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1.
Dehydration temperatures of serpentine were measured in the pressure range between 1.0GPa and 5.0GPa by using the electrical conductivity metod simultaneously at high temperatures and high pressures.The results show that with increasing pressure th dehydration temperature of antigorite increases slightly below 2.0GPa ,but drops markedly above2.0GPa .This strongly suggests that high pressure would favor the dehydration of serpentine minerals and the water released thereby would be an important source of fluids involved in magmatism in a subduction zone and mantle metasomatism,Meanwhile,the greatly enhanced electric conductivity in the presence of water may be one of the reasons underlying the occurrence of a high-conductivity zone in the lower crust.  相似文献   

2.
The experimental study on the melting of potassic basalt and eclogite with about 2% waterat 800-1300℃ and 1.0-3.5 GPa shows that the solidi of both rocks are significantly lower thanthose obtained from the previous experiments of the same type of rocks under dry conditions,and the former which is enriched in potassium has a lower melting point than the latter. It is con-sistent with the previous study. The melting temperature of eclogite increases with pressure,whereas potassic basalt has similar properties only at 1.5—2.5 GPa and>3.0 GPa, and at 2.5—3.0 GPa the melting temperature decreases with pressure. This can be explained as follows: (1)eclogite only has one hydrous mineral amphibole and the dehydous temperature is lower than thewet solidus of the rock. (2) Amphibole exists in potassic basalt at the pressures lower than 2.5GPa and phlogopite exists at pressures higher than 2.5 GPa, and the special compositions of bothminerals determine that amphibole has a dehydration temperature higher than or close to that ofthe wet solidus of the rocks, while phlogopite has a dehydration temperature lower than that ofthe wet solidus. On the other hand the features of the continuous solidus in the experiment ofhydrous eclogite were produced by the fact that the dehydration temperature of its amphibolelower than or close to the melting temperature of the hydrous conditions. So the melting tempera-ture lowers at higher pressures. Therefore, the composition of the rocks in the lithosphere and thetypes of hydrous minerals and their stable P-T conditions are the important factors controllingthe solidi of rocks. It can quite well explain the partial melting of rocks and the origin of the lowvelocity zone in the deep lithosphere.  相似文献   

3.
http://www.sciencedirect.com/science/article/pii/S1674987114000309   总被引：8，自引：2，他引：6  
In the early 1980s, evidence that crustal rocks had reached temperatures 〉1000 ℃ at normal lower crustal pressures while others had followed low thermal gradients to record pressures characteristic of mantle conditions began to appear in the literature, and the importance of melting in the tectonic evolution of orogens and metamorphic-metasomatic reworking of the lithospheric mantle was realized. In parallel, new developments in instrumentation, the expansion of in situ analysis of geological ma- terials and increases in computing power opened up new fields of investigation. The robust quantifi- cation of pressure （P）, temperature （T） and time （t） that followed these advances has provided reliable data to benchmark geodynamic models and to investigate secular change in the thermal state of the lithosphere as registered by metamorphism through time. As a result, the last 30 years have seen sig- nificant progress in our understanding of lithospheric evolution, particularly as it relates to Precambrian geodynamics.  相似文献   

4.
In order to recognize the impact of aqueous medium on gas yields and the kinetic behaviors of hydrogen isotope fractionation during organic matter thermal degradation, the gold tube apparatus was used to conduct thermal simulation experiments by mixing the nC18 with the water of different properties and proportions. The yields of natural gas components, the relation among hydrogen isotope composition of each component and the experimental temperatures vs. heating rates have been obtained, and the results indicate that under the higher temperature conditions, the hydrous experiment has obvious impact on gas yields, such as when more water is added, higher amounts of hydrocarbon gas and H2 are yielded, and the existence of water obviously prolongs the temperature interval with the existence of heavy hydrocarbon gas. It also shows that the hydrogen isotope of hydrocarbon gas generated by the hydrous experiment is obviously lighter than that generated by the anhydrous experiment, and with the increasing amount of added water, the δD value of hydrocarbon gas gradually decreases. Compared with gas yields, the variation of δD value is more sensitive to aqueous medium in the thermal simulation experiment. However, compared with the amount of the added water, the aqueous medium property has smaller impact on the gas yields, which still shows the inherit effect on hydrogen isotope composition of aqueous medium. Through the model simulation and the isotope fractionation behavior analysis, it is validated that the hydrogen isotope fractionation process can be well described by the chemical kinetic model. The difference of reaction fraction of normal methane and D-containing methane is large, corresponding to the same activation energy. The content of normal methane is obviously higher in the part with lower activation energy, while the content of D-containing methane is higher in the part with higher activation energy. Therefore, it will result in larger hydrogen isotope fractionation amplitude, and the δD values will be more sensitive to the variation of maturity. Meanwhile, the average activation energy of methane generation from nC18 in the hydrous experiment is higher than that in the anhydrous experiment, and the greater amount of added water, the larger the average activation energy of methane generation reaction. This has laid foundation for its exploratory application in the study of gas reservoir forming history and the gas-source correlation, which indicates the research and application prospects in this orientation.  相似文献   

5.
Carbonate melts are important active metasomatic agents and efficient transport agents; their thermodynamic properties at high temperatures and pressures are therefore of considerable interest for various geochemica applications. However, due to the extreme challenges in relevant experiments, current knowledge of even the density of carbonate melts is limited. In this study, we provide high quality volumetric data of Ca CO3-melt from firs principles at high temperatures and pressures(up to3,500 K and 60 GPa). The accuracy of these data is demonstrated through comprehensive comparison with available experimental data and a thorough discussion of the predictability of the re-scaling method proposed in this study. Based on the simulations, an equation of state has been established that is critical to relevant highly disputed questions such as the decomposition and solidification boundaries of Ca CO3 melts, the latter of which is briefly discussed in this study with a newly derived ab initio melting curve to high pressures.  相似文献   

6.
Glauconite is widely distributed in space and time.In China glauconite-bearing strata are extensive occurrence ranging from Late Cretaceous to Middle Proterozoic in age.X-ray powder analysis,X-ray diffracition analysis and differential thermal analysis revealed that glauconite has a mica-type structure between dioctahedron and trioctahedron.Its chemical composition is:Al2O310.6%,SiO249.23%,MgO3.24%,Fe2O317.40%,FeO1.8%,and K2O7.92%,Its crystal form and thermal properties are very similar to those of mica-like clay minerls.According to isotopic age determinations of glauconite in modern oceans (including the East China Sea,the South China Sea and the Yellow Sea),we consider that in the extreme case glauconite is an authigenic mineral.It is generally formed in sedimentary rocks.Is has further proved that glauconite can be used to determine the ages of sedimentary rocks.  相似文献   

7.
Unusual carbonaceous matter, termed here chiemite, composed of more than 90% C from the Alpine Foreland at Lake Chiemsee in Bavaria, southeastern Germany has been investigated using optical and atomic force microscopy, X-ray fluorescence spectroscopy, scanning and transmission electron microscopy, high-resolution Raman spectroscopy, X-ray diffraction and differential thermal analysis, as well as by δ13C and 14C radiocarbon isotopic data analysis. In the pumice-like fragments, poorly ordered carbon matter co-exists with high-ordering monocrystalline α-carbyne, and contains submicrometer-sized inclusions of complex composition. Diamond and carbyne add to the peculiar mix of matter. The required very high temperatures and pressures for carbyne formation point to a shock event probably from the recently proposed Holocene Chiemgau meteorite impact. The carbon material is suggested to have largely formed from heavily shocked coal, vegetation like wood, and peat from the impact target area. The carbonization/coalification high PT process may be attributed to a strong shock that instantaneously caused the complete evaporation and loss of volatile matter and water, which nevertheless preserved the original cellular structure seen fossilized in many fragments. Relatively fresh wood encapsulated in the purported strongly shocked matter point to quenched carbon melt components possibly important for the discussion of survival of organic matter in meteorite impacts, implying an astrobiological relationship.  相似文献   

8.
It has long been a controversy about the source of ore-forming materials of Au-Ag polymetallic deposits both in metallogenic theory and in ore-searching practice. In terms of a large wealth of the isotopic statistics data from Indosinian-Yanshanian endogenic ore deposits in northern Hebei (generally referring to the areas along the northern part of Taihang Mountains and northern Hebei, the same below) , it is considered that the ore-forming materials came from the deep interior of the Earth, which had migrated through plumes to the Earth surface while ex-perienced multi-stage evolution and then emplaced progressively in favorable structural loci to form ores. Their isotope data show that 559 sulfur isotopic data from 40 ore deposits are, for the most part, within the range of -5‰ -5‰, with a high degree of homogenization, indicating that the sulfur is derived mainly from magma; 200 lead isotope data from 37 ore deposits indi-cate that the ore-forming materials are principally of mantle source though some crust-source ma-terial was involved; 96 oxygen, hydrogen and carbon isotope data from 34 ore deposits illustrate that the ore-forming fluids are dominated by magmatic water while other sources of water would be involved. It may therefore be seen that the formation of endogenic deposits has nothing to do with the strata .  相似文献   

9.
Based on the daily precipitation data of 16 national meteorological observation stations on the north⁃ ern slope of Tianshan Mountains from 2000 to 2020（September to April the following year）,28 blizzard weath⁃ er processes were screened out. Then NCEP/NCAR reanalysis data and HYSPLIT model were used to simulate backward tracking of the water vapor during the snowstorm,analysis of the circulation background of the snow⁃ storm process on the northern slope of the Tianshan Mountains,as well as the main sources and transport of wa⁃ ter vapor and its contribution to the snowstorm. The research showed that the snowstorm area in the northern slope of the Tianshan Mountains was located on the right side of the axis of the southwest jet at 300 hPa high,the southwest airflow in front of the West Siberia trough at 500 hPa,the front convergence of the exit area of the southwest jet at low level at 700 hPa,and the convergence area of water vapor flux divergence and the overlap near the ground cold front area. The water vapor affecting the blizzard on the northern slope of the Tianshan Mountains mainly came from the Mediterranean Sea,the Black Sea and its vicinity,Southwest Asia,Central Asia,the Atlantic Ocean and its coasts,as well as the 850 hPa water vapor in Europe and northern Xinjiang. The water vapor from North America and other places had a relatively small contribution to the blizzard;after each water vapor source reaches the key area with the westerly airflow,under suitable circulation conditions. It mainly entered the blizzard area along the westward（southwest）and the northwest paths. But there were some differences between the layers. Based on the above characteristics,the structure of the source and transport of wa⁃ ter vapor in the snowstorm process on the northern slope of the Tianshan Mountains was established and the char⁃ acteristics of vapor transport at various heights were revealed. © 2023 The Author(s).  相似文献   

10.
In many Precambrian provinces the understanding of the tectonic history is constrained by limited exposure and aeromagnetic data provide information below the surface cover of sediments,water,etc.and help build a tectonic model of the region.The advantage of using the aeromagnetic data is that the data set has uniform coverage and is independent of the accessibility of the region.In the present study,available reconnaissance scale aeromagnetic data over Peninsular India are analyzed to understand the magnetic signatures of the Precambrian shield and suture zones thereby throwing light on the tectonics of the region.Utilizing a combination of differential reduction to pole map,analytic signal,vertical and tilt derivative and upward continuation maps we are able to identify magnetic source distribution,tectonic elements,terrane boundaries,suture zones and metamorphic history of the region.The magnetic sources in the region are mainly related to charnockites,iron ore and alkaline intrusives.Our analysis suggests that the Chitradurga boundary shear and Sileru shear are terrane boundaries while we interpret the signatures of Palghat Cauvery and Achankovil shears to represent suture zones.Processes like metamorphism leave their signatures on the magnetic data:prograde granulites(charnockites)and retrograde eclogites are known to have high susceptibility.We fnd that charnockites intruded by alkali plutons have higher magnetization compared to the retrogressed charnockites.We interpret that the Dharwar craton to the north of isograd representing greenschist to amphibolite facies transition,has been subjected to metamorphism under low geothermal conditions.Some recent studies suggest a plate tectonic model of subductionecollisioneaccretion tectonics around the Palghat Cauvery shear zone(PCSZ).Our analysis is able to identify several west to east trending high amplitude magnetic anomalies with deep sources in the region from Palghat Cauvery shear to Achankovil shear.The magnetic high associated with PCSZ may represent the extruded high pressureeultra high temperature metamorphic belt(granulites at shallow levels and retrogressed eclogites at deeper levels)formed as a result of subduction process.The EW highs within the Madurai block can be related to the metamorphosed clastic sediments,BIF and mafc/ultramafc bodies resulting from the process of accretion.  相似文献   

11.
高温高压下水和氯化钠溶液的物理化学性质研究徐有生（中国科学院地球化学研究所，贵阳５５０００２）关键词高温高压水和ＮａＣｌ溶液物理化学性质水和ＮａＣｌ溶液是地质上最常见的溶液，了解其物理化学性质有助于研究水溶液在地球内部各种地质作用和地质过程中所起的作...  相似文献   

12.
介绍近年来使用静态超高压大腔体实验技术 ,在模拟地球内部的高温高压条件下 ,对地球物质进行的若干物理和化学性质的实验研究。高压同时高温条件下多种岩石样品的弹性波速就位测量揭示出物质的声软化现象和振幅效应 ;高温高压下陨石和岩石的熔融结晶实验发现了陨石硅酸盐相的不混溶现象以及玄武岩熔体结构的变化 ,在玄武岩转变为榴辉岩的实验中观测到了刚玉相 ;在高温高压水的实验中 ,发现了冰 Ⅶ 的亚稳相和熔融前效应以及超临界水及其稀溶液的一些新性质。这些实验结果为探索地球深部物质的性质和状态以及迁移和演化提供了新的依据。  相似文献   

13.
Antigorite is one kind of hydrous serpentine that is present in meteorites and in the Earth mantle. In order to understand its dynamic behaviors, metastability and decomposition, shock experiments on antigorite have been conducted using a two-stage gas gun, and wave profiles of particle velocities have been measured to obtain the Hugoniot up to ~130 GPa and sound velocity at high pressures. The results show three regions of low-pressure phase below ~43 GPa and its metastable extension above a pressure of ~43 GPa for short durations of shock and high-pressure phase(s) above a pressure of ~43 GPa for long durations of shock. The dynamic behaviors of antigorite depend on not only the pressure but also the compression duration. Metastable extension state indicates that antigorite may survive beyond the stability depending on the shock conditions. Shock temperatures for antigorite are calculated along the Hugoniot. The pressure–density, sound velocity–pressure and shock temperature–pressure plots demonstrate that the decomposition reaction of antigorite into high-pressure phase(s) is accompanied by a volume expansion, sound velocity increase and temperature decrease, relative to the metastable extension phase above ~43 GPa. The decomposition should be sluggish and needs enough reaction time to complete and to overcome the activation energy. As a result of the high metastability of antigorite and possible decomposition assemblages, the hydrous serpentine (antigorite) may play a crucial role for the origin of water during the Earth accretion.  相似文献   

14.
We have investigated the evolution of the distortion of several oxide perovskites with increasing pressure, using EXAFS in the diamond anvil cell. Cubic perovskite BaZrO3 remains cubic up to 52 GPa. Orthorhombic perovskite CaGeO3 becomes less distorted as pressure increases, becomes tetragonal at about 12 GPa and evolves toward cubic structure, still not obtained at 23 GPa. The distortion of orthorhombic perovskite SrZrO3 first increases with pressure up to 8 GPa, then decreases until the perovskite becomes cubic at 25 GPa. The results are interpreted in terms of a systematics, relating the distortion to the ratio f of the volumes of the AO12 dodecahedron and the BO6 octahedron, and to the compressibilities of the polyhedra. For cubic perovskites, f=5, which may correspond to a situation where the compressibilities of octahedra and dodecahedra are equal.The behavior of SrZrO3 offers a clue to predict the evolution of the distortion of MgSiO3 at lower mantle pressures. It is suggested that the increase in distortion experimentally observed at lower pressures should stop above about 10 GPa, and the distortion decrease until the perovskite undergoes ferroelastic transitions to tetragonal and cubic phases, at pressures possibly below the pressure at the core-mantle boundary.  相似文献   

15.
俯冲带变质脱水作用对俯冲带的流体形成、岩浆起源和演化起着重要的控制作用。泥质岩是俯冲板块表层沉积物的典型代表,本文以天然泥质岩为对象,成功运用高压差热分析(HP-DTA)方法对其在1．5-4．0GPa下的脱水温度进行了实验研究。结果表明,泥质岩的脱水温度与压力呈很好的负相关关系。通过与冷、热俯冲带地热梯度线比较,确定了泥质岩在俯冲带深部发生变质脱水作用的深度范围(75-145 km),为岛弧岩浆源区位置的解释提供了实验证据。  相似文献   

16.
在1．0～5．0GPa压力范围内，运用高温同时高压下电导测量方法确定了蛇纹石的脱水温度。实验结果表明，压力小于2.0GPa时叶蛇纹石的脱水温度随压力的增大呈微弱升高趋势，压力大于2．0GPa时其脱水温度随压力的增大明显降低，意味着较高压力下有利于脱水反应的发生，是俯冲带岩浆作用及地幔交代作用流体的重要来源。蛇纹石脱水后，由于自由水的存在导致其电导明显增加，可能是高导层产生的原因之一。  相似文献   

17.
The solubility of water in melts in the NaAlSi3O8–H2O system at high P and T was deduced from the appearance of quenched products and from water concentrations in the quenched glasses measured by ion probe, calibrated by hydrogen manometry. Starting materials were gels with sufficient water added to ensure saturation of the melts under the run conditions. Experiments were carried out for 10–30 h in an internally heated argon pressure vessel (eight at 1400° C and 0.2–0.73 GPa and three at 0.5 GPa and 900–1200° C) and for 1 h in a piston-cylinder apparatus (three at 1200° C, 1–1.3 GPa). No bubbles were observed in the glasses quenched at P<0.5 GPa or from T<1300° C at 0.5 GPa. Bubble concentration in glasses quenched from 1400° C was low at 0.5, moderate at 0.55 GPa and very high at 0.73 GPa and still higher in glasses quenched in the piston cylinder. Water concentration was measured in all glasses, except for the one at 0.55 GPa, for which it was only estimated, and for those at 0.73 GPa because bubble concentration was too high. Inferred water solubilities in the melt increase strongly with increasing P at 1400° C (from 6.0 wt% at 0.2 GPa to 15 at 0.55 GPa) and also with increasing T at 0.5 GPa (from 9.0 wt% at 900° C to 12.9 at 1400° C). The T variation of water solubility is fundamental for understanding the behaviour of melts on quenching. If the solubility decreases with T at constant P (retrograde solubility), bubbles cannot form by exsolution on isobaric quenching, whereas if the solubility is prograde they may do so if the cooling rate is not too fast. It is inferred from observed bubble concentrations and from our and previous solubility data that water solubility is retrograde at low P and prograde at and above 0.45 GPa; it probably changes with T from retrograde below to prograde above 900° C at 0.5 GPa. Moreover, the solubility is very large at higher pressures (possibly>30 wt% at 1.3 GPa and 1200° C) and critical behaviour is approached at 1.3 GPa and 1200° C. The critical curve rises to slightly higher P at lower T and intersects the three-phase or melting curve at a critical end point near 670° C and 1.5 GPa, above which albite coexists only with a supercritical fluid.  相似文献   

18.
We predict the IR-TO, IR-LO and Raman modes (wave numbers and intensities) of magnesite (MgCO3) up to 50 GPa, at T = 0 K, using the density-functional perturbation theory up to a third order perturbation, under the harmonic assumption. The predicted IR-TO and Raman mode wave numbers, the mode Grüneisen parameters and the Davydov splittings are systematically compared with experimental data for all modes up to the pressures of 10–30 GPa and for some modes up to 50 GPa. Existing experiments allow extending this comparison only to IR-LO wave numbers of the E u (ν3) asymmetric-stretch mode, confirming the odd experimental behavior of this mode at very high pressures. Predicted IR-TO, IR-LO and Raman intensities up to 50 GPa are just tabulated, but data are missing for their comparison with precise experiments. However, the generally good agreement observed between numerical results and experimental data, when their comparison is possible, suggests that first-principles methods are a major help to predict the entire spectrum up to very high pressures.  相似文献   

19.
We have determined the P-V equation of state of Al-rich H-bearing SiO2 stishovite by X-ray powder diffraction at pressures up to 58 GPa using synchrotron radiation. The sample contained 1.8 wt% Al2O3 and up to 500 ppm H2O, and had a composition that would coexist with Mg-silicate perovskite in a subducted slab. By fitting a third-order Birch-Murnaghan equation of state to our compression data, we obtained a bulk modulus K T0=298(7) GPa with K′=4.3(5). With K′ fixed to a value of 4, the bulk modulus K T0=304(3) GPa. Our results indicate that Al3+ and H+ have a small effect on the elastic properties of stishovite. Compared with data obtained up to 43.8 GPa, peak intensities changed and we observed a decreased quality of fit to a tetragonal unit cell at pressures of 49 GPa and higher. These changes may be an indication that the rutile↔CaCl2 transition occurs between these pressures. After laser annealing of the sample at 58.3(10) GPa and subsequent decompression to room conditions, the cell volume is the same as before compression, giving strong evidence that the composition of the recovered sample is also unchanged. This suggests that Al and H are retained in the sample under extreme P-T conditions and that stishovite can be an agent for transporting water to the deepest lower mantle.  相似文献   

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