the Ocean Drilling Program (ODP) Leg 165 is established directly from downhole measurements. For the first time in the ODP, the magnetostratigraphy of sediments is determined from both logging magnetic data and paleomagnetic analysis of core material for an age interval of about 16 m.y. across the Cretaceous/Tertiary boundary. The total magnetic induction and the susceptibility of the surrounding sediment were recorded in situ and continuously by the GHMT (Geological High-sensitivity Magnetic Tool). The aim of processing these data is to determine the magnetic polarity. At Site 998 (Cayman Rise), no paleomagnetic results are available from the recovered cores given a hard secondary overprint. Nonetheless, a magnetostratigraphic sequence from early Miocene to late Oligocene is proposed from the analysis of the GHMT data. The comparison with biostratigraphic results shows the accuracy of the resulting magnetic polarity. At Site 1001 (Hess escarpment), cores were recovered in two holes thus allowing the comparison of the magnetostratigraphic results obtained from the GHMT data and from paleomagnetic analysis of core samples over a length of 200 m representing about 16 m.y. from early Eocene to late Cretaceous times. The sedimentation rates computed from the determined magnetochrons are very similar and correspond to the ones obtained from shipboard biostratigraphic results. One of the most striking result obtained from the magnetostratigraphic results, especially the GHMT data, at Site 1001, is the abrupt decrease in the sedimentation rate across the K/T boundary. This suppressed sedimentation lasted at least 4 Ma after the K/T event. 相似文献
7.
《Marine and Petroleum Geology》2012,35(1):62-71
High-quality logging-while-drilling (LWD) downhole logs were acquired in seven wells drilled during the Gulf of Mexico Gas Hydrate Joint Industry Project Leg II in the spring of 2009. Well logs obtained in one of the wells, the Green Canyon Block 955 H well (GC955-H), indicate that a 27.4-m thick zone at the depth of 428 m below sea floor (mbsf; 1404 feet below sea floor (fbsf)) contains gas hydrate within sand with average gas hydrate saturations estimated at 60% from the compressional-wave (P-wave) velocity and 65% (locally more than 80%) from resistivity logs if the gas hydrate is assumed to be uniformly distributed in this mostly sand-rich section. Similar analysis, however, of log data from a shallow clay-rich interval between 183 and 366 mbsf (600 and 1200 fbsf) yielded average gas hydrate saturations of about 20% from the resistivity log (locally 50−60%) and negligible amounts of gas hydrate from the P-wave velocity logs. Differences in saturations estimated between resistivity and P-wave velocities within the upper clay-rich interval are caused by the nature of the gas hydrate occurrences. In the case of the shallow clay-rich interval, gas hydrate fills vertical (or high angle) fractures in rather than filling pore space in sands. In this study, isotropic and anisotropic resistivity and velocity models are used to analyze the occurrence of gas hydrate within both the clay-rich and sand dominated gas-hydrate-bearing reservoirs in the GC955-H well. 相似文献
8.
综合大洋钻探计划(IODP) 334和344航次在U1381站位处的两个钻孔(A孔和C孔)获得了中美洲西海岸外科科斯脊基底拉斑玄武岩，对其岩浆过程开展研究可为理解其岩石成因提供重要依据。本文对科科斯脊玄武岩中斜长石斑晶和微晶进行了详细的原位主微量元素分析，结果表明，斜长石种属为培长石、拉长石及少量中长石。部分斜长石斑晶具有正环带结构；但多数斜长石斑晶不具有明显环带，仅从核部到边部存在微弱的成分变化。斜长石斑晶与微晶的微量元素差别较大:斜长石斑晶富集轻稀土和大离子亲石元素、亏损高场强元素，且具有明显的Eu正异常；斜长石微晶不相容元素含量通常高于斜长石斑晶。根据斜长石温度计计算获得斜长石斑晶结晶温度为1 050～1 253℃，斜长石微晶结晶温度为866～1 033℃。基于以上特征，推测斜长石斑晶核部是相对原始岩浆的产物，而斑晶边部以及微晶是演化岩浆的结晶产物。斜长石斑晶的成分变化及熔蚀麻点结构是由于岩浆补给及岩浆减压上升造成的。最后，本研究推测科科斯脊基底玄武岩来自于开放的岩浆房，且岩浆房内可能存在原始岩浆的不断注入及岩浆对流。 相似文献
9.
A sonic well log was obtained within the basement complex of the Walvis Ridge during Deep Sea Drilling Project Leg 74. The top of the basement complex is characterized by smooth acoustic reflectors. The rocks recovered within the basement complex consist of basalts with intercalated sediments. According to the log ～-50% of the upper 75 m of basement are igneous rocks and the other 50% sedimentary. Sonobuoy results indicate that the ratio of sediments to basalt increases with depth for an additional 225 m until a typical oceanic velocity structure is observed. Paleontological results suggest that the processes forming this upper 300 m of the basement complex was accomplished within a short time interval. 相似文献
10.
A sonic well log was obtained within the basement complex of the Walvis Ridge during Deep Sea Drilling Project Leg 74. The
top of the basement complex is characterized by smooth acoustic reflectors. The rocks recovered within the basement complex
consist of basalts with intercalated sediments. According to the log ∼-50% of the upper 75 m of basement are igneous rocks
and the other 50% sedimentary. Sonobuoy results indicate that the ratio of sediments to basalt increases with depth for an
additional 225 m until a typical oceanic velocity structure is observed. Paleontological results suggest that the processes
forming this upper 300 m of the basement complex was accomplished within a short time interval. 相似文献
11.
Mampi Karmakar Saumen Maiti Amrita Singh Maheswar Ojha Bhabani Sankar Maity 《Marine Geophysical Researches》2018,39(3):407-419
Modeling and classification of the subsurface lithology is very important to understand the evolution of the earth system. However, precise classification and mapping of lithology using a single framework are difficult due to the complexity and the nonlinearity of the problem driven by limited core sample information. Here, we implement a joint approach by combining the unsupervised and the supervised methods in a single framework for better classification and mapping of rock types. In the unsupervised method, we use the principal component analysis (PCA), K-means cluster analysis (K-means), dendrogram analysis, Fuzzy C-means (FCM) cluster analysis and self-organizing map (SOM). In the supervised method, we use the Bayesian neural networks (BNN) optimized by the Hybrid Monte Carlo (HMC) (BNN-HMC) and the scaled conjugate gradient (SCG) (BNN-SCG) techniques. We use P-wave velocity, density, neutron porosity, resistivity and gamma ray logs of the well U1343E of the Integrated Ocean Drilling Program (IODP) Expedition 323 in the Bering Sea slope region. While the SOM algorithm allows us to visualize the clustering results in spatial domain, the combined classification schemes (supervised and unsupervised) uncover the different patterns of lithology such of as clayey-silt, diatom-silt and silty-clay from an un-cored section of the drilled hole. In addition, the BNN approach is capable of estimating uncertainty in the predictive modeling of three types of rocks over the entire lithology section at site U1343. Alternate succession of clayey-silt, diatom-silt and silty-clay may be representative of crustal inhomogeneity in general and thus could be a basis for detail study related to the productivity of methane gas in the oceans worldwide. Moreover, at the 530 m depth down below seafloor (DSF), the transition from Pliocene to Pleistocene could be linked to lithological alternation between the clayey-silt and the diatom-silt. The present results could provide the basis for the detailed study to get deeper insight into the Bering Sea’ sediment deposition and sequence. 相似文献
12.
Estimating the amount of gas-hydrate and free-gas is difficult in deep seas even with scientific coring and downhole measurements. Well data may be incompatible between holes of a site as well as with depth in the same hole. In this paper, we demonstrate an approach to estimate saturation of gas-hydrate from seismic velocities at any site where data set is limited. The study is carried out in the outer Blake Ridge, which is one of the most intensively studied regions of natural gas-hydrate occurrences and a very distinctive example of studying geophysical signatures of gas-hydrate and free-gas in deep marine sediments. Although, downhole measurements from both vertical seismic profiles (VSPs) and sonic logs provide the most accurate and direct measurements of velocity, only VSP velocities at Ocean Drilling Program (ODP) Sites 994, 995, and 997 on the Blake Ridge are used to estimate the saturation of gas-hydrate and free-gas as sonic logs at ODP sites are not reliable. Here we derive a general trend of the background velocity with depth using the porosity and mineralogy from coring at discrete depth intervals. Saturations of gas-hydrate and free-gas are then estimated from this background velocity using the effective medium modeling. The porosity and mineralogical compositions are taken from four different depths at Site 995, as data quality is the best in this hole. Average saturations of gas-hydrate and free-gas at three holes are estimated as 10–14 and 2–3%, respectively. 相似文献
13.
The geotechnical consortium 《Marine Georesources & Geotechnology》2013,31(4):297-339
During Leg 75 of the Deep Sea Drilling Project (DSDP) from the D/V Glomar Challenger, a 200‐m deep hole was drilled at Hole 532A on the eastern side of Walvis Ridge at a water depth of 1331 m. Sediment cores were obtained by means of a hydraulic piston corer. All of the cores from this boring were designated for geotechnical studies and were distributed among eight institutions. The results of laboratory studies on these sediment cores were compiled and analyzed. Sediment properties, including physical characteristics, strength, consolidation, and permeability were studied to evaluate changes as a function of depth of burial. It was concluded that the sediment profile to the explored depth of 200 m at Walvis Ridge consists of approximately 50 m of foram‐nannofossil marl (Subunit la) over 64 m of diatom‐nannofossil marl (Subunit 1b) over nannofossil marl (Subunit lc) to the depth explored. All three sediment units appear to be normally consolidated, although some anomalies seem to exist to a depth of 120 m. No distinct differences were found among the sediment properties of the three subunits (la, 1b, and lc) identified at this site. 相似文献
14.
Ling Chen Limei Tang Jichao Yang Xiaohu Li Wei Wang Fengyou Chu Jie Zhang 《海洋学报(英文版)》2021,40(11):147-161
We present major and trace element data of lava recovered from the northern Yap Trench in the western Pacific and discuss their petrogenesis and tectonic implications within the framework of interactions between the Caroline Ridge and Yap Trench. Rocks were collected from both landward and seaward trench slopes and exhibited geochemical characteristics similar to backarc basin basalt (BABB) and mid-ocean ridge basalt (MORB), including high Fe content, tholeiitic affinity, high TiO2 value at a given FeOT/MgO ratio, Ti/V ratio between 20 and 50, low Ba/Nb ratio and Th/Nb ratio, and trace element patterns commonly displayed by BABB and MORB, which are distinct from arc lava. These rocks seem to have been generated during mantle upwelling and decompression melting at a spreading center. However, compared with typical forearc lava produced by seafloor spreading in the Mariana forearc region, such as the early Eocene forearc basalts and late Neogene forearc lava in the southernmost Mariana Trench, the Yap Trench lava is derived from a more fertile mantle and feature a more minor subduction component; thus, they cannot be the products of forearc mantle decompression melting. We suggest that the landward slope lava represents backarc basin crust that was overthrust onto the forearc lithosphere during the collision of the Caroline Ridge with the Yap Trench (20–25 Ma), which played a key role in the evolution of the Yap subduction system. Moreover, the seaward slope lava represents the subduction plate crust that accreted onto the deep trench during the collision. This collision event resulted in the cessation of Yap Arc magmatism; thus, the Yap Trench volcanic rocks (<25 Ma) previously suggested to be arc magma products may actually represent the nascent island arc lava with a lower subduction component than in the mature Mariana Arc lava. 相似文献
15.
Richard V. Tyson 《Marine and Petroleum Geology》1984,1(1):3-13
During the extension of Deep Sea Drilling Project (DSDP) Leg 76 a new and previously unpenetrated lithological unit composed mainly of claystones was cored above basalt basement at Site 534 in the Blake-Bahama Basin. The Callovian part of the new unit contains interbedded ‘black shales’ which were hitherto unexpected in this part of the section. This Paper presents a brief palynological examination of lithofacies-kerogen relationships in these sediments and shows that their organic content is almost entirely a function of the re-deposition of terrestial and marine organic matter versus the ambient redox conditions of the depositional environment. Allochthonous organic matter inputs are highest in the interbedded turbidites and decline progressively toward the pelagic black shales in which marine organic matter is comparatively well preserved. The significance of various kerogen and palynomorph indices are discussed. The study emphasizes the absolute necessity for sedimentologically-aware sampling in all palynological and geochemical work on lithologically heterogeneous sequences. 相似文献
16.
In 2006, the United States Geological Survey (USGS) completed a detailed analysis and interpretation of available 2-D and 3-D seismic data, along with seismic modeling and correlation with specially processed downhole well log data for identifying potential gas hydrate accumulations on the North Slope of Alaska. A methodology was developed for identifying sub-permafrost gas hydrate prospects within the gas hydrate stability zone in the Milne Point area. The study revealed a total of 14 gas hydrate prospects in this area.In order to validate the gas hydrate prospecting protocol of the USGS and to acquire critical reservoir data needed to develop a longer-term production testing program, a stratigraphic test well was drilled at the Mount Elbert prospect in the Milne Point area in early 2007. The drilling confirmed the presence of two prominent gas-hydrate-bearing units in the Mount Elbert prospect, and high quality well logs and core data were acquired. The post-drill results indicate pre-drill predictions of the reservoir thickness and the gas-hydrate saturations based on seismic and existing well data were 90% accurate for the upper unit (hydrate unit D) and 70% accurate for the lower unit (hydrate unit C), confirming the validity of the USGS approach to gas hydrate prospecting. The Mount Elbert prospect is the first gas hydrate accumulation on the North Slope of Alaska identified primarily on the basis of seismic attribute analysis and specially processed downhole log data. Post-drill well log data enabled a better constraint of the elastic model and the development of an improved approach to the gas hydrate prospecting using seismic attributes. 相似文献
17.
A promising method for gas hydrates exploration incorporates pre-stack seismic inversion data, elastic properties modeling, and seismic interpretation to predict saturation of gas hydrates (Sgh). The technology can be modified slightly and used for predicting hydrate concentrations in shallow arctic locations as well. Examples from Gulf of Mexico Walker Ridge (WR) and Green Canyon (GC) protraction areas illustrate how Sgh was derived and used to support the selection of well locations to be drilled for gas hydrates in sand reservoirs by the Chevron-led Joint Industry Project (JIP) Leg II cruise in 2009. Concentrations of hydrates were estimated through the integration of seismic inversion of carefully conditioned pre-stack data, seismic stratigraphic interpretation, and shallow rock property modeling. Rock property trends were established by applying principles of rock physics and shallow sediment compaction, constrained by regional geological knowledge. No nearby sonic or density logs were available to define the elastic property trends in the zone of interest. Sgh volumes were generated by inverting pre-stack data to acoustic and shear impedance (PI and SI) volumes, and then analyzing deviations from modeled impedance trends. In order to enhance the quality of the inversion, we stress the importance of maximizing the signal to noise ratio of the offset data by conditioning seismic angle gathers prior to inversion. Seismic interpretation further plays an important role by identifying false anomalies such as hard, compact strata, which can produce apparent high Sgh values, and by identifying the more promising strata and structures for containing the hydrates. This integrated workflow presents a highly promising methodology, appropriate for the exploration of gas hydrates. 相似文献
18.
在对CA海山玄武岩CAD21样品岩相学研究基础上,运用电子探针和X-荧光光谱法(XRF)对中太平洋CA海山斜长石斑晶中的环带、斜长石微晶和玄武岩中的硅酸盐进行了化学成分研究。CA海山玄武岩为地幔柱成因的板内玄武岩;斜长石斑晶具有环带结构,环带核部与边部为不连续消光,是不连续环带;环带核部为培长石,边部为拉长石,是岩浆演化过程中形成的正环带,其成因受岩浆演化过程中熔体组分及温、压条件的共同制约。斜长石斑晶核部、边部及斜长石微晶估算温度平均值分别为1 281,1 198和1 071 ℃,分别代表了岩浆源区、岩浆房及岩浆喷发温度,三者温度差值较小,这和洋岛玄武质岩浆的形成及喷发特点相吻合。 相似文献
19.
《Marine and Petroleum Geology》2012,35(1):85-95
Through the use of 3-D seismic amplitude mapping, several gas hydrate prospects were identified in the Alaminos Canyon (AC) area of the Gulf of Mexico. Two locations were drilled as part of the Gulf of Mexico Gas Hydrate Joint Industry Project Leg II (JIP Leg II) in May of 2009 and a comprehensive set of logging-while-drilling (LWD) logs were acquired at each well site. LWD logs indicated that resistivity in the range of ∼2 ohm-m and P-wave velocity in the range of ∼1.9 km/s were measured in the target sand interval between 515 and 645 feet below sea floor. These values were slightly elevated relative to those measured in the sediment above and below the target sand. However, the initial well log analysis was inconclusive regarding the presence of gas hydrate in the logged sand interval, mainly because large washouts caused by drilling in the target interval degraded confidence in the well log measurements. To assess gas hydrate saturations in the sedimentary section drilled in the Alaminos Canyon 21 B (AC21-B) well, a method of compensating for the effect of washouts on the resistivity and acoustic velocities was developed. The proposed method models the washed-out portion of the borehole as a vertical layer filled with sea water (drilling fluid) and the apparent anisotropic resistivity and velocities caused by a vertical layer are used to correct the measured log values. By incorporating the conventional marine seismic data into the well log analysis, the average gas hydrate saturation in the target sand section in the AC21-B well can be constrained to the range of 8–28%, with 20% being our best estimate. 相似文献
20.
The stability of gypsum in marine sediments using the entire ODP/IODP porewater composition database
The stability of gypsum in marine sediments has been investigated through the calculation of its saturation index at the sediment in situ temperature and pressure, using the entire ODP/IODP porewater composition database (14416 samples recovered from sediments collected during 95 ODP and IODP Legs). Saturation is reached in sediment porewaters of 26 boreholes drilled at 23 different sites, during 12 ODP/IODP Legs. As ocean bottom seawater is largely undersaturated with respect to gypsum, the porewater Ca content or its SO4 concentration, or both, must increase in order to reach equilibrium. At several sites equilibrium is reached either through the presence of evaporitic gypsum layers found in the sedimentary sequence, and/or through a salinity increase due to the presence of evaporitic brines with high concentrations of Ca and SO4. Saturation can also be reached in porewaters of seawater-like salinity (≈ 35‰), provided sulfate reduction is limited. In this case, saturation is due to the alteration of volcanogenic material which releases large amounts of Ca to the porewaters, where the Ca concentration can reach 55 times its seawater value as for example at ODP Leg 134 site 833. At a few sites, saturation is reached in hydrothermal environments, or as a consequence of the alteration of the basaltic basement. In addition to the well known influence of brines on the formation of gypsum, these results indicate that the alteration of sediments rich in volcanogenic material is a major process leading to gypsum saturation in marine sediment porewaters. Therefore, the presence of gypsum in ancient and recent marine sediments should not be systematically interpreted as due to hypersaline waters, especially if volcanogenic material is present. 相似文献