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1.
In Geropotamos River Basin, located on the north-central part of Crete, Greece, two main factors were believed to be affecting the geochemistry of the groundwater with high salt contents: seawater intrusion and/or Miocene evaporates. To identify the origin of the high salinity in groundwater, a hydrogeochemical and isotopic study was performed. Water samples from 22 wells and 2 springs were analyzed for physico-chemical parameters, major ions analysis, as well as stable isotopes (??18O, ??D). From the present survey, in which detailed hydrogeochemical investigation was conducted, the uncertainty of the contamination sources was decreased in the northern part of Geropotamos Basin. The results complement the scenario in which seawater and the widespread human activities are the principal sources of groundwater contamination. Moreover, the results of the stable isotopes analyses (??18O and ??D) support the same hypothesis and make seawater intrusion the most probable cause for the highest salinity waters. It is indicated that saline intrusion is likely to occur along fractures in a fault zone through otherwise low-permeability phyllite?Cquartzite bedrock, which demonstrates the critical role of fracture pathways in salination problems of coastal aquifers.  相似文献   

2.
金爱芳  李广贺  张旭 《地球科学》2012,37(2):247-252
由于目前缺乏一套完整成熟的地下水污染风险源准确识别与分级方法, 在综合解析污染源结构、污染物输移过程评价的基础上, 构建了涵盖地下水易污性和地下水污染源两部分多因素耦合的风险源识别模型, 其中从污染源特性和污染物性质两方面建立了污染源危害性评价参数体系.以地下水易污性指数和污染源潜在危害性评价指数作为风险源分级指标, 采用乘积模型进行了风险源的评价与分级.选择某水源地对所建方法进行实例分析, 确定了地下水污染的高风险源区.结果表明, 污染源和地下水易污性共同决定了地下水污染的风险源, 所建方法对地下水污染的预防及污染源的有效监管有重要意义.   相似文献   

3.
Rapid population growth and urbanization has placed a high demand on freshwater resources in southeast costal Tanzania. In this paper, we identify the various sources of groundwater and the major factors affecting the groundwater quality by means of multivariate statistical analyses, using chemical tracers and stable isotope signatures. The results from hierarchical cluster analyses show that the groundwater in the study area may be classified into four groups. A factor analysis indicates that groundwater composition is mainly affected by three processes, accounting for 80.6% of the total data variance: seawater intrusion, dilution of groundwater by recharge, and sewage infiltration. The hydrochemical facies of shallow groundwater was mostly of the Na–Ca–Cl type, although other water types were also observed. The deep groundwater samples were slightly to moderately mineralized and they were of the NaHCO3 type. This water type is induced mainly by dissolution of carbonate minerals and modified by ion exchange reactions. The signal from the stable isotope composition of the groundwater samples corresponded well with the major chemical characteristics. In the shallow groundwater, both high-nitrate and high-chloride concentrations were associated with localized stable isotope enrichments which offset the meteoric isotopic signature. This is inferred to be due to the contamination by influx of sewage, as well as intrusion by seawater. The depleted stable isotope values, which coincides with a chemical signature for the deep aquifer indicates that this deep groundwater is derived from infiltration in the recharge zone followed by slow lateral percolation. This study shows that a conceptual hydrogeochemical interpretation of the results from multivariate statistical analysis (using HCA and FA) on water chemistry, including isotopic data, provides a powerful tool for classifying the sources of groundwater and identifying the significant factors governing the groundwater quality. The derived knowledge generated by this study constitutes a conceptual framework for investigating groundwater characteristics. This is a prerequisite for developing a sound management plan, which is a requirement for ensuring a sustainable exploitation of the deep aquifer water resource in the coastal area of Tanzania.  相似文献   

4.
Sustainable development in El Arish area of North Sinai, Egypt, is retarded by serious environmental problems, where the land-use and land cover of the region is changing over present time. The impact of human activities in the study area is accompanied by the destruction and over-exploitation of the environment. This study applies multivariate statistics (factor and cluster analyses) and GIS techniques to identify both anthropogenic and natural processes affecting the groundwater quality in the Quaternary sands aquifer. The aim of this study was to investigate the impacts on groundwater resources, the potential pollution sources, and to identify the main anthropogenic inputs of both nutrients and trace metal. Since the depth to the water table is shallow especially in the northern part (<4?m), and the aquifer was exposed on the ground surface, it has poor buffering capacity and the pollution risk is very high. Groundwater chemistry in this coastal region has complex contaminant sources, where intensive farming activities and untreated wastes put stress on groundwater quality. Several areal distribution maps were constructed for correlating water quality with possible contributing factors such as location, land-use, and aquifer depth. These maps identified both anthropogenic and natural processes affecting groundwater quality of the studied aquifer. Cluster analysis was used to classify water chemistry and determine the hydrochemical groups, Q-mode dendrogram is interpreted and there are three main clusters. Factor analyses identify the potential contamination sources affecting groundwater hydrochemistry such as: nitrate, sulfate, phosphate and potassium fertilizers, pesticides, sewage pond wastes, and salinization due to circulation of dissolved salts in the irrigation water itself.  相似文献   

5.
Zhan  Liangtong  Wu  Linbo  Han  Hua  Zhang  Shuai  Zhou  Honglei  Song  Xue  Zhao  Li  Guo  Qimeng  Chen  Yunmin 《Hydrogeology Journal》2023,31(3):771-787

Tens of thousands of municipal solid waste (MSW) landfill sites worldwide hold a high risk of contaminating groundwater. This study aimed to establish a practical hydrogeological classification system for MSW landfill sites and explores the correlation between the classification and the risk of groundwater contamination. Hydrogeological information and groundwater contamination data from 80 MSW landfill sites in China were collected and analyzed, and a general hydrogeological model was proposed. The key hydrogeological parameters in the model were identified and analyzed, including the relative depth to the water table, the ratio of the length of the MSW site’s recharge boundary to the combined length of the discharge boundary and hydrobalance boundary, the hydraulic conductivity of the bearing layer, and the background hydraulic gradient. On the basis of the general model, hydrogeological conditions at the landfill sites were categorized into seven subtypes. By using chloride, ammoniacal nitrogen and chemical oxygen demand as the characteristic contaminants, the migration features of groundwater contaminants within the seven subtypes of landfill sites were revealed. It was found that the maximum contaminant migration distance could be 2,000 and 300 m at the landfill sites with ‘plain and intensive runoff’ type and ‘valley and weak runoff’ type, respectively, and the corresponding concentration gradients of the characteristic contaminants were less than 10 mg/(L × m) and greater than 10 mg/(L × m). This work provides a guide for implementing cost-effective site investigation and environmental risk management at landfill sites with different types of hydrogeological conditions.

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6.
Numerical modelling was done at the Cold Lake Air Weapons Range, Canada, to test whether the dissolved RDX and nitrate detected in groundwater come from the same sources, and to predict whether contamination poses a threat to the surface water receptors near the site. Military live fire training activities may indeed pose a risk of contamination to groundwater resources, however field investigations on military bases are quite recent, and little information is available on the long-term behaviour of munition residues related contaminants. Very limited information was available about the contaminant source zones, which were assigned based on our knowledge of current training activities. The RDX plume was well represented with the model, but the heterogeneous distribution of nitrate concentrations was more difficult to reproduce. It was nonetheless determined that both contaminants originate from the same areas. According to the model, both contaminants should reach the nearby river, but concentrations in the river should remain very low if the source zone concentration does not change. Finally, the model allowed the recommendation of a new location for the main bombing target, which would offer added protection to the river and the lake into which it flows.  相似文献   

7.
The results of integral pumping tests (IPTs) performed in the city of Fabriano, Italy, are presented. The IPT methodology was developed by the European Union project INCORE, as a tool for groundwater investigation and source localization in contaminated areas. This methodology consists of a multiple-well pumping test in which the wells are positioned along a control plane downstream of suspected contaminant source zones and perpendicular to the mean groundwater flow direction. During the pumping, concentration time series of target contaminants are measured. In Fabriano, two control planes were realized to identify a chlorinated aliphatic hydrocarbon plume, to estimate the mass fluxes and draw up a ranked list of the main contamination sources. A numerical flow model was implemented to support the IPT design and to interpret the results. This study revealed low-level trichloroethylene contamination (concentration below 8 μg/l), tetrachloroethylene contamination (mean concentration up to 500 μg/l) and a mass flow rate of about 300 g/day. Through the application of the IPT method, the mean contaminant concentrations, the spatial distribution of concentration values along the control planes, and the total contaminant mass flow rates were evaluated, and the investigation area was reduced for further and deeper investigation activities.  相似文献   

8.
 Anthropogenic activities create various contaminated leachate, which can migrate downward from the vadose zone to groundwater, transferring contaminants, including some hazardous ones. When these various sources of contamination influence the groundwater aquifer simultaneously, the effects of contamination are enhanced. The major concern of this study has been to determine whether the shape of a groundwater chlorograph might be the result of such deterministic effects as accumulation of one or more particular processes of groundwater contamination, and how this might relate to specific hydrological situations. This study proposes a classification of groundwater contamination on the basis of properties of the main components of groundwater quality graphs and the corresponding hydrogeological/environmental situation. The study further suggests that contamination of groundwater in any hydrogeological situation (e.g. sea water) may be graphically expressed. A variety of chlorographs and nitrographs, representative of various groundwater aquifers sampled from a number of wells throughout Israel attest to this. The study thus indicates that groundwater quality graphs may be considered as a complementary tool for groundwater quality control and better understanding aquifer situations.  相似文献   

9.
山东博山地下水污染研究   总被引：2，自引：0，他引：2  
朱学愚  吴春寅 《地质论评》1996,42(3):278-284
博山是山东省中部的一个工业城市，完全依靠地下水供水。主要的供水水源为中奥统碳酸盐岩石中的裂隙－喀斯特水。城区附近的水源受到相当程度的污染，本文研究了主要的污染源及其污染途径，地下水中主要污染成分及其空间分布特征，用模糊数学方法进行地下水的水质评价，用地质统计学中的趋势面分析和Ｋｒｉｇｉｎｇ方法模拟地下水中污染组分的空间分布，用灰色系统方法和对流弥散方面的特征有限元解进行地下水污染的预测，最后提出了  相似文献   

10.
Agricultural coastal areas are frequently affected by the superimposition of various processes, with a combination of anthropogenic and natural sources, which degrade groundwater quality. In the coastal multi-aquifer system of Arborea (Italy)—a reclaimed morass area identified as a nitrate vulnerable zone, according to Nitrate Directive 91/676/EEC—intensive agricultural and livestock activities contribute to substantial nitrate contamination. For this reason, the area can be considered a bench test for tuning an appropriate methodology aiming to trace the nitrate contamination in different conditions. An approach combining environmental isotopes, water quality and hydrogeological indicators was therefore used to understand the origins and attenuation mechanisms of nitrate pollution and to define the relationship between contaminant and groundwater flow dynamics through the multi-aquifer characterized by sandy (SHU), alluvial (AHU), and volcanic hydrogeological (VHU) units. Various groundwater chemical pathways were consistent with both different nitrogen sources and groundwater dynamics. Isotope composition suggests a mixed source for nitrate (organic and synthetic fertilizer), especially for the AHU and SHU groundwater. Moreover, marked heterotrophic denitrification and sulfate reduction processes were detected; although, for the contamination related to synthetic fertilizer, the attenuation was inefficient at removing NO3? to less than the human consumption threshold of 50 mg/L. Various factors contributed to control the distribution of the redox processes, such as the availability of carbon sources (organic fertilizer and the presence of lagoon-deposited aquitards), well depth, and groundwater flow paths. The characterization of these processes supports water-resource management plans, future actions, and regulations, particularly in nitrate vulnerable zones.  相似文献   

11.
 An early indication of groundwater contamination occurs when pollutant concentrations start to fluctuate and exceed background values of ambient fresh groundwater. An analysis of a characteristic situation of this type uses data from Israel's coastal phreatic granular aquifer. The pollutant is generally seawater, and the contamination process involves replacement of freshwater by encroaching sea- or other saltwater, a process augmented by human activity. The contamination process involves three stages: (1) groundwater composition remains relatively stable with small salinity content; (2) small salinity changes are perceptible with reversible fluctuations; and (3) salinity concentration increases at a sharply higher rate. The second stage is a useful early-indicator signal of contamination. Early-indicator signals of groundwater pollutant concentrations involve "minor" fluctuations in water chemistry at the advent of the contamination process. The intensity and magnitude of such a salinization/pollution process at any given location depends upon lithologic matrix, aquifer heterogeneity, and resultant flow domain characteristics, as well as contaminant properties. If such "signs" are detected at a sufficiently early stage, appropriate management steps may be taken to rectify further seawater and/or saltwater encroachment. Received: 23 July 1996 · Accepted: 25 June 1997  相似文献   

12.
区域性地下水有机污染调查与评价方法   总被引：16，自引：3，他引：13       下载免费PDF全文
借鉴国外区域地下水污染调查经验,针对中国的实际情况,提出了中国区域地下水有机污染调查与评价方法。内容包括有机调查指标选取,采样井选择和清洗、样品采集、保存与送检,实验分析方法和目标检出限,样品野外采集质量控制和实验分析质量控制,有机污染物检出评价、超标评价和相关分析方法。  相似文献   

13.
The purpose of this research is to evaluate the groundwater quality in Dindugal district of Tamil Nadu based on the water quality index by geographic information system (GIS) and statistical analysis. This area consists of 80 functional tanneries around Dindigul town with a capacity to process about 200 Mt of hides and skins as leather. In 13 villages, as many as 1090 houses were damaged by tannery contamination. A total of 66 groundwater samples were collected to identify the geochemical sources and contamination. The order of major cations is Na > Ca > Mg > K, while that of anions is Cl > SO4 > HCO3 > F > PO4. CaCl2, MgCl2, and (CaHCO3)2 types suggested that the mixing of high-salinity water was caused by irrigation return flow, domestic wastewater, and septic tank effluents, with existing water followed by ion exchange reactions. Moreover, Gibbs plots indicated that groundwater contamination was derived from the weathering of granitic gneisses as well as the leaching of evaporated and crystallized ions from agricultural and industrial effluents. The water quality index (WQI) exhibited 8 % of the groundwater samples were not suitable for drinking purpose. The GIS maps showed that the poor water quality decreased toward the southern part of the study area. WQI of TDS, fluoride, sodium, potassium, and bicarbonate were high in groundwater. Multivariate statistical analyses (principal component analysis (PCA), factor analysis (FA)) suggested that the groundwater chemistry was changed by the weathering of source rocks ion exchange and leaching of inorganic components and addition from anthropogenic effluents. Finally, it is thought that the monitoring and assessment works are very useful to understand the degree and sources of groundwater contamination.  相似文献   

14.
The study of hydrogeochemistry of the Mio-Pliocene sedimentary rock aquifer system in Veeranam catchment area produced a large geochemical dataset. Groundwater samples were collected at 52 sites over 963.86 km2 area and analyzed for major ions. The large number of data can lead to difficulties in the integration, interpretation and representation of the results. Two multivariate statistical methods, Hierarchical cluster analysis (HCA) and Factor analysis (FA), were applied to a subgroup of the dataset to evaluate their usefulness to classify the groundwater samples, and to identify geochemical processes controlling groundwater geochemistry. Hydrochemical data for 52 groundwater samples were subjected to Q- and R- mode factor and cluster analysis. R-mode analysis reveals the inter-relations among the variables studied and the Q-mode analysis reveals the inter-relations among the samples studied. The R-mode factor analysis shows that Ca, Mg and Cl with HCO3 account for most of the electrical conductivity, total dissolved solids and total hardness of groundwater. The ‘single dominance’ nature of the majority of the factors in the R-mode analysis indicates non-mixing or partial mixing of different types of groundwater. Both Q-mode factor and Q-mode cluster analyses indicate an exchange between the river water and the groundwater in the vicinity. The rock water interaction like flood basin back swamp deposits of silty clayey formation is the major cause for the cluster II classification. Cluster classification map reveals that 58% of the study area comes under cluster II classification.  相似文献   

15.
Depth-discrete tracing of residual dense non-aqueous phase liquid (DNAPL) sources in the subsurface is of great importance in making decisions related to contaminated groundwater remediation. Temporal variations in the natural tracer 222Rn and contaminant concentrations in groundwater contaminated with multiple chlorinated contaminants, such as trichloroethene, carbon tetrachloride, and chloroform, were examined to trace residual multiple DNAPL contaminants at an industrial complex in Wonju, Korea. The 222Rn activities and multiple DNAPL concentrations in the groundwater fluctuated irregularly according to the groundwater recharge. The natural tracer 222Rn in groundwater present in the soil layer, originating from the underlying crystalline biotite granite, had a wide range from 29,000 to 179,000 Bq/m3, and total concentrations of chlorinated solvents ranged from 0.06 to 17.77 mg/l, indicating the ambiguous results of 222Rn for tracing the residual DNAPL sources. In this paper, a method is presented to locate zones with a high probability of containing depth-discrete residual multiple DNAPL sources using 222Rn and considering relative contaminant concentrations. The results demonstrate that the combination of the 222Rn activities as a natural tracer and the relative contaminant concentrations is able to be used as a useful tool for tracing residual DNAPLs.  相似文献   

16.
Groundwater availability depends on its accessibility, as well as on its quality. Factor analysis (FA) has been used to analyze quality problems and provide strategies for water resources exploitation. The present study demonstrated the use of factor analysis to evaluate temporal variations in groundwater quality and find latent sources of water pollution in coastal areas of Ramanathapuram District, Tamil Nadu, India. The data set included data of eleven water quality parameters viz., pH, electrical conductivity, salinity, total dissolved solids, total alkalinity, calcium hardness, magnesium hardness, total hardness, chloride and fluoride for two different seasons (pre- and post-monsoon) in 2012. FA of the two seasons resulted in two latent factors accounting for 80.38 % of total variance for pre-monsoon (summer) and 73.03 % for post-monsoon (winter) in the water quality data sets. The results obtained from FA prove that the groundwater quality in winter is better than that of summer. Langelier Saturation Index was used to find out scaling and corrosive tendency of the groundwater samples for the study area. Karl Pearson correlation matrix was used to study the correlation between the studied water quality parameters. Hence, the analysis suggests that FA techniques are useful tools for identification of influence of various quality parameters on overall nature of the groundwater.  相似文献   

17.
The deterioration of groundwater quality, particularly due to salinization, because of the overexploitation of groundwater in the Lower Central Plain of Thailand remains a major concern. With increasing demand for water there is a growing need for sustainable management of the resource, which would benefit from an improved understanding of the sources of chloride contamination. Thus, a hydrochemical and isotopic study was carried out to chemically characterize groundwater and to investigate possible sources of salinization, and in particular of chloride contamination, in the multi-layered Bangkok aquifer system. Groundwater samples were taken from four topmost aquifers (Bangkok, Phra Pradaeng, Nakhon Luang, and Nonthaburi). Additionally, short-term rainwater sampling, as well as river and seawater sampling was performed and later analyzed for ionic composition and stable water isotopes. Ionic and isotopic data indicate at least three different recharge sources for groundwater. The major recharge source is rainwater. The influence of seawater is limited to the coastal region and tidally influenced areas of the two main rivers (Chao Phraya and Tha Chin). Bromide data also suggest the influence of saline water in deeper aquifers due to trapped water. Most importantly, although the influence of seawater on groundwater is recognizable, the surrounding geology contributes a significant number of dissolved ions detected in the groundwater.  相似文献   

18.
The application of compound-specific stable isotope analysis (CSIA) was evaluated to characterise a complex groundwater contamination. For this purpose, δ13C and δ2H analysis of benzenes and alkylated derivatives were used to interpret both the impact of different sources on a contaminant plume and the presence of degradation processes. The different contaminant sources could be distinguished based on their combined δ13C–δ2H signature of the benzene, toluene, ethylbenzene and xylenes (BTEX) dissolved in the groundwater. Despite this source differentiation, plume characterisation was not possible due to the complex mixing of the respective contaminant plumes. Furthermore, the original isotope signatures of the sources were not preserved across these plumes. To estimate the level of in situ biodegradation independently from concentration data, the Rayleigh equation was used. Although current literature identifies the application of CSIA as very promising in the frame of characterising organic groundwater pollution, this study has indicated that this approach can be limited with respect to successfully distinguish the different plumes and their relation to the known source zones.  相似文献   

19.
The intensive agricultural and economic activities induce the increase of the risk of groundwater quality degradation through high groundwater pumping rates. The salinization and contamination are the main sources of this pollution, especially in coastal aquifers. The explanation of the origin of salinity for the shallow aquifer of Northern Sahel of Sfax was analysed by a chemical study of the groundwater main compounds. The partitioning of groundwaters into homogenous groups is undertaken by graphical techniques, including a Stiff pattern diagram, an expanded Durov diagram and several binary diagrams. The study indicates the presence of various salinization processes. In the recharge area, salinization is the result of dissolution/precipitation of the aquifer formation material (group I). The irrigation water return and the intensive pumping have been identified as major sources of salinization in the south by direct cation exchange and mixing reactions (groups II and III). The anomaly of high groundwater salinity observed near the Hazeg zone was explained by the presence of a seawater intrusion in this area. This hypothesis is related to the high chloride concentration, to the presence of inverse cation exchange reactions (group IV), and to the piezometric level inferior to sea level. To cite this article: R. Trabelsi et al., C. R. Geoscience 337 (2005).  相似文献   

20.
About 70 percent of hazardous waste sites listed in the National Priority List (NPL) have some groundwater contamination that may require remediation. Such remediation is inadequate if the unsaturated soils above will continue to act as a source of groundwater contamination. Consequently, for most of these sites, it becomes necessary to determine what the cleanup levels for contaminants in soils should be so that subsequent contribution of contaminants from these soils to groundwater would not exceed groundwater protection levels. Representation of the dynamics of interactions between contaminants and soils is very complex, requiring among others, a thorough understanding of the chemical processes that influence the behavior of the contaminant once it enters the subsurface. Because of such complexities, environmental professionals frequently utilize methods with very simple assumptions that tend to err on the conservative side. While the public may feel protected, the needless spending of dollars could be avoided if attempts are made to incorporate, where possible, such complexities in the modeling efforts so that the system is represented as accurately as possible.  相似文献   

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